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Volume

Volume Labu
Konsentrasi
Takar yang
NO Standar Induk Luas Area
Dipergunakan Kosentrasi deret
yang dipindahkan standar yang
(mL)
(mL) dibuat (mg/L)
1 0.0 500 9181.24
2 0.0 10 1000 9778.90
3 0.0 1500 10354.06
Slope (b) 1.1728
Intersept (a) 8598.58
Koefisien Korelasi (r) 0.9999

Bobot Rerata Volume Sampel C terukur Luas Area C sampel


Bobot Sampel (mg)
Tablet (mg) (L) (mg/L) Sampel (mg/Kg)

60 504.47 9190.23 84077.98


686.5 60.2 458.94 9136.83 76617.13
0.01
59.9 495.31 9179.49 82277.48
Rata-rata 60.0333333333 486.24 9168.85 80990.86
C sampel
(mg/Tablet)

57.72 3893.279
52.60 0.000687
56.48 2.672736
55.60
DATA KETIDAKPASTIAN ASAL KURVA KALIBRASI

Deret
Xi ( mg/L) Yi (abs) Yc (abs) (Yi-Yc)^2 (Xi-Xr)
Standar
1 500 9181.24 9184.9900 14.0625 -500
2 1000 9778.90 9771.4000 56.25 0
3 1500 10354.06 10357.8100 14.0625 500
Rata-Rata 1000 9771.4 9771.4000 28.1250 0.0000
Jumlah 3000 29314.2 29314.2000 84.3750 0.0000
Yo (Rata-Rata abs Sampel)
Slope (b)
Intersept (a)
n (banyaknya deret)
n-2
S y/x
S y/x : slope (b)
1+1/n
(Yo-Yr)^2
b^2 * ∑(Xi-Xr)^2
(Yo-Yr)^2 : b^2 * ∑(Xi-Xr)^2
Ketidakpastian asal Kurva Kalibrasi

C Kafein terukur Kadar Kafein Kadar Kafein


Ulangan Luas Area larutan uji Dalam Sampel Dalam Sampel Keterangan
(mg/L) (mg/Kg) (mg/Tablet)
1 9190.23 504.47 84077.98 57.72
2 9136.83 458.94 76617.13 52.60
3 9179.49 495.31 82277.48 56.48
Rerata 9168.85 486.24 80990.86 55.60
Ketidakpastian Asal Faktor Presiis 3893.2793344383
RSD 0.0480706001
%RSD 4.80%
y = a+bx

(Xi-Xr)^2 std (ppm)

250000 500
0 1000
250000 1500
166666.6667 rata2
500000.0000 R
9168.85 Slope (b)
1.1728 Intersept
8598.5800 1000
3
1
9.1856
7.8321
1.3
363066.50
687753.3762
0.527902174
10.6850
luas area
sampel Abs
9181.24 1 9190.23
9778.90 2 9136.83
10354.06 3 9179.49
9771.4000 rata 9168.85
0.9999386646
1.17282
8598.58
LABU TAKAR µ Volume Labu
Takar ( mL )

Koefisien Muai Air Vol Variasi µ (Efek T)


Ketidakpastian Asal k
(C-1) (mL) suhu (0C) (mL)
Temperatur
0.00021 10 7 1.732050808 0.008487049
0.0167440537
Ketidakpastian Asal Data Kal.Spek Pabrik k µ Kal (mL)
Spesifikasi ( mL )
(Kalibrasi) pabrik
0.03 1.7320508076 0.014433757

PENIMBANGAN
µ Penimbangan
Data Kal. Spek Alat (mg) k µ Kal
Ketidakpastian asal
spesifikasi
penimbangan 0.4 2 0.2 0.2828427125
(Neraca Analitik )
PARAMETER SIMBOL NILAI (x) SATUAN
KURVA KALIBRASI REG 486.2383 mg/L
PRESIS METODE PM 80990.86188339 mg/Kg
LABU TAKAR LT 10.0000 mL
PENIMBANGAN P 60.0333 mg
KADAR Thiamin/Kg Csx 80990.8619 mg/Kg

80990.86 ± 8599.81
PELAPORAN
(8.10 ± 0.86) %b/b
KETIDAKPASTIAN HASIL HASIL^2
10.6850 0.0219749063 0.0004828965
3893.2793344383 0.0480706001 0.0023107826
0.0167 0.0016744054 2.80363333E-06
0.2828 0.0047114277 2.21975514E-05
JUMLAH 0.0028186803
µ Csx/Csx 0.0530912449
µ Csx 4299.90568458
µ 95 8599.81136916