ISBN-13: 978-0-13-700401-0
ISBN-10: 0-13-700401-X
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9 780137 004010
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Radiation Hazards
Objectives
This chapter provides an overview of pressure, temperature, and radiation hazards in
the process industries, which can affect people and the environment.
After completing this chapter, you will be able to do the following:
■ Name specific hazards associated with pressure and pressurized equipment used in
the process industries and discuss the specific hazards posed by this equipment:
Vacuum
High pressure
Compressed Gases
Pressure Vessels (Runaway Reactions)
■ Recognize the hazards of heat and temperature in the working environment.
■ Understand the effects of ionizing and non-ionizing radiation.
■ Describe governmental regulations and industry guidelines that address pressure,
heat, and radiation hazards.
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Key Terms
Atmospheric pressure—the pressure at Earth’s surface (14.7 psi at sea level).
Conduction—the transfer of heat through matter via vibrational motion.
Convection—the transfer of heat through the circulation or movement of liquid
or gas.
Dose—the amount of a substance taken into or absorbed by the body.
Endothermic—a chemical reaction that requires the addition or absorption
of energy.
Exothermic—a chemical reaction that releases energy.
Heat—the transfer of energy from one object to another as a result of a temperature
difference between the two objects.
Ionizing radiation—radiation that has enough energy to cause atoms to lose elec-
trons and become ions; an extreme health hazard that is usually confined to
restricted areas and requires employees to follow strict guidelines to keep exposure
as low as possible.
Non-ionizing radiation—low-energy radiation such as radio and television waves.
Pressure—the force exerted on a surface divided by its area.
Rad—radiation absorbed dose; the unit of ionizing radiation absorbed by a material,
such as human tissue.
Radiation—the transfer of heat through electromagnetic waves.
Rem—roentgen equivalent man; a unit of measure of the dose of radiation
deposited in body tissue, averaged over the body.
Runaway reaction—a reaction that is out of control; can be either endothermic or
exothermic.
Temperature—the degree of hotness or coldness that can be measured by a
thermometer and a definite scale.
Vacuum—any pressure below atmospheric pressure (14.7 psi).
Introduction
In the process industries, the physical hazards associated with temperature, pressure,
and radiation can cause injury, illness, or death if these hazards are not handled prop-
erly. They can also have short or long-term effects on the environment.
Government agencies use regulations, and the process industries use engineering,
administrative controls, and Personal Protective Equipment to protect or limit person-
nel exposure to temperatures, pressures, and radiation hazards. Process technicians are
required to share the responsibility to protect themselves, their co-workers, and the
community from such hazards.
Process technicians must be able to recognize and understand the temperature,
pressure, and radiation hazards associated with their operating facilities and how these
hazards can impact local communities.
This chapter provides an overview of the temperature, pressure, and radiation
workplace hazards that process technicians might encounter. Each hazard is briefly
described, along with its potential effects.
Pressure Hazards
We are constantly surrounded by air that pushes on every surface it touches. Pressure
is the force exerted on a surface divided by its area.
P = F/A
At sea level, air exerts a pressure on the surface of Earth of 14.7 pounds per square
inch (psi). We call this atmospheric pressure. Any pressure below 14.7 psi is referred to
as vacuum.
It is important for process technicians to understand the concept of pressure and
its impact on processes, equipment, and the human body. For example, pressure is used
frequently in the process industries to move fluids through pipes, hoses, and equip-
ment. Our bodies also use pressure to circulate our blood, operate our lungs, and con-
trol other functions such as balance and hearing.
Process technicians must familiarize themselves with the proper operation and
maintenance of pressure-related processes and equipment, and learn to respect the
hazards of compressed gases and air.
While the specific details of pressured equipment operations and maintenance are
outside the scope of this textbook, technicians can do several things to reduce pres-
sure-related hazards:
• Perform proper maintenance.
• Conduct periodic inspections.
• Ensure proper storage or placement of pressurized equipment and storage vessels
(e.g., store in locations away from heat or cold, if possible).
• Ensure that lines and hoses are firmly clamped.
• Release pressure before working on pressurized equipment.
• Use shielding around high-pressure systems.
• Limit access to areas near high-pressure systems.
• Compressed gases
• Runaway reactions in pressure vessels
Vacuum
A vacuum occurs when the pressure inside equipment is less than the air pressure
outside of the equipment. If the equipment is not designed for use with a vacuum, it
could implode and cause significant damage and/or potentially cause the release of
toxic substances. Less-than-atmospheric pressures and changes in atmospheric condi-
tions can also be caused by weather phenomena such as hurricanes and tornadoes.
High Pressure
High pressure can occur due to thermal expansion of a fluid inside its container.
Take water, for example. When water is heated to its boiling point (212°F), it expands
up to 1,600 times its original volume when converted from a liquid to a gas! This type
of thermal expansion can cause pipeline ruptures, fractures, and other equipment dam-
age. That is why pressurized systems are typically designed to handle expansion, and
include safety relief valves that reduce the pressure if it reaches a dangerous level.
Compressed Gases
Compressed gases can be extremely dangerous if suddenly released. For example,
if a cylinder of compressed gas (e.g., a scuba tank or a tank of helium used to blow up
balloons) develops a substantial leak, or if the tank falls over and the valve on the top
of tank breaks off, the cylinder may immediately be propelled like a rocket since the
energy being released from the leak can have more force than the weight of the cylin-
der. This can cause serious injury to personnel and equipment. That is why it is
extremely important for process technicians to inspect compressed gas cylinders peri-
odically, and report any that appear dangerous or are not secured properly.
Another hazard of compressed gases is they can replace oxygen and potentially
cause a hazardous atmosphere if they are released in a small or confined space, or if
flammable, can rapidly release a cloud of gas or toxic material.
Compressed air can also be dangerous if it is not handled properly. For example,
air lines can whip around or cause flying debris that can damage the eyes or other parts
of the body, or damage equipment. In extreme cases, compressed gases or steam can be
powerful enough to cut through the skin and cause serious physical injury or death.
Because of this, process technicians should never point air lines directly at a person,
use them for horseplay, or use them to clean any parts or clothing on the body.
Runaway Reactions
A runaway reaction is a reaction that is out of control. These types of reactions can
be extremely dangerous and difficult to stop. Reactions can be exothermic (generating
heat) or endothermic (consuming heat). If an exothermic reaction gets out of control,
the reaction vessel can become over-pressurized due to the uncontrolled release of
heat or gas generation, which increases the pressure. If an endothermic reaction gets
out of control, a vacuum can form inside the vessel as a result of pressure drops due to
a drop in temperature.
Pressure Leaks
Pressure leaks can be difficult to determine. If enough fluid leaks out, equilibrium
with the surrounding atmosphere may be reached and the leak may stop.
Leaks can be caused by a variety of factors, including the following:
• Dirty or damaged valves, threads, gaskets, and other devices used to control flow
• Vessel over-pressurization
• Thermal expansion of joints and materials due to temperature fluctuations
Temperature Hazards
Temperature is the degree of hotness or coldness that can be measured by a ther-
mometer and a definite scale. Extremely hot or cold temperatures can affect how peo-
ple work and their performance.
Process technicians face temperature hazards from equipment and processes (e.g.,
fired equipment, unfired pressure vessels, refrigeration, and cryogenics) that produce
extremely hot or cold working environments.
HEAT
Temperature and heat are not the same. Heat is the transfer of energy from one object
to another as a result of a temperature difference between the two objects. Heat
energy moves from hot to cold, and it cannot be created or destroyed; it can only be
transferred from object to another. Heat can be transmitted in three different ways:
conduction, convection, or radiation.
Conduction is the transfer of heat through matter via vibrational motion from
one object touching another, such as from a frying pan on a stove burner to an egg in
the pan.
Convection is the transfer of heat energy through the circulation or movement of a
fluid (liquid or gas), such as warm air being circulated through a heating system.
Heat Rash
Heat rash is a series of raised bumps or blisters on the skin that feel “prickly” to
the person. This condition occurs when sweat does not evaporate properly, such as in
high humidity environments.
Heat fatigue and heat collapse are other possible heat stress conditions. Sunburn is
another potential heat-related hazard.
Heat Exhaustion
Heat exhaustion can also be caused by sustained physical exertion in a hot envi-
ronment, along with inadequate replacement of water and salt lost through sweating.
Heat exhaustion occurs when the body’s water and/or salt levels become lower than
normal. As the body becomes dehydrated, the amount of circulating blood is reduced.
Following are common symptoms of heat exhaustion:
• Clammy, damp skin
• Pale or flushed skin
• Fainting/dizziness
• Fatigue
• Nausea
• Headache
If any of these symptoms occur, emergency personnel should be notified and the
person should be moved to a cool place where they can drink plenty of liquids (avoid
alcohol and caffeine, however).
Heat Stress
Heat stress is a common hazard associated with excessive temperatures. Heat
stroke (sometimes referred to as “sun stroke”) is one type of heat stress that happens
when the body’s ability to sweat becomes impaired or breaks down, causing the core
temperature to rise rapidly.
Prolonged physical activity in a hot environment can cause heat stress. Other fac-
tors that can contribute to heat stress are obesity, poor physical shape, and cardiovas-
cular disease. A person experiencing heat stress must be cooled down immediately. The
first step is to contact emergency personnel, then move the person into a cool environ-
ment and cover them with a damp sheet or spray them with cool water and fan them
with a newspaper or fan.
Heat Stroke
Heat stroke is one of the most serious heat-related conditions. It can occur even in
people who are not exercising if temperatures are hot enough. Individuals suffering
from heat stroke have warm, flushed skin and do not sweat. In most cases, heat stroke
victims also have a very high temperature (106 degrees F or higher), and may become
delirious, lose consciousness, or have seizures.
These individuals need to have their temperature reduced quickly, and must be
given IV fluids for rehydration. Emergency medical treatment should be sought as
quickly as possible. A hospital stay for observation may be required following heat
stroke since many different body organs can fail as a result of the excessive tempera-
tures and their physiological effects.
• Add salt to food, if necessary, to replenish salt lost due to sweating (salt tablets
should not be used).
• Avoid working outdoors between noon and 2 p.m. if possible, or at least limit
your exposure.
• Wear appropriate clothing and Personal Protective Equipment.
• Use a sunscreen (the Sun Protection Factor, or SPF, indicates the length of sun
exposure; for example, SPF 15 indicates 15 times longer sun exposure than
without sunscreen).
• Get enough sleep and eat light meals.
• Pay attention to the warning signs of heat stress hazards, for yourself and your
co-workers.
• Understand how certain gear such as respirators and protective suits can reduce
the body’s ability to tolerate heat.
• Avoid contact between skin and extremely hot surfaces.
Companies can also reduce heat-related hazards by limiting non-essential tasks in
hot environments or adding extra workers. Following are some other controls:
• Work-rest periods
• Climate-controlled facilities (air conditioning, fans, ventilation)
• Heat shielding and insulation
• Heat hazard and heat acclimation training
• Worker monitoring
• Personal Protective Equipment (e.g., reflective clothing, insulated suits and
gloves, face shields, ice vests, air cooled garments, vortex coolers, and water-cooled
garments)
COLD
Process technicians can also be exposed to cold conditions in the workplace. For exam-
ple, technicians may have to work outside in extremely cold conditions, or they may
experience cold due to process requirements or equipment. When the body is unable
to warm itself properly, serious cold-related injuries can result. Permanent tissue dam-
age or even death can occur.
Low temperatures, combined with wind speed and moisture, can result in cold-
related injuries. Wind speed can make the body sense coldness lower than the ther-
mometer reading. This is called the wind-chill factor. Temperature and wind-chill fac-
tor combine to determine a temperature colder than what a thermometer may
indicate. Along with moisture, wind can increase the hazard posed by cold tempera-
tures considerably.
Cold-related injuries are considered to be either generalized (affecting the whole
body) or localized (affecting a particular body part, such as the feet).
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Hypothermia
Hypothermia is a general hazard, during which the core body temperature drops
to dangerous levels, below 95° F. Symptoms of hypothermia include the following:
• Fatigue/drowsiness
• Uncontrollable shivering
• Cool, blue-colored skin
• Slurred speech
• Uncoordinated movements
• Irritable, confused, or irrational behavior
If not treated, hypothermia can result in death. Therefore, if hypothermia is sus-
pected, immediately contact emergency personnel, then move the person to a warm,
dry area. Remove any wet clothing and replace with dry clothing, then wrap the person
in blankets. Have the person drink warm, sweet drinks such as sugar water or sports
drinks (avoid caffeinated beverages). Have the person move the extremities to create
muscle heat. If this isn’t possible, place warm water bottles or hot packs on the arm pits,
groin, neck, and head. DO NOT rub the body or place the person in warm water.
Frostbite
Frostbite is a localized hazard that generally affects the hands, feet, fingers, toes,
ears, and the nose. Frostbite involves a freezing of deep layers of skin and tissue.
Following are symptoms of frostbite:
• Sensation of cold
• Hard, numb skin
• Tingling or stinging feeling
• Cramps
• Pale, waxy white skin color
If frostbite is suspected, contact emergency personnel, then move the person to a
warm, dry area. Remove any tight or wet clothing that affects the frostbitten area. Place
the affected area in a warm water bath (105 degrees F) to slowly warm the area. DO
NOT rub the affected area, or pour warm water directly on the affected area. If there is a
chance the affected area could get cold again, do not warm it until the person can stay in
a warm area. If the affected area is warmed then becomes cold again, tissue damage can
occur.After 25-40 minutes of warming, dry the affected area and wrap it to keep it warm.
Frostnip
Frostnip is a mild case of frostbite. If not treated properly, frostnip can become
frostbite. Trench foot is a frostnip-type condition caused by cold, wet environments (but
not freezing). Symptoms include foot pain, tingling, swelling, and itching. If not treated,
trenchfoot can result in tissue death and blistering, permanently damaging the foot.
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Process technicians can use a variety of ways to counter cold-related hazards, such
as the following:
• Acclimate to the environment by gradually increasing exposure to the cold work
environment.
• Drink plenty of warm drinks, including water and sports drinks, while avoiding
caffeinated drinks.
• Avoid working outdoors during the coldest part of the day, if possible, or at least
limit your exposure.
• Wear appropriate clothing in layers and Personal Protective Equipment.
• Use the buddy system.
• Keep feet and extremities dry.
• Take frequent, short breaks in a warm, dry shelter.
• Get enough sleep and eat warm, high-calorie meals (like pasta).
• Pay attention to the warning signs of cold hazards, for yourself and your co-workers
• Avoid contact between skin and extremely cold surfaces.
BURNS
The skin, the body’s largest organ, is composed of a tough outer layer called the
epidermis and an inner layer called the dermis. The skin provides these important
functions:
• Protection
• Secretion
• Respiration
• Sense
Burns prevent the normal functioning of skin, hindering its ability to protect vital
internal organs and disrupting the other functions listed above. The severity to which a
burn injures or damages the skin, and how deep the damage goes, is based on the
following:
• First-degree burns affect the outermost layer of skin, and result in a mild skin
inflammation (such as sunburn); the person may feel some pain and the skin can
feel sensitive to touch.
• Second-degree burns affect the outermost and underlying layer of skin, and result
in blisters, pain, redness, and swelling. The person feels more intense pain and the
skin is sensitive to touch.
• Third-degree burns extend into deep tissues under the skin and result in black-
ened, charred skin or white skin that can be numb. Moist burns from steam or hot
liquids produce white skin, while dry burns from fire or hot surfaces cause black-
ened, charred skin. Third degree burns can be fatal.
Along with the degree of burn, the surface area of the body burned is critical.
Burns covering more than 75 percent of the body’s surface area can be fatal. Burns are
classified as minor, moderate, or critical based on the degree of burn and the area
burned.
Both hot and cold objects can produce burns. Hot objects transfer heat to the skin,
while cold objects take heat from the skin. Cold burns can result from prolonged expo-
sure to moderately cold objects (such as snow) or brief contact with extremely cold
objects (such as dry ice or liquid nitrogen).
Chemicals can also cause burns if they come into contact with the skin. Chemical
burns are covered in the Chemical Hazards chapter.
RADIATION HAZARDS
Radiation is defined as energy traveling through space, either as rays or waves of parti-
cles. Radiation is a part of our daily lives, in sunlight, cell phones, power lines,
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Epidermis
Normal Dermis
Skin
Deep Tissue
Epidermis
1STDegree Dermis
Burned Skin
Deep Tissue
Epidermis
2ND Degree Dermis
Burned Skin
Deep Tissue
Epidermis
3RD Degree Dermis
Burned Skin
Deep Tissue
microwaves, radios, televisions, X-rays, and so on. We are exposed to background radi-
ation on a daily basis.
There are two types of radiation:
• Ionizing
• Non-ionizing
Process technicians may encounter both types of radiation in the workplace.
Various radiation sources can be found in a wide range of industrial settings. If radia-
tion is not properly controlled, it can prove hazardous to the health of workers. For
example, in the process industries radiation can be generated by processes, instrumen-
tation, testing, and other sources.
Ionizing radiation is radiation that is powerful enough to causes atoms to release
electrons and become ions.
Examples of ionizing radiation include x-rays and gamma rays. Ionizing radiation
can cause damage to the tissues and organs of the body. Ionizing radiation can also
cause mutations which could lead to cancer or birth defects. Ionizing radiation takes
two forms:
• Particulate (alpha, beta, neutrons)
• Electromagnetic (x-rays, gamma rays, high-speed electrons, and high speed protons)
9.5% 9.5%
6% 6%
3.5% 3.5%
• Ultraviolet (UV)
• Visible Light
Radiation at these low frequencies does not have enough energy to ionize atoms,
and thus does not damage tissue and organs as readily as ionizing radiation. The
higher frequencies of electromagnetic radiation, x-rays, and gamma rays, do have
enough energy to ionize atoms and are considered ionizing radiation. Non-ionizing
radiation can still cause damage though, as it can heat the skin and cause blisters or
damage vision.
Ionizing Radiation
A dose is the amount of a substance taken into or absorbed by the body. A dose of
radiation is the amount of ionizing radiation absorbed by the body, based on the unit of
mass for the body part that received the dose or the entire body. A dose is measured in
rads, the amount of ionizing radiation energy absorbed by body tissue related to the
mass of the tissue. A rad is equal to the absorption of 100 ergs per gram of tissue (an
erg is an extremely small unit of energy). A rem is a measure of ionizing radiation
dosage, based on the biological effect of that radiation on body tissue, compared to an
X-ray dosage. A millirem is one-thousandth of a rem.
DANGER
RADIOACTIVE
MATERIAL FIGURE 7-5 Radiation Symbol
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• The maximum dosage to the entire body over the calendar quarter does not
exceed three rems.
• The entire body dosage, when added to the accumulated occupation dosage to the
entire body, does not exceed 5(N-18) rems, where N is the person’s age.
• The company maintains updated records that show the worker’s past and current
exposure, to indicate that the addition of a dosage will not exceed the worker’s
specified dose.
The Nuclear Regulatory Commission (NRC) states that the total internal and
external dose for a worker cannot exceed five rems per year. Pregnant workers must
not exceed a dosage of 0.5 rems over the term of the pregnancy.
Personal monitoring devices must be used where appropriate. These devices
include dosimeters, film badges, and other similar devices worn or carried by a worker,
to measure the radiation dosage received. Special Personal Protective Equipment
(PPE) can also be worn when working in areas with radiation hazards (e.g., shielded
aprons, gloves, and radiation suits).
Access to areas with radiation hazards can be restricted. A radiation area is any
accessible area where a radiation hazard can deliver a dose of five millirem in one hour
to a major portion of the body, or 100 millirem over five days to a major portion of the
body. A high-radiation area is any accessible area where a radiation hazard can deliver
a dose of more than 100 millirem in one hour. Caution signs must be used to mark radi-
ation areas, high-radiation areas, areas where radioactive materials are stored, airborne
radioactive areas, and containers used to store radioactive materials. Companies that
produce, use, store, or transport radioactive materials may also have an auditory warn-
ing signal in the event the facility must be evacuated.
The best protection from radiation exposure is to distance yourself from the
source. The reduction in intensity is inversely proportional to the square of the distance
from the source. In other words, the intensity drops off rapidly as you move away from
the source.
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Radiation source shields can melt or be destroyed by fire and the source unaf-
fected. Because of this, process technicians should always follow post-fire procedures
for entering areas with radiation sources.
Ionizing radiation used in pipe and vessel x-rays can cause instrumentation to pro-
duce false readings where nuclear gauging is used and also cause flame detectors in
boilers and furnaces to fail. These instrument failures could be hazardous, so process
technicians need to be aware of their possibilities. All radiation-related problems must
be reported to the designated site-radiation safety representative.
Companies are required to notify OSHA of incidents and keep records and
reports of overexposure, along with cumulative exposure totals.
Various regulations apply to storage and disposal of radioactive materials, including
hazardous waste operations (HAZWOPER), which regulate hazardous material cleanup.
Radioactive materials must also be protected from unauthorized removal, so com-
panies that handle radioactive materials above certain regulatory quantities must be pre-
pared to deal with terrorist attacks or other attempts to gain control of these materials.
Non-Ionizing Radiation
Sunlight is the most common form of electromagnetic energy, consisting primarily
of infrared and ultraviolet light. Ultraviolet radiation from sunlight can cause eye dam-
age, premature aging of the skin, and skin cancers (such as melanoma). Workers can
protect themselves from these hazards by using sunscreen, and wearing appropriate
clothing and eyewear when outdoors.
Government Regulations
While OSHA does not have specific standards that address temperature in the work-
place it does publish fact sheets for working in hot and cold environments.
For pressure-related hazards, OSHA does not have one specific standard for pres-
sure vessels. Some OSHA standards require a pressure vessel to be built in accordance
with the industry codes and standards. Compressed gases are covered in 1910.101.
For radiation in the workplace, the following government regulations apply:
• Non-ionizing radiation OSHA 1910.97
• Ionizing radiation OSHA 1910.1096
• Hazardous Waste Operations (HAZWOPER) 1910.120 and 1926.65
• Occupational radiation protection Department of Energy 10 CFR 835
• Standards for protection against radiation Nuclear Regulatory Commission 10
CFR 20
Summary
In the process industries, the physical hazards associated with temperature, pressure,
and radiation can cause injury, illness, or death if these hazards are not handled prop-
erly. They can also have short or long-term effects on the environment.
Government agencies use regulations, and the process industries use engineering,
administrative controls, and Personal Protective Equipment to protect or limit person-
nel exposure to temperatures, pressures, and radiation hazards. Process technicians
share the responsibility to protect themselves, co-workers, and the community from
such hazards.
Process technicians must be able to recognize and understand the temperature,
pressure, and radiation hazards associated with their operating facilities and how these
hazards can impact local communities.
3. ____________ is the transfer of energy from one object to another as a result of a tempera-
ture difference between the two objects.
a. Temperature
b. Pressure
c. Radiation
d. Heat
4. Define convection, conduction, and radiation.
5. How many liters of sweat can a person lose if working extremely hard or in hot conditions?
6. What is the serious medical condition that occurs when the body’s ability to sweat becomes
impaired or breaks down, and the core temperature rises rapidly?
a. Heat stroke
b. Heat cramp
c. Heat stress
d. Metabolic heat
7. Which of the following is NOT a good recommendation for protecting yourself against heat
stress?
a. Drinking fluids regularly
b. Eating light meals
c. Drinking caffeinated beverages
d. Avoiding work outdoors between noon and 2 p.m.
8. (True or False) Hypothermia is a localized cold-related injury, only affecting extremities
such as the hands, feet, or nose.
9. ________ can prevent the normal functioning of skin, hindering its ability to protect vital
internal organs.
a. Frostbite
b. Hypoxia
c. Narcosis
d. Burns
10. Which of the following is NOT a type of ionizing radiation?
a. X-ray
b. Alpha particle
c. Gamma ray
d. Microwave
e. High speed electron
11. (True or False) Sunlight is a form of electromagnetic radiation.
Student Activities
1. Look on the OSHA web site for information on pressurized vessels or compressed gases.
Find out what the hazards are and how they can be prevented (controls). Make a list of haz-
ards and potential controls.
2. Research a heat stress or cold stress-related medical condition and write a one-page paper
describing the condition, potential effects (e.g. tissue damage, death), symptoms and treatment.
3. Use the Internet or library to research the short and long terms effects of radiation on peo-
ple and the environment, from either Hiroshima/Nagasaki or Chernobyl. Then, report the
findings to your fellow classmates.