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STD-BSI BS 6920-3-ENGL 2000 m Lb24664 0849373 044 m


BRITISH STANDARD BS 6920-1:2000

Suitability of
non-metallic products
for use in contact with
water intended for
human consumption
with regard to their
effect on the quality of
the water -
Part 1: Specification

ICs 13.060.20

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BS 6920-1:2000

Committees responsible for this


British Standard
The preparationof this British Standardwas entrusted by T ech ni Committee
d
EHß, Water q u a l i t y 7 to SubcommitteeEHßf7, Effects of materials on water@ t y 7
upon whichthe following bodies were represented:

Association of Manufacturem of Domestic Electrical Appliances


Automatic VendingAssocion of Britain
British Bathroom Council
British Cement Association
British coatings Federation Ltd.
British MalleableW e Fittings Association
British Non-Ferrous Metals Federation
British Plastics Federation
British Plumbii Fittings Manufacturers' Associon
British Precast Concrete FederationLtd.
British RubberManufacturem'Association
British Valve and Actuator manufacture^' Association
British Water
Department of the Environment for Northern Ireland
The Drink& Water Inspectorate
Galvanizem Association
Laboratory of the Government Chemist
Lead Development Association
Pipeline Industries Guild
UK Steel Association
UK Water Byelaws Scheme
Water Research Centre
Water UK
Zinc Development Association

This British Standard, having


been prepared under the
M o n of the Health and
Environment Sector committee,
was publishedunder the
authority of the Standards
Committee and comes into effect
on 15 May 2000
Q Es1 05-2000
Amendments issued since publication
Amd No. Date Comments

The following BSI references


relate to the work on this
British Standad
Committee reference EX"
DraR for comment 99/560123 DC

di2
ISBN O 580 33103 2 ..,. .* .P 1

. . ... . ..
. ..

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Contents

page
Committees responsible Inside front cover
Foreword ii
Intxoduction 1
1 Scope 1
2 Normative references 2
3 Terms and defínitions 2
4 Odour and flavour of water 2
5 Appearance of water 3
6 Growth of aquatic microorganisms 3
7 The extraction of substances that may be of concern to public health 3
8 The extraction of metals 3
9 High temperature tests 4
10 Odour and flavourof water from hoses intended for food and drink
mDlication
"
4
Annex A (informative) Scheme oftesting showing the relationship between the
standards of the BS 6920 series 5
Bibliography 7
Table 1 - Maximum allowableconcentrations of certain
metals 4

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Foreword

This part of BS 6920 has been preparedby SubcommitteeEHE37 under the


direction of the Health andEnvironment Sector Committee.This part of BS 6920
supersedes E S 692@1:1996,which is withdrawn
It is intended that appropriate British Standards and other specifications should
for the effects of the
crossrefer to this part of J3S 6920 if they specify requirements
specified product on the quality of water intended for human consumption.
Part 1 Spec@kation, Part 2Methods
BS 6920 is published in several parts, namely
of test, Part3 High temperature tests and Part 4 l%eGCMS ident.ification of water
leachable organic substance.
Part 2 is further subdividedi n t ~a number of sections and subsections as follows.
Section 2.1:S a m p h for testing;
SecEiOn 2.2:O h r and Flavour of water;
Subsection 2.2.1:Geneml method of tesc
MeUwd of testing alours a n d j l u w m imparted
Subsdion 2.2.2: to water by hoses
and composite pipes and tubes;
Subsec- Method of testing odmm a n d j l u w m imparted to water by h s e
2.2.3:
for conveying waterforfood and drink prepamtion;
Sectàun 2.3:Appeamnce of water;
Section 2.4:GroLvth of aquatic microolganisms;
Section 2.5:l7t.e e c t m c t b of substances that may be of concern to public M@
ktion2.6 m extmtàunO f m e t a l S .
Annex A is informative.
A British Standard does notpurport to include all the necessary provisions of a
contract Usem of British Standards are responsible for their correct application.
Compliance with a British Standard does not of itself confer immunity
from legal obligations.

Summary of pages
This document'comprisesa h n t cover, an inside h n t cover)pages i and ii, pag& 1
to 7 and a back cover.
the document was
The BSI copyright noticedisplayed in this document indicates when
lastissued.

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BS 6920-1:2000

Introduction Since there is no single test that can discriminate


The most common consumer complaint concerning between harmless andharmful extracts, the
cytotoxicity requirements given in clause 7 are meant
the wholesomeness of water intended for human
consumption is the presence of unacceptable taste. only as a preliminary screening test for extracts from
The role of construction and plumbing materials in products in contact with water intended for human
giving rise to certain typesof taste in water is well consumption. Passingthe tests indicates that
documented. Although the assessment of odours and extracts probably do not contain significant amounts
of acutely toxic substances, butthe tests cannot be
flavours is subjective, semiquantitative methodsof
assessing odours and flavours in water have been used to indicate the presence or absence of
used by the water industry for operational control substances that may be harmful on prolonged
exposure. A failure in thetests indicates that the
and quality monitoring purposes for many years.
The EC Directive relating to the quality of water product requires further investigation before it can
be accepted for use in contact with water intended
intended for human consumption (80/778/EEC)[ 11
specified for the first time a maximum admissible for human consumption.
threshold level fortaste in water intended for human Clause 8 deals with the extraction of certain metals,
consumption, andthis value is derived from the undesirable in excessive amounts, from non-metallic
assessment by individuals of a series of successive products. The limits for these metalsare given
dilutions of the water sample under examination. in Table 1. The range of metals included inthis
The latest version of this Directive (98/83/EC)[4] specification reflects the current knowledge and
states that odour andtaste of water shall be experience of metals likely to arise in waters
"acceptable to consumers and no abnormal intended for human consumption,as a result of
change" (sic). contact with the materials of construction of water
storage and distribution systems. Products submitted
The criteria usedto assess the ability of a product to
support an appreciable growth of aquatic for testing in accordance with BS 6920 in the future
may contain other metals whichmay be undesirable
microorganisms have been determined from a review
of data obtained fromthe use of the method in excessive amounts but whichare not listed
in Table 1. In this case, it will be necessary to obtain
described inBS 6920-2.4:2000 during investigations
an expert opinion from a competent national
into incidentsof microbial contaminationof water
intended for human consumption over a period authority onthe desirability of including their
determinations in this test.
of 20 years.
When samples drawn from more than one These tests were originally designed for materials
used in contact with cold water intended for human
commercial batchof a product are compared for the
consumption at temperatures up to 25 "C. BS 6920-3
purpose of quahty assurance or formulation
was introducedto allow these tests to be applied to
development, some variation inthe results should be
anticipated. Any variation in results should be materials likelyto be used in contact with hot water
critically examinedin light of the precision of the which may subsequently bedrunk.
method and alsothe homogeneity of the material or Clauses 9 and 10 deal with the specific requirements
the conditions employed during manu€actureor of products intended for use in contact with hot
storage, as these can substantially alterthe water intended for human consumption or culinary
characteristics of some products with respectto the use, and of hoses intended for conveying water for
availability of chemical substances that act as food and drink preparation respectively.
nutrients for microbialgrowth. NOTE A diagram showing the relationship of the various parts
and sections of this standard is given in annex A.
The criteria given in clause 6 have been set in the
light of the precision of the method, which was
calculated on the basis of a homogeneous reference 1 Scope
material. This part of BS 6920 specifies requirements forthe
Careful consideration has been givento the suitability of non-metallic products, including water
desirability of some form of toxicological evaluation fittings and components, pipes and materials used in
of extracts from products in contact with water coating, protection, lining, jointing, sealing and
intended for human consumption. It has been lubrication, for use in contact with either hot or cold
concluded that some form of toxicological evaluation water intended for human consumption, with regard
is essential, particularly in viewof the scarcity of to their effect onthe quality of the water.
toxicological data on many chemicals andthe lack of NOTE In some cases the appropriate national authorities or
knowledge of the chemical species whichmay be regulators may require specific additional testing to be carried out
extracted fromproducts in contact with water on extracts from certain types of these materials; interpretation of
the results from additional testing is the responsibility of the
intended for human consumption. requesting body.

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2 Normative references 3 Terms and definitions


The following normative documents contain For the purposes of this part of BS 6920, the
provisions which,through reference in this text, following definitions apply.
constitute provisions of this part of BS 6920. For 3.1
dated references, subsequent amendmentsto or
revisions of, any of these publicationsdo not apply. water fitting
For undated references,the latest edition of the component associatedwith supply, distribution, and
publication referred to applies. use of water, apart from its disposal
BS 6920-2.2.1, Suitability of non-metallic products NOTE This definition is taken h m BS 61W.3.
for use in contact with water intended for human 3.2
consumption with regard to their effect on the
quality of the water -Part 2: Methods of test - product
Section 2.2:Odour andjlawur of water - all or a component part of a manufactured item, in
Subsection 2.2.1:General method of test. its finished form, that comes into contact with water
BS 6920-2.2.2, Suitability of non-metallic products
for use in contact with water intended for human 4 Odour and flavour of water
consumption with regard to their effect on the NOTE 1 See also paragraph one of the IntrducXion
quality of the water- Part 2: Methods of test -
Section 2.2:O h r and jlavour of water- When assessed by the method given inBS 6920-2.2.1,
subsection A2.2:Method of testing tastes imparted the product shall be deemed suitable for contact
to water by hoses. with water intendedfor human consumption E
BS 6920-2.2.3, Suitability of non-metallic products a) at least two of the three test panellists report
f o r use in contact with water intended for human that there is no discernible odourin the test
consumption with regard to their effect on the extracts andno discernible flavourin the fust
quality of the water- Part 2: Methods of test - dilutions of both the final unchlorinated and fmal
Section 2.2:Odour andflavour of water - chlorinated extracts;
Subsection 2.2.3:Method of testing tastes imparted b) none of the panellists report flavour in the
to water by hoses for conveying water for food and second dilutions.
drink preparation.
These odour and flavour requirements shall also
BS 6920-2.3, Suitability of non-metallic products for apply to hoses and laminate/composite pipes
use in contact with water intended for human assessed in accordance withBS 6920-2.2.2. Hoses
consumption with regard to #wir effect on the intended for conveying water for food and drink
qualitg of the water- Part 2: Methods of test - preparation shall also meet the additional
Section 2.3:Appeamnce of water. requirements of clause 10.If the results from the
BS 6920-2.4, Suitability of non-metallic products for first extract conform to these requirements, the first
use in contact with water intended for human extract shall be defined as the f d extract
consumption with regard to their eflect on the NOTE 2 The methd yields results for the tirst and the final
W i t y of the water -Part 2:Meulals of test - extracts in a sequential series of seven extractions.
Section 2.4:Growth of aquatic micnnnyanisms. If two or more panellists report a flavour in the first
BS 6920-2.6, Suitability of non-metallic products for dilution of the final (Le. seventh) chlorinatedor
use in contact with water intended for human unchlorinatecl extracts, but not in the second
consumption with regad to their eflect on the dilution, thenthe product shall be deemed unsuitable
quality of the water- Part 2:Mehods of test - for contact with water intended forhuman
Section 2.5: The extraction of s u b s t a w thut may consumption unlesstwo further samplesare
be of c m m to public hedth. assessed and the results from both of these further
BS 6920-2.6, Suitability of non-metauic pmducts for samples are found to conform withthe requirements
use in contact with water intended for human of this clause.
crmsumptwn with regard to their eflect on the
quality of the water- Part 2:Methods of test -
Section 2.6: The extraction of metads.
BS 6920-3, Suitubility of non-metuUic products for
use in contact with water intended for human
consumption with regard to their eflmt on the
quality of the water- Part 3: High tempemtuw
tests.

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BS 6920-1:2000

6 Appearance of water If the test product extract affects the morphology of


the cell line in any way,test two further samples
When assessed in accordance with BS 6920-2.3, the using fresh reagents.If these exhibit a
product shall be deemed suitable for contact with "non-cytotoxic" responsethe products can be
water intended for human consumptionif the regarded as being suitable for contact with water
increase in colour and turbidity of the water in the intended for human consumption.
final extract is not more than 5 standard units
NOTE 3 Assistance can be gained by reference to the parameters
(of colour) mg/l Pt1) or 0.5 F N U , respectively. If a in annex 1of the EC Directive relahg to the quality of water
single sample does not conformto this requirement, intended for human consumption (80/77&'EEC) [l], now
then the product shall be deemed unsuitable for incorporated into the Water Supply (Water Quality)
contact with water intended for human consumption Regulations 1989 [2], and in Part B of the revised EC
unless two further samples are examined and the Directive (9WWC) [4].
mean colour and turbidityof the final extracts of all NOTE 4 Fittings in premises are considered by the Water
Regulations Advisory Scheme. Materials usedby water
the samples are not increasedby more than 5 undertakew are covered by the following legislation.
standard units (of colour) mg/l Pt')or 0.5 FNU, NOTE 5 All water undertakers in England and Wales are subject
respectively, after contact for9 days (seven to the requirements of the Water Supply (Water Quality)
extractions). Regulations 1989 [2], which came into force on 1September 1989.
Regulation 25 refers to the use of substances or products in the
treatment and provision of water supplies. Essentiallythe
6 Growth of aquatic microorganisms regulation requires that a water undertaker does not, other than
for the purpose of testing and research, apply to or introduce into
NOTE See also paragraphs two,three and four of the water which is to be supplied for d r i n k i n g , washing or cooking,
Intmduction
any substance or product unless it:
When a product is examined by the method given in a) has been approved by the Secretary of State;
BS 6920-2.4, it shall be deemed not to support b) is considered by the water undertaker to be unlikely to
appreciable microbialgrowth if the mean dissolved affect adversely the quality of the water;
oxygen difference (MDOD) is 2.39 mg/l or less. c) has been used by a water undertaker during the 12 months
If a single sampleof a product gives an MDOD value prior to 6 July 1989;
that is greater than 1.69 mg/l but not more d) is listed in the Water intended for human consumption
than 2.9 m g , then two further samples of the Inspectorate supplement in The Water Fittings and Materials
Directory [3].
product shall be examined.If the arithmetic mean of
the three MDOD values obtained is 2.39 mg/l or less,
then the product shallagain be regarded as not 8 The extraction of metals
being capable of supporting an appreciable microbial NOTE 1 See also paragraph seven of the Introduction.
growth when in contact with water intended for When tested in accordance withBS 6920-2.6, the
human consumption. product shall be deemed suitable for contact with
NOTEThe sigrufcance of any bacteriostatidbacteriocidal effects water intended for human consumption if the
observed, and/or any changes in the appearance of the tested
samples, may be assessed by the Nacioral Regulator. amounts of the specified metals inthe final extracts
do not exceed the specified limits given in Table1.
If the limit for any metal is exceeded in either ofthe
7 The extraction of substances that final extracts, then the product shall be deemed
may be of concern to public health unsuitable for contact with water intendedfor
NOTE 1 See also paragraphs five and six of the Introduction. human consumption unless afurther three untested
In general, when a product is assessed by the samples are tested and the amounts of the specified
method given inBS 6920-2.5, a product shall be metals in all of the further finalextracts do not
regarded as being suitable forcontact with water exceed the limits specified in Table 1.
intended for human consumptionif it exhibits a
"non-cytotoxic".
NOTE 2 There are no absolute criteria that can be applied to the
results obtained with the methods given in BS 6920-2.5.

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Table 1 - Maximum allowable concentrations When a metal fitting has been usedin the testing of
of certain metals a product, the assessment shall be made on the
differences in concentrations of the specified metals
between the final exbracts and the metal fitting blank
concentrations test.
If the results from the first 24 h exh-acts conformto
the limits in Table 1, then the first extracts shall be
defined as the final extxacts.
NOTE 2 Experience from testing products using the method
described in BS 6920-2.6 over a number of years has shown that
products that satisfy these criteria on the first 24 h extracts also
conform to thefinal 24 h extracts.

9 High temperature tests


NOTE See also paragraph eight of the Introduction
When tested in accordance withBS 6920-3, products
shall be deemed suitablefor contact with hot water
intended for human consumption or culinary use up
to and includingthe chosen test temperature if the
results obtained conformto clauses 4,6,7 and 8.
Products that conform to these high temperature test
requirements shall be deemed suitablefor use in
contact with cold water withoutany further testing.
NOTE 1 The signiflance of results that conform to the
specified limits in Table 1 in the seventh test extracts, but
exceed the limits in the 6rst extracts may be assessed by the 10 Odour and Flavour of water from
National Regulator. hoses intended for food and drink
NOTE 2 The National Regulator may also specify analysis for
other metals and assess the results obtained.
application
The Reporling limits required by the National Regulator for
NOTE 1 See also paragraph eight of the Introduction.
some of the metals are based upon thenew lower requiremenb When assessed in accordance with BS 6920-2.2.3,
specified in EC Directive on thequality of water intended for both samples of hose SMgive no reportable odour
human consumption (98/83/EC). to the undiluted test water, or flavour to the dilution
of the test water, from the second ( final) exh-action.
NOTE 2 The requirement for this test is considerably more
stringent than that of clause 4 (odour and tlavour of water).

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Annex A (informative)
Scheme of testing showing the relationship between the standards
of the BS 6920 series

I 1
micro organisms
(section 2.4)

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T T
l
I Sensory tests Leaching tests
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1 7 r-l

-
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I Odour and flavour
I of water
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I I (section 2.2)
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I Colour Turbidity
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1
-I-

Regulation 25 testing T - -
;Only for materials usedin water I
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treatment
and I
I distribution (BS 6920-4) I
I-""--""-----J
Regulation 25 of the Water Supply (Water Quality) Regulations 1989.

Figure A . l - Relationship between the standards of the BS 6920 series

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Bibliography

Standards publications
BS 6100:1992, Glossary of building and civil engineering terms - Section 3: Sanitation -
Subsection 3.3:Sanitation.
BS 692041997, Suitability of non-metallic products for use in contact with water intendedfor humn
consumption with regard to their effmt on the quality of the water- Part 4 Method of Test - l7t.e GCMS
identification of water leachuble organic substances.

Other documents
[ 11EC Directive relating to the quality of water intended for human consumption (W"7WEEC). official
Journal
of the European Communities,No. L 229/11 to 15,1988.
[2] GREAT BRITAIN. The Water Supply (Water Quality) Regulations 1989. Statutory Instruments 1989,
No. 1147 (and amendments). London: The Stationery Office.
[3] GREAT BRITAIN. The Water Fittings and Materials Directory. Oakdde: Water Regulations Advisory Scheme.
[4] EC Directive on the quality of water intended for human consumption (98/83/EC). official
Journal of the
European Communities, N o L330/32to 54,1998.
[5] GREAT BRITAIN. The Water Supply (Water Fittings) Regulations 1999. Statutory Instruments 1999,
No. 1148 (and amendments). London: The Stationery Office.

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