PHY./INO.

CHEMISTRY

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 50

This DPP is to be discussed in the week (26.10.2015 to 31.10.2015)

DPP No. # 50 (JEE-ADVANCED)

Total Marks : 62 Max. Time : 39 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.4 (3 marks, 2 min.) [12, 08]
Multiple choice objective ('–1' negative marking) Q.5 to Q.10 (4 marks, 2 min.) [24, 12]
Comprehension ('–1' negative marking) Q.11 to Q.12 (3 marks, 2 min.) [06, 04]
Single Integer type Questions ('–1' negative marking) Q.13 to Q.15 (4 marks 3 min.) [ 12, 09]
Match the Following (no negative marking) Q.16 (8 marks, 6 min.) [08, 06]

ANSWER KEY
DPP No. # 50 (JEE-ADVANCED)
1. (A) 2. (A) 3. (B) 4. (B) 5.* (ABCD) 6.* (AB) 7.* (BC)
8.* (ABD) 9.* (BCD) 10.* (ACD) 11. (A) 12. (C) 13. 2 14. 2.
15. 12 16. (A – p, r) ; (B – r) ; (C – q, s) ; (D – p, q, r, s).

1. An ideal gas undergoes a process in which T = T 0 +aV3, where T0 and ‘a’ are positive constants and V is
molar volume. The molar volume for which pressure will be minimum is
,d vkn'kZ xSl izØe esa ftlesa T = T0 +aV3 gksrk gS tgk¡ T0 rFkk ‘a’ /kukRed fu;rkad gSa rFkk V eksyj vk;ru gSA og eksyj
vk;ru] ftlds fy, nkc U;wure gksxk] fuEu gSA
1/3 1/3 2/3
 T0   T0   a 
(A*)   (B)   (C)   (D) None of these buesa ls dksbZ ugha
 2a   3a   3T0 
Sol. PVm = RT
RT
P= V
m

R
P = V (T0 + aVm3)
m

RT0
2
P= Vm + R a Vm

dP RT0
= – + 2a VmR = 0
dVm Vm2

RT0
R2 aVm =
Vm2

1\3
T0 T 
V m3 = or Vm   0 
2a  2a 

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 500 (K )
2. Vapour pressure & temperature relationship is shown as, log P   15 . Heat of vapourisation will
T
500 (K )
be : ok"i nkc o rkieku ds e/; lEcU/k, log P   15 gS rks ok"iu dh Å"ek gksxhA
T
(A*) 2.303 Kcal. (B) 4.606 Kcal. (C) 500 Kcal. (D) 550 Kcal. (E) 1000 Kcal.
 H
Sol. log P  A
2.303RT
H 500
On comparing we have, 
2.303RT T
H 500
rqyuk djus ij, 
2.303RT T
 H = 2.303 × R × 500
= 2.303 × 2 × 10–3 × 500 = 2.303 Kcal.

3. The density of a gaseous substance at 1 atm pressure and 750 K is 0.30 g/lt. If the molecular weight of the
substance is 27 the forces existing among gas molecules is -
(A) Attractive (B*) Repulsive (C) Both (A) and (B) (D) None of these
,d xSlh; inkFkZ dk 1 atm nkc rFkk 750 K ij ?kuRo 0.30 g/lt gSA ;fn inkFkZ dk v.kqHkkj 27 gS rks xSl ds v.kqvksa ds
e/; mifLFkr cy gksxk &
(A) vkd"kZ.k (B*) izfrd"kZ.k (C) (A) o (B) nksuksa (D) dksbZ ugha
PV PM 1  27
Sol. Z= = = = 1.46
nRT dRT 0.30  0.082  750

4. For first order parallel reaction k and k are 4 and 2 min–1 respectively at 300 K. If the activation energies for
1 2
the formation of B and C are respectively 30,000 and 38,314 joule/mol respectively. The temperature at which
B and C will be obtained in equimolar ratio is : (log2 = 0.30)

(A) 757.48 K (B*) 378.31 K (C) 600 K (D) None of these

izFke dksfV dh lekUrj vfHkfØ;k ds fy, k 1 rFkk k2, 300 K rki ij Øe'k% 4 rFkk 2 min– 1 gSA ;fn B rFkk C ds fuekZ.k
ds fy, lfØ;.k ÅtkZ Øe'k% 30,000 rFkk 38,314 joule/mol gSA og rki ftl ij B rFkk C dk leeksyj vuqikr izkIr
gksrk gS] fuEu gS & (log2 = 0.30)

(A) 757.48 K (B*) 378.31 K (C) 600 K (D) dksbZ ugha

k 1' E1  1 1
Sol. In = R T – T  ..... (i)
k1  1 2

k '2 E2  1 1
In = R T – T  ..... (ii)
k2  1 2

Solving we get (ii) – (i),

(ii) – (i) dks gy djus ij

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  k 2 ' k1'   E2 – E1   1 1
In  k  k  =  R   T – T 
 2 1  1 2

(for equimolar formation of B and C, k2’ = k 1’)

(B rFkk C ds leeksyj fuekZ.k ds fy, k2’ = k1’)

 k 1   8314  (T2 – 300)

In  k  =  
 2 8.314  300  T2

(T2 – 300 )
In 2 = (1000) × 300  T
2

;k or T2 = 378.31 K

5.* Which of the following statement is/are CORRECT :

(A*) In general, adsorption of a gas on a solid involves H < 0 and S < 0.
(B*) Chemisorption is much more specific than physisorption.
(C*) Among common protective colloids, gelatin has the least gold number and thus, maximum protective
power.
(D*) If critical temperature (TC) of gas increases then extent of adsorption increases.
fuEu esa ls dkSulk dFku vlR; gS %
(A*) lkekU;r;k] ,d Bksl ij xSl ds vf/k'kks"k.k ds fy, H < 0 rFkk S < 0 gksrk gSA
(B*) jklk;fudvf/k'kks"k.k] HkkSfrdvf/k'kks"k.k dh rqyuk esa cgqr T;knk fof'k"V gksrk gSA
(C*) lkekU; laj{kh dksykbMksa esa ls] ftysfVu dh Lo.kZ la[;k lcls de rFkk laj{kh {kerk lcls T;knk gksrh gSA
(D*) ;fn xSl ds Økafrd rki (TC) esa o`f) gksrh gS rc vf/k'kks"k.k dh ek=kk esa Hkh o`f) gksrh gSA
Sol. Micelle formation takes place only above a particular temperature, called Kraft temperature.
gy- felSy dk fuekZ.k dsoy ,d fuf'pr rki ds Åij gh gksrk gS] ftls Øk¶V rkieku dgrs gSaA

6.* Consider the following first order decomposition and the accompanying concentration – time plot:
A4(g)  4 A (g) [A]
Which of the following statements regarding the decomposition reaction is/are true ?
(A*) At 30 hrs , only 20 %reaction is complete. [A4]
(B*) Half –life of the reaction is 90 hrs (approximately). 30 hrs Time
(C) Rate of decomposition decreasing linearly with time.
(D) Changing initial concentration will change the time at which the two curves are intersecting.
fuEu izFke dksfV fo[k.Mu dk voyksdu dj lkUnzrk&le; ds chp vkjs[k [khapk x;k gSA
A4(g)  4 A (g) [A]

fuEu esa ls dkSulk@dkSuls dFku fo[k.Mu vfHkfØ;k ds lUnHkZ esa lgh gS@gSa \
(A*) 30 ?k.Vs ij dsoy 20 %vfHkfØ;k iw.kZ gksrh gSA [A4]
30 hrs Time
(B*) vfHkfØ;k dh v)Z&vk;q 90 ?k.Vs ¼yxHkx½ gSA
(C) fo[k.Mu dh nj le; ds lkFk js[kh; :i ls ?kVrh jgrh gSA
(D) izkjkfEHkd lkUnzUrk ifjofrZr djus ij og le; ifjofrZr gksxk] ftl ij fd nksuks oØ izfrNsfnr gksrs gSaA

7.* Which of the reaction defines molar H ° ?

f
fuEu es ls dkSulh vfHkfØ;k eksyj Hf° dks ifjHkkf"kr djrh gS \
(A) H+ (aq) + OH– (aq)  H O ()
2

(B*) 1/2 Br () + 1/2 H (g)  HBr(g)

2 2

(C*) N (g) + 2H (g) + O (g)  NH NO (s)

2 2 2 4 3

(D) H (g) + S + 2O (g)  H SO ()

2 monoclinic ¼,durk{k½ 2 2 4

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Sol. From the definition of molar enthalpy of formation.
lEHkou dh eksyj ,UFkSYih dh ifjHkk"kk lsA
H + O  H O is correct. ¼lgh gS½
2 2 2

H (g) + S + 2O (g)  H SO ()

2 Rhombic ¼fo”keyEck{k½ 2 2 4

8.* To a 25 ml H O solution excess acidified solution of KI was added. The iodine liberated rquired 20 ml of 0.3
2 2
N sodium thiosulphate solution. Use these data to choose the correct statements from the following :
(A*) The weight of H O present in 25 ml solution is 0.102 g.
2 2
(B*) The molarity of H O solution is 0.12 M.
2 2
(C) The weight of H O present in 1 L of the solution is 0.816 g.
2 2
(D*) The volume strength of H O is 1.344.
2 2
25ml H O foy;u esa KI ds vEyhd`r vkf/kD; foy;u dks feyk;k x;kA eqDr gqbZ vk;ksMhu ds fy, 20 ml, 0.3 N lksfM;e
2 2
Fkk;ks lYQsV vko';d gksrk gSA bu vkadM+ksa dk mi;ksx djrs gq, fuEu esa ls lgh dFku dks pqfu;s \
(A*) 25 ml foy;u esa H O dk Hkkj 0.102 g gSA
2 2
(B*) H O foy;u dh eksyjrk 0.12 M gSA
2 2
(C) foy;u ds 1 yhVj esa H O dk Hkkj 0.816 g gSA
2 2
(D*) H O dk vk;ru lkeF;Z 1.344 gSA
2 2
2–
Sol. No. of equivalents of S O = 20 × 0.3 × 10–3
2 3
= 6 × 10–3 eq.
No. of equivalents of I2 produced = 6 × 10–3 eq.
No. of equivalents of H2O2 produced = 6 × 10–3 eq.
Wt of H2O2 present in 25 ml of solution = 6 × 10–3 × 17
( Eq. wt H2O2 = 17) = 0.102 g
Statement (A) is correct.
0.102  1000
Wt of H2O2 in 1L of the solution =
25
= 4.08 g
Statement (C) is wrong.
4.08
molarity of H2O2 solution = = 0.12 M
34
Statement (B) is correct.
Volume strength = 11.2 × 0.12 = 1.344
Statement (D) is correct.
Sol. S2O32– dh rqY;kad dh la[;k = 20 × 0.3 × 10–3
= 6 × 10–3 rqY;kad
cuus okys rqY;kad dh la[;k = 6 × 10–3 rqY;kad
I2 ds
H2O2 ds cuus okys rqY;kad dh la[;k = 6 × 10–3 rqY;kad.
25 ml foy;u esa mifLFkr H2O2 dk Hkkj = 6 × 10–3 × 17
(H2O2 dk rqY;kadh Hkkj = 17) = 0.102 g
dFku (A) lgh gSA
0.102  1000
1L foy;u esa H2O2 dk Hkkj = = 4.08 g
25
dFku (C) xyr gS
4.08
 H2O2 foy;u dh eksyjrk = = 0.12 M dFku (B) lgh gSA
34
vk;ru lkeF;Z = 11.2 × 0.12 = 1.344
dFku (D) lgh gSA

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9.* The value of Htransition of C (graphite) — C (diamond) is 1.9 kJ/mol at 25ºC. Entropy of graphite is higher
than entropy of diamond. This implies that :
(A) C (diamond) is more thermodynamically stable than C (graphite) at 25ºC
(B*) C (graphite) is more thermodynamically stable than C (diamond) at 25ºC
(C*) diamond will provide more heat on complete combustion at 25ºC
(D*) Gtransition of C (diamond) — C (graphite) is –ve
25ºC ij C ¼xzsQkbV½ — C ¼ghjk½ dh H dk eku 1.9 kJ/mol gSA xzsQkbV dh ,UVªkWih] ghjs dh ,UVªkWih dh rqyuk esa
laØe.k

mPp gksxhA ;g bafxr djrk gS fd %

(A) 25ºC ij C ¼ghjk½] C ¼xzsQkbV½ dh rqyuk esa vf/kd Å"ekxfrdh; :i ls LFkk;h gSA
(B*) 25ºC ij C¼xzsQkbV½ ] C ¼ghjk½ dh rqyuk esa vf/kd Å"ekxfrdh; :i ls LFkk;h gSA
(C*) 25ºC ij ghjs ds iw.kZ ngu ij vf/kd Å"ek mRiUu gksxhA
(D*) C ¼ghjk½ — C ¼xzsQkbV½ dhG –ve gSA
laØe.k

Sol. More heat is evolved due to combustion of less stable form.

gy . de LFkk;h :i ds ngu ds dkj.k vf/kd Å"ek fu"dkflr gksrh gSA

10.* Identify incorrect statement/statements :

(A*) In adiabatic free expansion, heat involved is zero and therefore entropy change Ssys. will be zero
(B) The heat absorbed during isothermal expansion of an ideal gas against vaccum is zero
(C*) For irreversible cyclic process Ssurr. = 0
(D*) Intensive properties are additive properties
vlR; dFku@dFkuksa dks igpkfu, &
(A*) :)ks”eh; eqDr izlkj esa] iz;qDr Å"ek 'kwU; gS vr% ,UVªksih ifjorZu Sfudk; 'kwU; gksxkA
(B) fuokZr ds fo:) ,d vkn'kZ xSl esa lerkih; izlkj ds nkSjku vo'kksf"kr Å"ek 'kwU; gSA
(C*) vuqRØe.kh; pfØ; izØe ds fy, Sifjos'k = 0 gSA
(D*) ek=kk Lora=k xq.k/keZ ;ksxkRed xq.k/keZ gksrs gSaA
V2
Sol. (A) S sys.  nR n V
1

(B)  U  0 (isothermal ), W  0 (Pext  0)

(B)  U = 0 (lerkih;), W = 0 (Pext = 0)
 Q=0
(C) Ssurri > 0

Paragraph for Question Nos. 11 to 12

iz'u 11 ls 12 ds fy, vuqPNsn
A definite volume of H2O2 undergoing decomposition required 22.8 mL of standard KMnO 4 solution for
titration. After 10 and 20 min, the volumes of permanganate required were 13.8 and 8.25 mL, respectively.
H2O2 dk ,d fuf'pr vk;ru ds fo;kstu ds vUrZxr vuqekiu ds fy, 22.8 mL ekud KMnO4 foy;u vko';d gSA
10 o 20 feuV ds i'pkr~ ijeSxusV dk vk;ru Øe'k% 13.8 o 8.25 mL FkkA
11. Find order of reaction. vfHkfØ;k dh dksfV Kkr dhft,A’
(A*) 1 (B) 2 (C) 3 (D) 3/2

12. Calculate the time (in. min) required for the decomposition to be half completed.
fo;kstu ds vk/kk iw.kZ gksus ds fy, vko';d le; ¼feuV esa½ ifjdfyr dhft,A’
(A) 1.8 (B) 7.6 (C*) 13.7 (D) 20.4

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13. For the hypothetical reaction
A (g) + B (g) 2AB(g)
2 2
If  Gº and  Sº are 20 kJ/mol and –20 JK–1 mol–1 respectively at 200 K.
r r

 r Ho
rCp is 20 JK–1 mol–1 then value of kJ/mol. at 400 K is :
10
dkYifud vfHkfØ;k ds fy;s
A2(g) + B2(g) 2AB(g)
;fn 200 K ij rGº vkSj rSº Øe’’'’k% 20 kJ/mol vkSj –20 JK–1 mol–1 gS %
 r Ho
rCp , 20 JK–1 mol–1 gS] rc 400 K ij dk kJ/mol. esa eku gS %
10
Ans. 2
Sol. (1) G o200 = H0200 – TS0200

H0200 = 20 – 4 = 16 kJ/mol

H0T2 = H0T2 + C p [T2 – T1]

20  20
H0400 = H0200 + kJ/ mol = 16 + 4 = 20 kJ/mol.
1000

14. For the reaction A  products, the following data is given for a particular run.
time (min.) : 0 5 15 35
1
(M–1) : 1 2 4 8
[A ]
Determine the order of the reaction.
A  mRikn] vfHkfØ;k ds fy, vfHkfØ;k ds vk¡dM+s fn;s x;s gSA
le; (min.) : 0 5 15 35
1
(M–1) : 1 2 4 8
[A ]
vfHkfØ;k dh dksfV Kkr djksA
Ans. 2.

15. 10 mL of a H2SO4 solution is diluted to 100 mL. 25 mL of this diluted solution is mixed with 50 mL of
0.5 N NaOH solution. The resulting solution requires 0.265 gm Na 2CO3 for complete neutralization. The
normality of original H2SO4 solution is :
10 mL H2SO4 foy;u dks 100 mL rd ruq fd;k x;kA ruq foy;u ds 25 mL dks 50 mL 0.5 N NaOH foy;u ds lkFk
fefJr fd;k x;kA ifj.kkeh foy;u ds iw.kZ mnklhuhdj.k ds fy, 0.265 gm Na2CO3 dh vko';drk gksrh gSA ewy H2SO4
foy;u dh ukWeZyrk gS %
Ans. 12
Sol. meq of H2SO4 = meq of NaOH + meq of Na2CO3
0.265
N × 25 = 0.5 × 50 + × 103
106 / 2
or N = 1.2
In original H2SO4 solution
N1V1 = N2V2
or N1 × 10 = 1.2 × 100
or N1 = 12 N

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Sol. meq of H2SO4 = meq of NaOH + meq of Na2CO3
H2SO4 dk feyhrqY;kad = NaOH dk feyhrqY;kad + Na2CO3 dk feyhrqY;kad
0.265
N × 25 = 0.5 × 50 + × 103
106 / 2
;k N = 1.2
ewy H2SO4 foy;u esa
N1V1 = N2V2
;k N1 × 10 = 1.2 × 100
;k N1 = 12 N

16. Match the species/molecules listed in column-I with their characteristics listed in column-II.
Column-I Column-II
–
(A) CIF5 , BrF 4 , IF 6 (p) All molecules/ions are polar in nature.
–
(B) CIF3 , BrF 2 , ICI 4 (q) All molecules/ions have same number of lone pair (s) and same shape.
–
(C) XeF2 , ICI 2– , I 3 (r) All molecules/ions have same oxidation state of central atoms.
–
(D) CIOF3 , CIF 4 , IO2F 2 (s) All molecules/ions have same hybridisation of central atoms.
dkWye-I dh iztkrh;ksa ;k v.kqvksa dks dkWye-II esa mifLFkr buds xq.kksa ds lkFk lqesfyr dhft;sA
dkWye-I dkWye-II
–
(A) CIF5 , BrF 4 , IF 6 (p) lHkh v.kq@vk;u izd`fr esa /kzqfo; gSA
–
(B) CIF3 , BrF 2 , ICI 4 (q) lHkh v.kq @vk;u esa leku la[;k esa ,dkadh bysDVªkWu ;qXe rFkk leku vkd`fr gSA
–
(C) XeF2 , ICI 2– , I 3 (r) lHkh v.kq@vk;u esa dsUnzh; ijek.kq dh leku vkWDlhdj.k voLFkk gSA
–
(D) CIOF3 , CIF 4 , IO2F 2 (s) lHkh v.kq@vk;u esa dsUnzh; ijek.kq dk leku ladj.k gSA
Ans. (A – p, r) ; (B – r) ; (C – q, s) ; (D – p, q, r, s).
–
Sol. (A) CIF5 , BrF 4 , IF 6 ; all have same oxidation state (+ 5)

All have one lone pair of electrons each ; but different

shapes ; µ 0 so polar,
 –
(B) CIF3 , BrF 2 , ICI 4 ;all have same oxidation state (+3) ;

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 –
(C) XeF2 = +2 ; ICI2– = +1 ; I 3 = +1 ; ; ;

All have three lone pairs each and same shape but different oxidation state. In all µ = 0 ; so non - polar
–
(D) CIOF3 , CIF 4 , IO2F 2 ; All have same oxidation number (+5)

In all µ  0 , so all polar.

–
g y- (A) CIF5 , BrF 4 , IF 6 ; lHkh leku vkWDlhdj.k voLFkk (+ 5) j[krs gSaA

lHkh esa ,d ,dkdh bysDVªkWu ;qXe mifLFkr gSa ysfdu vkd`fÙk fHkUu gSA µ 0 vr% /kzqoh; gSA
 –
(B) CIF3 , BrF 2 , ICI 4 ; lHkh leku vkWDlhdj.k voLFkk (+ 3) j[krs gSaA

–
(C) XeF2 = +2 ; ICI2– = +1 ; I 3 = +1 ; ; ;

lHkh esa rhu ,dkdh bysDVªkWu ;qXe mifLFkr gSa rFkk vkd`fÙk leku gSA ysfdu vkWDlhdj.k voLFkk fHkUu gS A lHkh esa µ = 0
gS] vr% v/kzqfo; gSA
–
(D) CIOF3 , CIF 4 , IO2F 2 ; lHkh leku vkWDlhdj.k voLFkk (+ 5) j[krs gSaA

lHkh esa µ 0, vr% lHkh /kzqfo; gSA

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