This experiment was carried out to determine the identities of five colourless solutions to
which labels were given to match to each individual bottle. The method of qualitative analysis
was used to identify the solutions using simple tests involving reagents that were provided.
Variables:
The method of qualtitative analysis was carried out in this experiment to determine the
identity of five colourless solutions in which the labels have fallen off. Reagents were provided
to aid in the investigation. Tollen’s reagent, sodium bicarbonate powder and acidified potassium
permanganate were the reagents given. The labels which dropped off had written on them
ethanol, 2-methyl-2-propanol, ethanal, propanone and acetic acid. All of which are classified
Background theory:
Ethanol and 2-Methyl-propanol are both categeorized as alcohol group species. The
difference between the two is that ethanol is a primary alcohol whereas 2-Methyl-propanol is a
tertiary alcohol. Generally, alchohols are compounds in which one or more hydrogen atoms in an
alkane have been replaced by an –OH group. Primary (1°) alcohols, the carbon which carries the
–OH group has only one alkyl group attached to it. For example:
𝐶𝐻3 − 𝐶𝐻2 − 𝑂𝐻
Ethanol
Tertiary alcohols however, have three alkyl groups attached to the carbon carrying the –OH
which was provided to oxidize the alcohols. When added to ethanol which is a primary (1°)
alcohol, a colour change from purple to brown is observed. The colour change can be attributed
to the reduction of Mn7+ to Mn2+ in acidic condition. Partial oxidation occurs where an aldehyde
is formed. This outcome can only be achieved with excess amount of primary (1°) alcohol added.
The excess of alcohol means that there isn’t enough oxidizing agent present to carry out the
Tertiary alcohols have no reaction when acidified potassium permanganate is added. This
happens due to the lack of hydrogen atom attached to the carbon linked to the –OH group. In a
primary alcohol, the oxidizing agent is removing the hydrogen from the carbon atom attached to
the –OH group. The lack of which in a tertiary alcohol results in no reaction occuring.
To further conclude the findings and observations recorded, tollen’s reagent is added to both the
ethanol and 2-Methyl-propanol after being oxidized by the acidified potassium permanganate.
The primary (1°) alcohol would produce an aldehyde which will undergo a visible colour change
from brown to grey with precipitate. An aldehyde is a simple compound which contains a
carbonyl group (a carbon-oxygen double bond) that has a hydrogen atom attached to it with
either a second hydrogen atom or a hydrocarbon group like an alkyl. An example would be
reduced by aldehyde to produce metallic silver which results in the grey precipitate produced.
𝐴𝑔(𝑁𝐻3 )2 + 𝑒 − → 𝐴𝑔 + 2𝑁𝐻3
2𝐴𝑔(𝑁𝐻3 )+ −
2 + 𝑅𝐶𝐻𝑂 → 2𝐴𝑔 + 𝑅𝐶𝑂𝑂 + 4𝑁𝐻3 + 2𝐻2 𝑂
Tertiary alcohol in this case would not react with tollen’s reagent having unable to be oxidized
Moving on, one of the fallen labels had acetic acid written on it. Acetic acid can be grouped
under the organic compound branch of carboxylic acids. A carboxylic acid is a compound which
contains a –COOH group which is attached either to a hydrogen atom or to an alkyl group.
*ethanoic acid is also known as acetic acid.
To identify which one of the five unkown colourless solutions is acetic acid, sodium carbonate is
used. Theoretically, when a metal carbonate is added to a carboxylic acid; carbon dioxide, CO2
Propanone is classified under the organic compound group of ketones. Ketones are carbonyl
group compounds that have two hydrocarbon groups attached to it. They never have hydrogen
atoms attached to the carbonyl group which makes it distinct from aldehydes.
Aldehydes and ketones being nearly similar having carbonyl groups are distinguishable via the
addition of Tollen’s reagent as mentioned above. Ketones do not have any hydrogen atom
1. A sample of each one of the five unknown colourless solutions is put into five test tubes
2. A warm water bath is set up using a beaker half-filled with water placed on top of a
tripod stand with wire gauze which is then heated with a bunsen burner.
3. Three drops of tollen’s reagent were then added to test tubes labelled from A to D.
4. After that, all of the test tubes were put into the warm water bath to speed up the rate of
reaction.
5. Any changes in physical appearance and reactions were then recorded down.
Raw data
Analysis of data
alcohol, ethanol since it reacts with acidified potassium permanganate to produce a colour
change from purple to brown. The resulting brown solution formed an aldehyde as the alcohol
was oxidised. Tollen’s reagent was then added to the mixture and a grey precipitate was formed.
The grey precipitate formed was in fact silver metal as a result of the Diamminesilver(I) ion
being oxidised by the aldehyde produced. When Sodium bicarbonate was added to D, it
produced a brisk effervesence which was not observed in the other four samples. This
observation is in line with the reaction of metal carbonates with acids where in which carbon
dioxide gas is produced. Sample D can be then said to be acetic acid. Finally, the last sample E
reacted with tollen’s reagent to produce a grey precipitate which then confirmed it to be the
aldehyde propanal.
Lastly, the remaining two labels are that of ketone and tertiary alcohol species. The
challenging part arises when both of the samples do not exhibit any significant chemical reaction
that differs them from each other when tested with all three available reagents. A suggestion
yield an observation of a bright orange or yellow precipitate. The test is mainly to prove the
When added to tertiary alcohols, a similar condensation reaction occurs but no visible
The findings of the experiment can be summarized into a table as shown below:
Sample Label
C Ethanol
D Acetic acid
E Propanal
Discussion:
1. The concentration of the unkown colourless solutions may have been too low to
observe a silver mirror when tollen’s reagent was added and the test tube was left
2.
Reference list:
March 2018)
2018)
https://www.masterorganicchemistry.com/2010/06/16/1%C2%B0-2%C2%B0-3%C2%B0-