Environmental Statement for Mahidhara Chemicals Pvt. Ltd. 2009-2010

Environmental Statement for the year 2009-2010
ENVIRONMENTAL STATEMENT
(FORM V)
FOR THE YEAR 2009-2010
Submitted By
M/s. MAHIDHARA CHEMICALS PVT LIMITED

IDA, Phase-l , Patancheru, Medak district,
Andhra Pradesh
September - 2010
Prepared By
SAI LABORATORIES
(Recognized. By MoEF, GOI, New Delhi)
ISO 9001:2008 certified company
Challa Estate, Flat No. 210, Main Road
Erragadda, Hyderabad
Tel: 040-65501128, 23801420, Fax: 040-23814159
Email: sailabecd@gmail.com
Sai Laboratories 1 Mahidhara Chemicals Pvt.ltd

CONTENTS
S.No Contents Page No
1 Preamble 3
2 General Information 7
3 Manufacturing process 8
4 Process Flow Sheet & Material Flow Diagram 9-12
5 Analysis reports 15 - 28
6 Form-V 29 - 34

PREAMBLE
Environmental auditing, now renamed as Environmental Statement, is a tool comprising a
systematic, documented, periodic and objective evaluation of how well a unit is performing in order
to achieve the objective of the waste prevention and reduction, assessing compliance with regulatory
requirements and placing environmental information in public.
The preparation and submission of environmental audit report was mandatory under the
Environment (Protection) Rules, 1986 (second amendment) since March 1992. The industrial units
requiring consent under section 25 of the Water Act were required to submit environmental audit
report for the financial year to the Board on or before the 30th of September every year beginning
from the year 1993.
Environmental Audit is a technique being introduced for integrating the interest of the industry and
the environment so that these could be mutually supportive. This technique is basically a part of
industry’s internal procedures in meeting their responsibilities towards better environment. A
notification under The Environmental (Protection) Rules, 1996 has been issued on April 22, 1993,
requiring industries to submit an environmental statement for the financial year ending on March 31
in Form V to the concerned State Pollution Control Boards on or before September 30 every year
beginning 1993 (Annexure I). The Department of Company Affairs also agreed to include this
requirement as a part of the Director’s Annual Report. The submission on an environmental
statement is applicable to the following.
1. Those who require consent under the Water (Prevention & Control of Pollution) Act, 1974
2. Those who require consent under the Air (Prevention & Control of Pollution) Act, 1981, and
3. Those who require authorization under Hazardous wastes (Management & Handling) Rules,
1989.

BENEFITS OF ENVIRONMENTAL AUDIT:
Benefits of Environmental Audit Environmental auditing have far reaching benefits to the industry,
to the society and the nation at large. It
i) Determines how well the process systems and pollution control systems are performing, and
identifies the operations of poor performance
ii) Identifies potential cost savings which can be accrued through reduction in raw material
consumption by way of waste minimisation, and adoption of recycle/recovery/reduction in
pollution load
iii) Increases awareness of environmental requirements, policies and responsibilities
iv) Helps in understanding the technical capabilities and attitude of the environmental
organisation in a Company
v) Provides up-to-date environmental database for use in plant modification, emergencies etc.
vi) Unravels surprises and hidden liabilities due to which regulatory risk and exposure to
litigation can be reduced
vii) Ensures independent verification, identifies matters needing attention, and provides timely
warning to management on potential future problems and helps to safeguard environment,
and assists in complying with local, regional and national laws and regulations, with the
Company's policy and with the environmental standards.

OBJECTIVES OF ENVIRONMENTAL AUDIT:
OBJECTIVES OF THE ENVIRONMENTAL AUDIT HELPS IN POLLUTION CONTROL, improved production,

safety and health and conservation of natural resources and hence its overall objective can be stated
as achieving of sustainable development. However for conducting environmental audit, objectives
are to be defined clearly, or else the audit procedure will be subject to varying interpretations which
may yield and contribute to differences in approach thereby influencing the end results. The
objectives of environmental audit in an industry are:
i) To determine the mass balance of various materials used and the performance of various
process equipment so as to identify usage of materials in excess than required, to review the
conversion efficiencies of process equipment and accordingly fix up norms for
equipment/performance and minimisation of the wastes.
ii) (a) To identify the areas of water usage and wastewater generation and determine the
characteristics of wastewater; (b) to determine the emissions, their sources, quantities and
characteristics; and (c) to determine the solid wastes and hazardous wastes generated, their
sources, quantities and characteristics.
iii) To identify the possibilities of waste minimisation, and recovery and recycling of wastes
iv) To determine the performance of the existing waste treatment/control systems so as to
modify or install additional or alternative control equipment accordingly
v) To determine the impact on the surrounding environment (groundwater, stream, residential
area, agricultural area, sensitive zone, etc.) due to the disposal of wastewater, emissions and
solid wastes from the industry and accordingly identify suitable preventive measures. If
necessary
vi) To verify compliance with the standards and conditions prescribed by the regulatory bodies
under the Water Act, the Air Act and the Environmental Protection) Act; and

vii) To check the effectiveness of (a) organisational set-up of the industry for decision-making
and environmental management with special reference to their 'technical' view point,
'attitudinal' view point and training, and (b) environmental policy of the Company
viii) Environmental audit helps in assessing the use of raw materials (whether in excess or not)
and various methods to be adopted to recover the same . it also helps in periodical
assessment of the treatment schemes adopted for abatement of various pollutants generated
like wastewater, air and solid waste etc. and to modify the same to achieve better working
efficiency.
ix) Environmental auditing has far reaching benefits to the industry. to the society and the nation
at large. it helps in determining the working efficiencies of process and pollution control
systems. It helps in determining the working effaces of the process and pollution control
systems .it also aids in identifying the cost saving techniques that can be adopted and it
provides an up to date environmental data for use in emergencies. It helps in understanding
the technical capabilities and attitude of an organisation towards pollution control and
increases the awareness of environmental requirements. It ensures independent verification,
identifiesmatters needing urgent attention, provides warnings on potential futures problems
and thus reduces exposure to litigation. It mainly helps in safeguarding the environment and
assists in complying with regulatory norms of local, regional and national laws.
Environmental audit thus in pollution control and in improving production, safety, health ,and
conservation of natural resources.

1.0 GENERAL INFORMATION
M/s. MAHIDHARA CHEMICALS PVT LIMITED is an Chemical plant

Located at IDA, Phase-l , Patancheru, Medak district, Andhra Pradesh.
1.1 RAW MATERIALS

The following raw materials are used in the Mahidhara Chemicals Pvt Limited plant established in
Phase-I, IDA, Patancheru Medak district
S.No Raw materials Previous year (2008-09) Current year (2009-10)

1 Sodium 1.05 Kg 1.03Kgs
2 Parafin oil 1.80 Lts 1.60 Lts
3 Hydrogen gas 0.945m3 0.946m³
4 Ammonia 0.70 Kg 0.60 Kg
5 Sodium 0.30 Kg 0.25 Kg
6 Butanol 2.00 Kg 1.90 Kg
7 Potassium 0.10 Kg 0.10 Kg
1.2 PRODUCTS
S.No Products Quantity

1 Sodium Hydride (Dispersion) 15.0 TPM
2 Sodium Amide 5.0 TPM
3 Sodium Tertiary Butoxide / Potassium Tertiary Butoxide 300.0 Kg/day
4 N-Ethyl piperzine Nil

I. MANUFACTURING PROCESS OF SODIUM HYDRIDE:
A. Raw materials: Sodium metal, Hydrogen Gas in Cylinders, Mineral oil.
B. Manufacturing Process:
Sodium is heated to a temperature of around 180 C to 250 C in a SS reactor containing mineral

oil under nitrogen atmosphere. The heating of the reactor is done with thermic fluid. Once the
required temperature is attained Hydrogen Gas is passed into to the reactor from the cylinder.
When the reaction is completed, the sodium hydride dispersion in oil is cooled and unloaded into
a receiver and then it is packed in polythene bags under nitrogen atmosphere and kept in MS
drums/HDPE drums.
II. MANUFACTURING PROCESS OF SODIUM AMIDE:
A. Raw materials: Sodium metal, liquid ammonia cylinder
B. Manufacturing Process:
Sodium is charged into a MS reactor and the temperature is maintained to 300 C to 350C then
Ammonia gas is passed into the reactor and when the reaction is completed, the mass is
unloaded in to a ball mill and powdered. The powder is packing in polythene bags either 5kgs as
per the requirement of the customers and kept in MS drums. The excess ammonia and hydrogen
are flares in atmosphere.
III. MANUFACTURING PROCESS OF N-ethyl piperazine ;
Piperazine is reacted with diethyl sulfate and sodium hydroxide flakes in presence of toluene
solvent in reactor at a temperature of 80oC for 13 Hours duration. After mono alkylation’s of
piperazine, the reacted material is sent for layer separation by gravity. The aqueous layer
saturated with sodium sulphate is separated here. This sodium sulphate is recovered as by
product and sold to customers. The mass is then transferred to vacuum filter in which toluene is
separated and recycled back to reactor. The organic layer is sent to distillation column where
benzene is separated at low boiling point of 80oC for 4 hours duration by circulating steam .
Further the remaining liquid is fractionally distilled at 150oC by circulating furnace oil to
maintain that temperature for 4 hours time to get the final pure product N-ethyl piperazine in
liquid form.

FLOW SHEET OF N-ETHYL PIPERAZINE
Toluene separated at 80oC, time – 4hrs

initially
I Layer Vacuum
seperation Distillation
ALKYLATION filtration column
Sodium Sulphate mass

As by product
Temperature - 80oC
Reaction time - 13 Hours
Fractional
distillation
N-ethyl piperazine separated at 150oC

Time – 4 hours
I - Caustic flakes
Piperazine
Diethyl sulphate

SODIUM AMIDE
300 Kgs sodium

225 Kgs Ammonia
12.5 Kgs Hydrogen

2.5 Kgs ammonia
Sodium Amide
510 Kgs
10 Kgs
Ammonia solution
SODIUM HYDRIDE
250 Kgs. Sodium

11 Kgs Hydrogen
365 Kgs. Mineral Oil
620Kgs. Of
Sodium Hydride
Dispersion

SODIUM TERTIARY BUTOXIDE/POTASSIUM TERTIARY

BUTOXIDE PROCESS DETAILS
SODIUM : 100 Kgs per day
‘OR’
POTASSIUM : 120 Kgs. Per day
TERTIARY BUTONAL : 300 Kgs. Per day
PROCESS:
Sodium or potassium is added in to excess tertiary butonal in a rotary drier cum reactor. Excess
butonal is used to ensure the complete reaction of the corresponding metals.
Then the excess butonal is recovered by thermic fluid heating through a condenser and used again in
the next batches. A small quantity of hydrogen (1 to 1.5 Kgs. Per batch) is let out through a liquid
paraffin trap.
FLOW CHART
CONDENSOR
REC
EIV
ED
DRYER
CUM
REACTOR
K+C4H9OH C4H9OH+H
POTASSIUM+ TERTIARY BUTANOL POTASSIUM TERTIARY BUTOXIDE

POTASSIUM
60 KGS
+
TERTIARY BUTONAL
225 kGS
TERTIARY BUTOXIDE SOLUTION
150 KGS DRYER

POTASSIUM
TERTIARY BUTOXIDE
SODIUM TERTIARY BUTOXIDE

Na + C4H9OH C4H9OH + H
SODIUM+TERTIARY BUTANOL SODIUM TERTIARY BUTANOL+HYDROGEN
23+74 96+1
SODIUM
50 Kgs
+
T.BUTONAL
Sodium Tertiory
Butoxide
160 Kgs

1.5 WATER CONSUMPTION DETAILS
Water consumption details for plant and for domestic purposes for the period from April 2007 to
March 2008 are as follows.
Water Consumption :
I. Process : NIL
• Cooling : 180
• Domestic : 456
Water Consumption During previous financial year

2008-09 (As per Form-1)
Process Nil
Cooling 180 KL
Domestic 456 KL
Wash Water ---
Boiler Blow Down 46 KL
1.6 Outlet for discharge of effluents:
Outlet Outlet description Max. Daily Point of Disposal

No. Discharge
1 Trade effluents (Washings- 1.58 KLD • Forced Evaporation with in the
0.05 KLD + Boiler Blow premises.
down & Re- generation-0.13 • The condensate first forerun to
KLD + Domestic effluents distillate for recovery of solvents at
after septic tank- 1.40 KLD* on site and reuse.
• The secondary condensate to reuse
for make-up.
*The industry shall stop using the soap pits for final disposal of domestic effluents (1.40 KLD) with
immediate effect and shall force evaporate these effluents along with trade effluents in the existing
FE system.

1.8 AIR POLLUTION CONTROL

A stack height of 40 m has been provided for effective dispersion of SO2 emission into the
atmosphere.
1.9 SOLID WASTE

Forced Evaporation salts
1.10 Emissions from Chimneys:

1.10. (A) D.G. Sets
There are three D.G. sets of (a). 250 KVA
(b).125 KVA
(c). 82.5 KVA in the plant with diesel as fuel.
1.10. (B) Boilers
There is stack attached to Coal Fired Boiler of 0.5 TPH capacity.
1.10. (C) Heaters
There are attached to Thermic Fluid heaters of 3 X 2 Lakh K.Cal/hr capacities.

Flat No.210,Challa Estate,

Erragadda Main Road,
SAI LABORATORIES Hyderabad-500018
(Recognized. By MoEF, GOI, New Delhi) Tel: 040-65501128
Fax: 040-23814159
email: sailaboratories@gmail.com
Web: www.sailabs.in
Date: 20.07.2009
ANALYSIS REPORT
Name of the Industry /Organisation : M/s. Mahidhara Chemicals Pvt. Limited,
Plot No. 18-DII IDA, Patancheru,
Hyderabad-502319
Medak District, A.P.
Report Number : SL/EW/2009/07/50

Sample Description : Effluent Sample
Collected by/Date : Sai /13.07.2010
Date of Analysis : 14.07.2010
Date of Completion : 19.07.2010
S. No Parameters Method Unit Value
1. pH APHA -- 9.65
2. Total Solids APHA mg/l 32,019
3. Total Dissolved Solids at 180 oC APHA mg/l 28,365
4. Suspended Solids at 105oC APHA mg/l 3,654
5. Chemical Oxygen Demand APHA mg/l 1,654
6. Bio - Chemical Oxygen Demand @27oC APHA mg/l 397

for 3 days
7. Oil & Grease APHA mg/l 5.2
For Sai Laboratories,
Authorised Signatory


Fax: 040-23814159
Web: www.sailabs.in
Date: 20.07.2009
ANALYSIS REPORT
Name of the Industry / Organisation: : M/s. Mahidhara Chemicals Pvt. Limited,
Hyderabad-502319

Sample Description : Manjeera Water
CHEMICAL ANALYSIS
S.No Parameter Method Unit Results

1. Colour APHA Hazen Units <5
2. Turbidity APHA NTU <1
3. pH APHA -- 7.36
4. Total Dissolved Solids APHA mg/l 150
5. Phenolphthalein Alkalinity (as Ca Co3) APHA mg/l Nil
6. Total Alkalinity (as Ca Co3) APHA mg/l 62
7. Total Hardness (as Ca Co3) APHA mg/l 104
8. Calcium (as Ca ) APHA mg/l 30
9. Magnesium (as Mg) APHA mg/l 12
10. Iron (as Fe) APHA mg/l BDL
11. Sulphate (as SO4) APHA mg/l 12
12. Chloride (as Cl) APHA mg/l 22
13. Fluoride (as F ) APHA mg/l BDL
14 Nitrate (as NO3) APHA mg/l 3.0
15. Nitrite (as NO2) APHA mg/l BDL
16. Manganese (as Mn) APHA mg/l BDL
BDL: Below detectable level; BDL = 0.01mg/l


Fax: 040-23814159
Web: www.sailabs.in
Date: 20.07.2009
ANALYSIS REPORT
Hyderabad-502319

Sample Description : Bore Water
S.No Parameter Method Unit Results

1. Colour APHA Hazen Units <5
2. Turbidity APHA NTU <1
3. pH APHA -- 7.65
4. Total Dissolved Solids APHA mg/l 1256
5. Phenolphthalein Alkalinity (as Ca Co3) APHA mg/l Nil
6. Total Alkalinity (as Ca Co3) APHA mg/l 95
7. Total Hardness (as Ca Co3) APHA mg/l 253
8. Calcium (as Ca ) APHA mg/l 123
9. Magnesium (as Mg) APHA mg/l 68
10. Iron (as Fe) APHA mg/l Nil
11. Sulphate (as SO4) APHA mg/l 102
12. Chloride (as Cl) APHA mg/l 98
13. Fluoride (as F ) APHA mg/l BDL
14 Nitrate (as NO3) APHA mg/l 9.0
15. Nitrite (as NO2) APHA mg/l BDL
16. Manganese (as Mn) APHA mg/l BDL
BDL: Below detectable level; BDL = 0.01mg/l


Fax: 040-23814159
Web: www.sailabs.in
Date: 20.07.2009
ANALYSIS REPORT
Hyderabad-502319
Report Number : SL/AAQ/2009/07/65

Sample Particulars : Ambient Air Quality Monitoring
Sampling location : Near Plant
Date of Monitoring : 13.07.2010
National
S.No Parameters Method Unit Result Ambient Air
Quality
Standards
for
Residential,
Rural
& Other
areas
1. Suspended Particulate Matter IS 5182 Part-4 1999 µg / m3 153 500
(SPM)
2. Sulphur Dioxide (SO2) IS 5182 Part-2 2001 µg / m3 46 120
3. Oxides Of Nitrogen (Nox) IS 5182 Part-6 2008 µg / m3 20 120
EQUIPMENT DETAILS: MAKE: Aero Vironment Engineers INC

MODEL: RDS APM 460
CALIBRATED ON: 02.04.2009 DUE ON: 01.04.2010


Fax: 040-23814159
Web: www.sailabs.in
Date: 20.07.2009
ANALYSIS REPORT
Hyderabad-502319

Sampling location : Near Admn. office
National
S.No Parameters Method Unit Result Ambient Air
Quality
Standards for
Residential,
Rural
& Other
areas
(SPM)

MODEL: RDS APM 460


Fax: 040-23814159
Web: www.sailabs.in
Date: 20.07.2009
ANALYSIS REPORT
Hyderabad-502319

Sampling location : Near Security
National
Parameters Method Unit Result Ambient Air
S.No Quality
Standards for
Residential,
Rural
& Other
areas
(SPM)

MODEL: RDS APM 460

TABLE
AMBIENT AIR QUALITY STANDARDS
Unit: µg/m 3
Concentration in µg/m3
Category Area
SPM SO2 NOx CO
A Industrial and mixed use 500 120 120 5000
B Residential and Rural 200 80 80 2000
C Sensitive 100 30 30 1000


Fax: 040-23814159
Web: www.sailabs.in
Date: 20.07.2009
ANALYSIS REPORT
Name of the Industry/ Organisation: : M/s. Mahidhara Chemicals Pvt. Limited,
Hyderabad-502319
Report Number : SL/SE/2009/07/21

Sample Particulars : Stack Emission monitoring
Sampling location : Stack attached to Thermic Fluid Boiler
Flue gas Temperature : 1680c
Velocity : 6.02 m/sec
APPCB/CPCB
S.No Parameters Method Unit Result Standards
(mg/Nm3)
1. Suspended Particulate IS 11255Part-I 1985 mg/Nm3 90 115
Matter (SPM)
2. Sulphur Dioxide (SO2) IS 11255Part-2 1985 mg/Nm3 42 800
3. Oxides Of Nitrogen IS 11255Part-7 2005 mg/Nm3 26 600

(NOx)
EQUIPMENT DETAILS: MAKE: Vayubodhan Upakaram

MODEL: VSS – I
Authorized Signatory


Fax: 040-23814159
Web: www.sailabs.in
Date: 20.07.2009
ANALYSIS REPORT
Hyderabad-502319

Sampling location : Stack attached to Coal fired boiler (0.5 MT)
APPCB/CPCB
(mg/Nm3)
Matter (SPM)

(NOx)

MODEL: VSS – I


Fax: 040-23814159
Web: www.sailabs.in
Date: 20.07.2008
ANALYSIS REPORT

Hyderabad-502319

Sampling location : Stack attached to DG set 250 KVA - I
APPCB/CPCB
(mg/Nm3)
1. Suspended IS 11255Part-I 1985 mg/Nm3 102 115
Particulate Matter
(SPM)
2. Sulphur Dioxide IS 11255Part-2 1985 mg/Nm3 82 800
(SO2)
3. Oxides Of IS 11255Part-7 2005 mg/Nm3 36 600
Nitrogen (NOx)

MODEL: VSS – I


Fax: 040-23814159
Web: www.sailabs.in
Date: 20.07.2009
ANALYSIS REPORT
Hyderabad-502319

Sampling location : Stack attached to DG set 125 KVA - II
APPCB/CPCB
(mg/Nm3)
Matter (SPM)

(NOx)

MODEL: VSS – I


Fax: 040-23814159
Web: www.sailabs.in
Date: 20.07.2009
ANALYSIS REPORT
Hyderabad-502319

Sampling location : Stack attached to DG set 82.5 KVA
Flue gas Temperature : 152 0c
APPCB/CPCB
(mg/Nm3)
1. Suspended IS 11255Part-I 1985 mg/Nm3 86 115
Particulate Matter
(SPM)
2. Sulphur Dioxide IS 11255Part-2 1985 mg/Nm3 25 800
(SO2)
3. Oxides Of IS 11255Part-7 2005 mg/Nm3 32 600
Nitrogen (NOx)

MODEL: VSS – I

A. P. POLLUTION CONTROL BOARD'S

STANDARDS FOR STACK EMISSIONS
S. NO. PARTICULARS CONCENTRATION

1. Suspended Particulate Matter (SPM) 115 mg/Nm3
2. Sulphur dioxide (SO2) 800 mg/Nm3
3. Oxides of Nitrogen (NOx) -----


Fax: 040-23814159
Web: www.sailabs.in
Date: 20.07.2009
ANALYSIS REPORT
Name of the Industry /Organisation : M/s. Mahidhara Chemicals Pvt. Limited,
Hyderabad-502319
Report Number : SL/NM/2009/07/25

Sample Particulars : Noise Monitoring
S.No Name of the Location Day Time APPCB Norms

dB Day Time
1. Packing Room 72.5 75dB

2. Open Area 62.6 75dB
3. Near DG Room 74.3 75dB
4. Near Security 62.5 75dB
EQUIPMENT DETAILS: MAKE: CE

MODEL: TES 1350A

[FORM – V]
(See rule 14)
Environmental Statement for the financial year ending the 31st March 2008
PART – A
(i) Name and address of the owner/occupier of the industry operation or process.
Mr R. KIRAN, M.D
M/s. Mahidhara Chemicals Pvt. Ltd.,
18-D 11, Phase-I, Patancheru, Medak (Dt).
(i) Industry category Primary ----(STC code) Secondary.-----(SIC Code)
(ii) Production Capacity Units :
Sodium Hydride (Dispersion) : 15.0 MT/Month

Sodium Amide : 5.0 MT/Month
Sodium Tertiary Butoxide : 4.5 MT/Month
Potassium Tertiary Butoxide : 4.5 MT/Month
N-Ethyl piperzine : 15.0 TPM
IV). Year of Establishment : 1997
(V) Date of the last Environmental : October 2009

Statement submitted

PART – B
Water and Raw Material Consumption
Water Consumption :
I. Process : NIL
• Cooling : NIL
• Domestic : 0.50
.
Water Consumption During previous financial year During current financial year
2008-2009 2009-2010
Process Nil Nil
Cooling 2.0 M3 180 KL
Domestic 1.0 M3 456 KL
Wash Water 0.05 M3 --
Boiler Blow Down 2.0 M3 46 KL
RAW MATERIAL CONSUMPTION:
S.No Raw materials Previous year (2008-2009) Current year (2008-09)

2 Parafin oil 1.80 Lts 1.60 Lts
3 Hydrogen gas 0.945m3 0.945m3
4 Ammonia 0.70 Kg 0.60 Kg
6 Butanol 2.00 Kg 1.9 Kg
7 Potassium 0.10 Kg 0.10 Kg
PRODUCTS:
S.No Products Quantity

1 Sodium Hydride (Dispersion) 15.0 TPM
2 Sodium Amide 5.0 TPM
3 Sodium Tertiary Butoxide / Potassium Tertiary Butoxide 300.0 Kg/day
4 N-Ethyl piperzine 15.0 TPM

PART - C
Pollution discharged to environment/unit of output

(Parameter as specified in the consent issued)
1
1) Pollutants Quantity of pollutants Concentrations of pollutants Percentage of variation

discharged in discharges (mass/volume) from prescribed standards
(mass/day) with reasons
a) Water Reports enclosed Reports enclosed All values are within the
b) Air limits prescribed by A.P.
Pollution Control Board.
a. Water
• pH 6.94-7.20 Waste water generated is sent
• Suspended Solids 250 to reactor and steam is passed
• TDS 6000 to remove water content in it
• Oil & Grease <10 and solid waste is stored
• B.O.D 4200 separately and to TSDF.
• C.O.D 9100
Quantity of pollutants discharged Concentration of pollutants in Percentage of variation from

(mass/day) discharges (2007-2008) prescribed standards with
reasons.
b. Air
1. Particulates (mg/Nm3) 75-98 All values are within the
2. Sulphur Dioxide limits prescribed by
3
(mg/Nm ) 20-35 A.P.Pollution Control Board.
3. Oxides of Nitrogen
(mg/Nm3) 20-35

PART – D
Hazardous Wastes
(As specified under Hazardous Waste Management and Handling Rules, 1989)
Hazardous Wastes with disposal option:
Name of the Quantity of

S.No Hazardous Waste Stream Hazardous Disposal Option
Waste
1 Floor sweepings 34.6 of 300 Kgs/month TSDF Dundigal, Rangareddy
with spillages Schedule-1 District for inceneration
2 Forced Evaporation 34.3 of 8 tons/month TSDF Dundigal, Rangareddy
salts Schedule-1 District for land filling after
stabilization
Hazardous Wastes with recycling option:
Name of the Quantity of

S.No Hazardous Waste Stream Hazardous Disposal Option
Waste
1 Grease and Oil filter 5.1 of 200 Kgs/year Authorized agencies
and Cotton waste Schedule-1
2 Waste mineral oils 5.1 of 320 Lts/year
Schedule-1
3 Containers & 33.3 of 250 After detoxification, it shall
Container liners of Schedule-1 Drums/month be disposed to the outside
Hazardous waste agencies.
and chemicals
4 Used Lead Acid 22 of 2 Nos/year Return to dealer/manufacturer
Batteries Schedule-1 on buy back basis.
5 Aluminum foils 21 of 200 Kgs/year Authorized reprocessors
Schedule-1
HAZARDOUS WASTES
Total Quantity (Kg)
HAZARDOURS WASTES During the previous financial During the current financial
year 2008-09 year 2009-10
1. From Process 1200Kgs 1378.5 Kgs
2. From Pollution Control

Facilities

PART – E
Solid Wastes
Total Quantity During the previous During the current
Solid waste Financial year2008-09 Financial year2009-10
From the process -- --
Forced Evaporation Salts -- 101 Kgs
Quantity recycled or reutilised -- --
*Replaced once in two years with new oil
Total quantity during Total quantity during

Solid waste the previous financial the current financial
year 2008-09 year 2009-10.
a. From the process -- --
b. From pollution control Solid waste 2 MT/month 0.5 MT/month
facilities scales of forced
Evaporation*
Pre-treatment Facility Coal ash 300 Kg 36000 Kg
Sludge
Coal ash
c. Quantity recycled or Nil Nil
reutilized
(a) Form pollution control facility

(1) Quantity recycled or re-utilized
(2) Sold
(3) Disposed: It is collected into tanks and disposed periodically.
PART – F

Please specify the characterizations (in terms of composition of quantum) of hazardous as well
as solid wastes and indicate disposal practice adopted for both these categories of wastes.
1. There is no generation of Hazardous Waste from the process. Hazardous substances like used
thermic Fluid oil generated at the rate of 1000 Lts will be replaced with new oil, sold to
outside agencies, which are authorised by APPCB.
2. There is no generation of Hazardous Waste from the process. Solid waste like forced
Evaporation scales and Pre-treatment facility sludge are kept in HDPE drums separately in
the plant premises. Coal ash will be disposed to local dwellers. The solid waste is sent to
TSDF on regular basis.
PART – G
Impact of the pollution abatement measures taken on conservation of natural resources and
on the cost of production.
Regarding plantation and greenery the management is very keen and already lot of plants planted
and it is a continuous process. Adequate measures are taken to maintain clean environment in and
around the factory. A keen check was put on the consumption of all raw materials, fuels as well as
energy.
PART – H
Additional measures/investment proposal for environmental protection including abatement
of pollution, prevention of pollution.
In the next financial year the management is very keen interest to invert about Rs.30,000/- for
plantation, tree guards and Environment services. The company is planning to go for certification
and ISO 9001-2008.
---------
PART – I
Miscellaneous
Any other particulars in respect of Environment protection and abatement of pollution.
The management objective is to achieve the production without affecting the physical, chemical and
biological environment of the nearby vicinity. The industry has planned different varieties of plants
and keen in the pollution abatement and surrounding environment quality. Industry has planned
variety of trees in the plant premises. The steps taken by management will abate pollution and at the
same time improve the surrounding environment.

Environmental Statement for Mahidhara Chemicals Pvt. Ltd. 2009-2010

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Environmental Statement for Mahidhara Chemicals Pvt. Ltd. 2009-2010

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Environmental Statement for the year 2009-2010

M/s. MAHIDHARA CHEMICALS PVT LIMITED

Sai Laboratories 1 Mahidhara Chemicals Pvt.ltd

S.No Contents Page No

4 Process Flow Sheet & Material Flow Diagram 9-12

Sai Laboratories 2 Mahidhara Chemicals Pvt.ltd

Sai Laboratories 3 Mahidhara Chemicals Pvt.ltd

BENEFITS OF ENVIRONMENTAL AUDIT:

Sai Laboratories 4 Mahidhara Chemicals Pvt.ltd

OBJECTIVES OF ENVIRONMENTAL AUDIT:

OBJECTIVES OF THE ENVIRONMENTAL AUDIT HELPS IN POLLUTION CONTROL, improved production,

Sai Laboratories 5 Mahidhara Chemicals Pvt.ltd

Sai Laboratories 6 Mahidhara Chemicals Pvt.ltd

1.0 GENERAL INFORMATION

M/s. MAHIDHARA CHEMICALS PVT LIMITED is an Chemical plant

1.1 RAW MATERIALS

Phase-I, IDA, Patancheru Medak district

S.No Raw materials Previous year (2008-09) Current year (2009-10)

S.No Products Quantity

Sai Laboratories 7 Mahidhara Chemicals Pvt.ltd

I. MANUFACTURING PROCESS OF SODIUM HYDRIDE:

A. Raw materials: Sodium metal, Hydrogen Gas in Cylinders, Mineral oil.

Sodium is heated to a temperature of around 180 C to 250 C in a SS reactor containing mineral

II. MANUFACTURING PROCESS OF SODIUM AMIDE:

A. Raw materials: Sodium metal, liquid ammonia cylinder

III. MANUFACTURING PROCESS OF N-ethyl piperazine ;

Sai Laboratories 8 Mahidhara Chemicals Pvt.ltd

FLOW SHEET OF N-ETHYL PIPERAZINE

Toluene separated at 80oC, time – 4hrs

Sodium Sulphate mass

Reaction time - 13 Hours

N-ethyl piperazine separated at 150oC

Sai Laboratories 9 Mahidhara Chemicals Pvt.ltd

300 Kgs sodium

12.5 Kgs Hydrogen

250 Kgs. Sodium

Sai Laboratories 10 Mahidhara Chemicals Pvt.ltd

SODIUM TERTIARY BUTOXIDE/POTASSIUM TERTIARY

TERTIARY BUTONAL : 300 Kgs. Per day

Sai Laboratories 11 Mahidhara Chemicals Pvt.ltd

TERTIARY BUTOXIDE SOLUTION

150 KGS DRYER

SODIUM TERTIARY BUTOXIDE

Sai Laboratories 12 Mahidhara Chemicals Pvt.ltd

1.5 WATER CONSUMPTION DETAILS

Water Consumption During previous financial year

1.6 Outlet for discharge of effluents:

Outlet Outlet description Max. Daily Point of Disposal

Sai Laboratories 13 Mahidhara Chemicals Pvt.ltd

1.8 AIR POLLUTION CONTROL

1.9 SOLID WASTE

1.10 Emissions from Chimneys:

Sai Laboratories 14 Mahidhara Chemicals Pvt.ltd

Flat No.210,Challa Estate,

Report Number : SL/EW/2009/07/50

S. No Parameters Method Unit Value

2. Total Solids APHA mg/l 32,019

3. Total Dissolved Solids at 180 oC APHA mg/l 28,365

4. Suspended Solids at 105oC APHA mg/l 3,654

5. Chemical Oxygen Demand APHA mg/l 1,654

6. Bio - Chemical Oxygen Demand @27oC APHA mg/l 397

For Sai Laboratories,