Lecturer : Dr. Ir.

Kuswandi, DEA

Example 14.2 (Smith & Van Ness Hal 566)

Diketahui : Methane(1)/n-Butane(2) Binary System

Base Calculations on the Soave/Redlich/Kwong Equation

T = 100 F

Ditanya : P-x-y Diagram at 100 F ?

Penyelesaian :

T = 100 F = 310.93 K = 37.7778 C

R = 83.14

Parameter Assigments for Soave/Redlich/Kwong Equation

σ ϵ Ω Ψ Zc
1 0 0.08664 0.42748 0.3333333

Tabel B.1 Characteristic Properties of Pure Species

Komponen Tc/K Tr ω α (Tr) Pc/bar

methane (1) 190.6 1.6313 0.012 0.742533 45.99
n-butane (2) 425.1 0.7314 0.2 1.2411129 37.96

Tabel B.2 Constants For The Antoine Equation

Komponen A B C logPvi Pvi (bar) ai bi

methane (1) 3.7687 395.744 266.681 2.4689 294.3555 1.7331E+06 29.852998
n-butane (2) 3.93266 935.773 238.789 0.5491 3.5410 1.7458E+07 80.666528
Rumus-rumus perhitungan :

 
1.  SRK  1  0,480  1,574  0,176 1  Tr
2 1/ 2
  2

  Tri  R 2Tci2
a
2. i  T   
Pci
RTci
3. bi   P
ci
Bi
log Pvi  Ai 
4. Ci  T
T
Tri 
5. Tci
K i xi
6. yi 
 K i xi
i

a l  x12 a1  2 x1 x2 a1a2  x22 a2

7.

8. b  x1b1  x2b2
l

bP

9. RT
Z 
Z  1    q
10. Z  Z   
a (T )
q
11. bRT

  2 x1 a1  2 x 2 a1 a 2 b 
q1  q   1
 a b
12.  

  2 x 2 a 2  2 x1 a1 a 2 b2 
q 2  q 
 a b 
13.  
Z 
I  ln
14. Z

 bi 


15. i  exp  b  Z  1  ln  Z     qiI 

iL
16. K i   v
i
Trial P awal, Trial Z awal

x1 x2 P a b β q q1 q2 Z Guess
0 1 11.42 1.7458E+07 80.6665 0.0356 8.3722 2.1774 8.3722 -0.00011906 0.36839
0.1 0.9 22.03721 1.5149E+07 75.5852 0.0644 7.7529 2.1827 8.3719 -2.6354E-10 0.09282732
0.2 0.8 41.42412 1.3003E+07 70.5038 0.1130 7.1344 2.1885 8.3708 -3.4927E-09 0.16860145
0.3 0.7 61.62612 1.1021E+07 65.4225 0.1560 6.5165 2.1948 8.3687 2.4745E-09 0.24309542
0.4 0.6 82.34839 9.2026E+06 60.3411 0.1922 5.8997 2.2018 8.3649 -1.4789E-09 0.31660661
0.5 0.5 102.9208 7.5482E+06 55.2598 0.2200 5.2840 2.2094 8.3587 -5.6797E-10 0.38972329
0.6 0.4 121.861 6.0576E+06 50.1784 0.2365 4.6699 2.2175 8.3486 1.5166E-13 0.46373117
0.7 0.3 135.711 4.7308E+06 45.0971 0.2368 4.0580 2.2261 8.3324 5.0667E-11 0.54195334
0.8 0.2 135 3.5678E+06 40.0157 0.2090 3.4490 2.2347 8.3063 -7.4165E-05 0.63620671

y1 y2 a b β q q1 q2 Z Guess
0 1 1.7458E+07 80.6665 0.0356 8.3722 2.1774 8.3722 -0.000238658 0.36839
0.792 0.20756 3.6500E+06 40.4001 0.0344 3.4949 2.2341 8.3087 -1.34501E-08 0.91207
0.861 0.13931 2.9418E+06 36.9319 0.0592 3.0814 2.2395 8.2826 -1.88177E-07 0.87765
0.879 0.12085 2.7634E+06 35.9939 0.0858 2.9699 2.2408 8.2738 4.93213E-07 0.83826
0.880 0.11999 2.7552E+06 35.9503 0.1145 2.9647 2.2409 8.2734 -1.11313E-07 0.795
0.869 0.13142 2.8649E+06 36.5309 0.1454 3.0337 2.2400 8.2790 -1.3833E-07 0.74744
0.843 0.15711 3.1192E+06 37.8365 0.1784 3.1890 2.2381 8.2904 6.26904E-07 0.69387
0.794 0.20636 3.6369E+06 40.3390 0.2118 3.4876 2.2342 8.3084 2.65867E-07 0.62909
0.800 0.2 3.5678E+06 40.0157 0.2090 3.4490 2.2347 8.3063 -7.27374E-05 0.63624
 Liquid Vapor
K1 K2 Σ Kixi y1 y2
I Φ1 Φ2 I Φ1 Φ2
0.0923 1.9456 0.7376 0.0923 1.9456 0.7376 1.0000 1.0000 1.0000 0.0000 1.0000
0.5272 7.7888 0.1620 0.0371 0.9829 0.7026 7.9244 0.2306 1.0000 0.7924 0.2076
0.5129 4.1152 0.0949 0.0653 0.9563 0.5448 4.3034 0.1741 1.0000 0.8607 0.1393
0.4957 2.7375 0.0713 0.0975 0.9342 0.4130 2.9305 0.1726 1.0000 0.8791 0.1209
0.4744 2.0170 0.0609 0.1346 0.9168 0.3047 2.2000 0.2000 1.0000 0.8800 0.1200
0.4476 1.5763 0.0574 0.1778 0.9074 0.2182 1.7372 0.2628 1.0000 0.8686 0.1314
0.4122 1.2827 0.0595 0.2288 0.9131 0.1516 1.4048 0.3928 1.0000 0.8429 0.1571
0.3625 1.0797 0.0705 0.2902 0.9523 0.1024 1.1338 0.6879 1.0000 0.7936 0.2064
0.2840 0.9458 0.1062 0.2840 0.9458 0.1062 1.0000 0.9999 1.0000 0.8000 0.2000