– the clean way to turn high-sulphur residues into power and steam
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Refinery overview
H2S
Visbreaker
Refinery overview
H2S
Power / Steam
CLAUS Units
Sulphuric Acid
Visbreaker or
Delayed Coker Heavy Residues (Tar/Coke)
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Sulphur challenges
More sulphur in less sulphur out..?
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SNOX – the future solution
Replace expensive fuels in steam boiler plant with
heavy residues Excessive amounts of SO2 and NOx
in the flue gas
No waste products
Valuable products $
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SO2 < 200 mg/Nm3
SNOXTM – 100°C
NOx < 75 mg/Nm3
Dust < 2 mg/Nm3
Direct utilization of heat from H2S gas and SWS gas for HP steam
generation
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SNOXTM vs. Limestone scrubbing
STEAM and PREHEATED
COMBUSTION AIR CLEANED GAS
+$
FLUE GAS
SNOXTM SULPHURIC ACID
+$
–$
Limestone
scrubber
Topsøe SNOXTM
SULPHUR IN FUEL %
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SNOX vs. wet FGD
(800 MW - 7% sulphur in the petcoke)
Conventional wet
SNOX
FGD process
SO2 removal efficiency 95-98% > 98%
CaCO3 consumption 340,000 t/year 0
CaSOx disposal 588,000 t/year 0
Water consumption 2,100,000 m3/year 0
Waste water 504,000 m3/year 0
Net plant electrical efficiency 38% 40.7%
Coke consumption 2,545,200 t/year 2,377,200 t/hr
Sulphuric acid 0 350,000 t/year
and
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Case story – Petrobras Brazil
Petrobras Pernambuco Refinery
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Why PETROBRAS chose the SNOXTM
technology
Avoid limestone and gypsum in the refinery
- Infrastructure, storage
- Avoid dust and CO2 emission
Energy efficiency
- Recycle of hot, preheated air to the boilers
- Production of medium pressure steam
Petcoke
Boilers Flue gas
Heavy fuel oil SNOX
(3)
(2)
Tail
H2S gas (4 units) Claus gas
(2)
Elemental sulphur
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Petrobras RNEST SNOXTM – birds view
Stack
SO2 converter SCR reactor
Gas/gas heat
WSA condensers
exchanger
Flue gas
blowers
Cooling air
ESP’s blowers
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References on SNOX
AGIP, Gela Refinery
– No. of boilers: 4 (total 1,200 MWth)
– Fuel: Petcoke (88%)
– Total gas flow: 1,200,000 Nm3/h
– H2SO4 (95%): 384 mtpd
– Commissioned: 1999
References on SNOX
OMV Refinery, Austria
– Boiler: 180 MWe + 1,000 t/h steam
– Fuel: Liquid HS residues + Claus tail gas
– Total gas flow: 820,000 Nm3/h
– H2SO4 (93%): 225 mtpd
– Commissioned: 2007
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Summary for SNOX
No consumption of absorbents and water
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Thank you for your attention
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