JEE Main Sample Papers with Solutions

JEE Main
Sample Papers
with Solutions
by
FIITJEE - JEE (Main)
SAMPLE TEST - 1
Time Allotted: 3 Hours Maximum Marks: 360
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JEE-MAIN -SAMPLE TEST -1-PCM-2
Useful Data Chemistry:

Gas Constant R= 8.314 J K1 mol1
= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
-27
= 6.25 x 10 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
-27
1 amu = 1.66 x 10 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56,
Mn=55, Si = 28 Pb=207, u=197, Ag=108, F=19, H=2, Cl=35.5
Useful Data Physics:
Acceleration due to gravity g = 10 m / s2
Section – I (Physics)
1. A particle is projected vertically upwards with a velocity of 20 m/sec. Find the time at which the
distance travelled is twice the displacement
(A) 2 + 4 / 3 sec. (B) 1 sec. (C) 2 + 3/4 (D) 3 sec
1. A
Sol. For AB
B
2 2  2s 
v  u  2 g  
 2  s/2
 3s 
 0   20  20   2 10  .  
 2 C
20  20 40
S  s
10  3 3
1 2
Now, s  ut  gt A
2
40 1
  20t   10t 2
3 2
4
On solving t  2 
3
2. Two men who can swim with a speed v 1 in still water start from the middle of a river of width d
and move in opposite directions always swimming at an angle  with the banks. What is the
distance between them along the river when they reach the opposite banks, if the velocity of the
river is v2
dv 1 dv1 cos  dv 2 v2 d
(A) cot (B) (C) tan (D)
dv 2 v1  v 2 v1 v1 sin 
2. D
d /2
Sol. t1 
v1 sin 
d
Distance =  v 2  v1 cos     v2  v1 cos  
2v1 sin 
v2 d

v1 sin 
3. A uniform chain of mass m hangs from a light pulley, with unequal lengths of the chain hanging
from the two sides of pulley the force exerted by moving chain on the pulley is
(A) = mg (B) > mg
(C) < mg (D) either b or c depending upon acceleration of
chain
3. C
Sol. Force is less than mg as it is accelerated
4. In the figure ball A is released from rest, when the spring is at its natural
length. For the block B of mass M to leave contact with the ground at
some stage, the minimum mass of A must be
(A) 2M A
(B) M
(C) M/2
(D) a function of M and force constant of spring.
B M
4. C
Sol. For B
Just to loose contact
Kx
Mg
Mg  Kx  x 
K
Applying WET
WDg  WDs  KE
1
  Kx 2  mgx  0 N
2 Mg
M
 m
2
5. A system is shown in figure pulleys and strings are ideal system

is released from rest T
a1  acceleration of 2 kg, a2 = acceleration of 3 kg

(i) a1 = 2a2 (ii) a2 = 2a1 (iii) a1 = a2 = 0 s = 3 / 2 2 kg
(iv) Tension T in the string = 15 N 3 kg
(v) frictional force between 2 kg & incline = 5N 300
(vi) frictional force between 2 kg & incline = 15N
(A) (ii), (iv) & (vi) are correct (B) (iii), (v) are correct
(C) (iii), (iv) & (v) are correct (D) (i), (iv) & (vi) are correct
5. D
Sol. Using constraint
 a1  0 T
 a2 a1
2
  a1  2a2 ….(1) 2
3 a2
Applying Newton’s law and N
solving 2 g sin 
T  f  15 N f 2 g cos 
3g
6. A bullet of mass 10 gm is fired from a rifle with a velocity of 800 m/s. After passing through a mud
wall 180 cm thick, the velocity drops to 100 m/s. The average resistance of the wall is
(A) 750 N (B) 1250 N (C) 1750 N (D) 2250 N
6. C
Sol. Using Kinematics find time taken by bullet
P
Then,  F  1750 N
t
7. A body is gently dropped on a conveyor belt moving 3 m/s. If  = 0.5 how far will the body move
2
relative to the belt before coming to rest? (g = 10m/s )
(A) 0.3 m (B) 0.6 m (C) 0.9 m (D) 0.8 m
7. C
Sol. With respect to belt

v 2  u 2  2as
0  32  2   g  s
 s  9m
8. Consider the disc kept on a rough horizontal surface as F

shown in the diagram. If a horizontal force ‘F’ has to be h
applied such that the disc starts pure rolling, what
should be the value of ‘h’ ? R
(A) R (B) R/3

(C) R / 2 (D) Body can’t start pure rolling for any value of
‘h’
8. C
Sol. For Pure rolling
aCM  Rh
F R.F  h  R 

m mR 2
3
2
R
On solving, h 
2
9. Moment of inertia of a half shell of mass ‘M’ about an

R
axis tangential to it, as shown, would be
O
2 1
(A) MR 2 (B) MR 2 (C) MR2 (D) none of these
3 3
9. B
Sol. Applying parallel axis theorem
1
I  MR 2
3
10. Consider ‘3’ bodies namely a disc ‘A’, a sphere ‘B’ and a hollow cylinder all
with same mass and radius being released from top of fixed inclined plane.
If tA, tB & tc be the time they take to reach the bottom, find the correct
alternative for each of given situations.
In absence of any friction

(A) tC > tA > tB (B) tC < tA < tB (C) tC = tA = tB (D) none of these
10. C
Sol. In absence of friction only mg is acting through COM.
So, this case of sliding in all cases and time taken will be same as aCM is same.
11. A small ball starts rolling on an inclined track which

becomes loop if radius R in vertical plane.
R
h=2R
(A) speed of the ball at highest point is zero but and highest point is 2R above the ground.
(B) speed of the ball at highest point is non zero but highest point is 2R above the ground
(C) speed of the ball is along horizontal at highest point and highest point is less than the 2R
above the ground.
(D) speed of the ball is along horizontal at highest point but height of highest point above the
ground can not be calculated.
11. C
Sol. In Pure rolling, energy is conserved
PE  T .KE  R. KE
12. A double star consists of two stars having mass M and 2M. The distance between their centre is
equal to r. They revolve under their mutual gravitational interaction. Then which of the following
statements is/are correct.
(A) heavier star revolves in orbit of radius r/3
(B) kinetic energy of heavier star is twice of that of the other star.
2r
(C) lighter star revolves in orbit of radius
5
(D) all above are correct.
12. A
Sol. Taking M as origin applying COM
M  0    2m  r 2
xCM   r
3M 3
r
So, from heavier black
3
13. Three small identical bodies each of mass m are moving in circular orbit around a fixed point with
same angular velocity under their gravitational interaction. If the separation between any two
bodies is R, the total energy possessed by the system is given by
3GM2 3GM2 3GM2 3GM2
(A)  (B)  (C)  (D) 
2R 4R 2R cos 30 R
13. A
3GM 2
Sol. Total potential energy = 
R
3 GM 2
Total K.E. =
2 R
3 GM 2
So, total energy = KE  P.E  
2 R
14. A man of mass M stands at one end of a plank of length L which lies at rest on a frictionless
surface. The man walks to the other end of the plank. If the mass of the plank is M/3, the
distance that the man moves relative to the ground is
3L 4L L L
(A) (B) (C) (D)
4 5 4 3
14. C
Sol. Let the distance moved by plank be x.

Now, there is no external force so COM
Will not move
m1n1  m2 n2
xCM 
m1  m2
M
M  L  x  x
0 3
4M
3
Mx
 ML  Mx 
3
44
 ML  Mx.
3
3L
x
4
L
So, distance moved by person wrt.
4
15. The centre of mass of a half disc shown is at C while O is the centre. Thus OC
is
(A) R/2 (B) 2R/
C
4R R
(C) (D) none of the above
3 O
15. C
 
4 R sin  
Sol. COM of sector =
2
3
Here   
4R
r
3
16. If the tension in a stretched string fixed at both ends in changed by 20%, the fundamental
frequency is found to change by 15 Hz. Then the
(A) original frequency is 150 Hz
(B) velocity of propagation of the transverse wave along the string changes by 5 %
(C) velocity of propagation of the transverse wave along the string change by 10 %
(D) fundamental wavelength on the string does not change.
16. B
Sol. T2'  1.2T
T
v

17. Beats are produced by two progressive waves. Maximum loudness at the waxing is x times the
loudness of each wave. The value of x is
(A) 1 (B) 2 (C) 2 (D) 4
17. D
Sol. At maximum net amplitude = 2A
2
Loudness  A
18. A thermodynamic system undergoes a cyclic

process as shown in the figure. The cycle P
consists of two closed loops. Over one
complete cycle, the system performs
(A) positive work
(B)negative work
(C) zero work
(D) nothing can be predicted
V
18. B
Sol. Area under PV graph is greater is anticlockwise direction.
So, net W.D. is negative
19. A half ring of radius R is charged with a linear charged density . The field at the centre is
(A) 0 (B) k/R (C) 2k/R (D) k/R
19. C
Sol. dl  Rd
dq   .R
K .  dq  d
dE 
R2 
 /2
dq 2K
E   K . 2 cos  
  /2 R R
20. The maximum electric field strength E due to a uniformly charged ring of radius r, happens at a
distance x, where value of x is (x is measured from the centre of the ring)
R
(A) x = R (B) x = R/2 (C) x = (D) x = 2 R
2
20. C
KQx
Sol. E 3/ 2
R 2
 x2 
dE
For maximum 0
dx
R
So, x 
2
21. Two charges +q and q are placed fixed on the corner of a +q q

massless rigid rod of length 2L.Calculate the potential energy of
the dipole thus formed. 2L
2 2 2
1 q 1 q 1 q
(A) (B) (C) (D) None of these.
4 o 4L2 4  o 2L 2 o 2L
21. B
KqV 1 q2
Sol. PE = 
r 4 0 2 L
22. If the above discussed dipole is placed in a uniform electric field E as shown, E
calculate the proper potential energy of the dipole.
+q
1 q2 1 q2
(A) (B) 4qLE 
4  o 2L 4 o 2L
2L
1 q2 1 q2
(C) 2qLE  (D) 4qLE 
4  o 2L 4o 2L
22. D
Sol. Net PE = PE due to EF + PE of system
1 q2
 4qLE 
4 0 2 L
23. In the shown network current through 20  resistor equals 10 V 20 V

3 9
(A) A (B) A
2 2
2
(C) 1A (D) A 10 
3
20 
23. A
Sol. Applying KVL
3
I A
2
24. Equivalent resistance between the points A and B is 3
(A) 1  (B) 2  3 3 3
(C) 3  (D) 4  3
A 3 B
3
3 3
3
24. D
Sol. Using node removal method
Req  h
25. The two rails of a railway track; insulated from each other and the ground, are connected to
millivoltmeter. What is the reading of the millivoltmeter when a train passes at a speed of 180
km/hr along the track, given that the horizontal component of earth’s magnetic field is
0.2  10-4 wb/m2 and rails are separated by 1 metre
(A) 10-2 V (B) 10 mV (C) 1 V (D) 1 mV
25. D
  
Sol.  
  dl . B  v  1mV
26. In an R-L-C circuit v = 20 sin (314 t + 5/6) and i = 10 sin (314 t + 2/3)
The power factor of the circuit is
(A) 0.5 (B) 0.966 (C) 0.866 (D) 1
26. C
Sol. Conceptual based
27. A circular current carrying coil has a radius a. The distance from the centre of coil, on its axis,
where the magnetic induction will be 1/8 th of its value at centre of coil is
(A) 3a (B) + 3a (C)  3a (D)  2a / 3
27. C
0 IR 2 0 I
Sol. B  B
2 3/ 2
2  R2  x  2R
 x   3a
28. In photoelectric effect, the photo current

(A) increases with increase of frequency of incident photon
(B) decreases with increase of frequency of incident photon
(C) does not depend on the frequency of the photon but depends only on intensity of incident
light.
(D) depends both on intensity and frequency of photon.
28. C
Sol. Conceptual based
29. If refractive index of water is 4/3 and glass is 5/3 then critical angle so that light travelling form
glass to water is completely reflected is
(A) sin-1 (4/5) (B) sin-1 (5/4) (C) sin-1 (3/5) (D) sin-1 (5/3)
29. A
Sol. Applying 1 sin i   2 sin r
4
sin  
5
30. When a ray of light enters a glass slab from air
(A) its wavelength decreases (B) its wavelength increases
(C) its frequency increases (D) neither wavelength nor frequency changes
30. A
Sol. vf
f req remains constant
Here volume increases, so  decreases
space for rough work
Section – II (Chemistry)
1. For the equations
C  diamond   2 H 2  g   CH 4  g  ; H1
C  graphite   2H 2  g   CH 4  g  ; H 2
Predict whether
(A) H1  H 2 (B) H1  H 2
(C) H1  H 2 (D) H1  H 2  H vap  3  H diss  H 2 
1. B
Sol. This is because diamond is more stable than graphite and has more energy content.
2. Which of the following can behave as both electrophile and nucleophile?

(A) CH 3  C  N (B) CH 3OH (C) CH 2  CH  CH 3 (D) CH 3 NH 2
2. A
Sol. CH 3CN can behave as both electrophile and nucleophile.
3. Steam reacts with iron at high temperature as follows:

3Fe  s   4 H 2 O  g   Fe3O4  s   4 H 2  g 
The correct expression for the equilibrium constant (KP) is:
4 4
p   p   Fe O 
2
(A)
pH
2
(B)
H2
(C)
H2 3 4
(D)
 Fe3O4 
2
pH 2O p 
H 2O
4
 p   Fe
H 2O
4 3
 Fe
3. B
Sol. Molar concentration or partial pressure of solid = 1.
4. In which of the following solvents, AgBr has the maximum solubility?

(A) 10-3 M NaBr (B) 10-3 M NH4OH (C) Pure water (D) 10 3 M HBr
4. B
Sol. AgBr reacts with NH4OH to form a soluble complex.
AgBr  2 NH 4OH   Ag  NH 3  2  Br  2 H 2 O.
5. The electrode potential of a copper wire dipped in 0.1 M CuSO4 solution at 250C (the standard
reduction potential of copper is 0.34V):
(A) 0.34V (B) 0.31V (C) 0.349 V (D) 0.28 V
5. B
Sol. The electrode reaction written as reduction reaction is
Cu 2   2e   Cu  n  2
0.0591 1
Applying Nernst equation, E = E 0  log  Cu  s    1
2 Cu 2   
0.0591 1
 0.34  log
2 0.1
 0.34  0.0295 1  0.3105V
6. The strongest reducing agent among the following is

(A) F- (B) Cl- (C) Br- (D) I-
6. D
Sol. I- can losses electrons easily (undergoes oxidation easily). So strong reducing agent
7. Diazonium salt decomposes as:

C6 H 5 N 2  Cl   C6 H 5Cl  N 2
At 00 C , the evolution of N2 becomes two times faster when the initial concentration of the salt is
doubled., Therefore, it is
(A) a first order reaction (B) a second order reaction
(C) independent of the initial concentration of the salt
(D) a zero order reaction.
7. A
1
Sol. Because rate   conc 
3 n 3 
8. If 2.68  10 mole of a solution containing an ion A requires 1.61 10 mole of MnO4 for
n 
the oxidation of A to AO3 in an acidic medium, then what is the value of n?
(A) 3 (B) 2 (C) 5 (D) 4
8. B
Sol. An   MnO4  AO3  Mn 2
3
mole 2.68  10 1.61103
2.68  103   5  n   1.61 103  5
5n  3
n2
9. The equivalent weight of MnSO4 is half its molecular weight when it is converted to

(A) Mn2O3 (B) MnO2 (C) MnO4 (D) MnO42
9. B
Sol. Mn 2  Mn 4  2e 
nf  2
M .wt
E.wt 
2
10. The largest number of molecules is in
(A) 36 g of H2O (B) 28 g of CO
(C) 46 g of CH3CH2OH (D) 54 g of N2O5
(Use atomic weight: O = 16, C = 12, N = 14, H = 1)
10. A
36
Sol. N H 2O  N AV  2 N AV
18
28
N CO  N AV  N AV
28
46
N C2 H5OH  N AV  N AV
46
54
N N 2O5  N AV  0.5 N AV
28  80
11. 
Consider a titration of K 2Cr2O7 with acidified Mohr’s salt solution FeSO4 .  NH 4 2 SO4 .6 H 2O 
using diphenylamine as indicator. The number of moles of Mohr’s salt required per mole of
dichromate is

Fe2  Cr2O72 
H
 Fe 3  Cr 3
(A) 3 (B) 4 (C) 5 (D) 6
11. D
2
Sol. neq Mohr salt = neq Cr2 O7
n 1  1 6
n6
12. The normality of 0.3 M phosphorus acid  H 3 PO3  is

(A) 0.1 (B) 0.9 (C) 0.3 (D) 0.6
12. D
Sol.
O
HO P OH
H
nf  2
N  0.3  2  0.6
13. The energy of hydrogen atom in the ground state is 13.6 eV. Its energy corresponding to the
quantum number n = 5 is
(A) 0.54eV (B) 5.40 eV (C) 0.85eV (D) 2.72eV ]
13. A
13.6
Sol. En 
n2
14. If r1 is the radius of first orbit of hydrogen atom, then the radii of second, third and fourth orbit in
terms of r1 are
(A) 8r1 , 27 r1 , 64r1 (B) 2r1 , 6r1 ,8r1 (C) 4r1 ,9r1 ,16r1 (D) r1 , 2r1 ,3r1
14. C
Sol. rn  r1  n 2
15. If kinetic energy of an electron is increased nine times, the de-Broglie wavelength associated with
it would become
1 1
(A) 3 times (B) 9 times (C) times (D) times
3 9
15. C
1
Sol. 
KE
16. Which electronic level allows the hydrogen atom to absorb a photon but not emit a photon?
(A) 2s (B) 2p (C) 1s (D) 3d
16. C
Sol. 1s is the lowest energy level
CH3
NaOMe
17. 
CH 3OH
 Product. Product of the reaction is:
Br  E2 reaction 
CH3
(A) (B) (C) (D) No reaction

OMe
17. D
Sol. Since there is no   H present anti to Br, hence E2 doesn’t occur.
CH3
18. NaOEt Major product of the reaction is:

 
Cl
CH3 CH3 CH3 CH3
(A) (B) (C) (D)
18. B
CH3 CH3
and
Sol. The product obtained are:
(major) (minor)
19. Which of the given options best describes the product of the following reaction?
CH3
 
K t  BuO
Ph
 E2
 Product
CD3
Br
(A) Absolute configuration has been inverted
(B) Absolute configuration has been retained
(C) Racemisation (loss of absolute configuration)
(D) Loss of chirality has occurred (the product is achiral)
19. D
Sol.
CH3
CH2
 
K t  BuO
Ph
 E2
 Ph
CD3
Br CD 3
20. Which one of the following undergoes nucleophlic aromatic substitution at the fastest rate?
Cl Cl Cl Cl
(A) (B) (C) (D)
NO 2 Cl CH3 OMe
20. A
Sol. The electron – withdrawing groups make nucleophilic aromatic substitution proceed at the fastest
rate.
Br
NO 2

21. OH
   A Product of the following reaction is:
Br
Br OH Br
Br
NO 2 NO 2 HO NO 2
NO 2
(A) (B) (C) (D)
HO
OH Br Br
21. B
Sol. The electron-withdrawing groups at ortho or para position to the leaving group help nucleophilic
aromatic substitution proceed at a faster rate.
OH OH
Ph H 2 SO4
22.   P The product (P) is:
99% yield
Ph
(A) O (B) Ph (C) O (D) OH

Ph C Ph
Ph C
Ph Ph Ph
Ph
22. A
O
OH Ph
OH OH
Sol. Ph   H 2O Ph
 H 
 H
 

Ph
Ph Ph
23. An organic compound ‘B’ is formed by the reaction of ethyl magnesium iodide  CH 3CH 2 MgI 
with a substance ‘A’, followed by treatment with dil. aqueous acid. Compound ‘B’ doesnot react
with PCC. Identify A?
(A) O (B) O (C) CH 2  O (D) O
H3C C H CH3CH2 C CH3 CH2 CH2

23. B
O O(MgI) OH
CH3 CH2 C CH3  EtMgI 

 CH3 CH2 C CH3 dil aq
  CH3 CH2 C CH3
acid
Sol. A Et Et  B
PCC
No reaction
O
18
24. Ph C OH  H3C O 
H 
H
  X   H 2 O. Identify X
O
(A)
X  Ph C O CH3 (Esterification)
O
18
(B)
X  Ph C O CH3 (Esterification)
O
18
(C)
X  Ph C O CH3 (Saponification)
O
(D)
X  Ph C O CH3 (Hydrolysis)
24. B
OH OH2
OH
18 18
18
Ph C OH  H3C O  Ph
H  C O  Ph
CH3  C O CH3
OH H OH
Sol.
O
18
Ph C O CH3
X
SOCl2 O3 / Zn
CH 2  CH  CH 2  CH 2  CH 2OH 
pyridine  A 
 H 2O 
 B
25. Compound (B) is
 C4 H 7ClO 
(A) O
H3C C CH2 CH2
CH3
(B) O
HC CH2 CH2 CH2 CH2 Cl

(C) O
HC CH2 CH2 CH2
Cl
(D) O
HC CH2 CH CH3
Cl
25. C
O3 / Zn
Sol. CH 2  CH  CH 2  CH 2  CH 2Cl 
 H 2O 
 HCHO  CHO  CH 2  CH 2  CH 2Cl
A  B
26. Equimolar solutions of two non – electrolytes in the same solvent have
(A) same b.pt but different f.pt (B) same f.pt but different b.pt
(C) same b.pt and same f.pt (D) different b.pt and different f.pt
26. C
Sol. T f and Tb are constant for a solvent.
27. The degree of dissociation   of weak electrolyte Ax B y is related to van’t Hoff’s factor (i) by
the expression:
(A) 
i 1
(B) 
i 1
(C) 
 x  y  1 (D) 
 x  y  1
 x  y  1  x  y  1 i 1 i 1
27. A
Sol.  xA y   yB x 
Ax By 
1    x y
i  1     x  y
 i  1    x  y  1
i 1

 x  y  1
28. When 20 gm of naphthoic acid  C11 H 8O2  is dissolved in 50 gm of benzene k f  1.72 , a  
freezing point depression of 2k is observed. The van’t Hoff factor (i) is
(A) 0.5 (B) 1 (C) 2 (D) 3
28. A
Sol. T f  K f  molality i
20 1000
2  1.72   i
172 50
i  0.5
29. A 0.004 M solution of Na2 SO4 is isotonic with a 0.01 M solution of glucose at same temperature.
The apparent degree of dissociation of Na2 SO4 is
(A) 25% (B) 50% (C) 75% (D) 85%
29. C
Sol.  Na2 SO4   Glu cos e
CRT 1  2   CRT
0.004 1  2   0.01
  0.75
 75%
30. If equal volumes of BaCl2 and NaF solutions are mixed, which of these combination will not

give a precipitate. K sp of BaF2  1.7  10
7

3 2 3 2
(A) 10 M BaCl2 and 2  10 M NaF (B) 10 M BaCl2 and 1.5  10 M NaF
2 2 2 2
(C) 1.5  10 M BaCl2 and 10 M NaF (D) 2  10 M BaCl2 and 2  10 M NaF
30. C
Sol. For precipitation Qsp  K sp
pace for rough work
Section – III (Mathematics)

n  C n n 1 
Cr
1.   r  1r  n1
 equals to
r 1  
1 n
(A) (B)
n 1 n 1
(n  2) 1
(C) (D)
n1 n 1
1. B
n n 1
n
 n Cr n 1
Cr  Cr 1 n1Cr
Sol.  
r 1  r  1
 
n  1 
= 
r 1 n  1

n 1
1 n n 1 1 n
= ( Cr 1  n 1Cr ) = (1  n  1)  .
n  1 r 1 n 1 n1
2. Statement -1: If a, b, c are distinct and x, y , z are not all zero, then
ax  by  cz  0
bx  cy  az  0
cx  ay  bz  0
Gives a + b + c  0
Statement – 2: a 2  b 2  c 2  ab  bc  ca if a, b, c are distinct.
(A) Statement-1 is true, Statement-2 is true, but Statement-2 is a correct explanation for
Statement-1.
(B) Statement-1 is true, Statement-2 is true, but Statement-2 is not a correct explanation for
Statement-1.
(C) Statement-1 is true, Statement-2 is false.
(D) Statement-1 is false, Statement-2 is true.
2. D
a b c
Sol. Let D = b c a =    a 3  b3  c3  3abc 
c a b
   a  b  c   a 2  b 2  c 2  ab  bc  ca 
Now a 2  b 2  c 2  ab  bc  ca  0
 the given system of equations can have non-zero solution (x, y, z are not all zero)
If D = 0, i.e. If a  b  c  0
Statement -1 is false.
Again a 2  b 2  c 2  ab  bc  ca
1
  2a 2  2b 2  2c 2  2ab  2bc  2ca 
2
1 2 2 2
  a  b   b  c    c  a    0
2 
 a, b, c are all different 
2 2 2
 a  b  c  ab  bc  ca
 Statement-2 is true.
  D  holds.
3. If f  x  is an odd periodic function with period 2, then f  4  equals
(A) 0 (B) 2 (C) 4 (D) - 4
3. A
Sol. f  4   f  2  f  0  0
dy
4. The solution of the differential equation 2 x  y  3 represents
dx
(A) straight lines (B) circle (C) parabola (D) ellipse
4. C
dy y 3
Sol.  
dx 2 x 2 x
1
 I .F . 
x
y  3  c x
5
5. If [x] denotes the greatest integer less than or equal to x, then the value of   x  3  dx is
1
(A) 1 (B) 2 (C) 4 (D) 8
5. B
5 2
Sol.   x  3  dx 
1
  x dx
2
2
 2  x  dx
0
6. A tower AB leans towards west making an angle  with the vertical. The angular elevation of B,
the top most point of the tower, is , as observed from a point C due east of A at a distance d
from A. If the angular elevation of B from a point due east of C is at a distance 2d from C is  ,
then
(A) 2 tan   2cot   cot  (B) 2 tan   3cot   cot 
(C) tan   cot   cot  (D) None of these
6. B
Sol. B Let h be height of tower then
h
tan  90     ... 1
x
h
h tan   ...  2 
 xd
h
90     tan   ...  3
West East 3d  x
A C
Solve (1), (2) and (3)
x d 2d
2 tan   3cot   cot 
7. Let f  x   x3  ax 2  bx  5sin 2 x be an increasing function in the set of real number R. Then
(A) a 2  3b  15  0 (B) a 2  3b  15  0 (C) a 2  3b  15  0 (D) a  0 and b  0

7. C
dy
Sol.  3 x 2  2ax  b  10 sin x cos x
dx
and discriminant < 0
n
a1 a a a
8. If a1 , a2 , a3 ,... are in H.P. and f  k   a r  ak , then , 2 , 3 ,..., n are in
r 1 f 1 f  2  f  3 f n
(A) A.P. (B) G.P. (C) H.P. (D) None of these
8. C
n
Sol. Let a
r 1
r  Sn
1 1 1 1
, , ,.... in A.P.
a1 a2 a3 an
S n Sn Sn S
, , ,....., n in A.P.
a1 a2 a3 an
Sn S S
 1, n  1, n  1... in A.P.
a1 a2 a3
1 1 1
 , , ...... H.P.
Sn Sn Sn
1 1 1
a1 a2 a3
a a a
 1 , 2 , 3 ,..... in H.P.
f 1 f  2  f  3
1 1
9. A problem in mathematics is given to 3 students whose chances of solving individually are ,
2 3
1
and . The probability that the problem will be solved atleast by one is
4
1 1 23 3
(A) (B) (C) (D)
4 24 34 4
9. D
Sol. 1 – Nobody solves the problem
 1  1  1 
 1   1   1   1  
 2  3  4 
10. If a  I and the equation  x  a  x  10   1  0 has integral roots, then the values of a are
(A) 6, 8 (B) 8, 10 (C) 10, 12 (D) 8, 12
10. D
Sol.  x  a  x  10    11
so either x  a  1 and x  10  1
or x  10  1 and x  a  1
11. If 2 x  6 y  2 touches the hyperbola x 2  2 y 2  4 , then the point of contact is

1 1 
(A)  2, 6  (B)  5, 2 6  (C)  ,
2 6
 (D)  4,  6 
11. D
2  6y
Sol. Put x  in equation of hyperbola
2
 y 6  x4
2
12. Consider a circle with its centre lying on the focus of the parabola y  2 px such that it touches
the directrix of the parabola. Then a point of intersection of the circle and the parabola is
p  p   p p
(A)  , p  or  ,  p  (B)  , 
2  2   2 2
 p   p p
(C)   , p  (D)   ,  
 2   2 2
12. A
Sol. If focal chord is diameter of the circle then it touches the directrix of the parabola
x
13. 
If a, a
2
 falls inside the angle made by the linear equations y  , x  0 and y  3x, x  0 , then
2
a belongs to
 1  1 1 
(A)  3,   (B)  0,  (C)  3,  (D)  ,3 
 2  2 2 
13. D
Sol. Locus of point  a, a 2  is y  x
2
y  x2
y  3x x
 y  x 2 and y 
(3, 9) 2
x 1
y x  0,
2 2
 y  x 2 , y  3x
1 1 x  0,3
 , 
2 4 1
a3
2
14. The straight lines whose direction cosines satisfy al  bm  cn  0, fmn  gnl  hlm  0 are
perpendicular if
a 2 b2 c2
(A) af  bg  ch  0 (B)   0
f g h
f g h
(C)   0 (D) a 2 f  b 2 g  c 2 h  0
a b c
14. C
bm  cn
Sol. Put l  in the another equation,
a
 bm  cn 
fmn   gn  hm   0
 a 
 bhm  mn  bg  ch  af   cgn 2  0
2
m1m2 n1n2 ll
  12
g /b h/c f /a
–1 2
15. Domain of derivative of the function f (x) = |sin (2x – 1)| is
 1 
(A) [–1, 1] (B) [–1, 1] ~ 0,  
 2
 1 
(C) [–1, 1] ~ {0} (D) [–1, 1] ~  
 2
15. B
Sol. y = |sin–1 (2x2 – 1)|

sin1 (2x 2  1) 4x
y = 1 2

sin (2x  1) | 2x | 1  x 2
–1 2 2
 x  0 and sin (2x – 1)  0 and |2x – 1|  1  |x|  1
1
 x  0, x   .
2

 1 
16.  tan1  r 2  5r  7  equals to
r 1

(A) tan–1 3 (B)
4
1
(C) sin1 (D) cot–1 2
10
16. C
 1  1  (n  3)  (n  2) 
Sol. an = tan1    tan  
 1  (n  3)(n  2)   1  (n  3)(n  2) 
= tan–1 (n + 3) – tan–1 (n + 2)
Sn = tan–1 (n + 3) – tan–1 3
 1
S =  tan1 3  cot 1 3  sin1 .
2 10
17. If P1, P2, P3 be the lengths of perpendiculars from the vertices of the triangle ABC to the opposite
sides, then
(A) P1P2P3 = abc (B) P1P2P3 = 8R3
a2b2c 2 a2b2c 2
(C) P1P2P3 = (D) P 1 P 2 P 3 =
R3 8R 3
(where R is circumradius of triangle ABC).
17. D
Sol. P1 = c sin B, P2 = a sin C, P3 = b sin A

a2 b 2 c 2
P1P2P3 = abc sin A sin B sin C = .
8R3
18. A unit vector is orthogonal to 5iˆ  2jˆ  6kˆ and is coplanar to 2iˆ  ˆj  kˆ and ˆi  ˆj  kˆ , then the
vector is
3ˆj  kˆ 2iˆ  5ˆj
(A) (B)
10 29
6iˆ  5kˆ 2iˆ  2ˆj  kˆ
(C) (D)
61 3
18. A

Sol. Let a be the unit vector

 a    2iˆ  ˆj  kˆ     ˆi  ˆj  kˆ 

 | a | = 1  (2 + )2 + ( – )2 + ( + )2 = 1
 62 + 4 + 32 = 1

a is orthogonal to 5iˆ  2jˆ  6kˆ so, 5(2 + ) + 2( – ) + 6( + ) = 0
 18 + 9 = 0  2 = – 
 62 – 82 + 122 = 1
 102 = 1
1 2
= = 
10 10
ˆ
 3j k ˆ
a  .
10
2
19. If the curve y = x + bx + c touches the straight line y = x at the point (1, 1), then b and c are given
by
(A) –1, 1 (B) –1, 2
(C) 2, 1 (D) 1, 1
19. A
Sol. y = x touches y = x2 + bx + c
1=1+b+cb+c=0 ……(1)
dy
 2x  b (1, 1)  2  b  1  b  1 , c = 1.
dx
(b, c) = (–1, 1).
20. In the sequence 1, 2, 2, 3, 3, 3, 4, 4, 4, 4 ....... , where n consecutive terms have the value n, the
150th term is
(A) 17 (B) 16 (C) 18 (D) none of these
20. A
Sol. 1, 22, 333, 4444,........
1  2  3  4  .......
16  17 th
when last time 16 will appear that will be = 136 term
2
so after that 17 will repeat from 137th term to 153th term
Ans is 17
 5 2n 
21. The value of   , n  N where {.} denotes the fractional part of x, is
 24 
(A) 5/24 (B) 9/24 (C) 1/24 (D) None of these
21. C
n
Sol.
 24  1
24
z1  z 2 z
22. If z1 and z2 are two complex numbers satisfying the equation  1 , then 1 is a number
z1  z2 z2
which is
(A) Positive real (B) Negative real
(C) Zero or purely imaginary (D) None of these
22. C
z1 t 1
Sol. Let  t,  1 t  1  t  1
z2 t 1
 locus of t is line  y axis
23. The number of ways of switching the network such that the bulb glows is
(A) 61 (B) 60
(C) 63 (D) None of these
23. A
Sol.  3
C0  3C1  3C2  3C3   3  1  3  1  1 3  61
24. If 2 sin .sec 3 = tan 3  -tan , then 2[sin .sec 3+sin 3.sec 32 +..+sin 3n –1 .sec 3n] =
1
(A) tan 3n -tan  (B) tan 3n -ntan  (C) tan 3n -tan 3n –1 (D) (tan 3n -tan )
2
24. A
2 2
Sol. Using method of difference, 2sin 3 sec 3   tan 3   tan 3 and so on.
cos C tan A 0
25. The determinate sin B 0  tan A has the value where A, B, C are angles of a triangle
0 sin B cos C
(A) 0 (B) 1 (C) sinA. sinB (D) cosA cosB cosC
25. A
Sol. Expand along the 1st row
  cos C tan A sin B  tan A sin B cos C
26. The equation of the image of the circle x2  y 2  16 x  24 y  183  0 by the line mirror 4 x  7 y  13  0 is
(A) x2  y 2  32 x  4 y  235  0 (B) x2  y 2  32 x  4 y  235  0
(C) x2  y 2  32 x  4 y  235  0 (D) None of these
26. A
Sol. Radius will remain same, image of center (-8, 12) is (-16, -2) w.r.t. line 4 x  7 y  13  0
x2 y2
27. For hyperbola   1, which of the following remains constant with change in '  ' ?
cos 2  sin 2 
(A) abscissae of vertices (B) abscissae of foci
(C) eccentricity (D) directrix
27. B
Sol. eccentricity = sec 
so foci are constant
 sin  x 
 ,  x  0
28. If f  x     x 
 0,
  x  0
Where, [x] denotes the greatest integer less than or equal to x, then lim f  x  equals:
x0
(A) 1 (B) 0 (C) -1 (D) None of these
28. D
 sin  x 
 ,  x  0
Sol. f  x     x
0
 ,  x  0
lim f  x   0
x 0
sin  1
lim f  x    sin1
x 0 1
29. For a real number y, let [y] denote the greatest integer less than or equal to y. Then the function
tan   x    
f  x  2
is:
1   x
(A) discontinuous at some x
(B) continuous at all x, but the derivative f '  x  does not exist for some x
(C) f '  x  exists for all x, but the derivative f ''  x  does not exist for some x
(D) f ''  x  exists for all x
29. D
Sol. It is a zero function, f  x   0
1  (sin x)2 / 3
30.
 4/3
d(sin x)1/ 3 is equal to
1  (sin x)
2/ 3
1  sin x   1 1   sin x  2 / 3  1 
(A) c (B) tan1  c
2 2  sin x 
1/ 3
2  2  sin x 1 / 3 
 
1   sin x 1 / 3  1 
(C) tan1  c (D) none of these
2  2  sin x  2 / 3 
 
30. B
1
1/3
Sol. Let  sin x   t  d  sin x  3  dt
 1
d t  
Using algebraic twins, 
 t
2
 1
 t   2
 t
SAMPLE TEST - 2
response.
above.

= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
-27
= 6.25 x 10 erg.s
-27
1 amu = 1.66 x 10 kg
1 eV = 1.6 x 10-19 J
Au=79.
Mn=55, Si = 28 Pb=207, u=197, Ag=108, F=19, H=2, Cl=35.5
   
1. If A  B  B  A then the angle between A and B is
(A) (B)  / 3 (C)  / 2 (D)  / 4.
1. A
       
Sol.   
A  B  B  A or A  B – B  A  0 
     
   
or A  B  A  B  0 or 2 A  B  0 
or 2ABsin nˆ  0. As A  0 nor B  0,
So sin =0. Hence =0° or 
2. A ball is projected from the top of a tower of height 40 m with a velocity of 20 m/s at an angle of
300 with horizontal. The ratio of time of flight to the time taken to reach the ground is
(A) 1 : 1 (B) 1 : 2
(C) 2 : 1 (D) 2 : 3
2. B
2  20
Sol. t1 =  sin 30
10
t1 = 2 sec
1
40 = - 20 sin 30  t +  10  t2
2
t2 = 4 sec
t1 : t2 = 1 : 2
3. A particle starting from the origin (0, 0) moves in a straight line in (x, y) plane. Its coordinates at a
later time are (3, 3). The path of the particles makes with the x-axis an angle of.
(A) 45° (B) 60° (C) 0° (D) 30°.
3. B
Sol. Refer fig. let at a given time the particle be (A) and  be the angle between OA and OX. Then
3
tan   3  tan 60  or   60 
3
4. A body of mass 1 kg is projected with a velocity of 10m/s at an angle 600 w.r.t. horizontal ground.
The maximum value of gravitational potential energy in its motion is
(A) 50J (B) 25J
(C) 35J (D) 37.5J
4. D
15
Sol . Hmax. = m
4
PE = mg Hmaximum
1 10  15
PE = = 37.5
4
5. A block is kept on a frictionless inclined surface with angle of inclination ‘’ as shown in fig. the
incline is given an acceleration ‘a’ to keep the block stationary. Then a is equal to
(A) gtan (B) g (C) gcosec (D) g /tan .
5. A
Sol. As is clear from fig, the block is provided by stationary, when
gsin 
macos   mgsin  a   g tan .
cos 
6. A stationary particle explodes into two particles of masses m 1 and m2, which move in opposite
directions, with velocities v 1 and v2. The ratio of their kinetic energies (E1/E2) is
(A) m2 / m1 (B) m1 / m2 (C) 1 (D) m1 v2/m2v1
6. A
Sol. According to the principle of conservation of linear momentum,
m1v1 – m2v2 = 0
m1 v 2

m 2 v1
1
m v2 2
E1 2 1 1 m1  m2  m2
    
E2 1 m2  m1  m1
m2 v 22
2
7. Two spheres of masses m and M are situated in air and the gravitational force between them is F.
the space around the masses is now filled with a liquid of specific gravity 3. The gravitational
force will now be.
(A) 3 F (B) F (C) F / 3 (D) F / 9.
7. B
Sol. The gravitational force between two masses is independent of the presence of other masses.
8. In the fig. a common emitter configuration on NPN transistor with current gain  = 100 is used.
The output voltage of the amplifier will be
(A) 10 mV (B) 0.1 V (C) 1.0 V (D) 10 V

8. (C)
V0 R
Sol. Voltage gain, A V   ac  L
Vi Ri
RL
or V0  Vi  ac 
Ri
 100 
 
 10 –3 V  100   
 1 
  1V.
9. A particle is moving in a X-Y plane under the action of a force such that its instantaneous
momentum p  3 cos t î  3 sin t ĵ . The instantaneous angle between the force and momentum
is
 
(A) (B)
2 4
(C)  (D) zero
9. A
dp
Sol. F=   3 sin t î  3 cos t ĵ
dt
F.p = 0   = 900
10. A cylinder contains 10 kg of gas at pressure of 107 Nm–2, the quantity of gas taken out of the
cylinder, if final pressure is 2.5 × 106 Nm–2
(A) 7.5 kg (B) 10.5 kg (C) 5.2 kg (D) none of these.
10. (A)
1M 2
Sol. P C ;so,P  M
3V
P M
 1  1
P2 M2
P2 2.5  106
or M2  M1  10   2.5kg
P1 107
Quantity of gas taken out = 7.5Kg.

11. A particle of mass M and charge Q moving with velocity  describes a circular path of radius R
when subjected to a uniform transverse magnetic field of induction B. The work done by the field
when the particle completes one full circle is
 M2 
A   2 R (B) zero (C) BQ 2  R (D) BQ  2 R
 R 
11. (B)
 
Sol. In one complete circle, the displacement s = 0. As work done W  F.S  Fscos   0.
12. Two masses A of 0.5 kg and B of 0.3 kg having specific heat capacities of 0.85 J/kg K and 0.9
J/kg K respectively are at temperatures 600C and 900C respectively. When connected with each
other with a conducting rod, heat will flow from
(A) A to B
(B) B to A
(C) Initially from A to B and then from B to A
(D) Heat can’t flow
12. B
Sol. Irrespective of the heat content and nature of surfaces, heat will flow always from high
temperature eto low temperature object.
13. In an oscillating LC circuit, the maximum charge on the capacitor is Q. The charge on the
capacitor, when the energy is stored equally between the electric and magnetic field is
(A) Q/2 (B) Q / 2 (C) Q / 3 (D) Q/3
13. (B)
Q2
Sol. Max. Energy stored in a capacitor E1 
2C
When energy is stored equally between the electric and magnetic fields, then energy in the
1
capacitor is E2  E1
2
Q2 Q2 1 Q2
If Q’ is the charge on the capacitor in this case, then E 2   
2C 2C 2 2C
Q
Q'  .
2
14. In YDSE, two slits are made 5 mm apart and the screen is placed 2 m away. What is the fringe
separation when light of wavelength 500 nm is used?
(A) 0.002 mm (B) 0.02 mm (B) 0.2 mm (D) 2 mm
14. (C)
–3
Sol. Here, d = 5 mm = 5 × 10 m, D = 2m
–7
 = 500 nm = 5 × 10 m
 D 5  10–7  2
   2  10 –4 m
d 5  10 –3
= 0.2 mm.
15. A convex lens is dipped in a liquid whose refractive index is equal to the refractive index of the
lens. Then its focal length will
(A) Become zero (B) become infinite (C) Reduce (D) increase.
15. (B)
Sol. when 1 = 2, then from
1  u2  1 1 
  – 1 – 
f  u1  R1 R 2 
1
 0 or f  
f
i.e. focal length becomes infinite.
16. Momentum of a photon of energy 1 MeV in kg ms–1 will be
(A) 5 × 10–22 (B) 0.33 × 106 (C) 7 × 10–24 (D) 10–22
16. (A)
Sol. Energy of photon, E = 1 MeV
= 1 × 106 × 1.6 × 10–19 J
E
Momentum of photon, p 
c
6 –19
10  1.6  10
 8
 5.3  10 –22 kg ms–1.
3  10
17. If a star converts all helium in its core to oxygen then energy released per oxygen nuclei is
[Mass of He – 4.0026 a.m.u., mass of O – 15.9994 a.m.u.]
(A) 10.24 MeV (B) 0 (C) 7.56 MeV (D) 5 MeV
17. (A)
Sol.   4
4 2 He 8 O16  Q
m  4  4.0026   15.9994
 m  0.011
E  0.011  931.25
 10.24MeV
18. In the middle of the depletion layer of reverse biased p-n junction, the
(A) Electric Field is zero (B) Potential is maximum

(C) Electric field is maximum (D) Potential is zero
18. (D)
Sol. In case of a reserve biased p-n junction, the voltage applied supports the barrier voltage. Due to
which the electric potential at the middle of depletion layer becomes zero.
19. Consider telecommunication through optical fibres. Which of the following statements is not
correct?
(A) Optical fibres have extremely low transmission loss
(B) Optical fibres may have homogeneous core with a suitable cladding
(C) Optical fibres can be graded refractive index
(D) Optical fibers are subject to electromagnetic interference from outside
19. (D)
Sol. In optical fibers, the electromagnetic waves from outside cannot interfere with the
telecommunication through optical fibers.
20. A tuning fork of frequency 256 Hz produces a faint sound when kept near the mouth of a one end
closed cylindrical tube. When water is poured, such that 31 cm of air column exists, the sound
becomes loud. The speed of sound in air is
(A) 317 ms1 (B) 371ms 1 (C) 340 ms 1 (D) 332ms 1
20. A
v
Sol. f  as the cylinder will behave as a closed pipe.
4l
So, v  4lf  4  0.31  256  317.44 ms 1
21. A Carnot engine takes 3 × 106 cals of heat from a reservoir at 627°C and gives it to a sink at
27°C. the work done by the engine is
(A) 4.2 × 106J (B) 8.4 × 106 J (C) 16.8 × 106J (D) 3 × 106J
21. (B)
Sol. Here, T1 = 627º = 627 + 273 = 900 K
T2 = 27ºC = 27 + 273 = 300 K
Q1 = 3 × 106 cals, W = ?
Q2 T2 300 1
  
Q1 T1 900 3
Q1 Q 2 2
Q2  W  Q1 – Q 2  Q1 – 1  Q1   3  106 cals
3 3 3 3
6
W = 2 × 10 cals
= 8.4 × 106 J.
22. A car moving with a speed of 50 km/h, can be stopped by brakes after at least 6 m. if the same
car is moving at a speed of 100 km/h, the minimum stopping distance is
(A) 12 m (B) 18 m (C) 24 m (D) 6 m.
22. (C)
500
Sol. When u  50km / h  ms–1;
36
v  0,s  6m
2
v 2 – u2 0 –  500 / 36 
Then a    16ms–2
2s 2 6
2
500 v 2 – u2 u2  27.78 
when u  100km / h  2   27.78m / s. s  –   24m
36 2s 2a 2  16
23. Three charge are placed at the vertices of an equilateral triangle of side a as shown in Fig. The
force experienced by the charge placed at the vertex A in a direction parallel to BC is
2 2 2 2 2 2
(A) Q /4  0 a (B) – Q /4  0 a (C) Zero (D) Q /2  0 a
23. (A)
Q2
Sol. FAC   f, along CA.
4 0 a 2
Q2
FAB   f, along AB.
4 0 a2
Angle between the two forces,  = 120º.
Net force on the charge at A.
F  f 2  f 2  2ff cos120º
 f2  f2 – f2  f2
The direction of F is parallel to CB.
24. 2kg of ice at –20°C is mixed with 5 kg of water at 20°C in an insulating vessel having a negligible
heat capacity. Calculate the final mass of water remaining in the container. It is given that the
specific heats of water and ice are 1 kcal/kg./°C and 0.5 kcal/kg/°C. while the latent heat of fusion
of ice = 80 kcal/kg
(A) 7 kg (B) 6 kg (C) 4 kg (D) 2 kg.
24. (B)
Sol. heat released by 5 kg of water when its temperature falls from 20°C to 0°C
Q1 = cm (T) = 103 × 5 × 20 = 0.2 × 105 cals
This heat is used in raising the temp. of 2 kg of ice at –20° C to 0°C and then melting it
subsequently.
Heat energy taken by 2kg of ice at – 20°C in coming to 0°C is
Q2 = cmT = 500 × 2 × 20 = 0.2 × 105 cal
The remaining heat
5
Q = Q1 – Q2 = 0.8 × 10 cal.
Q 0.8  10 5
Mass of ice melted,m    1kg
L 80  10 3
 Temperature of mixture will become 0°C
Mass of water in it = 5 + 1 = 6 kg
Mass of ice left in it = 2 – 1 = 1 kg.
25. The rms value of the electric field of the light coming from the sun is 720 NC–1. The average total
energy density of the electromagnetic wave is
–3 –3 –6 –3 –9 –3 –12 –3
(A) 3.3 × 10 Jm (B) 4.58 × 10 Jm (C) 6.37 × 10 Jm (D) 81.35 × 10 Jm
25. (B)
Sol. Total average energy density of electromagnetic waves is
1 1
u  0 E02  0 Erms2 2
 2 0 Erms
2 2
–12 2
= (8.85 × 10 ) × (720)
–6 –3
= 4.58 × 10 Jm
26. The displacement of the body in metres varies with time as x = 2t3 + 5. The mass of the body is 2
kg. What is the increase in its kinetic energy one second after the start of the motion
(A) 20 J (B) 30 J
(C) 36 J (D) 48 J
26. C
dx
Sol. = 6t2 = v
dt
1 2 1
mv =  2. (6)2 = 36 J
2 2
27. A closed organ pipe of length L and an open organ pipe contain gases of densities 1 and  2
respectively. The compressibility of gases are equal in both the pipes. Both the pipes are
vibrating in their first overtone with same frequency. The length of the open organ pipe is
L 4L 4 L 1 4 L 2
(A) (B) (C) (D)
3 3 3 2 3 1
27. (C)
B B
v1 v2 1 2 4L 1
Sol.     L' 
1 2 4L 2L ' 3 2
3 2
28. The velocity of the small ball of mass M and density d1 when dropped in a container filled with
glycerin becomes constant after sometime. If the density of glycerin is d2, the viscous force acting
on the ball is.
(A) Mg (1 – d2/d1) (B) Mg d1/d2 (C) Mg (d1 – d2) (D) Mg d1d2.
28. (A)
Sol. when ball is moving through a medium with a terminal velocity, then viscous force
Fv = W – FB
M  d 
So Fv  Mg – d2 g  Mg  1– 2 
d1  d1 
29. The current flowing through wire depends on time as, I = 3t2 + 2t + 5. The charge flowing through
the cross-section of the wire in time t = 0 to t = 2 sec is
(A) 22 C (B) 20 C (C) 18 C (D) 5 C
29. (A)
dq
Sol. I  3t 2  2t  5
dt
or dq = (3t2 + 2t + 5)dt
t 2x
  3t 
2
 q  2t  5 dt
t 0
2
 3r 2 2t 2 
   5t 
 3 2 0
2

 t3  t 2  t  0
 22 C.
30. If the maximum speed of a particle in SHM is 5 m/s. The average speed of the particle is SHM is
equal to
5 10 5
(A) m/s (B) m/s (C) m/s (D) zero
  2
30. B
 A sin t 2 A 10
0
Sol. vavg. =   m/s
T  
 dt
0
1. What is the equivalent weight of HClO4 ?
(A) 100.5 (B) 50.3 (C) 60.1 (D) 90.5
1. A
molecular mass
Sol. Equivalent weight =  Basicity  1
Basicity
100.5
  100.5 gm
1
2. 1.82 gm of a metal requires 32.5 ml of 1N HCl to dissolve it. What is the equivalent weight of
metal?
(A) 46 (B) 65 (C) 56 (D) 42
2. C
Sol. mille equivalents of metal = N V ml 
weight
 1000  1 32.5
E
1.82 1820
 1000  32.5  E   56
E 32.5
3. For a p-electron, the orbital angular momentum is
h h h h
(A) 3 (B) (C) 2 (D)
2 2 2 
3. C
Sol. For p – electron  l  1
h h
O. A.M .  l  l  1  2
2 2
4. Calculate the frequency of the spectral line emitted when the electron in n = 3 in H-atom de-
excites to ground state.
(A) 2.92  1015 sec 1 (B) 4.52  1015 sec 1 (C) 3.2  1010 sec 1 (D) 1.9  1010 sec1
4. A
1 1 1 c 1 1
Sol.  RH Z 2  2  2    v  RH .Z 2 c  2  2 
  n1 n2    n1 n2 
v  2.92  1015 sec 1
5. Which one of the following transition metal ions is diamagnetic?

2 2 2 2
(A) Co (B) Ni (C) Cu (D) Zn
5. D
Sol. Zn 2 ions have all paired electrons, so it is diamagnetic.
6. Which of the following is expected not to exist?

(A) H 3 BO3 (B) NaBO2 (C) B2 N (D) B2 H 6
6. C
Sol. Boron nitrite is BN
7. The hydrogen bond is strongest in

(A) O  H    S (B) S  H    O (C) F  H    F (D) F  H    O
7. C
Sol. F  H    F hydrogen bond is strongest, because as the electronegativity difference increase,
H-bond strength increases
8. What is the increasing order of lattice energies of MgO, CaO, SrO and BaO
(A) MgO  CaO  SrO  BaO (B) CaO  MgO  BaO  SrO
(C) BaO  SrO  CaO  MgO (D) BaO  MgO  CaO  SrO
8. C
Sol. BaO  SrO  CaO  MgO
1
 Lattice energy 
size of cation
9. Which is the correct order for the graph below? P1

(A) P1  P2  P3 (B) P2  P1  P3 P2
(C) P3  P2  P1 (D) P3  P1  P2 P3
V
T
9. C
Sol. 1 P1
Since V   acc. to Boyle's law  P2
P
We can see from the graph P3
V
V1  V2  V3
 P3  P2  P1
10. Which is the incorrect graph?

(A) (B) (C) (D)
P P V PV
V V T V
10. A
Sol. 1
 P  acc. to Boyle's law 
V
P
11. HI was heated in sealed tube at 4000C till the equilibrium was reached. HI was found to be 22%
decomposed. The equilibrium constant for dissociation is
(A) 1.99 (B) 0.0199 (C) 0.0796 (D) 0.282
11. B
2 HI  H 2  I 2
Sol. 1 0 0
1  .22 .11 .11
 H   I  0.11  0.11
KC   2   2 2   2
 0.0199
 HI   0.78
12. When sulphur in the form of S8 is heated at 900K, the initial pressure of 1 atm falls by 30% at
equilibrium. This is because of conversion of same S8 to S2. Find the value of equilibrium
constant for this reaction?
3 3 3 3
(A) 2.55 atm (B) 2.96 atm (C) 0.71 atm (D) 3.4 atm
12. B
S8  g   4 S2  g 
Initially 1 0
Sol.
At equilibrium 1  .30  4  0.30
= 0.70 atm = 1.2 atm
4
KP 
 P   1.2  2.96 atm
'
S2
4
3
 P   0.70
S8
'
13. Catalyst is a substance which

(A) Supplies energy to the reaction
(B) Increases the equilibrium concentration of the product
(C) Changes the equilibrium constant of the reaction
(D) Lowers the activation energy barrier
13. D
Sol. Catalyst lowers the activation energy barrier
14. What is the pH of solution which have 0.1M NH3 and 0.05 M NH 4Cl Given that
K b  NH 3   105
(A) 9.3 (B) 5 (C) 4.74 (D) 8.26
14. A
Sol. For basic buffer
pOH  pK b  log
 Salt 
 Base 
pOH  4.7
 pH  14  4.7 = 9.3
15. DDT is an example of

(A) Fungicide (B) Herbicide (C) Insecticide (D) Analgesic
15. C
Sol. DDT is an example of Insecticide
-1 -1
16. The catalyst decrease the Ea from 100 kJ mol to 80 kJmol . At what temperature the rate of
reaction in the absence of catalyst at 500 K will be equal to rate of reaction in presence of
catalyst.
(A) 200 K (B) 400 K (C) 625 K (D) None of these
16. B
Sol. Using relation,
Ea
log k  log A 
2.303RT
Rate constant will not change in the presence of catalyst.
 log k1  log k2
Ea1 Ea2

T1 T2
100 80

500 T2
T2  400 K
17. The increasing order of stability of the following free radicals is

   
(A)  CH 3 2 C H   CH 3 3 C   C6 H 5 2 C H   C6 H 5 3 C
   
(B)  C6 H 5 3 C   C6 H 5 2 C H   CH 3 3 C   CH 3 2 C H
   
(C)  C6 H 5 2 C H   C6 H 5 3 C   CH 3 3 C   CH 3 2 C H
   
(D)  CH 3 2 C H   CH 3 3 C   C6 H 5 3 C   C6 H 5 2 C H
17. A
Sol. Free radicals stability
H5C6 C C6H5 > H5C6 CH > H3C C CH3 > H3CC H
C6H5 C6H5 CH3 CH3
Highly stable by delocalisation 9-hyperconjugative hydrogens
and +I effect
18. Among the following structures which is not a correct resonance form:
(A) + (B) H2C N O

H2C N O
CH3 CH3
(C) + (D) +
H2C N O H2C N O
CH3 CH3
18. B
Sol. In (B), resonating structure is not proper Lewis structure.
19. The reaction

H
OH H
H3C Cl
 SOCl2 
 H3C  SO2  HCl
CH3
CH3
Proceeds by the ……….mechanism.
(A) SNi (B) SN2 (C) SE2 (D) SE1
19. A
Sol. Since the given reaction proceeds through retention of configuration the mechanism of the
reaction is SNi
20. Which of the following statement about the sulphates of alkali metal is correct?
(A) Except Li2 SO4 , all sulphates of other alkali metals are soluble in water
(B) All sulphates of alkali metals except Li2 SO4 forms alum.
(C) The sulphates of alkali metals cannot be hydrolysed
(D) All of these
20. D
Sol. All are facts
21. The compound which undergoes SN1 reaction most rapidly is
(A) Br (B) Br (C) CH2Br (D) Br
21. B
Sol. In case of the given compound the carbocation intermediate is resonance stabilized. Hence the
reaction is most favoured by SN1.
22. A solution of (+) 1-chloro-1-phenylethane in toluene racemises slowly in the presence of small
amount of SbCl5, due to the formation of
(A) carbanion (B) carbene (C) free-radical (D) carbocation
22. D
Sol.
CH3 H CH3 CH3

 SbCl6  SbCl6
H Cl  SbCl5  Ph C  H Cl  Cl H
 SbCl5
Ph CH3
Ph Ph
23. A mixture of benzoic acid and phenol may be differentiated by treatment with
(A) NaHCO3 (B) NaOH (C) NH3 solution (D) KOH
23. A
Sol. Ph  COOH  NaHCO3  PhCOO  Na   CO2   H 2O
PhOH  NaHCO3  No reaction

24. The compound which reacts fastest with Lucas’ reagent at room temperature is
(A) 1-butanol (B) 2-butanol
(C) 2-methyl propan-1-ol (D) 2-methyl propan-2-ol
24. D
Sol. 2 –methylpropan-2-ol forms the most stable 30 carbocation hence (D) is most reactive.
O
25. The ether when treated with HI produces
(A) (B)
+ OH + I
I OH
(C) (D)
I OH + I
+
OH
25. A
Sol.
O
+ +
+ H Ph O I
PhOH  CH 2  Ph 

 Ph  CH 2 I
H Ph
26. 1 g of a monobasic acid HB (having pKa = 5) in 100g water lower the freezing point by 0.155K. If
M
0.45 g of same acid required 15 ml NaOH solution for complete neutralization
5
 k , H O  1.86 K kg mol , density of H O is 1 g/ml  , then which of the following option is
f 2
-1
2
incorrect regarding above question

(A) degree of ionization of acid is 0.25
(B) the pH of the resultant solution at the end point of neutralization is greater than 7
(C) normal molecular mass of acid is 150
(D) 10 g of acid HB is hypotonic with 0.625 g urea at the same temperature and same volume of
H2O.
26. D
Sol. T f  K f m
M  acid observed
 120
meq of acid = meq of base
M  acid normal
 150
150
i  1.25  1  
120
  0.25
pH > 7 as the solution contains salt of strong base and weak acid.
27. Which of the following electrolyte is most effective in the coagulation of gold sol?
(A) NaNO3 (B) K 4  Fe  CN 6  (C) Na3 PO4 (D) MgCl2
27. B
Sol. According to Hardy Schulze Rule.
28. Which of the following is false?

(A) When NaCl is heated in the atmosphere of Na, metal excess defect arise due to the migration
of Na from vapour to NaCl lattice.
(B) Both Schottky and Frenkel defects can effect electrical conductivity and this conduction is
known as intrinsic semiconduction.
(C) Density decreases in Frenkel defect but remains same in Schottky defect
(D) In compounds having metal excess defect F-centres are present which makes them
paramagnetic, coloured and help in n-type semiconduction.
28. C
Sol. C is false.
29. Ammonia gas can be dried by

(A) conc. H2SO4 (B) P2O5 (C) quick lime (D) None of these
29. C
Sol. NH 3  H 2 SO4   NH 4 2 SO4
NH 3  P2O5   NH 4 3 PO4
30. What is the relation between the following compounds?
O OH -
O
HN NH N N + +
HN NH
O NH O HO N OH - + -
O N O
H
(a) (b) (c)
(I) ‘b’ and ‘c’ are resonating structures.
(II) ‘a’ and ‘b’ are resonating structures.
(III) ‘a’ and ‘b’ are tautomers.
(IV) ‘a’ and ‘c’ are tautomers.
Which of the above statement/s is/are correct?
(A) (I), (III) only (B) (II), (IV) only (C) (III) only (D) (IV) only
30. C
Sol. Tautomers are functional group isomers in equilibrium
pace for rough work

1. A man standing on a horizontal plane, observes the angle of elevation of the top of a tower to be
 . After walking a distance equal to double the height of the tower, the angle of the elevation
becomes 2, then  is equal to
   
(A) (B) (C) (D)
2 6 12 18
1. B
Sol.
h C
 tan 
x
3h 2 tan 
 tan 2 
x 1  tan 2  2h
2 tan 
 3 tan    3  3 tan 2   2  tan   0 
1  tan 2  B
1
 3 tan 2   1  tan 2  
3 2 h
1  
 tan    . O
3 6 x A
y
2. If cos 1 x  cos 1  , then
2
4 x 2  4 xy cos   y 2 is equal to:
(A) 4sin 2  (B) 4sin 2  (C) 4 (D) 2 sin 2
2. B
y
Sol. cos 1 x  cos 1 
2
 xy y2 
 cos 1   1  x 2 1  
 2 4 

xy y2
  1  x2 1  cos 
2 4
y2
2 1 x2 1  2 cos   xy
4
 y2 
 4 1  x 2  1    4cos 2   x 2 y 2  4 xy cos 
 4 
 1  x 2  4  y 2   4 cos 2   x 2 y 2  4 xy cos 
 4  4 x 2  y 2  x 2 y 2  4 cos 2   4 xy cos   x 2 y 2
 4  4 x 2  y 2  4 cos 2   4 xy cos 
4 x 2  4 xy cos   y 2  4 1  cos 2    4sin 2 
  3 
3. sin  2 cos 1     is equal to
  5 
6 24 4 24
(A) (B) (C) (D) 
25 25 5 25
3. D
 3 3
Sol. Put cos 1       cos   
 5 5
 given expression  sin  2
 4
 2 sin  cos   sin   5 
 
4 3 24
 2.     
5 5 25
12 3 63
4. If cos   ,cos   , cos   , then cos        is:
13 5 65
(A) 1 (B) 2 (C) 3 (D) 0
4. D
Sol. cos         cos  cos  cos   sin  sin  cos   sin  cos  sin   cos  sin  sin 
12 3 63 5 4 63 5 3 16 12 4 16
 . .  . .  . .  . .
13 5 65 13 5 65 13 5 65 13 5 65
2268  1260  240  768
 0
13.5.65
5. India plays two matches each with West Indies and Australia. In any match probabilities of India
getting points 0, 1 and 2 are 0.45, 0.05 and 0.5 respectively. Assuming that the outcomes are
independent, the probability of India getting at least 7 points is
(A) 0.8750 (B) 0.0875 (C) 0.0625 (D) 0.0250
5. B
Sol. Since there are just four matches to be played, India can get a maximum of 8 points.
 P(India gets at least 7 points)
= P(getting exactly 7 points) + P(getting exactly 8 points)
= P(getting 2 in each of the 3 matches and 1 in one match) + P(getting 2 in each of the four
matches)
3 4
 4 c3  0.5   0.05   4 c4  0.5 
3
  0.5   0.2  0.5   0.125  0.7  0.0875
6. The equation of the plane through intersection of planes x  2 y  3z  4 and 2 x  y  z  5 and
perpendicular to the plane 5 x  3 y  6 z  8  0, is
(A) 7 x  2 y  3z  81  0 (B) 23x  14 y  9 z  48  0
(C) 23x  14 y  9 z  48  0 (D) 51x  15 y  50 z  173  0
6. D
Sol. Any plane through the intersection of the given planes is
x  2 y  3z  4  K  2 x  y  z  5  0
i.e. 1  2 K  x   2  K  y   3  K  z  5K  4  0
This is  to 5 x  3 y  6 z  8  0
 5 1  2K   3  2  K   6  3  K   0
 29  7 K  0
29
K  
7
 reqd. plane is
 58   29   29  145
1   x   2   y   3   z  4 0
 7   7   7  7
 51x  15 y  50 z  173  0
 51x  15 y  50 z  173  0
x y 1 z  2
7. Image of the point A 1, 6,3 in the line   is
1 2 3
(A)  7,1, 0  (B)  2,5, 7  (C) 1, 0, 7  (D) None of these
7. C
Sol. Any point P on the given line is
 r, 2r  1, 3r  2 
 direction ratios of AP are
 r  1, 2r  5,3r  1
Now AP  to the given line if
1  r  1  2  2r  5   3  3r  1  0
 14r  14  0  r  1
 P is 1,3, 5 .
Thus the foot of the  from A on the line is 1,3, 5 . Let B  a, b, c  be the image of A in the given
line. Then P is the mid point of AB.
a 1 c3
  1  a  1 and 5c7
2 2
b6
3b  0
2
 B is (1, 0, 7)
         
8. If  2a  4b c d     a c d    b c d  , then    
(A) 6 (B) -6 (C) 10 (D) 8
8. A
         
Sol.  2 a  4b c d   2  a c d   4  b c d 
    
     
  
  a c d    b c d  
  2,   4     6
       
9. If x  y  a , x  y  b and x  a  1, then
     
  
 a  ab  a 2  1 a  a  b
   a  ab   
a2  a  b
(A) x  ,y (B) x  ,y
a2 a2 a2 a2
     
 b  a b
(C) x 
 
, y can have any value
  b  1 b  a  b
(D) y 
2
,y can have any value

a2 a2
9. A
     
Sol. x  y  a  y  a  x …1
  
x y  b …2

 x.a  1 …3
   
By (1) and (2), x   a  x   b
  
 xa  b
  
 xa  b
    
 a x  a  a b
    
  a.a  x  1.a  a  b
2    
 a x  1.a  a  b
  
 x
 
a  ab 
a2
   
    a  a b
yax a
    a 1 a  a  b
2
a2 a2
10. The product of the perpendicular and drawn from any point on a hyperbola to its asymptotes is
ab ab a 2b 2 a2  b2
(A) (B) 2 (C) (D)
a b a  b2 a2  b2 a 2b 2
10. C
a 2b 2
Sol. Product of perpendicular and drawn from any point on a hyperbola to its asymptotes =
a2  b2
x2
11. The number of values of c such that the straight line y  4 x  c touches the curve  y 2  1 is
4
(A) 0 (B) 1 (C) 2 (D) infinite
11. C
x2 y 2
Sol. y  4 x  c touches  1
4 1
If c 2  a 2 m 2  b 2  Here a 2  4, b 2  1, m  4 
i.e. If c 2  4 16   1  65
This gives two values of c.
x y x2 y2
12. If   2 touches the ellipse 2  2  1, then its eccentric angle  is equal to
a b a b
(A) 00 (B) 900 (C) 450 (D) 600
12. C
x cos  y sin 
Sol. Let  be the eccentric angle, then tangent at '  ' is  1
a b
x y
Also,   1 is the tangent
2a 2b
cos  sin 
  1
1 1
2 2
1 1
 cos   ;sin      450
2 2
13. The latus rectum of a parabola whose focal chord is PSQ such that SP = 3 and SQ = 2 is given
by
24 12 6
(A) (B) (C) (D) None of these
5 5 5
13. A
2 1 1
Sol. Since   (Where l is the semi-latus rectum of the parabola)
l SP SQ
2 1 1 5 12 24
    l   2l 
l 3 2 6 5 5
24
 latus rectum =
5
14. Let PQ and RS be tangent at the extremities of the diameter PR of a circle of radius r. If PS and
RQ intersect at a point X on the circumference of the circle, then 2r equals
PQ  RS 2 PQ.RS PQ 2  RS 2
(A) PQ.RS (B) (C) (D)
2 PQ  RS 2
14. A
Sol.
PQ PQ
tan   
PR 2r S Q
  RS
Also tan     
2  2r
RS
i.e. cot   /2
2r 
PQ.RS  2 
 tan .cot   R P
4r 2 r r
 4r 2  PQ.RS  2r   PQ  RS 
15. The line of the system a  2 x  y  2   b  x  3 y  4   0 situated farthest from the point (1, 1) is
(A) x  y  4  0 (B) x  2 y  6  0 (C) 2 x  y  6  0 (D) None of these
15. A
Sol. Point of intersection of 2 x  y  2  0 and x  3 y  4  0 is (2, 2).
The line of the system a  2 x  y  2   b  x  3 y  4   0 situated farthest from the point (1, 1) is
the line passing through (2, 2) and perpendicular to the line passing through points (1,1) and
(2,2).
16. Solution of the equation

dy y
x  y  x tan is
dx x
x y x y
(A) sin  Cx (B) sin  Cx (C) sin  Cy (D) sin  Cy
y x y x
16. B
Sol. Put y  vx
dv dy
v  x 
dx dx
dx
 cot vdv   log sin v  log Cx
x
y
 sin v  Cx  sin  Cx
x
17. The solution of the equation

 x 2  xy  dy   xy  y 2  dx is
(A) xy  Ce  y / x (B) xy  Ce  x / y (C) yx 2  Ce1/ x (D) None of these
17. B
dy xy  y 2
Sol.  . Put y  vx
dx x 2  xy
dv v  v 2 dv v  v 2
v  x  x  v
dx 1  v dx 1  v
v  v 2  v  v 2 2v 2
 
1 v 1 v
1 v dx
 2 dv  2
v x
 1 1 dx
 2   dv  2
 v v  x
1
   log v  2 log x  const .
v
x y
   log  log x 2  log C1
y x
x y 
  log  . x 2 .C1   log  C1 xy 
y x 
 C1 xy  e  x / y
1 x / y 1
xy  e  C.e  x / y (Take C1  )
C1 C
/2
sin x
18.  dx 
0 sin x  cos x
 
(A) (B) (C) 0 (D) 1
4 2
18. A
/2
sin x 
Sol.  dx 
0 sin x  cos x 4
10 
19.  sin x dx is
0
(A) 20 (B) 8 (C) 10 (D) 18
19. A
10 
/ 2 

Sol.  sin x dx  10   sin xdx   sin xdx 
0 0 /2 
/ 2 
= 10   cos x 0  10   cos x  / 2
 10 1  1  10  2  20
dx
20. x is equal to
1  x3
1  1  x3  1  1  1  x3  3 
(A) log  c (B) log  c
3  1  x3  1  3  1  x3  3 
   
2  1  1  1 
(C) log  c (D) log  c
3 3  3 3 
 1 x   1 x 
20. A
Sol. Put 1  x 3  y 2  3 x 2 dx  2 ydy
dx 2 ydy 2 ydy
  
x 1 x 3 3
3 x 1  x 3
3 1  y 2  y
2 dy 2 1 y 1
  . log c
3  y2 1 3 2 y 1
1 1  x3  1
 log c
3 1  x3  1
1
21. If f  x   log x  bx  x 2 , x  0, where b  0 is a constant, then
8
1
(A) f  x  has local minimum at x  for b = 1
4
(B) f  x  has no extremum for 0  b  1
b  b2  1
(C) f  x  has a local minimum at x  ,b  1
4
b  b2  1
(D) f  x  has a local maximum at x  ,b  1
4
21. B
1 1
Sol. f’(x) =  b  2 x; f "  x    2  2
8x 8x
For max or min, f’(x) = 0
1 – 8bx + 16x2 =0
8b  64b 2  64 b  b 2  1
x 
32 4
1
Case I. When b = 0, f’(x) =  2x  0
8x
Hence there is no extreme value for b = 0
Case II. When 0 < b < 1, then b 2  1  0
 x is not real.
 there is no extreme value for 0  b  1
1
Case III. When b  1, then x 
4
f " x   2  2  0
1 1
f '''  x   3
 16   0  for x 
4x 4
1
 x is a point of inflexion.
4
Case IV. When b > 1
b  b2  1 b  b2  1
Let   , 
4 4
Clearly   
We have
2
1 2 1 1  2  b 1 
f ' x    b  2 x   x 2  bx     x     b 2  1 
8x x 2 16  x  4  16 
2  b 1 2  b 1 2 
 x  b 1   x   b  1 
x  4 4  4 4 
2 2
  x    x      x    x   
x x
 f '  x   0, for 0  x  
f ' x  < 0, for   x   and f '  x   0 for x  
 f  x  has a local Max. at
1
x
4

b  b2  1 and local min. at 
1
x    b  b2  1
4
 
22. y  2 x  cot 1 x  log  
1  x 2  x , then y
(A) increases in  0,   only (B) decreases in  0  

(C) neither increases nor decreases in  0   (D) increases in  ,  
22. D
dy 1 1  1 
Sol.  2 2
 
 .2 x  1
dx 1 x 1  x2  x  2 1  x 2 
1 1 x  1  x2
 2 
1 x2 1 x2  x 1 x2
1 1
= 2 
1  x2 1 x2
2 x2  1 1
 
1  x2 1 x2
2x2  1  1  x2

1 x2
dy
Now  0  2x2  1  1  x2  0
dx
2
  2 x 2  1  1  x 2
 4 x 4  3x 2  0
Which is true for all real value of x. Hence y increases in  ,   .
sin 2 x
 12 1
2
1
2

23. lim 1sin x  2 sin x  ...  n sin x  =
x0
 
(A)  (B) 0 (C)

 n  1 (D) n
2
23. D
Sol. We have
2 2 2 sin 2 x
lim 11/ sin  21/ sin x  ...  n1/ sin x 
x
x0  
1/ t  1 
 lim 1' 2' ....nt   where 2
 t  1
t 0
 sin x 
t
1t  2t  3t  ...  nt  1  2  3  ...  n 
Since  
n  n 
t
t t  n  n  1 
t
 1  2  ...  n  n  
 2n 
t
 n 1
 n 
 2 
 n 1 
1/ t
 1t  2t  ...  nt   n1/ t .  
 2 
1/ t  n  1  n 1
 lim 1t  2t  ...  nt   lim n1/ t  
t  t 
 2  2
 n  1
 n  1 2n  n  1  n  2 
 
1/ t
 lim 1t  2t  ...  nt  n
t 
24. C02  C12  C22 ....  1 Cn2 , where n is an even integer is
2n n 2n n 2n
(A) Cn (B)  1 Cn (C)  1 C n 1 (D) None of these
24. D
n
Sol. We have 1  x   C0  C1 x  C2 x 2  ...  Cn x n ... 1
n
 1 C1 C2 n Cn
 1    C0   2  ...   1 n ...  2 
 x  x x x
n
 C02  C12  C22 ...   1 Cn2
= co-eff. Of the term independent of x in
Product of R.H.S. (1) and (2)
= co-eff. Of term independent of x in
n
n  1
  
1  x 1  
 x
n n
= co-eff. Of x n in  1 1  x 2  n Cn / 2 n is even 
1225 1915 1225
25. The digit at unit’s place in the number 13   11   23  is equal to:
(A) 0 (B) 1 (C) 2 (D) None of these
25. B
1225 1915 1225
Sol. 10  3  10  1   20  3 
I II III
Last term of Ist and IIIrd expansion gets cancelled and rest are divisible by 10 and in IInd
expansion last term is 1 and rest are divisible by 10 so at unit place this number has digit 1.
26. The number of parallelograms that can be formed from a set of four parallel lines intersecting
another set of three parallel lines is
26. D
Sol. Since each parallelogram is formed by choosing two parallel straight lines from the first and two
from the second set.
 total no. of parallelograms formed
 4 C2 3 C2  6  3  18
27. The number of triangles which can be formed from 12 points out of which 7 are collinear is
(A) 105 (B) 210 (C) 175 (D) 185
27. D
Sol. Reqd. no. of triangles
12  11  10 7  6  5
12 C3  7 C3  
1 2  3 1 2  3
 220  35  185
28. One root of the equation

3x  8 3 3
3 3x  8 3  0 is which of the following?
3 3 3x  8
8 2 1 16
(A) (B) (C) (D) .
3 3 3 3
28. B
Sol. Operate R1  R2  R3 ,
3x  8 3 3
3 3x  8 3 0
3 3 3x  8
 x  2 / 3 as one of the roots.
29. If  is a complex number such that  2    1  0 , then 31 is

(A)  (B)  2 (C) 0 (D) 1
29. A
Sol. Since  2    1  0
1  1  4 1  3i
     or 2 .
2 2
Take   
10
  31  31  30 .   3  .
10
 1 .    
31
Take   2  31   2 
 62  60 .2  1 2  2  
Hence  31   .
30. The domain of

x
f  x   cot 1 , x  R is
x   x 2 
2
(A) R (B) R  0 

(C) R   n , n  N  (D) None of these.
30. D
x
Sol. Domain of cot 1 x is R and is defined if x 2   x 2   .
x   x 2 
2

i.e. x 2 is not integer  x 2   x 2  
Hence x 2  non negative integer i.e. 0 or +ve integer.
Hence domain = R   n  0, n  Z 
Thus correct answer is (D)
SAMPLE TEST - 3
JEE - MAIN 2017
SET - A
response.
above.
JEE-MAIN -2017-SAMPLE TEST -3-PCM-2

= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
-27
= 6.25 x 10 erg.s
-27
1 amu = 1.66 x 10 kg
1 eV = 1.6 x 10-19 J
Au=79.
Mn=55, Si = 28 Pb=207, u=197, Ag=108, F=19, H=2, Cl=35.5
1. If L, R, C, V respectively represent inductance, resistance, capacitance and potential difference,
L
then the dimensions of are the same as those of
RCV
(A) Current (B) 1 (C) Charge (D) 1
Current Charge
1. B
L
Sol. Dimensions of  Time
R
Dimensions of CV = Charge
2 A body starting from rest with acceleration  which varies with time t according as
  At  B
where A and B are the constants.
The velocity of the particle after time t is:
At 2 At 2 Bt
(A)  A  B t (B)  2 Bt (C)  Bt (D) At 2 
2 2 2
2. C
At 2
Sol.   dt   At  B   Bt
2
3. A particle starts from origin at t = 0 and moves in the x – y plane with a constant acceleration 6
x2
m/s2 in y-direction. The equation of motion is y  , then its velocity component along x-
3
direction at x = 2 is (in m/s)
3
(A) (B) 3 (C) 6 (D) 2
2
3. B
x2
Sol. y
3
dy 2 x  dx 
  
dt 3  dt 
2
d 2 y 2  dx  2 d 2 x
    x
dt 2 3  dt  3 dt 2
2
2  dx  d 2x 
 6    2
 0
3  dt   dt 
4. From the surface of a certain planet a body is projected with a certain velocity at a certain angle
from the horizontal surface. The horizontal and vertical displacements x and y are given by
x  10 3t and y  10t  t 2
where t is the time in second and x and y are in meter. The magnitude and direction of the
velocity of projection are:
(A) 10 ms-1 at 300 from the horizontal (B) 20 ms-1 at 600 from the horizontal
-1 0
(C) 10 ms at 60 from the horizontal (D) 20 ms-1 at 300 from the horizontal
4. D
Sol. s3  10 3t and s y  10t  t 2
u x  u cos , u y  u sin 
1
sx   u cos  t  axt 2  10 3t
2
u cos  10 3m / s 2
1
s y   u sin   t  a y t 2  10t  t 2
2
ay
u sin   10 m / s and  1m / s 2
2
ay  2 m / s 2
2 2
u2  ux 
2
  u y   102  10 3    20m / s
uy 1
tan       300
ux 3
-1
5. From the top of a tower of height 40m, a ball is projected upwards with a speed of 20 ms at an
2
angle of 300 to the horizontal. If g  10ms , after how long will the ball hit the ground?
A 1s B 2s C 3s D 4s
5. D
Sol. The horizontal range R = AC is
2 0
u sin 2 20  20  sin 60
  20 3m
g 10
-1
20ms
B
0
30 C
A
R
20m/s
40m
-1
20ms
Ground
D
At C, the velocity of the ball is again 20 ms-1 directed down as shown in Fig.
The downward vertical component of this velocity is 20sin300 = 10 ms-1. The ball will hit the
ground at D after travelling a vertical distance h = 40 m. If t1 is the time taken for this, then
1
h  ut1  gt
2 1
2
40  10t1  5t1
2
t1  2t1  8  0
The positive root of this quadratic equation is t1  2s . Now, the time of flight from A to C via B is
0
2u sin  2  20   sin 30
t2    2s
g 10
Total time taken = t1  t2  2s  2 s  4s . Hence the correct choice is D
6. A particle is moving in a circle of radius R. At t = 0 its speed is zero and during its motion speed
2
varies as v  2 s where s is the distance travelled. The angle made by acceleration vector with
radial direction after one revolution.
  1 1
(A) (B) (C) tan   (D) 
2 4  
6. C

Sol. dv vdv  v
at    8s 3 a
dt ds
v 2
4s 4 at
ac   
R R
a 8s 3 2R ac
tan   t  4 
ac 4 s / R s
After one revolution s  2 R
1
tan  

7. The displacement x of a particle at any instant is related to its velocity as v  2 x  9. Its

acceleration and initial velocity are:
(A) 1 unit and 3 unit (B) 3 unit and 9 unit (C) 9 unit and 3 unit (D) 2 unit and 9 unit
7. A
Sol. at x = 0
v2  9
initial velocity v = 3 units
dv 1 1/ 2 dx
a   2 x  9  .2
dt 2 dt
a = 1 unit
8. A body is moving down a long inclined plane of angle of inclination  . The coefficient of friction
between the body and the plane varies as   0.5x , where x is the distance moved down the
plane. The body will have the maximum velocity when it has travelled a distance x given by
2 2
A x  2 tan  B x C  2 cot  D x
tan  cot 
8. A
Sol. The acceleration of the body down the plane is
g sin    g cos  g  sin    cos    g  sin   0.5 x cos   . Therefore, the body will first
accelerate up to x < 2 tan  . The velocity will be maximum at x = 2 tan  , because for x > 2 tan  ,
the body starts decelerating. Hence, the correct choice is A
9. F
At the instant t = 0 a force F  kt  k is a constant  acts on a small body of

mass m resting on a smooth horizontal surface. The time, when body leaves
the surface is: m
(A) mgk sin  (B) k sin  / mg (C) mg sin  / k (D)
mg / k sin 
9. D
Sol.
kt sin   mg
mg
t
k sin 
10. If the potential energy of a gas molecule is
M N
U  ,
r 6 r12
M and N being positive constants, then the potential energy at equilibrium must be:
(A) zero (B) M 2 / 4 N (C) N 2 / 4 M (D) MN 2 / 4
10. B
du  6M 12 N 
Sol. F    13  0
dr  r 7 r  r r0
2N
 r06 
M
M2
So, U 0 
4N
11. A body is moving up an inclined plane of angle  with an initial kinetic energy E. The coefficient
of friction between the plane and the body is  . The work done against friction before the body
comes to rest is
 cos  E cos  E cos
A B  E cos C D ’
E cos  sin   cos  sin   cos  sin 
11. D
Sol. The retardation is given by (see fig)
a  g   cos  sin   ...  i 
Let u be the initial velocity of the body. If it is stopped after moving a distance s up the plane, then
2
u  2as
1 2 1
 Kinetic energy = E= mu  m  2as  mas ... ii 
2 2
W  mgs sin  ...  iii 
From (i), we have
a
g ...  iv 
  cos  sin  
sin 
Also   tan   or sin    cos ...  v 
cos
Using (iv) and (v) in (iii), we have
mas   cos 
W
  cos  sin  
Using (ii) in (vi), we get
 E cos
W , which is choice D
  cos   sin  
12. A body P strikes another body Q of mass that is p times that of body P and moving with a velocity
1
that is of the velocity of body P. If body P comes to rest, the coefficient of restitution is
q
pq pq pq pq
A B C D
pq q  p  1 p  q  1 p  q  1
12. D
Sol. Given mQ  pmP and vQ  vP / q. From the principle of conversion of momentum, we have (since
body P comes to rest after collision)
mP vP  mQ vQ  mQ v
Where v is the velocity of body Q after collision. Thus
vP
mP vP  PmP  pmP v
q
v pq
Which gives  ...  i 
vP pq
Now, the coefficient of restitution is given by
v v
e 
vP  vQ vP
vP 
q
v e
Which gives   q  1 ...  ii 
vP q
pq
Equating (i) and (ii), we get e  which is choice D.
p  q  1
13. A solid cylinder is rolling without slipping down an incline of inclination  . Minimum coefficient of
friction so that the cylinder does not slip on the incline is
tan  tan   
(A) tan  (B) (C) (D) tan  
2 3 3
13. C
Sol. For pure rolling on an inclined plane
mg sin 
friction needed = F 
 mR 2 
  1
 I 
Also F  f s /max
mg sin 
  mg cos 
 mR 2 
  1
 I 
14. A circular portion of diameter R is cut out from a uniform Cut out circular
circular disc of mass M and radius R as shown in Fig. The portion
moment of inertia of the remaining (shaded) portion of the
disc about an axis passing through the centre O of the disc
and perpendicular to its plane is R R
15 2 7 2
O
A MR B MR
32 16
13 2 3 2
C MR D MR
32 8
14. C
1 2 M 
Sol. Moment of inertial of complete disc about O is I  MR . Mass of the cut-out part is m   .
2  4 
The moment of inertial of the cut-out portion about its own centre
2
1 2 1  M  R  1 2
I 0  mr      MR because r = R/2. From the parallel axes theorem, the
2 2  4  2  32
moment of inertial of the cut out portion about O is
2
2 1 2  M  R  3 2
I c  I 0  mr  MR      MR
32  4  2  32
1 2 3 2 13 2
 Moment of inertial of the shaded portion about O is I s  I  I c  MR  MR  MR , which
2 32 32
is choice C.
15. The centres of a ring of mass m and a sphere of mass M of m M

equal radius R, are at a distance 8R apart as shown in
Fig The force of attraction between the ring and the sphere R R
is
2 2 GmM GmM A 8 B
A B R
27 R 2 8Rh 2
GmM
C 2
D
9R
2 GmM
9 9R2
15. A
Sol. Let  be the mass per unit length of the ring. L  2 R is C

dx
the length of the ring. Consider a small element of length dx
of the ring located at C. Then, Force along BC is R 3R
GM  dx
f  . Therefore, force along 
 3R 
2
A 8
B
R
GM  dx 8R 8 GM  dx
BA is dF = f cos  2
 2
9R 3R 27 R
8 GM 8 GMm
 Total force = 2 
 dx 
27 R 27 R 2
Because   dx    L  m, the mass of the ring. Hence the
correct choice is A.
16. The magnitude of gravitational force on a particle of mass m placed at a distance x l x

from the rod of mass M and length l as shown in the figure is:
GMm GMm
(A) (B)
l  x2 l l  x
GMm GMm
(C) (D)
l2  x x l  x
16. D
Sol.
l r
m
dr x
M
dm  dr
l
Gmdm GmM 1
dF   dr
r2 l r2
GmM 1 x 1 GmM
F  2 dr 
l x r x l  x 
17. Water from a tap emerges vertically downwards with an initial speed of 1 ms-1. The cross-
sectional area of top is 10-4m2. Assume that the pressure is constant throughout the stream of
water and that the flow is steady. The cross-sectional area of the stream 0.15 m below the top is
(take g = 10ms-2)
4 2 5 2 5 2 5 2
(A) 5  10 m (B) 1 10 m (C) 5  10 m (D) 2  10 m
17. C
Sol. From equation of continuity
a1v1  a2 v2
v1  1ms 1 , a1  10 4 m 2 , v2  velocity of stream at h = 0.15 m below the tap.
v22  v12  2 gh
v22  4
 a2  5  10 5 m 2
18. One end of a thermally insulated rod is kept at a temperature T1 and T1 l1 l2 T2

the other at T2. The rod is composed of two sections of lengths l1 and l2
and thermal conductivities k1 and k2 respectively. The temperature at
the interface of the section is
k1 k2
  
A k1l2T1  k2 l1T2 / k1l1  k 2l2     
B k 2l1T1  k1l2T2 / k2 l1  k1l2
C k l T  k l T  / k l
11 1 2 1 2 1 2
k l 
2 1
D k l T  k l T  / k l  k l 
11 1 2 2 2 11 2 2
18. A
Sol. Let T0 be the temperature at the interface and A be the cross-sectional area of each rod.
T0
T1 A k1 B k2 T2
l1 l2
In the steady state, the rate of flow of heat through rod A = rate of flow of heat through rod B, i.e.
Q1 Q2

t t


k1 A T1  T0   k A T
2 0
 T2 
l1 l2
 
 k1l2 T1  T0  k 2l1 T0  T2 
 T0 
k l T  k l T 
1 2 1 2 1 2
k l  k l 
1 2 2 2
19. A body cools from 50.0 0C to 49.9 0C in 5s. How long will it take to cool from 40.00C to 39.90C?
Assume the temperature of the surroundings to be 30.00C and Newton’s law of cooling to be
valid.
(A) 2.5s (B) 10 s (C) 20 s (D) 5 s
19. B
Sol. Rate of cooling
T1  T2  T  T  
   1 2   Ts 
t  2  
0.1
Case I:    49.95  30 
5
0.1

5  19.95
0.1
Case II.    39.95  30
t
0.1
  9.950 
t
0.1 0.1 9.95
    t  10s
5 5 19.95
20. In the following figures, the block of mass m is slightly k 2k
m
displaced from its mean position.
The ratio of time periods of oscillations in Fig(i) and Fig(ii)
(i)
is:
(A) 1 : 2 (B) 2 : 3 k 2k
m
(C) 3 : 2 (D) 1 : 1
(ii)
20. C
Sol. In first case
K .2 K 2K
Keff = 
K  2K 3
In second case
Keff K 2  K  2 K  3K
m
T  2
K
T1 3

T2 2
21. Third overtone of a closed organ pipe is in unison with fourth harmonic of an open organ pipe.
Find the ratio of lengths of the pipes:
(A) 1 : 2 (B) 3 : 4 (C) 5 : 6 (D) 7 : 8
Ans. D
7
21. lc  
4
4l
 c
7
7v
f7 
4lc
For open pipe
4v
f4 
2lo
 F7  closed = f  4  open
lc 14 7
 
lo 16 8
22. Two point charges q1 and q2 (q1/2) are placed at points A(0, 1) and y
B(1,0) as shown in the figure. The electric field vector at point P(1,1)
makes an angle  with the x-axis, then the angle  is: A
P 1,1
1
1 1
1
q1* *
(A) tan   (B) tan  
2 4
1 1
(C) tan 1 (D) tan  0 
B
x
O *
q2
22. A
Sol.
y
EB

EA
P
x
O q1 / 2
q1 q/2
EA  , EB 
4 0 4 0
E 1
tan   B 
EA 2
1
  tan 1  
2
l
23. Three point charges 4q , Q and q are placed in straight line of length l at points distant 0, , l
2
respectively. If the net force on charge q is zero, the magnitude of the force on charge 4q is
q2 2q 2 3q 2 4q 2
(A) (B) (C) (D)
 0l 2  0l 2  0l 2  0l 2
23. C
Sol. For net force on charge q to be zero, Q 

4q Q q
k  4q  q k Q q
negative  2 l
l2 l 0 l
2 2
 
 Q q
Q  q
k  4q  q k  4q  q
Net force on 4q charge = 2

l / 2 l2
k 4a 2
  4  1
l2
3q 2
F
 0l 2
24. The capacitance of a sphere of radius R1 is increased 3 times when it enclosed by an earthed
sphere of radius R2. The ratio R2/R1 is
3 4
A 2 B C D 3
2 3
24. B
Sol. C1  4 0 R1 , C2 

4 0 R1 R2 
R 2
 R1
4  R R 
0 1 2
Given C2  3C1 Hence  3  4 R
R  R 
2 1
0 1
R2 3
Which given  , Which is choice B
R1 2
25. The network shown in the following figure is part of a circuit. What is the I 1 15V 5H
potential difference VB  VA  . When current I is 5A and is decreasing A
at a rate of 10 3 A / s ?
(A) 5 V (B) 10 V
(C) 15 V (D) zero
25. B
nd
Sol. Kirchhoff’s 2 law
di
V A  VB = Ri  E  L
dt
 di 

1 5  15  5  103  103    10 A / s 
 dt
3

V A  VB  10V
VB  VA  10V
26. A particle of mass m and charge q moves with a constant velocity v along the positive x direction.
It enters a region containing a uniform magnetic field B directed along the negative z direction,
extending from x  a to x  b . The minimum value of v required so that the particle can just
enter the region x > b is
A qbB / m B q b  a  B / m C qaB / m D q  b  a  B / 2m
26. B
Sol. The radius r of the circular path is given by
(see Fig.)
y
B
x x x x
x x x x
x x x x
x x x x
x x x x
x x x x
x x x x
x x x x
x x x x
x
v xa xb
2
mv qB
 qvB or v  r 
r m
qB qB
 vmin  r
m min

m
 
 b  a  , which is choice B.
27.
 Loop
A square loop is placed in a uniform magnetic field B x x x x
as shown in figure. The power needed to pull it out of
the field with a constant velocity v is proportional to x x x x
1/ 2
(A) v (B) v v
x  x x x
2 3/ 2
(C) v (D) v B
x x x x
27. C
Sol. Induced emf   Blv
Blv
I
R
B 2 L2 v
Fmag  BIL 
R
Fext  Fmax
B 2 L2 v 2
Power = Fv 
R
28. An observer can see through a pin-hole the top end of a thin rod of height h,
placed as shown in the figure. The beaker height is 3h and its radius h. when
the beaker is filled with a liquid up to a height 2h, he can see the lower end of
the rod. Then the refractive index of the liquid is:
3h
5 5 3 3 2h
A B C D h
2 2 2 2
2h
28. B
Sol. When beaker is filled upto a height 2h, the bottom Q of A

B
the rod will be visible if the ray QD travelling in the liquid
refracts along DB in air. It follows from Fig. that D is the
Air
mid-point of diagonal PB of square ABPR. Hence DE = 450
D
0 0 F
PQ = h. Also BDF  45 since DPE  45 . From 3h
Snell’s law, we have (since the object is in a denser i Liquid
medium) 0
45 2h
P R
1 sin i QG / QD h / 5h 2 5 E
  0
  or   , which h
 sin r sin 45 1/ 2 5 2
is choice B.
Q G C
2h
29. A U shaped wire is placed in front of a concave mirror of radius of A D
curvature 20 cm as shown in the figure. The total length of the image
of the wire ABCD is nearly: 5cm
(A) 2.5 cm (B) 6 cm C
B
(C) 12.5 cm (D) 15 cm 30 cm
10cm
29. B
Sol. Focal length of concave mirror
R
f   10 cm
2
For the left arm(AB) of the U-tube
u1  40 cm
1 1 1
 
f v u
1 1 1
  
10 v1 40
40
v1   cm
3
For the right arm CD of the U-tube
u 2  30 cm
1 1 1
   cm
10 v2 30
v2  15 cm
Magnification for AB side
A ' B ' v1 40 / 3 1
  
AB u1 40 3
AB 5
A'B'   cm
3 3
Also For CD side
C ' D ' v2 15 1
  
CD u2 30 2
5
C ' D '  cm
2
Total length
A ' B ' B ' C ' C ' D '
5  40  5
  15   
3  3  2
= 6 cm
30. Interference pattern is obtained with two coherent light sources of intensity ratio n. In the
I max  I min
interference pattern, the ratio will be
I max  I min
n 2 n n 2 n
(A) (B) (C) 2
(D) 2
 n  1  n  1  n 1   n 1 
30. D
I1
Sol. Given  n. Therefore, the amplitude ratio is
I2
A1
 n
A2
2 2
Now I max  A1  A2   
and I min  A1  A2 
2
 A1 
2   1 2

I max

A  A 
1 2
 2
A  =  n 1 
2 2 2
I min A  A 
1 2
 A1 
  1
 n  1
 A2 
Hence the correct choice is D
1. For a hypothetical reaction
1  AB3 g  ; H   x kJ
AB2 g   B2 g  
2
More AB3 could be produced by
(A) using a catalyst (B) removing some of B2
(C) increasing the temperature (D) increasing the pressure
1. D
Sol. On increasing the pressure, equilibrium shifts towards lesser number of gaseous moles

2. The pK b of CN is 4.7. The pH of solution prepared by mixing 2.5 mole of KCN and 2.5 moles
of HCN in water and making the total volume upto 500 ml, is
(A) 10.3 (B) 9.3 (C) 4.7 (D)8.3
2. B
Sol. If forms basic buffer
 2.5 / 500 
pOH  pK b  log  
 2.5 / 500 
= 4.7
pH = 14 – 4.7 = 9.3
3. The pH of a solution of weak base at half neutralization with strong base is 8, K b for base is
4 6 8 7
(A) 1 10 (B) 1 10 (C) 1 10 (D) 1 10
3. B
Sol.

  
At half equi. point,  B   BOH ; Salt  Base   
pOH  pK b  log
 Salt 
 Base
pOH  pK b  6
pK b  6, K b  1 106
4. HBr and HI reduce sulphuric acid, HCl can reduce KMnO4 and HF can reduce
(A) H2SO4 (B) KMnO4 (C) K2Cr2O7 (D) None of these
4. D
Sol. HF does not behave as a reducing agent. Therefore, it cannot be oxidized by any of these
5. The correct IUPAC name of the compound given below is:

CH3
H3C
CH3
CH3
(A) 4-Ethyl-3-methyloctane (B) 3-Methyl-4-ethyloctane
(C) 2, 3-Dimethylheptane (D) 5-Ethyl-6-methyloctance.
5. A
Sol. Substituents must be written in alphabetical order.
6. The transition metal ion with least magnetic moment has the electronic configuration
(A) 3d 4 (B) 3d 9 (C) 3d 2 (D) 3d 8
6. B
Sol. 3d 9 configuration has only 1 unpaired electron.
So magnetic moment is least.
7. Potassium ferricyanide on ionization produces

(A) 2 ions (B) 1 ions (C) 5 ions (D) 4 ions
7. D
3
Sol. K3  Fe  CN 6   3K    Fe  CN  6  . Total 4 ions
8. Arrange the following free radicals in order of stability: Benzyl (I), Allyl (II), Methyl (III), Vinyl (IV)
(A) IV > III > II > I (B) I > II > III > IV (C) I > III > IV > II (D) IV > III > I > II
8. B
Sol. Benzyl CH2

is most stable due to greater number of resonating
radical
structures.
 
Allyl radical  C H 2  CH  CH 2  is less stable than benzyl due to lesser no. of resonating
 
structures. Vinyl radical is least stable of these because of sp hybridization .
9. A hydrocarbon ‘A’ with molecular mass 84 gives a single monochloride but four dichlorides on
photochemical chlorination. The hydrocarbon ‘A’ is
(A) Cyclopentane (B) Cyclohexane
(C) 2, 3-Dimethylbutane (D) Methyl cyclopentane
9. B
Sol.
Cl Cl Cl
Cl Cl Cl
Cl2 , hv
Cl
Cl2 , hv
    + + +
Cl
Cl
10. What would be the expected formula of a compound which is formed of element X containing 2
electrons in the valence shell and element Y contains 7 electrons in the valence shell?
(A) X2Y (B) XY2 (C) XY (D) X2Y2
10. B
Sol. X belongs to group 2 and Y belongs to Group 17
11. If one million atoms of silver weight 1.79  10 16 g , the gram atomic mass of silver is
(A) 107 g (B) 107.2 g (C) 107.8 g (D) 108.2 g
11. C
6
Sol. 1 million i.e. 10 atoms of Ag have mass = 1.79 1016 g
1.79  1016  6.023  1023
 6.023  10 23 atoms of Ag have mass =
106
 107.8g (gram atomic mass)
12. H2O2 can act as reducing as well as oxidising agent. In its reaction with NH2OH and KIO4, H2O2 is
acting as
(A) Oxidising agent, reducing agent (B) Reducing agent, oxidising agent
(C) Oxidising agent, oxidising agent (D) Reducing agent, reducing agent
12. A
1 5
Sol. N H 2OH  3H 2O2 
 H N O3  4 H 2O
oxidising agent
7 5
K I O4  H 2 O2 
 K I O3  H 2O  O2
reducing agent
13. The blue colour developed when Lassaigne’s extract is heated with fresh FeSO4 in presence of
alkali, cooled and acidified with dil. H2SO4 indicates…. and is due to the formation of…
(A) N , Fe4  Fe  CN 6  (B) N , Na4  Fe  CN 6 
3
(C) S , Na4  Fe  CN 5 NOS  (D) N  S , Fe  CNS 3

13 A
Sol. Blue colour in Lassaigne’s test indicates nitrogen and is due to the formation of Prussian blue i.e.,
Fe4  Fe  CN 6  .
3
8a
14. If the critical temperature of the gas be TC  and TB is the Boyle’s temperature, then which
27 Rb
of the following, is the correct relation between TC and TB?
4 27 8 27
(A) TC  TB (B) TC  TB (C) TC  TB (D) TC  TB
27 4 27 8
14. C
a 8a
Sol.  TB  and TC 
Rb 27 Rb
T 8
 C 
TB 27
15. The composition of a sample of wustite is Fe0.93O. What is the percentage of iron present as
Fe 3 ?
(A) 15% (B) 25% (C) 35% (D) 45%
15. A
Sol. Let, no. of O-2 ions in Fe0.93O  100
 Total no. of Fe 2  and Fe3 ions = 93
Let no. of Fe 2 ions in the sample = x and No. of Fe3 ions in the sample = y
 x  y  93 …(i)
Total –ve charge carried by 100 O-2 ions = 200
Total +ve charge carried by xFe 2  ions = 2x
Total charge carried by yFe 3 ions = 3y
Thus 2 x  3 y  200 …(ii)
Solving (i) and (ii), we get x = 79 and y = 14
 No. of Fe2+ ions, x = 79, and
 No. of Fe3+ ions, y = 14
 % of iron present as Fe(III)
14
  100  15.05%
79  14
16. The uncertainty in the position of a dust particle with mass equal to 1 mg (if uncertainty in its
velocity is 5.5 1020 ms 1 ) is:
o o
(A) 9.58 A (B) 958 A (C) 9.58 nm (D) None.
16. A
Sol. According to uncertainty principle,
h h
x.mv  or x 
4 4mv
v  5.5 1020 ms 1 , m  1mg  106 kg
  3.143; h  6.626 10 34 kgm 2 s 1 .
x 
 6.626  10 kgm s 
34 2 1
4  3.143  10 kg    5.5  10

6  20
ms 1 
o
 9.58  10 10 m  9.58 A.
17. Which of the following has highest bond dissociation energy?

(A) O2 (B) O2 (C) O2 (D) O22
17. B
Sol. O2 has higher bond order and highest bond dissociation energy.
Species Bond order

O2 2.0
O2 2.5
O2 1.5
O 2
2
1.0
54 56 57
18. Given, that the abundance of isotopes Fe, Fe and Fe are 5%, 90% and 5% respectively,
the atomic mass of Fe is
(A) 55.85 (B) 55.95 (C) 55.75 (D) 55.05
18. B
Sol. Av. atomic mass =

 54  5    56  90    5  57 
100
270  5040  285
  55.95
100
19. The volume strength of 1.5 N H2O2 solution is
(A) 4.8 (B) 8.4 (C) 3 (D) 8
19. B
Sol. volume strength = 5.6 N
= 5.6  1.5
 8.4
20. Which of the following has the maximum number of atoms?
(A) 24 g of C(12) (B) 56 g of Fe(56) (C) 27 g of Al(27) (D) 108 g of Ag(108)
20. A
Sol. No. of atoms of:
24
(i) N C   N AV  2 N AV
12
56
(ii) N Fe   N AV  N AV
56
27
(iii) N Al   N AV  N AV
27
108
(iv) N Ag   N AV  N AV
108
21. An aqueous solution of 6.3 g oxalic acid dihydrate (H2C2O4.2H2O) is made upto 250 ml. The
volume of 0.1 N NaOH required to completely neutralize 10 ml of this solution is
(A) 40 ml (B) 10 ml (C) 20 ml (D) 4ml
21. A
6.3
Sol. M oxalic acid dihydrate   0.2
126  250  103
neq NaOH  neq oxalic acid dihydrate
0.1 VNaOH  0.2  2  10  103
VNaOH  0.04l  40ml
22. In the standardization of Na2S2O3 using K 2Cr2O7 by iodometry, the equivalent weight of
K 2Cr2O7 is:
molecular weight molecular weight
(A) (B)
2 6
molecular weight molecular weight
(C) (D)
3 1
22. B
Sol. I   K 2Cr2O7  I 2  Cr 3
I 2  Na2 S2 O3  I   Na2 S4 O6
molecular weight
E.wt K 2Cr2 O7 
6
 12 3
as, 6e   Cr2   2Cr
23. What volume of CO2 at STP will evolve when 1 gm of CaCO3 reacts with excess of dil HCl?
(A) 224 ml (B) 112 ml (C) 58 ml (D) 448 ml
23. A
Sol.  100 gm CaCO3 gives 22,400 ml CO2
 1 gm CaCO3 will give 224 ml CO2
24. The vapour pressure of benzene at 280 K is 40 mbar. When urea is mixed at the same
temperature, the vapour pressure falls by 8 mbar. The mole fraction of benzene in the solution is
(A) 0.20 (B) 0.25 (C) 0.70 (D) 0.80
24. D
Sol. Vapour pressure of the solution = 40 mbar – 8 mbar = 32 mbar
o
P  Pbenzene  benzene
32 mbar = 40 mbar × benzene
benzene = 0.8
3
25. Ammonia gas is passed into water, yielding a solution of density 0.93 g/cm and containing
18.6% NH3 by weight. The mass of NH3 per cc of the solution is
(A) 0.17 g/cm3 (B) 0.34 g/cm3 (C) 0.51 g/cm3 (D) 0.68 g/cm3
25. A
18.6
wt. of NH3 =  wt. of 1 cm3 solution
100
18.6
  0.93
100
 0.17 gm
26. A sample of NaHCO3 + Na2CO3 required 20 ml of HCl using phenolphthalein as indicator and 35
ml more is required if methyl orange is used as indicator. Then molar ratio of NaHCO3 to Na2CO3
is
1 2 3 1
(A) (B) (C) (D)
2 3 4 3
26. C
meq. of Na2 CO3  w.r.t n. f .  2 
Sol.  meq. of HCl  for phenolphthalein 
2
meq of Na2CO3  w.r.t. n. f .  2 
meq. of NaHCO3   meq. of HCl  for methyl orange 
2
CH3
Br H
acetone
27.  NaI   Product. The product of the reaction is:
H CH3
C2H5
CH3 CH3 CH3 CH3

I H H I I CH3 I H
(A) (B) (C) (D)
H CH3 H CH3 H CH3 H3C H
C2H5 C2H5 C2H5 C2H5
27. B
Sol. The given reaction is Finkelstein reaction. It involves S N 2 reaction with the inversion of the
configuration.
28. Rank the following in order of decreasing rate of solvolysis with aq. ethanol.
H3C Br
CH3
H2C C Br H3C CH CH2CHMe2
Br
(1) (2) (3)
(A) 2 > 1 > 3 (B) 1 > 2 > 3 (C) 2 > 3 > 1 (D) 1 > 3 > 2
28. C
Sol. Solvolysis with aq. ethanol involves S N 1 reaction. More stable is the carbocation, greater is the
rate of S N 1 reaction.
29. In each of the following groups, which is the strongest nucleophile?

 O 
(I) In MeOH (1) CH O 3 (2) (3) Me  S
 
(II) In DMF (1) OH (2) H 2O (3) O  O  H
(A) I, 3; II, 2 (B) I, 2; II, 1 (C) I, 1; II, 2 (D) I, 3; II, 3
29. D

Sol. In MeOH solvation of anions occurs, hence MeS is least solvated and is the best nucleophile.
Since in DMF, no solvation of anion occurs and greater are the LP of electrons near the
nucleophilic site, better is the nucleophilicity.
30. Which of the following statement is correct regarding the rate of hydrolysis of the compounds (x)
and (y) by S N 1 reaction?
Br O Br
(x) (y)
(A) x reacts faster than y (B) y reacts faster than x
(C) Both x and y reacts at the same rate (D) Neither x nor y reacts
30. B
Sol. O is highly stabilized (Aromatic)
pace for rough work

2   1
x
1. Range of function f  x  is [ Where {x} represent fractional part of x]
2x  1
1 1
(A) [-2, 3] (B) [0, 1/3) (C)  ,  (D)  1 3 ,1
3 2
1. B
Sol.
0  {x}  1
 20  1 21  1   1
So  0
 2  1
, 1   0,
2 1   3 
2. If 00< x < 900, cos x = 3 , then value of log10 sin x + log10 cos x + log10 tan x is
10
(A) 0 (B) 1 (C) -1 (D) None of these
2. C
Sol.
3
cos x 
10
 9 1
 log10 sin 2 x  log10  1    log10  1
 10  10
 (2 x  1) 
3. The function f(x)=[x] cos   (Where [x] denotes the greatest integer function) is
 2 
discontinuous.
(A) at all x (B) at all integer points
(C) at no x (D) at x which is not integer
3. C
n
Sol. [x] is discontinuous at every integer but f (x) is continuous because cos is continuous, n I
2
4. Suppose a, b, c are in A.P and a2, b2, c2 are in G.P. If a < b < c and a + b + c = 3/2 , then value of
a is
1 1 1 1 1 1
(A) (B) (C)  (D) 
2 2 2 3 2 3 2 2
4. D
Sol. A < b < c, 2b = a + c, b2 = ac, a+b+c= 3
2
1
b  1 , 1 – a = c , = a (1-a)
2 4
1 1
a= 
2 2
5. If tan x tan y = a and x + y =  then tan x and tan y satisfy the equation,
6
2
(A) x  3 (1  a ) x  a  0 (B) 3 x 2  (1  a ) x  a 3  0
2
(C) x  3 (1  a) x  a  0 (D) 3 x 2  (1  a) x  a 3  0
5. B
Sol.
1
tan ( x  y ) 
3
Product of roots = tan x. tan y = a 3 (tan x  tan y ) 1  a
1 a

3
X2- (sum of roots) x + product of roots = 0
x f ( P)
6. Let f ( x ) = then is equal to
x 1 f ( P  1)
 P  1
(A) f (P 2 ) (B) f    (C) f   (D) f  P 
 P 1  P
6. A
x f ( P) P2
Sol. f ( x)  ,  2  f (P2 )
x  1 f ( P  1) P 1
7. The points (x1, y1), (x2, y2) , (x1, y2) and (x2 , y1) are always
(A) Vertices of a rhombus (B) Vertices of a square
(C) Con-cyclic (D) Collinear
7. C
Sol.
D C ABCD Diagonal always intersect at 900
y2 So ABCD is con-cyclic.
Y1 A B
X1 X2
8. A closet has 5 pair of shoes. The number of ways in which 4 shoes can be drawn such that there
will be no complete pair is
(A) 80 (B) 160 (C) 200 (D) 240
8. A
5 2 2 2 2
Sol. Total number of selection = C4  C1  C1  C1  C1
= 80
dy x 2  y 2
9. Solution of the differential equation  is
dx 2 xy
(A) k (x2 + y2) = x (B) k (x2 – y2) + x = 0 (C) k (x2 – y2) = x (D) k (x2 + y2) + x = 0
9. C
Sol. Put y = v x
10. The complex number z =1 + i is rotated through an angle 3 / 2 in anticlockwise direction about
the origin and stretched by additional 2 unit, then the new complex number is
(A)  2  2 i (B) 2 2 i (C) 2  2 i (D) None of these
10. D
z1 z i 3
Sol.  1 e 2
z z
11. If z  4, then iz  3  4i is less than
(A) 4 (B) 5 (C) 6 (D) 9

11. D
Sol. iz  (3  4i )  iz  3  4i  z  5  4  5  9.
12. If 4a + 2b + c = 0, then the equation 3ax 2 + 2bx + c = 0 has at least one real root lying between
(A) 0 and 1 (B) 1 and 2 (C) 0 and 2 (D) none of these
12. C
Sol. f(x) = ax3+ bx2+ cx
f(0) = 0, f(2) = 8a + 4b + 2c = 2 (0) = 0
At least one c  (0, 2) , such that f ‘ (c) = 0
2/ 3
13.  sec x cos ec 4 / 3 xdx is equal to
1/ 3 1 / 3 1 / 3 1 / 3
(A) 3  tan x  (B) 3  cot x  (C) 3  tan x  (D) 3  cot x 
13. C
dx sec 2 x
Sol.  cos2 / 3 x sin4 / 3 x   tan 4 / 3 x dx
Put tan x  t
100
14. The value of   x  dx (where {x} is the fractional part of x) is
0
14. D
Sol. { x }  x  [ x ], [.]  G.I .F put x = t2
100
2000 1 2 10


0
x   x  dx 
3

 2   0.dx0   1.dx  ........   9.dx 
0 1 9 
2
x cos x ex  /2
15. If f ( x)  sin x x2 sec x then the value of  f ( x) dx is equal to
  /2
tan x 1 2
15. A

2
Sol. f(x) is odd function so  f ( x)  0

2
16. The lines p(p2 +1)x – y + q = 0 and (p2 + 1)2 x + (p2 + 1) y + 2q = 0 are perpendicular to a
common line for
(A) No value of p (B) Exactly one value of p
(C) Exactly two values of p (D) More than two values of p
16. B
Sol. Lines must be parallel , m1 = m2
17. Tangents to the circle x 2 + y2 = a2 cut the circle x2 + y2 = 2a2 at P and Q. The tangents at P and Q
2 2 2
to the circle x + y = 2a intersect at angle  , then  is equal to
   
(A) (B) (C) (D)
4 6 3 2
17. D
Sol. PQ is chord of contact of circle of x 2 + y2 = 2a2
w.r. to point A (n, k) , A is intersection point of circle which lies on director circle to x 2 + y2 = 2a2.
2
18. The length of the latus rectum of parabola 4y + 2x – 20y + 17 = 0 is
(A) 3 (B) 6 (C) ½ (D) 0
18. C
2 1
Sol.  y  5 2 
2
 x  4
19. S and T are the foci of an ellipse and B is an end of the minor axis. If STB is an equilateral
triangle, then the eccentricity of the ellipse is.
(A) 1/4 (B) 1/3 (C) 1/2 (D) 2/3
19. C
2 2
Sol. SB = ST
x2 y2
20. The tangent at any point P on the hyperbola   1 meets the straight lines bx – ay = 0 and
a 2 b2
bx + ay = 0 in the points Q and R respectively. If C is the centre of the hyperbola, then CQ.CR is
2 2 2 2 a
(A) a – b (B) a + b (C) ab (D)
b
20. B
 a b 
Q  , 
 sec   tan  sec   tan  
Sol. Point  a b 
R  , 
 sec   tan  sec   tan  
x3 y4 z 5
21. The number of points common to the line   and the plane 4x – 2y – z =1 is
2 3 2
(A) 0 (B) 1 (C) infinite (D) none of these
21. A
Sol. Given line is parallel to the plane 4x  2y  z  1
22.    
If 4a  5b  9c  0, then (a  b)   b  c  c  a  is equal to
 
(A) A vector perpendicular to plane of a , b and c
(B) A scalar quantity

(C) 0
(D) None of these
22. C
   
Sol. b  c and c  a are collinear
0
  0
23. A unit vector in xy-plane which makes an angle of 45 with the vector i  j and an angle of 60
 
with the vector 3i  4 j is
   
 i j i j
(A) i (B) (C) (D) None of these
2 2
23. D
 ^ ^
Sol. Let r  a i  b j , a 2  b2  1
24. If x + y = a + b, x 2+ y2 = a2 + b2, then xn + yn = an + bn is true for

(A) n N (B) n  4 (C) n  3 (D) None of these
24. A
Sol. Check for any 3 Natural No. 5
2 3
25. If 1 + sin x  sin x  sin x  .........  4  2 3, 0  x   , x   / 2, then
  2 2 5 5
(A) x  (B) x  , (C) x  , (D) x 
6 3 3 3 6 6
25. B
1
Sol.  4 2 3
1  sin x
sin x   3
2

1  1 
26. The value of  tan  2 
is equal to
r0  1 r  r 
(A)  /2 (B)  /4 (C)  (D) 0
26. A
 
 1 
Sol.  tan 1 
1  r  r 2 
   tan 1
(r  1)  tan 1 r 
r 0   r 0
27. The centre and radius of the circle z z  (1  i) z  (1  i) z  7  0 is

(A) - 1 – i , 3 (B) 1 + i , 3 (C) 2 – i, 4 (D) 2 + i , 4
27. A
Sol. It represents a circle with centre - 1 – i.
28. If x 1 and y 1, then the sum to infinity of the series

(x + y) + (x 2 + xy + y2) + (x3 + x2y + xy2 + y3) + ………… to  is
( x  y  xy ) ( x  y  xy ) ( x  y  xy )
(A) (B) (C) (D) infinite
(1  x) (1  y ) (1  x) (1  y ) (1  x) (1  y )
28. A
Sol. (x + y) + (x 2 + xy + y2) + (x3 + x2y + xy2 + y3) + ………… to 
1  2
( x  y)   x  y 2   ( x 3  y 3 )  ( x 4  y 4 )  .............. 
29. If the roots of the equation bx2 + cx + a = 0 be imaginary, then for all real values of x, the
expression 3b2x2 + 6bcx + 2c2 is
(A) Greater than 4ab (B) Less than 4ab (C) Greater than – 4ab (D) Less than – 4ab
29. C
Sol. c2 - 4ab < 0
1 x
30. The coefficient of x 98 in the expansion of if x  1
1 x
(A) 1 (B) 2 (C) -1 (D) 0
30. B
1x
 1  2 x  2 x 2  2 x 3  ............
Sol. 1x
coeff . of x 98  2

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JEE Main

3. The test is of 3 hours duration.

Name of the Candidate (in Capital Letters) :_____________________________________

Enrolment Number :_________________________________________________________

Batch :________________________ Date of Examination : ________________________

Useful Data Chemistry:

Acceleration due to gravity g = 10 m / s2

5. A system is shown in figure pulleys and strings are ideal system

a1  acceleration of 2 kg, a2 = acceleration of 3 kg

Sol. With respect to belt

8. Consider the disc kept on a rough horizontal surface as F

(A) R (B) R/3

9. Moment of inertia of a half shell of mass ‘M’ about an

In absence of any friction

11. A small ball starts rolling on an inclined track which

Sol. Let the distance moved by plank be x.

18. A thermodynamic system undergoes a cyclic

21. Two charges +q and q are placed fixed on the corner of a +q q

23. In the shown network current through 20  resistor equals 10 V 20 V

28. In photoelectric effect, the photo current

space for rough work

2. Which of the following can behave as both electrophile and nucleophile?

3. Steam reacts with iron at high temperature as follows:

4. In which of the following solvents, AgBr has the maximum solubility?

6. The strongest reducing agent among the following is

7. Diazonium salt decomposes as:

12. The normality of 0.3 M phosphorus acid  H 3 PO3  is

(A) (B) (C) (D) No reaction

18. NaOEt Major product of the reaction is:

CH3 CH3 CH3 CH3

(A) (B) (C) (D)

(A) (B) (C) (D)

(A) O (B) Ph (C) O (D) OH

(A) O (B) O (C) CH 2  O (D) O

H3C C H CH3CH2 C CH3 CH2 CH2

CH3 CH2 C CH3  EtMgI 

H3C C CH2 CH2

HC CH2 CH2 CH2 CH2 Cl

HC CH2 CH2 CH2

pace for rough work

Section – III (Mathematics)

7. Let f  x   x3  ax 2  bx  5sin 2 x be an increasing function in the set of real number R. Then

(A) a 2  3b  15  0 (B) a 2  3b  15  0 (C) a 2  3b  15  0 (D) a  0 and b  0

11. If 2 x  6 y  2 touches the hyperbola x 2  2 y 2  4 , then the point of contact is

Sol. y = |sin–1 (2x2 – 1)|

Sol. P1 = c sin B, P2 = a sin C, P3 = b sin A

(D) f ''  x  exists for all x

3. The test is of 3 hours duration.

Name of the Candidate (in Capital Letters) :_____________________________________

Enrolment Number :_________________________________________________________

Batch :________________________ Date of Examination : ________________________

Useful Data Chemistry:

Acceleration due to gravity g = 10 m / s2

(A) gtan (B) g (C) gcosec (D) g /tan .

(A) 10 mV (B) 0.1 V (C) 1.0 V (D) 10 V

(A) Electric Field is zero (B) Potential is maximum

space for rough work

5. Which one of the following transition metal ions is diamagnetic?

6. Which of the following is expected not to exist?

7. The hydrogen bond is strongest in

9. Which is the correct order for the graph below? P1

10. Which is the incorrect graph?

Batch : Date of Examination :

Batch : Date of Examination :

Batch : Date of Examination :