Amcrican Mineralogi,st
Vol 57, pp 281-283 (1972)
Inrnonitcrron
X-ray fluorescence analysisis a widely acceptedtechniquefor ob-
taining rapid chemicalanalysesof geologicsamples.problems have
arisen,however,in samplepreparationthat is fast, reproducibleand
inexpensive,and which producesa durable, long-lived standard or
sample.
claisse (1956) pioneerdthe flux-fusion technique for preparation
of X-ray fluorescencesamples.Subsequentmodifications by Rose,
Adler, and Flanagan (1g62) have been widely adopted. However,
fluorescence samplespreparedby briquetting crushedgrassboulesare
susceptibleto contamination,are subjectto deterioration,and require
finely-machineddies and a laboratory press.A fusedglassdisk sample
preparationhas been describedby Norrish and Hutton (lg6g), but
the writers experienceddifficulty preparing disks that did not crack
upon remoyal from the graphite mold. The writers' proposedtech-
nique is similar to that developedby stephenson(1969), but elimi-
nates the oven annealing processdesignedto relieve stress within
282 MINERALOGICAL NOTES
100.00 wt Percent
Rock samplesare finely ground and mixed with the lithium metabo-
rate flux as follows:
FIux 3'000 g
Powderedrock samPle 0'450 g'
For Na and Mg analysis LiBOz rlisks are fused without heavy
absorber.Here we use a sample-to-LiBOz ratio of 1:1'
/l\ r
I /t\
ON
@@
I
,1, -ln_
p--6Omm-->p-7Omm
50mm----->{
plunger'
Fig. 1. Dimensional view of graphite crucible and
MINERALOGICALNOTES 2{]3
RnrpnoNcns
Cr,erssn,F. (1956) Accurate X-ray fluorescenceanalysis without internal btandard.
QuebecDept. Mines Preli,m.nep.927.
Nonusrr, K. exo J. T. Hurrox (1963) An accurate X-ray spectographic method
for the analysis of a wide range of geological samples. Geoch.hn.Cosmoch'im.
4cta,33,431453.
Rosn, I[. J., f. Anr,en eNl F. J. Fr,er'recew (1g62) Use of LazOe as a heavy ab-
sorber in X-ray fluorescenceanalysis of silisate rocks. U.8. Geol. 9uru., Prof .
Pap. 45v8,80-82.
Srorrrnrsow, D. A. (1969) An improved flux-fusion technique for X-ray emis-
sion analysis.Arnl. Chem.41, 966-967.