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CHEMISTRY QUIZ

Name : Class :
MARKS
Q1 / SOA (Total : 9) Q2 / Thermo (Total : 11) Q3 / Redox (Total : 12)

Answer all questions


1 Table 1 shows the proton number of two elements X and Y.
Jadual 1 menunjukkan nombor proton bagi dua unsur X dan Y.

Element Proton number


Unsur Nombor proton
X 6
Y 11

Table 1 / Jadual 1

(a) The number of neutron of atom of element X is 6. Draw the atomic structure of
atom X.
Bilangan neutron bagi atom unsur X adalah 6. Lukiskan struktur atom bagi atom X.

[2 marks]
(b) (i) Element X has isotopes. What is meant by isotopes?
Unsur X mempunyai isotop. Apakah yang dimaksudkan dengan isotop?

…………………………………………………………………….…………

…………………………………………………………………….…………
[1 mark]
(ii) State one example of an isotope.
Nyatakan satu contoh bagi isotop.

…………………………………………………………………….…………
[1 mark]

1
(c) The nucleon number of atom of element Y is 23. Calculate the number of
neutrons in atom Y.
Nombor nukleon bagi atom unsur Y adalah 23. Hitungkan bilangan neutron
dalam atom Y.

…………………………………………………………………….………………
[1 mark]
(d) Methanol is an organic compound with melting point of - 97 oC and boiling point
of 65 oC.
Metanol ialah sebatian organik dengan takat lebur - 97 oC dan takat didih 65
o
C.

(i) What is the physical state of methanol at room temperature?


Apakah keadaan fizik bagi metanol pada suhu bilik?

…………………………………………………………………….…………
[1 mark]
(ii) State how the movement of methanol particles changes when heated from
room temperature to 100 oC.
Nyatakan bagaimana pergerakan zarah metanol berubah apabila
dipanaskan daripada suhu bilik kepada 100 oC.

…………………………………………………………………….…………
[1 mark]
(iii) Sketch the graph of temperature against time when methanol is heated from
room temperature to 100 oC.
Lakarkan graf suhu melawan masa apabila metanol dipanaskan daripada
suhu bilik kepada 100 oC.
Temperature / oC
Suhu / oC

100

Room temperature
Suhu bilik

Time / min
Masa / min

[2 marks]

2
2 Diagram 2 shows the apparatus set-up to determine the heat of neutralisation between
a strong acid and a strong alkali. In this experiment, 50 cm3 of 2.0 mol dm-3
hydrochloric acid is reacted with 50 cm3 of 2.0 mol dm-3 sodium hydroxide
solution.
Rajah 5 menunjukkan susunan radas untuk menentukan haba peneutralan antara
asid kuat dengan alkali kuat. Dalam eksperimen ini, 50 cm3 asid hidroklorik
2.0 mol dm-3 ditindakbalaskan dengan 50 cm3 larutan natrium hidroksida 2.0 mol
dm-3

T1 T2
T3

Hydrochloric acid
Asid hidroklorik

Hydrochloric acid Sodium hydroxide solution Sodium hydroxide solution


Asid hidroklorik Larutan natrium hidroksida Larutan natrium hidroksida

Diagram / Rajah 2

Table 5 shows the results obtained:


Jadual 5 menunjukkan data yang diperolehi:

Initial temperature of hydrochloric acid, T1


28.0 °C
Suhu awal asid hidroklorik, T1

Initial temperature of sodium hydroxide solution, T2


28.0 °C
Suhu awal larutan natrium hidroksida, T2

The highest temperature reached by the mixture, T3


41.0 °C
Suhu tertinggi yang dicapai oleh campuran, T3

Table / Jadual 2

(a) What is the meaning of heat of neutralisation?


Apakah yang dimaksudkan dengan haba peneutralan?

.................................................................................................................................

.................................................................................................................................
[1 markah]

3
(b) Write the chemical equation for the neutralisation reaction.
Tuliskan persamaan kimia bagi tindak balas peneutralan tersebut.

.................................................................................................................................
[1 markah]
(c) (i) Calculate the number of mole of hydrochloric acid or the number of mole of
sodium hydroxide solution used in this experiment.
Hitungkan bilangan mol asid hidroklorik atau bilangan mol larutan natrium
hidroksida yang digunakan dalam eksperimen ini.

[1 markah]
(ii) Calculate heat change in the reaction.
Hitungkan perubahan haba dalam tindak balas ini.
[Specific heat capacity of solution, c = 4.2 J g-1°C-1]
[Muatan haba tentu larutan, c = 4.2 J g-1°C-1]

[1 markah]

(iii) Determine the heat of neutralisation of the reaction between hydrochloric acid
and sodium hydroxide solution.
Tentukan haba peneutralan bagi tindak balas antara asid hidroklorik dan
larutan natrium hidroksida.

[2 markah]
(d) Draw the energy level diagram for the reaction.
Lukiskan gambar rajah aras tenaga bagi tindak balas tersebut.

[3 markah]

4
(e) The experiment is repeated by replacing the hydrochloric acid with ethanoic acid.
All other conditions remain unchanged.
Eksperimen tersebut diulangi dengan menggantikan asid hidroklorik dengan asid
etanoik. Semua keadaan yang lain kekal tidak berubah.

(i) Predict the value of the heat of neutralisation for the between ethanoic acid and
sodium hydroxide solution.
Ramalkan nilai haba peneutralan bagi tindak balas antara asid etanoik dan
larutan natrium hidroksida.

.......................................................................................................................
[1 markah]

(ii) Explain your answer in (d) (i).


Terangkan jawapan anda di (d) (i).

.......................................................................................................................
[1 markah]

3 (a) Diagram 3.1 show a set of experiment to study a redox reaction.


Rajah 3.1 menunjukkan satu set eksperimen untuk mengkaji suatu tindak balas
redoks.

Bromine water
Air bromin

Iron(II) sulphate solution


Larutan ferum(II) sulfat

Diagram / Rajah 3.1

(i) State the observation for the experiment.


Nyatakan pemerhatian bagi eksperimen itu.

..........................................................................................................................
[1 mark]
(ii) Which substance that undergo reduction reaction.
Manakah bahan yang mengalami tindak balas penurunan

..........................................................................................................................
[1 mark]

5
(iii) Write the ionic equation for the oxidation reaction.
Tuliskan persamaan ion bagi tindak balas pengoksidaan.

..........................................................................................................................
[2 marks]

(iv) State the change in oxidation number for bromine water.


Nyatakan perubahan nombor pengoksidaan bagi air bromin.

..........................................................................................................................
[1 mark]

(v) If the bromine water is replaced by magnesium ribbon, state the colour
changes to the iron(II) sulphate solution.
Jika air bromin diganti dengan pita magnesium, nyatakan perubahan
warna kepada larutan ferum(II) sulfat.

..........................................................................................................................
[1 mark]

(b) Diagram 3.2 shows the set-up of apparatus to investigate the reaction between
potassium manganate(VII) solution and iron(II) chloride solution through the transfer
of electrons at a distance.
Rajah 3.2 menunjukkan susunan radas untuk menyiasat tindakbalas di antara larutan
kalium manganat (VII) dan larutan ferum(II) klorida melalui pemindahan elektron
pada satu jarak.
.

Carbon electrode Carbon electrode


Elektrod karbon P Q
P Q Elektrod karbon

Acidified Potassium
Iron(II) chloride solution
manganate(VII) solution
Larutanferum(II) klorida
Larutan Kalium
manganat(VII) berasid

Dilute sulphuric acid


Asid sulfurikcair

Diagram / Rajah 3.2

6
The incomplete ionic equation for the reaction is :
Persamaan ion yang tidak lengkap bagi tindak balas tersebut ialah :

………. Fe2+ + MnO4- + 8H+ → 5Fe3+ + Mn2+ + …………. H2O


(i) Complete the above equation.
Lengkapkan persamaan di atas. [1 mark]

(ii) What is the change of solution colour at electrode P?


Apakah perubahan warna dalam larutan pada elektrod P?

………………………………………………………………………………
[1 mark]
(iii) What is the substance that undergoes oxidation in this experiment? Explain
why.
Apakah bahan yang mengalami pengoksidaan dalam eksperimen ini?
Terangkan mengapa.
………………………………………………………………………………
………………………………………………………………………………
[2 marks]
(iii) Describe a chemical test to determine the product formed at electrode Q.
Huraikan satu ujian kimia untuk menentukan hasil yang terbentuk di elektrod
Q.
…………………………………………………………………………………
…………………………………………………………………………………
[2 marks]

7
CHEMISTRY QUIZ ANSWER SCHEME
1 (a)

Nucleus:
6p
6n

[Electron arrangement] 1
[Number of proton & neutron] 1 ...2

(b) (i) Isotopes are atoms (of the same element) with the same
proton number but different nucleon number // 1

Isotopes are atoms (of the same element) with the same
number of protons but different number of neutrons.
(ii) [Any example of isotope] 1

Sample answer :
Carbon-14, Cobalt-60, Sodium-24, Iodine-131 etc
(c) 12 1
(d) (i) Liquid 1
(ii) Becomes faster 1
(iii)
Temperature/ oC
100

65

RT

Time/ min
[Correct shape of the graph] 1
[Indicate the boiling point at 65 oC] 1 ...2

TOTAL 9

8
2 (a) Heat change when H+ ion combines with OH- ion to form 1 1
mol of water.

(b) HCl + NaOH → NaCl + H2O 1

(c) (i) Number of mole of NaOH/HCl = 2.0 x 50 // 0.1 1

1000

(ii) Heat change = 100 x 4.2 x (41-28) J // 5460 J 1

(iii) 1 mol H2O released 5460 J // 54600 J 1

0.1

Heat of neutralisation, ∆H = - 54.6 kJ mol-1 1

Energy
(d)
H+ + OH- // HCl + NaOH

∆H = - 54.6 kJ mol-1
3

H2O // NaCl + H2O

(e) (i) Less than 54.6 kJ mol-1 1

(ii) Heat released is absorbed /used by the molecule of


ethanoic acid to ionise completely
1

TOTAL 11

9
3 (a) (i) Green solution to brown // Brown to colourless 1
(ii) Bromine 1
(iii) Fe2+ → Fe3+ + e
[Correct formula of reactant and products] 1
[Balanced equation] 1 ...2

(iv) 0 → -1 1
(v) Green solution to colourless 1

(b) (i) …5…Fe2+ + MnO4- + 8H+ → 5Fe3+ + Mn2+ + …4... H2O 1

(ii) purple to colourless 1


(iii) Iron(II) ion // Fe2+ 1
Oxidation number of iron increased // Fe2+ donate electron 1 2
(iv) Add sodium hydroxide/ammonia solution. 1
Brown precipitate formed. 1 2
TOTAL 12

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