Volume 3 Issue 3
The article describes a vapor-injected vacuum-creating system (VCS) based on the steam
ejector pump (SEP) of the vacuum column in a primary oil refining unit. To develop a
computer model of the ejector, mathematical models of the ejector were presented on the
basis of thermodynamic relationships related to it. With the help of special mathematical
methods, a model based on the integration of the momentum and energy equations for
various parts of the ejector was developed and, finally, the results with real data for the
ejector system were evaluated in the vacuum unit.
technological system. Therefore, to date, the evacuated gas and viscous friction
the development of such models is best between the boundary layers of the viscous
done using mathematical modeling jet and the adjacent layers of pumped
techniques in the environment of universal mixture, the latter is entrained in the input
modeling programs (UMP). In this study, confusor, for the facilitation of a more
the main elements of the vacuum unit for complete mixing of steam with the gas.
separating fuel oil from the ELOU-AVT-6 This process is characterized by equalizing
unit: vacuum column, furnace, ejectors, all the parameters of the mixture (pressure,
intermediate capacitors, separators, etc., density, velocity, and temperature) along
were simulated using the ChemCad the flow section. Due to the exchange of
software. The use of the ChemCad in energies and the appearance of a shock
solving problems of this kind is considered wave, the pressure of the evacuated gas
in detail in [1-5]. increases, reaches the static pressure of the
mixture, and the flow rate decreases to
Theoretical part sound pressure. In the throat of the mixing
The ejector device is shown in Fig. 1 chamber, the alignment of the mixture
The pumped mixture enters the inlet fitting parameters is completed, and in the
and is compressed to an intermediate expanding output diffuser the kinetic
pressure by steam from the nozzle. The energy of the jet is further transferred to
vapor under pressure expires through the the potential one, which is accompanied
expanding nozzle 1 with supersonic speed by a decrease in the velocity and an
in the form of a turbulent jet and due to increase in the pressure of the mixture to
turbulent mixing of the vortex masses of the outlet pressure [6-9].
the steam turbulent jet with molecules of
technological process. Thus, the vacuum elements were introduced into the design
distillation unit can be considered as a scheme: the divider 3, the mixer 13, and
complex chemical-technological system the controller 17.
(SCS). In accordance with the
technological scheme (Fig. 2), the The mixer 13 simulates the thermal
calculation scheme of the vacuum destruction process by mixing the initial
rectification unit of fuel oil was stream (stream 1) with decomposition
synthesized in the CHEMCAD software gases (stream 8). In order to maintain the
package (Fig. 3) [10]. material balance, the initial flow 1 must be
reduced by the amount of the
The tube furnace (apparatus 2) was decomposition gas flow, so a divider 3 and
simulated using the Fired Heater (FIRE) controller 17 were introduced into the
module, which calculates the fuel circuit. The divider 3 withdraws from the
consumption required to heat the target stream 2 (flow after the furnace) the
stream to a predetermined temperature. amount of fuel oil that is equal to the flow
rate of the decomposition gases, and its
Modeling VC (device 1) in this work was specification is determined by the
carried out using the accurate calculation controller 17.
module Tower Plus column (TPLS), which
allows the calculation of mass exchange The rate of decomposition gases is
columns of any type. In this case, side determined by the operating mode of the
strippers, circulation irrigation, steam vacuum column and primarily by the
supply to the column cube and heat heating temperature of the feed stream,
exchangers on the side products which in turn depends on the pressure in
withdrawal line are considered as part of the bottom section of the VC. In the Pro-II
the TPLS module, and are calculated modeling system instruction manual
simultaneously with the main column (Simulation Sciences Inc. USA), the
without recycling calculations. following dependencies are given for
determining the decomposition gas rates
Calculation of vacuum capacitors for AVT vacuum columns [11]:
(apparatuses 10, 11, 12) was carried out G 2,86 0,15 exp[0,0495 (Tc 385)] Fm
using the Heat Exchanger module
(HTXR). In the apparatuses 10, 11 and 12,
the CGS is divided into three phases: Where G- is the flow rate of the
decomposition gases, diesel fraction, decomposition gases (kg / h), Fm- is the
water. vacuum column supply rate (Nm3/ hr), Tc
is the temperature of the raw material
In addition, the heating process is heating in the tube furnace (0C)
accompanied by thermal destruction of the
feedstock (fuel oil), so the following
Fig. 3 - Model of a vacuum processing unit for fuel oil Designations of apparatus (Arabic
numerals): 1 - vacuum column; 2-tube furnace; 3, 4, 5, 6 - dividers; 7, 8, 9 - steam ejectors;
10, 11, 12 - vacuum condensers; 13, 14, 15 - mixers; 16 - separator; 17 - controller; 18, 19,
20 – valves
However, in this methodology, there are appropriate changes. But in works [8-9],
no recommendations for submitting this composition of the decomposition
gases depends on the type of oil and the solve a similar problem. This model uses
heating temperature of the raw material. the following assumptions:
Therefore, the most suitable flow of these 1) The working vapor is isentropic in the
gases is calculated by formula (1), and nozzle. The working pair and the
their composition is taken from injected vapor are also isentropic.
experimental data [12-13]. 2) The working steam and the pumped
mixture in the ejector are saturated
Simulation of the ejector and have a low speed.
There is no module in the ChemCad 3) The velocity of the mixed stream
software that simulates the processes leaving the ejector is very low.
taking place in the steam ejectors. 4) The working steam and the pumped
However, with the help of a set of modules mixture are regarded as an ideal gas
included in the program database and their with a constant specific heat (Cp) and
specification by certain algorithms, it is a constant adiabatic exponent (γ).
possible to synthesize a design model that 5) Mixing of the working steam and the
will most fully describe a steam ejector. pumped mixture in the mixing
For this purpose, the ejector was divided chamber is carried out at a constant
into three parts (nozzle, mixing chamber pressure in section 4.
and diffuser), and the processes in them 6) The adiabatic index varies
were calculated using MIXE modules insignificantly.
(Apparatus 7, 8, 9) and Valve (VALV) 7) The equations completely describe the
(Apparatus 18, 19, 20). In this case, the behavior of vapor and gas.
MIXE modules modeled the nozzle and 8) In modeling, the ejector is divided
the mixing chamber, and the VALV into three parts: a nozzle, a mixing
modules simulated the output diffuser [9]. chamber and a diffuser (see Fig. 1).
In [14], a model was presented that 9) The pressure and temperature at the
describes a steam ejector and is used to nozzle section are determined by the
ratios (2) and (3):
γ
P1 γ 1 γ 1
1 M 2 (2)
P2 2
T1 γ 1
1 M2 (3)
T2 2
The main ratio used in simulating the ejector is:
γ1 1
2 γ 1 2 γ1 1
1 1 M 2 (4)
1 γ 2
A2 1
2
Aс M2
The pressure at the nozzle outlet is calculated from the ratio (5):
P1
P2 γ1
γ1 1 γ1 1 (5)
M 22 1
2ηc
The temperature at the outlet from the nozzle is calculated from the ratio (6):
T1
T2
γ 1 (6)
1 1 M 22
2ηc
The speed of sound at the nozzle exit:
C2 γ1 R1T2 (7)
Actual flow velocity (cross-section 2):
V2 C2 M 2 (8)
The Mach number before mixing the active and ejected streams in the nozzle is expressed by
the formula:
2 1
2 P 2
M 2 1 (9)
2 1 P2
In the general case, to obtain the critical Mach number in any section, we can use the
following relation:
M i2 ( 1)
M i* (10)
M i2 ( 1) 2
If we take into account equation (9), then the critical Mach number at the nozzle outlet is
calculated by the formula:
M 22 ( 2 1)
M 2* (11)
M 22 ( 2 1) 2
By definition, the ratio for the ejection coefficient is obtained as follows:
m
w ν (12)
m1
The critical Mach number of the moving vapor at the outlet of the nozzle before mixing with
the injected vapor is obtained as follows:
M 22 ( 1 1)
M *2 (13)
M 22 ( 1 1) 2
In modeling the mixing process, the one-dimensional continuity equations in combination
with the equations of motion and the energy equations can be combined into the following
relationships to calculate the critical Mach number and the Mach number in the diffuser:
T
M 2* wM ν*2 ν
T1
M 4* (14)
Tν
( 1 w ) 1 w
T1
2 M 4*
M4 (15)
( 3 1) M 4* ( 3 1)
2
To calculate the mixed active and ejected flow before the exhaust, the following relationship
is used:
T2
T4
1 2 (16)
1 3 M4
2
The Mach number at the entrance and exit from the diffuser:
2
M 42
3 1
M5 (17)
2 3
M 42 1
3 1
2
M 52
3 1
M3 (18)
2 3
M 5 1
2
3 1
It should be noted that the following relationships are used to calculate the temperature and
pressure at the entrance to the diffuser:
T2
T3
1 2 (19)
1 1 M3
2
P2
P3 3
1 2 3 1 (20)
1 3 M3
2
The speed of sound and the actual flow are determined by the following dependencies:
C3 3 R3T3 (21)
C4 3 R3T4 (22)
V3 C3 M 3 (23)
V4 C4 M 4 (24)
The temperature and pressure at the exit from the diffuser are calculated as follows:
1 2
1 3 M4
T5 2 (25)
1 2
1 3 M5
2
1 3 M 42
P5 P4 (26)
1 3 M 52
In order to calculate the outlet pressure from the ejector, we can use the following
relationships:
1
1 γ1 1 2
1
P2 γ1 P γ3
2 1 2
P6 P6
Ac P6 1 (27)
Ad P1 Tν 1 1
2 γ3 1 2
( 1 w ) 1 w T 1
2
γ1 1 3 1
1
γ
γ3
γ 1 γ3 1
P6 P5 ηd 3 M 52 1 (28)
2
Thus, the output stream from the ejector:
m6 m1 mν (29)
On the basis of the above equations, there operating modes of the ejectors. A block
is a complete set of ratios that participate diagram of the calculation of the ejector is
in the work of the ejector, which we can shown in Fig. 3.
write down in the algorithm for various
the module, a mixed flow of working the environment from the evacuated
steam and the pumped mixture is formed object. In this paper, it was assumed that
and the adiabatic coefficient γ3 is this pressure remains unchanged over the
determined in ChemCad, the value of investigated range of VCS. If during the
which is transferred to equation (20). calculation the pressure at the output of the
Then, by the equation (28), the pressure at SEP III stage condenser is higher or lower
the exit from the ejector is determined and than the fixed value, the pressure at the
the ejection coefficient is determined from inlet to the top of the vacuum column
Eq. (27), which is compared with the value changes, which leads to a change in the
determined in Chemcad (data on the flow rate of the medium that is pumped
streams of the working and pumped out out of the VCS. The pressure was changed
mixtures is transferred to the user program until the pressure at the outlet from the
in which the ejection coefficient is VCS became equal to the fixed back
calculated). pressure.
If these values do not match, then the The discussion of the results
pressure at the inlet to the ejector changes The verification of the adequacy of the
(since the pressure of the working vapor calculated data was carried out by
and throat diameter of the nozzle do not comparison with the data of the
change, the stream of the working vapor technological survey of the installation
remains unchanged). As a result, the (which were determined by averaging the
thermos-physical parameters and the flow readings of the instruments for a certain
rate of the pumpedout mixture change, and period of time). As shown in Table 1, the
the calculation is repeated. If the values relative error between production and
are the same, the calculation ends. design data is negligible, therefore, the
developed software, because of its
An important parameter that determines accuracy, can be used to evaluate the
the operability of VCS is the backpressure various parameters used in this block.
at the output of the system, as it "cuts off"
When the pressure of the vacuum column case, the heating temperature in the
increases, at a fixed temperature in the furnace was changed until the calculation
furnace, the amount of vapor phase in the of the column began to "converge". The
vacuum column decreases, which causes results, formed as a dependence of the
the column to "converge" at some heating temperature on the pressure at the
pressures, which corresponds to the top of the vacuum column, are shown in
"physical" nature of the process. In this Fig. 3.
Fig. 3.Dependence of the heating temperature on the pressure at the top of the vacuum
column.
When the pressure of the top of the combined effects of a large temperature
vacuum column changes, the flow of the difference and the presence of
medium entering the suction in the VCS uncondensed media. For the first few
changes, which leads to a change in the zones of the heat exchanger, the
distribution of the compression ratios condensation temperature is partly
along the pump stages. isothermal, and in the latter zone there can
be a significant temperature difference and
In addition, a considerable amount of the amount of non-condensable
gases (light hydrocarbons formed in the components can become more significant.
coils of the fuel oil heating furnace), which Thus, the resistance coefficient in this last
significantly impairs the conditions for the zone can be large, in which case half of the
condensation of water vapor, enter the required area is often necessary only for
inter-tube space of the intermediate the last zone.
capacitors. To take this phenomenon into
account, CHEMCAD uses a method In Fig. 4. The dependence of the amount
similar to that proposed [9,15]. For each of the medium entering the intake in the
step along the condensation curve, the VCS from the pressure at the entrance to
program calculates the resistance the system is shown.
coefficient, which takes into account the
According to the obtained RC This can be explained by the fact that the
characteristic, it can be concluded that the compression ratio in the steam ejectors of
residual pressure at the top of the column the second and third stages varies
has a significant effect on the flow rate of insignificantly, and the condensation
non-condensed gases. With increasing conditions of the mixture in the
pressure, both the flow rate and the intermediate condenser of the first stage
temperature of the vapor-gas mixture improve, as the condensing pressure
increase. increases. In this case, the second stage
ejector "pulls" the first, which leads to an possible when cold circulating water is
increase in the amount of the mixture at supplied at a temperature of no higher than
the inlet to the pump. 20 ° C. This condition seems to be quite
tough, especially for summer conditions,
Recommendations for optimizing the and thus ensuring a given vacuum when
VCS scheme using the existing condensation unit is
The efficiency of the vacuum-creating problematic and leads to increased flow
system is largely determined by the rate of water and working steam.
operation of the condensation unit. In the
investigated object, the pressure at the top To reduce the overall energy consumption,
of the VC is at the level of 22 mm Hg. the installation developed a new process
And the condensation temperature is flow scheme, the resulting process flow
approximately 27 ° C, which is only diagram is shown in Figure 5.
Since the evacuated mixture mainly tube space of the 1st stage condenser, and
consists of water vapor and distillate then sequentially into the capacitors of
components (88% by weight), it is most stages II and III.
advantageous in the 1st stage condenser to
condense the maximum amount of water Based on the developed scheme, a new
vapor to reduce the flow rate of the steam model of the vacuum unit was created in
by subsequent steps. To do this, the whole the CHEMCAD software package. The
volume of cooling water is fed into the resulting model is shown in Figure 51.
For maximum condensation of water vapor temperature, so for this stage a small
and condensed hydrocarbons, a special capacitor of 600 KCG-0.6-1.6-M1 / 25G-
vacuum condenser 2000 KVKG-1-M1 / 3-2 was chosen according to TU 3612-
25G-6-6 according to TU 3612-007- 024-00220302-02.
00220302-99 was chosen as the first stage
condenser. The capacitor of the second To reduce the flow rate of steam, the
stage was replaced by a capacitor with a geometry of the steam ejectors was also
lens compensator on the housing 800 adjusted.
KKG-0,6-1,6-M1 / 25G-3-2 according to The costs of energy resources according to
TU 3612-024-00220302-02. the existing and proposed schemes are
presented in Table. 2.
In the condenser of the last stage, there is
no need to provide a low condensation
Table 2:The results of the implementation of recommendations for the VCS optimization
Index Before reconstruction After reconstruction Increase in the efficiency of energy
consumption, %
Cooling water
1060 700 33,96%
flow rate, m3 / hr
Working steam
7450 6400 14,09%
flow rate, kg / hr
I stage, kg / hr 3750 3600 4,00%
II stage, kg / hr 2250 1500 33,33%
III stage, kg / hr 1450 1300 10,34%
As calculations show, the limiting step that the condensation temperature was
with the maximum energy consumption increased, the cooling water consumption
(working steam and circulating water) is was reduced by 34%. As a result of the
the first stage of VCS, but the SEP stage, correction of the geometry of the steam
which allows to reduce the overall power ejectors, the working steam consumption
consumption of the system, is the second was also reduced by 14%.
stage, namely, the ejector and the second The heat exchangers mentioned above
stage condenser. have large heat transfer surfaces and cross-
sectional areas in the inter-tubular space
As can be seen from the table, after the that exist, which allows increasing the
change in the return water supply scheme, condensation temperature, lowering the
as well as the replacement of the hydraulic resistance of the capacitors,
intermediate capacitors, despite the fact thereby reducing the consumption of
circulating water and working steam. In plant, the cost of water vapor is 650 rubles
addition, an increase in the condensation / Gcal, and of circulating water - 460
temperature in the shell space will increase rubles / Gcal. If you take the existing
the temperature of fresh recycled water, operating costs for water and steam as the
thereby reducing the required heat base value of the assessment, you can
dissipation from the circulating water estimate the reduction in operating costs
supply systems of the plant. and calculate the approximate payback
period of the project
Typically, as a criterion for the
effectiveness of a design solution, the A comparison of the operating costs of the
relative operating costs of a particular existing and proposed schemes is
energy source (working steam and presented in Table. 3.
recycled water) are used. According to the
Based on the results of the technical and enterprise to reduce the cost of production
economic comparison of VCS, it can be on the installation.
seen that the developed recommendations
for optimizing the work of the VCS V. Notations and symbols
allowed to reduce the total operating costs VCS - vacuum-creating system
by 13%. SEP - Steam Ejector Pump
P - Pressure (kPa)
The required amount of investment T - Temperature (K)
required to replace the existing VCS, A - Cross-sectional area (m2)
installation works, was adopted equal to γ - The adiabatic exponent
20 million rubles, and the estimated η - EFFICIENCY
payback period of the project will be about C - Sound speed (m / s)
3 years, which is an acceptable value in V - Actual speed (m / s)
the evaluation of projects of this kind. M- Mass flow rate (kg / s)
Consequently, the decision to implement M- Mach number
the developed recommendations is w- Ejection factor
appropriate, which in turn will allow the R - The universal gas constant