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Lampiran 4.

Data Perhitungan Akurasi Besi

Bobot Volume
Konsetrasi konsentrasi
No Abs contoh akhir FP %Recovery
(mg/L) contoh (mg/kg)
(gram) (ml)
0.2622 4.4021 0.500 22010.6551
VP 100 25
0.2683 4.5045 22522.7260
VP 0.500 100 25 22323.05370
0.2673 4.4878 22438.7800
VP 0.500 100 25
0.4441 7.4561 0.503 37058.0936 98.22693267
1 100 25
0.4387 7.3654 0.501 36753.6262 96.19715
2 100 25
0.4378 7.3503 0.501 36678.2255 95.69447867
3 100 25
0.4495 7.5468 0.506 37286.3150 99.74840867
4 100 25
0.4431 7.4393 0.500 37196.4961 99.149616
5 100 25
0.4379 7.3520 0.500 36759.9766 96.239486
6 100 25
0.4350 7.3033 0.501 36443.6458 94.130614
7 100 25
0.4391 7.3721 0.502 36713.8564 95.932018
8 100 25
0.4355 7.3117 0.500 36558.5061 94.89634933
9 100 25
0.4401 7.3889 0.501 36870.9161 96.97908267
10 100 25
0.4422 7.4242 0.503 36899.5473 97.16995733
11 100 25
0.4426 7.4309 0.502 37006.4971 97.882956
12 100 25
0.4418 7.4175 0.501 37013.3395 97.928572
13 100 25
0.4417 7.4158 0.501 37004.9617 97.87272
14 100 25
0.4399 7.3856 0.501 36854.1604 96.867378
15 100 25
0.4358 7.3167 0.500 36583.6899 95.06424133
16 100 25
0.4329 7.2680 0.500 36340.2463 93.441284
17 100 25
0.4283 7.1908 0.501 35882.3298 90.38850733
18 100 25
0.4245 7.1270 0.500 35635.0995 88.74030533
19 100 25
0.4348 7.2999 0.501 36426.8901 94.01890933
20 100 25
0.4291 7.2043 0.501 35949.3526 90.835326
21 100 25
0.4255 7.1438 0.500 35719.0455 89.29994533
22 100 25
0.4242 7.1220 0.500 35609.9157 88.57241333
23 100 25
0.4223 7.0901 0.500 35450.4182 87.50909667
24 100 25
0.4277 7.1807 0.500 35903.7269 90.53115467
25 100 25
94.04068
Mean
3.617708
SD
3.84696
% SRD
5.38289
2/3 CV Horwitz
Min 87.50909667
Max 99.74840867
%RSD < 2/3 CV Horwitz : 3.84696 < 5.38289
Syarat keberterimaan : 80 - 120%

Contoh perhitungan kadar logam Fe yang di tambahkan pada sampel:


mg L
V pipet (mL) x C induk ( )x10-3 ( )
L mL
Konsentrasi spike (mg/kg) = kg
bobot contoh(gram) x10-3 ( )
g

mg L
7.5 mL x 1000 x10-3 ( )
L mL
= kg
0.500 g x 10-3 ( )
g

=15000 mg/kg

Contoh perhitungan konsentrasi logam Fe dalam contoh+spike pada ulangan ke-1:


mg L
volakhir(mL)x konsentrasilogam Fe ( )x 10-3 ( )
L mL
Konsentrasi contoh + spike = kg
bobotcontoh(gram)x 10-3 ( )
g
mg L
100 mL x 7.4561 x 10-3 ( )
L mL
= kg
0.503 g x 10-3 ( )
g

= 37058.0936 mg/kg

Contoh perhitungan % Recovery pada ulangan ke-1 :


(Konsentrasi spike + contoh) – (konsentrasiContoh)
% Recovery = x 100%
konsentrasi spike

37058.0936 – 22324.05370
= x 100 %
15000

= 98.23 %