Dated : 04-01-2019

[ FULL TEST - 9 ] [ JEE-MAIN ]

1. D 16. A 31. B 46. A 61. C 76. B
2. D 17. A 32. B 47. B 62. C 77. C
3. D 18. B 33. D 48. D 63. B 78. D
4. A 19. A 34. B 49. D 64. C 79. C
5. A 20. C 35. D 50. C 65. C 80. C
6. D 21. C 36. D 51. C 66. D 81. B
7. A 22. B 37. B 52. A 67. B 82. B
8. B 23. C 38. D 53. B 68. A 83. C
9. B 24. B 39. C 54. D 69. C 84. A
10. A 25. C 40. C 55. C 70. C 85. C
11. A 26. D 41. C 56. D 71. B 86. A
12. D 27. B 42. C 57. B 72. C 87. B
13. C 28. A 43. D 58. A 73. A 88. C
14. A 29. C 44. B 59. D 74. A 89. A
15. B 30. B 45. B 60. B 75. D 90. D

1.  = 100 cm; v = 25 cm s-1 N 1

25 1 1 1 1 VSD = MSD
  s or T= or T = 4s N
100 4  V.C. = 1 MSD – 1 VSD
2r 2 (    0 ) g  N 1  1
2. Terminal velocity, v = = 1 MSD –   MSD= MSD
9  N  N
i.e., v  r2  v' = 4v 1 1
= mm  cm
hc N 10N
3. Incident energy E = hv =
 7. The angular frequency of oscillating electric field is
12400 given by
or E(in eV) = (eV Å) qB 1.6 1019  2
 (Å)    108 radian/sec
12400(eV Å) m 2 1.6 1027
= = 4.13 eV 8. The maximum kinetic energy gained by the
3000 (Å) positive ion is given by
According to Einstein’s photoelectric equation
1 B2 q 2 R 2 2mE max
Incident energy = work function + Emax = or R=
kinetic energy of emitted photoelectrons 2 m B2 q 2
hv =  + K Substituting the values of m, Emax, B and q in above
or K = hv –  = 4.13 – 1 = 3.13 eV equation, we get
1 2
mv  3.13 1.6 1019 2  2 1.6 1027 100 106 1.6 1019
or R
2 4 1.6 1019 1.6 1019
3.13 1.6 1019  2  1  1m
v2 
9.11031
or v = 106 ms-1 9. In SHM, v   a 2  y 2 or v2 = 2a2 – 2y2
speed of light in vacuum (c) v2 y2
4.   Dividing both sides by 2a2,   1 . This is
speed of light in medium (v)  2a2 a2
c 1 l equation of an ellipse. Hence the graph between v and y is
v  t  an ellipse not a parabola.
 t c 10. The beautiful colours are seen on account of
5. Initial potential energy = 10 joule interference of light reflected from the upper and lower
Since potential energy  x2, surfaces of the thin film. As the conditions for
 Final potential energy = 40 joule constructive and destructive interference are dependent on
Work done = 40 J – 10 J = 30 J wavelength of light, therefore, coloured interference
6. N VSD = (N – 1) MSD fringes are observed.
11. 1 V = 1 J C-1
 2GM GI g 1000 104 101 1
12. Escape velocity of satellite, ve  S     0.01 
R I  Ig 10  10 4
10 100
GM This is to be connected in parallel to the given
Orbital velocity of a satellite, v0  galvanometer.
R
23. In order to melt the given amount of ice completely,
 ve  2v0 the heat required is 50 × 80 cal i.e. 4000 cal. Heat given
13. The time period of second pendulum out by water in cooling from 20oC to 0oC is 50 × 1 × 20
i.e. 1000 cal. This much heat will not be sufficient to melt
l
T  2 the whole of ice.
g v 2 sin 30
The value of g is less on moon than that of earth, 24. 1.5 =
therefore, to get same value of time period decrease the
g
length of the pendulum. v2
or = 1.5 × 2 km = 3 km
14. Power = n h v g
Power 10 103 v2
or n =  = is the range when the angle of projection is 45o.
h 6.6 1034  880 103 But
g
1034 25. Draw a circuit diagram as
6.6  88
or n = 1.7 × 10-3 × 1034 = 1.7 × 1031
dz 1 2
15. z  t 2  1;  (t  1)1/2  2t
dt 2
dz t
or  ; Applying Kirchoff’s law
dt t2 1 Loop PQVWP : 10 I1 + 10(I1 – I2) – 5(I – I1) = 0
1 2t  5I1 – 2I2 = I ...(i)
2
t2 1  t 
d z
 2 t2 1 Loop QRUVQ
20 I2 + 20(I2 – I3) – 10(I1 – I2) – 10(I – I2) = 0
dt 2 t2 1
 6 I2 – 2I3 – I1 = I ...(ii)
Loop RSTUR : 30 I3 – 20(I2 – I3 – 15(I – I3) = 0
d 2z 1 1  13 I3 – 4I2 = 3I
 2  3 ...(iii)
dt 2
(t  1) 3/2
z Loop AWVUTBEA
16. Absolute zero of temperature is that temperature at 5(I – I1) + 10(I – I2) + 15(I – I3) = E
which all molecular motion ceases.  30I – 5I1 – 10I2 – 15 I3 = E ...(iv)
17. At the magnetic equator, the angle of dip is zero Solving equation (i), (ii) and (iii), we get
V I I I
  tan 0  V  0 I1 = , I2 = and I3 =
H 3 3 3
i.e. at equator magnetic field of earth has only horizontal From (iv),
component. 5 10 15
18.  = v – r = (µv – 1) A – (µr – 1) A 30 I  I  I  I  IR eq (Ohm's law)
3 3 3
 = (µv – µr)A = (1.54 – 1.52)10o 20 I = I Req Req = 20 
2 26. D
 10  0.2
100 27. Choose the positive direction of x-axis to be
19. Higher the range of ammeter, the smaller will be the from south to north. THen
resistance of ammeter. vA = +54 kmh-1 = 15 ms-1
20. In nuclear reactor cadmium of boron rods are used as vB = –90 kmh-1 = –25 ms-1
a control rods. In a nuclear reactor control rods are used to Relative velocity of B with respect to A = vB – vA
absorb the slow down neutrons. = –40 ms-1, i.e. the train B appears to move with a speed
h 1 of 40 ms-1 from north to south.
21.  ;  28. Relative velocity of ground with respect to B = 0 – vB
2mqV mq = 25 ms-1.
p h m q 4m p  2q p 29. Let the velocity of the monkey with respect to ground
   be vM. Relative velocity of the monkey with respect
 mp q p 1 mp q p to A,
p vMA = vM – vA = –18 kmh-1 = –5 ms-1
 82 2 :1 Therefore, vM = (15 – 5) ms-1 = 10 ms-1
 30. If germanium (tetravalent) is doped with donor
22. Ig = 0.1 × 10-3 A; G = 1000  I = 10 A impurity the donor impurity should be pentavalent.
31. B PbS + 4O  PbSO4
Overall
PbS + H2O2  PbSO4 + 4H2O
32.
49. Like diamond SiO2, and carborundum are tetrahedral
33. None of these have -H-atom. So, all of these will
molecules.
undergo Cannizzaro reaction.
34. Volume of the unit cell (V)
= Area of rhombic base × b = (a2 sin 60o) × b
3
= (4.53 × 10-8) 2 × × 7.41 × 10-8 cc
2
= 131.7 × 10-24cc
35. Mass of unit cell = Volume × density
= 131.7 × 10-24 × 0.92 × 6.02 × 1023g = 73 g
36. Molecular weight of H2O = 18
As mass of unit cell is about 4 times the molecular weight
of H2O, hence there are 4 molecules of H2O per unit cell.
H
37. C18H32O16 + 2H2O   3C6H12O6 50. All oxides form brown vapours on heating or
rate  [C18H32O16] [H2O] 0 oxidation but N2O3 is blue liquid which decomposes
38. For conjugate acids and bases, Ka.Kb = Kw as
K 11014
 Ka    5.5 1010
K b 1.8 105
39. The heat of ionisation for weak acid or weak base is 51. R—CH2—NC is major product but R—CH2—CN is
taken from heat of neutralization. minor product.
CH3COOH + KOH CH3COOK + H2O 52. A
Heat of neutralization = 13.7 – 0.3 = 13.4 kcal/mol 53. H2O2  H2O + [O]
40. Molality does not depend upon volume thus it does 2KI + H2O + [O]   2KOH + I2
not depend on temperature. 2KI + H2O2   2KOH + I2
41. Recovery of silver is based on the fact that more H2O2 reduces MnO-4 to Mn2+ ion with the liberation
electropositive metal can displace less electropositive of O2.
metal from its salt solution. 2KMnO4 + 3H2SO4 K2SO4 + 2MnSO4 + 3H2O
2NaAg(CN) 2 + Zn  Na2Zn(CN) 4 + 2Ag + 5[O]
5H2O2 + 5[O]  5H2O + 5O2
2KMnO4 + 3H2SO4 + 5H2O2  K2SO4 + 2MnSO4
+ 8H2O + 5O2
54. In a group of isomeric alcohols, the primary alcohol
42. has the highest boiling point and the teritary the lowest,

C6 H5 — C —C6 H 5 with the secondary having an intermediate value. The
lower members are far less volatile than is to be expected
43. | - trityl carbonium ion from their molecular weight, and this is due to association
C6 H 5 through hydrogen bonding extending over a chain of
44. BH3 is electron deficient compound so it overcomes molecules, thus giving rise to a large molecule the
its non-octet nature by dimerisation. volatility of which would be expected to be low.

The lower alcohols are very soluble in water and the

solubility diminishes as the molecular weight increases.
Their solubility in water is to be expected since the
oxygen atom of the hydroxyl group in alcohols can form
45. hydrogen bonds with the water molecules. In the lower
46. Sc3+  3d0; Ti3+  3d1 alcohols the hydroxyl group constitutes a large part of the
Fe2+  3d6 molecule, whereas the molecular weight of the alcohol
Ti and Fe2+ contain 1 and 4 unpaired electrons
3+
increases the hydrocarbon character of the molecule
respectively, so they are paramagnetic in nature. However increases, and hence the solubility in water decreases.
Sc3+ has no unpaired electron. Thus it is diamagnetic. This, however, is not the complete story; the structure of
47. B the carbon chain also pays a part, e.g., n-butanol is fairly
48. H2O2 oxidises black lead sulphide (PbS) to white lead soluble in water, but t-butanol is miscible with water in all
sulphate (PbSO4). proportions.
[H2O2  H2O + O] × 4 55. C
56. PCl3 (sp3 ), H3PO3 (sp3 )
SF4 (sp3d), H2SO3 (sp3 )
BCl3 (sp2 ), H3BO3 (sp2 )
XeF6 (sp3d 2 ), XeO3 (sp3 )
57. 2NO + Cl2  2NOCl (nitrosyl chloride).  4 
i   
58. The Grignard’s reaction is a chemical reaction e  3 
.( z2  z1 )
involving alkyl or aryl magnesium halides, also known as
Grignard’s reagent with aldehydes and ketones. or z3 – z1 = (z2 – z1) ei /3
59. Enthalpy of formation of Hf of SO2 is the heat z1, z2, z3 form an equilateral triangle.
liberated when 1 mole of SO2 i.e. 64 g of SO2 is 66. Vectors a  iˆ  ˆj  kˆ, b  4iˆ  3 ˆj  4kˆ
formed.
0.5 g S  1g SO2; q = –4.6 kJ and c  iˆ   ˆj   kˆ are linearly independent if
32 g of S  64 g of SO2 1 1 1 1 0 0
H = (–4.6 kJ) × 64 = –294.4 kJ 4 3 4  0 or 4 1 0
60. From rate law, rate = k(A)n
15 × 10-4 = k (0.0025) n ...(i) 1   1  1  1
5 × 10-4 = k(0.0075) n ...(ii) (C2  C2–C1, C3  C3 – C1)
dividing equation (i) by equation (ii), we have or ( – 1) = or  = 1
3 = (1/3) n or (3)1 = (3)-n
n = –1 and | c |  1   2   2  3
 0 a b 
or   1    1,   1
61. If A   a 0 c 
 n
 b c 0  67. sin n =  b sin
r 0
r
r

The system is (I – A)X = 0  X = 0 since
I – A is nonsingular. ( A is skew symmetric matrix) Put n = 0, b0 = 0; Put n = 1, sin = b1 sin
 b1 = 1 for n = 1, Put n = 5
x15  1 x15  1 x10  1
62. lim  lim lim sin 5 = sin (b1 + b2sin + b3sin2 + b4sin3 +
x 1 x10  1 x 1 x  1 x 1 x  1
b5sin4)
15(1)14 3  xn  an  or sin (3 – 4 sin2) cos2 + 2sin cos cos3
   using lim  n.a n 1  = sin (b1 + b2sin + b3sin2 + b4sin3 + b5sin4)
10
2 x a x  a
10(1) 
i.e. (3 – 4 sin2)cos 2 + 2cos cos3
Both statements are true and statement-2 is the proper
= b1 + b2sin + b3sin2 + b4sin3 + b5sin4
explanation of statement-1.
Put  = 0, b1 = 5. Hence b1 = 5 for n = 5.
 9  10  The above conditions are satisfied by (b) only.
63. N = 9.9.8 –      = 648 – 84 – 120
3  3  68. 240 is divisible by 4n + 2.
= 444 = 22.31.371 or 120 is divisible by 2n + 1
The sum of the divisors of N is Numbers of the form (2n + 1), n  +I are all odd natural
numbers. So in essence you have to find out all odd
(23  1)(32  1)(37 2  1)
 7.4.38  1064 numbers dividing 120. These numbers are 1, 3, 5, 15.
(2  1)(3  1)(37  1) n
r
Statement-1 is false. But statement-2 is true. 69. Let bn  
r 0
n
Cr
64. a  2iˆ  2 ˆj  2kˆ, c  4iˆ  6 ˆj  2kˆ 0 1 2 n
  n  n  ...  n (nCr = nCn-r)
c  a  2iˆ  4 ˆj, b  3iˆ  2 ˆj  kˆ n
C0 C1 C2 Cn
(c  a )
a b  2iˆ  2 ˆj  2kˆ  3iˆ  2 ˆj  kˆ ( n 1)/2 (r  n  r )
b .b   n
if n is odd
 r 0 Cr
 5i  4 ˆj  3kˆ giving the points (5, 4, 3)
ˆ  ( n 1)/2
 (r  n  r ) n /2
65. Substacting z1(1 +  +) = 0 
 r 0 n
+n if n is even
from z1 + z2 + z3 = 0, Cr Cn /2
we get (z2 – z1) +  (z3 – z1) = 0 ( n 1)/2 2
or z3 – z1 = – (z2 – z1)   n if n is odd
n  r 0 Cr n
 ( n 1)/2   an
2 2 1 2
 +
 r 0 n Cr n Cn /2
if n is even
70. Remember in cyclic order. Dot and cross can be 76. Number of ways in which the two faulty machines be
interchanged. detected (depending on the test done to identify the
faulty machines) = 4C2 = 6
Number of favourable cases = 1
(when faulty machines are identified in the first and
the second test).
Required probability = 1/6
u.(v  w)  [uvw] x C
77. y = (C1 + C2) cos(x + C3) – C4e 5
(v  w).u  u.(v  w)  [uvw] C
= C6cos(x + C3) – ex × C4 × e 5
v.(u  w)  v.(w  u )  [vwu ]  [uvw] = C6cos(x + C3) – ex × C7
(u  v ).w  [uvw] Hence you have to differentiate y three times to eliminate
71. f (x) = 3x – 5 the three constants. Therefore the order of the differential
f (x) is monotonically increasing function. Hence euqation is 3.
inverse exists. 78. Slope of Ist line = –1/3
y 5 x5 Slope of second line = 3  m1 × m2 = –1
x  g ( y)   f 1 ( x)  The diagonals are perpendicular to each other.
3 3 For a parallelogram this happens if it is a square or a
1 rhombus. But the square is a particular case of rhombus,
72. Tm = a + (m – 1)d = ...(1)
n the parallelogram PQRS must be a rhombus.
1 79. Let number of newspapers be x.
Tn = a + (n – 1)d = ...(2) If every student reads one newspaper, the number of
m
students would be x × 60.
1 1
On solving you get, a  ;d As every student reads 5 newspapers,
mn mn x  60
1 1 number of student =  300 ,  x = 25
Tmn = a + (mn – 1) d   (mn  1) 1 5
mn mn 80. 16x2 + 25y2 = 400
73. g (f (x)) = | sin x |, f (g(x)) = (sin x )2 x2 y 2
  1 (ellipse)
(a) f (x) = sin2x, g(x) = x 25 16
Focus of the ellipse = (± ae = 0)
 g ( f ( x))  sin 2 x = | sin x |, f (g(x)) = (sin x )2 [ b2=a2 (1 – e2)  16 = 25(1– e2)  e = 3/5)]
(b)f (x) = sin x, g(x) = | x |  3 
g(f (x)) = | sin x |, f (g(x)) = sin | x | i.e.  5  , 0  i.e. (±3, 0)
 5 
(c) f (x) = x2, g(x) = sin x
Now for an ellipse with focus F1 and F2 and a point
 g(f(x)) = sin | x |, f (g(x)) = (sin x )2 lying on it, PF1 + PF2 = 2a
(d)f and g cannot be determined,” does not stand true as In this case PF1 + PF2 = 2 × 5 = 10
(a) gives f and g. 2
74. f (x) = x – [x]
81. y  cos( 2 x) has a period  2
2
[x] = –1 –1 < x < 0
y = cos x has a period 2.
[x] = 0 0<x<1
1 1

 f ( x)dx   ( x  [ x])dx
1 1

z
1 F z [ x]dx z [ x]dxI
0 1
 xdx 
1
GH1 0
JK Hence after attaining a maximum value at x = 0 (at
F I F0 1 I
 G  z 1dxJ  1. G z xdx  0, odd functionJ
x = 0, y = 1), the function
H K H1 1 K y  cos 2 x  cos x
won’t ever attain this value again, is clear from the graph.
2
 c2  82. Equating (1 + lny) – (1 + lnx)
75. x     a gives x1, x2, x3, x4
2 2
and (1 + lnz) – (1 + lny)
 x you have ln(y/x) = ln(z/y) i.e. y/x = z/x
2
 c2  or y2 = xz, which is true as x, y, z are in G.P.
   y  a gives y1, y2, y3, y4
2 2
 1 1
 x Hence , , are in H.P.
i.e. x4 + c4 – a2x2 = 0
1  ln x 1  ln y 1  ln z
i.e. x1 + x2 + x3 + x4 = 0 and x1x2x3x4 = c4 83. 3 sin2x – 7 sin x + 2 = 0
Similarly y1+ y2 + y3 + y4 = 0
 0 < M < 1 where M = XY.
87. We have A + C =  – B and
1 
(A – B + C) =  B
2 2
7  49  24 7  5 1 c  a 2  b2
2
or sin x    2, 2 ac cos B = 2ac  c 2  a 2  b2
6 2 3 2ac
As sin x < 1, 2 is rejected, sin x = 1/3 88. We have
Clearly, from the graph, sin x = 1/3 intersect at 6 points on x
 3
 1 x 
[0, 5].
 x 3 
x

  Lim
84. Coordinates of the vertices Lim    ;
 (x1, y1), (x2, y2), (x3, y3), x1, x2, x3, y1, y2, y3 are x 
 x2 x 
 1 2 
rational.  x
x1  x2  x3   3
x
Centroid : x 
3   1  x  e3 1
 rational point.  Lim    2  5
y1  y2  y3 
 1 2 
x  e e
y
3   x
ax  bx2  cx3  C
Incentre : x  1 89. Given C = R  2R=c
abc 2 2sin( / 2)
depends on values of a, b, c may or may not be 
rational. Also r = (s – c) tan = s – c  2r = 2s – 2c
Circumcentre : 4
=a+b–c ( 2s = a + b + c)
x sin 2A  x2 sin 2B  x3 sin 3C
x 1 2R + 2r = a + b – c + c = a + b
sin 2A  sin 2B  sin 2C
 13 
depends on values A, B, C; may or may not be 90. S :  , 1
rational. 2 
x1 tan A  x2 tan B  x3 tan C
Orthocentre : x 
tanA  tanB  tanC
depends on the values of A, B, C; may or may not be
rational.
1 2
85. We have f () = sin (sin + sin3) Slope of line PS = 
= sin (sin + 3sin – 4sin3) 13 9
2–
= sin (4 sin – 4 sin3) = 4 sin2 [1 – sin2] 2
= 4sin2 cos2 > 0  real . required equation is
86. Let X = a + b, Y = c + d 2
 X + Y = 2, X, Y > 0 y + 1 =  ( x  1)  9y + 2x + 7 = 0
9
Since AM > GM
XY
  XY  XY  1
2