Perhitungan

Penentuan Volume Molar Parsial

1) Penentuan Masssa Air

Massa Air = (massa pikno + air) – massa pikno kosong
a. mA = 25,8252 gr - 15,8258 gr = 9,9994 gr
b. mB = 28,4506 gr - 17,9104 gr = 10,5402 gr
c. mC = 22,9690 gr - 13,6401 gr = 9,3289 gr
d. mD = 25,9995 gr - 16,3557 gr = 9,6438 gr
2) Molalitas H2O
mair
n H 2 O=
Mr H 2 O
9,9994
a. n = = 0,5551 mmol
18,0152
10 ,5402
b. n = = 0,5851 mmol
18,0152
9,3289 g
c. n = = 0,5178 mmol
18,0152
9,6438
d. n = = 0,5353 mmol
18,0152
3) Penentuan Massa NaCl
Massa NaCl = (massa pikno + NaCl) – massa pikno kosong

a. m NaCl = 26,9851 gr - 15,8258 gr = 11,1593 gr

b. m NaCl = 29,2021 gr - 17,9104 gr = 11,2917 gr
c. m NaCl = 23,1205 gr - 13,6401 gr = 9,4804 gr
d. m NaCl = 26,3046 gr - 16,3557 gr = 9,9489 gr
4) Volume Air
mair mair
air =  V air =
V air ρ air
9,9994 g
a. V air = =10,0587 ml
0.9941
10,5402 g
b. V air = =10,6028 ml
0.9941
9,3289 g
c. V air = =9,3843 ml
0.9941
9,6438 g
d. V air = =9,7010 ml
0.9941
5) Massa Jenis NaCl
mNaCl
NaCl ¿
V air
 11,1593 gr
a. ρ= =1,1159 gr /ml
10 ml
11,2917 gr
b. ρ= =1,1292 gr /ml
10 ml
9,4804 gr
c. ρ= =0,9480 gr /ml
10 ml
9,9489 gr
d. ρ= =0,9949 gr /ml
10 ml
6) Volume NaCl
m
V NaCl= NaCl
ρNaCl

11,1593 g
a. V= =10 ml
1,1159 g/ml
11,2917 g
b. V = =10 ml
1,1292 g /ml
9,4804 g
c. V = =10 ml
0,9480 g/ml
9,9489 g
d. V = =10 ml
0,9949 g/ml
7) Molalitas NaCl
n NaCl =M × V

a. n = 3 x 10 = 30 mmol
b. n = 1,5 x 10 = 15 mmol
c. n = 0,75 x 10 = 7,5 mmol
d. n = 0,375 x 10 = 3,75 mmol
8) Volume Molar Nyata
1 1000 m ( pikno+ NaCl )−m( pikno+ air)
∅=
ρ NaCl [ Mr NaCl− ×
n NaCl m ( pikno +air )−m( piknokosong ) ]
1 1000 26,9851−25,8252
a. ∅=
1,1159[58,5−
30
×
25,8252−15,8258 ]
=48,9578 ml /mol

1 1000 29,2021−28,4506
b. ∅=
1,1292[58,5−
15
×
19.9663−11.695 ]
= 47,5985 ml/ mol

1 1000 23,1205−22,9690
c. ∅=
0,9480[58,5− ×
7.5 22,9690−13,6401 ]
=59,4223 ml /mol

1 1000 26,3046−25,9995
d. ∅=
0,9949
58,5− [ ×
3.75 25,9995−16,3557
=50,3206 ml /mol ]
9) Volume Molar Parsial NaCl

(M) NaCl ∅ NaCl √ n NaCl

 3 48,9578 5,4772
1.5 47,5985 3,8730
0.75 59,4223 2,7386
0.375 50,3206 1,9365

Grafik hubungan nilai volume molar parsial

NaCl dengan akar dari nilai molalitas NaCL
70
Grafik hubungan nilai
60 volume molar parsial NaCl
50 dengan akar dari nilai
f(x) = − 1.51 x + 56.87 molalitas NaCL
40 R² = 0.19
Ø NaCl

Linear (Grafik hubungan

30 nilai volume molar parsial
NaCl dengan akar dari nilai
20 molalitas NaCL)
10
0
1.5 2 2.5 3 3.5 4 4.5 5 5.5 6
√ n NaCl

∂∅
V NaCl=∅+ √ n NaCl
[ ∂ √n NaCl ]
→ V NaCl=∅+ √ n NaCl ×m

a. = 48,9578 + (5,477 x -1,508) = 40,6982 ml/mol

2
b. = 47,5985 + (3,873 x -1,508) = 41,7580 ml/mol
0
c. = 59,4223 + (2,738 x -1,508) = 55,2925 ml/mol
6
d. = 50,3206 + (1,936 x -1,508) = 47,4004 ml/mol
5

10) Volume Molar Parsial Air

m air 18,0152 mol
V air °=
= =18,221
ρair 0,9941 ml
n NaCl
V air=V air °− √ n NaCl× m
n air
30
a. V air=18,221− × 5,4772× (−1,508 )=464,6064 ml/mol
0 , 555 1
15
b. V air=18,221− ×3,8730 × (−1,508 )=167,9514 ml /mol
0,5851
 7.5
c. V air=18,221− × 2,7386× (−1,508 )=78,0386 ml /mol
0,5178
3.75
d. V air=18,221− × 1,9365× (−1,508 )=38,6785 ml /mol
0,5353