PR 1

For the system methanol(1)/methyl acetate(2), the following equations

provide a reasonable correlation for the activity coefficients:
where ln P1 sat/(kPa)=16.59158-(3643.31/
(T/kelvin)-33.424)
A=2.771-0.00523T

ln g1=AX2^2 ln P1 sat/(kPa)=14.25326-(2665.54/
(T/kelvin)-53.424)
ln g2=AX1^2

b) P and xi, for y1= 0.5 and T=330K (DEW P)

T= 330 kelvin
Trial
gamma 1 1.135466 x1 0.651345
gamma 2 1.55797 x2 0.348655

A 1.0451
p1 sat 74.2179 gamma 1-hit 1.135466
p2 sat 101.0504 gamma 2-hit 1.55797

y1= 0.5 galat= 0.00

y2= 0.5

p 109.7801
C) T and yi, for x1=0.6 and P=90kPa (BUBLB T)

A=2.771-0.00523T

ln g1=AX2^2 ln P1 sat/(kPa)=16.59158-(3643.31/ a1
(T/kelvin)-33.424)
ln g2=AX1^2 b1
c1
ln P1 sat/(kPa)=14.25326-(2665.54/
(T/kelvin)-53.424)
p

Trial T 334.0408 kelvin T1 sat

gamma 1 1.310959 x1 0.6 T2 sat
gamma 2 1.31281 x2 0.4

A 1.023966
p1 sat 87.54319 gamma 1-hit 1.178019
p2 sat 116.094 gamma 2-hit 1.44575

y1= 0.583621 galat= 0.00

y2= 0.515973

p 129.0137
16.59158 a2 14.25326
3643.31 b2 2665.54
-33.424 c2 -53.424

90 kpa

334.7289 (tmax)
326.716 (tmin)