LIM
CHEMISTRY
FOLIO
CHAPTER 9: Manufactured Substances in Industry
(i)
CONTENTS
Prepared by : Y.H.LIM
Glass................................................................................................................. 24
Ceramics .......................................................................................................... 25
(ii)
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CHAPTER 9 : Manufactured Substances in Industry
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9.1: Sulphuric Acid
The manufacture of sulphuric acid is one of the most important chemical
industries at the present time.
The chemical formula for sulphuric acid is H₂SO4 , it is a
non-volatile diprotic acid.
a)Manufacture of fertilizers
Sulphuric acid reacts with tricalcium phosphate can produce the
superphosphate fertilizers which is calcium dihydrogen phosphate :
2H2SO4 + Ca3(PO4)2 Ca(H2PO4)2 + 2CaSO4
Calcium dihydrogen phosphate
c)Manufacture of detergents
Detergents are the cleaning agents such as washing powder , dish
soap etc.
Sulphuric acid reacts with hydrocarbon to produce sulphonic acid.
Sulphonic acid is then neutralized with sodium hydroxide to
produce detergent.
d)Manufacture of polymers
Polymers is a long molecule made up from lots of small molecules
which called monomers . Polymers also can be called as synthetic
fibre. Rayon is an example of a synthetic fibre that is produced from
the action of sulphuric acid on cellulose.
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CHAPTER 9 : Manufactured Substances in Industry
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e)In school laboratories
- As a strong acid
- As a drying or dehydrating agent
- As an oxidising agent
- As a sulphonating agent
- As a catalyst
Diagram above shows the three stages in the manufacture of sulphuric acid by the Contact process in
industry.
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CHAPTER 9 : Manufactured Substances in Industry
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1) Ammonium sulphate
Ammonia reacts with sulphuric acid by neutralization to produce
ammonium sulphate.
2NH3 + H2SO4 (NH4)2 SO4
Ammonium sulphate
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CHAPTER 9 : Manufactured Substances in Industry
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2) Ammonium nitrate
Ammonia reacts with nitric acid by neutralization to produce
ammonium nitrate.
NH3 + HNO3 NH4NO3 Ammonium nitrate
3) Urea
Ammonia reacts with carbon dioxide at a temperature of
200。C and pressure of 200 atmospheres (200atm) to produce urea .
2NH3 + CO2 (NH2)2 CO + H2O
Urea
b)Coolant
Liquid ammonia is suitable for use as a cooling agent (refrigerant) in
refrigerators because it has low boiling point and very volatile
platinum
4NH3 + 5O2 4NO + 6H2O
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CHAPTER 9 : Manufactured Substances in Industry
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2NO + O2 2NO2
d)Explosives
Nitric acid is used to make explosives such as TNT when nitric acid
reacts with organic substance such as methylbenzene
(common name : toluene)
e)Electrolytes
Ammonia reacts with hydrogen chloride to produce ammonium
chloride which is used as the electrolyte in dry cells
In 1981, Fritz Haber was awarded the Nobel prize for his
discovery of the manufacture of ammonia gas from hydrogen
gas and nitrogen gas
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CHAPTER 9 : Manufactured Substances in Industry
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Haber Process
Nitrogen gas used in the Haber process is obtained from the factional
distillation of liquid air. Hydrogen gas used in the Haber process can be
obtained by two methods :
(a) The reaction between steam and heated coke (carbon)
H2O + C CO + H2
This mixture is known as water gas
(b) The reaction between steam and natural gas (consists mainly
of methane, CH4 )
2H2O + CH4 CO2 + 4H2
N2 + 3H2 2NH3
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CHAPTER 9 : Manufactured Substances in Industry
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The gas mixture produced consists of about 17% ammonia gas. The
ammonia gas is liquefied when gas mixture is cooled.The unreacted
nitrogen gas and hydrogen gas are pumped back and be reacted again.
Ammonium Fertilisers
1) Plants require nitrogen to produce protein. Nitrogen is absorbed by
plants in the form of nitrates, NO3- which are soluble in water.
Percentage of
Compound Formula Molar mass nitrogen by
mass
14
X 100%
Ammonia NH3 17 17
= 82.35%
28
X 100%
Ammonium NH4NO3 86 80
Nitrate = 35%
28
X 100%
Ammonium (NH4)2SO4 132 132
sulphate = 21.21%
28
X 100%
Urea CO(NH2)2 60 60
= 46.67%
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CHAPTER 9 : Manufactured Substances in Industry
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9.3 : Alloys
(c) Ductile
When a force is applied to a metal, the atoms can slide over one
another easily.This makes the metals ductile and metals can be
drawn to form long wires (Figure 9.3a)
Force
(d) Malleable
Empty space exists in the structures of pure metals.When
hammered or pressed , groups of metal atoms may slide into new
positions in these empty spaces. This makes metal malleable ,
able to be made into different shapes or pressed into thin
sheets(Figure 9.3b)
Force
Force
Importance of alloys
• increase strength and hardness of metals
• to prevent corrosion of metals
• to improve appearance of metal
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Stainless steel 74% iron Shiny , strong , and cultery , chemical plant ,
18% chromium resists corrosion machine parts
8% nickel
Bronze 90% copper Hard , strong and shiny Ornaments , medals , statues ,
10% tin swords
Magnalium 70% aluminium Light , hard and strong Aircraft body frames , rims of
30% magnesium racing car tyres
Duralumin 95% aluminium Light , hard and strong Fan blade , electrical cable ,
3% copper racing bicycles , bodies of
1% magnesium aircraft , bullet trains
1% manganese
Polymers
The relative molecular mass of polymers is large because it is
macromolecule (a very big molecule)
The properties of a polymer are different from its monomers
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b) Synthetic polymers
-Polymers that are man-made by chemical processes in the
laboratories.
Examples :
( )
H CH3 H H H CH3 H H
nC = C C=C C = C C=C
H H H H n
Isoprene(monomer) natural rubber (polymer)
b)Synthetic Polymers
Three types of synthetic polymers:
1) Plastic
When subjected to heat , becomes soft so they can be moulded into
various shapes.
It is light, strong and inert to chemicals such as alkali and acid and
are insulators of electricity and heat.
Examples : polyethylene , PVC , polypropylene , Perspex , Bakelite
2) Synthetic fibres
Long chain polymers that withstand stretching.
Examples: Nylon ( make rope,fishing lines , stocking , clothing )
Terylene ( clothing, sleeping bags , fishing nets )
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CHAPTER 9 : Manufactured Substances in Industry
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3) Elastomers
Can regain its original shape after being stretched or pressed
Examples: natural rubber , synthetic rubber (neoprene,SBR)
Styrene-butadiene rubber (SBR) is used to make car tyres
Glass Ceramic
Transparent Opaque
Softens when heated High melting point , hence retains
shape on heating
Impermeable Usually porous except when glazed
Table 9.5a The differences in properties between glass and ceramic
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CHAPTER 9 : Manufactured Substances in Industry
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Glass
Fused glass is the simplest type of glass, which consists mainly of silica
or silicon dioxide.Occasionally a little boron oxide is added.
Other types of glass are mainly metal silicates.
Table 9.5d shows the type of glass and their uses.
Name of glass Composition Properties Examples
of uses
Fused glass Silicon dioxide -High melting point, Telescope
-Difficult to change the mirrors, lens,
shape optical fibres
-Good heat insulator
Soda lime glass Silicon dioxide -Low melting point Bottle, light
Calcium oxide -Transparent bulb, flat
Sodium oxide -Easily shaped glass, bowls
Borosilicate Silicon dioxide -High melting point Laboratory
glass (Pyrex) Boron oxide -Good heat insulator apparatus,
Sodium oxide -Resistant to heat and Cooking
Aluminium oxide chemical attack untensils ,
-Transparent to visible electrical-
and infrared radiations tubes and
glass pipelines
Lead glass Silicon dioxide -Low melting point Decorative
Lead(II) oxide -High density items, crystal
Sodium oxide -High refractive index glasswares,
lens
Table 9.5d properties , composition and uses of different types of glass
Ceramics
Ceramic is manufactured substance made from clay that is dried
and then baked in a kiln at high temperature.
The main constituent of clay is aluminate, silica, and feldspar.
Kaolinite is an example of high quality white clay that consist of
hydrated aluminosilicate crystals.
Red clay contains iron (III) oxide which gives its red colour.
Examples: Tiles, Cement , Bricks , Porcelain
Table 9.5e shows the comparison between metals, non-metals and
ceramics
Conducting Glass
The type of glass that can conduct electricity.It is produced by
embledding a thin layer of conducting material in glass.It can be
classified to two types.The first type is produced by adding indium
tin (IV) oxide (ITO) to conduct the electricity.This type is used in
the making of LED (Liquid Crystal Display) panel.Another type is
produced by thin gold treads.It is used to heat the windows of
aircraft to remove the condensed water by passing electric current.