PROBLEMA 7.

14

Se va enfriar a 27°C, 5m 3/s de un gas pobre 65% N 2 , 35% CO2 , inicialmente seco
a 1atm a 315°c , mediante contacto a contracorriente con agua que entra a 18°c .
Se va a utilizar una torre empacada con anillos Raching de cerámica de 50mm,
con L2/G´2=2 . Especificar el diámetro de la torre empacada y la altura.

Datos:
Densidad del liquido = 0.5808kg/m 3
G=2.902.kg/s
Y1=0
Pt=1atm

Densidad del Liquido =1.125 kg/s

Mpro=27.7 kg/kmol
Cb=1089 j/kg
Ca=1884 j/kg
L´1=3.319 kg/sm2
L´2=3.354 kg/sm2
TL2=18°c
TG2=27°c
TG1=315°c
G´=1.641 kg/sm2

Balance de energía global

L’2 CpL (TL – T0) + G’s {Cb (TG1 – T0) =
2

L’1 CpL (TL – T0) + G’s {Cb (TG2 – T0) + Y2 [CA (TG2 – T0) + 0]}
1

Calculamos TL1(Todos los calculos en las hojas de Excel)

ECUACION 1
Suponemos una Ti Y´i
dY '  M A FG .aV Y ' M A / M B
 Ln
dz G' s Y 'i  M A / M B

con este valor calculamos la siguiente ecuación 2:

G ' sC A  dY ' / dz 
h' G .a H   G ' sC a  dy ' / dz 

1 e hG a H

Siguiente ecuación 3 y 4 :

dTG h' .a  T  Ti 
 G H G
dz G ' sC ' H
   dY '  
 dT 
  
G ' s C ' H  G   C ATG  C AL TL  C AL  C A T0  0   
  dz   dz  
Ti  TL 
 dY ' 
G ' sC AL    hL aV
 dz 

Si la temperatura Ti supuesta concuerda con esta calculada podemos pasar a las

siguientes ecuaciones si, no se supone otra Ti y se repiten los cálculos
.
Cumplida la anterior restricción se prosigue:

Si se cumple entonces escogemos un TG

dTG/dz = TG/z z = TG / (dTG/dz)

TG = TG + TG
z=0

Y’ = Y’ + (dY’/dz).z
z=0

Y'
P AG 
M
Y ' A
MB

C’H = f(Y’, TG)

Balance de masa en el fondo de la torre

L’ – L’1 = G’s (Y’ – Y’1)

Calculamos L’ que seria la cantidad de liquido que le entra ala torre en z .

Balance de energía entre el fondo y una altura .z

L’CpL (TL – T0) + G’s [Cb (TG – T0)] = L’1 CpL (TL – T0) + G’s {Cb (TG2 – T0) + Y2.
1

[Ca (TG2 – T0) + 0]}

Calculamos TL . Con esta TL a calcular desde el principio la rutina de calculos

en donde aparece ECUACION 1
 Resultados de las iteraciones hechas:

Tis pai dy/dz h'Ga dtG/dZ termino ental ti

48.22 0.11136567 0.2219645 4233.32315 -638.78049 2888432.6200 48.4368482
48.4368482 0.11258579 0.22454751 4229.55233 -637.69274 2888432.6200 48.3968906
48.3968906 0.11236011 0.22406946 4230.25003 -637.89354 2888432.6200 48.4042835
48.4042835 0.11240183 0.22415783 4230.12104 -637.85640 2888432.6200 48.4029167
48.4029167 0.11239412 0.22414149 4230.14489 -637.86326 2888432.6200 48.4031694
48.4031694 0.11239554 0.22414451 4230.14048 -637.86199 2888432.6200 48.4031227
48.4031227 0.11239528 0.22414396 4230.1413 -637.86223 2888432.6200 48.4031313
48.4031313 0.11239533 0.22414406 4230.14115 -637.86219 2888432.6200 48.4031297
48.4031297 0.11239532 0.22414404 4230.14118 -637.86219 2888432.6200 48.40313
48.40313 0.11239532 0.22414404 4230.14117 -637.86219 2888432.6200 48.40313

Z TG Y' Pag Cs L' TL

0.0470321 285 0.01054197 0.01612082 1096.73772 3.33670569 47.9316335

Tis pai dy/dz h'Ga dtG/dZ termino ental ti

47.9316335 0.10976078 0.18813754 4440.73112 -584.73348 2833470.1454 48.4642281
48.4642281 0.11274067 0.19444479 4431.44016 -582.19919 2833470.1454 48.3689678
48.3689678 0.11220262 0.19330441 4433.11904 -582.65432 2833470.1454 48.3861774
48.3861774 0.11229966 0.19351003 4432.81629 -582.57215 2833470.1454 48.3830739
48.3830739 0.11228216 0.19347293 4432.87091 -582.58697 2833470.1454 48.3836337
48.3836337 0.11228532 0.19347963 4432.86106 -582.58430 2833470.1454 48.3835328
48.3835328 0.11228475 0.19347842 4432.86283 -582.58478 2833470.1454 48.383551
48.383551 0.11228485 0.19347864 4432.86251 -582.58469 2833470.1454 48.3835477
48.3835477 0.11228483 0.1934786 4432.86257 -582.58471 2833470.1454 48.3835483
48.3835483 0.11228483 0.1934786 4432.86256 -582.58471 2833470.1454 48.3835482
48.3835482 0.11228483 0.1934786 4432.86256 -582.58471 2833470.1454 48.3835482

Z TG Y' Pag Cs1 L' TL

0.05149466 255 0.02050508 0.03088589 1115.39166 3.353061138 47.3194725

Tis pai dy/dz h'Ga dtG/dZ termino ental ti

47.3194725 0.10641972 0.1528568 4545.79092 -515.59714 2779862.4271 48.0086185
48.0086185 0.11018728 0.16081583 4533.97092 -512.55002 2779862.4271 47.8915764
47.8915764 0.10953943 0.15944484 4536.00549 -513.06997 2779862.4271 47.9117148
47.9117148 0.10965066 0.15968017 4535.65621 -512.98058 2779862.4271 47.9082574
47.9082574 0.10963156 0.15963975 4535.7162 -512.99593 2779862.4271 47.9088512
47.9088512 0.10963484 0.15964669 4535.7059 -512.99329 2779862.4271 47.9087493
47.9087493 0.10963428 0.1596455 4535.70767 -512.99375 2779862.4271 47.9087668
47.9087668 0.10963437 0.1596457 4535.70736 -512.99367 2779862.4271 47.9087638
47.9087638 0.10963436 0.15964567 4535.70742 -512.99368 2779862.4271 47.9087643
47.9087643 0.10963436 0.15964567 4535.70741 -512.99368 2779862.4271 47.9087642
47.9087642 0.10963436 0.15964567 4535.70741 -512.99368 2779862.4271 47.9087642
47.9087642 0.10963436 0.15964567 4535.70741 -512.99368 2779862.4271 47.9087642

Z TG Y' Pag Cs1 L' TL

0.05848025 225 0.0298412 0.04432515 1132.87168 3.368387312 46.3837811
 Tis pai dy/dz h'Ga dtG/dZ termino ental ti
46.3837811 0.10148223 0.11662552 4668.97436 -448.42964 2727608.3599 47.2523163
47.2523163 0.10605858 0.12628185 4654.51564 -444.86719 2727608.3599 47.1135324
47.1135324 0.10531561 0.12471078 4656.86599 -445.43936 2727608.3599 47.1360772
47.1360772 0.105436 0.12496525 4656.48523 -445.34649 2727608.3599 47.1324246
47.1324246 0.10541648 0.124924 4656.54695 -445.36153 2727608.3599 47.1330166
47.1330166 0.10541965 0.12493069 4656.53695 -445.35910 2727608.3599 47.1329207
47.1329207 0.10541913 0.12492961 4656.53857 -445.35949 2727608.3599 47.1329362
47.1329362 0.10541922 0.12492978 4656.5383 -445.35943 2727608.3599 47.1329337
47.1329337 0.1054192 0.12492975 4656.53835 -445.35944 2727608.3599 47.1329341
47.1329341 0.10541921 0.12492976 4656.53834 -445.35944 2727608.3599 47.132934
47.132934 0.10541921 0.12492976 4656.53834 -445.35944 2727608.3599 47.132934
47.132934 0.10541921 0.12492976 4656.53834 -445.35944 2727608.3599 47.132934

Z TG Y' Pag Cs1 L' TL

0.06736132 195 0.03825663 0.05612361 1148.62789 3.382202088 45.0491651

Tis pai dy/dz h'Ga dtG/dZ termino ental ti

45.0491651 0.09478187 0.07796355 4780.3425 -380.15543 2677023.3932 46.0875048
46.0875048 0.09996057 0.0886597 4764.19118 -376.24750 2677023.3932 45.9368062
45.9368062 0.09919416 0.08707288 4766.58497 -376.81750 2677023.3932 45.9591158
45.9591158 0.0993073 0.08730705 4766.23167 -376.73318 2677023.3932 45.9558226
45.9558226 0.0992906 0.08727246 4766.28385 -376.74562 2677023.3932 45.9563089
45.9563089 0.09929306 0.08727757 4766.27614 -376.74379 2677023.3932 45.9562371
45.9562371 0.0992927 0.08727682 4766.27728 -376.74406 2677023.3932 45.9562477
45.9562477 0.09929275 0.08727693 4766.27711 -376.74402 2677023.3932 45.9562461
45.9562461 0.09929274 0.08727691 4766.27714 -376.74402 2677023.3932 45.9562464
45.9562464 0.09929275 0.08727691 4766.27713 -376.74402 2677023.3932 45.9562463
45.9562463 0.09929275 0.08727691 4766.27713 -376.74402 2677023.3932 45.9562463
45.9562463 0.09929275 0.08727691 4766.27713 -376.74402 2677023.3932 45.9562463

Z TG Y' Pag Cs1 L' TL

0.07962966 165 0.04520646 0.06564988 1161.64006 3.393610931 43.1710781
Tis pai dy/dz h'Ga dtG/dZ termino ental ti
45.0491651 0.09478187 0.07796355 4780.3425 -380.15543 2677023.3932 46.0875048
46.0875048 0.09996057 0.0886597 4764.19118 -376.24750 2677023.3932 45.9368062
45.9368062 0.09919416 0.08707288 4766.58497 -376.81750 2677023.3932 45.9591158
45.9591158 0.0993073 0.08730705 4766.23167 -376.73318 2677023.3932 45.9558226
45.9558226 0.0992906 0.08727246 4766.28385 -376.74562 2677023.3932 45.9563089
45.9563089 0.09929306 0.08727757 4766.27614 -376.74379 2677023.3932 45.9562371
45.9562371 0.0992927 0.08727682 4766.27728 -376.74406 2677023.3932 45.9562477
45.9562477 0.09929275 0.08727693 4766.27711 -376.74402 2677023.3932 45.9562461
45.9562461 0.09929274 0.08727691 4766.27714 -376.74402 2677023.3932 45.9562464
45.9562464 0.09929275 0.08727691 4766.27713 -376.74402 2677023.3932 45.9562463
45.9562463 0.09929275 0.08727691 4766.27713 -376.74402 2677023.3932 45.9562463
45.9562463 0.09929275 0.08727691 4766.27713 -376.74402 2677023.3932 45.9562463

DZ TG Y' Pag Cs1 L' TL

0.07962966 165 0.04520646 0.06564988 1161.64006 3.393610931 43.1710781
 Tis pai dy/dz h'Ga dtG/dZ termino ental ti
43.1710781 0.08600095 0.04108558 4877.97394 -311.63839 2628712.3092 44.3247411
44.3247411 0.09130737 0.0519488 4861.44056 -307.64106 2628712.3092 44.1741613
44.1741613 0.09059912 0.05049521 4863.65068 -308.16497 2628712.3092 44.1942558
44.1942558 0.09069336 0.05068856 4863.35666 -308.09509 2628712.3092 44.191582
44.191582 0.09068081 0.05066282 4863.3958 -308.10439 2628712.3092 44.1919379
44.1919379 0.09068248 0.05066625 4863.39059 -308.10315 2628712.3092 44.1918905
44.1918905 0.09068226 0.05066579 4863.39128 -308.10332 2628712.3092 44.1918969
44.1918969 0.09068229 0.05066585 4863.39119 -308.10330 2628712.3092 44.191896
44.191896 0.09068229 0.05066584 4863.3912 -308.10330 2628712.3092 44.1918961
44.1918961 0.09068229 0.05066585 4863.3912 -308.10330 2628712.3092 44.1918961
44.1918961 0.09068229 0.05066585 4863.3912 -308.10330 2628712.3092 44.1918961
44.1918961 0.09068229 0.05066585 4863.3912 -308.10330 2628712.3092 44.1918961

Z TG Y' Pag Cs1 L' TL

0.09736994 135 0.05013979 0.07229623 1170.87674 3.401709486 40.6153837

Tis pai dy/dz h'Ga dtG/dZ termino ental ti

40.6153837 0.0751852 0.00566925 4959.12628 -243.51620 2583236.3346 41.842053
41.842053 0.0802199 0.0155917 4943.91105 -239.61391 2583236.3346 41.7052926
41.7052926 0.07964453 0.01445501 4945.65248 -240.05021 2583236.3346 41.720905
41.720905 0.07971003 0.01458438 4945.45426 -240.00041 2583236.3346 41.7191274
41.7191274 0.07970257 0.01456965 4945.47684 -240.00608 2583236.3346 41.7193299
41.7193299 0.07970342 0.01457133 4945.47427 -240.00544 2583236.3346 41.7193068
41.7193068 0.07970333 0.01457114 4945.47456 -240.00551 2583236.3346 41.7193094
41.7193094 0.07970334 0.01457116 4945.47452 -240.00550 2583236.3346 41.7193091
41.7193091 0.07970334 0.01457116 4945.47453 -240.00550 2583236.3346 41.7193092
41.7193092 0.07970334 0.01457116 4945.47453 -240.00550 2583236.3346 41.7193092
41.7193092 0.07970334 0.01457116 4945.47453 -240.00550 2583236.3346 41.7193092
41.7193092 0.07970334 0.01457116 4945.47453 -240.00550 2583236.3346 41.7193092

Z TG Y' Pag Cs1 L' TL

0.12499713 105 0.05196115 0.07472618 1174.28686 3.404699419 37.0978931

Tis pai dy/dz h'Ga dtG/dZ termino ental ti

37.0978931 0.06223274 -0.02415054 5004.53421 -176.28094 2541784.5153 38.3140267
38.3140267 0.06647303 -0.01599008 4991.94143 -172.68811 2541784.5153 38.2010929
38.2010929 0.066069 -0.01676923 4993.14286 -173.02219 2541784.5153 38.2118295
38.2118295 0.06610732 -0.01669535 4993.02893 -172.99043 2541784.5153 38.210811
38.210811 0.06610368 -0.01670236 4993.03974 -172.99345 2541784.5153 38.2109077
38.2109077 0.06610403 -0.01670169 4993.03871 -172.99316 2541784.5153 38.2108985
38.2108985 0.066104 -0.01670176 4993.03881 -172.99319 2541784.5153 38.2108994
38.2108994 0.066104 -0.01670175 4993.0388 -172.99318 2541784.5153 38.2108993
38.2108993 0.066104 -0.01670175 4993.0388 -172.99318 2541784.5153 38.2108993
38.2108993 0.066104 -0.01670175 4993.0388 -172.99318 2541784.5153 38.2108993
38.2108993 0.066104 -0.01670175 4993.0388 -172.99318 2541784.5153 38.2108993
38.2108993 0.066104 -0.01670175 4993.0388 -172.99318 2541784.5153 38.2108993
 Z TG Y' Pag Cs1 L' TL
0.17341724 75 0.04906478 0.070856 1168.86398 3.399944735 32.2017392

Tis pai dy/dz h'Ga dtG/dZ termino ental ti

32.2017392 0.04744152 -0.04330689 4994.05745 -111.39055 2506101.0232 33.2835029
33.2835029 0.05041565 -0.03786539 4985.62448 -108.39171 2506101.0232 33.2059303
33.2059303 0.05019712 -0.0382658 4986.24469 -108.60678 2506101.0232 33.2116093
33.2116093 0.05021309 -0.03823654 4986.19937 -108.59103 2506101.0232 33.2111942
33.2111942 0.05021192 -0.03823868 4986.20268 -108.59218 2506101.0232 33.2112246
33.2112246 0.050212 -0.03823852 4986.20244 -108.59210 2506101.0232 33.2112223
33.2112223 0.050212 -0.03823853 4986.20246 -108.59211 2506101.0232 33.2112225
33.2112225 0.050212 -0.03823853 4986.20246 -108.59211 2506101.0232 33.2112225
33.2112225 0.050212 -0.03823853 4986.20246 -108.59211 2506101.0232 33.2112225
33.2112225 0.050212 -0.03823853 4986.20246 -108.59211 2506101.0232 33.2112225
33.2112225 0.050212 -0.03823853 4986.20246 -108.59211 2506101.0232 33.2112225
33.2112225 0.050212 -0.03823853 4986.20246 -108.59211 2506101.0232 33.2112225

Z TG Y' Pag Cs1 L' TL

0.27626318 45 0.03850088 0.0564617 1149.08519 3.382603039 25.1324588

Tis pai dy/dz h'Ga dtG/dZ termino ental ti

25.1324588 0.03149485 -0.04288479 4885.55107 -51.45625 2479509.8924 25.8853975
25.8853975 0.03293393 -0.04044312 4881.7655 -49.46780 2479509.8924 25.8474835
25.8474835 0.03286012 -0.04056844 4881.95976 -49.56789 2479509.8924 25.8494193
25.8494193 0.03286388 -0.04056205 4881.94985 -49.56278 2479509.8924 25.8493205
25.8493205 0.03286369 -0.04056237 4881.95036 -49.56304 2479509.8924 25.8493255
25.8493255 0.0328637 -0.04056236 4881.95033 -49.56303 2479509.8924 25.8493253
25.8493253 0.0328637 -0.04056236 4881.95033 -49.56303 2479509.8924 25.8493253
25.8493253 0.0328637 -0.04056236 4881.95033 -49.56303 2479509.8924 25.8493253
25.8493253 0.0328637 -0.04056236 4881.95033 -49.56303 2479509.8924 25.8493253
25.8493253 0.0328637 -0.04056236 4881.95033 -49.56303 2479509.8924 25.8493253
25.8493253 0.0328637 -0.04056236 4881.95033 -49.56303 2479509.8924 25.8493253
25.8493253 0.0328637 -0.04056236 4881.95033 -49.56303 2479509.8924 25.8493253

Z TG Y' Pag Cs1 L' TL

0.20176328 35 0.03031688 0.04499992 1133.7623 3.369168194 21.4490405

Tis pai dy/dz h'Ga dtG/dZ termino ental ti

21.4490405 0.02521675 -0.03209785 4791.02386 -34.88261 2476198.3145 21.9926963
21.9926963 0.02606825 -0.03072978 4788.90717 -33.46835 2476198.3145 21.9699138
21.9699138 0.02603207 -0.03078794 4788.99713 -33.52760 2476198.3145 21.9708778
21.9708778 0.0260336 -0.03078548 4788.99333 -33.52510 2476198.3145 21.970837
21.970837 0.02603353 -0.03078558 4788.99349 -33.52520 2476198.3145 21.9708387
21.9708387 0.02603353 -0.03078558 4788.99348 -33.52520 2476198.3145 21.9708386
21.9708386 0.02603353 -0.03078558 4788.99348 -33.52520 2476198.3145 21.9708386
21.9708386 0.02603353 -0.03078558 4788.99348 -33.52520 2476198.3145 21.9708386
21.9708386 0.02603353 -0.03078558 4788.99348 -33.52520 2476198.3145 21.9708386
21.9708386 0.02603353 -0.03078558 4788.99348 -33.52520 2476198.3145 21.9708386
21.9708386 0.02603353 -0.03078558 4788.99348 -33.52520 2476198.3145 21.9708386
21.9708386 0.02603353 -0.03078558 4788.99348 -33.52520 2476198.3145 21.9708386

Z TG Y' Pag Cs1 L' TL

0.14914155 30 0.02572547 0.03844682 1125.1658 3.361630937 19.4654659

Tis pai dy/dz h'Ga dtG/dZ termino ental ti

-
19.4654659 0.02231257 0.02565393 4748.44021 -27.08211 2475136.0907 19.8950311
-
19.8950311 0.02291537 0.02470308 4746.97097 -25.96975 2475136.0907 19.8785586
-
19.8785586 0.022892 0.02473997 4747.02796 -26.01239 2475136.0907 19.879195
-
19.879195 0.0228929 0.02473854 4747.02576 -26.01074 2475136.0907 19.8791704
19.8791704 0.02289287 -0.0247386 4747.02584 -26.01081 2475136.0907 19.8791713
19.8791713 0.02289287 -0.0247386 4747.02584 -26.01081 2475136.0907 19.8791713
19.8791713 0.02289287 -0.0247386 4747.02584 -26.01081 2475136.0907 19.8791713
19.8791713 0.02289287 -0.0247386 4747.02584 -26.01081 2475136.0907 19.8791713
19.8791713 0.02289287 -0.0247386 4747.02584 -26.01081 2475136.0907 19.8791713
19.8791713 0.02289287 -0.0247386 4747.02584 -26.01081 2475136.0907 19.8791713
19.8791713 0.02289287 -0.0247386 4747.02584 -26.01081 2475136.0907 19.8791713
19.8791713 0.02289287 -0.0247386 4747.02584 -26.01081 2475136.0907 19.8791713

Z TG Y' Pag Cs1 L' TL

0.11533668 27 0.02287221 0.03432899 1119.82363 3.356947013 18.2474033

La altura de la torre es = 1.44m .

CONCLUSIONES

 La temperatura de la interfase es diferente a la TL, lo que indica que el gradiente en

es diferente de infinito.
 BIBLIOGRAFÍA

1. TREYBAL, Robert E., Operaciones de Transferencia de Masa. McGraw-Hill:

México, 1988
2. PERRY, Robert H., GREEN, Don W., MOLONEY, Jame O., Perry Manual del
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