JP XII Physical&Inorganic Chemistry (24) - Prev Chaps + Inorg. Chem PDF

PHY./INO.
CHEMISTRY
TARGET : JEE (Main + Advanced) 2016
Course : VIJETA (JP) NO. 38 & 39
This DPP is to be discussed in the week (07.09.2015 to 12.09.2015)

DPP No. # 38 (JEE-MAIN)
Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]
ANSWER KEY DPP No. # 38

1. (D) 2. (A) 3. (B) 4. (B) 5. (A) 6. (D) 7. (C)
8. (D) 9. (B) 10. (D) 11. (B) 12. (B) 13. (C) 14. (C)
15. (B) 16. (C) 17. (A) 18. (D) 19. (C) 20. (B)
ANSWER KEY DPP No. # 39

1. (A) 2. (A) 3. (C) 4.* (BCD) 5.* (AD) 6.* (AC) 7.* (ACD)
8.* (ABC) 9.* (AC) 10. (B) 11. (C) 12. (B) 13. 45 cm 14._ x=6
15. 3 16. 06 17._ (A – p, q, s); (B – p, q, s) ; (C – p, s); (D – r, s)
M
1. The mass of 75% pure Glucose (C6H12O6) required to prepare 50 mL of its aqueous solution is :
9
M
75% 'kq) Xywdkst (C6H12O6) dk og nzO;eku] tks blds tyh; foy;u ds 50 mL dks cukus ds fy, vko';d gS] fuEu gS&
9
4
(A) 4 g (B) 1 mg (C) 1 g (D*) g
3
Moles of solute
Sol. Molarity =
Volume of solution (in L)
1 m / 180
 =
9 50 /1000
4
 m = mass of glucose required = 1 g % purity = 75 hence weight required = g.
3
gy eksyjrk = (L )
1 m / 180
 =  m = Xywdkst dk vko';d nzO;eku = 1 g
9 50 /1000
4
% 'kq)rk = 75 vr% vko';d Hkkj = g.
3
2. Atomic mass of Cesium is 133 u and atomic mass of Chlorine is 35.5 u. How many unit cell are present in
16.85 g of CsCl ?
lhft;e dk ijek.kq nzO;eku 133 u gS rFkk Dyksjhu dk ijek.kq nzO;eku 35.5 u gSA 16.85 g CsCl esa mifLFkr ,dd dksf"Bdk
dh la[;k fdruh gS \
(A*) 6.023 × 1022 (B) 1.204 × 1022 (C) 6.023 × 1021 (D) 1.204 × 10 23
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PAGE NO.- 1
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16.85
Sol. Unit cells ,dd dksf"Bdk = × 6.023 × 1023
168.5
3. The vapour pressure of a pure liquid A is 40 mmHg at 310 K. The vapour pressure of this liquid in a solution
with liquid B is 35 mm Hg. Mole fraction of A in the solution is 0.8 then
(a) It is non ideal solution having negative deviation.
(b) Temperature of system is decreased.
Find the correct statements.
(A) Only (a) (B*) Only (b) (C) (a) & (b) both (D) none
310 K ij ‘'kq) nzo A dk ok"inkc 40 mmHg gSA bl nzo dk] nzo B ds lkFk foy;u esa ok"i nkc 35 mmHg gSA foy;u
esa A dk eksy izHkkt 0.8 gS] rc&
(a) ;g vukn'kZ foy;u tks _.kkRed fopyu iznf'kZr djrk gSA
(b) fudk; dk rki ?kVrk gSA
lgh dFku dh igpku dhft, &
(A) dsoy (a) (B*) dsoy (b) (C) (a) o (b) nksuksa (D) buesa ls dksbZ ugha
4. At 900ºC Kp = 1.04 atm for the reaction

CaCO3(s)  CaO(s) + CO2(g). At low temperature 58.4 g CO2, 655 g CaO and 95 g CaCO3 are introduce
in 50 L reaction chamber. The temperature is raised to 900ºC amount of CaO will ……..
(A) increase (B*) decrease (C) remain same (D) none
fuEu vfHkfØ;k ds fy, 900ºC ij Kp = 1.04 atm
CaCO3(s)  CaO(s) + CO2(g). fuEu rki ij 58.4 g CO2, 655 g CaO rFkk 95 g CaCO3 dks 50 L vfHkfØ;k ik=k
esa ysrs gSA rkieku 900ºC rd c<+rk gSA CaO dh ek=kk gksxh %
(A) c<s+xh (B*) ?kVsxh (C) leku jgsxh (D) buesa ls dksbZ ugha
PV
Sol. nCO2 =
RT
1.04  50
=
0.0821 1173
= 0.53 mol
WCO2 = 23.75 g
QP > KP hence reaction goes to back.
QP > KP vr% vfHkfØ;k izrhi fn'kk esa tkrh gSA
5. 10Cl (aq) + 2MnO4– (aq) + 16H+ (aq) 5Cl2(g) + 2Mn2+(aq) + 8H2O()

–
The value of Eº for the above reaction at 25ºC is 0.15V. Hence, the value of K for this reaction is .
10Cl– (aq) + 2MnO4– (aq) + 16H+ (aq) 5Cl2(g) + 2Mn2+(aq) + 8H2O()
25ºC rki ij mijksDr vfHkfØ;k ds fy, Eº dk eku 0.15V gSA vr% bl vfHkfØ;k ds fy, K dk eku gS %
10Cl– (aq) + 2MnO4– (aq) + 16H+ (aq) 5Cl2(g) + 2Mn2+(aq) + 8H2O()
(A*) 2.4 × 1025 (B) 4.9 × 1012 (C) 1.2 × 1015 (D) 3.4 × 1020
0.0591
Sol. Eºcell = log Keq.
n
0.0591
0.15 = log Keq.
10
1.5
= log Keq. log K = 25.38 Keq. = 2.4 × 1025
0.0591
6. Which of the following statement is not correct about Ellingham diagram?
(A) G increases with an increases in temperature
(B) It consists of plots of fG vs T for formation of oxides
(C) A coupling reaction can be well expressed by this diagram
(D*) It express the kinetics of the reduction process
PAGE NO.- 2
,fyaxe vkjs[k (Ellingham diagram) ds lUnHkZ esa] fuEu esa ls dkSulk dFku lgh ugha gS\
(A) rki esa o`f) ds lkFk G c<+rk gSA
(B) vkWDlkbM ds fuekZ.k ds fy, ;g vkjs[k fG rFkk T ds e/; cuk;k tkrk gSA
(C) ;qXeu vfHkfØ;k dks bl vkjs[k }kjk HkyhHkkafr le>k ldrs gSA
(D*) ;g vkjs[k vip;u çØe dh cy xfrdh dks le>krk gSA
Sol. Ellingham diagrams are based on thermodynamic concepts. It does not tell anything about the kinetics of
the reduction process.
gy- ,fyaxe vkjs[k Å”ekxfrdh fl)kar ij vk/kkfjr gSA ;g vip;u çØe dh cy xfrdh ds lanHkZ esa dqN ugha crkrk gSA
7. The kinetic energy for 14 grams of nitrogen gas at 127°C is nearly (mol. mass of nitrogen = 28 and gas
constant = 8.31 JK–1 mol–1)
127 °C ij 14 xzke ukbVªkstu xSl ds fy, xfrt ÅtkZ yxHkx gksrh gS] (ukbVªkstu dk v.kqHkkj = 28 rFkk xSl fu;rkad =
8.31 JK–1 mol–1)
(A) 1.0 J (B) 4.15 J (C*) 2493 J (D) 3.3 J
3
Sol. Average K.E. for one mole = RT
2
1  3 8.314
Average K.E. for 14 g of N2  mole  = × × 400 = 2494 J.
2  2 2
3
gy- 1 eksy ds fy, vkSlr xfrt ÅtkZ = RT
2
1  3 8.314
14 g N2 dh vkSlr xfrt ÅtkZ  2 = × × 400 = 2494 J.
  2 2
8. Borax on heating strongly above its melting point melts to a liquid, which then solidifies to a transparent
mass commonly known as borax-bead. The transparent glassy mass consists of :
(A) sodium pyroborate (B) boric anhydride
(C) sodium meta-borate (D*) boric anhydride and sodium metaborate
cksjsDl blds xyukad ls Åij izcy :i ls xeZ djus ij nzo esa ifjofrZr gks tkrk gS] tks fd Bksl ikjn'khZ nzO;eku tks fd
lkekU;r% cksjsDl eudk ds :i esa tkuk tkrk gS] esa ifjofrZr gks tkrk gSA ikjn'khZ dk¡p tSlk nzO;eku fuEu dk cuk gksrk gS&
(A) lksfM;e ikbjkscksjV
s (B) cksfjd ,ugkbMªkbM
(C) lksfM;e esVkcksjsV (D*) cksfjd ,ugkbMªkbM o lksfM;e esVkcksjsV
Sol. 
Na2B4O7 10H2O  
 Na2B4O7  2NaBO2 + B2O3
Electrolysis in castner
9. Brine 
Kellner cell
(Products of cathode); A, B & C are
yo.kh; ty (Brine) ¼dSFkksM dk mRikn½; A, B o C fuEu gS&
A B C
(A) Na PH3 NaH2PO2
(B*) NaOH PH3 NaH2PO2
(C) NaOH Na3P NaH2PO4
(D) NaOH PH3 NaH2PO3
10. PCl3, when dissolved in excess as NaOH, give :

PCl3 dks tc NaOH ds vkf/kD; esa ?kksyk tkrk gS rks izkIr mRikn gksxk %
(A) NaH2PO2 (B) Na3PO4 (C) Na3PO3 (D*) Na2HPO3
PAGE NO.- 3
11. Which of the following coordination entities should be expected to absorb light of lowest frequency?
fuEu esa ls dkSulh milgla;ksth izfof'V fuEure vko`fr dk çdk'k vo'kksf"kr djrk gS \
(A) [Cr(en) ]3+
3
(B*) [CrCl6]3– (C) [Cr(NH3)6]3+ (D) [Cr(CN)6]3–
Sol. The coordination entity, for which crystal field splitting is smaller, absorbs light of lowest frequency. Weaker
the ligand field strength, smaller will be the crystal field splitting. The order of field strength of various ligands
is as CN– > en > NH > Cl–
3
Hence, [CrCl ]3– due to the presence of Cl– ligand absorbs light of lowest frequency.
6
Sol. milgla;ksth izfof'V] ftlds fy, fØLVy {ks=k foikVu de gksrk gS] mruk gh fuEure vko`fr vo'kksf"kr djrk gSA fyxsaM
{ks=k lkeF;Z ftruh de gksrh gS mruk gh fØLVy {ks=k foikVu de gksxkA fofHkUu fyxsaMks dh {ks=k lkeF;Z dk Øe fuEu gS&
CN– > en > NH > Cl–
3
vr% Cl fyxsaM dh mifLFkfr ds dkj.k [CrCl6]3– fuEure vko`fr dk izdk'k vo'kksf"kr djrk gSA
–
12. The straight chain polymer is formed by :

(A) hydrolysis of (CH3)3 SiCl followed by condensation polymerization.
(B*) hydrolysis of (CH3)2 SiCl2 followed by condensation polymerization.
(C) hydrolysis of (CH3) SiCl3 followed by condensation polymerization.
(D) hydrolysis of (CH3)4 Si followed by condensation polymerization.
ljy J`a[kyk cgqyd dk fuekZ.k fuEu }kjk fd;k tkrk gS %
(A) (CH3)3 SiCl dk ty&vi?kVu rRki'’pkr~ la?kuu cgqydhdj.k }kjk
(B*) (CH3)2 SiCl2 dk ty&vi?kVu rRki'’pkr~ la?kuu cgqydhdj.k }kjk
(C) (CH3) SiCl3 dk ty&vi?kVu rRki'’pkr~ la?kuu cgqydhdj.k }kjk
(D) (CH3)4 Si dk ty&vi?kVu rRi’pkr~ la?kuu cgqydhdj.k }kjk
13. Let the total number of orbitals in ath shell be 16 and value of azimuthal quantum number for the unpaired
electron in vanadium atom (Z = 23) be ‘b’, then find the sum (a + b).
ekuk fd ath dks'k esa d{kdksa dh dqy la[;k 16 gS rFkk osusfM;e ijek.kq (Z = 23) esa v;qfXer bysDVªkWu ds fy, f}xa'kh DokaVe
la[;k dk eku ‘b’ gS rc (a + b) ds ;ksx dk eku Kkr dhft,A
(A) 4 (B) 5 (C*) 6 (D) 3
th 2
Sol. Total number of orbitals in a shell = a = 16
 a = 4.
value of  for unpaired electron in V atom = 2. ( 3d orbital)
 b=2
 (a + b) = 4 + 2 = 6.
gy. a dks'k esa d{kdksa dh dqy la[;k = a2 = 16
th
 a = 4.
V ijek.kq esa] v;qfXer bysDVªkWu ds fy,  dk eku = 2. ( 3d d{kd)
 b=2
 (a + b) = 4 + 2 = 6.
14. W hich of the following orders of ionic radii is correctly represented?

fuEu esa ls dkSuls fodYi esa vk;fud f=kT;k dk Øe lgh :i ls iznf'kZr gS \
(A) H – > H + > H (B) Na + > F – > O 2– (C*) O2– > F– > Na + (D) Al3+ > Mg 2+ > N 3–
Sol. F – = 133 pm
O 2– = 140 pm
Na+ = 102 pm
15. Which of the following compound(s) is / are formed during the hydrolysis of PCl3 ?
PCl3 ds ty&vi?kVu ds nkSjku fuEu esa ls dkSulk@dkSuls ;kSfxd curk gS@gSa \
(A) POCl3 (B*) H3PO3 (C) HOCl (D) HClO3
PAGE NO.- 4
Sol.  
..
P + HCl
   
 2H2O Cl OH
Tautomerism   
Cl
Sol.  
..
P + HCl
  
)  2H2O Cl OH
(   
Cl
16. Which of the following is incorrect order ?

(A) F2 > Cl2 > Br2 > 2 (oxidising power) (B) F2 < Cl2 < Br2 < 2 (bond length)
(C*) F2 > Cl2 > Br2 > 2 (bond energy) (D) F2 < Cl2 < Br2 < 2 (boiling point)
fuEu esa ls dkSulk Øe lgh ugha gS \
(A) F2 > Cl2 > Br2 > 2 (vkWDlhdkjh {kerk) (B) F2 < Cl2 < Br2 < 2 (ca/k
yEckbZ)
(C*) F2 > Cl2 > Br2 > 2 (ca/k ÅtkZ) (D) F2 < Cl2 < Br2 < 2 (DoFkukad)
17. CsBr has b.c.c. structure with edge length 4.3 Å. The shortest inter ionic distance in between Cs + and
Br – is:
CsBr dks j yEckbZ 4.3 Å ds lkFk b.c.c. la jpuk j[krk gS rc Cs + rFkk Br – ds e/; U;wu re vUrjkvk;fud nwj h gS&
(A*) 3.72 (B) 1.86 (C) 7.44 (D) 4.3
3a 3  4.3
Sol. r+ + r– = = = 3.72 Å
2 2
18. The molar heat capacity ‘C’ of water at constant pressure is 75 JK–1 mol–1, when 1.0 kJ of heat is supplied to
100 g of water which is free to expand, the increase in temperature of water is :
(A) 4.8 K (B) 6.6 K (C) 1.2 K (D*) 2.4 K
ty dh fLFkj nkc ij eksyj Å"ek /kkfjrk] ‘C’ 75 twy K eksy gSaA 100 xzke- ty dks] tks fd izlkj.k ds fy, Lora=k gSa]
–1 –1
1.0 fdyks twy Å"ek nh tkrh gSa] tks ty ds rki esa o`f) gksrh %
(A) 4.8 K (B) 6.6 K (C) 1.2 K (D*) 2.4 K
q
Sol. C = n(T  T )
2 1
Given that fn;k x;k C = 75 JK-1 mol-1,
PAGE NO.- 5
q = 1.0 kJ = 1000 J
1000  100 
75 =  n  5.55 
5.55 x T  18 
1000
 T = 5.55 x75 = 2.4 K
19. An ideal gas is taken around the cycle ABCA as shown in P-V diagram. The value of q for the cycle is equal
to :
P-V js[kkfp=k eas n'kkZ;s vuqlkj pØh; ABCA izØe esa ,d vkn'kZ xSl dks fy;k tkrk gSA pØ ds nkSjku q dk eku fuEu
ds cjkcj gS &
(A) 7 P1V1 (B) –5 P1V1 (C*) 5 P1V1 (D) None of these

(A) 7 P1V1 (B) –5 P1V1 (C*) 5 P1V1 (D) buesa ls dksbZ ugha
Sol. Work done by the gas in the cyclic process = Area bounded (ABCA) = – 5 P 1V1
Therefore, q = – W = 5 P1V1 (cyclic process, so E = 0)
g y- pØh; çØe esa xSl }kjk fd;k x;k dqy dk;Z = lEc) {ks=kQy (ABCA) = 5P1V1
vr%, q = – W = 5 P1V1 (pfØ; izØe, vr% E = 0)
20. The following structures represent various silicate anions. Their formulas are respectively
fuEu lajpuk,¡ fofHkUu flfydsV _.kk;uksa dks iznf'kZr djrh gSA muds lw=k Øe'k% fuEu gSa&
(A) SiO44– & Si3O88– (B*) SiO44– & Si3O108–

(C) SiO42– & Si3O92– (D) SiO34– & Si3O108–
(A) SiO44– o Si3O88– (B*) SiO44– o Si3O108–
(C) SiO42– o Si3O92– (D) SiO34– o Si3O108–
PAGE NO.- 6
DPP No. # 39 (JEE-ADVANCED)
Total Marks : 66 Max. Time : 42 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.3 (3 marks, 2 min.) [09, 06]
Multiple choice objective ('–1' negative marking) Q.4 to Q.9 (4 marks, 2 min.) [24, 12]
Comprehension ('–1' negative marking) Q.10 to Q.12 (3 marks, 2 min.) [09, 06]
Integer type Questions ('–1' negative marking) Q.13 to Q.16 (4 marks 3 min.) [16, 12]
Match the Following (no negative marking) Q.17 (8 marks, 6 min.) [08, 06]
1. NH4ClO4 + HNO3(dilute)  HClO4 + [X]


[X]  Y(g)
[X] and [Y] are respectively.
(A*) NH4NO3 and N2O (B) NH4NO2 and N2
(C) HNO4 and O2 (D) None
NH4ClO4 + HNO3(ruq)  HClO4 + [X]


[X]  Y(g)
[X] rFkk [Y] Øe'k% gS
(A*) NH4NO3 rFkk N2O (B) NH4NO2 rFkk N2
(C) HNO4 rFkk O2 (D) dksbZ ugha
Sol. NH4ClO4 + HNO3  HClO4 + NH4NO3

2NH4NO3  2N2O + 4H2O
2. On the basis of following reactions, identify the correct matching

heat
A(aq) + Al   (B)(gas). (Colorless combustible gas which is lightest)
heat
A(aq) + C   PH3(gas).
heat
A(aq) + NH4Cl   (D)(gas) . (turns red litmus blue)
fuEu vfHkfØ;kvksa ds vk/kkj ij] lgh feyku dks igpkfu;s
A(aq) + Al  
 (B)(xSl). (jaxghu ngu'khy xSl] tksfd lcls gYdh xSl Hkh gS )
A(aq) + C  
 PH3(xSl).
A(aq) + NH4Cl  
 (D)(xSl). (yky fyVel dks uhyk dj nsrh gS)
(A*) A = NaOH, C = P4 (B) A = CH3COOH, B = CH4
(C) A = KOH, D = NH3, C = H3PO4 (D) A = HCl, B - H2, C = H3PO4
(E) A = H2SO4, D = HCl, C = P4
Sol. A = NaOH.
heat
NaOH + Al   
 NaAlO2 + H2 (g)
heat
NaOH + P4   
 NaH2PO2 + PH3
heat
NaOH + NH4Cl   
 NH3 + NaCl + H2O.
3. XeF2 reacts with PF3 to give :

XeF2 , PF3 ls vfHkfØ;k djds nsxk :
(A) XeF6 (B) [XeF]+ [PF6]– (C*) Xe + PF5 (D) [PF4]+ [XeF3]–
Sol. PF3 will be easily oxidized to PF5 by XeF2, a powerful oxidant.
XeF2 }kjk PF3 vklkuh ls PF5 esa vkWDlhd`r gks tkrk gSA ;g ,d 'kfDr'kkyh vkWDlhdkjd gSA
PAGE NO.- 7
4.* Aqueous solution of hydrogen peroxide :
(A) turns blue litmus pink
(B*) gives bright blue colour in ether with acidified K2Cr2O7 solution.
(C*) gives yellow or orange coloured solution with an acidified solution of titanium salt.
(D*) bleaches blue litmus.
gkbMªkstu ijvkWDlkbM dk tyh; foy;u&
(A) uhys fyVel dks xqykch djrk gSA
(B*) vEyhd`r K2Cr2O7 foy;u ds lkFk bZFkj esa pedhyk uhyk jax nsrk gSA
(C*) VkbZVsfu;e yo.k ds vEyhd`r foy;u ds lkFk ihyk vFkok ukjaxh foy;u nsrk gSA
(D*) uhys fyVel dks fojaftr djrk gSA
5.* Which of the following order(s) is / are incorrect ?

(A*) H3PO4 > H3PO3 > H3PO2 (reducing character)
(B) N2O < NO < N2O3 < N2O5 (oxidation state on nitrogen atom.)
(C) NH3 > PH3 > AsH3 > SbH3 (basicity.)
(D*) SbH3 > NH3 > AsH3 > PH3 (reducing character.)
fuEu esa dkSulk@dkSuls Øe xyr gS ?
(A*) H3PO4 > H3PO3 > H3PO2 (vipk;d xq.k)
(B) N2O < NO < N2O3 < N2O5 (ukbVªkstu ijek.kq dh vkWDlhdj.k voLFkk )
(C) NH3 > PH3 > AsH3 > SbH3 ({kkjdrk)
(D*) SbH3 > NH3 > AsH3 > PH3 (vipk;d xq.k)
6.* ClO– formed in the following reaction

Cl2 + 2OH –  ClO – + Cl– + H 2O
In this reaction :
(A*) Cl2 has undergone disproportionation
(B) Cl2 has been reduced to ClO – and Cl–
(C*) equivalent mass of Cl2 is equal to its molar mass
(D) equivalent mass of Cl 2 is half of its molar mass
ClO – fuEu vfHkfØ;k esa curk gS
Cl2 + 2OH –  ClO – + Cl– + H 2O
bl vfHkfØ;k esa&
(A*) Cl2 dk fo"kekuqikru gksrk gSA
(B) Cl2 dks ClO – rFkk Cl– esas vipf;r fd;k tkrk gSA
(C*) Cl2 dk rqY;kadh Hkkj] blds eksyj Hkkj ds cjkcj gksrk gSA
(D) Cl2 dk rqY;kadh Hkkj] blds eksyj Hkkj dk vk/kk gksrk gSA
7.* An energy of 40.8 eV is required to excite a Hydrogen-like species from 1 st Bohr orbit to second. Which
is/are correct statement(s) :
(A*) Atomic number of H-like species is 2.
(B) Ionisation energy of H-like species is 122.4 eV.
(C*) Kinetic energy of electron in 1st orbit is 54.4 eV.
(D*) Energy of second orbit is –13.6 eV.
,d gkbMªkstu leku Lihf'kt esa izFke cksj d{kk ls f}rh; d{kk esa mRrstu ds fy, 40.8 eV dh ÅtkZ vko';d gSA rc fuEu
esa ls dkSulk@dkSuls dFku lgh gS@gSa %
(A*) H- leku Lihf'kt dk ijek.kq Øekad 2 gSA
(B) H-leku Lihf'kt dh vk;uu ÅtkZ 122.4 eV gSA
(C*) 1st d{kk esa bysDVªkWu dh xfrt ÅtkZ 54.4 eV gSA
(D*) f}rh; d{kk dh ÅtkZ –13.6 eV gSA
PAGE NO.- 8
Sol. E2 – E1 = E
1 1 3 2
40.8 = 13.6 Z2  1  4  = 13.6  Z
  4
Z2 = 4  Z = 2
IE = 13.6 Z2 = 13.6  22 = 54.4 ev
KE1 = 13.6 Z2 = 13.6  22 = 54.4 ev
13 .6  22
E2 = – = – 13.6 ev
22
8.* An aqueous solution of iodine become colorless on adding ?

(A*) Excess of Na2S2O3 solution (B*) Excess of Cl2 water
(C*) Excess of NaOH solution (D) Excess of NaBr solution
vk;ksMhu ds tyh; foy;u esa D;k feykus ij ;g jaxghu gks tkrk gS \

(A*) Na2S2O3 foy;u dk vkf/kD; (B*) Cl2 ty dk vkf/kD;
(C*) NaOH foy;u dk vkf/kD; (D) NaBr foy;u dk vkf/kD;
Sol. 2 + 2S2O32–  – + S4O62–
2 + Cl2 + H2O  O3– + Cl–
2 + NaOH  NaO3 + Na

Br– + 2 does not show reaction.
Br– + 2 vfHkfØ;k ugha n'kkZrs gSA
9.* Which of the following plots represent the correct variation of of strong electrocyte ?
(A*) (B)
(C*) (D)
fuEu esa ls dkSulk vkjs[k] izcy fo|qrvi?kV~; ds fy, ds lgh ifjorZu dks iznf'kZr djrk gS \
(A*) (B)
(C*) (D)
PAGE NO.- 9
Sol. For strong electrolytes
0
= m – b c
1
dilution = .
concentrat ion
Sol. izcy fo|qrvi?kV~; ds fy,
0
= m – b c
1
ruqrk = .
COMPREHENSION # (Q.10 to Q.12)

Take two sealed glass bulbs A and B with same sample of oxide of nitrogen at same pressure. At room
temperature both the bulb have light reddish brown colour because of components in A and B bulbs are at
equilibrium. When bulb 'B' is heated at 883 K, then gas becomes colourless due to formation of another
oxide of nitrogen (X). Compound of bulb (B) can be prepared by oxidation of (X) by air. Compound (X) is
slightly heavier than water and when dissolved in acidified FeSO 4 solution a dark colour nitrosyl complex of
iron (Y) is obtained.
vuqPNsn # (Q.10 to Q.12)
leku nkc ij] nks lhy can dk¡p ds cYc A rFkk B esa ukbVªkstu ds vkWDlkbM ds leku uewus ysrs gSA dejs ds rki ij nksuksa
cYc gYdk yky Hkwjk jax j[krs gS] D;ksafd A rFkk B cYcksa esa ?kVd lkE; ij gSA tc cYc 'B' dks 883 K ij xeZ djrs gS]
rc ukbVªkstu ds vU; vkWDlkbM (X) ds fuekZ.k ds dkj.k xSl jaxghu gks tkrh gSA ok;q ls (X) ds vkWDlhdj.k }kjk cYc dk
;kSfxd cuk;k tk ldrk gSA ;kSfxd (X) ty dh rqyuk esa gYdk lk Hkkjh gksrk gS rFkk tc bls vEyh; FeSO4 foy;u esa
?kksyrs gS rc yksgs dk ,d xgjs jax dk ukbVªksfly ladqy (Y) izkIr gksrk gSA
10. The IUPAC name of (Y) is :

(A) Tetraaquonitrosyliron (I) ion (B*) Pentaaquonitrosyliron (I) ion
(C) Pentaaquonitrosyliron (II) ion (D) Pentaaquonitroiron (I) ion
(Y) dk IUPAC uke gS %
(A) VªsVk,DokukbVªksflyvk;ju (I) vk;u (B*) isUVk,DokukbVªksflyvk;ju (I) vk;u
(C) isUVk,DokukbVªksflyvk;ju (II) vk;u (D) isUVk,DokukbVªksvk;ju (I) vk;u
SOl. FeSO4 + NO + 5H2O  [Fe(H2O)5NO+]SO4
brown ring complex
11. The (X) is -
(X) gS &
(A) N2O3 (B) N2O4 (C*) NO (D) NO2
SOl. 2NO2  heat
  2NO + O2
(x)
12. Which of the following is/are correct when the bulb (A) is placed in ice -
(A) The intensity of brown colour will be greatly reduced due to decomposition to the lower oxide.
(B*) The intensity of brown colour will be greatly reduced due to dimersation.
(C) The intensity of brown colour will be increased.
(D) The colour of the complex change from brown to pale blue.
cYc (A) dks cQZ esa j[kus ij fuEu esa ls dkSulk@dkSuls dFku lgh gS&
(A) fuEu vkWDlkbM esa fo?kVu ds dkj.k Hkwjs jax dh rhozrk cgqr rsth ls ?kVrh gSA
(B*) f}ydhdj.k ds dkj.k Hkwjs jax dh rhozrk cgqr rsth ls ?kVrh gSA
(C) Hkwjs jax dh rhozrk c<+sxhA
(D) ladqy dk jax Hkwjs ls gYdk uhyk gks tkrk gSA
PAGE NO.- 10
SOl. 2NO2 N 2 O4
brown colour colour less
on decreasing the temperature equilibrium will shift in forward direction.
2NO2 N 2 O4
Hkwjk jax jaxghu
rki ?kVus ij lkE; vkxs dh vksj foLFkkfir gks tkrk gSA
13.
If the above tube is kept vertically with open end downward then find the length of the air column in the 2 nd
column ? [Hg = 13.6 gm/ml]
;fn mijksDr ufydk dks Åij ls [kqyk rFkk uhps ls cUn j[kk tkrk gS rks 2nd vk;u esa okqLrEe dh yEckbZ Kkr dhft,A
[Hg = 13.6 gm/ml]
Ans. 45 cm
Sol. Patm = 75 cm of Hg
10 × 6.8 = 13.6 × h1
 h1 = 5 cm of Hg
(Pgas)2 (PxSl)2 = 75 + 5 + 10 = 90 cm of Hg
(Pgas)2 = 75 – 5 – 10 = 60 cm of Hg
 P1V1 = P2V2
60 x = 90 × 30
 x = 45 cm
14._ One mole each of benzene (PB0 = 600 torr), toluene (PT0 = 400 torr) and mercury (Pm0 = 100 torr) are mixed
in a well-stirred container and allowed to reach equilibrium with their vapors.The vapors are formed in very
little amount. Vapor pressure of this mixture is 100 x (torr). Find x.
,d ik=k esa csathu (PB0 = 600 torr), VkWyqbZu (PT0 = 400 torr) o edZjh (Pm0 = 100 torr) izR;sd ds ,d eksy dks fefJr djrs
gS rFkk budh ok"i ds lkFk lkE;koLFkk LFkkfir gksus nsrs gSA ok"i vfr lw{e ek=kk esa curh gSaA bl feJ.k dk ok"i nkc 100
x (torr) gSA x dk eku Kkr dhft,A
Ans. x=6
PAGE NO.- 11
Sol. Benzene and toluene are miscible with each other while Hg dissolves in neither. For benzene and toluene :
P = xBPB0 + xTPT0 = 500 torr.
Immiscible mercury has independent vapor pressure of 100 torr.
Hence P = 500 + 100 = 600 torr = 100x
 x = 6.
Sol. csathu o VkWyqbZu ,d nwljs esa feJ.kh; gS tcfd Hg fdlh esa Hkh foy; ugha gksrk gSA csathu o VkWyqbZu ds fy, %
P = xBPB0 + xTPT0 = 500 torr.
vfeJ.kh; edZjh dk Lora=k ok"i nkc 100 torr gSA
vr% P = 500 + 100 = 600 torr = 100x
 x = 6.
15. How many among the following species contain P–P bond(s) :
fuEu esa ls fdruh Lih'kht esa P–P cU/k mifLFkr gS %
(i) P (red) yky (ii) H4P2O5 (iii) H4P2O7
(iv) (PO3–)3 (v) (PO3–)2 (vi) P4O10
(vii) P4S3 (viii) P4O6 (ix) P4
Ans. 3
Sol. (i) (ii) (iii)
(iv) (v) (vi)
(vii) (viii) (ix) 7
16. How many of the following compounds liberate NH3 on heating ?

fuEu ;kSfxdksa esa ls fdrus ;kSfxd xeZ djus ij NH3 eqDr djrs gS \
(NH4)2SO4 ; NH4HCO3 ; NH4Cl ; NH4NO3 ; (NH4)2 Cr2O7; FeSO4·(NH4)2SO4 ·6H2O; (NH4)2SO4·Al2(SO4)3
·6H2O; Mg(NH4)PO4; NH4ClO4
Ans. 06
Sol. (NH4)2SO4 ; NH4HCO3 ; NH4Cl ; FeSO4·(NH4)2SO4 ·6H2O; (NH4)2SO4·Al2(SO4)3 ·6H2O; Mg(NH4)PO4;
Ammonium salts containing oxidising anions on heating liberates N 2 or N2O.
veksfu;e yo.k vkWDlhdj.k _`.kk;u j[krk gS ftls xeZ djus ij N2 ;k N2O eqDr gksrk gSA
PAGE NO.- 12
17._ Match the following (one or more than one)
Column - I Column - II
(i ) 415K
(A) H3PO2 ( 
ii) 435K
(p) One of the products acts as reducing agent.
435 K
(B) PCl3 + H2O  (q) One of the products is tribasic and non reducing.

(C) NO2 + H2O  (r) Dehydration

(D) HNO3 + P4O10   (s) In one of the products the central atom is in +5 oxidation state.
fuEu dks lqesfyr dhft, ¼,d ;k ,d ls vf/kd½
LrEHk- I LrEHk- II
(i ) 415K
(A) H3PO2 ( 
ii) 435K
(p) ,d mRikn vipk;d dh rjg O;ogkj djrk gSA
435 K
(B) PCl3 + H2O  (q) ,d mRikn f=k{kkjh; rFkk vu~vipk;d gksrk gSa

(C) NO2 + H2O  (r) futZyhdj.k

(D) HNO3 + P4O10   (s) ,d mRikn esa dsUnzh; ijek.kq dh vkWDlhdj.k voLFkk +5 gksrh gSA
Ans. (A – p, q, s); (B – p, q, s) ; (C – p, s); (D – r, s)
415 K
Hint : (A) 3H3PO2   2H3PO3 + PH3 
435 K
4H3PO3   3H3 PO 4  PH3
(B) Hydrolysis
PCl3 + 3H2O   H3PO3 + 3HCl
 
435 K
4H3PO3   3H3 PO 4  PH3 
(C) 2NO2 + H2O  HNO2 + HNO3

(D) 4HNO3 + P4O10  4HP O3  2 N 2O
5
* PH3 and HNO2 act as reducing agents.
PAGE NO.- 13

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PHY./INO.

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 38 & 39

This DPP is to be discussed in the week (07.09.2015 to 12.09.2015)

ANSWER KEY DPP No. # 38

ANSWER KEY DPP No. # 39

4. At 900ºC Kp = 1.04 atm for the reaction

5. 10Cl (aq) + 2MnO4– (aq) + 16H+ (aq) 5Cl2(g) + 2Mn2+(aq) + 8H2O()

yo.kh; ty (Brine) ¼dSFkksM dk mRikn½; A, B o C fuEu gS&

10. PCl3, when dissolved in excess as NaOH, give :

12. The straight chain polymer is formed by :

14. W hich of the following orders of ionic radii is correctly represented?

16. Which of the following is incorrect order ?

Given that fn;k x;k C = 75 JK-1 mol-1,

(A) 7 P1V1 (B) –5 P1V1 (C*) 5 P1V1 (D) None of these

(A) SiO44– & Si3O88– (B*) SiO44– & Si3O108–

1. NH4ClO4 + HNO3(dilute)  HClO4 + [X]

NH4ClO4 + HNO3(ruq)  HClO4 + [X]

2. On the basis of following reactions, identify the correct matching

3. XeF2 reacts with PF3 to give :

5.* Which of the following order(s) is / are incorrect ?

6.* ClO– formed in the following reaction

8.* An aqueous solution of iodine become colorless on adding ?

vk;ksMhu ds tyh; foy;u esa D;k feykus ij ;g jaxghu gks tkrk gS \

2 + Cl2 + H2O  O3– + Cl–

2 + NaOH  NaO3 + Na

COMPREHENSION # (Q.10 to Q.12)

10. The IUPAC name of (Y) is :

Sol. (i) (ii) (iii)

(iv) (v) (vi)

(vii) (viii) (ix) 7

16. How many of the following compounds liberate NH3 on heating ?

(C) NO2 + H2O  (r) Dehydration

(C) NO2 + H2O  (r) futZyhdj.k

(C) 2NO2 + H2O  HNO2 + HNO3

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