Lampiran

Perhitungan Data Vapour Liquid Equilibrium (VLE)

1. Perhitungan Densitas
Diketahui :
M total = 70 gram
Fraksi mol etanol = 0,375
Fraksi mol aquades = 0,625

Mol Etanol
Xethanol =
Mol Total

Mol Etanol
Xethanol =
Mr Etanol

Mol Etanol m aquades

+
Mr Etanol Mr aquades

Mol Etanol
0,375 =
46

Mol Etanol 70−m etanol

+
46 18

Mol Etanol
0,375 =
46
18. metanol + 46(70 – metanol)

Mol Etanol
=
46
18. metanol + 3220 - 46 metanol)

1207,5 = 18 metanol + 10,5 metanol

1207,5 = 28,5 metanol
metanol = 42, 368 gr
maquades = 70 – 42,368
= 27,632 gr

 Volume etanol dan aquades

m = ρ.V
mol aquades
Vaquades =
ρ aquades
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27,632
=
1,014
= 27,2 ml

mol etanol
Vetanol =
ρ etanol

42,368
=
0,842
= 50,3 ml

Densitas etanol dan aquades

 massa piknometer kosong etanol = 14,93
 massa piknometer kosong aquades = 11,23
 massa piknometer etanol terisi = 19,14
 massa piknometer aquades terisi = 16,30

Densitas Etanol
ρetanol = massa piknometer terisi – massa piknometer kosong
volume piknometer
= 19,14-14,93
5
= 0,842
Densitas Aquades
ρaquades = massa piknometer terisi – massa piknometer kosong
volume piknometer
= 16,30 – 11,23
5
= 1,014

 Running data ke-1

Diketahui :
Massa piknometer etanol kosong = 14,93
Massa piknometer air kosong = 11,23
Volume piknometer = 5 ml
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Distilasi

ρdistilasi = massa piknometer terisi – massa piknometer kosong

volume piknometer
= 19.44 - 14.93
5
= 0.902 g/ml
ρbottom = massa piknometer terisi – massa piknometer kosong
volume piknometer
= 15.73- 11.23
5
= 0.9

Running ke-2
Penambahan etanol = 8gr
Fraksiuap = mol etanol
mol etanol+ mol aquades
= (42,368+8)/46
(42,368+8)/46 + 27,632/18
= 1,094
1,094 + 1,535
= 0,4163
Fraksicair = 1- 0,4163
= 0,5837
Densitas
ρdistilasi = massa piknometer terisi – massa piknometer kosong
volume piknometer
= (18.84 - 14.93)
5
= 0,782
Lampiran

ρbottom = massa piknometer terisi – massa piknometer kosong

volume piknometer
= 15,65 – 11,23
5
= 0,884

Running ke-3
Penambahan etanol = 8gr
Fraksiuap = mol etanol
mol etanol+ mol aquades
= (50,368+8)/46
(50,368+8)/46 + 27,632/18
= 1,268
1,268 + 1,535
= 0,4525
Fraksicair = 1- 0,452
= 0,5475

Densitas
ρdistilasi = massa piknometer terisi – massa piknometer kosong
volume piknometer
= (18.78 - 14.93)
5
= 0,77

ρbottom = massa piknometer terisi – massa piknometer kosong

volume piknometer
= 15,6 – 11,23
5
= 0,874
Lampiran

Running ke-4
Penambahan etanol = 8gr
Fraksiuap = mol etanol
mol etanol+ mol aquades
= (58,368+8)/46
(58,368+8)/46 + 27,632/18
= 1,442
1,442 + 1,535
= 0,484
Fraksicair = 1- 0,484
= 0,515

Densitas
ρdistilasi = massa piknometer terisi – massa piknometer kosong
volume piknometer
= (18.76 - 14.93)
5
= 0,766

ρbottom = massa piknometer terisi – massa piknometer kosong

volume piknometer
= 15,52 – 11,23
5
= 0,858

Running ke-5
Penambahan etanol = 8gr
fraksiuap = mol etanol
mol etanol+ mol aquades
= (66,368+8)/46
(66,368+8)/46 + 27,632/18
Lampiran

= 1,616
1,616 + 1,535
= 0,512
fraksicair = 1- 0,512
= 0,487

Densitas
ρdistilasi = massa piknometer terisi – massa piknometer kosong
volume piknometer
= (18.76 - 14.93)
5
= 0,766

ρbottom = massa piknometer terisi – massa piknometer kosong

volume piknometer
= 15,52 – 11,23
5
= 0,858

2. Tabel Hasil Perhitungan Densitas Top

T(0C) Running m pikno m Volume Densitas(gr/ml)
kosong pikno pikno (ml)
isi
80 1 14.93 19.44 5 0.902

81 2 14.93 18.84 5 0.782

81 3 14.93 18.78 5 0.77

80 4 14.93 18.76 5 0.766

80 5 14.93 18.73 5 0.76

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3. Tabel Hasil Perhitungan Densitas bottom

T (0C) Running m pikno m Volume Densitas(gr/ml

kosong pikn pikno 0
o isi (ml)
80 1 11.23 15.7 5 0.9
3
81 2 11.23 15.6 5 0.884
5
81 3 11.23 15.6 5 0.874

80 4 11.23 15.5 5 0.858

2
80 5 11.23 15.5 5 0.858
2

4. Kurva T,x,y
Tabel fraksi etanol dan uap terhadap suhu
T (0C) Fraksi Liquid Fraksi Vapour

80 0.625006 0.374994

81 0.583677 0.416323

81 0.547476 0.452524

80 0.515502 0.484498

80 0.487057 0.512943

100

95

90
T

85

80

75
0 0.2 0.4 0.6 0.8 1
x,y
T-x literatur T-y literatur T-x praktikum T-y praktikum
Gambar Kurva T-xy