CONTENTS
2.1 The Role of Water as a Solvent
2.2 Writing Equations
for Aqueous Ionic Reactions
2.3 Precipitation Reactions
2.4 Acid
Acid--Base or Neutralization Reactions
The Major Classes of
Chemical Reactions 2.5 Oxidation
Oxidation--Reduction
(REDOX
REDOX)) Reactions
Chapter 2
2.6 Reversible Reactions
An electrolyte
A substance that, when dissolved in
water, results in a solution that can
conduct electricity.
electricity.
Non--
Non weak strong
A non
nonelectrolyte
electrolyte electrolyte electrolyte electrolyte
A substance that, when dissolved in
water, results in a solution that does
not conduct electricity.
electricity.
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pr e c i pi ta te
total ionic equation PbI2
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Feel slippery
slippery.. Many soaps contain bases. HNO3 → H+ + NO3– Strong electrolyte,
electrolyte,
strong acid
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Until222.
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Dilution = procedure for preparing a less How would you prepare 60.0 mL of 0.2 M
concentrated solution from a more HNO3 from a stock solution of 4.00 M HNO3?
concentrated solution.
MiVi = MfVf
Dilution
Mi = 4.00 M Vf = 0.06 L
Mf = 0.200 M Vi = ? L
Add Mf Vf 0.200 × 0.06
Solvent Vi = = = 0.003 L
Mi 4.00
Moles of solute Moles of solute = 3 mL
before dilution ((ii) = after dilution (f) 3 mL of acid + 57 mL of water
MiVi = MfVf = 60 mL of solution
O2 + 4e– 2O2–
half--reaction (gain e–)
Reduction half
When a piece
2Mg + O2 + 4e− 2Mg2+ + 2O2− + 4e− Cu2+ ions are of copper wire is placed in
converted to Cu atoms. an aqueous AgNO3 solution, Cu
2Mg + O2 2MgO Zn atoms enter the atoms enter solution as Cu2+ ions.
solution as Zn2+ ions. Ag+ ions are converted to solid Ag.
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Iodine heptafluoride
Oxidation
numbers IF7 4 Types of Redox Reactions
F = −1
of all elements in 7×(−1) + ? = 0
the following? Combination reactions
I = +7
Sodium Iodate Potassium dichromate Decomposition reactions
NaIO3 K2Cr2O7
Na = +1 O = −2 O = −2 K = +1 Displacement reactions*
3×(−2) + 1 + ? = 0 7×(−2) + 2
2××(+1)
+1) Disproportion reactions
I = +5 +22×
×(?) = 0
Cr = +6
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E.g. O x i d a t i o n n u m b e r
Electrochemical series
Metal Displacement
for M e tal D i s pl a c e me n t
0 +2
Zn((s) → Zn2+(aq)
Zn aq) + 2e−
A metal in a compound can Electrochemical series
be displaced by another
metal in elemental state.
Electrochemical series
Convenient summary of
results of many possible
displacement reactions.
Any metal above H2 will
displace it ((H
H2) from water**
For example:
or from an acid
acid..
Any metal listed in the series will react (displace
(displace))
Zn(s) + CaSO
CaSO4(aq)
aq) Zn
ZnSO
SO4(aq)
aq) + Ca(s)
with any metal (in a compound) below it in the series. Zn(s) + CuSO
CuSO4(aq)
aq) Zn
ZnSO
SO4(aq)
aq) + Cu(s)
7A
Halogen Displacement F
Cl
A B
Power of halogens as oxidizing agents Br A reversible reaction.
decreases as we go down Group 7A from F2 to I2. I Reaction can occur in both directions.
Halogens’ behavior in halogen displacement reactions:
Strongest CaCO3(s) CaO(s) + CO2(g)
oxidizing agent F2 > Cl2 > Br2 > I2 Forward reaction
Predict what will happen if molecular bromine (Br2) CaO(s) + CO2(g) CaCO3(s)
is added to a solution containing NaCl & NaI at 25°
25°C. Reverse reaction
Answer Br2 will oxidize I− but not Cl −
−1 0 0 –1
CaCO3(s) CaO(s) + CO2(g)
2I − + Br2 I2 + 2Br − END of
Chapter 2