Jarullah
The water vapor or the steam is pumped due to the following reasons:
1) Available
2) Cheap
3) Don't mix with crude oil
4) Good heat transportation
ps pt pn
( pt pn )
ns nt
pt
pn: is the press. of H.C
Ex: Estimate the no. of moles of steam required to add to the distillation column to reduce the
boiling temperature from 400 to 350F.
Sol.:
400 at 760mmHg
From Fig. 17, (by connection 350 with 400F) so pn=400mmHg
Let n t =100 mol
(760 400)
n s 100 47.38 moles
760
Types of Reflux
1) Top tray reflux. In this type, the steam from the top of distillation column is
condensed then some of it is returned to the distillation column. This method
is easy to design and operate, but create big quantity of steam inside the
distillation column and the amount of reflux is not enough. The quantity of
heat drawn is calculated as (mcpT L.H ) (m for every lb).
2) Pump back reflux. In this arrangement, reflux is provided regular intervals.
This helps every plate to act as a true fractionator. The vapor load in the tower
is fairly uniform and hence a uniform and smaller diameter tower will do. The
rejected heat at the reflux locations can be effectively utilized. This method
provides enough liquid at different points along distillation column and hence
good separation, but so difficult to design and operate. The quantity of heat
drawn is calculated as (mcpT ) (m for every lb).
3) Pump around reflux. In this way, reflux from a lower plate is taken, cooled
and fed into the column at a higher level by 2 to 3 plates. This method needs
column distillation with high plates because the whole cut will be on one plate.
The quantity of heat drawn is calculated as (mcpT ) (m for every lb).
The remaining part at the bottom of atmospheric distillation will be sent to the vaccum
distillation tower.
Example: A petroleum cut has the following ASTM D86 Distillation data:
Divide the TBP curve of the petroleum cut into 20 pseudo-components. Calculate the liquid
volume percentage of each pseudo-component.
Sol:
Firstly, the temperatures should be converted from ASTM to TBP, as given previously. The
results will be as follow
Vol. % 0 10 30 50 70 90 95
ASTM (°C) 36.5 54 77 101.5 131 171 186.5
TBP (°C)-API 14.1 33.4 69 101.6 135.2 180.5 194.1
TBP (°C). Duabert -5.3 27.5 66.7 101.7 138.1 184.6 201.1
The TBP curve obtained extends to 95 volume percent distilled only. In order to obtain the
average boiling point of the last cuts, the curve is extrapolated to the final point of the
distillation (100%) by fitting the curve to a suitable polynomial function and extrapolating the
results. An Excel spreadsheet program was used to fit a fifth order polynomial function, as
shown Figure below for TBP temperature versus volume% using Duabert method.
Petroleum Refining Fourth Year Dr.Aysar T. Jarullah
Petroleum Refining Fourth Year Dr.Aysar T. Jarullah
Ex.: Plot the true boiling point curve for the kerosene product from Table below
Sol.:
The cumulative vol% at the IBP of kerosene = 1.33 + 7.27 + 16.56 = 25.16%
The cumulative vol% at the EBP of kerosene = 25.16 + 10.05 = 35.21%
The cumulative vol% at the 10% of kerosene cut = 0.1(10.05) + 25.16 = 26.17%. At vol% of
26.17% the estimated TBP is 186.73 °C (via drawing TBP curve directly or from the
polynomial fit equation of the Fig.). The procedure is repeated at 20% of kerosene volume
which yield 27.17% and TBP of 189.26 °C. Figure below shows the TBP curve for kerosene
which starts at IBP of 180 °C and ends at EBP of 240 °C.