PHY./INO.

CHEMISTRY

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 52

This DPP is to be discussed in the week (16.11.2015 to 21.11.2015)

DPP No. # 52 (JEE-MAIN)
Total Marks : 60 Max. Time : 40 min.
Single choice Objective (no negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]

ANSWER KEY
DPP No. # 52 (JEE-MAIN)
1. (C) 2. (C) 3. (C) 4. (C) 5. (C) 6. (B) 7. (A)
8. (C) 9. (C) 10. (B) 11. (B) 12. (D) 13. (D) 14. (C)
15. (B) 16. (C) 17. (B) 18. (D) 19. (B) 20. (A)

1. The correct name of [Pt(NH3)4Cl2][PtCl4] is :

(A) tetraamminedichloridoplatinum(II) tetrachloridoplatinate (IV).
(B) dichloridotetraammineplantinum(IV) tetrachloridoplatinate(II).
(C*) tetraamminedichloridoplatinum(IV) tetrachloridoplatinate(II).
(D) tetrachloridoplantinum(II) dichloridotetraammineplatinate(IV).
[Pt(NH3)4Cl2][PtCl4] dk lgh uke gS :
(A) VSVªk,EehuMkbDyksjkbMksIysfVue(II) VSVªkDyksjkbMksIysfVusV(IV)A
(B) MkbDyksjkbMksVSVªk,EehuIySfVue(IV) VSVªkDyksjkbMksIysfVusV(II)A
(C*) VSVªk,EehuMkbDyksjkbMksIysfVue(IV) VSVªkDyksjkbMksIysfVusV(II)A
(D) VSVªkDyksjkbMksIysfVue (II) MkbDyksjkbMksVSVªk,EehuIySfVusV(IV)A
Sol: According to IUPAC nomenclature [Pt(NH 3) 4 Cl 2 ][PtCl 4] is tetraamminedichloridoplatinum(IV)
tetrachloridoplatinate(II). Where oxidation number of Pt are (IV) and (II) respectively
IUPAC ukedj.k ds vuqlkj [Pt(NH3)4Cl2][PtCl4] VSVªk,EehuMkbDyksjkbMksIysfVue(IV) VSVªkDyksjkbMksIysfVusV(II) gS] tgk¡ Pt
ds fy, vkWDlhdj.k la[;k Øe'k% (IV) o (II) gSA

2. The number of P—O—P bonds in tricyclic metaphosphoric acid is :

(A) zero (B) two (C*) three (D) four
f=kpØh; esVkQkWLQksfjd vEy esa P—O—P cU/k dh la[;k gSa %
(A) 'kwU; (B) nks (C*) rhu (D) pkj

Sol.

According to the structure of cyclic metaphosphoric acid, (HPO 3)3, three are there P – O – P bonds.
pØh; esVkQkWLQksfjd vEy, (HPO3)3 dh lajpuk ds vk/kkj ij ;gk¡ rhu P – O – P cU/k gSA

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3. Two unpaired electrons present in carbon atom are different with respect to their
(A) Principle quantum number (B) Azimuthul quantum number
(C*) Magnetic quantum number (D) Spin quantum number
dkcZu ijek.kq esa mifLFkr nks v;qfXer bysDVªkWu ,d nwljs ls fdl lanHkZ esa fHkUu gSaA
(A) eq[; DokUVe la[;k (B) f}ax'kh DokUVe la[;k
(C*) pqEcdh; DokUVe la[;k (D) pØ.k DokUVe la[;k
Sol. Two unpaired electrons present in carbon atom are in different orbitals. So they have different magnetic
quantum number.
gy % dkcZu ijek.kq ds vyx&vyx d{kd esa nks v;qfXer bysDVªkWu mifLFkr gSA blfy, ;g fHkUu&fHkUu pqEcdh; DokUVe la[;k
j[krs gSA
4. Which the following molecules / species have identical bond order and same magnetic properties ?
(I) O2+ ; (II) NO ; (III) N2+
fuEu esa ls dkSulk v.kq@Lih'kht dk cU/k Øe leku gS rFkk leku pqEcdh; xq.k gksrk gSaA
(I) O2+ ; (II) NO ; (III) N2+
(A) (I) , (II) only (B) (I) and I I I only (C*) (I) ,(I I) and (I I I) (D) (I I) and (I I I) only
(A) dsoy (I) , (II) (B) dsoy (I) rFkk I I I (C*) (I) , (I I) rFkk (I I I) (D) dsoy (I I) rFkk (I I I)
Sol. (I) O2+ : (1s)2 (*1s)2 (2s)2 (*2s)2 (2pz)2 (2p2x = 2p2y ) (*2px1 = *2p0y)
Bond order = 1/2(10 – 5) = 2.5.
(II) NO is derivative of O2 and isoelectronic with O 2+ :
so (1s)2 (*1s)2 (2s)2 (*2s)2 (2pz)2 (2p2x = 2p2y ) (*2px1 = *2p0y)
Bond order = 1/2(10 – 5) = 2.5.
(III) N2+ : (1s)2 (*1s)2 (2s)2 (*2s)2 (2p2x = 2p2y ) 2pz)1
Bond order = 1/2(9 – 4) = 2.5.
O2+ , NO and N2+ have same bond order i.e. 2.5 and have same magnetic property having one unpaired
electron.
g y- (I) O2+ : (1s)2 (*1s)2 (2s)2 (*2s)2 (2pz)2 (2p2x = 2p2y ) (*2px1 = *2p0y)
ca/k Øe = 1/2(10 – 5) = 2.5.
(II) NO , O2 dk O;qRiUu gS rFkk ;g O2+ ds le bysDVªkWfud gS A:
vr% (1s)2 (*1s)2 (2s)2 (*2s)2 (2pz)2 (2p2x = 2p2y ) (*2px1 = *2p0y)
ca/k Øe = 1/2(10 – 5) = 2.5.
(III) N2+ : (1s)2 (*1s)2 (2s)2 (*2s)2 (2p2x = 2p2y ) 2pz)1
ca/k Øe = 1/2(9 – 4) = 2.5.
O2+ , NO rFkk N2+ leku ca/k Øe j[krs gS] vFkkZr~ 2.5 rFkk ,d v;qfXer bysDVªkWu ds lkFk leku pqEcdh; xq.k j[krs gSaA

5. EAN of a metal carbonyl M(CO)x is 36. If atomic number of metal M is 26, what is the value of x ?
,d /kkrq dkcksZfuy M(CO)x dk izHkkoh ijek.kq Øekad 36 gSA ;fn] /kkrq M dk ijek.kq Øaekd 26 gS] rks x dk eku D;k gS\
(A) 4 (B) 8 (C*) 5 (D) 6
Sol. x is number of lone pairs of electrons donated to central metal ion.
10
So, 26 + 2x = 36 or x= =5
2
g y- x = dsUnzh; /kkrq vk;u dks fn;s x;s ,dkdh bysDVªkWuksa ds ;qXeksa dh la[;k gSA
10
vr% 26 + 2x = 36 ;k x= =5
2

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6. Consider the following reaction at 1000°C.
1
A. Zn(s) + O (g)  ZnO (s) ; G° = – 360 kJ mol–1
2 2
1
B. C(gr) + O (g)  CO(g) ; G° = – 460 kJ mol–1
2 2
Choose the correct statement at 1000°C
(A) zinc can be oxidised by carbon monooxide. (B*) zinc oxide can be reduced by graphite.

(C) both statements (a) and (b) are true. (D) both statements (a) and (b) are false.
1000°C ij fuEu vfHkfØ;k dk voyksdu dhft,A
1
A. Zn(s) + O (g)  ZnO (s) ; G° = – 360 kJ mol–1
2 2
1
B. C(gr) + O (g)  CO(g) ; G° = – 460 kJ mol–1
2 2
1000°C ij lgh dFku pqfu;sA
(A) dkcZueksuks vkWDlkbM }kjk ftad dks vkWDlhd`r fd;k tk ldrk gSA
(B*) xzsQkbV }kjk ftad vkWDlkbM dks vipf;r fd;k tk ldrk gSA
(C) (a) o (b) nksuksa lR; gSA (D) (a) o (b) nksuksa vlR; gSaA
1
Sol. ZnO (s)  Zn(s) + O2(g) ; G° = 360 kJ mol–1
2
1
C(gr) + O (g)  CO(g) ; G° = – 460 kJ mol–1
2 2
____________________________________________________________
ZnO(s) + C(gr)  Zn (s) + CO(g) ; G° = – 100 kJ mol–1
therefore reaction is spontaneous.
blfy, vfHkfØ;k Lor% gksxhA

7. Give the correct order of initials T or F for following statements. Use T if statement is true and F if it is false.
S1 : AgI is less soluble in water than AgF due to more polarisation of I- in comparison to F– ion.
S2 : LiI is less soluble in water than LiF due to more polarisation of I– in comparison to F– ion.
S3 : Melting point of BaCl2 is higher than the melting point of BeCl2 due to greater ionic nature of BaCl2.
S4 : Order of hydrated radii is : Al3+ (aq) > Mg2+ (aq) > Na+ (aq)
fuEu dFkuksa ds fy, T ;k F dk lgh Øe nhft;sA ;fn dFku lgh gS rks T vkSj ;fn xyr gS rks F dk iz;ksx djsaA
S1 : AgI, AgF dh rqyuk esa ty esa de foys; gksrk gS D;ksafd I- dk F– vk;u dh rqyuk esa vf/kd /kqzo.k gksrk gSA
S2 : LiI, LiF dh rqyuk esa ty esa de foys; gksrk gSa D;ksfd I– dk F– vk;u dh rqyuk esa vf/kd /kqzo.k gksrk gSA
S3 : BaCl2 dk xyukad BeCl2 ds xyukad dh rqyuk esa vf/kd gksrk gSa D;ksfd BaCl2 vf/kd vk;fud çd`fr dk gksrk gSA
S4 : ty;ksftr f=kT;kvksa dk Øe gS % Al3+ (aq) > Mg2+ (aq) > Na+ (aq)
(A*) T F T T (B) T T T T (C) T F F T (D) F F T T
Sol. AgI is less soluble than AgF due to covalent nature. LiI is more soluble then LiF due to high size difference
of ions more ionic nature, more melting point.
gy- lgla;kstd çd`fr ds dkj.k % AgI ; AgF dh rqyuk esa de foys; gS rFkk vk;uksa ds vkdkj esa vf/kd vUrj rFkk vf/kd vk;fud
çd`fr vkSj vf/kd xyukad ds dkj.k LiI ; LiF dh rqyuk esa vf/kd foys; gSA

8. Which of the following statement is not correct when a mixture of NaCl and K2Cr2O7 is gently warmed with
concentrated H2SO4 ?
(A) A deep red vapour is evolved
(B) The vapour when passed into NaOH solution gives a yellow solution of Na2CrO4
(C*) Chlorine gas is evolved
(D) Chromyl chloride is formed

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 fuEu esa ls dkSulk dFku lgh ugha gSa] tc NaCl o K2Cr2O7 ds feJ.k dks lkanz H2SO4 ds lkFk xeZ fd;k tkrk gS &
(A) xgjh yky ok"i fudyrh gSaA
(B) ok"i tc NaOH foy;u esa izokfgr gksrh gS] rks Na2CrO4 dk ihyk foy;u nsrh gSaA
(C*) Dyksjhu xSl eqDr gksrh gSA
(D) Øksfey DyksjkbM curk gSA
Sol. Chromyl chloride confirmatory test for ionic chlorides which forms CrO2Cl2 (deep red)
Øksfey DyksjkbM ijh{k.k] vk;fud DyksjkbM ds fy;s gksrk gSA ftlesa CrO2Cl2 (xgjk yky) fufeZr gksrk gSA

9. Phosphine, acetylene and ammonia can be formed by treating water with

QkWLQhu, ,flfVyhu o veksfu;k dks fuEu ds lkFk ty dks mipkfjr dj cuk;k tk ldrk gSA
(A) Mg3P2, Al4C3.Li3N (B) Ca3P2, CaC2.NaN3
(C*) Ca3P2, CaC2, CaCN2 (D) Ca3P2, Mg2C, NH4NO3
1
10. Number of electron having the quantum numbers n = 4,  = 0, s =  in Zn+2 ion is/are :
2
1
Zn2+ vk;u esa mu bysDVªkWuksa dh la[;k fdruh gksxh ftudh DokUVe la[;k;sa Øe'k% n = 4,  = 0, s =  gSA
2
(A) 1 (B*) 0 (C) 2 (D) 5
2+ 2 2 6 2 6 10
Sol. Electronic configuration of Zn ion is 1s 2s 2p 3s 3p 3d so no electron in 4s orbital.
gy % Zn2+ vk;u dk bysDVªkWfud foU;kl 1s2 2s2 2p6 3s2 3p6 3d10 gSA blfy, 4s d{kd esa dksbZ bysDVªkWu ugha gSA

11. The factor of G values is important in metallurgy. The G values for the following reactions at 800ºC are
given as :
S2(s) + 2O2(g)  2SO2(g) ; G = – 544 kJ
2Zn(s) + S2(s)  2ZnS(s) ; G = – 293 kJ
2Zn(s) + O2(g)  2ZnO(s) ; G = – 480 kJ
The G for the reaction
2ZnS(s) + 3O2(g)  2ZnO(s) + 2SO2(g)
will be :
(A) – 357 kJ (B*) – 731 kJ (C) – 773 kJ (D) – 229 kJ
G eku dk xq.kkad /kkrqdeZ esa egRoiw.kZ gSA 800ºC ij fuEu vfHkfØ;kvksa ds fy, G gS %
S2(s) + 2O2(g)  2SO2(g) ; G = – 544 kJ
2Zn(s) + S2(s)  2ZnS(s) ; G = – 293 kJ
2Zn(s) + O2(g)  2ZnO(s) ; G = – 480 kJ
fuEu fØ;k ds fy, G gksxh %
2ZnS(s) + 3O2(g)  2ZnO(s) + 2SO2(g)
(A) – 357 kJ (B*) – 731 kJ (C) – 773 kJ (D) – 229 kJ
Sol. G of formation of different substances are as : fofHkUu inkFkksZa ds fy, lEHkou dh G fuEu izdkj ls gS %
2SO2 = – 544 kJ
2ZnS = – 293 kJ
ZnO = – 480 kJ
For the reaction, vfHkfØ;k ds fy,
2ZnS + 3O2 (g) 2ZnO (s) + 2 SO2 (g)
G = [ (G(products)–G (reactants) ]
G = [ (G(mRikn) –G (vfHkdkjd) ]
= [(– 480) + (– 544) – (– 293)]
= – 1024 + 293 = – 731 kJ

12. Chemical equilibrium is dynamic in nature because :

(A) the equilibrium is attained quickly.
(B) concentration of reactants and products are constant but different.
(C) concentration of reactants and products become same at equilibrium.
(D*) both forward and backward reactions occur at all times with same speed.

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 izd`fr esa jklk;fud lkE; xfr'khy gksrk gS] D;ksafd :
(A) lkE; 'kh/kzrk ls LFkkfir gksrk gSA
(B) fØ;kdkjdks rFkk mRiknksa dh lkUnzrk fLFkj fdUrq fHkUu gksrh gSA
(C) lkE; ij fØ;kdkjdks rFkk mRiknksa dh lkUnzrk leku gksrh gSA
(D*) vxz o i'p nksuksa vfHkfØ;k;sa lHkh le; ij leku pky ls lEiUu gksrh gSA

13. The compound in which Mn has oxidation state of +3 is :

og ;kSfxd ftlesa Mn +3 vkWDlhdj.k voLFkk j[krk gS] fuEu gS %
(A) KMnO4 (B) K2[Mn(CN)6] (C) MnSO4 (D*) CsMn(SO4)2.12H2O
Sol. CsMn(SO4)2.12H2O ; (1) + (x) + 2 (–2) + 12(0) = 0 or x = 3

14. A certain gas takes two times as long to effuse out as methane under identical conditions. The gas could be:
vkn'kZ ifjfLFkfr;ksa esa ,d xSl] eSFksu dh rqyuk esa fulfjr gksus esa nks xquk le; ysrh gSA og xSl fuEu gks ldrh gS %
(A) He (B) O2 (C*) SO2 (D) None of these (buesa ls dksbZ
ugha)
1
Sol. r 
M

r2 M2
r1 = M
1

Vg / 2t 16

VCH4 / t M

M = 64 g/mole

15. Calculate the molality of a solution of ethanol in water in which the mole fraction of ethanol is 0.36.
,FksukWy ds ty esa fdlh foy;u ds fy, eksyyrk dh x.kuk dhft,] ftlesa ,FksukWy dk eksy fHkUu 0.36 gSA
(A) 12.23 m (B*) 31.25 m (C) 38.65 m (D) 98.765 m

16. The following equilibria are given :

N2 + 3H2 2NH3 K1
N 2 + O2 2NO K2
1
H2 + O H2O K3
2 2
The equilibrium constant of the reaction :
5
2NH3 + O 2NO + 3H2O in terms of K1, K2 and K3 is :
2 2

K1 K 2 K1K32 K 2 K 33
(A) K3 (B) (C*) (D) K1 K2 K3
K2 K1

fuEu lkE; fn;s x;s gSa %

N2 + 3H2 2NH3 K1
N 2 + O2 2NO K2
1
H2 + O H2O K3
2 2

5
vfHkfØ;k 2NH3 + O
2 2
2NO + 3H2O dk lkE; fu;rkad K1, K2 o K3 ds inksa esa fuEu gS %

K1 K 2 K1K32 K 2 K 33
(A) K (B) (C*) (D) K1 K2 K3
3 K2 K1

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 [NH3 ] 2
Sol. (I) N2 + 3H2 2NH3; K1 =
[N2 ][H2 ] 3

[NO] 2
(II) N2 + O2 2NO; K2 =
[N2 ][O 2 ]

[H2O]
(III) H2 + 1 O2 H2O; K3 = 1
2 [H2 ][O 2 ] 2

5
[NO] 2 [H2 O] 3 K 2K 33
(IV) 2NH3 + 2 O2 2NO + 3H2O; Kc = 5
=
[NH3 ] 2 [O 2 ] 2 K1

17. Which of the following acids is monoprotic :

fuEu esa ls dkSulk vEy eksuksizksfVd gS %
(A) H2S (B*) H3PO2 (C) H3PO3 (D) H3PO4

18. Rate constant k is not increases with increasing temperature in the case of :
(A) zero order reaction (B) first order reaction
(C) second order reaction (D*) radioactive decay
fuEu esa ls fdu ifjfLFkfr;ksa esa] lkekU;r% rki esa o`f) ds lkFk osx fu;rkad (k) esa o`f) ugh gksrh gS %
(A) 'kwU; dksfV vfHkfØ;k esa (B) izFke dksfV vfHkfØ;k esa
(C) f}rh; dksfV vfHkfØ;k esa (D*) jsfM;kslfØ; fo?kVu esa
Sol. Radio active decay does not depend upon temperature.
According Arrehenius equation
E
ln k = ln A –
RT
E
T  lnk 
RT
 so K 
gy jsfM;ks lfØ; fo?kVu rki ij fuHkZj ughas djrs gSaA
vkfgZfu;l lehdj.k ds vuqlkj
E
ln k = ln A –
RT
E
T  lnk   blfy, K 
RT

19. What is the activation energy for a reaction if its rate doubles when the temperature is raised from 20C to
35C ? (R = 8.314 J mol–1 K–1)
fdlh vfHkfØ;k dh lfØ;.k ÅtkZ D;k gksxh vxj mldh nj ¼jsV½ nqxquh vkSj rki 20C ls 35C gks tk, \
(R = 8.314 J mol–1 K–1)
(A) 269 kJ mol–1 (B*) 34.6 kJ mol–1 (C) 15.1 kJ mol–1 (D) 342 kJ mol–1

K2 Ea  1 1 
Sol. log    
K1 2.303R  T1 T2 

Ea  1 1 
log 2  
2.303  8.314  293 308 


Ea 15
0. 3   = 34558 J mole–1
2.303  8.314 293  308
= 34.6 kJ mole–1

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20. Sodium metal shows b c c structure. The distance between nearest sodium atoms is 0.368 nm. The edge
length of unit cell is :
lksfM;e /kkrq b c c lajpuk n'kkZrh gSA fudVe lksfM;e ijek.kqvksa ds e/; nwjh 0.368 nm gSA ,dd dksf"Bdk dh
dksj yEckbZ gS %
(1*) 0.425 nm (2) 0.575 nm (3) 0.368 nm (4) 0.184 nm
Sol. (1)

3a
In bcc, nearest distance between atoms 2r and r =
4

3a
bcc esa ijek.kq ds e/; fudVre nwjh 2r gS rFkk r =
4

2  3a 3a
 d= =
4 2
2 d 2  .368
 d= = = 0.425 nm
3 3

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