5.

2 Comparison the experimental diffusivity and literature diffusivity value of Cobalt

(II) Chloride.

Literature value of diffusivity of cobalt (II) chloride.

𝐖𝐢𝐥𝐤𝐞 𝐂𝐡𝐚𝐧𝐠 𝐄𝐪𝐮𝐚𝐭𝐢𝐨𝐧

T
DAB = 1.173 × 10−16 (∅MB )0.5
μB VA0.6

T = 298 K

kg
MB = molecular weight of water (18.016 )
kgmol

kg
μB = viscosity of water (0.8937 × 10−3 )
m. s

∅ = 2.6

m3
vA = atomic volume of CoCl2 ( kg )

m3
Atomic volume of Co (6.67 × 10−3 )
kg

m3 m3
Atomic volume of Cl2 (21.6 × 10−3 ) × 2 = 43.2 × 10−3
kg kg

m3
Total atomic volume of is 49.87 × 10−3 kg

𝟐𝟗𝟖
𝐃𝐀𝐁 = 𝟏. 𝟏𝟕𝟑 × 𝟏𝟎−𝟏𝟔 (𝟐. 𝟔 × 𝟏𝟖. 𝟎𝟏𝟔)𝟎.𝟓
(𝟎. 𝟖𝟗𝟑𝟕 × 𝟏𝟎−𝟑 ) (𝟒𝟗. 𝟖𝟕 × 𝟏𝟎−𝟑 )𝟎.𝟔

−𝟑
𝐦𝟐
𝐃𝐀𝐁 = 𝟏. 𝟔𝟏𝟕𝟖 × 𝟏𝟎
𝐬
 Stokes Einstein Equation

9.96 × 10−16 T
DAB = 1/3
μVA

𝟗. 𝟗𝟔 × 𝟏𝟎−𝟏𝟔 (𝟐𝟗𝟖)
𝐃𝐀𝐁 = 𝟏/𝟑
(𝟎. 𝟖𝟗𝟑𝟕 × 𝟏𝟎−𝟑 ) (𝟒𝟗. 𝟖𝟕 × 𝟏𝟎−𝟑 )

−𝟏𝟎
𝐦𝟐
= 𝟗. 𝟎𝟐𝟑 × 𝟏𝟎
𝐬

Compare the experimental value of diffusivity with the theoretical value

𝑚2
Experimental value = 0.877 𝑠

𝑚2
Literature value of Wilke Chang Equation = 1.6178 × 10−3 𝑠

𝑚2
Literature value of Stokes Einstein Equation = 9.023 × 10−10 𝑠

Calculation the percentage error between experimental diffusivity value with literature
value

Percentage error of Wilke Chang Equation

𝐷𝐴𝐵 𝑒𝑥𝑝𝑒𝑟𝑖𝑚𝑒𝑛𝑡𝑎𝑙 − 𝐷𝐴𝐵 𝑙𝑖𝑡𝑒𝑟𝑎𝑡𝑢𝑟𝑒

= × 100%
𝐷𝐴𝐵 𝑒𝑥𝑝𝑒𝑟𝑖𝑚𝑒𝑛𝑡𝑎𝑙
0.877 − 1.6178 × 10−3
= × 100%
0.877
= 99.99%

Percentage error of Stokes Einstein Equation

𝐷𝐴𝐵 𝑒𝑥𝑝𝑒𝑟𝑖𝑚𝑒𝑛𝑡𝑎𝑙 − 𝐷𝐴𝐵 𝑙𝑖𝑡𝑒𝑟𝑎𝑡𝑢𝑟𝑒

= × 100%
𝐷𝐴𝐵 𝑒𝑥𝑝𝑒𝑟𝑖𝑚𝑒𝑛𝑡𝑎𝑙
0.877 − 9.023 × 10−10
= × 100%
0.877
= 99.99%