Think Exergy,
not Energy
Acknowledgment
The authors would like to express their special appreciation
and thanks to Dr Bonnie Wolff-Boenisch, Head of Research
Affairs at Science Europe, for her support and encouragement.
3
Educators, researchers, policy
makers,
stakeholders and citizens are urged to
consider energy and natural resources
on the basis of exergy, and in doing so
understand that:
Exergy-based Energy
and Resource Efficiency:
the Basics
The Need to Measure Energy and Secure, clean and efficient energy
Resource Efficiency Smart, green and integrated transport
Climate action, environment,
The European Commission highlighted resource efficiency and raw materials
seven societal challenges to reflect the
policy priorities of its ‘Europe 2020’ If the aim is to improve energy and
strategy. Out of these seven challenges, resource efficiency, the question arises
at least four are directly related to the of how to measure this. Of course, the
availability of energy and resources: amount of energy and raw materials
that go into making something, or
Food security, sustainable agriculture that go into services such as heating,
and forestry, marine and maritime communication, or transport, can be
and inland water research, and the easily measured. However, that does not
Bioeconomy consider the quality of the energy nor the
4
rarity of the materials used. In order to The energy contained in the movement
account for the quality and not just the of air molecules in a 20m3 office at
quantity of energy, as well as factoring 20°C is more than the energy stored in
in the raw materials used, we need to three standard 12V car batteries. While
measure exergy. you can only use the energy in the air
to keep yourself warm, you could use
Exergy can be considered to be useful the energy in the batteries to start your
energy, or the ability of energy to do car, cook your lunch, and run your
work. Exergy can be measured not computer. The reason is that even if their
only for individual processes, but also quantities were the same, the quality –
for entire industries, and even for whole or usefulness – of the energy in the air
national economies. It provides a firm and in the battery is different. In the air,
basis from which to judge the effect the energy is randomly distributed, not
of policy measures taken to improve readily accessible, and not easily used
energy and resource efficiency, and to for anything other than keeping you
mitigate the effects of climate change. warm. In contrast, the electric energy in
the battery is concentrated, controllable,
Exergy as a Measure and available for all sorts of uses. This
of Energy Quality difference is taken into account by
exergy.
The need to take the quality of energy
into account can be shown with a
simple everyday example (see Figure 1).
Figure 1 Everyday example of exergy showing (A) battery used to start a car versus (B) air molecules
in an office used to heat the occupant.
5
Thermodynamics is the Science chemical energy stored in coal to produce
of Energy steam in a boiler, which is then converted
by a turbine into mechanical energy and
The concept of exergy is inextricably finally by a generator into electricity. In this
contained within the basic physical laws process, only 30–35% of the chemical
governing energy and resources, called energy contained in the coal is converted
thermodynamics. These laws cannot be into electrical energy; the remaining
ignored: they are fundamental. Two of 65–70% is lost in the form of heat.
the basic laws in thermodynamics need
to be considered: Exergy analysis of this power generation
plant identifies the boiler and turbine
First – Energy is conserved. as the major sources of exergy loss. In
order to improve the exergy efficiency,
Second – Heat cannot be fully converted the boiler and turbine systems need to
into useful energy. be altered through technical design and
operational changes.
The second law concerns the concept of
exergy. Every energy-conversion process It is of utmost importance to look at the
destroys exergy. exergy balance of processes. In fact,
we need to go much further: the exergy
Take for example a conventional fossil- balance of whole economies can and
fuel power station, shown schematically should be routinely considered, as will be
in Figure 2. Such a station transforms the shown later.
Pollution
Exhaust Control Cooling
Gases Water Steam Water
Condenser
Pump
Steam Synchronous
Valve Generator
6
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iStock.
7
Exergy Destruction in the Process Methanol, for example, is a primary
Industry liquid petrochemical manufactured
from natural gas. It is a key component
Industry is a large user of both material of hundreds of chemicals that are
and energy resources. Typically, an integral parts of our daily lives such as
industrial production process needs plastics, synthetic fibres, adhesives,
the input of materials and of energy to insulation, paints, pigments, and
transform those materials into products. dyes. Before methanol production
Much of these inputs end up being even begins, 10% of the natural gas
discarded: in the case of materials is used to warm the chemical reactor.
as waste, and in the case of energy Subsequently, during production
as heat. This is exergy destruction, further reactor losses amount to
since – recalling the Second Law of 50%. This contributes to the exergy-
Thermodynamics – not all inputs can be destruction footprint of methanol
fully recovered as useful energy. production and of all its products.
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iStock.
8
How can we Increase the Energy The obvious question is whether the
Efficiency of Production? same distillation results can be achieved
with a higher exergy efficiency by
While exergy destruction for any process operating the column differently. The
is never zero, it can be minimised. Every answer to that question is yes, as there
process has a characteristic exergy- are better ways to add heat to the
destruction footprint. Knowledge of column than by a boiler. The boiler and
this footprint can be used to rationalise condenser can be replaced by a series
resource choices before production of heat exchangers along the column,
begins and to monitor the use of energy such as on the right-hand side of Figure 3,
and resources during production. In a producing a more exergy-efficient
full life-cycle approach, it can be used to heating pattern. This arrangement
consider the total energy and resource minimises the exergy destruction in the
‘cost’ of a product: essentially its exergy- system, reducing the exergy footprint
destruction footprint. of the process. In this way, the same
product can be obtained with only 60%
An example of a process where reducing of the original exergy loss. This of course
exergy destruction can increase energy requires investment in replacing or
efficiency is distillation. Distillation is retrofitting the technology, but in the
the most commonly applied separation long run such costs are compensated
technology in the world, responsible for by lower operating costs. Financial
up to 50% of both capital and operating benefits aside, the potential impact
costs in industrial processes. It is a of technological development driven
process used to separate the different by exergy analysis on the energy
substances from a liquid mixture by and material efficiency of industry,
selective evaporation and condensation. is enormous.
Commercially, distillation has many
applications; in the previous example of
methanol production, it is used to purify
the methanol by removing reaction by-
products from it, such as water.
9
It is important to keep
in mind that there
is no production without
an exergy destruction
footprint.
Tabel 1 Exergy streams in single- or two-stage crude oil distillation systems.4 The feed and product streams are the same.
10
A Large-scale Problem Needs only to quantify the historical resource
a Common-scale Solution use, efficiency and environmental
performance, but also to explore future
In 2013, industry accounted for 25% of transport pathways, building structures
the EU’s total final energy consumption,5 and industrial processes.
making it the third-largest end-user after
buildings and transport. Over 50% of As explained in the Opinion Paper
industry’s total final energy consumption ‘A Common Scale for Our Common
is attributed to just three sectors: iron and Future: Exergy, a Thermodynamic
steel, chemical and pharmaceutical, and Metric for Energy’,1 a major roadblock
petroleum and refineries. for implementing – or even finding –
solutions to our societal challenges
Between 2001 and 2011, EU industry is the fact that energy and resource
reduced its energy intensity by 19%.5 efficiency are commonly defined in
However, significant efficiency potential economic, environmental, physical,
remains. As previous examples of and even political terms. Exergy is the
several industrial processes have shown, resource of value, and considering it
exergy analysis offers a guide to the as such requires a cultural shift to the
development of more energy-efficient thermodynamic-metric approach of
technologies and provides an objective energy analysis. Exergy provides an
basis for the comparison of sustainable apolitical scale to guide our judgement
alternatives. on the road to sustainability. Exergy is
first step to a common-scale solution
Energy analysis explains that electric and to our large-scale problems.
thermal energy are equivalent according
to the First Law of Thermodynamics,
and that heating by an electric resistance
heater can be 100% efficient. Exergy
analysis, however, explains that heating
by an electric heater wastes useful
energy. When we know about this kind
of waste, we can start to reduce it by
minimising exergy destruction.
11
Adopting Exergy Efficiency
as the Common National
Energy-efficiency Metric
Energy Efficiency as a Key Climate sources is lacking. A central problem is
Policy: the Need to Measure that there is no single, universal definition
Progress with Exergy of national energy efficiency. In this void,
a wide range of metrics is inconsistently
Improving the efficiency of energy use adopted, based on economic activity,
and transitioning to renewable energy are physical intensity or hybrid economic–
the two main climate policies aimed at physical indicators.
meeting global carbon-reduction targets.
The 2009 Renewable Energy Directive6 None of these methods are based on
mandates that 20% of energy consumed thermodynamics, however, making
in the EU should be renewable by 2020. them inherently incapable of measuring
At the same time, the EU’s 2012 Energy energy efficiency in a meaningful way.
Efficiency Directive7 sets a 20% reduction As such, they are unable to contribute
target for energy use. to evidence-based policy making or
to measure progress towards energy-
Progress towards the renewable-energy efficiency targets. The EU is not alone,
target is straightforward to measure, there is currently no national-scale
since national energy use by renewable thermodynamic based reporting of energy
sources is collected and readily available. efficiency by any country in the world.
Indeed, for many citizens, the proportion
of domestic electrical energy generated Second-law thermodynamic efficiency
from renewable sources appears clearly – in other words, exergy efficiency –
defined on their electricity bills. stands alone in offering a common scale
In contrast, national-scale energy for national, economy-wide energy-
efficiency remains unclear and a efficiency measurement, applicable
qualitative comparison of renewable at all scales and across all sectors.
12
Figure 4 shows a flow diagram from The useful energy is the last point of
primary exergy to useful work for the common thermodynamic measurement
United Kingdom for the year 2010.8 before it is exchanged for energy
Energy supplied from coal, oil, gas, services, such as thermal comfort,
renewables, and food and feed provides motion, or light.
the primary exergy. It is transformed into
ready-to-use energy, such as diesel or The national exergy efficiency εNational
electricity, which then provides ‘useful therefore represents the second-law
energy’ through high-temperature heat, thermodynamic efficiency of the energy
mechanical drive, or electrical devices. conversion, defined in exergy terms as:
Primary exergy (223.9Mtoe) Energy sector own use + TFC Useful work by end use Useful work by end sector
TPES (199.4Mtoe) (146.0Mtoe) (30.9Mtoe) (30.9Mtoe)
Coal products 3.3 1.0
3.3
Direct Heat 9.2 Energy sector 4.3
2.3
Coal
9.4 1.8 Industry 9.2
32.9 20.2 Direct Mechanical
10.1 work 10.0
Oil & oil products Transport 9.0
53.6 Electricity 11.7
41.5
Residential/other 8.4
Mech work
(Man labour) 0.01
Oil 53.6
66.9 5.4
0.4
11.7
1.2 Gas & gas products 46.4
51.8
11.8
Electricity
51.8
Generation
Gas 32.6 20.0
88.1
1.2
5.3
Nuclear
16.2 10.9
1.8 0.6
Renewables 8.2
Food & Feed 0.9 4.9
Legend
Gas [Mtoe] Coal [Mtoe] Renewables [Mtoe] Heat [Mtoe] Electricity [Mtoe]
Oil [Mtoe] Exergy losses [Mtoe] Food & feed [Mtoe] Mech Drive [Mtoe] Nuclear [Mtoe]
Figure 4 2010 United Kingdom Exergy flow chart: primary to final energy.8
13
The Benefits of Exergy-efficiency energy. This accounting practice needs
Reporting to be reinstated. One of the downstream
benefits of formalising the national-
Once this formal definition is in place, scale exergy-efficiency definition and
reporting exergy-efficiency at a national development of a consistent reporting
scale is not only desirable, but also framework, is that it enables exergy
possible. Widespread use would enable -efficiency to be included as part of the
comparison between technologies, overall policy-design process. Energy
sectors, and countries, enabling best use and efficiency can then be tracked
practice and energy-efficiency to view progress towards targets and
opportunities to be identified. Figure 5 policies can be amended if the desired
shows the aggregate exergy-efficiency energy reduction is not occurring.
percentage of China, the United States It should not be misunderstood, however,
and the United Kingdom for the period that the benefits of adopting exergy-
1971 to 2010.9 The figure shows an efficiency as the common national
increase in exergy efficiency in the United energy-efficiency metric is to merely
Kingdom and China, while it remains satisfy a reporting exercise. In the words
stagnant in the United States. Such of Fatih Birol, the International Energy
comparisons provide detailed insight into Agency’s Executive Director: “any
the reality of current energy-efficiency progress with climate change must have
policies and their implementation in the energy sector at its core or risk being
everyday life. judged a failure”.10 The energy sector can
only be understood by applying second-
In the 1970s and 1980s, Eurostat law thermodynamics, or exergy.
collected national accounts of useful
20.0%
18.0%
Aggregate exergy efficiency %
16.0%
14.0%
12.0%
10.0%
8.0%
6.0%
4.0%
2.0%
0.0%
1971 1974 1977 1980 1983 1986 1989 1992 1995 1998 2001 2004 2007 2010
14
Natural Resource
Consumption
From Gaia to Thanatia: How to Assess
the Loss of Natural Resources
15
The Price the Planet Pays While this example gives invaluable
insight into the environmental impact of
To put the situation in context, consider materials that we typically consume, it is
the example of a hotel building in Greece, important to go further in appreciating
with an exergetic lifecycle of construction, the cost of our living to our planet.
use and withdrawal phases. Table 2
compares the exergy, embodied exergy An Essential Approach to Making
and composition of the total building for Better Use of our Mineral Resources:
selected materials. the Application of Mineral Exergy
Rarity
The comparison of the embodied exergy
reveals that the main material used in The exergy of a mineral resource as
large quantities is concrete, which has calculated with Thanatia as a reference
the lowest embodied exergy of the listed can be measured as the minimum
materials (1.7 MJ/Kg), while aluminium energy that could be used to extract
is the least used material but has the that resource from bare rocks, instead
highest embodied exergy (249 MJ/Kg), of from its current mineral deposit. This
due to the very high energy demand is an essential approach, since the
during its production. In general, exergy European Commission’s Communication
analysis finds that three quarters of the ‘Towards a Circular Economy: A Zero
building’s exergy consumption over Waste Programme for Europe’,12 states
an 80-year life cycle, stems from the that “valuable materials are leaking from
period it is in use (heating, cooling, our economies” and that “pressure
lighting), while the remaining relates to its on resources is causing greater
construction period (material extraction, environmental degradation and fragility,
process, transport). Europe can benefit economically and
environmentally from making better use
The exergy concept can be applied to of those resources.”
the whole process involving a building, Applied to minerals we can define a
not just the use of materials in its ‘Mineral Exergy Rarity’ (in kWh) as “the
construction, but also the energy use, amount of exergy resources needed to
eventual demolition, and recycling. obtain a mineral commodity from bare
Table 2 Exergy (GJ), embodied exergy (MJ/kg) and composition of the total building material (%) for selected materials
used in the lifecycle of a hotel [data extracted from reference 11].
16
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17
Integrating Exergy Analysis
into Our Daily Lives
Exergy-based Law-making As a result of this legislation, the net
energy yields of renewable and non-
As far back as 1974, the Congress renewable energy supply technologies
of the United States passed Public are now publically available.
Law 93.577, the Federal Non-Nuclear
Energy Research and Development Unfortunately, despite the fact that
Act, to establish a national programme exergy analysis has matured in the
for research and development in intervening years, it has remained
non-nuclear energy sources, with the largely confined to the academic world.
governing principle that the potential for An exception is the canton of Geneva,
production of net energy be analysed which in 2001 introduced a new article
and considered in evaluating the featuring the exergy concept in their
potential of any proposed technology.14 energy law.15 Geneva authorities require
In effect, this legislation states that city developers to include an exergy
net energy, rather than conventional approach in their project proposal.
economic analysis, should provide the The law applies to about 20% of total
basis for prospective energy technologies. developments in particular buildings
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iStock.
18
or building areas used for apartments, fundamental thermodynamics and
offices, and commercial premises, contrary to its intention, is potentially
representing close to 80% of damaging the environment.
the energy consumption of new building
developments. In practice, an internet Charging Exergy Loss, not Energy
framework allowing users to calculate Use – Radical Thinking or Just
their efficiency indicators was set- Common Sense?
up. Today, the law seems to be fully
implemented with energy efficiency One of the leading proponents of the
featuring heavily within the building 1974 US Federal Non-Nuclear Energy
application process.16 Research and Development Act, Senator
Mark Hatfield, interpreted the Act as
The Cost of a Recycling Policy – a step towards replacing money with
a Cautionary Tale energy as the standard of value. While
still some way off from an ‘energy
Recycling contributes significantly currency’, there have been repeated calls
to the preservation of natural resources. for an energy-based tax as an incentive
At least, that is what policy and for exergy and resource conservation.
legislation leads us to believe. However, Current EU rules for taxing energy
exergy analysis shows that well-intended products and electricity are laid down in
legislation may actually not have the the Energy Tax Directive 2003/96/EC,18
desired effects. which entered into force in 2004 with
the aim of reducing distortions caused
Since recycling technology itself requires by divergent national tax rates, removing
materials and energy input, both of which competitive distortions between mineral
contribute to the depletion of natural oils and other energy products, and
resources, it is important to evaluate creating incentives for energy efficiency
the efficiency of the whole recycling and emission reductions. However, as
chain to determine its actual benefit. the taxation rates are based on volume,
Exergy analysis allows evaluation and rather than energy content, products
optimisation of any recycling system’s with lower energy content, such as
environmental performance on a renewables, carry a heavier tax burden
fundamental basis, capturing efficiency than the fuels they are competing with.
in the system as a function of physical,
metallurgical, and thermal processing, Encouragingly, in 2011, the European
and of the quality of reclaimed materials. Commission presented a proposal to
Such studies have shown that the high revise the rules on taxation of energy
recycling quotas for end-of-life vehicles products in the EU, in order to reflect
as required by EU legislation appear CO2 emissions and energy content
to be totally erroneous, since they are (€/GJ), rather than on volume.
based on first-law arguments.17 The The following year, however, the
present stringent legislation is violating European Parliament voted against
19
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Concluding Remarks
and Recommendations
Thermodynamics is the science of basis for work on energy efficiency
energy. Exergy measures useful energy. improvements
Exergy efficiency is the real efficiency The reintroduction of national useful
of an energy system or process. To this energy accounting
end, and compared with conventional Taxation of excess exergy destruction
first-law thermodynamics energy footprints to drive the development of
approaches, the second-law exergy more energy efficient technology
approach can identify and quantify Use of exergy rarity to monitor the
the causes of inefficiencies. Exergy is earth’s mineral resources
therefore the right metric to value energy The creation of accounts of exergy
use and resource scarcity. destruction footprints and exergy
rarity to support the IPCC in finding
In December 2015, world leaders signed measures to mitigate climate changes
a historic climate agreement in Paris.
For the first time, all countries agreed The EU has a moral responsibility
to play their part in keeping the global to show the same leadership in
temperature increase below 1.5°C. But implementing the Paris agreement as it
the Paris negotiations may turn out to did in making the agreement possible.
have been the easy part. Any progress The climate crisis was not solved in
with climate change must tackle energy Paris: the COP21 was just one step in
use. Decision-makers must see beyond the right direction. The second step
economic and national interests to chart requires the common sense and courage
a new course of radical climate policies to implement exergy as the rightful metric
based on the science of energy. for energy and natural resource use.
With this in mind, the authors make the As wisely said by Howard Scott in 1933:
following recommendations:
“It is the fact that all forms of energy, of
The teaching of concepts related whatever sort, may be measured in units
to exergy in schools and of ergs, joules or calories that is of the
universities utmost importance. The solution of the
The promotion of the exergy social problems of our time depends
concept, with policy makers and upon the recognition of this fact. A dollar
energy stakeholders taking a lead may be worth - in buying power - so
in informing the public much today and more or less tomorrow,
The introduction of exergy but a unit of work or heat is the same in
destruction footprints to give a useful 1900, 1929, 1933 or the year 2000.”20
21
References
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Singapore, 2014.
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crisis”, Harpers Magazine, Jan. 1933.
Colophon
June 2016
‘In a Resource-constrained World: Think Exergy, not Energy’: D/2016/13.324/5
Author: Science Europe
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