SAFETY DATA SHEET

Revision Date 25-Jan-2016 Version 1

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING
1.1. Product identifier

Product Name 3939DB BLACK

Product Code 1060034
Description THERMOPLASTIC ELASTOMER

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use Restricted to professional users

Uses advised against No information available

1.3. Details of the supplier of the safety data sheet

Manufacturer
Teknor Apex BV
P.O. Box 43
6160 AP Geleen
The Netherlands

SDS Contact (email of responsible person)

E-mail address TeknorSDS@TeknorApex.com
1.4. Emergency telephone number

Emergency Telephone EU: [+31] (0) 46 465 - 468

ChemTel 24-Hr Emergency Response Telephone Number:

USA Only: 800-255-3924
International: 001-813-248-0585
Contract #: MIS0006505

Section 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)

Classification according to Directive 67/548/EEC or 1999/45/EC

This mixture is not classified as dangerous according to 1999/45/EC

Full text of R-phrases: see section 16

2.2. Label elements

Labeling according to Regulation (EC) No. 1272/2008 [CLP]

Hazard Statements
Not Applicable
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Precautionary Statements - EU (§28, 1272/2008)

Not Applicable

SUPPLEMENTAL INFORMATION

No information available

2.3. Other hazards

No information available

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

The components of this product are embedded in an impervious polymer matrix and are therefore not biologically available. Any
hazardous constituents are fixed in the polymer matrix and therefore present a negligible exposure risk under normal conditions of
processing and handling. Additives contained in this product do not pose a risk to health unless they are liberated during
processing (fumes from melting, dusts). Suitable Industrial Hygiene precautions should be implemented to prevent (respirable) dust
and fume exposures. Exposure to (melting) fumes should be kept as low as possible, using suitable ventilation equipment. Dusts
and fumes created from secondary processing may be irritating to respiratory tract and skin and should be considered as
potentially hazardous. If user operations generate dust, fumes, or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.

Chemical Name EC No CAS No weight-% Classification Classification according REACH Reg. No

according to to Regulation (EC) No.
Directive 1272/2008 [CLP]
67/548/EEC or
1999/45/EC
ZINC OXIDE 215-222-5 1314-13-2 <2 N; R50-53 Aquatic Acute 1 (H400) No data available
Aquatic Chronic 1 (H410)
TALC 238-877-9 14807-96-6 <2 - - No data available
CARBON BLACK 215-609-9 1333-86-4 <2 - - No data available
435-640-3
Stannous Chloride 231-868-0 7772-99-8 <2 - - No data available

Full text of R-phrases: see section 16

Full text of H- and EUH-phrases: see section 16

Further information
There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned a workplace exposure limit and
hence require reporting in this section.
See section 8 for more information

Section 4: FIRST AID MEASURES

4.1. Description of first aid measures

General advice Dusts and fumes created from secondary processing may be irritating to respiratory tract
and skin and should be considered as potentially hazardous.

Inhalation None under normal use conditions.

Skin Contact Rinse with plenty of running water. Do not pull coagulated product loose. Get medical
attention.

Eye contact Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if
symptoms occur.

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Ingestion Never give anything by mouth to an unconscious person. Clean mouth with water and drink
afterwards plenty of water. Get medical attention if symptoms occur.

Self-protection of the first aider No action shall be taken involving any personal risk or without suitable training.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms No known effects under normal use conditions.

4.3. Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

Section 5: FIRE FIGHTING MEASURES

5.1. Extinguishing media

Suitable Extinguishing Media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Small Fire Dry chemical or CO2.

Large Fire Dry chemical, CO2, alcohol-resistant foam or water spray.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from No specific hazard known

the chemical

Hazardous combustion productsCarbon monoxide. Carbon dioxide (CO2). Hydrocarbons. Aldehydes. Organic Vapors.
Acrolein. Formaldehyde.

5.3. Advice for firefighters

Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required.

Section 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Personal Precautions
No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Put on appropriate personal protective equipment.

For emergency responders

If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable
materials. See also Section 8 for additional information on hygiene measures.

6.2. Environmental precautions

No specific measures identified.

6.3. Methods and material for containment and cleaning up

Methods for Containment Vacuum or sweep material and place in a disposal container.

Methods for Clean-Up Vacuum or sweep material and place in a disposal container. Recover or recycle if possible.
Prevent dust cloud. After cleaning, flush away traces with water.

6.4. Reference to other sections

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See section 1 for more information

See section 8 for more information
See section 13 for more information

Section 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Advice on safe handling

Ensure adequate ventilation, especially in confined areas.

General Hygiene Considerations

Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. Wash
hands thoroughly after handling. Keep working clothes separately. Use personal protection recommended in Section 8.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions
No special measures are necessary.

7.3. Specific end use(s)

Specific use(s)
Not available.

Risk Management Methods (RMM)

Not Applicable.

Other Information
Octabins can be stacked up to three high. Big Bags and pallets may not be stacked. Small amounts of fine particles or dust may be
formed from pelletised product impacting with material handling systems. If permitted to accumulate, these fine particles or dust
can, under certain conditions, pose an explosion hazard.

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Chemical Name ZINC OXIDE

1314-13-2
France TWA: 5 mg/m3 VME fume
TWA: 10 mg/m3 VME dust
Spain STEL: 10 mg/m3 VLA-EC
TWA: 2 mg/m3 VLA-ED respirable fraction
Germany TWA: 0.1 mg/m3 MAK respirable fraction
TWA: 2 mg/m3 MAK inhalable fraction
Peak: 0.4 mg/m3 respirable fraction
Peak: 4 mg/m3 except Zinc chloride inhalable fraction
Portugal STEL: 10 mg/m3 VLE-CD respirable fraction
TWA: 2 mg/m3 VLE-MP respirable fraction
Finland TWA: 2 mg/m3 fume
STEL: 10 mg/m3 fume
Denmark TWA: 4 mg/m3 Zn
TWA: 4 mg/m3 Zn fume
Austria TWA: 5 mg/m3 TMW respirable fraction, smoke
Switzerland STEL: 3 mg/m3 KZW respirable dust, smoke
TWA: 3 mg/m3 MAK respirable dust, smoke
Poland STEL: 10 mg/m3
TWA: 5 mg/m3
Norway TWA: 5 mg/m3
STEL: 10 mg/m3
Ireland TWA: 2 mg/m3 fume
STEL: 10 mg/m3 fume
Chemical Name TALC
14807-96-6
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United Kingdom STEL: 3 mg/m3 calculated respirable dust

TWA: 1 mg/m3 respirable dust
Spain TWA: 2 mg/m3 VLA-ED containing no Asbestos fibers;this value is for the particulate matter that is free
from Asbestos and contains less than 1% of Crystalline silica;see UNE EN 481:1995 Workplace
atmospheres. Definition of the fractions by particle size for aerosol measurement respirable fraction
Germany Skin
Portugal TWA: 2 mg/m3 VLE-MP respirable fraction, particulate matter containing no Asbestos and <1%
Crystalline silica
Netherlands TWA: 0.25 mg/m3
Finland TWA: 0.5 fiber/cm3 fiber
STEL: 2 ppm granular form, inhalable dust
STEL: 1 ppm granular form, respirable
Denmark TWA: 0.3 fiber/cm3 containing fibers
Austria TWA: 2 mg/m3 TMW Asbestos-free fibers respirable fraction
Switzerland TWA: 2 mg/m3 MAK respirable dust
Poland TWA: 4.0 mg/m3
TWA: 1.0 mg/m3
Norway TWA: 6 mg/m3 total dust
TWA: 2 mg/m3 respirable dust
STEL: 6 mg/m3 total dust
STEL: 2 mg/m3 respirable dust
Ireland TWA: 10 mg/m3 total inhalable dust
TWA: 0.8 mg/m3 respirable dust
STEL: 30 mg/m3 calculated total inhalable dust
STEL: 2.4 mg/m3 calculated respirable dust
Chemical Name CARBON BLACK
1333-86-4
United Kingdom STEL: 7 mg/m3
TWA: 3.5 mg/m3
France TWA: 3.5 mg/m3 VME
Spain TWA: 3.5 mg/m3 VLA-ED
Germany Skin
Portugal TWA: 3.5 mg/m3 VLE-MP
Finland TWA: 3.5 mg/m3
STEL: 7 mg/m3
Denmark TWA: 3.5 mg/m3
Poland TWA: 4.0 mg/m3
Norway TWA: 3.5 mg/m3
STEL: 3.5 mg/m3
Ireland TWA: 3.5 mg/m3
STEL: 7 mg/m3
Chemical Name Stannous Chloride
7772-99-8
European Union TWA: 2 mg/m3 as Sn
United Kingdom TWA: 2 mg/m3 except SnH4 Sn
Spain TWA: 2 mg/m3 VLA-ED Sn
Portugal TWA: 2 mg/m3 VLE-MP indicative limit value;except Tin hydride Sn
Finland TWA: 2 mg/m3 Sn
Denmark TWA: 2 mg/m3 Sn
Austria STEL: 4 mg/m3 KZW Sn inhalable fraction 4 X 15 min
TWA: 2 mg/m3 TMW Sn inhalable fraction
Switzerland STEL: 4 mg/m3 KZW Sn inhalable dust
TWA: 2 mg/m3 MAK Sn inhalable dust
Poland TWA: 2 mg/m3
Norway TWA: 2 mg/m3 Sn
STEL: 2 mg/m3 Sn
Ireland TWA: 2 mg/m3 except SnH4 Sn
STEL: 6 mg/m3 calculated;except SnH4 Sn

If this product contains ingredients with exposure limits, personal, workplace atmosphere or
Restriction and monitoring of
exposure biological monitoring may be required to determine the effectiveness of the ventilation or
other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to European Standard EN 689 for methods for the assessment
of exposure by inhalation to chemical agents and national guidance documents for methods
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Derived No Effect Level (DNEL)
Predicted No Effect Concentration
(PNEC)
8.2. Exposure controls
Engineering Controls
Personal Protective Equipment
Eye/face Protection
Hand Protection
Skin and Body Protection
Respiratory Protection
Environmental exposure controls
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Physical State
Appearance
Color
Property
pH
Melting point/freezing point
Boiling point / boiling range
Flash Point
Evaporation Rate
Flammability (solid, gas)
Flammability Limit in Air
Upper Flammability Limit
Lower Flammability Limit
Vapor Pressure
Vapor Density
Specific Gravity
Water solubility
Partition coefficient
Autoignition Temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
9.2. Other information
Softening Point
Molecular weight
VOC Content (%)
Density
Bulk Density
Section 10: STABILITY AND REACTIVITY
10.1. Reactivity
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1060034 Revision Date 25-Jan-2016
No information available
No information available.
None required. However, use of adequate ventilation is good industrial practice.
Tight sealing safety goggles.
Wear protective gloves.
Suitable protective clothing.
No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Emissions from ventilation or work process equipment should be checked to ensure they
comply with the requirements of environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process equipment will be necessary
to reduce emissions to acceptable levels.
Solid
Pellets Odor Slight
No information available Odor Threshold No information available
Values Remar ks •Met hod
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
Negligible
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
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No specific test data related to reactivity available for this product or its ingredients.

10.2. Chemical stability

Stable under recommended storage and handling conditions (see section 7).

Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.

10.3. Possibility of hazardous reactions

Possibility of Hazardous Reactions

None under normal processing.

10.4. Conditions to avoid

Decomposition temperature.

10.5. Incompatible materials

Oxidizing agent.

10.6. Hazardous decomposition products

No data.

Section 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Acute Toxicity

Product Information
Product does not present an acute toxicity hazard based on known or supplied information.

Inhalation No data available.

Eye contact No data available.

Skin Contact No data available.

Ingestion No data available.

Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
ZINC OXIDE > 5000 mg/kg ( Rat ) - -
CARBON BLACK > 15400 mg/kg ( Rat ) - -
Stannous Chloride = 2300 mg/kg ( Rat ) - -

Skin corrosion/irritation No information available.

Serious eye damage/eye irritation No information available.

Sensitization No information available.

Germ cell mutagenicity No information available.

Carcinogenicity No information available.

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Chemical Name European Union IARC NTP

CARBON BLACK - Group 2B -

Reproductive toxicity No information available.

STOT - single exposure No information available.

STOT - repeated exposure No information available.

Target Organ Effects No information available.

Aspiration hazard No information available.

Remarks The components of this product are embedded in an impervious matrix, therefore not
biologically available.

Section 12: ECOLOGICAL INFORMATION

12.1. Toxicity

Not available
Chemical Name Algae/aquatic plants Fish Crustacea
TALC - LC50: >100 g/L (Brachydanio rerio, -
96 h, semi-static)

Stannous Chloride - - EC50: =55 mg/L (48h)

12.2. Persistence and degradability

Not available.

12.3. Bioaccumulative potential

Bioaccumulation Not available

Partition coefficient Not available

12.4. Mobility in soil

Mobility in soil
Not available.

Mobility
Not available.

12.5. Results of PBT and vPvB assessment

Not available.

12.6. Other adverse effects

Not available

Section 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods
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Waste from residues/unused Disposal should be in accordance with applicable regional, national and local laws and
products regulations.

Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal.

Section 14: TRANSPORT INFORMATION

IMDG
14.1 UN/ID no Not regulated
14.2 Proper shipping name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing Group Not regulated
14.5 Marine pollutant Not Applicable
14.6 Special Provisions None
14.7 Transport in bulk according to No information available
Annex II of MARPOL 73/78 and the
IBC Code

RID
14.1 UN/ID no Not regulated
14.2 Proper shipping name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing Group Not regulated
14.5 Environmental Hazard Not Applicable
14.6 Special Provisions None

ADR
14.1 UN/ID no Not regulated
14.2 Proper shipping name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing Group Not regulated
14.5 Environmental Hazard Not Applicable
14.6 Special Provisions None

ICAO (air)
14.1 UN/ID no Not regulated
14.2 Proper shipping name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing Group Not regulated
14.5 Environmental Hazard Not Applicable
14.6 Special Provisions None

IATA
14.1 UN/ID no Not regulated
14.2 Proper shipping name Not regulated
14.3 Hazard Class Not regulated
14.4 Packing Group Not regulated
14.5 Environmental Hazard Not Applicable
14.6 Special Provisions None

Section 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

European Union

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EU Regulation (EC) No. 1907/2006 (REACH)

As formulated, this product does not contain any SVHC

EU - REACH (1907/2006) - Annex XVII - Restrictions on Certain Dangerous Substances

Not Applicable

EU - Hazardous Substances Restricted or Prohibited in Electrical Equipment (2011/65/EU) (RoHS)

As formulated, this compound complies with the EU RoHS Directive (2011/65/EU) (RoHS 2) and does not contain any restricted
materials above threshold levels. The RoHS directive restricts the use of Lead, Cadmium, Chrome VI, Mercury, PBBs and all
PBDE materials.

15.2. Chemical safety assessment

No information available

Section 16: OTHER INFORMATION

Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of R-phrases referred to under sections 2 and 3

R23 - Toxic by inhalation
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment

Full text of H-Statements referred to under sections 2 and 3

H400 - Very toxic to aquatic life
H410 - Very toxic to aquatic life with long lasting effects
H301 - Toxic if swallowed
H311 - Toxic in contact with skin
H331 - Toxic if inhaled
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H341 - Suspected of causing genetic defects if inhaled
H350 - May cause cancer if swallowed

Legend
NTP (National Toxicology Program)
IARC (International Agency for Research on Cancer)
TWA TWA (time-weighted average)
STEL STEL (Short Term Exposure Limit)
Ceiling Maximum limit value
* Skin designation

Key literature references and Literature data and/or investigation reports are available through the manufacturer
sources for data

Training Advice Before handling this substance/preparation, the personnel involved should be instructed by
means of this safety data sheet

Revision Date 25-Jan-2016

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

Disclaimer
To the best of our knowledge, the information contained herein is correct and accurate but does not purport to be all
inclusive and shall be used only as a guide. The information relates only to the specific material designated. Teknor
Apex, nor any of it subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information
contained herein. Teknor Apex Company warrants only that the goods sold shall conform to Teknor Apex Company's
standard specifications or such other mutually agreed-to and documented specification. This express warranty is in lieu
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of and excludes all other express warranties and is extended only to Buyer. TEKNOR APEX COMPANY EXPRESSLY
DISCLAIMS ALL OTHER WARRANTIES INCLUDING THE WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE AND
MAKES NO WARRANTY AS TO THE RESULTS BUYER CAN EXPECT FROM BUYER'S USE OF THE GOODS. No employee
or agent of Teknor Apex Company is authorized to make warranties about goods sold by Teknor Apex Company, and
Buyer should not rely on any oral or written communications from employees or agents of Teknor Apex Company that
purport to constitute a warranty. Any assistance furnished by Teknor Apex Company in the selection of goods or
suggestions as to their processing or use are accepted by Buyer at Buyer's own risk, and Teknor Apex Company shall
not be liable to Buyer for results obtained by Buyer from such assistance or suggestions. In no event and under no
circumstances will Teknor Apex Company be liable for consequential damages of any kind.

End of Safety Data Sheet

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