HOJA DE EXCEL PARA EL CALCULO DEL CALOR Q

F mol/h T1 ºK P1 Kpa T2 ºK P2 Kpa

1500 303.15 300 373.15 250

COMPUESTO z K CALCULO POR EL METODO DE NEWTON-RAPHSON

ISO-BUTANO 0.32 5 Ψ F(Ψ) F´(Ψ) Ψ1 % DE ERROR

PENTANO 0.21 1.7 0.5 0.17590129 1.71839454 0.3976362617 -0.2047275

OCTANO 0.28 0.19 0.3976362617 0.00584644 1.63941929 0.3940700993 -0.0089684
NONANO 0.19 0.07 0.3940700993 -1.7306E-06 1.64043201 0.3940711542 2.6771E-06
0.3940711542 -1.7786E-13 1.64043167 0.3940711542 2.7511E-13
COMPUESTO xi yi
ISO-BUTANO 0.1242098788 0.621049394 V L
PENTANO 0.1645961764 0.2798135 591.106731322 908.893269
OCTANO 0.4112794173 0.078143089
NONANO 0.2999145276 0.020994017
Sumatoria 1 1

PARA EL PARA

LIQUIDO Cpº EL GAS a b c d Cpº

CH3 8.8 CH3 0.6087 2.1433E-02 -8.52E-06 1.14E-09 484.604604
CH2 7.26 CH2 0.3945 2.14E-02 -1.20E-05 2.60E-09 444.237362
CH 5 CH -3.5232 3.49E-02 -2.82E-05 8.02E-09 374.205597

CALCULO DE Cp
COMPUESTO CpLiq CpGas Cp*xi Cp*yi
ISO-BUTANO 31.4 1.8280E+03 3.90E+00 1135.29035
PENTANO 39.38 2301.9212937 6.48179743 644.108653
OCTANO 61.16 3.63E+03 2.52E+01 284.021481
NONANO 68.42 4078.8707426 2.05E+01 85.6318814

Sumatoria 5.61E+01 2149.05236

Qv Kcal/h QL Kcal/h Q kcal/h
1270319.317 50948.910849 1321268.23
 z K q F(q) F"(q) q1 M xi
0.15 5 0.023 -0.58860363 2.4342855 0.26479729 10.5129256 0.06708117
0.2 2.01 0.26479729 -0.27807624 1.02204039 0.53687679 1.0275011 0.15242572
0.15 0.94 0.53687679 0.2024929 0.89117 0.30965539 -0.42322821 0.15283376
0.3 0.43 0.30965539 0.0006018 0.95310042 0.30902398 -0.00203907 0.36414123
0.2 0.22 0.30902398 -2.5155E-07 0.95389795 0.30902424 8.5335E-07 0.26351812
1

F mol/h V mol/h L mol/h

85000 26267 58733
T1 ºK 303.15
P1 Kpa 450
T2 ºK 373.15
LIQUIDO CH3 8.8 P2 Kpa 250
CH2 7.26

a b c d Cp
GAS CH3 0.6087 2.1433E-02 -8.52E-06 1.14E-09 7.47906334
CH2 0.3945 2.14E-02 -1.20E-05 2.60E-09 6.83427193

CALCULO DE Cp (Kcal/mol*K)
compuesto CpLiq CpGas Cp*xi Cp*yi
BUTANO 32.12 28.6266705 2.15464716 9.60155268
PENTANO 39.38 35.4609425 6.002525 10.8643712
HEXANO 46.64 42.2952144 7.12816658 6.07628845
HEPTANO 53.9 49.1294863 19.6272121 7.6927307
OCTANO 61.16 55.9637582 16.1167683 3.24444217

SUMA 51.0293191 37.4793852

Qv Kcal/h QL Kcal/h Q kcal/h

68913130.1 209797133 278710263
 yi
0.33540585
0.3063757
0.14366373
0.15658073
0.05797399
1
 z K q F(q) F"(q) q1 M
ISO-BUTANO 0.32 5 0.02 -0.91957203 4.85007992 0.20959936 9.47996779
PENTANO 0.21 1.7 0.20959936 -0.33178793 2.11324417 0.36660342 0.74906751
OCTANO 0.28 0.19 0.36660342 -0.04524894 1.6568239 0.39391407 0.07449644
NONANO 0.19 0.07 0.39391407 -0.00025768 1.6404821 0.39407115 0.00039876
0.39407115 -3.9668E-09 1.64043167 0.39407115 6.1363E-09

F mol/h T1 ºK P1 Kpa T2 ºK P2 Kpa

1500 303.15 300 373.15 250

GAS
a b c d
CH3 0.6087 2.1433E-02 -8.52E-06 1.14E-09 7.40113876
CH2 0.3945 2.14E-02 -1.20E-05 2.60E-09 6.76647402
CH -3.5232 3.49E-02 -2.82E-05 8.02E-09 5.8930478

LIQUIDO
CH3 8.8
CH2 7.26
CH 5

CALCULO DE Cp

compuesto CpLiq CpGas Cp*xi Cp*yi

ISO-BUTANO 31.4 2.8096E+01 3.90E+00 17.449292
PENTANO 39.38 35.1016996 6.48179743 9.82192941
OCTANO 61.16 5.54E+01 2.52E+01 4.32921479
NONANO 68.42 62.1675957 2.05E+01 1.30514756

SUMA 5.61E+01 32.9055838

Qv Kcal/h QL Kcal/h Q kcal/h

1361549.84 3566423.76 4927973.6
xi yi V L
0.12420988 0.62104939 591.106731 908.893269
0.16459618 0.2798135
0.41127942 0.07814309
0.29991453 0.02099402

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