Acido Nitrico

{
Unit System:
- Mass Flow (Kg/s)

- Temperature (°C)
- Pressure (KPa)
- Electric/Energy Rate (KW)
- Enthalpy (KJ/Kg)
- Entropy (KJ/Kg-K)
- Flow Exergy (KJ/Kg)
- Fuel Exergy (KW)
- Products Exergy (KW)
- Destroyed Exergy (KW)
{
h_ST_Outs=enthalpy(Steam_IAPWS,s=s_ST_In, T=T_ST_Out)
h_2_2s=enthalpy(Air_ha,s=s_2_1,P=P_2_2)
h_3s=enthalpy(Air_ha,s=s_2_5,P=P_3)
h_2_4s=enthalpy(Air_ha,s=s_2_4,P=P_2_4)
h_23s=Fm_O2_23*enthalpy(O2,s=s_22,P=Fn_O2_23*P_23)+Fm_N2_23*enthalpy(N2,s=s_22,P=F
n_O2_23*P_23) + Fm_NO_23*Enthalpy(NO,s=s_22,P=Fn_O2_23*P_23) +
Fm_Steam_23*enthalpy(Steam_IAPWS,s=s_22,P=Fn_Steam_23*P_23)
eta_ST=(h_ST_In-h_ST_Outs)/(h_ST_In-h_ST_Out)
eta_HPC=(h_2_2-h_2_1)/(h_2_2s-h_2_1)
eta_LPC1=(h_2_4-h_2_2)/(h_2_4s-h_2_3)
eta_LPC2=(h_3-h_2_5)/(h_3s-h_2_5)
eta_EXP=(h_22-h_23)/(h_22-h_23s)
eta_CONV=(m_dot_6*h_6+m_dot_7*h_7+m_dot_21*h_21)/(m_dot_8*h_8+m_dot_22*h_22)
eta_AH=(m_dot_8*h_8-m_dot_9*h_9)/(m_dot_6*h_6-m_dot_4*h_4)
eta_HRSG=(m_dot_9*h_9-m_dot_10*h_10) /(m_dot_FWout_HRSG*h_FWout_HRSG-
m_dot_FWin_HRSG*h_FWin_HRSG)
eta_TGH=(m_dot_11*h_11-m_dot_12*h_12)/(m_dot_21*h_21-m_dot_20*h_20)
eta_TGTH=(m_dot_Steam_TGTH*h_Steam_TGTH- m_dot_Cond_TGTH*h_Cond_TGTH
)/(m_dot_20*h_20-m_dot_16*h_16)
eta_COND=(m_dot_13*h_13+ m_dot_14*h_14 +
m_dot_CWout_CC*h_CWout_CC)/(m_dot_12*h_12+m_dot_CWin_CC*h_CWin_CC)
eta_ABS=-(m_dot_16*h_16 + m_dot_CWout_ABS*h_CWout_ABS+
m_dot_19*h_19)/(m_dot_13*h_13+m_dot_14*h_14+m_dot_15*h_15+m_dot_CWin_ABS*h_CWin_
ABS+ m_dot_5*h_5)
}
"ADDITIONAL INFORMATION"
"Universal Constant Of Gases (KJ/Kmol-K)"

R=8.31434
"Temp. And Pressure - Dead State"

T_0=25
P_0=101.325
"Chemical Exergy - Components Flows (J/mol)"
Psi_Chem_O2=3.97*1000
Psi_Chem_N2=0.72*1000
Psi_Chem_H2O=0.9*1000
Psi_Chem_NO=88.9*1000
Psi_Chem_HNO3=43.5*1000
Psi_Chem_Steam=9.5*1000
Psi_Chem_NH3=336.6*1000
"Flow - Steam Turbine"
T_ST_In=280.556
T_ST_Out=55.556
P_ST_In=1618.1995
P_ST_Out=24.8211
m_dot_ST=3.7799
h_ST_In=enthalpy(Steam_IAPWS,T=T_ST_In,P=P_ST_In)
s_ST_In=entropy(Steam_IAPWS,T=T_ST_In,P=P_ST_In)
h_ST_Out=enthalpy(Steam_IAPWS,T=T_ST_Out, P=P_ST_Out)
s_ST_Out=entropy(Steam_IAPWS,T=T_ST_Out,P=P_ST_Out)
h_ST_0=enthalpy(Steam_IAPWS,T=T_0,P=P_0)
s_ST_0=entropy(Steam_IAPWS,T=T_0,P=P_0)
Psi_ST_In=h_ST_In-h_ST_0-(T_0+273.15)*(s_ST_In-s_ST_0)
Psi_ST_Out=h_ST_Out-h_ST_0-(T_0+273.15)*(s_ST_Out-s_ST_0)
"Flow 2 - (Inlet Air) Compressor Stages"
T_2_1=32.611
T_2_2=100.389
T_2_3=35.667
T_2_4=108.278
T_2_5=38.111
T_3=172.111
P_2_1=99.97
P_2_2=212.74
P_2_3=212.74
P_2_4=453.72
P_2_5=453.72
P_3=963.39
h_2_1=enthalpy(Air_ha,T=T_2_1,P=P_2_1)
h_3=enthalpy(Air_ha,T=T_3,P=P_3)
h_0=enthalpy(Air_ha,T=T_0,P=P_0)
s_2_1=entropy(Air_ha,T=T_2_1,P=P_2_1)
s_3=entropy(Air_ha,T=T_3,P=P_3)
s_0=entropy(Air_ha,T=T_0,P=P_0)
Psi_2_1=h_2_1 - h_0 - (T_0+273.15)*(s_2_1 - s_0)

Psi_2_2=h_2_2 - h_0 -(T_0+273.15)*(s_2_2 - s_0)
Psi_2_3=h_2_3 - h_0 - (T_0+273.15)*(s_2_3 - s_0)
Psi_2_4=h_2_4 - h_0 - (T_0+273.15)*(s_2_4 - s_0)
Psi_2_5=h_2_5 - h_0 - (T_0+273.15)*(s_2_5 - s_0)
Psi_3=h_3 - h_0 - (T_0+273.15)*(s_3 - s_0)
"Flow 4 - Process Air"
T_4= 184.444
P_4=949.408
m_dot_4=19.38956
Fm_O2_4=0.23034
Fm_N2_4=0.75858
Fm_Steam_4=0.01109
Fn_O2_4=0.20629
Fn_N2_4=0.77607
Fn_Steam_4=0.01764
h_4=Fm_O2_4*enthalpy(O2,T=T_4)+Fm_N2_4*enthalpy(N2,T=T_4)+Fm_Steam_4*enthalpy(Stea
m_IAPWS,T=T_4,P=Fn_Steam_4*P_4)
s_4=Fm_O2_4*entropy(O2,T=T_4,P=Fn_O2_4*P_4)+Fm_N2_4*entropy(N2,T=T_4,P=Fn_N2_4*P
_4)+Fm_Steam_4*entropy(Steam_IAPWS,T=T_4,P=Fn_Steam_4*P_4)
h_4_0=Fm_O2_4*enthalpy(O2,T=T_0)+Fm_N2_4*enthalpy(N2,T=T_0)+Fm_Steam_4*enthalpy(Ste
am_IAPWS,T=T_0,P=Fn_Steam_4*P_0)
s_4_0=Fm_O2_4*entropy(O2,T=T_0,P=Fn_O2_4*P_0)+Fm_N2_4*entropy(N2,T=T_0,P=Fn_N2_4*
P_0)+Fm_Steam_4*entropy(Steam_IAPWS,T=T_0,P=Fn_Steam_4*P_0)
Psi_4=h_4-h_4_0-(T_0+273.15)*(s_4-s_4_0)
Psi_Chem_4=(Fn_O2_4*Psi_Chem_O2+Fn_N2_4*Psi_Chem_N2+Fn_Steam_4*Psi_Chem_Steam
+
R*(T_0+273.15)*(Fn_O2_4*LN(Fn_O2_4)+Fn_N2_4*LN(Fn_N2_4)+Fn_Steam_4*LN(Fn_Steam_4)
))/(Fn_O2_4*Molarmass(O2)+Fn_N2_4*Molarmass(N2)+Fn_Steam_4*Molarmass(Steam))
"Flow 5 - Bleach Air"
T_5=121.111
P_5=956.303
m_dot_5=2.65452
Fm_O2_5=0.23035
Fm_N2_5=0.75859
Fm_Steam_5=0.01106
Fn_O2_5=0.20631
Fn_N2_5=0.77601
Fn_Steam_5=0.01768
Psi_5=h_5-h_5_0-(T_0+273.15)*(s_5-s_5_0)
"Flow 6 - Converter Air"
T_6=306.667 [C]
P_6=928.724 [kPa]
m_dot_6=19.38956 [kg/s]
Fm_O2_6=0.23034
Fm_N2_6=0.75858
Fm_Steam_6=0.01109
Fn_O2_6=0.20629
Fn_N2_6=0.77607
Fn_Steam_6=0.01764
Psi_6=h_6-h_6_0-(T_0+273.15)*(s_6-s_6_0)
Psi_Chem_6=(Fn_O2_6*Psi_Chem_O2+Fn_N2_6*Psi_Chem_N2+Fn_Steam_6*Psi_Chem_Steam
+
R*(T_0+273.15)*(Fn_O2_6*LN(Fn_O2_6)+Fn_N2_6*LN(Fn_N2_6)+Fn_Steam_6*LN(Fn_Steam_6)
))/(Fn_O2_6*Molarmass(O2)+Fn_N2_6*Molarmass(N2)+Fn_Steam_6*Molarmass(Steam))
"Flow 7 - Vapor Ammonia"
T_7=63.889 [C]
P_7=1307.935 [kPa]
m_dot_7=1.22470 [kg/s]
Fm_Steam_7=0.00504
Fm_NH3_7=0.99496
Fn_Steam_7=0.00473
Fn_NH3_7=0.99527
h_7=Fm_Steam_7*enthalpy(Steam_IAPWS,T=T_7,P=Fn_Steam_7*P_7) +
Fm_NH3_7*enthalpy(Ammonia,T=T_7,P=Fn_NH3_7*P_7)
s_7=Fm_Steam_7*entropy(Steam_IAPWS,T=T_7,P=Fn_Steam_7*P_7) +
Fm_NH3_7*entropy(Ammonia,T=T_7,P=Fn_NH3_7*P_7)
h_7_0=Fm_Steam_7*enthalpy(Steam_IAPWS,T=T_0,P=Fn_Steam_7*P_0)+Fm_NH3_7*enthalpy(
Ammonia,T=T_0,P=Fn_NH3_7*P_0)
s_7_0=Fm_Steam_7*entropy(Steam_IAPWS,T=T_0,P=Fn_Steam_7*P_0)+Fm_NH3_7*entropy(A
mmonia,T=T_0,P=Fn_NH3_7*P_0)
Psi_7=h_7-h_7_0-(T_0+273.15)*(s_7-s_7_0)
Psi_Chem_7=(Fn_Steam_7*Psi_Chem_Steam + Fn_NH3_7*Psi_Chem_NH3 +
R*(T_0+273.15)*(Fn_Steam_7*LN(Fn_Steam_7)+Fn_NH3_7*LN(Fn_NH3_7)))/(Fn_Steam_7*Molar
mass(Steam)+Fn_NH3_7*Molarmass(NH3))
"Flow 8 - Process Gas"
T_8= 649.444 [C]

P_8=880.461 [kPa]
m_dot_8=20.61426 [kg/s]
Fm_O2_8=0.08227
Fm_N2_8=0.71740
Fm_NO_8=0.09581
Fm_Steam_8=0.10451
Fn_O2_8=0.06434
Fn_N2_8=0.69245
Fn_NO_8=0.08634
Fn_Steam_8=0.15687
h_8=Fm_O2_8*enthalpy(O2,T=T_8)+Fm_N2_8*enthalpy(N2,T=T_8) +
Fm_NO_8*Enthalpy(NO,T=T_8) +
Fm_Steam_8*enthalpy(Steam_IAPWS,T=T_8,P=Fn_Steam_8*P_8)
_8) +Fm_NO_8*Entropy(NO,T=T_8,P=Fn_NO_8*P_8) +
Fm_Steam_8*entropy(Steam_IAPWS,T=T_8,P=Fn_Steam_8*P_8)
h_8_0=Fm_O2_8*enthalpy(O2,T=T_0)+Fm_N2_8*enthalpy(N2,T=T_0) +
P_0) +Fm_NO_8*Entropy(NO,T=T_0,P=Fn_NO_8*P_0) +
Psi_8=h_8-h_8_0-(T_0+273.15)*(s_8-s_8_0)
Psi_Chem_8=(Fn_O2_8*Psi_Chem_O2 + Fn_N2_8*Psi_Chem_N2 + Fn_NO_8*Psi_Chem_NO +

Fn_Steam_8*Psi_Chem_Steam +
R*(T_0+273.15)*(Fn_O2_8*LN(Fn_O2_8)+Fn_N2_8*LN(Fn_N2_8)+Fn_NO_8*LN(Fn_NO_8)+Fn_
Steam_8*LN(Fn_Steam_8)))/(Fn_O2_8*Molarmass(O2) + Fn_N2_8*Molarmass(N2) +
Fn_NO_8*Molarmass(NO) + Fn_Steam_8*Molarmass(Steam))

T_9= 555 [C]
P_9=859.776 [kPa]
m_dot_9=20.61426 [kg/s]
Fm_O2_9=0.07410
Fm_N2_9=0.71740
Fm_NO_9=0.10399
Fm_Steam_9=0.10451
Fn_O2_9=0.06271
Fn_N2_9=0.69366
Fn_NO_9=0.08649
Fn_Steam_9=0.15714
_9) +Fm_NO_9*Entropy(NO,T=T_9,P=Fn_NO_9*P_9) +
P_0) +Fm_NO_9*Entropy(NO,T=T_0,P=Fn_NO_9*P_0) +
Psi_9=h_9-h_9_0-(T_0+273.15)*(s_9-s_9_0)
Psi_Chem_9=(Fn_O2_9*Psi_Chem_O2 + Fn_N2_9*Psi_Chem_N2 + Fn_NO_9*Psi_Chem_NO +

R*(T_0+273.15)*(Fn_O2_9*LN(Fn_O2_9)+Fn_N2_9*LN(Fn_N2_9)+Fn_NO_9*LN(Fn_NO_9)+Fn_
Steam_9*LN(Fn_Steam_9)))/(Fn_O2_9*Molarmass(O2) + Fn_N2_9*Molarmass(N2) +
T_10= 243.333 [C]

P_10=852.881 [kPa]
m_dot_10=20.61426 [kg/s]
Fm_O2_10=0.06352
Fm_N2_10=0.71740
Fm_NO_10=0.11456
Fm_Steam_10=0.10451
Fn_O2_10=0.05426
Fn_N2_10=0.69991
Fn_NO_10=0.08727
Fn_Steam_10=0.15856
s_10=Fm_O2_10*entropy(O2,T=T_10,P=Fn_O2_10*P_10)+Fm_N2_10*entropy(N2,T=T_10,P=Fn_
N2_10*P_10) +Fm_NO_10*Entropy(NO,T=T_10,P=Fn_NO_10*P_10) +
s_10_0=Fm_O2_10*entropy(O2,T=T_0,P=Fn_O2_10*P_0)+Fm_N2_10*entropy(N2,T=T_0,P=Fn_
Psi_10=h_10-h_10_0-(T_0+273.15)*(s_10-s_10_0)
Psi_Chem_10=(Fn_O2_10*Psi_Chem_O2 + Fn_N2_10*Psi_Chem_N2 +
Fn_NO_10*Psi_Chem_NO + Fn_Steam_10*Psi_Chem_Steam +
R*(T_0+273.15)*(Fn_O2_10*LN(Fn_O2_10)+Fn_N2_10*LN(Fn_N2_10)+Fn_NO_10*LN(Fn_NO_1
0)+Fn_Steam_10*LN(Fn_Steam_10)))/(Fn_O2_10*Molarmass(O2) + Fn_N2_10*Molarmass(N2) +
T_11=278.333 [C]
P_11=845.987 [kPa]
m_dot_11=20.61426 [kg/s]
Fm_O2_11=0.05244
Fm_N2_11=0.71740
Fm_NO_11=0.12564
Fm_Steam_11=0.10451
Fn_O2_11=0.04521
Fn_N2_11=0.70661
Fn_NO_11=0.08810
Fn_Steam_11=0.16008
Psi_11=h_11-h_11_0-(T_0+273.15)*(s_11-s_11_0)
T_12=196.111 [C]
P_12=839.092 [kPa]
m_dot_12=20.61426 [kg/s]
Fm_O2_12=0.05057
Fm_N2_12=0.71740
Fm_NO_12=0.12751
Fm_Steam_12=0.10451
Fn_O2_12=0.04367
Fn_N2_12=0.70775
Fn_NO_12=0.08824
Fn_Steam_12=0.16034
Psi_12=h_12-h_12_0-(T_0+273.15)*(s_12-s_12_0)
T_13=46.667
P_13=811.513
m_dot_13=17.33214
Fm_O2_13=0.03468
Fm_N2_13=0.85326
Fm_NO_13=0.10781
Fm_HNO3_13=0.00108
Fm_Steam_13=0.00317
Fn_O2_13=0.03165
Fn_N2_13=0.88944
Fn_NO_13=0.07326
FN_HNO3_13=0.00051
Fn_Steam_13=0.00514
Fm_NO_13*Enthalpy(NO,T=T_13) + Fm_HNO3_13*Enthalpy(HNO3,T=T_13) +
N2_13*P_13) +Fm_NO_13*Entropy(NO,T=T_13,P=Fn_NO_13*P_13)
+Fm_HNO3_13*Entropy(HNO3,T=T_13,P=Fn_HNO3_13*P_13) +
Fm_NO_13*Enthalpy(NO,T=T_0) + Fm_HNO3_13*Enthalpy(HNO3,T=T_0) +
N2_13*P_0) +Fm_NO_13*Entropy(NO,T=T_0,P=Fn_NO_13*P_0)
+Fm_HNO3_13*Entropy(HNO3,T=T_0,P=Fn_HNO3_13*P_0) +
Psi_13=h_13-h_13_0-(T_0+273.15)*(s_13-s_13_0)
Fn_NO_13*Psi_Chem_NO + Fn_HNO3_13*Psi_Chem_HNO3 + Fn_Steam_13*Psi_Chem_Steam
+
3)
+Fn_HNO3_13*LN(Fn_HNO3_13)+Fn_Steam_13*LN(Fn_Steam_13)))/(Fn_O2_13*Molarmass(O2)
+ Fn_N2_13*Molarmass(N2) + Fn_NO_13*Molarmass(NO) + Fn_HNO3_13*Molarmass(HNO3) +
Fn_Steam_13*Molarmass(Steam))
"Flow 14 - Weak Acid - HNO3"
T_14=45
P_14=859.776
m_dot_14=3.28212
Fm_NO_14=0.00983
Fm_HNO3_14=0.40988
Fm_Steam_14=0.58029
Fn_NO_14=0.00552
Fn_HNO3_14=0.16706
Fn_Steam_14=0.82742
h_14=Fm_NO_14*enthalpy(NO,T=T_14)+Fm_HNO3_14*Enthalpy(HNO3,T=T_14)+Fm_Steam_14*
enthalpy(Steam_IAPWS,T=T_14,P=Fn_Steam_14*P_14)
s_14=Fm_NO_14*entropy(NO,T=T_14,P=Fn_NO_14*P_14)+Fm_HNO3_14*Entropy(HNO3,T=T_1
4,P=Fn_HNO3_14*P_14)+Fm_Steam_14*entropy(Steam_IAPWS,T=T_14,P=Fn_Steam_14*P_14)
h_14_0=Fm_NO_14*enthalpy(NO,T=T_0)+Fm_HNO3_14*Enthalpy(HNO3,T=T_0)+Fm_Steam_14*
s_14_0=Fm_NO_14*entropy(NO,T=T_0,P=Fn_NO_14*P_0)+Fm_HNO3_14*Entropy(HNO3,T=T_0,
P=Fn_HNO3_14*P_0)+Fm_Steam_14*entropy(Steam_IAPWS,T=T_0,P=Fn_Steam_14*P_0)
Psi_14=h_14-h_14_0-(T_0+273.15)*(s_14-s_14_0)
Psi_Chem_14=(Fn_NO_14*Psi_Chem_NO + Fn_HNO3_14*Psi_Chem_HNO3 +
R*(T_0+273.15)*(Fn_NO_14*LN(Fn_NO_14)+Fn_HNO3_14*LN(Fn_HNO3_14)+Fn_Steam_14*LN(
Fn_Steam_14)))/(Fn_NO_14*Molarmass(NO) + Fn_HNO3_14*Molarmass(HNO3) +
Fn_Steam_14*Molarmass(Steam))
"Flow 15 - ABS FW (Demi Water)"
T_15=37.778
P_15=928.724
m_dot_15=1.81387
h_15=enthalpy(Water,T=T_15,P=P_15)
s_15=entropy(Water,T=T_15,P=P_15)
h_15_0=enthalpy(Water,T=T_0,P=P_0)
s_15_0=entropy(Water,T=T_0,P=P_0)
Psi_15=h_15-h_15_0-(T_0+273.15)*(s_15-s_15_0)
"Flow 16 - Tail Gas"
T_16=40.556
P_16=770.144
m_dot_16=17.73282
Fm_O2_16=0.04285
Fm_N2_16=0.94753
Fm_NO_16=0.00318
Fm_Steam_16=0.00643
Fn_O2_16=0.03761
Fn_N2_16=0.94978
Fn_NO_16=0.00259
Fn_Steam_16=0.01002
Psi_16=h_16-h_16_0-(T_0+273.15)*(s_16-s_16_0)
"Flow 17 - Unbleached Acid"
T_17=43.333
P_17=970.092
m_dot_17=3.3565
h_17=Enthalpy(HNO3,T=T_17)
h_17_0=Enthalpy(HNO3,T=T_0)
s_17=Entropy(HNO3,T=T_17,P=P_17)
s_17_0=Entropy(HNO3,T=T_0,P=P_0)
Psi_17=h_17-h_17_0-(T_0+273.15)*(s_17-s_17_0)
Psi_Chem_17=Psi_Chem_HNO3/Molarmass(HNO3)
"Flow 18 - Bleacher Gas"
{T_18=54.444
P_18=811.513
m_dot_18=7.34983
Fm_NO_18=0.00983
Fm_HNO3_18=0.40988
Fm_Steam_18=0.58029
Fn_NO_18=0.00552
Fn_HNO3_18=0.16706
Fn_Steam_18=0.82742
Psi_18=h_18-h_18_0-(T_0+273.15)*(s_18-s_18_0)}
"Flow 19 - Product Acid - HNO3"
T_19=54.444
P_19=811.513
m_dot_19=7.34983
Fm_NO_19=0.00983
Fm_HNO3_19=0.40988
Fm_Steam_19=0.58029
Fn_NO_19=0.00552
Fn_HNO3_19=0.16706
Fn_Steam_19=0.82742
Psi_19=h_19-h_19_0-(T_0+273.15)*(s_19-s_19_0)
T_20= 73.889
P_20=756.355
m_dot_20=17.73282
Fm_O2_20=0.04285
Fm_N2_20=0.94753
Fm_NO_20=0.00318
Fm_Steam_20=0.00643
Fn_O2_20=0.03761
Fn_N2_20=0.94978
Fn_NO_20=0.00259
Fn_Steam_20=0.01002
h_20=Fn_O2_20*enthalpy(O2,T=T_20)+Fm_N2_20*enthalpy(N2,T=T_20) +
Psi_20=h_20-h_20_0-(T_0+273.15)*(s_20-s_20_0)
T_21= 176.667
P_21=735.671
m_dot_21=17.73282
Fm_O2_21=0.04285
Fm_N2_21=0.94753
Fm_NO_21=0.00318
Fm_Steam_21=0.00643
Fn_O2_21=0.03761
Fn_N2_21=0.94978
Fn_NO_21=0.00259
Fn_Steam_21=0.01002
Psi_21=h_21-h_21_0-(T_0+273.15)*(s_21-s_21_0)
T_22= 593.333
P_22=701.197
m_dot_22=17.73282
Fm_O2_22=0.04285
Fm_N2_22=0.94753
Fm_NO_22=0.00318
Fm_Steam_22=0.00643
Fn_O2_22=0.03761
Fn_N2_22=0.94978
Fn_NO_22=0.00259
Fn_Steam_22=0.01002
Psi_22=h_22-h_22_0-(T_0+273.15)*(s_22-s_22_0)
T_23=307.22
P_23=103.421
m_dot_23=17.73282
Fm_O2_23=0.04285
Fm_N2_23=0.94753
Fm_NO_23=0.00318
Fm_Steam_23=0.00643
Fn_O2_23=0.03761
Fn_N2_23=0.94978
Fn_NO_23=0.00259
Fn_Steam_23=0.01002
h_23_0=Fn_O2_23*enthalpy(O2,T=T_0)+Fm_N2_23*enthalpy(N2,T=T_0) +
Psi_23=h_23-h_23_0-(T_0+273.15)*(s_23-s_23_0)
" - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - COOLING WATER (CW) -

FEEDWATER (FW) - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - "
"Inlet FW (Water) - HRSG"
T_FWin_HRSG=148.889
P_FWin_HRSG=790.8286
m_dot_FWin_HRSG=3.7799
h_FWin_HRSG=enthalpy(Water,T=T_FWin_HRSG,P=P_FWin_HRSG)
s_FWin_HRSG=entropy(Water,T=T_FWin_HRSG,P=P_FWin_HRSG)
h_FWin_HRSG_0=enthalpy(Water,T=T_0,P=P_0)
s_FWin_HRSG_0=entropy(Water,T=T_0,P=P_0)
Psi_FWin_HRSG=h_FWin_HRSG-h_FWin_HRSG_0-(T_0+273.15)*(s_FWin_HRSG-
s_FWin_HRSG_0)
"Outlet FW (Steam) - HRSG"

T_FWout_HRSG=243.3333
P_FWout_HRSG=1997.412
m_dot_FWout_HRSG=3.7799
h_FWout_HRSG=enthalpy(Steam_IAPWS,T=T_FWout_HRSG,P=P_FWout_HRSG)
s_FWout_HRSG=entropy(Steam_IAPWS,T=T_FWout_HRSG,P=P_FWout_HRSG)
h_FWout_HRSG_0=enthalpy(Steam_IAPWS,T=T_0,P=P_0)
s_FWout_HRSG_0=entropy(Steam_IAPWS,T=T_0,P=P_0)
Psi_FWout_HRSG=h_FWout_HRSG-h_FWout_HRSG_0-(T_0+273.15)*(s_FWout_HRSG-
s_FWout_HRSG_0)
"-----------------------------------------------------------------------
------------------------------------------------------------------------
- -"
"Inlet FW (Steam) - TGTH"

T_Steam_TGTH=187.777
P_Steam_TGTH=1135.5665
m_dot_Steam_TGTH=0.2753
h_Steam_TGTH=enthalpy(Steam_IAPWS,T=T_Steam_TGTH,P=P_Steam_TGTH)
s_Steam_TGTH=entropy(Steam_IAPWS,T=T_Steam_TGTH,P=P_Steam_TGTH)
h_Steam_TGTH_0=enthalpy(Steam_IAPWS,T=T_0,P=P_0)
s_Steam_TGTH_0=entropy(Steam_IAPWS,T=T_0,P=P_0)
Psi_Steam_TGTH=h_Steam_TGTH-h_Steam_TGTH_0-(T_0+273.15)*(s_Steam_TGTH-
s_Steam_TGTH_0)
"Outlet FW (Cond) - TGTH"

T_Cond_TGTH=t_sat(Water,P=1101.0927)
P_Cond_TGTH=p_sat(Water,T=187.777)
m_dot_Cond_TGTH=0.2753
h_Cond_TGTH=enthalpy(Water,T=T_Cond_TGTH,P=P_Cond_TGTH)
s_Cond_TGTH=entropy(Water,T=T_Cond_TGTH,P=P_Cond_TGTH)
h_Cond_TGTH_0=enthalpy(Water,T=T_0,P=P_0)
s_Cond_TGTH_0=entropy(Water,T=T_0,P=P_0)
Psi_Cond_TGTH=h_Cond_TGTH-h_Cond_TGTH_0-(T_0+273.15)*(s_Cond_TGTH-
s_Cond_TGTH_0)
"-----------------------------------------------------------------------
------------------------------------------------------------------------
- -"
"Inlet CoolerWater - Absortion Column"

T_CWin_ABS=48.8889
P_CWin_ABS=790.8286
m_dot_CWin_ABS=1.3879
h_CWin_ABS=enthalpy(Water,T=T_CWin_ABS,P=P_CWin_ABS)
s_CWin_ABS=entropy(Water,T=T_CWin_ABS,P=P_CWin_ABS)
h_CWin_ABS_0=enthalpy(Water,T=T_0,P=P_0)
s_CWin_ABS_0=entropy(Water,T=T_0,P=P_0)
Psi_CWin_ABS=h_CWin_ABS-h_CWin_ABS_0-(T_0+273.15)*(s_CWin_ABS-s_CWin_ABS_0)
"Outlet CoolerWater - Absortion Column"

T_CWout_ABS=51.667
P_CWout_ABS=790.8286
m_dot_CWout_ABS=1.3879
h_CWout_ABS=enthalpy(Water,T=T_CWout_ABS,P=P_CWout_ABS)
s_CWout_ABS=entropy(Water,T=T_CWout_ABS,P=P_CWout_ABS)
h_CWout_ABS_0=enthalpy(Water,T=T_0,P=P_0)
s_CWout_ABS_0=entropy(Water,T=T_0,P=P_0)
Psi_CWout_ABS=h_CWout_ABS-h_CWout_ABS_0-(T_0+273.15)*(s_CWout_ABS-
s_CWout_ABS_0)
"-----------------------------------------------------------------------
------------------------------------------------------------------------
- -"
"Inlet CoolerWater - Cooler Condenser"

T_CWin_CC=51.667
P_CWin_CC=790.8286
m_dot_CWin_CC=1.3879
h_CWin_CC=enthalpy(Water,T=T_CWin_CC,P=P_CWin_CC)
s_CWin_CC=entropy(Water,T=T_CWin_CC,P=P_CWin_CC)
h_CWin_CC_0=enthalpy(Water,T=T_0,P=P_0)
s_CWin_CC_0=entropy(Water,T=T_0,P=P_0)
Psi_CWin_CC=h_CWin_CC-h_CWin_CC_0-(T_0+273.15)*(s_CWin_CC-s_CWin_CC_0)
"Outlet CoolerWater - Cooler Condenser"

T_CWout_CC=204.444
P_CWout_CC=790.8286
m_dot_CWout_CC=1.3879
h_CWout_CC=enthalpy(Water,T=T_CWout_CC,P=P_CWout_CC)
s_CWout_CC=entropy(Water,T=T_CWout_CC,P=P_CWout_CC)
h_CWout_CC_0=enthalpy(Water,T=T_0,P=P_0)
s_CWout_CC_0=entropy(Water,T=T_0,P=P_0)
Psi_CWout_CC=h_CWout_CC-h_CWout_CC_0-(T_0+273.15)*(s_CWout_CC-s_CWout_CC_0)
"----------------------------------------------------------------
EQUIPMENT ANALYSIS - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -
- - - - - - - - - -"
"MULTI-STAGE COMPRESSOR C-801 "
"Mass Flow - Metodology"

P_atm=P_0
T_atm=T_0*1.8 + 491.67 "Rankine Scale"
T_act_LPC=T_2_1*1.8 + 491.67 "Rankine Scale"
T_act_HPC=T_2_3*1.8 + 491.67 "Rankine Scale"
"LP-Compressor Inlet Mass Flow"

V_dot_LPC_In=(29298.46/((P_2_1/P_atm)*(T_act_LPC/T_atm)))*(0.3048^3) "ft^3/min --> m^3/min
"
rho_LPC_In=density(Air_ha,T=T_2_1,P=P_2_1)
m_dot_LPC=(V_dot_LPC_In*rho_LPC_In)/60
"HP-Compressor Inlet Mass Flow"

V_dot_HPC=(28010/((P_2_3/P_atm)*(T_act_HPC/T_atm)))*(0.3048^3)
rho_HPC=density(Air_ha,T=T_2_3,P=P_2_3)
m_dot_HPC=(V_dot_HPC*rho_HPC)/60
"LP-HP Compressor Power "

W_dot_Comp=(m_dot_LPC*(h_2_2-h_2_1) + m_dot_HPC*(h_2_4-h_2_3) + m_dot_HPC*(h_3-
h_2_5))
{
"Exergy Analysis"
X_dot_F_Comp=W_dot_Comp
X_dot_P_Comp=(m_dot_LPC*(Psi_2_2-Psi_2_1) + m_dot_HPC*(Psi_2_4-Psi_2_3) +
m_dot_HPC*(Psi_3-Psi_2_5))
X_dot_dest_Comp=X_dot_F_Comp - X_dot_P_Comp
"Exergy Efficiency"
epsilon_Comp/100=X_dot_P_Comp/X_dot_F_Comp
}
"-----------------------------------------------------------------------
------------------------------------------------------------------------
- -"
"COMPRESSION TRAIN"
"Q.Loss Compression Trainr"

Q_dot_Loss_CT=m_dot_ST*(h_ST_In-h_ST_Out) + m_dot_22*(h_22-h_23) - m_dot_LPC*(h_2_2-
h_2_1) - m_dot_HPC*(h_2_4-h_2_3) - m_dot_HPC*(h_3-h_2_5)
"Boundary Temp "

T_b_CT=80
"Exergy Analysis"
X_dot_F_CT=m_dot_ST*(h_ST_In-h_ST_Out) + m_dot_22*(h_22-h_23)
X_dot_P_CT=m_dot_LPC*(Psi_2_2-Psi_2_1) + m_dot_HPC*(Psi_2_4-Psi_2_3) +
m_dot_HPC*(Psi_3-Psi_2_5) "+ Q_dot_Loss_CT*(1-((T_0+273.15)/(T_b_CT+273.15)))"
X_dot_dest_CT=X_dot_F_CT - X_dot_P_CT
"Exergy Efficiency"
epsilon_CT/100=X_dot_P_CT/X_dot_F_CT
Y_k_CT/100=X_dot_dest_CT/X_dot_F_CT
"Termoeconómico"
"-----------------------------------------------------------------------
------------------------------------------------------------------------
- -"
"CONVERTER CO-801 + REHEATER E-803"
"Q-in Converter"
m_dot_7*h_7+m_dot_6*h_6+m_dot_21*h_21+Q_dot_CONV =m_dot_8*h_8+m_dot_22*h_22
"Boundary Temp "

T_b_CONV="156.2592"926.666
"Exergy Analysis"
X_dot_F_CONV=m_dot_6*(Psi_6 +
Psi_Chem_6)+m_dot_7*(Psi_7+Psi_Chem_7)+m_dot_21*(Psi_21+Psi_Chem_21) +
Q_dot_CONV*(1-((T_0+273.15)/(T_b_CONV+273.15)))
X_dot_P_CONV=m_dot_8*(Psi_8+Psi_Chem_8)+m_dot_22*(Psi_22+Psi_Chem_22)
X_dot_dest_CONV=X_dot_F_CONV-X_dot_P_CONV
"Exergy Efficiency"
epsilon_CONV/100=X_dot_P_CONV/X_dot_F_CONV
Y_k_CONV/100=X_dot_dest_CONV/X_dot_F_CONV
"-----------------------------------------------------------------------
------------------------------------------------------------------------
- -"
"AIR HEATER E-815"
"Q.Loss - Air Heater"

Q_dot_Loss_AH=m_dot_4*(h_6-h_4) - m_dot_8*(h_8-h_9)
"Heat Transfer Efficiency - AH"

epsilon_Q_AH/100=(m_dot_8*h_8-m_dot_9*h_9)/( m_dot_6*h_6-m_dot_4*h_4)
"Boundary Temp."
T_b_AH=37.0740
"Dest. Exergy Analysis"

X_dot_F_AH=m_dot_8*(Psi_8+Psi_Chem_8)-m_dot_9*(Psi_9+Psi_Chem_9)
X_dot_P_AH=m_dot_6*(Psi_6)-m_dot_4*(Psi_4)
X_dot_dest_AH=X_dot_F_AH-X_dot_P_AH
" % Des. Exergy"

epsilon_AH/100=X_dot_P_AH/X_dot_F_AH
Y_k_AH/100=X_dot_dest_AH/X_dot_F_AH
"-----------------------------------------------------------------------
------------------------------------------------------------------------
- -"
"WASTE HEAT EXCHANGER - HRSG B-801"
"Q-Loss - HRSG"
Q_dot_Loss_HRSG=(m_dot_FWout_HRSG*h_FWout_HRSG -
m_dot_FWin_HRSG*h_FWin_HRSG) - (m_dot_9*h_9 -
m_dot_10*h_10)
"Heat Transfer Efficiency"

epsilon_Q_HRSG/100=(m_dot_9*h_9 - m_dot_10*h_10)/(m_dot_FWout_HRSG*h_FWout_HRSG -
m_dot_FWin_HRSG*h_FWin_HRSG)
"Boundary Temp. - verificar"

T_b_HRSG=74.6481

X_dot_F_HRSG= m_dot_9*(Psi_9+Psi_Chem_9)-m_dot_10*(Psi_10+Psi_Chem_10)
X_dot_P_HRSG=m_dot_FWout_HRSG*(Psi_FWout_HRSG)-
m_dot_FWin_HRSG*(Psi_FWin_HRSG)
X_dot_dest_HRSG=X_dot_F_HRSG-X_dot_P_HRSG
"% Dest. Exergy"

epsilon_HRSG/100=X_dot_P_HRSG/X_dot_F_HRSG
Y_k_HRSG/100=X_dot_dest_HRSG/X_dot_F_HRSG
"-----------------------------------------------------------------------
------------------------------------------------------------------------
- -"
"TAIL GAS HEATER E-802"
"Q.Loss - Tail Gas Heater"

Q_dot_Loss_TGH=(m_dot_21*h_21-m_dot_20*h_20) - (m_dot_11*h_11-m_dot_12*h_12)
"Heat Transfer Efficiency - TGH"

epsilon_Q_TGH/100=(m_dot_11*h_11-m_dot_12*h_12)/(m_dot_21*h_21-m_dot_20*h_20)
"Boundary Temp. - VERIFICAR"
T_b_TGH=192.3888

X_dot_F_TGH=m_dot_11*(Psi_11+Psi_Chem_11)-m_dot_12*(Psi_12+Psi_Chem_12)
X_dot_P_TGH=m_dot_21*(Psi_21)-m_dot_20*(Psi_20)
X_dot_dest_TGH=X_dot_F_TGH-X_dot_P_TGH
" % Des. Exergy"

epsilon_TGH/100=X_dot_P_TGH/X_dot_F_TGH
Y_k_TGH/100=X_dot_dest_TGH/X_dot_F_TGH
"-----------------------------------------------------------------------
------------------------------------------------------------------------
- -"
"TAIL GAS TEMPERING HEATER E-809"
"Q-Loss - TGTH"
Q_dot_Loss_TGTH=(m_dot_20*h_20 - m_dot_16*h_16) - (m_dot_Steam_TGTH*h_Steam_TGTH -
m_dot_Cond_TGTH*h_Cond_TGTH)
"Heat Transfer Efficiency - TGTH"

epsilon_Q_TGTH/100=(m_dot_Steam_TGTH*h_Steam_TGTH -
m_dot_Cond_TGTH*h_Cond_TGTH)/(m_dot_20*h_20 - m_dot_16*h_16)
"Boundary Temp."
T_b_TGTH=121.8518

X_dot_F_TGTH=m_dot_Steam_TGTH*(Psi_Steam_TGTH ) -
m_dot_Cond_TGTH*(Psi_Cond_TGTH )
X_dot_P_TGTH=m_dot_20*(Psi_20+Psi_Chem_20) - m_dot_16*(Psi_16+Psi_Chem_16)
X_dot_dest_TGTH=X_dot_F_TGTH - X_dot_P_TGTH
"% Dest. Exergy"

epsilon_TGTH/100=X_dot_P_TGTH/X_dot_F_TGTH
Y_k_TGTH/100=X_dot_dest_TGTH/X_dot_F_TGTH
"-----------------------------------------------------------------------
------------------------------------------------------------------------
- -"
"COOLER CONDENSER E-801 A/B"
"Q-Loss - CC"
Q_dot_Loss_CC=m_dot_12*(h_12)+m_dot_CWin_CC*(h_CWin_CC) - (m_dot_13*(h_13) +
m_dot_14*(h_14) + m_dot_CWout_CC*(h_CWout_CC))
X_dot_F_CC=m_dot_12*(Psi_12 +Psi_Chem_12)+m_dot_CWin_CC*(Psi_CWin_CC)
X_dot_P_CC=m_dot_13*(Psi_13 +Psi_Chem_13) + m_dot_14*(Psi_14 +Psi_Chem_14) +
m_dot_CWout_CC*(Psi_CWout_CC)
X_dot_dest_CC=X_dot_F_CC - X_dot_P_CC
"% Dest. Exergy"

epsilon_CC/100=X_dot_P_CC/X_dot_F_CC
Y_k_CC/100=X_dot_dest_CC/X_dot_F_CC
"-----------------------------------------------------------------------
------------------------------------------------------------------------
- -"
"ABSORTION COLUMN TO-801"
"Q-Loss - CC"
Q_dot_Loss_ABS=
m_dot_13*(h_13)+m_dot_14*(h_14)+m_dot_15*(h_15)+m_dot_CWin_ABS*(h_CWin_ABS) -
(m_dot_16*(h_16) + m_dot_17*(h_17)+ m_dot_CWout_ABS*(h_CWout_ABS))

X_dot_F_ABS=m_dot_13*(Psi_13 +Psi_Chem_13)+m_dot_14*(Psi_14
+Psi_Chem_14)+m_dot_15*(Psi_15)+m_dot_CWin_ABS*(Psi_CWin_ABS)+ m_dot_5*(Psi_5)
X_dot_P_ABS=m_dot_16*(Psi_16 +Psi_Chem_16) + m_dot_CWout_ABS*(Psi_CWout_ABS)+
m_dot_19*(Psi_19)
X_dot_dest_ABS=X_dot_F_ABS - X_dot_P_ABS
"% Dest. Exergy"

epsilon_ABS/100=X_dot_P_ABS/X_dot_F_ABS
Y_k_ABS/100=X_dot_dest_ABS/X_dot_F_ABS
"-----------------------------------------------------------------------
------------------------------------------------------------------------
- -"
"OVERALL SYSTEM"
"Total Exergy Destruction "

X_dot_dest_TOTAL=X_dot_dest_CT + X_dot_dest_CONV + X_dot_dest_AH + X_dot_dest_HRSG
+ X_dot_dest_TGH + X_dot_dest_TGTH + X_dot_dest_CC + X_dot_dest_ABS
"Total Exergy Inlet"

X_dot_F_TOTAL=X_dot_F_CT + X_dot_F_CONV + X_dot_F_AH + X_dot_F_HRSG +
X_dot_F_TGH + X_dot_F_TGTH + X_dot_F_CC + X_dot_F_ABS
"Total Exergy Outlet"

X_dot_P_TOTAL=X_dot_P_CT + X_dot_P_CONV + X_dot_P_AH + X_dot_P_HRSG +
X_dot_P_TGH + X_dot_P_TGTH + X_dot_P_CC + X_dot_P_ABS
"Total Exergy Efficiency"

epsilon_TOTAL/100=X_dot_P_TOTAL/X_dot_F_TOTAL
"-----------------------------------------------------------------------
------------------------------------------------------------------------
- -"
"TOTAL DESTRUCTION EXERGY RATIO - PER EQUIPMENT"
"Compression Train"
Y_CT/100=X_dot_dest_CT/x_dot_dest_TOTAL
"Converter"
Y_CONV/100=X_dot_dest_CONV/x_dot_dest_TOTAL
"Air Heater"
Y_AH/100=X_dot_dest_AH/x_dot_dest_TOTAL
"Waste Heat Exchanger"

Y_HRSG/100=X_dot_dest_HRSG/x_dot_dest_TOTAL
"Tail Gas Heater"

Y_TGH/100=X_dot_dest_TGH/x_dot_dest_TOTAL
"Tail Gas Tempering Heater"

Y_TGTH/100=X_dot_dest_TGTH/x_dot_dest_TOTAL
"Cooler Condenser"
Y_CC/100=X_dot_dest_CC/x_dot_dest_TOTAL
"Absortion Column"
Y_ABS/100=X_dot_dest_ABS/x_dot_dest_TOTAL
"-----------------------------------------------------------------------
------------------------------------------------------------------------
- -"
"Q-LOSS TOTAL"
Q_dot_Loss_TOTAL=Q_dot_Loss_CT + Q_dot_Loss_AH + Q_dot_Loss_HRSG +

Q_dot_Loss_TGH + Q_dot_Loss_TGTH + Q_dot_Loss_CC + Q_dot_Loss_ABS

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{

- Mass Flow (Kg/s)

"Universal Constant Of Gases (KJ/Kmol-K)"

"Temp. And Pressure - Dead State"

"Flow - Steam Turbine"

"Flow 2 - (Inlet Air) Compressor Stages"

Psi_2_1=h_2_1 - h_0 - (T_0+273.15)*(s_2_1 - s_0)

"Flow 4 - Process Air"

"Flow 5 - Bleach Air"

"Flow 6 - Converter Air"

"Flow 7 - Vapor Ammonia"

"Flow 8 - Process Gas"

T_8= 649.444 [C]

Psi_Chem_8=(Fn_O2_8*Psi_Chem_O2 + Fn_N2_8*Psi_Chem_N2 + Fn_NO_8*Psi_Chem_NO +

"Flow 9 - Process Gas"

Psi_Chem_9=(Fn_O2_9*Psi_Chem_O2 + Fn_N2_9*Psi_Chem_N2 + Fn_NO_9*Psi_Chem_NO +

"Flow 10 - Process Gas"

T_10= 243.333 [C]

"Flow 11 - Process Gas"

"Flow 12 - Process Gas"

"Flow 13 - Process Gas"

"Flow 14 - Weak Acid - HNO3"

"Flow 15 - ABS FW (Demi Water)"

"Flow 16 - Tail Gas"

"Flow 17 - Unbleached Acid"

"Flow 18 - Bleacher Gas"

"Flow 19 - Product Acid - HNO3"

"Flow 20 - Tail Gas"

"Flow 21 - Tail Gas"

"Flow 22 - Tail Gas"

"Flow 23 - Tail Gas"

" - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - COOLING WATER (CW) -

"Outlet FW (Steam) - HRSG"

"Inlet FW (Steam) - TGTH"

"Outlet FW (Cond) - TGTH"

"Inlet CoolerWater - Absortion Column"

"Outlet CoolerWater - Absortion Column"

"Inlet CoolerWater - Cooler Condenser"

"Outlet CoolerWater - Cooler Condenser"

"MULTI-STAGE COMPRESSOR C-801 "

"Mass Flow - Metodology"

"LP-Compressor Inlet Mass Flow"

"HP-Compressor Inlet Mass Flow"

"LP-HP Compressor Power "

"Q.Loss Compression Trainr"

"Boundary Temp "

"CONVERTER CO-801 + REHEATER E-803"

"Boundary Temp "

"AIR HEATER E-815"

"Q.Loss - Air Heater"

"Heat Transfer Efficiency - AH"

"Dest. Exergy Analysis"

" % Des. Exergy"

"WASTE HEAT EXCHANGER - HRSG B-801"

"Heat Transfer Efficiency"

"Boundary Temp. - verificar"

"Dest. Exergy Analysis"

"% Dest. Exergy"

"TAIL GAS HEATER E-802"

"Q.Loss - Tail Gas Heater"

"Heat Transfer Efficiency - TGH"

"Dest. Exergy Analysis"

" % Des. Exergy"

Psi_Chem_8=(Fn_O2_8Psi_Chem_O2 + Fn_N2_8Psi_Chem_N2 + Fn_NO_8*Psi_Chem_NO +

Psi_Chem_9=(Fn_O2_9Psi_Chem_O2 + Fn_N2_9Psi_Chem_N2 + Fn_NO_9*Psi_Chem_NO +