Aiits 1820 Ot Jeea Paper 2

FIITJEE
ALL INDIA INTEGRATED TEST SERIES

OPEN TEST
JEE (Advanced)-2020
PAPER – 2
TEST DATE: 03-02-2019
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
SECTION – A
1. ABCD
Sol. Equilibrium of piston gives
kx0
PS  kx0 or P PS kx0
S
Since, the chamber is thermally insulated Q = 0
 Elastic potential energy of spring = work done by gas
1 2
or work done by gas = kx0
2
This work is done in the expense of internal energy of the gas.
1 2
Therefore, internal energy of the gas is decreased by kx0 .
2
Internal energy of an ideal gas depends on its temperature only. Internal energy of the gas is
decreasing. Therefore, temperature of the gas will decrease.
2. ABC
Sol. At steady state, the rate of heat gain and the rate of heat loss are equal.
3. ABCD
 1
Sol. F  3iˆ  4ˆj, Wcon.f  Ui  Uf  34  9  25 & mv 2  16 = 34
2
4. BC
m 2gh Mm
Sol. Velocity of m when the string just become taut = upward and acceleration = g
Mm Mm
downward.
2m 2gh M  m 2m 2h
 t 
M  m (M  m)g M  m g
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AIITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/20 2
2
1  m 2gh  1 2  Mm 
E = (M  m) 
2
  m
 Mm  2  2gh  = 
Mm
 gh
 
5. A
1
Sol. sin (45° – r) > and

1
 sin r = 1 sin 45° =
2
1 1 1 1
sin r =  cos r  sin r 
 2 2 2 
2
 1  sin2 r  sin r 

2
 2 2 1  45°
 1  sin r    
   2 
 r
2
 2  1
 sin2 r  1    45° r r
 2  45° r
1 9 45° 45°
  1 2
45°+ r
2 45° r
 2  2
45°
 2 > 5 ; > 5 45°
6. ABD
Sol. Bernoulli’s theorem for an orifice at depth ‘x’ in liquid ‘3d’.
H  1
Po +  dg  3dg.x  = Po +  3d  v z …(1)
2  2
H 1
 x  gt 2 …(2)
2 2
R = Vt …(3)
Solve for R and apply maxima/minima.
7. B
 Fr  R  F r  R 
Sol. For (P)   Ia     2 2

I MR  MR 2MR2
  0 and aCM  0, so  P   1
For (Q)   0 but aCM  0, so  Q   4
(R)  4
(S),   0 and aCm  0, so (S)  2,4
8. A
Sol. Velocity of the wave in the wire AB
T 160
v1    80 m/s
1 0.12 / 4.8
Velocity of the wave in the wire BC
3 AIITS-OT-(Paper-2)-PCM(Sol.)-JEE(Advanced)/20
T 160
v2    32 m/s
2 0.4 / 2.56
Amplitude of the reflected wave
 v  v1  32  80
ar   2  ai   3.5  1.5 cm
 v1  v 2  32  80
Negative sign signifies that reflected wave is inverted.
2v 2 2  32
Amplitude of the transmitted wave a t  a   3.5  2.0 cm
v1  v 2 t 32  80
Equation of the reflected wave y r  1.5 sin(t  kx)
 Resultant wave equation in the wire AB
y  3.5 sin( t  kx)  1.5 sin(t  kx)
y  1.5 sin( t  kx)  1.5 sin(t  kx)  2.0 sin( t  kx)
y  3.0 sinkx cos t  2.0 sin(t  kx)
Maximum displacement of the nodes in the wire AB = 2.0 cm
ar2 1.5  1.5
Fraction of power transmitted in the wire BC  1   1  0.82
ai2 3.5  3.5
9. D
GM 1 1 1  1 1 1 
Sol. (P) EP = 0, EQ = 2
, VP = GM     , VQ = GM    
x  R 2R 3R   x 2R 3R 
Where R < x < 2R
 (P)  1,2,5
R
GM   2
(Q) EP =
 3   GM ; V  GM 3R 2   R    26 GM
P    
R3 3R2 2R3   3   57 R
GM GM GM
EQ = 2
 2
; VQ 
( 2 R) 2R 2R
EP 2 VP 26 2
  ;   1  Q  1,2
E Q 3 VQ 57
GM E
(R) Ep = 0 ; EQ = 2
 P = 0
R EQ
R R R
G dm G(4 x 2 dx)f  M 
VP =     4 G  3  
xdx
R/2 x R/2 x  4 / 3 R  R/2
3GM  2 R2 
= R  
2R3  4
3 GM
=
8 R
GM VP 3
VQ = ;  
R VQ 8
 R  1,2,5
2GM 4GM
(S) | VP | 
2
R 5R
R2   
2
GM GM GM  1 
| VQ |    1 
R R 2  R2 R  2
VP 4 2
   1
VQ 5( 2  1)
E
EP = 0  P  0  S  1,2,5
EQ
10. B
(2n  1)v
Sol. For closed pipe,   and for first overtone, n = 1
4L
nv
For open pipe,   and for fourth harmonic, n = 4.
2L
SECTION – D
11. 00006.28
Sol. Let elongation of spring be x0 in equilibrium. Then,
2T  mg sin   2kx 0 …(i)
and T  mg …(ii)
Let Block B is displaced by x down the inclination
F.B.D. of B 2k(x0 + 2x)
maB  2k(x 0  2x)  2T   mg sin  …(iii)
aB
F.B.D. of A
mg – T  = maA
Also, a A  2aB
2T 
mg sin
T   mg  2maB
maB  2kx 0  4kx  2mg  4maB  mg sin 
maB  4kx  4maB T
4k
aB   x
5m aA
5m
 T  2
4k mg
T = 6.28 s.
12. 00005.00
Sol. At stable equilibrium, U is minimum.
dU d2U
= 0 and >0
dx dx 2
1  x 3 ax 2 
=    20x  = 0.
dx  3 2 

 x2 – 9x + 20 = 0.
 (x – 5) (x – 4) = 0.
x = 5 and x = 4 are points of equilibrium.
d2U
And U minimum when > 0. i.e. at x = 5.00
dx 2
13. 00003.60
Sol.  external force does not work on system
So, according to concept of mass
36x = 9 × (18 – x)
x = 3.60 m.
14. 00059.00
Sol. Using work energy theorem,
mgs  mgh
s = 40 m (where is the total distance travelled on the rough surface)
15. 00008.00
1 1 
Sol. 50(0.4)2  10    50(0.4)2  4  6.25(0.2)2  
2  2 
w = 8.00
16. 00006.00
Sol. For equilibrium of the cylinder in the horizontal direction.
In the vertical direction, N2 + N1 = F + Mg …………….. (ii)

Solving these two equations with F = 40 N, M = 2 kg and  = 1/3,
we get
N1 = 18 N
and N2 = 54 N
Now, Fd = (N1 + N2)r
  N1  N2  r 1 / 3 18  54 0.1
 d = = 6.00 cm.
F 40
17. 00005.00
Sol. 5gl2  gl1
l1
 5
l2
18. 00002.50
Sol. Velocity of ball when it hits the floor,
V0  2gH = 100 m/s
Normal impulse on the ball when it hits the floor,
JN = meV0 – (– mV0) = mV0 (1 + e)
 Frictional impulse Jf = JN = mV0 (1 + e)
So velocity of ball immediately after collision
Vertical velocity : vy = eV0 = 50 ms–1 ;
Jf –1
Horizontal velocity v x = = V0 (1 + e) = 50 ms
m
So time taken to hit the wall after it strikes the floor is given by,
x = v xt = 250 = 50 t
 t = 5 seconds
1 2 1 1
 h = v yt – gt = 50t – × 10 × t 2 = 50 × 5 – × 10 × 25 = 125 m.
2 2 2
Chemistry PART – II
SECTION – A
19. ABCD
Sol. A = Li+ being smallest in size shows maximum hydration
B = Solubility increases from LiOH to CsOH due to increased ionic character (Fajan’s rule)
1
C = Lattice energy 
size of cation
+ +
D = Li will attract H more strongly because size of Li is smaller
20. C
st nd
Sol. Let ‘x’ no. of moles transferred from 1 to 2 container
xRT2
P(2v)  II container
3
P(v)  (0.1  x)RT2 Ist container
On solving
WI 1

WII 6
21. BC
Sol. Using VSEPR theory and hybridization concepts
22. CD
Sol. HNO3 + CH3COONa  CH3COOH + NaNO3
(excess)
will form an acidic buffer containing (CH3COOH and CH3COONa)
23. A
Sol. nfactor of FeSO4  1
nfactor of FeC2 O 4  3
Hence geq. of FeSO 4  g  e.q of KMnO 4
12 = 5x  (1)
geq. of FeC2O4 = geq of KMnO4
32 = 5y
Hence x/y = 1/3
24. ABCD
Sol. Precipitation for a salt will occur when its Qip (ionic product) > Ksp (salt) (solubility product)
2
i.e., Ba2   F    K sp BaF2 
25. A
2+ 2
Sol. (P) CaC2 is an ionic compound comprising of Ca and C2
CaC2  2H2O  Ca  OH 2  HC  CH
(Q) TiC  H2O  Ti  OH4  CH4
(R) SiC is covalent (network) solid it does not undergo hydrolysis.
26. A
Sol. H 2S + NaOH  NaHS + H2O
(100 ml, 0.01 M) 1M
NaHS + NaOH  Na2S + H2O
When no NaOH is added:
The significant reaction producing H+ will be

H2S  
 HS + H
+
0.01 – x x x
x2 x2
 K a1 H2S   
0.01  x 0.01
where [H+] = x = 10–4.5  pH = 4.5
When 0.5 ml of NaOH is added, buffer of H2S and NaHS will be formed and
pH  pK a1  log
NaHS
H2S
Here in this case, [NaHS] = [H2S]  pH  pK a1  7
When 1.0 ml of NaOH is added, first end point reached and NaHS alone will be present
pK a1  pK a1 21
for which pH    10.5
2 2
27. C
Sol. CH3
H Br Anti Eli
(P) Stereospecific
H Br Zn
CH3
(Q) SN2 then Anti Eli
Ph OH Ph Ph
H+ 
+
(R)
Ph
Br
+
H EtONa
(S) E2
CH3 EtOH
28. D
Sol. Fact based
SECTION – D
29. 00004.80 to 00005.00

Sol. P = 1 atm, T = 298 K
Cu  4 M  2NO3  2NO 2  Cu2  2H2O
63.6 g of Cu gives 2 moles of NO2
6.36 g of Cu would give 0.2 moles of NO2
PV = nRT
0.2  0.0821 298
VNO2   4.893 CV
1
30. 00077.5
Sol. 

X  g  
 Y  g
100 0
at equm 100 – 20 20
= 80
20 1
K C    0.25
80 4


X  g   Y  g
80 20
80 + x – y +y
20 + y = 35.5  y = 35.5 – 20 = 15.5
20  y 35.5
   0.25
80  x  y 64.5  x
On solving x = 77.5
31. 00009.25
Sol. For basic buffer mixtures:
pOH  pK b  log
Salt 
Base
Also, pH = 14 – pOH
Hence, pH = 9.25
32. 00000.96
Sol. 

PCl5 
 PCl3  Cl2
t=0 1 0 0
t = teq (1 - )  
n
nPCl3  nCl2  P 
So, K p   
nPCl5   n 
So, Kp = 0.0404 atm
Similarly, when  = 0.2 P = 0.969 atm
33. 00060.00
actual yield
Sol. %yield   100
theoritical yield
34. 00235.60
Sol. Ca  HCO3 2  H2SO4 
 CaSO4  2CO2  2H2O
 Moles of H2SO4  Moles of Ca(HCO3)2  Moles of CaCO3
200  11.78  10 3 = 2.356  10–3 mole = (2.356  10–3  100)g = 0.2356 g

1000
103 g water has 0.2356 g CaCO3
 106 g water has = 0.2356  103 = 235.6 g CaCO3
 Degree of hardness = 235.6 ppm
35. 00051.75
Sol. obs  4.8
Dipole moment of the molecule having 100% ionic character is
   
ionic  4.8  10 10  1.27  108 = 6.096  10–18 = 6.096 D
obs 3.15468
 % ionic character =  100   100  51.75%
ionic 6.096
36. 00001.30 to 00001.40

Sol. MACOHCACOH  MNaOH VNaOH
MACOH  20  18  1.5
18  1.5
MACOH   1.35
20
Mathematics PART – III
SECTION – A
37. AB
Sol. Note that S  0 and min. S  0 for z1  z 2  z3
Thus,   0
2 2 2
Since a  b  a  b  ab  ab, we get
2 2 2
z 2  z3  z3  z1  z1  z 2

 6  z2 z3  z2 z3  z3 z1  z3 z1  z1 z2  z1z 2 
 6  z1  z 2  z 3   z 2  z 3  z1   z 3  z1  z 2  (1)
2
Also 0  z1  z 2  z 3
2 2 2
 z1  z2  z3  z1  z2  z3   z 2  z3  z1   z3  z1  z3 
 z1  z 2  z 3   z 2  z 3  z1   z 3  z1  z 2   3 (2)
Thus, from (1) and (2), we get
2 2 2
z 2  z3  z3  z1  z1  z 2  9
The value 9 is attained when z1  1 z 2   z3  2
where   1 is a cube root of unity.
38. AD
Sol. Area POA = 2|x|, are POB = 3|y|
39. ABD
 t3   2 
Sol. a,b,c are roots of    m t  3   n  0
  
 t  1  t 1 
40. BD
Sol. 
xn  1   x  1 x    x  2 ..... x  n1   
d
1  2x  ....   n  1 xn2   x    ........  x      x     x    ......  x    by
2 n 1 2 n 1
dx
differentiating wrto x and put x  
41. BC
4
Sol. x 4  y4   x  y 

 2xy 2x 2  3xy  2y 2  0 
 two real and two complex roots
42. B
Sol. EF = Distance between AC and BD
EF  2 | f( ) |
AC = 2PE
AE = EC = PE
AC = 2 (OP – OE)
 | f( ) | 
= 2  2  
 2 
 | f(  ) | 
BD  2  2  
 2 
AC + BD = 4 2 
1
Area of trapezium ABCD = (AC + BD) EF
2
4 2. 2 | f( ) |

2
 4 | f( ) |
k
| f( ) |

43. C
Sol. (P) z  x  iy, Re(z2 )  Re(z  z)  x 2  y2  2x  x2  y 2  2x  0 Rectangular hyperbola
(Q) conceptual
i
z
( R) 2  1 isacircle
z 1 2
1 1  i z  1  i  z  1
(S) z  i 
2 2 2
PS = ePM, where S is the focus and 1  i  z  1  i z  1 is equation of directrix.
44. D
9 3
Sol. 2 Rr  3  r  
43 4
r x 1
   x 1
R x3 4
 3
tan 
2 4
D C
y
 

2 2
3
R
x r
/2
A B
 
y  R cot   
2 2
 9
 3 tan 
2 4
ABCD is a rhombus with side

9 25
4 
4 4
Area of ABCD
3
2 
25 25 25 25 4
  sin   
4 4 4 4 9
1
16
75 1
A  d1d2
2 2
 d1d2  75
2
d12 d22 625  d1  d2   2d1d2
  
4 4 16 4
 d1  d2  35 / 2
45. A
c 2 3 1
Sol. B  60o , sinC  sinB    and C  45o
b 3 2 2
A  75  cos  A  C   cos 30  sin 60o  sinB
o o
B 
sin  A  C   sin   , sin  A  C   sin 2B and
2
B
sin  2C  A   sin15o  sin  
4
46. B
 1 
Sol. Here L   1, 
 2
Tangent at L is x  2y  2
1
Normal at L is 2 x  y 
2
1   5 
T = (2, 0), N   , 0  , M   2, 
2   2
SECTION – D
47. 00000.08
Sol. Let x  n, where n  integers  n  0 
4n  9
 an2  4n  9  0  a 
n2
 4n  9  2
 n is root of equation  2  x  4x  9  0
 n 
Let the other root be  .
9 9n 2  4n  9   n  18
  n     2
 
 4n  9  / n 4n  9 4n  9
n  18
2
4n  9
 9 
If  is integer then n  18  4n  9  n   , 9  ~ 0
 5 
Moreover, n is an integer n  1, 1, 2, 3, 4, 5, 6, 7, 8, 9
It is only for n  2,3,9 that  is an integer.
1
 n  2; a  
4
1
n  3; a 
3
1
n  9; a 
3
1 1
 possible values of ‘a’ are and
4 3
48. 00002.00
Sol.
 3nC0  3nC1x  3nC2 x 2  .......  3nC3n x 3n …………(i)
3n
1  x 
Put x  1, , 2
23n  3nC0  3nC1  3nC 2  .......  3nC3n ………..(ii)
 3nC0  3nC1  3nC22  .......  3nC3n3n …………….(iii)

3n
1  
3n …………..(iv)
1    2
 3nC0  3nC12  3nC2 4  .......  3nC3n 6n
Equation (ii) gives S  23n  8n
n
(ii) + (ii) + (iv) we get

3n 3n
8n  1     1  2   3  3n
C0  3nC3  ...........  3nC3n 
3n 3n

Sn  2      3 Tn
n
Sn   1  2   3Tn
n
 Sn  3Tn  2  1
49. 00000.05
12!
Sol. The number of ways of putting 12 objects in 3 cells, four in each cell is 3
 4!
12!
If the cell are identical, we get 3
.
3!  4!
50. 00000.83
Sol. Suppose k  2  log2 a  3  log3 b  log6  a  b  , then we have a  2k 2, b  3k 3 , a  b  6k ,
1 1 ab 6k
and therefore,    k  2 k  3  22  33 .
a b ab 2 3
51. 00002.00
Sol. Let   a  ib and   a  ib
from     2 3 we here b  3
 3
Since  is real
2   2
3
3
We conclude that  is real, since  a  ib   
 a a2  3b2  ib 3a2  b2  
2 2
We have 3a  b  0  a  1
Hence   a 2  b2  2
52. 00001.50
Sol.
P(1, 5) P(2, 1)
(h, k)
 k  5  k 1
We have     1
 h 1  h  2 
 Locus of (h, k) is x2 + y2 – 3x + 4y – 3 = 0
53. 00000.47
x C
Sol. cos ec15 
1
 x  cos ec15
4 1
=1  15
6 2  1
x
=1 6  2
54. 00002.00
Sol. Given that a, b, c are in G.P.
2
So, b  ac …..(i)
ab
x …..(ii)
2
bc
y …..(iii)
2
a c 2a 2c 2  ab  bc  2ca 
Now    
x y a  b b  c ab  ac  b2  bc
2  ab  bc  2ca 
 2. b2  ac 
 ab  ac  ac  bc 

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FIITJEE

ALL INDIA INTEGRATED TEST SERIES

TEST DATE: 03-02-2019

ANSWERS, HINTS & SOLUTIONS

In the vertical direction, N2 + N1 = F + Mg …………….. (ii)

29. 00004.80 to 00005.00

36. 00001.30 to 00001.40

Mathematics PART – III

ABCD is a rhombus with side

23n  3nC0  3nC1  3nC 2  .......  3nC3n ………..(ii)

 3nC0  3nC1  3nC22  .......  3nC3n3n …………….(iii)

(ii) + (ii) + (iv) we get

P(1, 5) P(2, 1)

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