Stoichiometery MCQS

(A)
1. CaCO3 contains __________ percent of Ca by weight.
A. 40 B. 48
C. 96 D. 12
Answer & Explanation
Answer: Option A
Explanation:
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2. Solutions which distil without change in composition are called
A. ideal B. saturated
C. supersaturated D. azeotropic
Answer: Option D
Explanation:
3. Gases having same reduced temperatures and reduced pressures
A. deviate from ideal gas behaviour to the same degree.
B. have nearly the same compressibility factor.
C. both (a) and (b).
D. neither (a) nor (b).
Answer: Option C
Explanation:
4. Which of the following is not a unit of pressure ?
A. Torr
B. Newton/m2
C. Parsec
D. Ata, bar or pascal
Answer: Option C
Explanation:
5. The evaporation of aqueous solution of sugar causes its molarity to
A. decrease. (b) increase.
B. remain unchanged.
C. either (a) or (b); depends on the concentration of the solution.
Answer: Option B
(B)
1. One mole of methane undergoes complete combustion in a stoichiometric amount of air. The
reaction proceeds as CH4 + 2O2 → CO2 + 2H2O. Both the reactants and products are in gas phase.
ΔH°298 = - 730 kJ/mole of methane. Mole fraction ofwater vapour in the product gases is about
A. 0.19 B. 0.33
C. 0.40 D. 0.67

Answer: Option A
Explanation:
2. Volume percent for gases is equal to the
A. weight percent.
B. mole percent.
C. weight percent only for ideal gases.
D. mole percent only for ideal gases.
Answer: Option D
Explanation:
3. Compressibility factor of a real gas is the ratio of the actual volume to that predicted by ideal gas
law. As the pressure of the gas approaches zero, the compressibility factor approaches
A. ∞ B. 0
C. 1 D. 0.24
Answer: Option C
Explanation:
4. Cp equals Cv at
A. 0°C B. 0°K
C. 0°F D. 0°R
Answer: Option B
Explanation:
5. Pick out the wrong statement.
A. The evaporation of aqueous solution of glucose causes its molarity to increase.
Both the freezing point as well as boiling point of sea water is more than that of
B.
distilled water.
The solution containing equal masses of two liquids 'X' and 'Y' has the same mole
C.
fraction of' 'X' and 'Y'.
D. both (b) and (c)
Answer: Option D
(C)
1. Which of the following is insensitive to changes in pressure ?
A. Heat of vaporisation
B. Melting point
C. Heat of fusion
D. Both (b) and (c)
Answer: Option D
Explanation:
2. The heat capacity of a solid compound is calculated from the atomic heat capacities of its
constituent elements with the help of the
A. Trouton's rule
B. Kopp's rule
C. Antonie equation
D. Kistyakowsky equation
Answer: Option B
Explanation:
3. How many phases are present at eutectic point ?
A. 1 B. 2
C. 3 D. unpredictable
Answer: Option C
Explanation:
4. The increase in the temperature of the aqueous solution will result in decrease of its
A. weight % of the solute.
B. mole fraction of the solute.

C. molarity.
D. molality.
Answer: Option C
Explanation:
5. Which of the following gases is the most soluble in water ?
A. NH3 B. CO2
C. H2S D. CH4
Answer: Option A
(D)
1. In a binary liquid system, the composition expressed as __________ is independent of the

temperature & pressure.
A. kg of solute/kg of solvent
B. kg-mole of solute/kg-mole of solvent
C. kg-mole of solute/1000 kg of solvent
D. all (a), (b) & (c)
Answer: Option D
Explanation:
2. A sugar solution containing __________ percent sugar is equivalent to 1 Brix.

A. 0.01 B. 0.1
C. 1 D. 10
Answer: Option C
Explanation:
3. __________ equation gives the effect of temperature on heat of reaction.
A. Kirchoffs B. Maxwell's
C. Antonie D. Kistyakowsky
Answer: Option A
Explanation:
4. Which of the following has the smallest least effect on the solubility of a solute into the solvent ?
A. Nature of the solute
B. Nature of the solvent
C. Temperature
D. Pressure
Answer: Option D
Explanation:
5. 1 Kcal/kg. °C is equivalent to __________ BTU/lb. °F.
A. 1
B. 2.42
C. 4.97
D. none of these
Answer: Option A
(E)
1. No cooling occurs, when an ideal gas undergoes unrestrained expansion, because the molecules
A. collide without loss of energy.
B. do work equal to loss in kinetic energy.
C. are above the inversion temperature.
D. exert no attractive force on each other.
Answer: Option C
Explanation:
2. With increase in the solute concentration, the specific heat of aqueous solutions
A. increases
B. decreases
C. remains unchanged
D. either (a) or (b); depends on the type of solution
Answer: Option B
Explanation:
3. The heat capacity of a substance is
A. greater for liquid state than for solid state.
B. lower for liquid state than for gaseous state.
C. higher for solid state than for liquid state.
D. equal for solid and liquid states below melting point.
Answer: Option A
Explanation:
4. The heat of solution depends upon the
A. nature of solvent
B. concentration of solution
C. nature of solute
D. all (a), (b) & (c)
Answer: Option D
Explanation:
5. The molar composition of a gas is 10% H2, 10% O2, 30% CO2 and balance H2O. If 50% H2O
condenses, the final mole percent of H2 in the gas on a dry basis will be
A. 10% B. 5%
C. 18.18% D. 20%
Answer: Option D
(F)
1. The heats of vaporisation of CS2, C2H5OH &H2O are 26.8, 38.6 & 40.6 KJ/kg mole respectively.
The order of decreasing inter-molecular forces in these liquids is
A. H2O > C2H5OH > CS2
B. CS2 > C2H5OH > H2O
C. H2O > CS2 > C2H5OH
D. CS2 > H2O > C2H5OH
Answer: Option A
Explanation:
2. A liquid is in equilibrium with its vapor at its boiling point. On an average, the molecules in the
liquid and gaseous phases have equal
A. kinetic energy.
B. intermolecular forces of attraction.
C. potential energy.
D. total energy.
Answer: Option A
Explanation:
3. Pure aniline is evaporating through a stagnant air film of 1 mm thickness at 300 K and a total
pressure of 100 KPa. The vapor pressure of aniline at 300 K is 0.1 KPa. The total molar
concentration under these conditions is 40.1 mole/m3 . The diffusivity of aniline in air is 0.74xl0-
5 2
m /s.The numerical value of mass transfer co-efficient is 7.4 x 10-3. Its units are
A. m/s B. cm/s
C. mole/m2.s.Pa D. kmole/m2.s.Pa
Answer: Option C
Explanation:
4. If 1.5 moles of oxygen combines with aluminium to form Al2O3, then the weight of aluminium
(atomic weight = 27 ) used in this reaction is __________ gm.
A. 27 B. 54
C. 5.4 D. 2.7
Answer: Option B
Explanation:

5. The unit of dynamic viscosity is
A. stoke
B. poise
C. gm/cm sec.
D. both (b) & (c)
Answer: Option D
(G)
1. One kg of saturated steam at 100°C and 1.01325 bar is contained in a rigid walledvessel. It lias a
volume of 1.673 m3. It cools to 98°C ; the saturation pressure is 0.943 bar ; one kg
of water vapour under these conditions has a volume of 1.789 m3. The amount of water vapour
condensed (in kg) is
A. 0.0 B. 0.065
C. 0.1 D. 1.0
Answer: Option B
Explanation:
2. Which of the following holds good for a solution obeying Raoult's law (i.e., an ideal solution)
(where, ΔH = heat of mixing, and ΔV = volume change on mixing ) ?
A. ΔH = 1 (+ ve)and Δ V = -ve
B. ΔH = 0
C. ΔV = 0
D. both (b) and (c)
Answer: Option D
Explanation:
3. Which equation is not an equation of state ?
A. PV = RT + B/V + y/V2 + ....
B. (P + a/V2)(V-b) = RT
C.
D.
Answer: Option C
Explanation:
4. Number of gm moles of solute dissolved in 1 kg of solvent is called its
A. normality B. molarity
C. molality D. formality
Answer: Option C
Explanation:
5. Size range of the colloidals particles is

A. 5 - 200 milli-microns
B. 50 - 200 microns
C. 500 - 1000 microns
D. 10 - 50 Angstrom
Answer: Option A
(H)
1. Colligative properties of a dilute solution are those which depend entirely upon the
A. constitution of the solute.
B. chemical composition of the solute.
C. number of solute molecules contained in a given volume of the solvent.
D. none of these.
Answer: Option A
Explanation:
2. For an ideal solution, the total vapor pressure varies __________ with thecomposition(expressed
as mole fraction).
A. inversely B. exponentially
C. linearly D. negligibly
Answer: Option C
Explanation:
3. Pick out the wrong statement.

Atomic heat capacities of the crystalline solid elements are nearly constantand equal to
A.
6.2 kcal/kg-atom according to the law of Petit and Dulong.
Atomic heat capacities of all solid elements decrease greatly with decrease in
B. temperature, approaching a value of zero at absolute zero temperature, when in the
crystalline state.
Generally, the heat capacities of compounds are lower in the liquid than in the solid
C.
state.
The heat capacity of a heterogeneous mixture is an additive property, but when

D.
solutions are formed, this additive property may no longer exist.
Answer: Option C
Explanation:
4. Measurement of the amount of dry gas collected over water from volume of moist gas is based on
the
A. Charle's law.
B. Dalton's law of partial pressures.
C. Avogadro's hypothesis.
D. Boyle's law.
Answer: Option B
Explanation:

5. In physical adsorption, as compared to chemisorption, the
A. quantity adsorbed per unit mass is higher.
B. rate of adsorption is controlled by the resistance to surface reaction.
C. activation energy is very high.
D. heat of adsorption is very large.
Answer: Option A

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(A)

1. CaCO3 contains __________ percent of Ca by weight.

Answer & Explanation

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2. Solutions which distil without change in composition are called

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3. Gases having same reduced temperatures and reduced pressures

A. deviate from ideal gas behaviour to the same degree.

B. have nearly the same compressibility factor.

C. both (a) and (b).

D. neither (a) nor (b).

Answer & Explanation

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4. Which of the following is not a unit of pressure ?

D. Ata, bar or pascal

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5. The evaporation of aqueous solution of sugar causes its molarity to

A. decrease. (b) increase.

C. either (a) or (b); depends on the concentration of the solution.

Answer & Explanation

Answer & Explanation

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2. Volume percent for gases is equal to the

C. weight percent only for ideal gases.

D. mole percent only for ideal gases.

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Answer & Explanation

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5. Pick out the wrong statement.

A. The evaporation of aqueous solution of glucose causes its molarity to increase.

D. both (b) and (c)

Answer & Explanation

1. Which of the following is insensitive to changes in pressure ?

D. Both (b) and (c)

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3. How many phases are present at eutectic point ?

Answer & Explanation

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A. weight % of the solute.

B. mole fraction of the solute.

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5. Which of the following gases is the most soluble in water ?

Answer & Explanation

1. In a binary liquid system, the composition expressed as __________ is independent of the