Ch 4. Statistics
by statistical treatment
4.2
x i
x i
n
4.4
4.6
3) std.dev. of mean
more measurements more confident on average
1 (nearly the true value)
uncertainty decreases by : n = number of meas.
n
s
standard deviation of mean = : s = std.dev.
n
s
* relative standard deviation = (RSD)
x
or into percentage = s 100 = C.V.
x
x
precision of mean =
n
average deviation of mean = d ( d xx )
n n
4.8
4.10
4.12
x1 x 2 n1n2
t
S pooled n1 n2
S pooled
(x i x1 )2 ( x j x 2 )2
s12 (n1 1) s22 (n2 1)
n1 n2 2 n1 n2 2
4.14
2. <t-test> A new gravimetric method is developed for iron (II) in which the iron
is precipitated in crystalline form with an organocarbon "cage" compound. The
accuracy of the method is checked by analyzing the iron in an ore sample and
comparing with the results using the standard precipitation with ammonia and
weighing of Fe2O3. The results, reported as % Fe for each analysis, were as
follows.
Test method Reference Method
20.10% 18.89%
20.50 19.20
18.65 19.00
19.25 19.70
19.40 19.40
19.99 19.40
=19.65% =19.24%
Is there a difference between the two methods ?
t cal
d
n sd
(d i d )2
Sd n 1
4.16
F test ---- check two std.devs are significantly different each other.
S12
Fcalc 2 If Fcalc > Ftable then significant
S2
4.18
y = mx + b
m: slope, b: y-intercept
4.20
1 1 y y 2
the probability Pi Pi exp i
i 2
i
2
minimizing (assume )
2
2
m
2
b
n ( x i y i ) x i y i
METHOD OF m
LEAST SQUARES n ( xi2 ) ( xi )2
b ( xi2 ) yi ( xiyi ) xi
n ( xi2 ) ( xi )2
Anal. Chem. by Prof. Myeong Hee Moon
4.22
std. dev. of y
y sy (di )2
deg rees of freedom ( n - 2)
2yn
m
2
n ( xi2 ) ( xi )2
2y ( xi2 )
b2
n ( xi2 ) ( xi )2
4.24
m : slope
4.26
Homework