2 NaCl 2 H2O 2 NaOH Cl2 H2

M 137 1,038.66 0 0 0
R 125 125.00 125 63 63
S 12 913.66 125 63 63

1 Hitung Stream 7 dengan asumsi stream 7

2 Stoikiometrinya cari reaktan
3 Hitung dari stream 1 & 3
steam 3 %w/w dapat massa dan mol
4 Hitung Stream 2
5 hitung stream 4 & 5 dari stoikiometri
6 Hitung steam 6
7 dapat komponen stream 6 dari tabel 3
8 massa air distream 6 dari tabel 2 (massa total stream 6)

Sehingga di cek
Inlet = 26,708.3
Outlet = 26,708.3

Jawaban Soal :
1 Konversi Total NaCl =(mol mula NaCl - mol akhir NaCl) / mol mula NaCl
Konversi Total NaCl = 91.26%
Pembentukan NaOH = massa NaOH / massa mula NaCl
Pembentukan NaOH = 62.402%
2 Massa Cl2 / lb produk = massa Cl2 / massa total produk
Massa Cl2 / lb produk = 0.166146646 lb / lb produk
Total Produk = stream 4 + 5 + 7 + 8
Total Produk = 26,708.3

3 H2O terevaporasi = massa H2O terevaporasi / massa total produk

H2O terevaporasi = 0.45475819 lb / lb produk
 2NaCL + 2H2O 2NaOH + Cl2 + H2

Asumsi Molar Rate Flow Produk = 10,000 lbm/h

Inlet
Komponen BM (lbm / lb mole) <1>
n x Mass xm
NaCl 58.5 137 1 8,013 1
H2O 18
Cl2 71
H2 2
NaOH 40
Total 137 1 8,013 1

Inlet
Komponen BM (lbm / lb mole) <3>
n x Mass xm
NaCl 58.5 137 0.1165 8,013 0.3
H2O 18 1,039 0.8835 18,696 0.7
Cl2 71 - - - -
H2 2 - - - -
NaOH 40 - - - -
Total 1,176 1 26,708 1
26,708

Inlet
Komponen BM (lbm / lb mole) <6>
n x Mass r
NaCl 58.5 12 0.0114 700 0.0316
H2O 18 913.7 0.8696 16,445.8 0.7426
Cl2 71
H2 2
NaOH 40 125 0.1190 5,000 0.2258
Total 1,050.6 1.0 22,145.8 1.0
22,145.8
 Stream 3 = 30% w/w, maka

Inlet Outlet
<2> <3>
n x Mass xm n x Mass xm
137 0.1165 8,013 0.3
1,038.66 1 18,696 1 1,038.66 0.8835 18,696 0.7

1,038.66 1 18,696 1 1,176 1 26,708 1

26,708

Outlet
<4> <5> <6>
n x Mass xm n x Mass xm n
12
913.7
62.5 1 4,438 1
62.5 1 125 1
125
62.5 1 4,438 1 63 1 125 1 1,050.6

Outlet
<7> <8>
n x Mass xm n x Mass xm
12 0.0318 700 0.07
239 0.6356 4,300 0.43 674.8 1 12,146 1

125 0.3326 5,000 0.50

376 1 10,000 1 674.8 1.0 12,146 1
 <6>
x Mass xm
0.0114 700 0.0316
0.8696 16,446 0.7426

0.1190 5,000 0.2258

1 22,146 1
 OMB CMB
F=W+P G=F+R Penyelesaian
F = 100 + P G=R+W+P 1 Hitung neraca massa tanpa recycle dengan asumsi P
2 Hitung besar stream recycle ( R )
maka, 3 Hitung Stream F
R=G-F
comp A xa R = xa G - xa F
R= 240 -0.20 F F = (R-240)/-0.2

comp B xb R = xb G - xb F
0= 360 -0.80 F F = (360/0.8)

maka, nilai R adalah Jawaban :

-5 R + 1200 = 450
5R = 750
R = 150 kg
 Perhitungan Tanpa Recycle

xm =
W A

Separator
G G P
xm =
Process xm =
A 0.40 A
B 0.60 B
1.00

Asumsi P = 500 kg
Inlet Outlet
Komponen Stream G Stream W Stream P
xm Mass xm Mass xm Mass
A 0.40 240 1 100 0.05 25
B 0.60 360 - - 0.95 475
e dengan asumsi P Total 1 600 1 100 1 500
sehingga
Inlet Outlet
Komponen Stream F Stream R Stream G
xm Mass xm Mass xm Mass
A 0.20 90 1.00 150 0.40 240
B 0.80 360 - - 0.60 360
Total 1 450 1 150 1 600

kg R/ kg feed (F) = 0.33333333 kg R/kg feed

kg R/ kg feed (G) = 0.25 kg R/kg feed
1.00

0.05
0.95
1.00
 T
P

R 5 H
D
F
J

B A
1 C
2 G
3
E K
L

N 4 M

Mula
Reaksi
Sisa

Mula
Reaksi
Sisa

Langkah Penyelesaian
1 merah Mula
2 aqua Reaksi
3 ungu Sisa
4 jingga
5 hijau

Mula
Reaksi
Sisa

Mula
Reaksi
Sisa
Produk Hidrogen = 100 ton/day
Produk Hidrogen = 4166.667 kg/h
Produk Hidrogen = 2083.333 kgmol/h

Reaksi 3

6 FeCl2 8 H2O 2 Fe3O4 12 HCl 2 H2

6250 8333.333 0 0 0
6250 8333.333 2083.333 12500 2083.333
0 0 2083.333 12500 2083.333
Reaksi 2

6 FeCl3 6 FeCl2 3 Cl2

6250 0 0
6250 6250 3125
0 6250 3125
Reaksi 5

3 Cl2 3 H2O 6 HCl 1.5 O2

3125 3125 0 0
3125 3125 6250 1562.5
0 0 6250 1562.5
Reaksi 4

2 Fe3O4 0.5 O2 3 Fe2O3

2083.333 572.9167 0
2083.333 520.8333 3125
0 52.08333 3125
Reaksi 1 tanpa tambahan Fe2O3

3 Fe2O3 18 HCl 6 FeCl3 9 H2O

2604.167 15625 0 0
2604.167 15625 5208.333 2604.167
0 0 5208.333 2604.167
 Stream A

Maka, stream B adalah Stream A - Fe 2O3 dari reaksi 4

Fe2O3 Pada Stream B = -520.833 kgmol/h
Sehingga Neraca Massa Overall-nya dapat dituliskan sebagai berikut
Reaksi 3
Inlet Outlet
Komponen BM (kg/kgmol)
n x Mass xm n
Fe2O3 160 - - - 0 -
Fe3O4 232 - - - 0 2,083.33
FeCl2 127 6,250.00 0.43 793,750.00 0.84106 -
FeCl3 162.5 - - - 0 -
HCl 36.46 - - - 0 12,500.00
H2O 18 8,333.33 0.57 150,000.00 0.15894 -
Cl2 71 - - - 0 -
O2 32 - - - 0 -
H2 2 - - - 0 2,083.33
Total 14,583.33 1 943,750.00 1 16,666.67
Reaksi 2
Inlet Outlet
Komponen BM (kg/kgmol)
n x Mass xm n
Fe2O3 160 - - - 0 -
Fe3O4 232 - - - 0 -
FeCl2 127 - - - 0 6,250.00
FeCl3 162.5 6,250.00 0.43 1,015,625.00 1.076159 -
HCl 36.46 - - - 0 -
H2O 18 - - - 0 -
Cl2 71 - - - 0 3,125.00
O2 32 - - - 0 -
H2 2 - - - 0 -
Total 6,250.00 0 1,015,625.00 1 9,375.00
Reaksi 5
Inlet Outlet
Komponen BM (kg/kgmol)
n x Mass xm n
Fe2O3 160 - - - 0 -
Fe3O4 232 - - - 0 -
FeCl2 127 - - - 0 -
FeCl3 162.5 - - - 0 -
HCl 36.46 - - - 0 6,250.00
 H2O 18 3,125.00 0.21 56,250.00 0.059603 -
Cl2 71 3,125.00 0.21 221,875.00 0.235099 -
O2 32 - - - 0 1,562.50
H2 2 - - - 0 -
Total 6,250.00 0 278,125.00 0 7,812.50
Reaksi 4
Inlet Outlet
Komponen BM (kg/kgmol)
n x Mass xm n
Fe2O3 160 - - - 0 3,125.00
Fe3O4 232 2,083.33 0.14 483,333.33 0.512141 -
FeCl2 127 - - - 0 -
FeCl3 162.5 - - - 0 -
HCl 36.46 - - - 0 -
H2O 18 - - - 0 -
Cl2 71 - - - 0 -
O2 32 572.92 0.04 18,333.33 0.019426 52.08
H2 2 - - - 0 -
Total 2,656.25 0 501,666.67 1 3,177.08
Reaksi 1
Inlet Outlet
Komponen BM (kg/kgmol)
n x Mass xm n
Fe2O3 160 2,604.17 0.18 416,666.67 0.441501 -
Fe3O4 232 - - - 0 -
FeCl2 127 - - - 0 -
FeCl3 162.5 - - - 0 5,208.33
HCl 36.46 15,625.00 1.07 569,687.50 0.603642 -
H2O 18 - - - 0 2,604.17
Cl2 71 - - - 0 -
O2 32 - - - 0 -
H2 2 - - - 0 -
Total 18,229.17 1 986,354.17 1 7,812.50
 Outlet
x Mass xm
- - -
0.13 483,333.33 0.51
- - -
- - -
0.75 455,750.00 0.48
- - -
- - -
- - -
0.13 4,166.67 0.00
1.00 943,250.00 1

Outlet
x Mass xm
- - -
- - -
0.38 793,750.00 0.84
- - -
- - -
- - -
0.19 221,875.00 0.24
- - -
- - -
0.56 1,015,625.00 1

Outlet
x Mass xm
- - -
- - -
- - -
- - -
0.38 227,875.00 0.24
 - - -
- - -
0.09 50,000.00 0.05
- - -
0.47 277,875.00 0

Outlet
x Mass xm
0.19 500,000.00 0.53
- - -
- - -
- - -
- - -
- - -
- - -
0.00 1,666.67 0.00
- - -
0.19 501,666.67 1

Outlet
x Mass xm
- - -
- - -
- - -
0.31 846,354.17 0.90
- - -
0.16 46,875.00 0.05
- - -
- - -
- - -
0.47 893,229.17 1
 T
P
R 5 H
D
F

B A
1C 2 G
3
E
L

N 4

Langkah Penyelesaian
1 merah
2 aqua
3 ungu
4 jingga
5 hijau

Jawaban : c. Overall Reaction

11 H2O 0.5 O2 9 H2O 1.5

2 H2O 1 O2 2 H2

ΔH°f = 285.84 kJ/mol

ΔH°f = 285840 kJ/kg mol

a b (T) c (T^2) d (T^3)

100 100000 1000000000
H2O (g) = 33.46 0.00688 0.000007604 -3.593E-09
O2 = 29.1 0.01158 -0.000006076 1.311E-09
H2 = 28.84 0.0000765 0.000003288 -8.698E-10

ΔH°Overall = 285.84 320429489.55 54742738.305664 62416320.8008

285.84 + 437588548.65293 -
42,265,550.39 kJ untuk produksi 100 ton H2 / day
 J

K Produk Hidrogen = 100 ton/day Misal Basis Fe2O3 =

Produk Hidrogen = 4166.667 kg/h
Produk Hidrogen = 2083.333 kgmol/h

M
Reaksi 1 tanpa tambahan Fe2O3

3 Fe2O3 18 HCl 6 FeCl3

Mula 3125 18750 0
Reaksi 3125 18750 6250
Sisa 0 0 6250

Stream A

Reaksi 2

6 FeCl3 6 FeCl2 3 Cl2

Mula 6250 0 0
Reaksi 6250 6250 3125
Sisa 0 6250 3125
Reaksi 5

3 Cl2 3 H2O 6 HCl

Mula 3125 3125 0
Reaksi 3125 3125 6250
Sisa 0 0 6250
Reaksi 3

O2 2 H2 6 FeCl2 8 H2O 2 Fe3O4

Mula 6250 8333.333 0
Reaksi 6250 8333.333 2083.333
Sisa 0 0 2083.333
Reaksi 4
 2 Fe3O4 0.5 O2 3 Fe2O3
Mula 2083.333 572.9167 0
Reaksi 2083.333 520.8333 3125
Sisa 0 52.08333 3125

Selisih H2 Asumsi dengan Hasil = 0

275062581.38 107398868.31 12861834.4

395323284.1
 Jawaban : a. Fe2O3 sebelum recycle =
Fe2O3 sesudah recycle =

O2 Requirement =
H2O Requirement =

Sehingga Neraca Massa Overall-nya dapat dituliskan sebagai berikut

Misal Basis Fe2O3 = 3125 kgmol/h Reaksi 1
Inlet
Komponen BM (kg/kgmol)
n
Fe2O3 160 3,125.00
Fe3O4 232 -
FeCl2 127 -
FeCl3 162.5 -
9 H2O HCl 36.5 18,750.00
0 H2O 18 -
9375 Cl2 71 -
9375 O2 32 -
H2 2 -
Total 21,875.00
Reaksi 2
Inlet
Komponen BM (kg/kgmol)
n
Fe2O3 160 -
Fe3O4 232 -
FeCl2 127 -
FeCl3 162.5 6,250.00
HCl 36.5 -
H2O 18 -
1.5 O2 Cl2 71 -
0 O2 32 -
1562.5 H2 2 -
1562.5 Total 6,250.00
Reaksi 5
Inlet
Komponen BM (kg/kgmol)
12 HCl 2 H2 n
0 0 Fe2O3 160 -
12500 2083.333 Fe3O4 232 -
12500 2083.333 FeCl2 127 -
FeCl3 162.5 -
HCl 36.5 -
 H2O 18 3,125.00
Cl2 71 3,125.00
O2 32 -
H2 2 -
Total 6,250.00
Reaksi 3
Inlet
Komponen BM (kg/kgmol)
n
Fe2O3 160 -
Fe3O4 232 -
FeCl2 127 6,250.00
FeCl3 162.5 -
HCl 36.5 -
H2O 18 8,333.33
Cl2 71 -
O2 32 -
H2 2 -
Total 14,583.33
Reaksi 4
Inlet
Komponen BM (kg/kgmol)
n
Fe2O3 160 -
Fe3O4 232 2,083.33
FeCl2 127 -
FeCl3 162.5 -
HCl 36.5 -
H2O 18 -
Cl2 71 -
O2 32 572.92
H2 2 -
Total 2,656.25
2 O3
sebelum recycle = 500.00 ton/h
2O3 sesudah recycle = 5.82E-14 ton/h

Requirement = 15.10 ton/h

O Requirement = 2.083 ton/h

dituliskan sebagai berikut

Inlet Outlet
x Mass xm n x Mass xm
0.1429 500,000.00 0.4222 - - - -
- - - - - - -
- - - - - - -
- - - 6,250.00 0.40 1,015,625.00 0.8575
0.8571 684,375.00 0.5778 - - - -
- - - 9,375.00 0.60 168,750.00 0.1425
- - - - - - -
- - - - - - -
- - - - - - -
1 1,184,375.00 1 15,625.00 1.00 1,184,375.00 1

Inlet Outlet
x Mass xm n x Mass xm
- - - - - - -
- - - - - - -
- - - 6,250.00 0.6667 793,750.00 0.7815
1.00 1,015,625.00 1.00 - - - -
- - - - - - -
- - - - - - -
- - - 3,125.00 0.3333 221,875.00 0.2185
- - - - - - -
- - - - - - -
1 1,015,625.00 1 9,375.00 1.00 1,015,625.00 1

Inlet Outlet
x Mass xm n x Mass xm
- - - - - - -
- - - - - - -
- - - - - - -
- - - - - - -
- - - 6,250.00 0.80 228,125.00 0.8202
 0.50 56,250.00 0.2022 - - - -
0.50 221,875.00 0.7978 - - - -
- - - 1,562.50 0.20 50,000.00 0.1798
- - - - - - -
1 278,125.00 1 7,812.50 1.00 278,125.00 1

Inlet Outlet
x Mass xm n x Mass xm
- - - - - - -
- - - 2,083.33 0.1250 483,333.33 0.5121
0.4286 793,750.00 0.8411 - - - -
- - - - - - -
- - - 12,500.00 0.7500 456,250.00 0.4834
0.5714 150,000.00 0.1589 - - - -
- - - - - - -
- - - - - - -
- - - 2,083.33 0.1250 4,166.67 0.0044
1 943,750.00 1 16,666.67 1.00 943,750.00 1

Inlet Outlet
x Mass xm n x Mass xm
- - - 3,125.00 0.98 500,000.00 0.9967
0.7843 483,333.33 0.9635 - - - -
- - - - - - -
- - - - - - -
- - - - - - -
- - - - - - -
- - - - - - -
0.2157 18,333.33 0.0365 52.08 0.02 1,666.67 0.0033
- - - - - - -
1 501,666.67 1 3,177.08 1 501,666.67 1