Bilangan Gelombang (cm-1) Serapan gugus Referensi

Hasil Sintesis Teoritis

3402 3434 O-H vibrasi ulur (Yang et al.,
2014)
1625 C-O amina
2924; 2839 2929; 2851 C-H vibrasi ulur
1427 1461 C-N
;1049 1400; 1085 Vibrasi tekuk C-O
Ikatan C-O-C

3402; 3201; 3086 3418; 3122 Vibrasi ulur O-H, gugus

fungsi asam
karboksilat, vibrasi
ulur N-H

 The functional groups of the precursor, and CDs@colistin-3 were characterized by FTIR
spectroscopy, as shown in Fig. 1(a). The
two broad peaks at around 3473 cm−1 and 3170 cm−1, indicating the O H stretching
vibration of carboxylic acid, hydroxyl functional group as well as N H stretching
vibration of the synthesized CDs@colistin-3 [37]. The coexistence of hydroxyl and
carboxylic
groups on the surface of the CDs@colistin-3 is also supported by zeta potential
experiments with a value of −21.8 mV at neutral
pH. In the FTIR spectrum of CDs@colistin-3, peak at 1680 cm−1 is attributed to the C O
stretching vibration mode of amide [38]. The shifting of C O starching frequency (at 1728
cm−1) of ammonium citrate to the C O stretching frequency (at 1680 cm−1) of
CDs@colistin-3 indicates the formation of amide types bond at the surface of the CDs.
Simultaneously, peak at 1410 cm−1 indicates the stretching vibration of C N bond [39].
Slightly shifting of the carbonyl stretching frequency at 1706 cm−1 in FTIR spectrum of
CDs
 from the carbonyl stretching vibration of CDs@colistin-3 indicates the attachment of
colistin to the surface of the CDs. Further, the
attachment of the colistin to the surface of the CDs was confirmed by 1HNMR and HR-
Mass spectroscopy of the CDs@colistin-3 as well
as the precursors.

The structure and composition of N-doped CDs were characterized by FT-IR spectroscopy. As shown in
Fig. 3A, the
synthesized N-doped CDs show a main absorption band of O–H
stretching vibration at 3434 cm1 and the amine bond from C]
O stretching at 1625 cm1 in the spectrum. The peaks at 2920
and 2851 cm1 are related to the C–H bond stretching vibrations. The characteristic stretch band of the
amine III C–N bond
is at 1461 cm1. The bending vibration of the C–O bond and the
stretching peak of the C–O–C bond appear at 1400 and
1085 cm1, respectively.22 The FT-IR spectrum of reactant
ammonium citrate is also shown in Fig. 3A. Two diferent
chemical environment carboxyl groups at 1592 and 1719 cm1
in ammonium citrate were changed into one C]O stretching
peak under hydrothermal conditions