JEE ( Main ) Examination–2019/Morning Session/11-01-2019

TEST PAPER OF JEE(MAIN) EXAMINATION – 2019

(Held On Friday 11th JANUARY, 2019) TIME : 9 : 30 AM To 12 : 30 PM
CHEMISTRY
1. For the cell Zn(s) | Zn2+(aq) || Mx+ (aq) | M(s), 4. The concentration of dissolved oxygen (DO) in
different half cells and their standard electrode cold water can go upto :
potentials are given below : (1) 10 ppm (2) 14 ppm
(3) 16 ppm (4) 8 ppm
Au 3+ (aq) / Ag + (aq) / Fe3+ (aq) / Fe2+ (aq) / Ans. (1)
M x + (aq / M(s)
Au(s) Ag(s) Fe2+ (aq) Fe(s) Sol. In cold water, dissolved oxygen (DO) can reach
E oM x+ / M ( v ) 1.40 0.80 0.77 -0.44 a concentration upto 10 ppm
5. The major product of the following reaction is:
If E Zn 2+ / Zn = -0.76V , which cathode will give a
o
O

mximum value of E ocell per electron transferred ? OEt ¾¾¾¾¾

(i) Ni / H 2
®
(ii)DIBAL -H
CN
(1) Fe3+ / Fe2+ (2) Ag+ / Ag
H
(3) Au3+ / Au (4) Fe2+ / Fe N
Ans. (2)
2. The correct match between items-I and II is :
Item-I Item-II
EN (1)

(3)
O
CHO

NH
(2)

(4)
OH

NH2
(Mixture) (Separation method)
Ans. (2)
(A) H2O : Sugar (P) Sublimation Sol.
(B) H2O : Aniline (Q) Recrystallization O O
LL
(C) H2O : Toluene (R) Steam distillation C – OEt (1) H/Ni C – OEt
2

(S) Differential CN CHN

2 H2

extraction DIBAL–H
O
(1) A-Q, B-R, C-S (2) A-R, B-P, C-S C– H
N –HO
(3) A-S, B-R, C-P (4) A-Q, B-R, C-P 2
CHN
2 H2
A

Ans. (1)
6. Th correct statements among (a) to (d) regarding
Sol. (Mixture) (Seperation method) H2 as a fuel are :
H2O : Sugar Þ Recrystallization (a) It produces less pollutant than petrol
H20 : Aniline Þ Steam distillation (b) A cylinder of compressed dihydrogen weighs
H2O : Toluene Þ Differential extraction ~ 30 times more than a petrol tank producing
3. If a reaction follows the Arrhenius equation, the the same amount of energy
(c) Dihydrogen is stored in tanks of metal alloys
1 like NaNi5
plot lnk vs gives straight line with a
(RT) (d) On combustion, values of energy released per
gram of liquid dihydrogen and LPG are 50 and
gradient (–y) unit. The energy required to
142 kJ, respectively
activate the reactant is :
(1) b and d only (2) a, b and c only
(1) y unit (2) –y unit (3) b, c and d only (4) a and c only
(3) yR unit (4) y/R unit Ans. (2)
Sol. Option (a), (b) & (c) are correct answer
Ans. (1)
(NCERT THEORY BASED)
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JEE ( Main ) Examination–2019/Morning Session/11-01-2019
7. The major poduct of the following reaction is: 10. The major product of the following reaction is :
Cl COCH3
(i) KMnO4 / KOH, D
¾¾¾¾®
(i) HBr ¾¾¾¾¾¾
(ii) H2SO4 (dil)
®
(ii) alc.KOH
CH3
O
COCOOH
Cl
(1)
(1) (2) HOOC
OH O COOH
Cl OH (2)
HOOC
(3) (4)
COOH
O O
(3)
Ans. (1) OHC
Sol. COCH3
Cl Cl (4)
(1) HBr alc HOOC
Br
O O EN
KOH
O

Tauto
Ans. (2)

O
C–CH3 COOH
HO
(1) KMnO/4 OH/D
Sol. (2) HSO(dil)
8. The element that usually does not show variable 2 4

oxidation states is : CH3 COOH

LL
(1) V (2) Ti (3) Sc (4) Cu
11. Among the following compound which one is found
Ans. (3)
in RNA ?
Sol. Usally Sc(Scandium) does not show variable
oxidation states. O NH2
CH3
Most common oxidation states of : NH N
A

(1) (2)
(i) Sc : +3 N O N O
(ii) V : +2, +3, +4, +5 H H
(iii) Ti : +2, +3, +4 O O
(iv) Cu : +1, +2 NH NMe
9. An organic compound is estimated through Dumus (3) (4)
N O N O
method and was found to evolve 6 moles of CO2. H Me
4 moles of H2O and 1 mole of nitrogen gas. The Ans. (3)
formula of the compound is :
Sol. For the given structure
(1) C12H8N (2) C12H8N2 'uracil' is found in RNA
(3) C6H8N (4) C6H8N2 O
Ans. (4) NH

Sol. [CxHyNz] ¾¾¾®

Duma
Method
6CO2 + 4H2O + N2 N O
Hence, C6H8N2 H

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 JEE ( Main ) Examination–2019/Morning Session/11-01-2019
12. Which compound(s) out of the following is/are not 15. Consider the reaction,
aromatic ? ˆˆ† 2NH3(g)
N2(g) + 3H2(g) ‡ˆˆ
The equilibrium constant of the above reaction is
KP. If pure ammonia is left to dissociate, the partial
pressure of ammonia at equilibrium is given by
Å Å (Assume that PNH3 << Ptotal at equilibrium)
3 1 3 1
(A) (B) (C) (D) 2 2 2 2 2 2
(1) 3 K P P (2) 3 K P P
(1) C and D (2) B, C and D 4 16
1 1
(3) A and C (4) B 2 2 2 2
(3) K P P (4) K P P
Ans. (2) 16 4
Ans. (2)
Sol. out of the given options only is aromatic. 16. Match the ores(Column A) with the metals
(column B) :
Column-A Column-B
Hence (B), (C) and (D) are not aromatic
Ores Metals
13. The correct match between Item(I) and Item(II) (I) Siderite (a) Zinc
is : (II) Kaolinite (b) Copper

Item-I
(A) Nortehindrone
(B) Ofloxacin
Item-II
EN
(P) Anti-biotic
(Q) Anti-fertility
(III) Malachite
(IV) Calamine
(c) Iron
(d) Aluminium
(1) I-b ; II-c ; III-d ; IV-a
(2) I-c ; II-d ; III-a ; IV-b
(3) I-c ; II-d ; III-b ; IV-a
(C) Equanil (R) Hypertension (4) I-a ; II-b ; III-c ; IV-d
Ans. (3)
(S) Analgesics Sol. Siderite : FeCO3
(1) A-R, B-P, C-S (2) A-Q, B-P, C-R Kaolinite : Al2(OH)4Si2O5
LL
Malachite : Cu(OH)2.CuCO3
(3) A-R, B-P, C-R (4) A-Q, B-R, C-S
Calamine : ZnCO3
Ans. (2) 17. The correct order of the atomic radii of C, Cs, Al
Sol. (A) Norethindrone – Antifertility and S is :
(1) S < C < Al < Cs (2) S < C < Cs < Al
(B) Ofloaxacin – Anti-Biotic (3) C < S < Cs < Al (4) C < S < Al < Cs
(C) Equanil – Hypertension (traiquilizer) Ans. (4)
A

14. Heat treatment of muscular pain involves radiation In a period

AR ¯
of wavelength of about 900 nm. Which spectral
In a group (AR-Atomic radius)
line of H-atom is suitable for this purpose ? Sol.
[R H = 1 × 10 5 cm –1 , h = 6.6 × 10 –34 Js, AR ­
c = 3 × 108 ms–1] Atomic radii order : C < S < Al < Cs
(1) Paschen, 5 ® 3 (2) Paschen, ¥ ® 3 Atomic radius of C : 170 pm
Atomic radius of S : 180 pm
(3) Lyman, ¥ ® 1 (4) Balmer, ¥ ® 2
Atomic radius of Al : 184 pm
Ans. (2) Atomic radius of Cs : 300 pm

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JEE ( Main ) Examination–2019/Morning Session/11-01-2019
18. Match the metals (Column I) with the coordination 20. The major product of the following reaction is :
compound(s) / enzyme(s) (Column II)
OH
Column-I Column-II
Metals Coordination
compound(s) / Enzyme(s) ¾¾¾¾
Br2 (excess)
®
(A) Co (i) Wilkinson catalyst SO3 H
(B) Zn (ii) Chlorophyll OH OH
(C) Rh (iii) Vitamin B12 Br Br Br
(D) Mg (iv) Carbonic anhydrase (1) (2)
(1) A-ii ; B-i ; C-iv ; D-iii SO3H
Br
(2) A-iii ; B-iv ; C-i ; D-ii
OH OH
(3) A-iv ; B-iii ; C-i ; D-ii
Br Br
(4) A-i ; B-ii ; C-iii ; D-iv
(3) Br Br (4)
Ans. (2)
Br SO3H
Sol. (i) Wilkinson catalyst : RhCl(PPh3)3
(ii) Chlorophyll : C55H72O5N4Mg
(iii) Vitamin B12(also known as
EN
cyanocobalamin) contain cobalt.
Ans. (1)
Sol.

OH
Br2/excess
Br
OH
Br
+ SO3­
(iv) Carbonic anhydrase contains a zinc ion. Due to Ipso attack
SO3H Br
19. A 10 mg effervescent tablet contianing sodium
bicarbonate and oxalic acid releases 0.25 ml of
LL
21. Two blocks of the same metal having same mass
CO2 at T = 298.15 K and p = 1 bar. If molar and at temperature T1 and T2, respectively. are
volume of CO2 is 25.0 L under such condition, what brought in contact with each other and allowed to
is the percentage of sodium bicarbonate in each attain thermal equilibrium at constant pressure. The
tablet ? [Molar mass of NaHCO3 = 84 g mol–1] change in entropy, DS, for this process is :
(1) 16.8 (2) 8.4
é 1
ù
A

(3) 0.84 (4) 33.6 æ T1 + T2 ö ê (T1 + T2 ) 2

ú
(1) 2CP ln ç 4T T ÷ (2) 2C P ln ê T1T2 ú
Ans. (1) è 1 2 ø ëê ûú

é (T1 + T2 ) 2 ù é T1 + T2 ù
(3) P ê 4T T ú
C ln (4) 2CP ln ê 2T T ú
ë 1 2 û ë 1 2 û

Ans. (3)

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 JEE ( Main ) Examination–2019/Morning Session/11-01-2019
22. The chloride that CANNOT get hydrolysed is : 26. The polymer obtained from the following reactions
is :
(1) SiCl4 (2) SnCl4
(i ) NaNO 2 / H 3O +
NH2 ¾¾¾¾¾¾
(3) PbCl4 (4) CCl4 ®
HOOC (ii ) Polymerisation

Ans. (4) O
H
(1) —C–(CH ) –N—
Sol. CCl4 cannot get hydrolyzed due to the absence of 2 4
n
vacant orbital at carbon atom. O
(2) —O–(CH ) –C—
23. ˆˆ† Y , the
For the chemical reaction X ‡ˆˆ 2 4
n

standard reaction Gibbs energy depends on O O

H
(3) —HNC(CH ) –C–N—
temperature T (in K) as : 2 4
n
O
3 (4) —OC(CH ) O—
Dr Go (in kJ mol–1) = 120 – T 2 4
n
8
Ans. (2)
The major component of the reaction mixture at Sol.
T is : NaNO2 OH

(1) X if T = 315 K
(2) X if T = 350 K
(3) Y if T = 300 K
EN HOOC
NH2
H 3O
+ HOOC

C
Polymerisation

O
n
(4) Y if T = 280 K O

Ans. (1) 27. An example of solid sol is :

(1) Butter (2) Gem stones
LL
24. The freezing point of a diluted milk sample is found (3) Paint (4) Hair cream
to be –0.2°C, while it should have been –0.5°C for Ans. (2)
pure milk. How much water has been added to 28. Peoxyacetyl nitrate (PAN), an eye irritant is
pure milk to make the diluted sample ? produced by :
(1) 2 cups of water to 3 cups of pure milk (1) Acid rain (2) Photochemical smog
(2) 1 cup of water to 3 cups of pure milk (3) Classical smog (4) Organic waste
A

Ans. (2)
(3) 3 cups of water to 2 cups of pure milk
Sol. Photochemical smog produce chemicals such as
(4) 1 cup of water to 2 cups of pure milk
formaldehyde, acrolein and peroxyacetyl nitrate
Ans. (3) (PAN).
29. NaH is an example of :
25. A solid having density of 9 × 103 kg m–3 forms
(1) Electron-rich hydride (2) Molecular hydride
face centred cubic crystals of edge length
(3) Saline hydride (4) Metallic hydride
200 2 pm. What is the molar mass of the Ans. (3)
solid ? Sol. NaH is an example of ionic hydride which is also
known as saline hydride.
(Avogadro constant @ 6 × 1023 mol–1, p @ 3)
30. The amphoteric hydroxide is :
(1) 0.0216 kg mol–1 (2) 0.0305 kg mol–1 (1) Ca(OH)2 (2) Be(OH)2
(3) Sr(OH)2 (4) Mg(OH)2
(3) 0.4320 kg mol–1 (4) 0.0432 kg mol–1
Ans. (2)
Ans. (2) Sol. Be(OH)2 is amphoteric in nature while rest all
alkaline earth metal hydroxide are basic in nature.

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