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BASIC CONCEPTS
AND DEFINITIONS
Thermodynamics is the branch of science which treats of various phenomena of energy, and especially of the laws of
transformations of heat into other forms, and vice versa.
The science that is devoted to understanding energy in all its forms such as, mechanical, electrical, chemical, and how energy
changes forms.
Derived from the Greek words, therme, meaning heat and dynamis, meaning strength, particularly applied to motion.
Flow
through a pipe (Open System)
Piston cylinder assembly (Closed System)
F
d
mv m dv v dm
W mg o
g
o
dt dt dt V g cV gc
but, from classical mechanics mass is invariable with Specific Gravity / Relative Density is the ratio of the
velocity density of a substance to the density of a standard substance.
dm - for liquid the standard substance is water and for gas the
0
dt standard substance is air at same pressure and temperature.
dv Density of Substance
F m ma S .G.
dt Density of Standard Substance
by introducing a gravitational constant, gc
ma For Solid and Liquid : ratio of the weight of substance to the
F
gc weight of equal volume of water.
W subs. subs.V subs.
S .G.
W std . subs. std . subs.V std . subs.
subs. g o g cVsubs.
S .G.
std . subs. g o g cVstd . subs.
but Vsubs Vstd .subs.
subs. subs.
gc
ma
s 1slug1 Ft s
1kgm 1 m 2 2
S .G. subs.
std . subs. std . subs. Water at 4 deg . Celsius
F 1N 1lb f subs. subs
S .G.
kg m m kg f 1000kg 62.4
lbm
gc 1 9.8066 2 m3 ft 3
s N
2
s N
lb Ft Weight in air
slug Ft S .G.
1 2 32.174 2m Weight in air Weight in water
s lb f s lb f
S .G.
Weight in air Since temperature is related to the kinetic energy of the
Weight in air Weight in water fluid, it is evident that the motion of the molecules will increase
with increasing temperature. At absolute zero there will be no
For Ideal Gases (ratio of molecular weight of the gas to the motion, and the molecules will be completely still.
molecular weight of air)
Pg Temperature
K °C R °F
gas RgTg Scale
S .G.
air Pa Steam point
373.15 100 671.67 212
RaTa (Boiling point)
but, Pg = Pa and Tg = Ta Triple Point of
273.16 0.01 491.69 32.02
_ _ water
R R Ice point
Ra and Rg 273.15 0 491.67 32
MWa MWg (Freezing point)
_ Absolute zero 0 -273.15 0 -459.67
R
R MWa MWg
S .G. a _ S .G. Note: ΔC = ΔK , ΔF = ΔR and 1ΔC = 1.8ΔF (ΔC = C°)
Rg R MWa
MWg
x FPx y FPy
MWg BPx FPx BPy FPy
S .G.
MWa
Pressure is the force exerted by a fluid per unit area.
F
P
Temperature is the measure of hotness and coldness of A
a body. It is a measure of the average linear kinetic energy
of the molecules of the substance, that is, the total kinetic
energy of all the molecules divided by the number of
molecules.
Temperature Scale
1) Absolute Temperature Scale (ex. Kelvin & Rankine)
2) Arbitrary or Man-made Temperature Scale (ex. Celsius &
Fahrenheit)
Atmospheric pressure Determine (a) the flow rate in kg/s; (b) the time it takes to fill the
Atmospheric pressure is the pressure associated with tank.
the atmosphere due to the weight of air. Although this
pressure varies according to location and weather patterns, Solution:
an average value at sea level is 101.325 kPa.
a) flow rate
Standard Atmospheric Pressure
m V S .G.Water V
1 atm = 101.325 kPa = 1.01325 Bar = 760 mmHg
= 760 mmHg = 14.7 psi = 29.92 in. Hg
kg L 1m 3 1 min kg
m 1.21000 3 300 6.0
m min 1000L 60s s
Gauge pressure
Gauge pressure is the amount by which pressure b) time to fill the tank
differs from atmospheric pressure. This is measured with a V V 333m 3 1000L t 90 min or 1.5 hr
V t
gauge that measures the pressure above (or below) t V 300
L m3
atmospheric pressure. The gauge pressure below min
800
kg
kg
0.01m 3 0.01m 3 500 3
V1
m3 m
0.003m 3
1500 500 kg3
m
V2 0.01 V1 0.01 0.003 0.007 m3
m1 1 V1 1500
kg
m3
0.003m 3 4.5 kg
+h -h kg
m2 2 V2 500 3 0.007m 3
m
3.5 kg
mm m1 m2 4.5 3.5 8 kg
SAMPLE PROBLEMS
m
8kg 9.675 2
1.1 A pump discharges into a 3 m per side cubical tank. Wm
mm g o
s
7.8926 N
gc kg m
The flow rate is 300 liters/min, and the fluid has a density 9.8066 2
s N
1.2 times that of water (density of water ρ=1000.0 kg/m3).
a 5gO mg O
F W W W W 6W 6
1.3 The mass of a given airplane at sea level (g=32.10 fps2) gO gO gC
is 10 tons. Find its mass in lbm, slugs and kg and its
gravitational weight in lbf and in N when it is travelling at a m
80kg m 9.8066 2
50,000 ft. elevation. The acceleration of gravity F 6 s
4707.168 N
kg m
(g) decreases by 3.33 × 10-6 fps2 for each foot of elevation. 1 2m
s N
Solution :
a) Mass in lbm, slugs and kg
1.5 Make a conversion formula from Fahrenheit scale to
lb f lb ft
10tons 2000 32.174 2m Celsius scale and vice versa.
lb f
Wg c tons s
m
ft
Solution :
go
32.10 2
s
m 20,046.106lbm C 0C F 32 F C F 32
100C 0C 212 32 F 100 180
1kg m
m 20,046.106lbm 9,092.854 kg m
2.2046lbm
9
F C 32 and C
5
F 32
5 9
slug
m 20,046.106lb 623.053slug
32.174lb
1.6 At what temp is the Fahrenheit and Celsius scale has the
same reading?
b) Weight lbf and N Solution : (F = C = A)
mg o
623.053slug 32.10 3.33x10 6 50,000 ft
W s2
slug ft C 0C F 32 F C F 32
gc
1 2
s lb f 100C 0C 212 32 F 100 180
C F 32 A A 32
W 19,896.263lb f
100 180 100 180
1kg f 9.8066N A 40 C or F
W 19,896.263lb f
2.2046lb 1kg
f f
W 88.503.444 N
1.7 At what temperature will the Fahrenheit scale be 64° more
that the Celsius scale?
1.4 During take-off in a space ship, an 80 kg astronaut is Solution :
subjected to an acceleration equal to 5 times the pull of
earth’s standard gravity. If the take-off is vertical, what force F = 64 + C
does he exert on the seat? C 0 F 32 F C 64 C 32
Solution: 100C 0C 212 32 F 100 180
C C 32
5 9
C 40 C or F 104 F
the total mass and weight of the barrel when it is filled with
beer. (Ans.294N)
that of the centigrade reading. What is the temperature of man would experience in an aircraft whose acceleration is 6
the fluid in Rankine and Kelvin scale? (Ans. 433) g’s.
(24) A 150 lbm astronaut took his bathroom scale (a spring (33) Determine the force necessary to accelerate a mass of 20
scale) and a beam scale (compares masses) to the moon lbm at a rate of 60 ft/s2 vertically upward. (Ans.53.3 lbf)
where the local gravity is g=5.48 ft/s2. Determine how much
he will weigh (a) on the spring scale and (b) on the beam (34) The weight of a10 lb mass is measured at a location where
scale. (Ans. 25.5 lb, 150 lb) g=32.1 ft/s2 on a spring scale originally calibrated in a region
where g=32.3 ft/s2. What will be the reading?
(25) The acceleration of high-speed aircraft is sometimes
expressed in g’s (in multiples of the standard acceleration of (35) A gas is contained in a vertical, frictionless piston cylinder
gravity). Determine the net upward force, in N that a 90 kg device. The piston has a mass of 4 kg and a cross sectional
area of 35 cm2. A compresses spring above the piston exerts a
force of 60 N on the piston. If the atmospheric pressure is 95 (41) A 20 ft3 tank of air separated by a membrane into section
kPa, determine the pressure inside the cylinder. A with an initial specific volume of 0.80ft3/lbm and section B with
a mass of 12.0 lbm. The membrane is broken, and the resulting
density is 1.350lbm/ft3. Find the initial specific volume in section
B. in ft3/lbm. (Ans. 0.667)
(48) A constant volume gas thermometer is brought into where Tatm is the temperature of the atmosphere in Kelvin and z
contact with a system of unknown temperature T and then is the altitude in kilometer with z = 0 at sea level. Determine the
into contact with the triple state of water. The mercury average temperature of the atmosphere outside an airplane
column attached to the thermometer has readings of 14.6 that is cruising at an altitude of 11,000 m.
and -2.6 in, respectively. The barometer pressure is 29.80 in
Hg, and the specific gravity of mercury is 13.6. Find the (52) Two liquid streams are pouring in a container, 8 in.
value of the unknown temperature in degrees Rankine. diameter and 15in. high. The mass flow rate of stream A is 1.2
lb/sec and the volume flow rate of B is 0.035 ft3/s. If the specific
(49) The average atmospheric pressure on earth is gravities of A and B are 1.1 and 0.9, respectively, in how many
approximated as a function of altitude by the relation seconds will the container be filled? What is the gage and
neglected. Determine the acceleration of the mass if the entries of 2.667 (at 150°F) and 3.819 (at 200°F). Assume a
external vertical force is (a) downward, (b) upward in ft/s2. linear relation between the two.
(Ans. 67.9, 5.65)
(62) Determine the pressure at point A for the inclined
(58) An 9-m3 tank of nitrogen is separated by a membrane manometer shown in the figure below.
into two sections. Section A has an initial density of 1.667
kg/m3 and section B has a mass of 6 kg. After the
Open to atmosphere
membrane is broken, the density is found to be 1.778kg/m3.
Find the initial density of the gas in section B in kg/m3. (Ans. Air A
Reservoir
0.667)