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  • PLED Lecture: Polymer Light-Emitting Diode Basics

    Diunggah oleh

    Alok Kushwaha
    40 tayangan21 halaman
    This document discusses polymer light-emitting diodes (PLEDs). PLEDs work similarly to small molecule OLEDs but use a light-emitting polymer layer instead of small molecules. The key advantages of PLEDs are their flexibility, wide viewing angles, and potential for high-resolution printing fabrication. The document outlines the basic structure and working principle of PLEDs and discusses various light-emitting polymers and fabrication methods like inkjet printing and spin coating. Challenges for PLEDs include improving their lifespan, color balance, and outdoor performance.

    Deskripsi Asli:

    PLED

    Judul Asli

    PLEDs Adrian Podlinski

    Hak Cipta

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    This document discusses polymer light-emitting diodes (PLEDs). PLEDs work similarly to small molecule OLEDs but use a light-emitting polymer layer instead of small molecules. The key advantages of PLEDs are their flexibility, wide viewing angles, and potential for high-resolution printing fabrication. The document outlines the basic structure and working principle of PLEDs and discusses various light-emitting polymers and fabrication methods like inkjet printing and spin coating. Challenges for PLEDs include improving their lifespan, color balance, and outdoor performance.

    Hak Cipta:

    © All Rights Reserved
    Unduh sebagai PDF, TXT atau baca online dari Scribd
    Tandai sebagai konten tidak pantas
    40 tayangan21 halaman

    PLED Lecture: Polymer Light-Emitting Diode Basics

    Diunggah oleh

    Alok Kushwaha
    This document discusses polymer light-emitting diodes (PLEDs). PLEDs work similarly to small molecule OLEDs but use a light-emitting polymer layer instead of small molecules. The key advantages of PLEDs are their flexibility, wide viewing angles, and potential for high-resolution printing fabrication. The document outlines the basic structure and working principle of PLEDs and discusses various light-emitting polymers and fabrication methods like inkjet printing and spin coating. Challenges for PLEDs include improving their lifespan, color balance, and outdoor performance.

    Hak Cipta:

    © All Rights Reserved
    Unduh sebagai PDF, TXT atau baca online dari Scribd
    Tandai sebagai konten tidak pantas
    dari 21

    PLED

    Polymere Light Emitting
    y g g Diode
    Lecture: Incoherent Light Sources 
    Lecture: Incoherent Light Sources
    SS 2013
    Adrian Podlinski
    Differentiation of OLEDs
    Differentiation of
    • SMOLED (small molecule organic light‐
    emittingg diodes))

    • PLED (Polymer
    PLED (P l li h
    light‐emitting
    i i diodes)
    di d )

    • PHOLED (Phosphorescent organic light‐


    emitting
    itti diode)
    di d )
    Working Principle
    Working Principle
    Structure
    SMOLED
    Structure
    PLED

    LEP: Light
    LEP: Light‐emitting
    emitting Polymer
    Polymer
    iL: Interlayer
    HiL: Hole Injection Layer
    Semiconducting Polymers
    • Conjugated‐π‐Electron‐System
    • Contiguous sp2 hybridized carbon centers
    • P‐orbitals form a one‐dimensional electronic 
    b d
    band
    • Higher conductivity higher degree of 
    g y g g
    crystallinity and better alignment of the chains
    Conducting Polymer
    • Conductivity can be increased by
    oxidation/reduction
    Light Emitting Polymers
    Light‐Emitting
    • PPV was suggested for lighting application in 
    1990
    • Synthesis:
    Light Emitting Polymers
    Light‐Emitting
    • By substituting a polymer different properties 
    g
    can be changed, like:
    – Stability
    – Solubility
    – Conductivity
    – Emission spectrum
    Light Emitting Polymers
    Light‐Emitting
    Fabrication
    • Ink‐Jet‐Printing
    k i i

    + High resolution + Large area
    ‐Uneven Emission because of different layer 
    thicknesses 
    Fabrication
    • Spin‐Coating
    i i

    + Uniform films
    + Simple R&D process
    ‐ High wastage
    High wastage
    ‐ Not ideal for big production quantities
    Phosphorescent OLEDs
    • 2 types of excitons are possible 
    – statistical ratio singlet:triplet
    g p =1:3
    Phosphorescent OLEDs
    • In order for triplet excitons to emit, spin‐orbit 
    p g q
    coupling is required
    • This effect is strong in heavy atoms
    • Transition metals are common candidates to 
    T ii l did
    enable phosphorescence from organic
    molecules
    • Doping a host polymer with 
    Doping a host polymer with
    an organometallic complex
    Advantages
    • Light weight & flexible plastic substrates
    • Wider viewing angles & improved brightness
    Wider viewing angles & improved brightness
    • Better power efficiency and thickness
    • Response time
    Disadvantages
    • Lifespan
    • Color balance issues
    Color balance
    • Outdoor performance
    • High Cost
    • Power consumption increases for white
    Power consumption
    images
    OLED / LED
    OLED / LED
    Applications
    Flexible OLEDs
    Flexible OLEDs
    • Two major challenges are the backplane and 
    p
    the encapsulation.
    Sources
    • htt
    http://www.oled‐info.com/
    // l di f /
    • http://www.cdtltd.co.uk/
    • http://www.sigmaaldrich.com/technical‐
    // /
    documents/articles/material‐matters/light‐
    emitting polymers html
    emitting‐polymers.html
    • http://www.nobelprize.org/nobel_prizes/chemist
    ry/laureates/2000/advanced‐
    chemistryprize2000.pdf
    • http://www.nature.com/nature/journal/v347/n6
    http://www nature com/nature/journal/v347/n6
    293/pdf/347539a0.pdf
    PLED
    Polymere Light Emitting
    y g g Diode
    Incoherent Light Sources
    Light Sources SS 2013
    SS 2013
    Adrian Podlinski

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