PROGRAM CHEM CHECK-UP 2.

0
DK024 SESI 2018/2019
STAGE 5 – TREATMENT 4

+
G

KMnO4, H
HB
r ,C

3O +
H3
OO

/H
CH

2O
3

H
CH3
KMnO4,OH-,cold CH3
B F CH3 CH CH2
CH3COOH, Conc H2SO4
CH3 C CH2
OH K
H 2
,Pt
l2
2C

Na PCC, CH2Cl2
H

HB
,C

R2

r
r2
B

A
R1 +
D C I KMnO4, H
CH3 N

H-
M

O
CH3 C CH3

3) +
2 ,

H2
Br

KCN, H2SO4

O,
( N
Ag

H
+
, AlCl3

L Q
H
P
 PROGRAM CHEM CHECK-UP 2.0
DK024 SESI 2018/2019
STAGE 5 – TREATMENT 4

1. For the reaction scheme above:

a) Predict the structures of compounds/ the reagents used in the reactions. [17 Marks]
b) Give the IUPAC name of compound B, C, D, E,H, J,M and Q. [8 Marks]
c) State the type of reaction R1 and R2. [2 Marks]
d) Define the rule that used in the formation of C. [1 Mark]

2. Give a chemical test for the following compound:

i. 2-methylpropene and stucture E. [4 Marks]
ii. 2-methyl-1-propanol and structure H. [4 Marks]
iii. 3-methyl-2-pentanone and structure M. [4 Marks]
Total = 40 Marks