ELECTROQUÍMICA

2 +1 +5 -2 +1 -2 +2 -2 0 +1 -2
𝐇𝐍𝐎𝟒 +𝐇𝟐𝐒−→ +𝐍𝐎 + 𝐒 + 𝐇𝟐 𝐎
.
+5 +2
2 𝐍+ 𝟑𝒆− →𝐍

3 -2 0
𝐒 → 𝐒 + 𝟐𝒆−

𝟐 𝑵 + 𝟔𝒆− → 𝟐𝐍

𝟑 𝐒 → 𝟑𝐒 + 𝟔𝒆−

𝟐𝐇𝐍𝐎𝟒+𝟑𝐇𝟐 𝐒−→ +𝟐𝐍𝐎 + 𝟑𝐒 + 𝟒𝐇𝟐 𝐎

3 +1 +7 -2 +2 -1 +1 +6 -2 +1 -1 +2 +6 -2 +3 -1 +1 -2
𝟏𝐊𝐌𝐧𝐎𝟒 + 𝟓𝐅𝐞𝐂𝐥𝟐 + 𝐇𝟐 𝐒𝐎𝟒 → 𝐊𝐂𝐥 + 𝟏𝐌𝐧𝐒𝐎𝟒 + 𝟓𝐅𝐞𝐂𝐥𝟑 + 𝐇𝟐 𝐎
.
+1 +7 -2 +2 +6 -2
1 𝐊𝐌𝐧𝐎𝟒 + 𝟓𝒆− → 𝐌𝐧𝐒𝐎𝟒
+2 -1 +3 -1
5
𝐅𝐞𝐂𝐥𝟐 → 𝐅𝐞𝐂𝐥𝟑 + 𝟏𝒆−

𝟏𝐊𝐌𝐧𝐎𝟒 + 𝟓𝒆− → 𝟏𝐌𝐧𝐒𝐎𝟒

𝟓𝐅𝐞𝐂𝐥𝟐 → 𝟓𝐅𝐞𝐂𝐥𝟑 + 𝟓𝒆−

𝟏𝐊𝐌𝐧𝐎𝟒 + 𝟓𝐅𝐞𝐂𝐥𝟐 → 𝟏𝐌𝐧𝐒𝐎𝟒 + 𝟓𝐅𝐞𝐂𝐥𝟑

4. +1 +7 -2 +1 -1 +1 +6 -2 +1 +6 -2 +2 +6 -2 0 +1 --2
𝟐𝐊𝐌𝐧𝐎𝟒 + 𝟏𝟎𝐊𝐂𝐥 + 𝟖𝐇𝟐 𝐒𝐎𝟒 → 𝟐𝑲𝟐 𝐒𝐎𝟒 + 𝟐𝐌𝐧𝐒𝐎𝟒 + 𝟓𝐂𝐥𝟐 + 𝟖𝐇𝟐 𝐎

+1 +7 -2 +2 +6 -2
1 𝐊𝐌𝐧𝐎𝟒 + 𝟓𝒆− → 𝐌𝐧𝐒𝐎𝟒
+1 -1 0
5
𝐊𝐂𝐥 → 𝐂𝐥𝟐 + 𝟏𝒆−

𝟏𝐊𝐌𝐧𝐎𝟒 + 𝟓𝒆− → 𝟏𝐌𝐧𝐒𝐎𝟒

𝟓𝐊𝐂𝐥 → 𝟓𝐂𝐥𝟐 + 𝟓𝒆−

𝟐𝐊𝐌𝐧𝐎𝟒 + 𝟏𝟎𝐊𝐂𝐥 → 𝟐𝐌𝐧𝐒𝐎𝟒 + 𝟓𝐂𝐥𝟐

5. +1 +6 -2 +1 -2 +1 +6 -2 +3 +6 -2 0 +1 +6 -2 +1 --2
𝟏𝐊 𝟐 𝐂𝐫𝟐 𝐎𝟕 + 𝟑𝐇𝟐 𝐒 + 𝟒𝐇𝟐 𝐒𝐎𝟒 → 𝟏𝐂𝐫𝟐 (𝐒𝐎𝟒 )𝟑 + 𝟑𝐒 + 𝑲𝟐 𝐒𝐎𝟒 + 𝟕𝐇𝟐 𝐎

+1 +6 -2 +3 +6 -2
2 𝐊 𝟐 𝐂𝐫𝟐 𝐎𝟕 + 𝟑𝒆− → 𝐂𝐫𝟐 (𝐒𝐎𝟒 )𝟑
+1 -2 0
3
𝐇𝟐 𝐒 → 𝐒 + 𝟐𝒆−

𝟐𝐊𝟐 𝐂𝐫𝟐 𝐎𝟕 + 𝟔𝒆− → 𝟏𝐂𝐫𝟐 (𝐒𝐎𝟒 )𝟑

𝟑𝐇𝟐 𝐒 → 𝟑𝐒 + 𝟔𝒆−

𝟏𝐊𝟐 𝐂𝐫𝟐 𝐎𝟕 + 𝟑𝐇𝟐 𝐒 → 𝟏𝐂𝐫𝟐 (𝐒𝐎𝟒 )𝟑 + 𝟑𝐒

 0 +1 -2 +1 +1 +5 -2 +1 -1 +1 -2
6. 𝟔𝐂𝐥𝟐 + 𝟏𝟐𝐊𝐎𝐇 → 𝟐𝐊𝐂𝐥𝐎𝟑 + 𝟏𝟎𝐊𝐂𝐥 + 𝟔𝐇𝟐 𝐎
0 +1 +5 -2
1 𝐂𝐥𝟐 + 𝟏𝟎𝒆𝟏 → 𝟐𝐊𝐂𝐥𝐎𝟑

0 +1 -1
5 𝐂𝐥𝟐 → 𝟐𝐊𝐂𝐥 + 𝟐𝒆−

𝐂𝐥𝟐 + 𝟏𝟎𝒆− → 𝟐 𝐊𝐂𝐥𝐎𝟑

𝟓𝐂𝐥𝟐 → 𝟏𝟎𝐊𝐂𝐋 + 𝟏𝟎𝐞−

𝟔𝐂𝐥𝟐 → 𝟐 𝐊𝐂𝐥𝐎𝟑 + 𝟏𝟎𝐊𝐂𝐋

 +1 -1 +1 +7 -2 +4 -2 +1 -2 +1 0 +1 -2
7. 𝟑𝐇𝟐 𝐎𝟐 + 𝟐𝐊𝐌𝐧𝐎𝟒 → 𝟐𝐌𝐧𝐎𝟐 + 𝟐𝐊𝐎𝐇 + 𝟑𝟎𝟐 + 𝟐𝐇𝟐 𝐎

+1 +7 -2 +4 -2
1 𝟐𝐊𝐌𝐧𝐎𝟒 + 𝟔𝒆− → 𝟐𝐌𝐧𝐎𝟐
+1 -1 0
3 𝐇𝟐 𝐎𝟐 → 𝟎𝟐 + 𝟐𝒆−

𝟐𝐊𝐌𝐧𝐎𝟒 + 𝟔𝒆− → 𝟐𝐌𝐧𝐎𝟐

𝟑𝐇𝟐 𝐎𝟐 → 𝟑𝟎𝟐 + 𝟔𝒆−

𝟐𝐊𝐌𝐧𝐎𝟒 + 𝟑𝐇𝟐 𝐎𝟐 → 𝟐𝐌𝐧𝐎𝟐 + 𝟑𝟎𝟐

8. +1 +3 -2 +1 +7 -2 +1 +6 -2 +1 +5 -2 +2 +6 -2 +1 +6 -2 +1 -2
𝟓𝐇𝐍𝐎𝟐 + 𝟐𝐊𝐌𝐧𝐎𝟒 + 𝟑𝐇𝟐 𝐒𝐎𝟒 → 𝟓𝐇𝐍𝐎𝟑 + 𝟐𝐌𝐧𝐒𝐎𝟒 + 𝟏𝐊 𝟐 𝐒𝐎𝟒 + 𝟑𝐇𝟐 𝐎

+1 +7 -2 +2 +6 -2
2 𝐊𝐌𝐧𝐎𝟒 + 𝟓𝒆− → 𝐌𝐧𝐒𝐎𝟒
+1 +3 -2 +1 +5 -2
5
𝐇𝐍𝐎𝟐 → 𝐇𝐍𝐎𝟑 + 𝟐𝒆−

𝟐𝐊𝐌𝐧𝐎𝟒 + 𝟏𝟎𝒆− → 𝟐𝐌𝐧𝐒𝐎𝟒

𝟓𝐇𝐍𝐎𝟐 → 𝟓𝐇𝐍𝐎𝟑 + 𝟏𝟎𝒆−

𝟐𝐊𝐌𝐧𝐎𝟒 + 𝟓𝐇𝐍𝐎𝟐 → 𝟐𝐌𝐧𝐒𝐎𝟒 + 𝟓𝐇𝐍𝐎𝟑

 +3 -1 0 +1 -2 +1 +1 +7 -2 +1 +6 -2 +1-1 +1 -2
9. 𝐂𝐫𝐈𝟑 + 𝐂𝐥𝟐 + 𝐊𝐎𝐇 → 𝐊𝐈𝐎𝟒 + 𝐊𝟐𝐂𝐫𝐎𝟒 + 𝐊𝐂𝐥 𝟔𝐇𝟐𝐎
0 +1 +5 -2
27 𝐂𝐥𝟐 + 𝟐𝒆− → 𝟐𝐊𝐂𝐥𝐎𝟑

+3 -1 +6 +7
2 𝐂𝒓 + 𝑰𝟑 𝟐𝟕𝒆− → 𝐂𝐫 + 𝟑𝐈

𝟐𝐂𝐫𝐈𝟑 + 𝟐𝟕𝐂𝐥𝟐 + 𝟔𝟒𝐊𝐎𝐇 → 𝟔𝐊𝐈𝐎𝟒 + 𝟐𝐊𝟐𝐂𝐫𝐎𝟒 + 𝟓𝟒𝐊𝐂𝐥 + 𝟑𝟐𝐇𝟐 𝐎

 +1 +6 -2 +2 +6 -2 +1 -1 +3 -1 +3 +6 -2 +3-1 +1 -2
10. K2Cr2O7 + FeSO4 + HCl → CrCl3 + Fe2(SO4)3 + FeCl3 + H2O

2Fe+2S+6O-24 → Fe+32(S+6O-24)3 + 2e-

Fe+2S+6O-24 → Fe+3Cl-13 + e-
K+12Cr+62O-27 + 6e- → 2Cr+3Cl-13

K2Cr2O7 + 6FeSO4 + 7HCl → 2CrCl3 +2 Fe2(SO4)3 + 2FeCl3 + 7H2O

11. 𝟑𝐂𝐥𝟐 + 𝟔𝐍𝐚𝐎𝐇 → 𝟓𝐍𝐚𝐂𝐥 + 𝟏𝐍𝐚𝐂𝐥𝑶𝟑 + 𝟑𝐇𝟐 𝐎
0 -1
10 𝐂𝐥𝟐 + 𝟐𝒆− → 𝟐𝐂𝐥

0 -5 -2
2 𝟏𝟐𝟎𝐇 + 𝐂𝐥𝟐 → 𝟐𝐂𝐥𝑶𝟑 + 𝟏𝟎𝒆− + 𝟔𝑯𝟐 𝑶

𝟏𝟎𝐂𝐥𝟐 + 𝟐𝟎𝒆− → 𝟐𝟎𝐂𝐥

𝟐𝟒𝟎𝐇 + 𝟐𝐂𝐥𝟐 → 𝟒𝐂𝐥𝑶𝟑 + 𝟐𝟎𝒆− + 𝟏𝟐𝑯𝟐 𝑶

𝟏𝟐𝐂𝐥𝟐 + 𝟐𝟒𝐎𝐇 → 𝟐𝟎 𝐂𝐥 + 𝟒𝐂𝐥𝑶𝟑 + 𝟏𝟐𝑯𝟐 𝑶

𝟑𝐂𝐥𝟐 + 𝟔𝐎𝐇 → 𝟓 𝐂𝐥 + 𝟏𝐂𝐥𝑶𝟑 + 𝟑𝑯𝟐 𝑶

 +3 -1 0 +1 -2 -1 +1 +7 -2 +1 +7 -2 +1 -1 +1 -2
12. 𝟏𝐂𝐫𝐂𝐥𝟑 + 𝟐𝐂𝐥𝟐 + 𝟖𝐊𝐎𝐇 → 𝟏𝐊𝐂𝐫𝑶𝟒 + 𝟎𝐊𝐈𝑶𝟒 + 𝟕𝐊𝐂𝐥 + 𝟒𝐇𝟐 𝐎
0 -1
4 𝐂𝐥𝟐 + 𝟐𝒆− → 𝟐𝐂𝐥

+3 -7 -2
2 𝟖𝟎𝐇 + 𝐂𝐫 → 𝐂𝐫𝑶𝟒 + 𝟒𝒆− + 𝟒𝑯𝟐 𝑶

𝟒𝐂𝐥𝟐 + 𝟖𝒆− → 𝟖𝐂𝐥

𝟏𝟔𝟎𝐇 + 𝟐𝐂𝐫 → 𝟐𝐂𝐫𝑶𝟒 + 𝟖𝒆− + 𝟖𝑯𝟐 𝑶

𝟒𝐂𝐥𝟐 + 𝟏𝟔𝐎𝐇 + 𝟐𝐂𝐫 → 𝟖𝐂𝐥 + 𝟐𝐂𝐫𝑶𝟒 + 𝟖𝑯𝟐 𝑶

𝟐𝐂𝐥𝟐 + 𝟖𝐎𝐇 + 𝟏𝐂𝐫 → 𝟒𝐂𝐥 + 𝟏𝐂𝐫𝑶𝟒 + 𝟒𝑯𝟐 𝑶

 +3 -2 +1 +1 -2 +1 -2 +1 +1 +5 -2 +1 -1 +1 -2
13. 1Bi2O3 + 2NaClO + 2NaOH → 2NaBiO3 + 2NaCl+ 1H2O
+1 -1
4 𝐇𝟐 𝐎 + 𝐂𝐥𝐎 + 𝟐𝒆− → 𝐂𝐥 + 𝟐𝟎𝐇

+3 -5 -2
2 𝟏𝟐𝟎𝐇 + 𝐁𝒊𝟐 → 𝟐𝐁𝐢𝑶𝟑 + 𝟒𝒆− + 𝟔𝑯𝟐 𝑶

𝟒𝐇𝟐 𝐎 + 𝟒𝐂𝐥 + 𝟖𝒆− → 𝟒𝐂𝐥 +𝟖𝟎𝐇

𝟐𝟒𝟎𝐇 + 𝟐𝐁𝒊𝟐 → 𝟒𝐁𝐢𝑶𝟑 + 𝟖𝒆− + 𝟏𝟐𝑯𝟐 𝑶

𝟒𝐂𝐥 + 𝟏𝟔𝐎𝐇 + 𝟐𝐁𝒊𝟐 → 𝟒𝐂𝐥 + 𝟒𝐁𝐢𝑶𝟑 + 𝟖𝑯𝟐 𝑶

𝟐𝐂𝐥 + 𝟖𝐎𝐇 + 𝟏𝐁𝒊𝟐 → 𝟐𝐂𝐥 + 𝟐𝐁𝐢𝑶𝟑 + 𝟒𝑯𝟐 𝑶

14. +2 -1 0 +1 -2 +3 -2 +1
𝟒𝐌𝐧(𝐎𝐇)𝟐 + 𝐎𝟐 + 𝟑𝐇𝟐 𝐎 → 𝟒𝐌𝐧(𝐎𝐇)𝟑

0 -2 +1
1 𝟔𝐎𝐇+𝐎𝟐 + 𝟒𝒆− → (𝐎𝐇)𝟑 + 𝟑𝐇𝟐 𝐎

+2 +3 -2 +1
4 𝐌𝐧(𝐎𝐇)𝟐 → 𝐌𝐧(𝐎𝐇)𝟑 + 𝟏𝒆−

𝟔𝐎𝐇+𝐎𝟐 + 𝟒𝒆− → (𝐎𝐇)𝟑 + 𝟑𝐇𝟐 𝐎

𝟒𝐌𝐧(𝐎𝐇)𝟐 → 𝟒𝐌𝐧(𝐎𝐇)𝟑 + 𝟒𝒆−

𝐎𝟐 + 𝟒𝐌𝐧(𝐎𝐇)𝟐 → 𝟒𝐌𝐧(𝐎𝐇)𝟑 + 𝟑𝐇𝟐 𝐎

 0 +1 +5 -2 +1 -2 +1 +5 -2 +1 -1
15. 𝟒𝐏𝟒 + 𝟓𝐊𝐂𝐥𝐎𝟑 + 𝟏𝟔𝐇𝟐 𝐎 → 𝟏𝟔𝐇𝟑 𝐏𝟎𝟒 + 𝟓𝐊𝐂𝐥

0 +1 +5 -2
4 𝟖𝑯+ + 𝐏𝟒 + 𝟓𝒆− → 𝟒𝐇𝟑 𝐏𝟎𝟒 + 𝟒𝐇𝟐 𝐎

+1 +5 -2 +1 -1
5 𝐊𝐂𝐥𝐎𝟑 → 𝐊𝐂𝐥 + +𝟒𝒆−

𝟑𝟐𝑯+ + 𝟒𝐏𝟒 + 𝟐𝟎𝒆− → 𝟏𝟔𝐇𝟑 𝐏𝟎𝟒 + 𝟏𝟔𝐇𝟐 𝐎

𝟓𝐊𝐂𝐥𝐎𝟑 → 𝟓𝐊𝐂𝐥 + +𝟐𝟎𝒆−

𝟑𝟐𝑯+ + 𝟒𝐏𝟒 + 𝟓𝐊𝐂𝐥𝐎𝟑 → 𝟓𝐊𝐂𝐥 + 𝟏𝟔𝐇𝟑 𝐏𝟎𝟒 + 𝟏𝟔𝐇𝟐 𝐎