NERACA MASSA PRA RANCANGAN PABRIK SODIUM TRYPOLYPHOSPHATE

KAPASITAS 66000 TON/TAHUN

Kapasitas = 66000 ton/tahun

Operasi = 330 hari/tahun
Basis operasi = 1 jam
Jumlah produksi = 8333.3333 kg/jam
= 22.6533 kmol/jam Na5P3O10

Reaksi :
2 H 3 PO4  Na 2 CO3  2 NaH 2 PO4  CO2  H 2 O
3a 3a/2 3a 3a/2

2 NaH 2 PO 4  Na 2 CO 3  2 Na 2 HPO 4  CO 2  H 2 O
2a a 2a a

NaH 2 PO 4  2 Na 2 HPO 4  Na 5 P3 O 10  2 H 2 O
a 2a a 2a

Konversi reaksi = 94% US PATENT 4,224,294

Reaksi : 6 H 3 PO4  5 Na2CO3  2 NaH 2 PO4  4 Na2 HPO4  5CO2 

3a 2.5a a 2a

Reaksi : 6 H 3 PO4  5 Na2CO3  2 NaH 2 PO4  4 Na2 HPO4  5CO2 

67.9598 56.6332 22.6533 45.3065

6 H 3 PO4  5 Na2CO3  2 NaH 2 PO4  4 Na2 HPO4  5CO2 

Awal 67.9598 60.2481

Reaksi 67.9598 56.6332 22.6533 45.3065
Akhir 0.0000 3.6149 22.6533 45.3065

2 H 3 PO4  Na 2 CO3  2 NaH 2 PO 4  CO2  H 2 O

Awal 67.9598 60.2481
Reaksi 67.9598 33.9799 67.9598 33.9799
Akhir 0.0000 26.2682 67.9598 33.9799

2 NaH 2 PO 4  Na 2 CO 3  2 Na 2 HPO 4  CO 2  H 2 O
Awal 67.9598 26.2682
Reaksi 45.3065 22.6533 45.3065 22.6533
Akhir 22.6533 3.6149 45.3065 22.6533

NaH 2 PO 4  2 Na 2 HPO 4  Na 5 P3 O 10  2 H 2 O
Awal 22.6533 45.3065
Reaksi 22.6533 45.3065 22.6533 45.3065
Akhir 0.0000 0.0000 22.6533 45.3065

Kemurnian Bahan Baku

Asam Fosfat 85.00%
Natrium Karbonat 99.88%

Neraca Massa : Material out = Material in + Generation - Consumption - Accumulation

1 MIXER

1
M - 01 3
2

Kelarutan
Jumlah airNatrium Karbonatuntuk
yang dibutuhkan pada temperatur
melarutkan 30
o
umpanC = Natrium Karbonat
38.8 g/100
: ml

38.8 g 4644.0944  10 3

100 ml x
X= 16457809 ml = 16457.80878 L = 16457.81 kg

Nomor Arus Arus 1 Arus 2

 Komponen % massa kg/jam kmol/jam % massa kg/jam
Na2CO3 0.9988 6385.6298 60.2481 - -
H2O 0.0012 7.4993 0.4163 1 16457.8088
Fe 0.000007 0.0448 0.0008 - -
Cl 0.00002 0.1279 0.0036 - -
Sub Total 1 6393.3018 1 16457.8088
Total 22851.1106

2 REAKTOR

4
R - 01 8
6 ma
mole B
Y  A

mole B
ma
B

Nomor Arus Arus 4 Arus 6

Komponen % massa kg/jam kmol/jam % massa kg/jam
H3PO4 - - - 0.8500 6659.7441
CaO - - - 0.0001 0.3917
F- - - - 0.0008 6.2680
Al2O3 - - - 0.0001 0.7835
Fe2O3 - - - 0.0001 0.5484
MgO - - - 0.0000 0.2350
Na2O - - - 0.0000 0.1959
SiO2 - - - 0.0010 7.8350
SO42- - - - 0.0020 15.6700
Na2CO3 0.2794 6385.6298 60.2481 - -
Fe 0.0000 0.0448 0.0008 - -
Cl 0.0000 0.1279 0.0036 - -
Na5P3O10 - - - - -
NaH2PO4 - - - - -
Na2HPO4 - - - - -
CO2 - - - - -
H2O 0.7205 16465.3081 913.9604 0.1459 1143.3214
Sub Total 1 22851.1106 974.2129 1 7834.9930
Total 30686.1036
M TRYPOLYPHOSPHATE
UN

Komponen Rumus Molekul BM (kg/kmol)

Asam Fosfat H3PO4 97.99531
Natrium Karbonat Na2CO3 105.98895
Sodium Tripolyphosphate Na5P3O10 367.8644
Monosodium Fosfat NaH2PO4 119.97714
Disodium Fosfat Na2HPO4 141.95897
Karbon Dioksida CO2 44.00995
Water H2O 18.015

 H 2O 2 H 3 PO4  Na 2 CO3  2 NaH 2 PO4  CO

3a/2 67.9598 33.9799
a= 22.6533

2  H 2O 2 NaH 2 PO 4  Na 2 CO 3  2 Na 2 HPO 4  C
a 45.3065 22.6533

 2 H 2O NaH 2 PO 4  2 Na 2 HPO 4  Na 5 P3 O 1
2a 22.6533 45.3065

Bahan Baku % massa

Na2CO3 99.8800%
H2O 0.1173%
Fe 0.0007%
Cl 0.0020%

Bahan Baku % massa

H3PO4
Na2 HPO4  5CO2  5 H 2O 85.00%
CaO 0.01%
2.5a 2.5a F- 0.08%
Al2O3 0.01%
Fe2O3
Na2 HPO4  5CO2  5 H 2O 0.01%
MgO 0.00%
56.6332 56.6332 Na2O 0.00%
SiO2 0.10%
SO42-
Na2 HPO4  5CO2  5 H 2O 0.20%
H2O 14.59%
 56.6332 56.6332
56.6332 56.6332

O2  H 2 O

33.9799
33.9799

O 2  H 2O

22.6533
22.6533

 2 H 2O

45.3065
45.3065

n - Accumulation

Perry's

Arus 2 Arus 3
 kmol/jam % massa kg/jam kmol/jam
- 0.2794 6385.6298 60.2481
913.544167 0.7205 16465.3081 913.9604
- 0.0000 0.0448 0.0008
- 0.0000 0.1279 0.0036
1 22851.1106
22851.1106

Jumlah uap air dalam CO2 (Arus 7)

A = uap air
B = CO2
Pada kondisi jenuh T= 90 ˚C
PA = PAs = 70.1390 kPa = 0.6922 atm
PAs
Ys  Pt = 1.0000 atm
Pt  PAs
Ys = 2.2491
massa A  massa B 
massa A  Y     BM A
mole BM  BM B 
Y  A
 A

mole B
massa B

BM massa uap air = 2294.6316 kg/jam

B

Arus 6 Arus 7 Arus 8

kmol/jam % massa kg/jam kmol/jam % massa kg/jam kmol/jam
67.9598 - - - - - -
0.0070 - - - 0.0000 0.3917 0.0070
0.3299 - - - 0.0002 6.2680 0.3299
0.0077 - - - 0.0000 0.7835 0.0077
0.0034 - - - 0.0000 0.5484 0.0034
0.0058 - - - 0.0000 0.2350 0.0058
0.0032 - - - 0.0000 0.1959 0.0032
0.1304 - - - 0.0003 7.8350 0.1304
0.1631 - - - 0.0006 15.6700 0.1631
- - - - 0.0148 383.1378 3.6149
- - - - 0.0000 0.0448 0.0008
- - - - 0.0000 0.1279 0.0036
- - - - - - -
- - - - 0.1049 2717.8751 22.6533
- - - - 0.2483 6431.6711 45.3065
- 0.5207 2492.4237 56.6332 - - -
63.4638 0.4793 2294.6316 127.3710 0.6307 16334.2640 906.6864
132.0741 1 4787.0554 184.0042 1 25899.0482 978.9161
30686.1036
 Atom Massa Atom
H 1.00797
P 30.9738
O 15.9994
Na 22.9898
C 12.01115

 2 NaH 2 PO4  CO2  H 2 O

67.9598 33.9799 33.97991

 2 Na 2 HPO 4  CO 2  H 2 O
45.3065 22.6533 22.6533

PO 4  Na 5 P3 O 10  2 H 2 O
22.6533 45.3065

BM
105.9890
18.0153
55.8470
35.4530

BM
97.9953
56.0794
18.9984
101.9612
159.6922
40.3114
61.9790
60.0838
96.0616
18.0153