Lecture 3
Physicochemical
Processes
Physicochemical Processes
Air stripping
Carbon adsorption
Steam stripping
Chemical oxidation
Supercritical fluids
Membrane processes
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1. Air Stripping
1. Air Stripping
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1. Air Stripping
1. Air Stripping
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1. Air Stripping
In order to develop a
design equation, a
section of the stripping
tower is selected.
The section has a
superficial surface
area B, and a
differential thickness
dz.
1. Air Stripping
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1. Air Stripping
1. Air Stripping
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2. Carbon Adsorption
2. Carbon Adsorption
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2. Carbon Adsorption
Carbon contactors
2. Carbon Adsorption
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2. Carbon Adsorption
2. Carbon Adsorption
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Factor Effect
Solubility Less soluble compounds are adsorbed to
greater extent than more soluble compounds.
Molecular structure Branch-chain organics are more easily
adsorbed than straight-chain organics.
Molecular weight Larger molecules are more easily adsorbed
than smaller molecules. However, pore
diffusion governs the absorption process, the
adsorption rate decreases with molecular
weight.
Polarity Less polar organics are more easily adsorbed
than polar organics.
Hydrocarbon Unsaturated organics are adsorbed more
saturation easily than saturated organics.
Adsorption isotherms
Langmuir isotherm
q = abC/(1+bC) (Eq.2)
q : mass of contaminant absorbed
a,b : constants
C : concentration
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Adsorption isotherms
Freundlich isotherm
q = KCf1/n (Eq. 3)
q = (Ci -Cf)xV / mass of carbon (mg)
2. Carbon Adsorption
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3. Steam Stripping
3. Steam Stripping
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3. Steam Stripping
3. Steam Stripping
The steam exits the top of the column and enters the
condenser.
This supersaturated liquid enters the decanter to
separate by floating or sinking.
The aqueous phase from the decanter is returned to the
top of the column.
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3. Steam Stripping
3. Steam Stripping
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3. Steam Stripping
3. Steam Stripping
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4. Chemical Oxidation
4. Chemical Oxidation
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4. Chemical Oxidation
UV/H2O2 system
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4. Chemical Oxidation
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4. Chemical Oxidation
4. Chemical Oxidation
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4. Chemical Oxidation
Solution:
This implies that 2.5 moles of Cl2 are required for each mole of
NaCN.
5. Supercritical Fluids
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5. Supercritical Fluids
5. Supercritical Fluids
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5. Supercritical Fluids
5. Supercritical Fluids
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6. Membrane Processes
Electrodialysis
Reverse osmosis
Ultrafiltration
Electrodialysis
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Electrodialysis
Reverse osmosis
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Reverse osmosis
Reverse osmosis
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Reverse osmosis
Reverse osmosis
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Ultrafiltration (UF)
Ultrafiltration (UF)
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Ultrafiltration (UF)
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