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MATERIAL SAFETY DATA SHEET IDENTITY: #4101 Natura Ie Supel DEoR SASSER SECTION I Manufacturer Name: Emergency Telephone Number Arrow Chemical Corp. Infotrac 1-800-535-5053 28 Rider Place. Telephone For Information Freeport NY 11520 516-377-7770 Date Prepared July 2014 Prepared By: Staff "SECTION Il - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION OTHER PERCENT Hazardous Components OSHA PEL ACGIH TLV UMITS OPTIONAL, d-Limonene NA CAS# 5989-27-5 Methyl Ester, soybean oil NA NA NA CAS# 67784-80-9 *Nonylphenol ethoxylate CAS# 9016-45-9 NA NA 10 “*Nonyiphenol Ethoxylate contains traces of Residual Ethylene Oxide which are subject to SARA 302/304. Glycol ethers are subject to SARA Section 311, listed on California Prop 65 and subject to Right To Know laws in Pennsylvania. Health Rating .... 4 Flammability 2 Reactivity .. DOT Shipping Classification: Not hazardous when shipped domestically in containers < 110 gallons SECTION Ill - PHYSICAL / CHEMICAL CHARACTERISTICS Boiling Point: . 100 deg. C 212 degF. Specific Gravity.(H20=1) <1 Vapor Pressure(mm Hg)....NA Melting Point.........: NA Vapor Density (air=1). Evaporation 21 Solubility in water...... Miscible (Butyl Acetate= Appearance and Odor: Pale Yellow/orange Liquid, Citrus scent SECTION IV - FIRE AND EXPLOSION HAZARD Flash Point (Method Used): 125 deg. F_ Flammabie Limits: a SUE Extinguishing Media: Dry chemical, foam or carbon tetrachloride Special Fire Fighting Procedures: Closed containers exposed to heat, but not burning, could be suitably cooled with water. Unusual Fire and Explosion Hazards: Keep away from heat and open flame. SECTION V #4101 pg.2 Stability Unstable | | Stable|X| Conditions to Avoid: None Incompatibility (materials to avoid): Strong oxidizing materials Hazardous Decomposition or Byproducts: When heated to decomposition, d-Limonene emits acrid smoke, fumes, CO and CO2. Hazardous polymerization May occur || Will not occur [X| Conditions to Avoid: Exposure to flames, excessive heat. May reacts violently with iodine pentafluoride in tetrafluoroethylene. SECTION VI - Health Hazard Data Route(s) of entry Inhalation? Yes Skin? Yes Ingestion? Yes Health Hazards(Acute and Chronic): May be mild irritant to skin, eyes, throat and respiratory passages. Carcinogenicity: | NTP? NO (ARC Monographs)? NO OSHA Regulated? NO Medical Conditions Generally Aggravated by Exposure: None known Emergency and First Aid Procedures: Skin-wash off with water. Eyes - Flush with water and see physician. Inhalation - Remove person to fresh air and see physician if necessary. Ingestion - obtain physician. SECTION VII - Precautions for Safe Handling and Use Steps to Be Taken in Case Material is Releasec.or Spilled: Small spills - Wipe up with paper rags. Place them in metal waste container. Large spills - Pick up with absorbant. Waste Disposal Method: According to federal, state and local regulations only. Precautions For Storing and Handling: Store away from heat and open flames. Other Precautions: None Respiratory Protection (Specify Type): Not normally required but if in a confined area use a NIOSH approved respirator. Ventilation | Local Exhaust:Yes Speci | Mechanical :Yes Other: No Protective Gloves: Solvent Resistant gloves Eye Protection: Safety glasses or face shield Other Protective Clothing or Equipment: Eye wash facilities should be available. Work Hygienic Practices: Wash thoroughly after handling. HOJA DE DATOS DE SEGURIDAD DE MATERIALES ‘SE ACATA A LAS NORMAS DE COMUNICACION DE PELIGRO DE LA OSHA (29 CFR 1910.1200) 'SECCION I- IDENTIFICACION DEL PRODUCTO ombre det Producto: Oeagrasador Industrial Fuerte, Eapomosa, CLASH. tls (Sogn Cone on Ascooo Nimar det Produ sro Prepaodo ot zma07 ‘Ohinina’ tiger. "sales “pe do Producer ‘AEROSOL SGrave astro. Forma: 22 Popa Nombre de Sepia: Teand net, he “Tel. normacé: (95) 974.540 Dreosin del Suro, #0. Hox 657770, Pompano Beach, FL29068 Tel Emargentas (0M) 9900009, Desatpcén pera DOT: PRODUCT DE CONSUMO, OFNLD. aa SECCION Il: INGREDENTES ‘NowpRe auitaco oss ‘ses Muauin Pet Garcinggene ek 8 ‘Tespeno Cites ‘soar 2-2 NON NO" we UWE ter Moncetic de Distlonogot 144000 420 SND No NE 23 pom Detaatanina 1102 io x 3 No. Seem oe ppm (Soe aude de Peo cureece 10-29 "ow NO 00D gpm 1000 9pm SECCION i -DATOS Fisicos Punto do Coun: 22°F 1000) contact RO-NBTORELIC) 0 pe 103 Sonia En Au Compote AspectlOor omabincater act, Denied do Vopare=t * % Tota vor: so20% resin de Vapor fats on @TFI222C 55 pig 'SECCION IV- DATOS DE FUEGO Y EXPLOSION eorutanscn cit 1257) ears SaginPuta Fang de tnCSUA} spay No inasbla loos de Extn rm C22 Onin Same Prosdinenis Especits do Extn: Usar equipo anon de respira y ropa potter, Ena a conteaedres expos ego para ear omaha. Petros inumnios do Fusgoy Exploin: La exposson a tomperausssipenors 3 120" (88°C) puede caurar erleion SECCION V -DATOS DE REACTIMIDAD staat str esa PaimerensonPegoak Moar ‘ncanpataad: Eve al contacto con agentes aidan Rees Produtos de Dessorpasisin Ptgrocos: Ohad do Carton, Monéso do Caton 'SECCION VI- ALMACENAMIENTO Y MANESO LMAWTENER FUERA DEL ALCANCE 0€ LOS NIROS. ‘Cédigo NFPA Clas 200: Nie 1 Rerosot, Para uo nist eines amon. ‘Genser er untae feecay sce, lejos del ory dt ego. ‘Nowimcetar a tomperatiastupatores a 120° Fo). 'SECCION ViI- SALUD Y PRIMEROS AUXILIOS AS PRIMARIAS DE ENTRADA & GFECTOS DE LA SOGREEXPOSICION. (i: Punde ausar iain ke moderada 2 sever, sean, ereecnens lagrineo, vin bares, La expt prong puede dar too ear, "ie: contac necieteo rekon pose case rac, Inula: ta ilactn de co puns causar tain dls vst aso vests, La lela sbi 0 en exces puede caitrniacin an apa rei ‘stpecor, mareos, mused, oes clos on oan heros con Ingnet: Puede cousariniacén gosbonesina nus, wine, y dares La api delet ens pulmencs puede Gass eskn pumona, PROCEDIMIENTOS OF PRMEROS AUKIIOS: es: Enjaoue con grandes cantdades de apis cotete esc ran menos 15 mos maatonindo le plane cuprore inetors abe, Sa htadn pers, ‘sue slencn médeainmodatorata Piette con ag y ab, Sti ition pes, bueque ater sca Intocn:Yrasdese af ae Hee. Busque slzb mca inmedatament, Sd de reap adrnsre repaint Ingsatén: No provorve ef wimito. Busaueatencen midi eaten 'SECCION Vil - DATOS DE PROTECCION ESPECIAL rotccin Respirator: No es nocosaa, ie pra exo acecuadD conte alos nstuccaes oni ei entice: ital tn esp ol para mantener os concentvaions de ste de singe qe ane ts Sain por ba ls tes copes, Gates do Protec: Use quanto: resistnes a preicos quiicas ova 3 ebetctte cn as as Prtecain par os Ojos: Use sere antes de eogurdad o gota existe a sucanlas ante Guan taba con probs qumios SECCION IX PROTECCION POR DERRAME 0 FUGA, EASOS & SEGUE EM CASO DE DERRAME O FUGA: Penna ques Ovpar propulsr: Martha un escape oelyvetlaciinadecxada No fume. Mantenga sc Matis de clo, yaa, seas dl dear ofgs, Oso ibe con meal abeorbentey tart Lave eae Ps evr enbones: essehw date seen ‘snpopods ge aceive toe regamentos odors sites) loa [METODO OE ELRANACION DE DESHECHOS: Las latas de sro, cinco estén vaca y sn peo, po uso nomi o cansitaen en peli de deeech,y deberin ‘etinse, Conute con ts avieniades faders, etalon y locas prt ear cndis om bs proces geben A= NOAPLICA ~ NIESNO SE HA ESTABLECIO - NO-NO SEA OETERMINADO ~

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