SA-213 /SA-213M
(Identical with ASTM Specification A 213 /A 213M-99a⑀1 except for the additional H Grade heat treatment requirements in 6.4, the editorial
deletion of 11.5, and the editorial addition of Grade T92 to 6.1.3.)
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SA-213 /SA-213M 2007 SECTION II, PART A
3.1.9 Specification designation, and NOTE 1 — Isothermal annealing as applied to tubular products, may
involve austenitizing a ferrous alloy and then cooling to and holding within
3.1.10 Special requirements and any supplementary the range of temperature at which austenite transforms to a relatively soft
requirements selected. ferrite-carbide aggregate.
6.1.4 Grade T23 shall be normalized at 1900°F
[1040°C] minimum and tempered at 1350°F [730°C] mini-
4. General Requirements mum as a final heat treatment.
4.1 Material furnished under this specification shall
conform to the applicable requirements of the current edi- 6.2 If any controlled structural characteristics are
ton of Speficication A 450/A 450M, unless otherwise pro- required these shall be so specified as to be a guide as to
vided herein. the most suitable heat treatment.
6.3 All austenitic tubes shall be furnished in the heat-
treated condition. The heat-treatment procedure, except for
5. Materials and Manufacture the H grades and S30815, shall consist of heating the
5.1 Tubes shall be made by the seamless process and material to a minimum temperature of 1900°F [1040°C]
shall be either hot finished or cold finished, as specified. and quenching in water or rapidly cooling by other means.
Grade TP347HFG shall be cold finished. Alternatively, immediately following hot forming, while
the temperature of the tubes is not less than the specified
5.2 Grain Size:
minimum solution treatment temperature, tubes may be
5.2.1 The grain size of Grades 304H, 316H, 321, individually quenched in water or rapidly cooled by other
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2007 SECTION II, PART A SA-213 /SA-213M
335
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11.3 Flaring Test — One flaring test shall be made on 14. Surface Condition
specimens from each end of one finished tube, not the one 14.1 The ferritic cold drawn steel tubes shall be free
used for the flattening test, from each lot (Note 2). of scale and suitable for inspection. A slight amount of
11.4 Hardness Test — Brinell or Rockwell hardness oxidation is not considered scale.
tests shall be made on specimens from two tubes from 14.2 Ferritic hot rolled steel tubes shall be free of loose
each lot (Note 3). scale and suitable for inspection.
11.5 Grain Size — Grain size determinations, to demon- 14.3 Austenitic steel tubes shall be pickled free of scale.
strate compliance with 5.2, shall be made on one end of When bright annealing is used, pickling is not necessary.
one finished tube from each lot (Note 2).
14.4 Any special finish requirement shall be subject to
agreement between the supplier and the purchaser.
12. Hydrostatic or Nondestructive Electric Test
12.1 Each tube shall be subjected to the nondestructive
15. Product Marking
electric test or the hydrostatic test. The type of test to be
used shall be at the option of the manufacturer, unless 15.1 In addition to the marking prescribed in Specifica-
otherwise specified in the purchase order. tion A 450 /A 450M, the marking shall include whether
the tube is hot finished or cold drawn. For Grades TP304H,
TP309H, TP309HCb, TP310H, TP310HCb, TP316H,
13. Forming Operations TP321H, TP347H, TP347HFG, TP348H, S21500, S33228,
and S30815, the marking shall also include the heat number
13.1 Tubes when inserted in the boiler or tube sheet
and heat-treatment lot identification. When either T2 or
shall stand expanding and beading without showing cracks
T12 are ordered with sulfur content higher than 0.025 but
or flaws. Superheater tubes when properly manipulated
equal or less than 0.045, the marking shall include the
shall stand all forging, welding, and bending operations
grade with the designation, S; example T2S and T12S.
necessary for application without developing defects.
NOTE 4 — Certain of the ferritic steels covered by this specification
will harden if cooled rapidly from above their critical temperature. Some 16. Keywords
will air harden, that is, become hardened to an undesirable degree when 16.1 alloy steel tube; austenitic stainless steel; boiler
cooled in air from high temperatures, particularly the 4 to 9% chromium
steels. Therefore, operations that involve heating such steels above their
tubes; ferritic stainless steel; heat exchanger tube; high-
critical temperatures, such as welding, flanging, and hot bending, should temperature applications; seamless steel tube; steel tube;
be followed by suitable heat treatment. superheater tubes; temperature service applications-high
336
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Cb 0.02–0.08
B 0.0005–0.006
N 0.030 max.
Al 0.030 max.
T91 0.08–0.12 0.30–0.60 0.020 0.010 0.20–0.50 8.00–9.50 0.85–1.05 ... 0.18–0.25 Cb 0.06–0.1
N 0.030–0.070
337
Ni 0.40 max.
Al 0.04 max.
T92 0.07–0.13 0.30–0.60 0.020 0.010 0.50 max. 8.50–9.50 0.30–0.60 ... 0.15–0.25 W 1.5–2.00
Cb 0.04–0.09
2007 SECTION II, PART A
B 0.001–0.006
N 0.03–0.07
Ni 0.40 max.
Al 0.04 max.
T122 0.07–0.14 0.70 max. 0.020 0.010 0.50 max. 10.00–12.50 0.25–0.60 ... 0.15–0.30 W 1.50–2.50
Cu 0.30–1.70
Cb 0.04–0.10
NOTES:
(1) It is permissible to order T2 and T12 with 0.045 max. Sulfur.
(2) Grade T5c shall have a titanium content of not less than four times the carbon content and not more than 0.70%.
(3) Grade 18Cr-2Mo shall have Ti + Cb p 0.20 + 4 (C + N) min., 0.80 max.
SA-213 /SA-213M
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SA-213 /SA-213M
TABLE 2
CHEMICAL REQUIREMENTS OF AUSTENITIC STEEL
TP TP TP TP TP TP TP
Grade TP201 TP202 TP304 304H 304N 304LN 304L 309Cb 309H 309HCb
Carbon 0.15 max. 0.15 max. 0.08 max. 0.04–0.10 0.08 max. 0.035 max. 0.035 max. 0.08 max. 0.04–0.10 0.04–0.10
[Note (2)] [Note (2)]
Manganese, 5.50–7.50 7.50–10.0 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00
max.
Phosphorus, 0.060 0.060 0.040 0.040 0.040 0.040 0.040 0.045 0.045 0.045
max.
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Sulfur, max. 0.030 0.030 0.030 0.030 0.030 0.030 0.030 0.030 0.030 0.030
Silicon 1.00 max. 1.00 max. 0.75 max. 0.75 max. 0.75 max. 0.75 max. 0.75 max. 0.75 max. 0.75 max. 0.75 max.
338
Nickel 3.50–5.50 4.00–6.00 8.00–11.0 8.00–11.0 8.00–11.0 8.00–11.0 8.00–13.0 12.00–16.00 12.00–15.00 12.00–16.00
Chromium 16.0–18.0 17.0–19.0 18.0–20.0 18.0–20.0 18.0–20.0 18.0–20.0 18.0–20.0 22.00–24.00 22.00–24.00 22.00–24.00
2007 SECTION II, PART A
Molybdenum ... ... ... ... ... ... ... 0.75 max. 0.75 max. 0.75 max.
Titanium ... ... ... ... ... ... ... ... ... ...
Columbium ... ... ... ... ... ... ... 10 ⴛ C ... 10 ⴛ C
+ tantalum min., min.,
1.10 max. 1.10 max.
Tantalum, ... ... ... ... ... ... ... ... ... ...
max.
Carbon 0.08 max. 0.08 max. 0.04–0.10 0.04–0.10 0.04–0.10 0.08 max. 0.08–0.12 0.08 max. 0.04–0.10
Manganese, 2.00 2.00 2.00 2.00 2.00 2.00 1.5–2.0 2.00 2.00
max.
Phosphorus, 0.045 0.045 0.040 0.045 0.030 0.045 0.030 0.040 0.040
max.
Sulfur, max. 0.030 0.030 0.030 0.030 0.030 0.030 0.015 0.030 0.030
Silicon 0.75 max. 0.75 max. 0.75 max. 0.75 max. 0.75 max. 0.75 max. 0.3–0.7 0.75 max. 0.75 max.
Nickel 12.00–15.00 19.00–22.00 19.0–22.00 19.0–22.00 17.00–23.00 19.00–22.00 14.0–16.0 11.0–14.0 11.0–14.0
Chromium 22.00–24.00 24.00–26.00 24.00–26.00 24.00–26.00 24.00–26.00 24.00–26.00 14.0–16.0 16.0–18.0 16.0–18.0
Molybdenum 0.75 max. 0.75 max. ... 0.75 max. ... 0.75 max. 1.0–1.4 2.00–3.00 2.00–3.00
339
Titanium ... ... ... ... ... ... 0.3–0.6 ... ...
Columbium ... 10 ⴛ C ... 10 ⴛ C 0.20–0.60 ... ... ... ...
+ tantalum min., min.,
2007 SECTION II, PART A
NOTES:
(1) New designation established in accordance with Practice E 527 and SAE J1086.
(2) For smaller diameter or thin walls, or both, where many drawing passes are required, a carbon maximum of 0.040% is necessary in grades TP304L and TP316L. Small outside diameter
tubes are defined as those less than 0.500 in. [12.7 mm] in outside diameter and light wall tubes are those less than 0.049 in. [1.2 mm] in average wall thickness (0.044 in. [1.1 mm] in
minimum wall thickness).
(3) For seamless TP316L tubes, the silicon maximum shall be 1.00%.
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SA-213 /SA-213M
TABLE 3
Carbon 0.035 max. 0.08 max. 0.035 max. 0.08 max. 0.035 max. 0.08 max. 0.04–0.10 0.08 max. 0.04–0.10 0.005– 0.06–0.10 0.08 max.
[Note (2)] [Note (2)] 0.020
Manganese, 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00
max.
Phosphorus, 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040
max.
Sulfur, max. 0.030 0.030 0.030 0.030 0.030 0.030 0.030 0.030 0.030 0.030 0.030 0.030
Silicon 0.75 max. 0.75 max. 0.75 max. 0.75 max. 0.75 max. 0.75 max. 0.75 max. 0.75 max. 0.75 max. 0.75 max. 0.75 max. 0.75 max.
340
[Note (3)]
Nickel 10.0–15.0 11.0–14.0 11.0–14.0 11.0–14.0 11.0–15.0 9.00–13.0 9.00–13.0 9.00–13.0 9.00–13.0 9.00–13.0 9.00–13.0 9.00–13.0
Chromium 16.0–18.0 16.0–18.0 16.0–18.0 18.0–20.0 18.0–20.0 17.0–20.0 17.0–20.0 17.0–20.0 17.0–20.0 17.0–20.0 17.0–20.0 17.0–20.0
2007 SECTION II, PART A
Molybdenum 2.00–3.00 2.00–3.00 2.00–3.00 3.00–4.00 3.00–4.00 ... ... ... ... ... ... ...
Titanium ... ... ... ... ... [Note (4)] [Note (5)] ... ... ... ... ...
Columbium ... ... ... ... ... ... ... [Note (6)] [Note (7)] 0.2–0.5 8 x C-1.0 [Note (6)]
+ tantalum [Note (8)]
Tantalum, ... ... ... ... ... ... ... ... ... ... ... 0.10
max.
Nitrogen ... 0.10–0.16 0.10–0.16 ... ... ... ... ... ... 0.06–0.10 ... ...
[Note (3)]
Carbon 0.04–0.10 0.08 max. 0.016– 0.05–0.10 0.025 0.06–0.15 0.03 max. 0.03 max. 0.07 max. 0.04–0.08 0.06 max. 0.02 max.
341
Tantalum, 0.10 ... ... ... ... ... ... ... ... ... ... ...
max.
Nitrogen ... ... ... 0.14–0.20 0.09–0.15 ... 0.10 max. 0.10–0.20 ... ... 0.20–0.40 ...
[Note (3)]
2007 SECTION II, PART A
Cerium ... ... ... 0.03–0.08 ... ... ... ... ... 0.05–0.10 ... ...
Others ... ... Al 0.8–1.5 ... Cb 0.75– Cu 0.75 Cu 0.75 Cu 1.5– Al 0.025 V 0.10– ...
1.25 max. max. 2.5 max. 0.30
V 0.15–
0.40
B 0.003–
0.009
(9) The method of analysis for nitrogen shall be a matter of agreement between the purchaser and manufacturer.
SA-213 /SA-213M 2007 SECTION II, PART A
TABLE 5
TENSILE REQUIREMENTS
Elongation
in 2 in. or
Tensile Yield 50 mm,
Strength, Strength, Min., %
UNS Min., ksi Min., ksi [Note (1),
Grade Designation [MPa] [MPa] (2)]
Ferritic Grades:
T12 ... 60 [415] 32 [220] 30
T23 ... 74 [510] 58 [400] 20
T91 ... 85 [585] 60 [415] 20
T92 K92460 90 [620] 64 [440] 20
T122 ... 90 [620] 58 [400] 20
18Cr-2Mo ... 60 [415] 40 [275] 20
All other grades 60 [415] 30 [205] 30
Austenitic Grades:
TP201 S20100 95 [655] 38 [260] 35
TP202 S20200 90 [620] 45 [310] 35
TP304 S30400 75 [515] 30 [205] 35
TP304H S30409 75 [515] 30 [205] 35
TP304N S30451 80 [550] 35 [240] 35
TP304L S30403 70 [485] 25 [170] 35
TP304LN S30453 75 [515] 30 [205] 35
TP309Cb S30940 75 [515] 30 [205] 35
TABLE 4 TP309H S30909 75 [515] 30 [205] 35
NUMBER OF TUBES IN A LOT HEAT TREATED BY THE TP309HCb S30941 75 [515] 30 [205] 35
CONTINUOUS PROCESS OR BY DIRECT QUENCH TP309S S30908 75 [515] 30 [205] 35
TP310Cb S31040 75 [515] 30 [205] 35
AFTER HOT FORMING TP310H S31009 75 [515] 30 [205] 35
Size of Tube Size of Lot TP310HCb S31041 75 [515] 30 [205] 35
TP310HCbN S31042 95 [655] 43 [295] 30
TP310S S31008 75 [515] 30 [205] 35
2 in. [50.8 mm] and over in outside not more than 50 S31272 65 [450] 29 [200] 35
diameter and 0.200 in. [5.1 mm] and tubes TP316 S31600 75 [515] 30 [205] 35
over in wall thickness TP316H S31609 75 [515] 30 [205] 35
2 in. [50.8 mm] and over in outside not more than 75 TP316L S31603 70 [485] 25 [170] 35
diameter and under 0.200 in. [5.1 mm] tubes TP316N S31651 80 [550] 35 [240] 35
TP316LN S31653 75 [515] 30 [205] 35
in wall thickness TP317 S31700 75 [515] 30 [205] 35
Less than 2 in. [50.8 mm] but over 1 in. not more than 75 TP317L S31703 75 [515] 30 [205] 35
[25.4 mm] in outside diameter tubes TP321 S32100 75 [515] 30 [205] 35
1 in. [25.4 mm] or less in outside diameter not more than 125 TP321H S32109 75 [515] 30 [205] 35
tubes TP347 S34700 75 [515] 30 [205] 35
TP347H S34709 75 [515] 30 [205] 35
TP347LN S34751 75 [515] 30 [205] 35
TP347HFG ... 80 [550] 30 [205] 35
TP348 S34800 75 [515] 30 [205] 35
TP348H S34809 75 [515] 30 [205] 35
XM-15 S38100 75 [515] 30 [205] 35
... S30615 90 [620] 40 [275] 35
... S30815 87 [600] 45 [310] 40
... S31050:
t ≤ 0.25 in. 84 [580] 39 [270] 25
t > 0.25 in. 78 [540] 37 [255] 25
... S33228 73 [500] 27 [185] 30
... S21500 78 [540] 33 [230] 35
... S31725 75 [515] 30 [205] 35
... S32726 80 [550] 35 [240] 35
... S32615 80 [550] 32 [220] 25
XM-19 S20910 100 [690] 55 [380] 35
... S25700 78 [540] 35 [240] 50
NOTES:
(1) When standard round 2 in. or 50 mm gage length or smaller
proportionally sized specimens with gage length equal to 4D (4
times the diameter) is used, the minimum elongation shall be 22%
for all ferritic grades except 18Cr-2Mo, T23 and T91.
(2) For longitudinal strip tests, a deduction from the basic minimum
elongation values of 1.00% for 18Cr-2Mo, T23, T91, and T122,
1.50% for all other ferritic grades for each 1⁄32-in. [0.8 mm]
decrease in wall thickness below 5⁄16 in. [8 mm] shall be made.
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TABLE 6
COMPUTED MINIMUM VALUES [NOTE (1)]
Elongation in 2 in. or
Wall Thickness 50 mm, Min., %
18Cr-2Mo,
T23, T91, All Other
in. mm and T122 Ferritic Grades
5
⁄16 [0.312] 8 20 30
9
⁄32 [0.281] 7.2 19 29
1
⁄4 [0.250] 6.4 18 27
7
⁄32 [0.219] 5.6 17 26
3
⁄16 [0.188] 4.8 16 24
5
⁄32 [0.156] 4 15 23
1
⁄8 [0.125] 3.2 14 21
3
⁄32 [0.094] 2.4 13 20
1
⁄16 [0.062] 1.6 12 18
0.062 to 0.035, excl. 1.6 to 0.9 12 17
0.035 to 0.022, excl. 0.9 to 0.6 11 17
0.022 to 0.015 incl. 0.6 to 0.4 11 16
NOTE:
(1) Calculated elongation requirements shall be rounded to the nearest
whole number.
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SUPPLEMENTARY REQUIREMENTS
The following supplementary requirements shall apply only when specified by the purchaser
in the inquiry, contract, or order.
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