LDPI Class I (Gases and Vapors)Hazardous Substances

Flammable Limits Vapor

Class I Autoignition Temperatures Flash Point Percent by Volume Density

Material Group °F °C °F °C Lower Upper (Air = 1.0)
Carbon Disulfide *3 194 90 -22 -30 1.3 50 2.6
Acetylene A 581 305 gas gas 2.5 100 0.9
Formaldehyde (Gas) B 795 429 gas gas 7 73 1
Fuels and Combustible
Process Gas (containing
more than 30% H 2 by
volume) B - - - - - - -
Hydrogen B 968 520 gas gas 4 75 0.1
Propyl Nitrate B 347 175 68 20 2 100 -
Acrolein (Inhibited) 1 B [C] 455 235 -15 -26 2.8 31 1.9
Ethrlene Oxide 1 B [C] 804 429 -20 -28 3 100 1.5
Propylene Oxide 1 B [C] 840 449 -35 -37 2.3 36 2
1.3-Butadiene 1 B [C] 788 420 gas gas 2 12 1.9
Acetaldehyde C 347 175 -38 -39 4 60 1.5
Allyl Alcohol C 713 378 70 21 2.5 18 2
Butyl Mercaptan C - - 35 2 - - 3.1
n-Butyraldehyde C 425 218 -8 -22 1.9 12.5 2.5
Carbon Monoxide C 1128 609 gas gas 12.5 74 1
Chloroacetaldehyde C 190 88 - - - - -
1-Chloro - 1
Nitropropane C - - 144 62 - - 4.3
Crotonaldehyde C 450 232 55 13 2.1 15.5 2.4
1.1-Dichloro - 1
Nitroethane C - - 168 76 - - 5
Dicylopentadiene C 937 503 90 32 - - -
Diethyl Ether C 320 160 -49 -45 1.9 36 2.6
Diethylamine C 594 312 -9 -23 1.8 10.1 2.5
Diethylminoethanol C - - - - - - -
Diethylene Glycol
Monobutyl Ether C 442 228 172 78 0.85 24.6 5.6
Diethylene Glycol Monomethyl
Ether C 465 241 205 96 - - -
N-N-Dimenthyl Aniline C 700 371 145 63 - - 4.2
Dimenthylamine C 752 400 gas gas 2.8 14.4 1.6
1.4-Dioxane C 356 180 54 12 2 22 3
Di-N-Propylamine C 570 299 63 17 - - 3.5
Dipropylene Glycol
Methyl Ether C - - 186 86 - - 5.1
Du-Isopropylamine C 600 316 - - - - -
Epichlorohydan C 772 411 88 31 3.8 21 3.2
Ethyl Mercaptan C 572 300 <0 < -18 2.8 18 2.1
n-Ethyl Moorpholine C - - - - - - -
2-Ethyl - 3-Propyl Acrolein C - - 155 68 - - 4.4
Ethylene C 842 450 gas gas 2.7 36 1
Ethylene Glycol
Monobutyl Ether C 460 238 143 62 1.1@200 °F 12.7@200 °F 4.1
Ethylene Glycol
Monobutyl Ether Acetate C 645 340 160 71 0.88@200 °F 8.54@200 °F -
Ethylene Glycol
Monoethyl Ether C 455 235 110 43 1.7@200 °F 15.6@200 °F 3
Ethylene Glycol
Monoethyl Ether Acetate C 715 379 124 52 1.7 - 4.72
Ethylenimine C 608 320 12 -11 3.3 54.8 1.5
2-Ethylehexaldehyde C 375 191 112 44 0.85@200 °F 7.2@200 °F 4.4
Furfural C 600 316 140 60 2.1 19.3 3.3
Furfural Alcohol C 915 490 167 75 1.8 16.3 3.4
Hydrazine C 74 - 518 23 - 270 100 38 2.9 9.8 1.1
Hydrogen Cynaide C 1000 538 0 -18 5.6 40 0.9
Hydrogen Sulfide C 500 260 gas gas 4 44 1.2
Hydrogen Selenide C - - - - - - -
Isobutyraldehyde C 385 196 -1 -18 1.6 10.6 2.5
Isodecalfehyde C - - -1 -18 - - 5.4
Iso-octyl Alcohol C - - 180 82 - - -
Iso-octyl Aldehyde C 387 197 - - - - -
Methylacetylene C - - gas gas 1.7 - 1.4
Methylacetylene-
Propadiene (stabilized) C - - - - - - -
Methyl Ether C 662 350 gas gas 3.4 27 1.6
Methyl Formal C 460 238 - - - - -
Monomethyl Aniline C 900 482 185 85 - - 3.7
Monomethyl Hydrazine C 382 194 17 -8 2.5 92 1.6
Morpholine C 590 310 98 37 1.4 11.2 3
Nitroethane C 778 414 82 28 3.4 - 2.6
Nitromethane C 785 418 95 35 7.3 - 2.1
1-Nitropropane C 789 421 75 24 2.6 11 3.1
2-Nitropropane C 802 428 96 36 2.2 - 3.1
Propionaldehyde C 405 207 -22 -30 2.6 17 2
n-Propyl Ether C 419 215 70 21 1.3 7 3.53
Tetrahydrofuran C 610 321 6 -14 2 11.8 2.5
Triethylamine C 480 249 16 -9 1.2 8 3.5
Unsymmetrical Dimethyl
Hydrazine (UDMH) C 480 249 5 -15 2 95 2
Valeraldehyde C 432 222 54 12 - - 3
Acetic Acid D 867 464 103 39 4 19.9@200 °F 2.1
Acetic Anhydride D 600 316 120 49 2.7 10.3 3.5
Acetone D 869 465 -4 -20 2.5 13 2
Acetone Cyanohydrin D 1270 688 165 74 2.2 12 2.9
Acetonitrile D 975 524 42 6 3 16 1.4
Acrylic Acid D 820 438 122 50 2.4 8 2.5
Acrylionitrile D 898 481 32 0 3 17 1.8
Adiponitrile D - - 200 93 - - -
Allyl Chlordie D 905 485 -25 -32 2.9 11.1 2.6
Alpha-Methyl Styrene D 1066 574 129 54 1.9 6.1 -
Ammonia 2 D 928 498 gas gas 15 28 0.6
n-Amyl Acetate D 680 360 60 16 1.1 7.5 4.5
Aniline D 1139 615 158 70 1.3 11 3.2
Benzene D 928 498 12 -11 1.3 7.9 2.8
Benzyl Chloride D 1085 585 153 67 1.1 - 4.4

Page 1
 LDPI Class I (Gases and Vapors)Hazardous Substances
Butane D 550 288 -76 -60 1.6 8.4 2
1-Butanol D 650 343 98 37 1.4 11.2 2.6
2-Butanol D 761 405 75 24 1.7@212 °F 9.8@212 °F 2.6
Iso-butyl Acetate D 790 421 - - - - -
n-Butyl Acetate D 790 421 72 22 1.7 7.6 4
sec-Butyl Acetate D - - 88 31 1.7 9.8 4
n-Butyl Acrylate (inhibited) D 559 293 118 48 1.5 9.9 4.4
n-Butyl Glycidyl Ether 1 D 132 55 - - - - -
n-Butylacetate D 790 421 - - - - -
n-Butylacetate (inhibited) D 559 293 - - - - -
Butylamine D 594 312 10 -12 1.7 9.8 2.5
Butylene D 725 385 gas gas 1.6 10 1.9
n-Butyric Acid D 830 443 161 72 2 10 3
Chlorobenzene D 1099 593 82 28 1.3 9.6 3.9
Chloroprene D - - -4 -20 4 20 3
Cresol D 1038 - 1110 559 - 599 178 - 187 81 - 86 1.1 - 1.4 - -
Cumene D 795 424 96 36 0.9 6.5 4.1
Cyclohexane D 473 245 -4 -20 1.3 8 2.9
Cylcohexanol D 572 300 154 68 - - 3.5
Cyclohexanone D 473 245 111 44 1.1@212 °F 9.4 3.4
Cyclohexene D 471 244 < 20 < -7 - - 2.8
Cyclopropane D 938 503 gas gas 2.4 10.4 1.5
p-Cymene D 817 436 117 47 0.7@212 °F 5.6 4.6
n-Decanol D 550 288 180 82 - - 5.5
Decene D 455 235 < 131 < 55 - - 4.84
Diacetopne Alcohol D 1118 603 148 64 1.8 6.9 4
o-Dichloroethane D 1198 647 151 66 2.2 9.2 5.1
1.1-Dichloroethane D 820 438 22 -6 5.6 - -
1.2-Dichloroethylene D 860 460 36 2 5.6 12.8 3.4
1.3-Dichloropropene D - - 95 35 5.3 14.5 3.8
Diethyl Benzene D 743 - 842 395 - 450 133 - 135 56 - 57 - - 4.6
Di-Isobutyl Kelone D 745 396 120 49 0.8@200 °F 7.1@200 °F 4.9
Di-Isobutylene D 736 391 23 -5 0.8 4.8 3.9
Dimethyl Formamide D 833 455 136 58 2.2@212 °F 15.2 2.5
Dipenlene D 458 237 113 45 0.7@302 °F 6.1@302 °F 4.7
Dimethyl Sulfate D 370 188 - - - - -
Dodecene D 491 255 - - - - -
Ethane D 882 472 gas gas 3 12.5 1
Ethanol D 685 363 55 13 3.3 \19 1.6
Ethyl Acetate D 800 427 24 -4 2 11.5 3
Ethyl Acetate (inhinited) D 702 372 50 10 1.4 14 3.5
Ethyl Benzene D 810 432 70 21 0.8 6.7 3.7
Ethyl Butanol D - - - - - - -
Ethyl Butyl Ketone D - - 115 46 - - 4
Ethyl Chloride D 966 519 -58 -50 3.8 15.4 2.2
Ethyl Formate D 851 455 -4 -20 2.8 16 2.6
2-Ethyl Hexyl D 448 231 164 73 0.9 9.7 4.5
2-Ethyl Hexyl Acrylate D 485 252 180 82 - - -
Ethyl Silicate D - - 125 52 - - 7.2
Ethylamine D 725 385 <0 < -18 3.5 14 1.6
Ethylene Chlorohydrin D 797 425 140 60 4.9 15.9 2.8
Ethylene Dichloride D 775 413 56 13 6.2 16 3.4

Ethylene Glycol Monomethyl Ether D 545 285 102 39 1.8@STP 14@STP 1.5
Ethylenediamine D 725 385 104 40 2.5 12 2.1
Formic Acid (90%) D 813 434 122 50 18 57 1.6
Fuel Oils D 410 - 765 210 - 407 100 - 336 38 - 169 0.7 5 -
Gasoline D 536 - 880 280 - 471 -36 to -50 -38 to -48 1.2 - 1.5 7.1 - 7.6 3.4
Heptane D 399 204 25 -4 1.1 6.7 3.5
Heptene D 500 260 < 32 <0 - - 3.39
Hexane D 437 225 -7 -22 1.1 7.5 3
Hexanol D - - 145 63 - - 3.5
2-Hexanone D 795 424 77 25 - 8 3.5
Hexenes D 473 245 < 20 < -7 - - 3
sec-Hexyl Acetate D - - - - - - -
Isoamyl Acetate D 680 360 77 25 1.0@212 °F 7.5 4.5
Isoamyl Alcohol D 662 350 109 43 1.2 9.0@212 °F 3
Isobutyl Acrylate D 800 427 86 30 - - 4.42
Isophorone D 860 460 184 84 0.8 3.8 -
Isopropene D 428 220 -65 -54 1.5 8.9 2.4
Isopropyl Acetate D 860 460 35 2 1.8@100 °F 8 3.5
Isopropyl Ether D 830 443 -18 -28 1.4 7.9 3.5
Isopropyl Glycidyl Ether D - - - - - - -
Isopropylacetate D 860 460 - - - - -
Isopropropylamine D 756 402 -35 -37 - - 2
Kerosene D 410 210 110 - 162 43 - 72 0.7 5 -
Liquified Petroleum
Products D 761 - 842 405 - 540 - - - - -
Mesityl Oxide D 652 344 87 31 1.4 7.2 3.4
Methane D 999 537 gas gas 5 15 0.6
Methanol D 725 385 52 11 6 36 1.1
Methyl Acetate D 850 454 14 -10 3.1 16 2.8
Methyl Acrylate D 875 468 27 -2 2.8 25 3
Methyl Amyl Alcohol D - - 106 41 1 5.5 -
Methyl n-Amyl Ketone D 740 393 102 39 1.1@151 °F 7.9@250 °F 3.9
Methyl Ethyl Ketone D 759 404 16 -9 1.7@200 °F 11.4@200 °F 2.5
Methyl Formate D 840 449 -2 -19 4.5 23 2.1
Methyl Isobutyl Ketone D 840 449 64 18 1.2@200 °F 8.0@200 °F 3.5
Methyl Mercaptan D - - - - 3.9 21.8 1.7
Methyl Isocynate D 994 534 19 -7 5.3 26 1.97
Methyl Methacrylate D 792 422 50 10 1.7 8.2 3.6
2-Methyl - 1-Propanol D 780 416 82 28 1.7@123 °F 10.6@202 °F 2.6
2-Methyl - 2-Proponal D 892 478 52 11 2.4 8 2.6
Methylamine D 806 430 gas gas 4.9 20.7 1
Methylcyclohexane D 482 250 25 -4 1.2 6.7 3.4
Methylcyclohexanol D 565 296 149 65 - - 3.9
o-Methylcyclohexanone D - - 118 48 - - 3.9
Monoethanolamine D 770 410 185 85 - - 2.1
Monoisopropanolamine D 705 374 171 77 - - 2.6
Naptha (Coal Tar) D 531 277 107 42 - - -
Naptha (Petroleum) 4 D 550 288 <0 < -18 1.1 5.9 2.5

Page 2
 LDPI Class I (Gases and Vapors)Hazardous Substances
Nitrobenzene D 900 482 190 88 1.8@200 °F - 4.3
Nonane D 401 302 88 31 0.8 2.9 4.4
Nonene D - - 165 74 0.8@212 °F 6.1@212 °F 5
Octane D 403 206 56 13 1 6.5 3.9
Octene D 446 230 70 21 - - 3.9
n-Octyl Alcohol D - - 178 81 - - 4.5
Pentane D 470 243 < -40 < -40 1.5 7.8 2.5
1-Pentanol D 572 300 91 33 1.2 10.0@212 °F 3
2-Pentanone D 846 452 45 7 1.5 8.2 3
1-Pentene D 527 275 0 -18 1.5 8.7 2.4
Pheneylhydrazine D - - 190 88 - - -
Propane D 842 450 gas gas 2.1 9.5 1.6
1-Propanol D 775 413 74 23 2.2 13.7 1.6
2-Propanol D 750 399 53 12 2 12.7@200 °F 2.1
Proprionic Acid D 870 466 126 52 2.9 12.1 2.5
Proprionic Anhydride D 545 285 145 63 1.3 9.5 \4.5
n-Propyl Acetate D 842 450 55 13 1.7@100 °F 8 3.5
Propylene D 851 455 gas gas 2 11.1 1.5
Propylene Dichloride D 1035 537 60 16 3.4 14.5 3.9
Pryidine D 900 482 68 20 1.8 12.4 2.7
Styrene D 914 490 88 31 0.9 6.8 3.6
Tetrahydronapthalene D 725 385 160 71 0.8@212 °F 5.0@302 °F 4.6
Carbon Disulfide *3 194 90 -22 -30 1.3 50 2.6
Acetylene A 581 305 gas gas 2.5 100 0.9
Formaldehyde (Gas) B 795 429 gas gas 7 73 1
Fuels and Combustible
Process Gas (containing
more than 30% H 2 by
volume) B - - - - - - -
Hydrogen B 968 520 gas gas 4 75 0.1
Propyl Nitrate B 347 175 68 20 2 100 -
Acrolein (Inhibited) 1 B [C] 455 235 -15 -26 2.8 31 1.9
Ethrlene Oxide 1 B [C] 804 429 -20 -28 3 100 1.5
Propylene Oxide 1 B [C] 840 449 -35 -37 2.3 36 2
1.3-Butadiene 1 B [C] 788 420 gas gas 2 12 1.9
Acetaldehyde C 347 175 -38 -39 4 60 1.5
Allyl Alcohol C 713 378 70 21 2.5 18 2
Butyl Mercaptan C - - 35 2 - - 3.1
n-Butyraldehyde C 425 218 -8 -22 1.9 12.5 2.5
Carbon Monoxide C 1128 609 gas gas 12.5 74 1
Chloroacetaldehyde C 190 88 - - - - -
1-Chloro - 1
Nitropropane C - - 144 62 - - 4.3
Crotonaldehyde C 450 232 55 13 2.1 15.5 2.4
1.1-Dichloro - 1
Nitroethane C - - 168 76 - - 5
Dicylopentadiene C 937 503 90 32 - - -
Diethyl Ether C 320 160 -49 -45 1.9 36 2.6
Diethylamine C 594 312 -9 -23 1.8 10.1 2.5
Diethylminoethanol C - - - - - - -
Diethylene Glycol
Monobutyl Ether C 442 228 172 78 0.85 24.6 5.6
Diethylene Glycol Monomethyl
Ether C 465 241 205 96 - - -
N-N-Dimenthyl Aniline C 700 371 145 63 - - 4.2
Dimenthylamine C 752 400 gas gas 2.8 14.4 1.6
1.4-Dioxane C 356 180 54 12 2 22 3
Di-N-Propylamine C 570 299 63 17 - - 3.5
Dipropylene Glycol
Methyl Ether C - - 186 86 - - 5.1
Du-Isopropylamine C 600 316 - - - - -
Epichlorohydan C 772 411 88 31 3.8 21 3.2
Ethyl Mercaptan C 572 300 <0 < -18 2.8 18 2.1
n-Ethyl Moorpholine C - - - - - - -
2-Ethyl - 3-Propyl Acrolein C - - 155 68 - - 4.4
Ethylene C 842 450 gas gas 2.7 36 1
Ethylene Glycol
Monobutyl Ether C 460 238 143 62 1.1@200 °F 12.7@200 °F 4.1
Ethylene Glycol
Monobutyl Ether Acetate C 645 340 160 71 0.88@200 °F 8.54@200 °F -
Ethylene Glycol
Monoethyl Ether C 455 235 110 43 1.7@200 °F 15.6@200 °F 3
Ethylene Glycol
Monoethyl Ether Acetate C 715 379 124 52 1.7 - 4.72
Ethylenimine C 608 320 12 -11 3.3 54.8 1.5
2-Ethylehexaldehyde C 375 191 112 44 0.85@200 °F 7.2@200 °F 4.4
Furfural C 600 316 140 60 2.1 19.3 3.3
Furfural Alcohol C 915 490 167 75 1.8 16.3 3.4
Hydrazine C 74 - 518 23 - 270 100 38 2.9 9.8 1.1
Hydrogen Cynaide C 1000 538 0 -18 5.6 40 0.9
Hydrogen Sulfide C 500 260 gas gas 4 44 1.2
Hydrogen Selenide C - - - - - - -
Isobutyraldehyde C 385 196 -1 -18 1.6 10.6 2.5
Isodecalfehyde C - - -1 -18 - - 5.4
Iso-octyl Alcohol C - - 180 82 - - -
Iso-octyl Aldehyde C 387 197 - - - - -
Methylacetylene C - - gas gas 1.7 - 1.4
Methylacetylene-
Propadiene (stabilized) C - - - - - - -
Methyl Ether C 662 350 gas gas 3.4 27 1.6
Methyl Formal C 460 238 - - - - -
Monomethyl Aniline C 900 482 185 85 - - 3.7
Monomethyl Hydrazine C 382 194 17 -8 2.5 92 1.6
Morpholine C 590 310 98 37 1.4 11.2 3
Nitroethane C 778 414 82 28 3.4 - 2.6
Nitromethane C 785 418 95 35 7.3 - 2.1
1-Nitropropane C 789 421 75 24 2.6 11 3.1
2-Nitropropane C 802 428 96 36 2.2 - 3.1
Propionaldehyde C 405 207 -22 -30 2.6 17 2
n-Propyl Ether C 419 215 70 21 1.3 7 3.53
Tetrahydrofuran C 610 321 6 -14 2 11.8 2.5
Triethylamine C 480 249 16 -9 1.2 8 3.5

Page 3
 LDPI Class I (Gases and Vapors)Hazardous Substances
Unsymmetrical Dimethyl
Hydrazine (UDMH) C 480 249 5 -15 2 95 2
Valeraldehyde C 432 222 54 12 - - 3
Acetic Acid D 867 464 103 39 4 19.9@200 °F 2.1
Acetic Anhydride D 600 316 120 49 2.7 10.3 3.5
Acetone D 869 465 -4 -20 2.5 13 2
Acetone Cyanohydrin D 1270 688 165 74 2.2 12 2.9
Acetonitrile D 975 524 42 6 3 16 1.4
Acrylic Acid D 820 438 122 50 2.4 8 2.5
Acrylionitrile D 898 481 32 0 3 17 1.8
Adiponitrile D - - 200 93 - - -
Allyl Chlordie D 905 485 -25 -32 2.9 11.1 2.6
Alpha-Methyl Styrene D 1066 574 129 54 1.9 6.1 -
Ammonia 2 D 928 498 gas gas 15 28 0.6
n-Amyl Acetate D 680 360 60 16 1.1 7.5 4.5
Aniline D 1139 615 158 70 1.3 11 3.2
Benzene D 928 498 12 -11 1.3 7.9 2.8
Benzyl Chloride D 1085 585 153 67 1.1 - 4.4
Butane D 550 288 -76 -60 1.6 8.4 2
1-Butanol D 650 343 98 37 1.4 11.2 2.6
2-Butanol D 761 405 75 24 1.7@212 °F 9.8@212 °F 2.6
Iso-butyl Acetate D 790 421 - - - - -
n-Butyl Acetate D 790 421 72 22 1.7 7.6 4
sec-Butyl Acetate D - - 88 31 1.7 9.8 4
n-Butyl Acrylate (inhibited) D 559 293 118 48 1.5 9.9 4.4
n-Butyl Glycidyl Ether 1 D 132 55 - - - - -
n-Butylacetate D 790 421 - - - - -
n-Butylacetate (inhibited) D 559 293 - - - - -
Butylamine D 594 312 10 -12 1.7 9.8 2.5
Butylene D 725 385 gas gas 1.6 10 1.9
n-Butyric Acid D 830 443 161 72 2 10 3
Chlorobenzene D 1099 593 82 28 1.3 9.6 3.9
Chloroprene D - - -4 -20 4 20 3
Cresol D 1038 - 1110 559 - 599 178 - 187 81 - 86 1.1 - 1.4 - -
Cumene D 795 424 96 36 0.9 6.5 4.1
Cyclohexane D 473 245 -4 -20 1.3 8 2.9
Cylcohexanol D 572 300 154 68 - - 3.5
Cyclohexanone D 473 245 111 44 1.1@212 °F 9.4 3.4
Cyclohexene D 471 244 < 20 < -7 - - 2.8
Cyclopropane D 938 503 gas gas 2.4 10.4 1.5
p-Cymene D 817 436 117 47 0.7@212 °F 5.6 4.6
n-Decanol D 550 288 180 82 - - 5.5
Decene D 455 235 < 131 < 55 - - 4.84
Diacetopne Alcohol D 1118 603 148 64 1.8 6.9 4
o-Dichloroethane D 1198 647 151 66 2.2 9.2 5.1
1.1-Dichloroethane D 820 438 22 -6 5.6 - -
1.2-Dichloroethylene D 860 460 36 2 5.6 12.8 3.4
1.3-Dichloropropene D - - 95 35 5.3 14.5 3.8
Diethyl Benzene D 743 - 842 395 - 450 133 - 135 56 - 57 - - 4.6
Di-Isobutyl Kelone D 745 396 120 49 0.8@200 °F 7.1@200 °F 4.9
Di-Isobutylene D 736 391 23 -5 0.8 4.8 3.9
Dimethyl Formamide D 833 455 136 58 2.2@212 °F 15.2 2.5
Dipenlene D 458 237 113 45 0.7@302 °F 6.1@302 °F 4.7
Dimethyl Sulfate D 370 188 - - - - -
Dodecene D 491 255 - - - - -
Ethane D 882 472 gas gas 3 12.5 1
Ethanol D 685 363 55 13 3.3 \19 1.6
Ethyl Acetate D 800 427 24 -4 2 11.5 3
Ethyl Acetate (inhinited) D 702 372 50 10 1.4 14 3.5
Ethyl Benzene D 810 432 70 21 0.8 6.7 3.7
Ethyl Butanol D - - - - - - -
Ethyl Butyl Ketone D - - 115 46 - - 4
Ethyl Chloride D 966 519 -58 -50 3.8 15.4 2.2
Ethyl Formate D 851 455 -4 -20 2.8 16 2.6
2-Ethyl Hexyl D 448 231 164 73 0.9 9.7 4.5
2-Ethyl Hexyl Acrylate D 485 252 180 82 - - -
Ethyl Silicate D - - 125 52 - - 7.2
Ethylamine D 725 385 <0 < -18 3.5 14 1.6
Ethylene Chlorohydrin D 797 425 140 60 4.9 15.9 2.8
Ethylene Dichloride D 775 413 56 13 6.2 16 3.4
Ethylene Glycol Monomethyl Ether D 545 285 102 39 1.8@STP 14@STP 1.5
Ethylenediamine D 725 385 104 40 2.5 12 2.1
Formic Acid (90%) D 813 434 122 50 18 57 1.6
Fuel Oils D 410 - 765 210 - 407 100 - 336 38 - 169 0.7 5 -
Gasoline D 536 - 880 280 - 471 -36 to -50 -38 to -48 1.2 - 1.5 7.1 - 7.6 3.4
Heptane D 399 204 25 -4 1.1 6.7 3.5
Heptene D 500 260 < 32 <0 - - 3.39
Hexane D 437 225 -7 -22 1.1 7.5 3
Hexanol D - - 145 63 - - 3.5
2-Hexanone D 795 424 77 25 - 8 3.5
Hexenes D 473 245 < 20 < -7 - - 3
sec-Hexyl Acetate D - - - - - - -
Isoamyl Acetate D 680 360 77 25 1.0@212 °F 7.5 4.5
Isoamyl Alcohol D 662 350 109 43 1.2 9.0@212 °F 3
Isobutyl Acrylate D 800 427 86 30 - - 4.42
Isophorone D 860 460 184 84 0.8 3.8 -
Isopropene D 428 220 -65 -54 1.5 8.9 2.4
Isopropyl Acetate D 860 460 35 2 1.8@100 °F 8 3.5
Isopropyl Ether D 830 443 -18 -28 1.4 7.9 3.5
Isopropyl Glycidyl Ether D - - - - - - -
Isopropylacetate D 860 460 - - - - -
Isopropropylamine D 756 402 -35 -37 - - 2
Kerosene D 410 210 110 - 162 43 - 72 0.7 5 -
Liquified Petroleum
Products D 761 - 842 405 - 540 - - - - -
Mesityl Oxide D 652 344 87 31 1.4 7.2 3.4
Methane D 999 537 gas gas 5 15 0.6
Methanol D 725 385 52 11 6 36 1.1
Methyl Acetate D 850 454 14 -10 3.1 16 2.8
Methyl Acrylate D 875 468 27 -2 2.8 25 3
Methyl Amyl Alcohol D - - 106 41 1 5.5 -

Page 4
 LDPI Class I (Gases and Vapors)Hazardous Substances
Methyl n-Amyl Ketone D 740 393 102 39 1.1@151 °F 7.9@250 °F 3.9
Methyl Ethyl Ketone D 759 404 16 -9 1.7@200 °F 11.4@200 °F 2.5
Methyl Formate D 840 449 -2 -19 4.5 23 2.1
Methyl Isobutyl Ketone D 840 449 64 18 1.2@200 °F 8.0@200 °F 3.5
Methyl Mercaptan D - - - - 3.9 21.8 1.7
Methyl Isocynate D 994 534 19 -7 5.3 26 1.97
Methyl Methacrylate D 792 422 50 10 1.7 8.2 3.6
2-Methyl - 1-Propanol D 780 416 82 28 1.7@123 °F 10.6@202 °F 2.6
2-Methyl - 2-Proponal D 892 478 52 11 2.4 8 2.6
Methylamine D 806 430 gas gas 4.9 20.7 1
Methylcyclohexane D 482 250 25 -4 1.2 6.7 3.4
Methylcyclohexanol D 565 296 149 65 - - 3.9
o-Methylcyclohexanone D - - 118 48 - - 3.9
Monoethanolamine D 770 410 185 85 - - 2.1
Monoisopropanolamine D 705 374 171 77 - - 2.6
Naptha (Coal Tar) D 531 277 107 42 - - -
Naptha (Petroleum) 4 D 550 288 <0 < -18 1.1 5.9 2.5
Nitrobenzene D 900 482 190 88 1.8@200 °F - 4.3
Nonane D 401 302 88 31 0.8 2.9 4.4
Nonene D - - 165 74 0.8@212 °F 6.1@212 °F 5
Octane D 403 206 56 13 1 6.5 3.9
Octene D 446 230 70 21 - - 3.9
n-Octyl Alcohol D - - 178 81 - - 4.5
Pentane D 470 243 < -40 < -40 1.5 7.8 2.5
1-Pentanol D 572 300 91 33 1.2 10.0@212 °F 3
2-Pentanone D 846 452 45 7 1.5 8.2 3
1-Pentene D 527 275 0 -18 1.5 8.7 2.4
Pheneylhydrazine D - - 190 88 - - -
Propane D 842 450 gas gas 2.1 9.5 1.6
1-Propanol D 775 413 74 23 2.2 13.7 1.6
2-Propanol D 750 399 53 12 2 12.7@200 °F 2.1
Proprionic Acid D 870 466 126 52 2.9 12.1 2.5
Proprionic Anhydride D 545 285 145 63 1.3 9.5 \4.5
n-Propyl Acetate D 842 450 55 13 1.7@100 °F 8 3.5
Propylene D 851 455 gas gas 2 11.1 1.5
Propylene Dichloride D 1035 537 60 16 3.4 14.5 3.9
Pryidine D 900 482 68 20 1.8 12.4 2.7
Styrene D 914 490 88 31 0.9 6.8 3.6
Tetrahydronapthalene D 725 385 160 71 0.8@212 °F 5.0@302 °F 4.6
Tetramethyl Lead D - - - - - - -
Toluene D 896 480 40 4 1.1 7.1 3.1
Tridecene D - - - - - - -
Triethylbenzene D - - 181 83 - - 5.6
Triproptlamine D - - 105 41 - - 4.9
Turpentine D 488 253 95 35 0.8 - -
Undecene D - - - - - - -
Vinyl Acetate D 756 402 158 -8 2.6 13.4 3
Vinyl Chloride D 882 472 -108.4 -78 3.6 33 2.2
Vinyl Toluene D 921 494 127 53 0.8 11 4.1
Vinylidene Chloride D 1058 570 -19 -28 6.5 15.5 3.4
Xylenes D 867 - 984 464 - 529 81 - 90 27 - 32 1.0 - 1.1 7 3.7

Autoignition temperature of a substance is the lowest temperature at which the substance will spontaneously combust in a normal atmosphere,
without an external source of ignition (such as a flame or spark).
Flash point is the temperature at which a liquid or solid gives off vapors that can form as a flammable mixture with air.
Flammable limits apply generally to vapors and are defined as the concentration range in which a flammable substance can produce a flame or
explosion when an ignition source (such as a flame or spark) is present. The concentration is generally expressed as a percent
fuel by volume. Above the upper flammable limit the mixture of substance is to rich in fuel to burn. Below the lower flammable
limits the mixture lacks sufficient fuel to burn.
Vapor density is defined as the relative weight of a gas or vapor compared to air, which has an arbitrary value of one. If a gas or vapor has a vapor
density of less than one it will generally rise in the air. If the vapor density is greater than one, it will generally sink in air.

1 If equipment is isolated be sealing all conduit 1/2" or larger, in accordance with Section 501.5(A) of NFPA 70, National
Electric Code , equipment for
the group classification shown is permitted.
2 For classification of areas involving Ammonia, see Safety Code for Mechanical Refregeration , ANSI/ASHRAE 15, and
Safety Requirements for the
Storage and Handling of Anhydrous Ammonia , ANSI/CGA G2.1.
3 Certain chemicals may have characteristics that requires safeguards beyond those required for any of the above groups.
Carbon disulfide is one of
those chemicals because of its low autoignition temperature and the small joint clearance to arrest flame propagation.
4 Petroleum Naptha is a saturated hydrocarbon mixture whose boiling point is 20° to 135° C. It is also known as benzine,
ligroin, petroleum ether and naptha.

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