Suggested by :
UNIVERSITAS DIPONEGORO
SEMARANG
2016
Format halaman pengesahan
mengikuti contoh yang tercantum
dalam petunjuk pelaksanaan
CERCo pada bagian III.3 VALIDATION PAGE
halaman pengesahan
ditandatangani oleh ketua tim,
dosen pembimbing, dan
dekan/rektor/yang mempunyai
otoritas (stempel)
iii
FOREWORD
Praise to the Almighty God for the gift that was given to us, so that we can
solve a scientific paper entitled “The Influenced of Activated Zeolite-Chitosan
Nanoparticle towards Nutrient Released from Urea Fertilizer Using Encapsulized
Method for Increased Slow Release Fertilizer Efficiency”.
This scientific writing proposed in order to follow Chemical Engineering
Research Competition (CERCo) 2016. Hence, we thank you for the opportunity
that has been given by event organizers of CERCo 2016 for us to develop our
interest in competition in this paper. We also thank for our lecturers who have
taken the time to discuss with us and we do not forget to thank the parents that
given the blessing prayers and motivation to solve this scientific paper.
Innovation through scientific papers that we hope the knowledge we gain
from the learning process in these colleges can be more beneficial and can solve
environmental problems existing in the field of Indonesian’s animal husbandry.
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LIST OF CONTENTS
v
LIST OF TABLES
vi
LIST OF FIGURES
vii
Chapter I Pendahuluan berisi: latar belakang, rumusan masalah, Bagian utama (naskah artikel)
tujuan penulisan, manfaat penulisan, sistematika penulisan. diberi nomor halaman
menggunakan angka arab 1
yang dimulai dengan nomor
Penulisan Bab dan
halaman 1 (satu) dan diketik
Subbab tidak
di sebelah kanan atas dengan
menggunakan
sistem numeral, CHAPTER 1 PRELIMINARY jarak 3 cm dari tepi kanan dan
artinya tidak ada 1,5 cm dari tepi atas
penomoran Bab dan Background
Sub-bab.
Indonesia is a country with a very large agricultural commodities. As an
agricultural country, fertilizer is the main support in the field of agriculture.
Indonesia is one of the large consumer of urea fertilizer, that is of 3.2 million
Latar belakang : berisi
tonnes per year (Ministry of agriculture, 2010). Urea is one type of chemical
informasi, data, dan
penelitian-penelitaian fertilizers used in agriculture i.e. about 3.6 million tons. Many farmers, especially
terdahulu serta for food crops using fertilizers irrationally anymore especially urea fertilizer
kelemahannya usage that range between 100 – 600 kg/ha. The efficiency of fertilization until
(maksimal 10 tahun recently perceived in agriculture is still low, especially for rice crops due to loss
terakhir, disertai sitasi),
of nutrient elements. Craswell, et al (1991) reported that the use of urea fertilizer
mengapa dilakukan
that is spread to the surface of the soil in the long time can cause the soil become
acidic and dependency to chemical fertilizers. In addition, the efficiency of
nutrient release by urea only 30%-40% , so that it becomes its own problems in
agriculture.
Beri argumen-argumen Therefore, it is necessary to other innovations to improve the efficiency of
mengapa penelitian ini nutrient release urea fertilizer. One of the efforts to reduce the loss of nutrient
penting dilakukan elements is to make nutrient elements be slow (slow release). Efforts to slow the
release of fertilizer can decrease the environmental pollution of agriculture
because of release of nutrient elements being controlled. One of the efforts to
improve the efficiency of urea fertilizer is by modifying the slow release fertilizer
fertilizers (SRF). One of the efforts is by mixing urea with ingredients that have a
cation exchange capacity (CEC) high as zeolites and Chitosan nanoparticles. By
making the fertilizer-based urea, zeolites, and Chitosan is expected to improve the
efficiency of nitrogen fertilizers. In addition, modification of zeolite and Chitosan
nanoparticle size will be very effective in nutrient absorption by plants.
According to Suwardi (1999) the addition of zeolite on nitrogen fertilizers will be
issued by ammonium menjerap fertilizer. At a time when the concentration of
nitrates in the soil decreased ammonium that have been dijerap by zeolite will be
released back into the soil solution.
tunjukkan kelebihan Chitosan is a polymer that is most abundant biodegradable. Source of
dan inovasi dari chitin and Chitosan is present on most types of crustaceans with a population of
penelitian about 70% (Muzzarelli, 1977). Some of the benefits of the Chitosan among
others: slowing the release of fertilizer nutrients by covering a large part of the
pore-water porinya so can stay signed in to dissolve through the pores that are not
covered. Therefore, Chitosan as selected upholstery because Chitosan can not
water soluble and able to coat the fertilizer (Liu, 2014), has biodegradibel,
biocompatible bonding agent, nontoxic and eco-friendly. Modification of
Chitosan application as a aims to penyalut in fertilizer, because of its ability to
withstand the release of nutrient elements gradually. Chitosan has many benefits
in a variety of fields, including agriculture. One of the benefits of chitosan in the
field of agriculture, namely increasing nitrogen fixation, where nitrogen fixation
affects plant growth. In addition to other material which has the effect on the
effectiveness of release of nutrient elements i.e. zeolite. Benefits of zeolite of
which contains many minerals that are abundant, the ability of the CEC, and keep
the pH balance of the soil (Gufron, 2013). As for the Chitosan is made in sizes
Naskah diketik 1 (satu) spasi pada kertas berukuran A4 dengan font 12,
Times New Roman, jarak pengetikan 4 cm dari samping kiri, 3 cm dari
samping kanan, 3 cm dari batas atas, dan 3 cm dari batas bawah
Jangan lupa sitasi pada setiap
kalimat yang merujuk pada
tulisan/sumber yang diperoleh 2
dari penulis lain
nano with the goal of keeping the required elements of this plant can be
appropriately absorbed by the cells of the target, because nanoparticles have a
much larger surface area against the comparative volume (Szeto, 2007).
Starting from the above problem, then research highlights against testing
the efficiency of urea nutrient release in combination with Chitosan nanoparticles
activated zeolite as a controller release nutrient elements. Blend of urea-activated
zeolite with Chitosan nanoparticles as a development of nano-fertilizers on the
expected release of nutrient enhancement capable in fertilizer. It will have an
effect on the nature of the physical, chemical, and biological in farmland. The
advantages of this fertilizer is the ability that a slow release nutrient elements
which is released slowly and continuously in a certain period of time, thereby
losing due to nutrient leaching by water.
Rumusan masalah tunjukkan
Problems penelitian memberi
banyak manfaat
The problems formulation in this study include :
1. How to improve the effectiveness of release nutrient elements from urea
fertilizer.
2. How to design method of modification urea fertilizer development
zeolite-Chitosan nanoparticles as a controller release nutrient elements.
3. How to know the effectiveness of fertilizer testing the nano as a slow
release fertilizers.
Sistematika
Systematically Writing penulisan
its ability to withstand the release of nutrient elements gradually. Chitosan has
many benefits in a variety of fields, including agriculture. One of the benefits of
chitosan in the field of agriculture, namely increasing nitrogen fixation, where
nitrogen fixation affects plant growth (Tolaimate, 2003)
Activated Zeolit
Fertilizer off slow (Slow Release Fertilizers) is a fertilizer with the release
mechanism of nutrient elements at regular intervals following a pattern of
absorption by the plant nutrient elements. Several mechanisms that can be
applied in the production of the SRF that is the mechanism of coating fertilizer.
The main principle of the mechanism is to create an obstacle in the form of
molecular interactions so that a fertilizer granules in the nutrient substances not
easily off to the environment. Slow release fertilizer can increase the efficiency
of absorption of fertilizer by plants to 75-80% if compared with the usual 40%
only fertilizer, fertilizing SRF applications only once done in one growing season.
Compared to chemical fertilizer urea given 2-3 times (Akelah, 2006).
The source of the data used in this study i.e. from experimental results or test data
laboratoium as well as the study of literature, journal and previous research in a
comprehensive manner.
Sasaran penulisan
Writing’s Variable
Fixed Variable :
1. The main raw materials (Urea, Chitosan and Zeolite)
Independent Variable :
1. Urea composition-zeolite: Chitosan nanoparticle
Measuring Variables :
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Materials
Commercial urea fertilizer, natural zeolite come from klaten, Central Java,
waste of skin shrimp, filter paper, pH paper universal comes from Hepilab, HCl
NaOH technical, aqudest, HF 1% Tween 80, NH4Cl, and ethylene glycol.
temperature 90oC. Furthermore, the skin dried shrimp then muted and stirred then
dried chitin, and the result is then washed with aquades until the pH becomes
neutral. Chitin already washed coupled with ethanol 70% and continued with
filtering, then washed sediment with akuades heat and acetone to remove color,
done twice. Chitin-shaped solid powders, dried at the temperature 80oC for 24
hours. Deasetilasi is the last stage in the manufacture of Chitosan. Marinated
shrimp skins and stirred in the NaOH 60%, then the mixture is stirred and heated
at the temperature is 120oC for 4 hours. The mixture is filtered through filter
paper wollfram, the next solution titrated using HCl to precipitate back Chitosan
back into the solution so that it will be formed Chitosan
Hasil The SEM microscope work principle is the wave nature of the electron
penelitian/analisis diffraction in the form of very small angles (Samsiah,2009 and Wulandari,2010).
data ditulis urut
Information on particle surfaces can be obtained with the introduction of the
sesuai yang
tercantum pada probes in the path of the electron beam or on the surface of the particle.
metode penelitian. Information can also be carried by the probe captures the electrons on the surface
of the tunnel between the particles of the specimen with the tip of the probe or a
probe that capture the thrust between the surface with the tip of the probe (Poole
and Owens,2003). The SEM characteristics of Chitosan nanoparticles results
showed the particles that form a circle resembling a ball. Particle size can be
determined by measuring the diameter of the ball. SEM was used to observe the
morphology of a materials. Following are the results of the analysis:
Hasil penelitian
sesuai dengan
kejadian yang
sebenar-benarnya /
tidak dimanipulasi
seuai keinginan.
Sertakan gambar dan
grafik.
Figure 4. a) The results of examination with SEM magnification of 1000x
chitosan, b) SEM magnification of 3000X, c) SEM magnification of 4000x
Tabel diberi judul dengan penomoran tabel sesuai dengan
urutan kemunculannya dalam naskah. Judul tabel ditulis di
atas tabel dengan nomor tabel menggunakan angka arab 9
The curve shows the FTIR transmitter results of chemical profile pattern
spectrum. In this study, there is 1 sample tested, namely powder Chitosan results
synthesis. Firdaus et al. (2008) Chitosan has specific clusters, namely (NH2 –
and – OH). Can be seen on the curve of the FTIR Chitosan cluster Amine (NH2 –
) are on the wave number 1650 cm-1, whereas the hydroxyl (– OH) are on the
wave number 3450 cm-1. According to Pebriani et al. (2012) absorption wave
numbers of functional Amine (NH2 –) and hydroxyl (– OH) on commercial
Chitosan is at wavelength 1655 cm-1 and 3450 cm-1. So it can be conclude that
synthesis of results has been detected pure Chitosan.
form of oxides
SiO2 61,86 %
Al2O3 10,42 %
Fe2O3 3.93%
CaO 4.53
MgO 0.74
TiO2 0.24
Na2O 0.14
K2O 1.06
MnO 0.03
H2O 5.33
K2O 13.8
The testing method used is the Kjeldahl method for Nitrogen content,
while for N, P and K method used AAS, and uv-vis Spektrofotometeri. In this
study the most optimum composition in the get on urea-zeolite: comparison with
Chitosan nanoparticle 40%: 10%: 50%. This active formulations to make
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fertilizer urea into solid and gel that changes color from white to black because of
the influence activated zeolite addition. Here are the results :
Table 3.Nitrogen Content
Sample Parameters Results
Urea N Total 7,73 %
Urea : Chitosan N Total 10,35 %
Urea : Chitosan : N Total 9,8 %
Zeolite
Nitrogen content analysis using methods kjehdahl. From the test results ,
most optimum composition on a combination of urea: chitosan which the nitrogen
content of 10. 35%, while the composition of urea-zeolite: chitosan had lower
levels of the grading of 9. 8%. The decline caused by zeolite in the composition of
the fertilizer. The decline in the percentage of the total N of the most active
formulations caused by the amount of urea is reduced and replaced by zeolite,
while the main source of nitrogen is from fertilizer urea. This is what causes the
nitrogen content is reduced. But on the other side with the addition of the raw
material zeolite in the womb of fertilizer will cause the cation exchange capability
of the mineral fertilizers contained in the soil increase as well as the nature of
other zeolite support the absorption capacity.
Table 4. Phosphorus Content
Sample Parameters Result
Urea Phosphorus 15,32 %
Urea : Chitosan Phosphorus 17,13 %
Urea : Chitosan : Phosphorus 17,78 %
Zeolite
Then the further testing is the content of phosphorus. The method used is a
UV-VIS spectrophotometer. From the analysis of testing can be seen an increase
of urea, urea: chitosan and urea-zeolite: chitosan. Most visible results on the
content of urea-zeolite composition: chitosan namely phosphorus content of 17.
78%. While the urea-chitosan composition has a content of 17. 13%. Increased
levels of phosphorus is caused because andanya cation exchange ability of zeolite.
Phosphor itself is one mineral that have a good cation growth for processes in
plants, with the addition of zeolite will certainly lead to the cation exchange
process of mineral nutrients will be increased.
The third test is a test of potassium content. From the results of nutrient
elements content testing in potassium using SSA-Flame method. The test results
look that urea fertilizer combination of chitosan and zeolite have higher levels i.e.
potassium levels amounted to 13. 64%. While in urea: chitosan amounted to 12.
86% and urea control with 10 levels. 69%. The increase in the level of potassium
is caused due to the addition of chitosan and zeolite, activated. Potassium is the
same as with the phosphor is, it is still related to cation exchange capability and
the absorption properties of the zeolite content in fertilizers which are able to fix
the nutrient content of potassium in the fertilizer. So the presence of chitosan is
able to enhance the capabilities of release of potassium from manure, whereas
zeolite acts against power of fertilizer absorbs.
Analysis using EDS (Energy Dispersy Spectroscopy) aims to find out the
content of nutrient elements contained in the soil. In the analysis by using energy
dispersy spectroscopy shows all of the material contained in the sample will be
detected, but only at the results of this analysis show the nutrient psospor and
potassium, while for the element nitrogen cannot be detected by testing samples.
This is caused because the gaseous nitrogen, whereas samples which can be
analysis only at solid phase. Here the following analysis results:
70 25.91
60 21.31
18.24
50
14.42 34.52
40 32.1
Nilai
29.1
30 21.86
20
10
0
Kontrol Urea Kitosan-Urea Urea-Kitosan-Zeolit
Nilai K Nilai P
30 9.84 27.16
6.91
20
12.25
10 9.42
0
Kontrol Urea Kitosan-Urea Urea-Kitosan-Zeolit
Nilai K Nilai P
Figure 7. EDS Analysis After Watering Them with Water for 2 Weeks
The fourth variation of the difference that can be seen on the nutrient
elements such as P and K. On the variation of urea-zeolite: chitosan slowdown in
the release rate of the most effective nutrients. The test results Potassium content
of 34. 52% down to 30. 4% while the phosphor of 25. 91% down to 21 to 48%.
From the observation charts can be seen a significant increase in the addition of
zeolite and chitosan nanoparticles in the formulation of slow release urea
fertilizer. Decreasing the release of fertilizer efficiency lead to the release of
nutrients will run longer and in the long term. This is because the pores of urea
will be coated with chitosan nanoparticles, resulting in degradation of the ability
of water to urea will be smaller. This will impact on the ability of urea nutrient
release better.
Analysis of soil properties made after 1 month of fertilizer in the soil. The
goal is to determine the effect of fertilizers on the physical properties of the soil.
There are 4 samples in the analysis of control, urea, urea and urea-chitosan-
zeolite: chitosan. Here the following analysis results:
EDS of the chart data can be analyzed the efficiency of nutrients release
from fertilizers. Comparative test in use is the control of urea with urea-modified
zeolite: chitosan nanoparticles. The element phosphorus has increased from
release of 8.76 to the treatment of urea to 4.43 by using the most active
formulations, it is also evident from nutrient release of potassium from 16.85
down to 4.12. The decline in the release of nutrients will increase the power
16
Pebriani et al. 2012. Modifikasi Komposisi pada Proses Sintesis Komposit TiO2-
Chitosan. Jurnal Kimia Unand Vol. 1 (1).
Poole & Owens FJ. 2003. Introduction to Nanotechnology. New Jersey: John
Wiley & Sons Inc.
Prima. 2009. Permasalahan Pupuk dan Langkah-langkah Penanggulangannya di
Indonesia. Kementrian Sekertariat Negara Indoneisa. Jakarta. Vol 14.
24-34.
Rachmania D. 2012. Karakterisasi Nano Chitosan Cangkang Udang Vanamei
dengan Metode Gelasi Ionik. Bogor: FPIK, Institut Pertanian Bogor.
Suwardi. 1999. Pemanfaatan Zeolit sebagai Media Tumbuh Tanaman
Hortikultura. Prosiding. Temu Ilmiah. 1-3 September 1995. PPI.
Tokyo. Jepang.
Szeto, et al. 2007. Exploring Nanochitosan. ATA-Journal for Asia on Textile &
Apparel. China.
Wahyono D. 2010. Ciri Nanopartikel Chitosan dan Pengaruhnya pada Ukuran
Partikel dan Efesiensi Penyalutan Ketoprofen. Bogor: Pascasarjana
IPB.
Wulandari T. 2010. Sintesis Nanopartikel Ekstrak Temulawak (Crucuma
xanthorrhiza Roxb.) Berbasis Polimer Chitosan-TPP dengan Metode
Emulsi [Skripsi]. Bogor: Fakultas MIPA, Institut Pertanian Bogor.
Yanti, S. 2014. Pengaruh Penambahan Berbagai Dosis Aplikasi Pupuk Urea
terhadap Produksi Tanaman Sawi. Junal Ornaline Argoteknologi ISSN
No. 2337-6957.
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Lampiran-Lampiran terdiri atas :
Halaman pengesahan, Lembar orisinilitas
karya, Biodata peserta, Biodata dosen
pembimbing, Fotokopi Kartu
Mahasiswa/KTM yang masih berlaku, dan
ATTACHMENT Lampiran lain jika diperlukan
1. VALIDATION PAGE
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2. ORIGINALITY PAGE
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PARTICIPANT
A. Identity
a. Full Name : Annizah Rahmatya Gerhana
b. Birth Date and Place : Jayapura, 24 Oktober 1995
c. NIM : 21030113120076
d. Department/Faculty : Teknik Kimia/ Teknik
e. Phone Number : 085713541575
f. Adress : Jl. Gatotkoco 2 Pancaarga 2 Magelang
g. Email : anisa.gerhana@che.undip.ac.id
h. Awards :-
All the data I input and biographical data contained is correct and legally
defensible . If later on it turned out to be found different with reality, I should
accept the sanctions. Thereby I created this biographical data to fulfill the
requirements of Chemical Engineering Research Competition.
Annizah R. Gerhana
B. Identity
a. Full Name : Alfin Darari
b. Birth Date and Place : Semarang, 17 Februari 1994
c. NIM : 24040112140089
d. Department/Faculty : Fisika/ Sains dan Matematika
e. Phone Number : 085713541575
f. Adress : Puri Anjasmoro, Semarang
g. Email : Alfin.darari@st.fisika.undip.ac.id
h. Awards :-
All the data I input and biographical data contained is correct and legally
defensible . If later on it turned out to be found different with reality, I should
accept the sanctions. Thereby I created this biographical data to fulfill the
requirements of Chemical Engineering Research Competition.
Alfin Darari
21
C. Identity
a. Full Name : Eko Siswoyo
b. Birth Date and Place : Pati, 2 Agustus 1995
c. NIM : Ekosiswoyo37@gmail.com
d. Department/Faculty : Kimia/ Sains dan Matematika
e. Phone Number : 085740763575
f. Adress : Pati, Jawa Tengah
g. Email : Ekosiswoyo37@gmail.com
h. Awards :-
All the data I input and biographical data contained is correct and legally
defensible . If later on it turned out to be found different with reality, I should
accept the sanctions. Thereby I created this biographical data to fulfill the
requirements of Chemical Engineering Research Competition.
Eko Siswoyo
22