Narayana IIT Academy 26-07-15_ Jr.

IIT-IZ-CO-SPARK _JEE-ADV(2013-P1)_WTA-11_Key & Sol’s

NARAYANA IIT ACADEMY

INDIA
Sec: Jr.IIT-IZ-CO-SPARK Date: 26-07-15
Time: 9:00 AM to 12:00 Noon WTA-11 Max.Marks:180
KEY SHEET
PHYSICS CHEMISTRY MATHS
Q.NO KEY Q.NO KEY Q.NO KEY
1 D 21 B 41 C
2 A 22 C 42 D
3 A 23 A 43 B
4 C 24 C 44 D
5 C 25 A 45 B
6 A 26 B 46 C
7 A 27 C 47 A
8 C 28 D 48 B
9 C 29 C 49 A
10 B 30 D 50 B
11 C 31 AD 51 BC
12 BCD 32 ABCD 52 AD
13 B 33 AC 53 ABCD
14 ACD 34 ABD 54 AB
15 ABD 35 ABC 55 ABCD
16 8 36 6 56 3
17 1 37 4 57 6
18 4 38 5 58 5
19 2 39 5 59 3
20 1 40 3 60 2

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PHYSICS-SOLUTIONS
1. Potential energy (Spring + Gravitational) with position is as shown
ne
U t li
ai gh
str

parabola

Speed  v0

X
initial max
position compression
Spring K .E
relaxed max
position position

The above graph is traversed twice (back and forth) so, vo is achieved four times.

2. Work done by F along path 1
1 2

  y 2 dx   x 2 dy
0 0
1 2 2
 y
  (2 x) 3 dx     dy
0 0
2
 2J  Wext  2 J

Work done by F along path 2
2 1
2 2
 0 x dy  0 y dx
 
along yaxis along x axis
2 1

  12 dy   odx
0 0

 2  0  2 J  Wext  2 J
Fx Fy
  non-conservative force.
y x
3. With time t, only dependent on m,l,g, we may write t  ma l b g c and use dimensional analysis to
1 1 l
obtain a  0, b  , c  . So t  .
2 2 g
4. Using W.E theorem
 3l  1
We get mg    mv 2  0
2 2
 v  3gl

ac

60 at

l
2
V

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Narayana IIT Academy 26-07-15_ Jr.IIT-IZ-CO-SPARK _JEE-ADV(2013-P1)_WTA-11_Key & Sol’s

v2
At t  T  , aC   3g
l
3g
at  g cos 30o 
2
 vertical acceleration
 3g 
  3 g  cos 60o    sin 60
o

 2 
3g 3g 3g
   upwards
2 4 4
But at t  T  , vertical acceleration = g downwards
3g 7 g
 change = g  
4 4
1 1 v
5. For maximum compression being xo , W.E. theorem gives mvo 2  kxo 2 and when v  o , we get
2 2 2
1  2 vo2  1 3
m  vo    k  x02  x 2   kx  kxo
2  4 2 2
2h
6. It is a horizontal projectile, time taken =
g
' dx '
7. For every ‘dx’ displacement of the block, point ‘B’ moves towards right. Force
2
l
dx 1
applied by left half on right half is kx towards left. So work done    k x    k l2
0
2 4
U F
8. Stable eq   0, x  0
x x
U F
Unstable eq   0, x  0
x x
Neutral eq  U = constant
E  E3 has only one turning point, x  x3
   
9.  F1 .ds  0,  2 .ds  0 for conservative forces.
F
10. When U is maximum (=E) then K.E is min = 0 but when K.E is maximum then U min need not be
zero.
U
also, a  0  F  0  0
x

11. F.B.D s after applying constraint

T  2T
 2m 3m  a
2a  
2mg 3mg
2mg  T  2m  2a  2T  3mg  3ma
g
a
11

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Narayana IIT Academy 26-07-15_ Jr.IIT-IZ-CO-SPARK _JEE-ADV(2013-P1)_WTA-11_Key & Sol’s

2g
2a 
11
1 g 2
Distance travelled by pulley B in ‘t’ sec  t work done by gravity on pulley
2 11
1 g 2
B  3mg  t 
 2 11 
1 g 2
3mg  t 
 2 11  3mg 2t
Average power delivered   
t 22
12. Forward force comes from the road = F
Power P0  Fv . Initially car needs very large force to start it from v = 0.
P dv
At any instant F  R  Ma  0  R  M
v dt
1 Vdv
  dt  
M P0  Rv
1 1  P  Rv  P0 
 dt   0  dv
M R  P0  Rv 
1 dv P0 dv
  dt  
M R R  P0 Rv 
t v P  P0 
   02 ln   -- (1)
M R R  P0  Rv 
P0
Also vmax  a  0  vmax 
R
Substituting v  vmax in (1) we get T  
vmax MP  1
Substituting v  in (1) we get t  20 ln 2  
2 R  2
13. Using work energy theorem between top and bottom points for bead,
1
Wg  Wsp  WN  mv 2  0
2
Here WN  0 , so
1 2 1 2 1
mg  4 R   k  4 R   k  6 R   mv 2
2 2 2
v  28 gR
v2
ac   7g
4R
F.B.D of the bead at bottom is
k(4R) = 4mg
ac
37

at O

mg

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 16  24mg
N  4mg cos 37  mg  mac  N   8   mg  N 
 5 5
12 g
Also 4mg sin 37  mat  at 
5
14. We can use work energy theorem on person W.R.T ground frame. At every instant
person will be moving up with an effective speed of u – V where as his point of
contact with travellator moves down the incline at V to avoid shipping. The F.B.D of
person W.R.T ground is
N

O
fs
mg sin 

mg cos 
Wmg sin   W f s  Wint   k .E  0
Here Wmg sin   mgh and f s  mg sin 
If t is time taken to climb then
h cos ec
t 
u v
Power delivered by friction   mg sin  v
mgh v
 W.D by friction  mg sin   t   
u v
Students are advised to try the same problem using travellator frame in which W.D
by friction = 0
  K .E   K .E
15. Pinst  , Pavg 
t t
Wall   K .E
4 mg
16. Min-extension required for ‘4m’ to lift  y  say  using W.E theorem on block of mass ‘m’
k
Wall   K .E
1
wg  wsp  0  m v02
2
1 2 1
mgy  ky  0  m v02
2 2
m
Substituting for ‘y’ we get v0  8 g
k
17. If it reaches A ' then it will reach A.
18. Speed at horizontal position  6 g l
   
Change in momentum  p f  pi  p 2f  pi2  as p f  pi   m 14 g l
Fx
19. Fmax   0  2x  l  0  x  l
x 2
2 2
U U U
Wmax   0, 2  0  Fx  0, 2  0  x  l .
x x x
1
20. Pmax happens when v = 1. Wall   k .E  m v 2  1J
2
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CHEMISTRY SOLUTIONS
21. Polarity  
For A  D,   416   434  341 / 2  28.5
For A  C ,   432   434  242  / 2  94
For A  B ,   570   434  154  / 2  276

22. E. A. of M   I .P. of M
Ionization energy of all elements in modern periodic table is higher than the electron gain enthalpy of
any element (in magnitude) in modern periodic table.

23. NCERT,Class XI,Part-I,P.no:87

Except for IA group, in remaining groups H eg of first element is more than that of second element
of the same group.

24. In lanthanides Eu has highest and Yb has second highest atomic radius.

25. Decrease in atomic radius between successive elements order is s  p  d  f due to shielding effect
order s  p  d  f .The observed decrease in ionic radius amongst representative elements is
relatively more than the corresponding decrease in atomic radius for the same elements.

26.

1s 1p

2s 2p 2d

3s 3p 3d 3f

Zn  30 :1s 2 1 p 6 2 s 2 2 p 6 3s 2 2d 10 3 p 2

28. Si<P<S<Cl(not in the order as we expect based on E.C.)

29. In addition to the differences between the first member of each group and its congeners there are also
similarities between elements with atomic numbers Z and Z+8

Z 14 15 16 17
Si P S Cl
Z+8 22 23 24 25
Ti V Cr Mn

Similarities of S and Cr are: SO42  , S 2O72  , CrO42 , Cr2O72

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30. NCERT,Class XI,Part-I,P.no:95,Q.no:3.38

31. NCERT,class XI,part-I,page no:87,174

Apply kirchaff’s equation. Ionization energy and electron affinity are defined at absolute zero.
but H eg and H ie are calculated at Tk.
H 2  H1
 C p
T2  T1
X  g   e 
 X g 
H eg    Ae  5 5 5  5
 R  R  R   R
T 0 2 2 2  2
5
  eg   Ae  RT
2
M  g   M g   e
H ie  E0  5 5  5 5
  R  R  R  R
T 0 2 2  2 2
5
 H ie  Eo  RT
2
32. NCERT,Class XI,Part-I,P.no:94

33. NCERT,Class XI,Part-I,P.no:90

34. From Cu to Zn size increased hence E.N. decreased.

35.

36. As2O3 , Sb2O3  amphoteric metalloid oxides

BeO, Al2O3 , SnO, SnO2 , PbO, PbO2 -amphoteric metal oxide
CO-neutral oxide
GeO2  distinctly acidic oxide
NCERT – class XI,page no: 91,Part-II,p.no:316

37. Exothermic: c,d,f,j

Endothermic : a,b,e,g,h,I
Electron gain enthalpy is positive for Be,Mg,N and noble gases

38. Li2O, BeO, B2O3 , CO2 , N 2O5

39. 600 kj
M   M  , M1 
400 kj
 M12 
11 0 1 1
4 4

40. Thorium

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MATHS -SOLUTIONS
41. Let the line be  x   y    0
 t3 t 2  3 
Where  ,  lies on it (where t  a, b, c )
 t 1 t  1 
 
Equation will be cubic in ‘t’ with the roots a,b,c
  3  
Now a  b  c  , ab  bc  ca   abc 
  
Finally abc   ab  bc  ca   3  a  b  c   0   3
42.
A  ,  

O
B  2 ,   C  3 ,  

OA  BC  slope OA  1  A  , 
1
OB  CA  slope of OB  , B  2 ,  
2
1
OC  AB  slope of OC  , C  3 ,  
3
Slope of BC  1  3  2
Slope of CA  2  3  5
 5 5   4 2 
 A  ,      ,   , B  2  ,      ,   , C  3 ,  
 3 3   3 3 
4 y 2
Centroid G  2 ,    
 9  x 9
43. A 1, 2  , B  , 2  , C   ,   3 , P  2,3 
3  2
Slope of BP  1   1    5
2 
1  6 1
Slope of CP       10
2  2 2
 B  5,10  , C 10,7  gives equation of BC x  5 y  45
 p  q  50
y

A
450 D
x
O 450
B
44.
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a
Here OD  AD  BD OD  P
5
2
1 a
Area of le OAB   2 P  P   sq. units
2 5
45. Solving x  y  4  0, 2 x  y  2  0
Circum centre is  2, 2 
Circum diameter  10
46.  x  2     x  y  1  0  Point  2,1 distance from origin  2
47.
y

A 1,1 C  C ,1 B  9,1

  C
D  C, 
 9
x
O
 0,C 

1 C  1
2   1    9  C    8  1  C  3 (C = 15 is not possible)
2 9 2
48. mb  0  m  0 and b  0 or m  0 and b  0
Either cases lines cut –ve X-axes and +ve Y-axis or –ve X-axes and –ve Y-axes
 X-intercept cannot be +ve
49.

Q
 0 0
R x ,y

O  0,0  P

 
Let R x0 , y0 be the foot of the perpendicular from  0,0 
y
Slope of OR  0
x
0
Equation of PQ : xx0  yy0  x02  y02
 OP  OQ  a

x2
0  x
 y2
0 0
y
0   ax0 y0
Locus is  x 2
y
2
  x  y   axy
50. Homogenising curve using the line
Since the curve is equally inclined to the axes coefficient of xy  0  k  1
51. Triangle formed is obtuse angled so centoid and incenter lie inside
x y 1
52. Clearly 1 1 1
x y 1 0
2 2 2
x y 1
3 3

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Points are collinear and cannot lie on a circle

53. A  , 2  3
1
Area      2
2
    2  2    4 or 8    6
  2,3, 7, 6
Hence A can be  2,7  3,9  7, 11 6, 9 
54. ‘L’ must be angular bisector of L1 and L2 ,
3x  4 y  1  5 x  12 y  2 
  
5  13 
 14 x  112 y  23  0 or 64 x  8 y  3  0
m m m
55. 1  9, 1 2   7 on solving m  2 , 1 or m   2 ,  1
m 2 1 m m 9 2 3 3 2 3 3
2 1 2
3 3
m  3, or m  3, 
1 2 2 2
All four options are possible.
56. Let the line through  2,3 with slope m be y  3  m  x  2 
Given area of le  12 sq. unit
On solving we get m  3 2 and two more values are possible.
So three lines are possible
57. Since these represent pair of lines   0 and since they cut X-axes  y  0 
3
Gives,   ,   24 ,  20    6
2
58.  3x  7 y  11 sec   5 x  3 y  11 cos ec  0 passes through 1, 2   permissible values
of ' ' , PA  PB  AB
PA  PB  6 2  22  2 10  n  5
max
13
59. p = Perpendicular distance from  2,3 to 3x  4 y  5  0 is
1
, 1  sin 2   p1,  n1  0
5
p = Perpendicular distance from 1,3 to 3x  4 y  15  0 is 2
2
sec 2   2cos ec 2  3  p
2
 n  2, equation becomes 2 x 2  6 x  0
2
Sum of roots  3
60. m  m2
2 1
Condition is ab  a  b   6abh  8h3  0    86  2

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