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Perhitungan

Penentuan Volume Molar Parsial

1) Penentuan Masssa Air


Massa Air = (massa pikno + air) – massa pikno kosong
a. mA = 25,8252 gr - 15,8258 gr = 9,9994 gr
b. mB = 28,4506 gr - 17,9104 gr = 10,5402 gr
c. mC = 22,9690 gr - 13,6401 gr = 9,3289 gr
d. mD = 25,9995 gr - 16,3557 gr = 9,6438 gr
2) Molalitas H2O
m air
n H2 O =
Mr H2 O
9,9994
a. n = 18,0152 = 0,5551 mmol
10,5402
b. n = = 0,5851 mmol
18,0152
9,3289 g
c. n = 18,0152 = 0,5178 mmol
9,6438
d. n = 18,0152 = 0,5353 mmol
3) Penentuan Massa NaCl
Massa NaCl = (massa pikno + NaCl) – massa pikno kosong

a. m NaCl = 26,9851 gr - 15,8258 gr = 11,1593 gr


b. m NaCl = 29,2021 gr - 17,9104 gr = 11,2917 gr
c. m NaCl = 23,1205 gr - 13,6401 gr = 9,4804 gr
d. m NaCl = 26,3046 gr - 16,3557 gr = 9,9489 gr
4) Volume Air
mair mair
air =  Vair =
Vair ρair
9,9994 g
a. Vair = = 10,0587 ml
0.9941
10,5402 g
b. Vair = = 10,6028 ml
0.9941
9,3289 g
c. Vair = = 9,3843 ml
0.9941
9,6438 g
d. Vair = = 9,7010 ml
0.9941
5) Massa Jenis NaCl
mNaCl
NaCl = Vair
11,1593 gr
a. ρ= = 1,1159 gr⁄ml
10 ml
11,2917 gr
b. ρ= = 1,1292 gr⁄ml
10 ml
9,4804 gr
c. ρ= = 0,9480 gr⁄ml
10 ml
9,9489 gr
d. ρ= = 0,9949 gr⁄ml
10 ml
6) Volume NaCl
mNaCl
VNaCl =
ρNaCl

11,1593 g
a. V= = 10 ml
1,1159 g/ml
11,2917 g
b. V= = 10 ml
1,1292 g/ml
9,4804 g
c. V= = 10 ml
0,9480 g/ml
9,9489 g
d. V= = 10 ml
0,9949 g/ml
7) Molalitas NaCl
nNaCl = M × V

a. n = 3 x 10 = 30 mmol
b. n = 1,5 x 10 = 15 mmol
c. n = 0,75 x 10 = 7,5 mmol
d. n = 0,375 x 10 = 3,75 mmol
8) Volume Molar Nyata
1 1000 m (pikno + NaCl) − m (pikno + air)
∅= [Mr NaCl − × ]
ρNaCl n NaCl m (pikno + air) − m (pikno kosong)
1 1000 26,9851−25,8252
a. ∅ = [58,5 − × ] = 48,9578 ml/mol
1,1159 30 25,8252−15,8258
1 1000 29,2021−28,4506
b. ∅ = [58,5 − × ] = 47,5985 ml/mol
1,1292 15 19.9663−11.695
1 1000 23,1205−22,9690
c. ∅ = [58,5 − × ] = 59,4223 ml/mol
0,9480 7.5 22,9690−13,6401
1 1000 26,3046−25,9995
d. ∅ = [58,5 − × ] = 50,3206 ml/mol
0,9949 3.75 25,9995−16,3557
9) Volume Molar Parsial NaCl
(M) NaCl ∅ NaCl √n NaCl
3 48,9578 5,4772
1.5 47,5985 3,8730
0.75 59,4223 2,7386
0.375 50,3206 1,9365
Grafik hubungan nilai volume molar
parsial NaCl dengan akar dari nilai
molalitas NaCL
80 y = -1.5089x + 56.865
R² = 0.1876
60
Ø NaCl

Grafik hubungan nilai


40
volume molar parsial
20 NaCl dengan akar dari
nilai molalitas NaCL
0
0 2 4 6
√ n NaCl

∂∅
V NaCl = ∅ + √n NaCl [ ] → V NaCl = ∅ + √n NaCl × m
∂√n NaCl

a. = 48,9578 + (5,4772 x -1,508) = 40,6982 ml/mol


b. = 47,5985 + (3,8730 x -1,508) = 41,7580 ml/mol
c. = 59,4223 + (2,7386 x -1,508) = 55,2925 ml/mol
d. = 50,3206 + (1,9365 x -1,508) = 47,4004 ml/mol

10) Volume Molar Parsial Air


m air 18,0152 mol
V air° =
= = 18,221
ρair 0,9941 ml
n NaCl
V air = V air° − √n NaCl × m
n air
30
a. V air = 18,221 − 0,5551 × 5,4772 × (−1,508) = 464,6064 ml/mol
15
b. V air = 18,221 − × 3,8730 × (−1,508) = 167,9514 ml/mol
0,5851
7.5
c. V air = 18,221 − × 2,7386 × (−1,508) = 78,0386 ml/mol
0,5178
3.75
d. V air = 18,221 − × 1,9365 × (−1,508) = 38,6785 ml/mol
0,5353