CONFIDENTIAL

SULTAN IDKIS EDUCATION UNIYfRSITY

UNIVERSITI PENOIOIKAN SULTAN lORIS

FINAL EXAMINATION
SEMESTER 1 SESSION 2016/2017

CODE: SKA3013 COURSE : ANALYTICAL CHEMISTRY

0 3 JAN 2017 2 HOURS 30 MINUTES

� DATE: DURATION:

INSTRUCTIONS

1. Thisquestion paper consists of THREE (3) structured questions.

2. Answer ALL questions in the spaces provided in this question paper. Please DO NOT
use pencil.
3. SHOW YOUR WORK. Marks may be deducted for incomplete work.
4. Scientific calculator may be used in this examination.
5. Your answers should be brief, exact and clear.

This question paper contains 10 pages including the cover page

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PROGRAMME:

YEAR: LECTURE GROUP:

@' B / C/O / E
REGISTRATION NO: I I I I I I I
IDENTITY CARD NO:
I I I I I I I I I I I I I
LECTURER: DR. WAN HASLINDA BINTI WAN AHMAD

DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE TOLD TO DO SO

CONFIDENTIAL

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 SKA3013 Analytical Chemistry 2

1. (a) What is the principal of liquid-liquid extraction?

[3 Marks}

(b) _

Why this type of separation is chosen?

[4 Marks}

(c) A hexane solvent is used to separate 0.005 M of solute P in 25.0 mL

aqueous solution. The distribution ratio of this solute between both solvent is

8. About 90.56% of P was successfully extracted after using a volume of

hexane for the first extraction.

(i) What is the volume of hexane used?

[3 Marlcs}

[See next page

 3
SKA3013 Analytical Chemistry

(ii) What is the concentration of P in both solvent after extraction?

[6 Marks]

2. What the desirable properties of a standard solution?

(a) are

[4 Marks]

[See next page

SKA3013 Analytical Chemistry 4

b) Calculate the pH of the solution obtained when 40.0 mL of 0.100 M NH3

(Kb =
1.75 X 10-5) is:

(i) diluted with 20.0 mL distilled water

[7 Marks]

[See next page

SKA3013 Analytical Chemistry 5

(ii) mixed with 20.0 mL of 0.200 M Hel solution

[7 Marks]

[See next page

SKA3013 Analytical Chemistry 6

(iii) mixed with 20.0 mL of 0.200 M NH4CI solution

[3 Marks1

(iv) mixed with 20.0 mL of 0.250 M HCI

[4 Marksj

[See next page

SKA3013 Analytical Chemistry 7

3. Substances of X and Y were found to have retention times of 16.20 and 25.03 min,

respectively, on a 45.0 cm column. An unretained species passed through the column

in 2.70 min. The peak widths (at base) for X and Y were 2.35 and 3.62 min,

respectively.
(a) Draw the chromatogram obtained with complete data and symbols
[5 Marks]

(b) Calculate:

(i) Column resolution (Rs)

[3 Marks]

{See next page

SKA3013 Analytical Chemistry 8

(ii) Average number of plates (N) in the column

[6 Marks]

(iii) Plate height (H)

[3 Marks]

[See next page

SKA3013 Analytical Chemistry 9

(iv) Difference of retention factor (k) between substance X and Y

[6 Marks]

(v) Separation factor (a) for both substances

[3 Marks]

[See next page

SKA3013 Analytical Chemistry 10

(vi) Number of effective plates required (Neff(req))

[3 Marks}

END OF QUESTIONS