CAREER POINT JEE Main Online Paper

JEE Main Online Exam 2019

[Memory Based Paper]
Questions & Answer
10th January 2019 | Shift - II

CHEMISTRY
CH3 CH3
Q.1
Br
H

(1) 2-Bromo-3-methyl Pent-3-ene (2) 3-methyl-4-Bromo Pent-2-ene

(3) 4 Bromo-3-methyl pent-2-ene (4) 4-Bromo-3-methyl But-2-ene
Ans. [3]

Q.2 Two complex compound have same chemical formula one shows optical isomerism and other do not show
optical isomerism. Which kind of isomer these are
(1) Ionisation (2) Linkage (3) Geometrical (4) None of these
Ans. [3]

Q.3 Which of the following pair contain 2 P–H bond.

(1) H3PO2, H3PO3 (2) H3PO2, H4P2O5 (3) H3PO3, H4P2O6 (4) H3PO2, H4P4O6
Ans. [2]

Q.4 Number of 2 atom 2-electron and 3 atom 2-electron bonds in B2H6 are -
(1) 2, 4 (2) 3, 1 (3) 4, 2 (4) 1, 3
Ans. [3]

Q.5 A metal form high spin and low spin complex. If difference between number of unpaired electron is two then
metal ion is -
(1) Co 2  (2) Mn 2 (3) Fe 2 (4) Ni 2

Ans. [1]

Q.6 For 1 molal compound elevation in boiling point is 2K and for 2 molal depression in freezing point is 2 K
what is the relation between Kb and Kf.
(1) Kb = Kf (2) Kb = 1.5 Kf (3) Kb = 2Kf (4) Kb = 0.5 Kf
Ans. [3]

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Q.7 A solid having HCP arrangement with formula A2B3. Which atom form lattice and which atom occupied
void-
2
(1) B atom occupy lattice and A atom occupy octahedral voids
3
1
(2) B atoms occupy lattice and A atoms occupy octahedral voids
3
2
(3) A atom occupy lattice and B atoms occupy tetrahedral voids
3
1
(4) A atoms occupy lattice and B atoms occupy octahedral voids
3
Ans. [1]

Q.8 When Na is treated with liquid NH3 blue colour solution is formed. What is the reason for colour formation
(1) Due to [Na(NH3)x]+
(2) Due to Ammoniated (solvated) e– or [e(NH3)y]–
(3) Due to hydrated e–
(4) Due to formation of NaNH2
Ans. [2]

O O
C–OEt
Q.9
(i) NaOEt
O (ii) 

O O
(1) (2)

C–OEt C–OEt
O O
O
(3) O (4) None of these
CH2–C–OC2H5
Ans. [2]

Q.10 Amount of sugar required to form 2L of 0.1 M solution

(1) 136.8 g (2) 34.2 g (3) 17.1 g (4) 68.4 g
Ans. [4]

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NH3/ Br2
Q.11 C7H6O2 (B) (C) C6H7N
KOH
(A)
Compound ‘A’ is

O O
C–OH H–C=O OH C–OH

(1) (2) (3) (4)

CH3 OH OH
OH
Ans. [1]

Q.12 5.1 g NH4HS(s) is heated at 327ºC in a closed container of volume 3L, it decomposes into NH3(g) and
H2S(g). If at equilibrium 30% decomposition is taking place. Find Kp -
(1) 0.248 × 10–2 (2) 0.243 (3) 0.9706 (4) 0.496
Ans. [2]

Q.13 NaBH4
HN O

(1) (2)
NH2 OH NH2 OH

(3) (4)
NH OH NH OH
Ans. [4]

CH3
OH
(i) aq NaOH
Q.14 Product
(ii) CH3I

The product is -

OH CH3 H OH
H CH3 CH3 H
O O O
O
(1) (2) (3) (4)
CH3 CH3
CH3
Ans. [2]

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NH
Q.15 HNO3 + H2SO4
O

NO2 NO2
O
(1) NH – C (2)
NH – C NO2
O

(3) H2N C – NH (4) NO2 NH – C

O O
Ans. [4]

Q.16 When potassium permanganate reacts with oxalate ion, total number of electron(s) gained or lost in the
reaction -
(1) 2 (2) 8 (3) 10 (4) 6
Ans. [3]

Q.17 Which can not be used for test of protein

(1) Xanthoprotic (2) Ninhydrin (3) Biuret Test (4) Boford Test
Ans. [4]

Q.18 In which of the following entropy change is negative -

(1) N2(g) + 3H2(g)  2NH3(g) (2) Dissociation of HI
(3) Sublimation of Ice (4) Dissociation of PCl5
Ans. [1]

Q.19 Which type of sol are haemoglobin and gold sol

(1) Both are positive
(2) Both are negative
(3) Haemoglobin is positive and gold is negative
(4) Haemoglobin is negative and gold is positive
Ans. [3]

Q.20 For an element having Z = 71, in which orbital the last electron will enter
(1) 6s (2) 5d (3) 9f (4) 6d
Ans. [2]

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Q.21 For the following equation

K1
2A A2
K–1

d[A ]
Then find
dt
(1) 2K1[A]2 – 2K–1[A2] (2) 2K1[A]2 – K–1[A2]
(3) K1[A]2 – 2K–1 (4) K1[A]2 – K–1[A2]
Ans. [1]

Q.22 Which of the following reaction needs catalyst -

(1) H2 + F2  2HF (2) H2 + Br2  2HBr
(3) H2 + I2  2HI (4) H2 + Cl2  2HCl
Ans. [3]

Q.23 Which of the reaction is not involve in ozone layer depletion

uv •
(1) ClO• + O(g)  Cl • + O2(g) (2) CF2Cl(g)  Cl • (g ) + C F2 Cl ( g )
(3) Cl • + O3(g)  ClO• + O2(g)` (4) Cl2 + H2O  2HOCl
Ans. [4]

O
?
Q.24
OH OH
Reagent for conversion is
(1) CrO3 (2) KMnO4 (3) Tollen's reagent (4) NaOH + I2
Ans. [4]

O O
(i) HCl/
Q.25 CH3O C–C–OCH3
(ii) (COOH)2

OH
O O O O
——O —C––C–O C––C––
O O
(1) C––C–– (2)

OCH3 n CH3O n
O O
C––C–OH
O O
O O O—C––C—––
(3) —O— C––C–– (4)

OH OCH3 n
n
Ans. [1]

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