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Ontario Geological Survey
Miscellaneous Paper 129

Volcanology and Mineral

Deposits

edited by
John Wood and Henry Wallace

1986

Reprinted by:

Ministry of
Northern Development
and Mines
Ontario
 1986 Government of Ontario ISSN 0704-2752
Printed in Ontario, Canada ISBN 0-7729-1327-7
Reprinted 1988
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Toll-free from Area Code 807 O-ZENITH-67200

Canadian Cataloguing in Publication Data

Wood, John
Volcanology and mineral deposits
(Ontario Geological Survey miscellaneous paper, ISSN 0704-2752 ; 129
ISBN 0-7729-1327-7

1. Volcanic ash, tuff, etc. l. Wallace, Henry. II. Ontario. Ministry of Northern Devel
opment and Mines. III. Ontario Geological Survey. IV. Title. V. Series.
QE461.W66 1986 549.11423 C86-099663-8

Every possible effort is made to ensure the accuracy of the information contained
in this report, but the Ministry of Northern Development and Mines does not
assume any liability for errors that may occur. Source references are included in
the report and users may wish to verify critical information.

Parts of this publication may be quoted if credit is given. It is recommended that

reference be made in the following form:

Easton, R.M., and Johns, G.W.

1986: Volcanology and Mineral Exploration: The Application of Physical Vol
canology and Facies Studies; P.2-40 in Volcanology and Mineral Deposits,
edited by John Wood and Henry Wallace, Ontario Geological Survey, Miscella
neous Paper 129, 183 p.

If you wish to reproduce any of the text, tables or illustrations in this report, please
write for permission to the Director, Ontario Geological Survey, Ministry of Northern
Development and Mines, 11th floor, 77 Grenville Street, Toronto, Ontario,
M7A 1W4.
Cover: Photo of lava lake activity, Mount Nyiragongo, West African Rift Valley, Zaire.
Photo taken by R.M. Easton, August 1972.
Scientific Editor: Guy Kendrick 1500-88-U of T Press
Foreword

In December of 1982, during the annual Ontario Geoscience Seminar, the staff of
the Precambrian Section of the Ontario Geological Survey conducted a half-day
forum with the theme "Volcanology and Mineral Deposits".

This volume documents the presentations given at that seminar in an ex

panded form. The chapters included here are intended to remind geologists of
basic principles and techniques employed in fields such as physical volcanology
and volcanic stratigraphy, and to acquaint them with new developments in these
areas that have significant implications for mineral exploration. Examples are
taken from Ontario's Archean greenstone belts, and illustrate the types of work
done by many Ontario Geological Survey geologists over the past several years, l
hope that the reader will find this a useful aid and reference in these increasingly
complex fields.

V.G.Milne
Director
Ontario Geological Survey

Mi
Introduction

Stratigraphy, lithologic parameters and structural features are fundamentally im

portant controls known to influence the location and character of most types of
mineral deposits. This volume deals with the interrelationship between these
fundamental factors in volcanic terrains. Even though the emphasis here is on the
discussion of volcanic stratigraphy and lithologies, it should be clear that a
knowledge and understanding of structure are obligatory in describing and inter
preting both mineral deposits and the rocks in which they occur. This maxim
applies equally in the quest for new deposits, particularly in complex Archean
terrain.
The purpose of this publication is to inform and interest the exploration
geologist in a wide variety of topics related to volcanology, mineral deposits, and
the geology of Ontario. Volcanology, like many other subdisciplines of geology,
has become a multi-faceted, rapidly expanding field. In light of this, the first
chapters included here introduce terminology commonly employed, and describe
concepts, principles and techniques applied in the later chapters. Two of these
principles, volcanic facies analysis and stratigraphic analysis are basic to under
standing spatial and genetic relationships between volcanic rocks and mineral
deposits.
Following the thematic chapters are a series which illustrate the use and
utility of these techniques and concepts when applied to common problems of
mapping and mineral exploration in Archean supracrustal belts. Mineral deposits in
such areas as Timmins-Kirkland Lake, Wawa, Red Lake, and Lake of the Woods
are placed within their stratigraphic context.and possible volcanological controls
on their development are discussed.
The last two chapters in the volume differ from those outlined above in that
they are concerned primarily with chemical characteristics of volcanic rocks
which serve as useful clues in the search for mineral deposits. The first illustrates
the significance of these related concepts in volcanology, namely volcanic cyclic-
ity within volcanic environments and stratigraphic intervals of high mineral poten
tial.
The last chapter deals with the use of statistical techniques which, when
applied to lithogeochemical data, can help define the extent and character of
alteration commonly associated with mineral deposits. These methods, used in
conjunction with geological information, greatly enhance the geologist's ability to
identify exploration targets from the mass of chemical data typically acquired
during modern regional exploration programs.
This volume by no means provides an exhaustive coverage of our stated
subject; we hope that for many it will serve as a useful introduction or reminder of
what can be accomplished. Even though many of the cited examples of economic
mineralization are base-metal deposits, it should be borne in mind that the ability
to unravel volcanology and stratigraphy is fundamental to the understanding of
the geology of any Archean greenstone belt, and hence is of immense value even
in the search for structurally controlled deposits. For more information on the
topics outlined; references are of course included in each of the chapters, and the
geological staff of the Ontario Geological Survey are always available to those
interested in discussing any aspect of Ontario's geology and mineral potential.
Contents

PART ONE: CONCEPTS AND PRINCIPLES IN THE STUDY OF

VOLCANOES AND VOLCANIC ROCKS___________________
Chapter 1 Volcanology and Mineral Exploration:
The Application of Physical Volcanology and Facies Studies
P.M. Easton and G. W. Johns ...................................................................................... 2

Chapter 2 Stratigraphic Correlation Techniques

N.F. Trowell................................................................................................................ 41

PART TWO: VOLCANIC STRATIGRAPHY IN ARCHEAN GREENSTONE

BELTS_______________________________________
Chapter 3 Stratigraphic Correlation of the
Western Wabigoon Subprovince, Northwestern Ontario
N.F. Trowel! and G. W. Johns .................................................................................... 50

Chapter 4 Stratigraphic Correlation in the Wawa Area

P.P. Sage.................................................................................................................... 62

Chapter 5 Mineralization and Volcanic Stratigraphy

in the Western Part of the Abitibi Subprovince
L.S. Jensen................................................................................................................. 69

Chapter 6 Developments in Stratigraphic Correlation:

Western Uchi Subprovince
H. Wallace, P.O. Thurston, and F. Corfu................................................................. 88

PART THREE: VOLCANIC LITHOGEOCHEMISTRY AND MINERAL

EXPLORATION____________________________
Chapter 7 Volcanic Cyclicity in Mineral Exploration;
the Caldera Cycle and Zoned Magma Chambers
P.O. Thurston ........................................................................................................... 104

Chapter 8 Recognition of Alteration in Volcanic Rocks

Using Statistical Analysis of Lithogeochemical Data
E.G. Grunsky............................................................................................................. 124

vii
 CONVERSION FACTORS FOR MEASUREMENTS IN ONTARIO GEOLOGICAL
________________SURVEY PUBLICATIONS.—-———————-————-
CONVERSION FROM SI TO IMPERIAL CONVERSION FROM IMPERIAL TO SI
SI Unit Multiplied by Gives Imperial Unit Multiplied by Gives
LENGTH
1 mm 0.039 37 inches 1 inch 25.4 mm
1 cm 0.393 70 inches 1 inch 2.54 cm
1 m 3.280 84 feet 1 foot 0.304 8 m
1 m 0.049 709 chains 1 chain 20.1168 m
1 km 0.621 371 miles (statute) 1 mile (statute) 1.609 344 km

AREA
1 cm2 0.1550 square inches 1 square inch 6.451 6 crrr
1 m2 10.7639 square feet 1 square foot 0.092 903 04 m2
1 km2 0.386 10 square miles 1 square mile 2.589 988 km2
1 ha 2.471 054 acres 1 acre 0.404 685 6 ha

VOLUME
1 cm3 0.061 02 cubic inches 1 cubic inch 16.387 064
1 m3 35.314 7 cubic feet 1 cubic foot 0.028 316 85 m
1 m3 1.3080 cubic yards 1 cubic yard 0.764 555 m3

CAPACITY
1 L 1.759 755 pints 1 pint 0.568 261
1 L 0.879 877 quarts 1 quart 1.136 522
1 L 0.219969 gallons 1 gallon 4.546 090

MASS
19 0.035 ounces (avdp) 1 ounce (avdp) 28.349 523
273 96 g
19 0.032 ounces (troy)
15075 1 ounce (troy) 31.1034768 g
1 kg 2.204 62 pounds (avdp) 1 pound (avdp) 0.453 592 37 kg
1 kg 0.001 tons (short)
102 3 1 ton (short) 907.18474 kg
1 t 1.102 311 tons (short) 1 ton (short) 0.907 184 74 t
1 kg 0.00098421 tons (long) 1 ton (long) 1016.046 908 8 kg
1 t 0.984 206 5 tons (long) 1 ton (long) 1.016 046 908 8 t
CONCENTRATION
1 g/t 0.029 166 6ounce (troy)/ 1 ounce (troy)/ 34.285 714 2 g/t
ton (short) ton (short)
1 g/t 0.58333333 pennyweights/ 1 pennyweight/ 1.7142857 g/t
ton (short) ton (short)

OTHER USEFUL CONVERSION FACTORS

1 ounce (troy) per ton (short) 20.0 pennyweights per ton (short)
1 pennyweight per ton (short) 0.05 ounces (troy) per ton (short)
Note. Conversion factors which are in bold type are exact. The conversion
factors have been taken from or have been derived from factors given in the
Metric Practice Guide for the Canadian Mining and Metallurgical Industries,
published by the Mining Association of Canada in cooperation with the Coal
Association of Canada.

viii
Part One: Concepts and Principles in the
Study of Volcanoes and Volcanic Rocks
Chapter 1

Volcanology and Mineral Exploration: The Application

of Physical Volcanology and Facies Studies
R.M.Easton and G.W.Johns

CONTENTS Example 2 - Berry River formation 34

Volcanic Facies and Known
Abstract............................................................................. 4
Massive-Sulphide Deposits ................ 35
Introduction ....................................................................... 4 The Millenbach Deposit.................. 35
Relationship Between Physical The Corbet Mine .............................. 36
Volcanology and Mineral Exploration ....................... 4 Discussion ............................................ 36
Scope of Chapter......................................................... 4
Terminology .................................................................. 5 Summary ................ 37
Physical Volcanology ...................................................... 5 Acknowledgments 37
Types of Volcanic Eruptions ...................................... 5 References ............. 38
Eruption Products......................................................... 5
Volcanic Rock Classification ..................................... 8 TABLES
Extrusive Rocks ....................................................... 8 1.1. Classification of volcanic eruptions
Grain Size Classification .................................... 8 and the types of volcanic products
Textures ................................................................ 8 associated with each .......................... .. 6
Structures.............................................................. 8 1.2. Origin of lahars .................................... 12
Flow Morphology .............................................. 11
Volcanic Fragmental Rocks ................................ 11 1.3. Comparison of other coarse-grained
Type of Fragmentation .................................... 11 deposits with lahars ............................ 12
Grain Size Classification ................................. 12 1.4. Some types of volcanic breccias ...... 13
Fragment Composition and Shape ................ 13 1.5. Terms for mixed pyroclastic-
Method of Emplacement ................................. 13 epiclastic rocks .................................... 15
Criteria Used to Distinguish Types of 1.6. Some characteristics of the three
Volcanic Fragmental Rocks..................................... 16 main pyroclastic deposit types........... 17
Grain Size .............................................................. 17 1.7. Types of pyroclastic flows ................., 18
Fragment Type ...................................................... 17
Fragment Shape.................................................... 18 1.8. Summary descriptions of types of
Welding .................................................................. 19 pyroclastic flow and surge deposits.. 19
Sorting .................................................................... 19 1.9. Criteria for subdividing pyroclastic
Bedding/Stratification .......................................... 19 rocks ....................................................... 20
Matrix ...................................................................... 19 1.10. Selected characteristics of some
Facies and Extent of Deposit.............................. 21 common breccia types ......................... 20
Summary ................................................................ 21 1.11. Bedding thickness terms ...................... 25
Volcanic Facies......................................................... 21 1.12. Field criteria used in the greenschist
Introduction............................................................ 21 facies to distinguish between felsic
Volcanic Facies .................................................... 21 metatuff, porphyritic felsic flows, and
Volcanic Facies on a Regional poorly bedded, muscovite-bearing
Scale................................................................... 23 metagreywacke...................................... 25
Composite Volcano .......................................... 23
Central or Vent Facies ................................. 23 1.13. Products associated with the four
Proximal Facies ............................................ 24 main volcanic facies of a central
Distal Facies ................................................. 24 vent composite volcano, as shown in
Epiclastic Facies .......................................... 24 Figure 1.25 .............................................. 28
Mafic Shield Volcano....................................... 26 1.14. Products associated with the main
Central or Vent Facies ................................. 26 volcanic facies of a mafic shield
Proximal Facies ............................................ 26 volcano, as shown in Figure 1.26 ....... 28
Distal Facies ................................................. 26 1.15. Exploration criteria for Archean
Volcanic Facies on a Deposit Scale.............. 26 volcanogenic massive-sulphide
Felsic and Intermediate deposits ..................................................., 37
Pyroclastic Flows ......................................... 26
Mafic Flows ................................................... 31 FIGURES
Environment Indicators.................................... 31
1.1. Relationship between physical
Summary ............................................................ 32
volcanology and mineral exploration .................. 4
Case Studies ................................................................. 32
1.2. Relationship of landform to
Mapping of Pyroclastic Sequences and
environment for basaltic volcanism .................... 7
Identification of Volcanic Facies............................ 32
Example 1 - Skead Group, Abitibi
Subprovince .......................................................... 32

1.3. a) Facies model for pyroclastic
deposits resulting from a medium- to
large-scale silicic explosive eruption
in a subaerial environment; b)
Schematic diagram showing the
deposits of an explosive silicic
eruption. ................................................., ,. 7
1.4. Model of an Archean island volcanic
system ...................................................., .. 8
1.5. Two types of facies variation
observed in subaqueous basalt and
andesite flows ........................................ , 9
1.6. Vesicle shape and distribution in aa,
pahoehoe, and pillowed lava flows..... , 9
1.7. Flow morphology in aa (a), pahoehoe
(b), and pillowed (c) lava flows as
seen in cross section ............................. 10
1.8. a) Schematic cross sections through
an endogeneous dome and flow of
viscous lava and b) through a
rhyolitic obsidian flow........................... 10
1.9. Structure of an Archean subaqueous
rhyolite flow from Rouyn- Noranda,
Quebec .................................................... 10
1.10. Illustration showing the inherent
classification problems with some
pyroclastic rocks............................... 11
1.11. Granulometric classification for
unimodal, well-sorted pyroclastic
rocks ................................................... 13
1. 12. Granulometric classification of
pyroclastic deposits (left) and
subdivision of tuffs and ashes
according to their fragmental
composition (right) ................................. 14
13. Granulometric classification for
polymodal volcanic fragmental rocks
where a more detailed classification
than shown in Figure 1.12 is needed .. 14
14. Sketch showing characteristics of
various pyroclastic rocks under the
microscope .............................................. 16
1 15. The three main types of pyroclastic
deposit based on depositional
mechanism, and their geometric
relations with the underlying
topography............................................... 16
16. Classification scheme of pyroclastic
fall deposits ............................................. 20
17. Md^/o Median grain diameter versus
deviation in grain diameter) plot
showing the fields of pyroclastic fall
and flow deposits ................................... 21
18. Grain size distribution in ash-flows
and lahars ................................................ 21
1.19. Schematic diagrams showing
characteristics of some common
volcanic fragmental rocks................. 24
1.20. Types of volcanoes............................ 25
1.21. Pyroclastic rock distribution in the
western and the eastern Caribbean 25
P.M. EASTON AND G. W. JOHNS
1.22. Principal facies variation in volcanic
rocks related to a large central vent
composite volcano ............................... 26
1.23. Principal facies variation in volcanic
rocks related to a large shield
volcano................................................... 27
1.24. Conditions of initiation and types of
subaqueous transport........................... 29
1.25. Schematic drawings of a submarine
eruption producing subaqueous
pyroclastic flows, and subsequent
appearance of the deposits of such
an eruption.............................................. 29
1.26. Lateral facies variation in
subaqueous pyroclastic flows ............. 30
1.27. Structure sequences of subaqueous
pyroclastic flows.................................... 30
1.28. Facies model for subaqueous mafic
flows on the flank of a shield
volcano, showing proximal massive
facies and distal pillowed facies ........ 31
1.29. Environment of formation of volcanic
breccias and specific lava flow
features (water depth figures only
approximate)........................................... 31
1.30. Distribution of the pyroclastic rocks
of the Skead Group in southern
Bryce and Tudhope Townships........... 32
1.31. Distribution of volcanic facies of the
pyroclastic rocks of the Skead Group
in southern Bryce and Tudhope
Townships............................................... 33
1.32. Volcanic facies of the Berry River
formation, eastern Lake of the
Woods...................................................... 34
1.33. Geology of the Millenbach deposit,
looking northeast along a northwest-
southeast section ................................ 36
1.34. Geology through the Corbel Mine,
looking north along section 800 N 36
PHOTOGRAPHS
1.1. Structure and features in Archean
and Proterozoic volcanic fragmental
rocks ...................................................................... 15
1.2. Pyroclastic breccias............................................ 22
1.3. Flow breccias and hyaloclastites ..................... 23
CHAPTER 1

ABSTRACT Q
EMPIRICAL
Recognition of volcanic facies regimes in the Ar
chean is a potential mineral exploration tool which
can help discriminate between barren and mineral
ized environments. Recognition of volcanic facies re
quires the ability to classify Archean pyroclastic and
volcanic fragmental rocks, and to identify, where pos
sible, the eruptive and depositional mechanisms
which produced these deposits. This chapter reviews
the classification of volcanic fragmental rocks.the
classification of facies models for volcanic se
quences, and illustrates how these concepts can be
applied in four Archean case studies with reference
to their potential use in mineral exploration. b phreatic"\L CONCEPTUAL
ORE
INTRODUCTION
Mineral deposits are anomalies, and Sangster (1980)
has noted that massive-sulphide mining districts
have an average diameter of 32 km; that is, an area
of 800 km2. Within this 800 km2 area, a mineral de
posit is still a very small target. Many massive-sul
phide deposits are associated with volcanic rocks in
what is commonly called a proximal volcanic environ
ment. Identification and mapping of the physical heat flow:
character of volcanic rocks (physical volcanology)
and their environment of deposition (facies analysis)
will narrow the search area and make more efficient
use of the exploration dollar. Figure 1.1. Relationship between physical vol
canology and mineral exploration may be seen
RELATIONSHIP BETWEEN PHYSICAL VOLCANOLOGY
in an empirical or a conceptual sense. In an
AND MINERAL EXPLORATION
empirical sense (a), there is an observed asso
ciation between ore and rock type. In a con
Physical volcanology can be related to mineral ex ceptual sense (b), a model is developed to
ploration in two ways. Firstly, it can be related to explain the observed ore/rock associations.
mineral exploration in an empirical sense, as is This model can then be used to explore for
shown in Figure 1.1 a. In this model of a typical new deposits. Both examples shown are for
Kuroko massive-sulphide deposit, there exists a the Kuroko massive-sulphide district, Japan
physical association between lava domes, phreatic (modified from Franklin et al. 1981). a) ideal
breccias, and ore. This association most commonly ized cross section of a typical Kuroko deposit;
occurs in a proximal volcanic environment. Sangster b) essential features of recent genetic models
(1972) has observed a similar association between for volcanic-associated deposits.
coarse pyroclastic breccias, which he termed
"mill-rock", and volcanogenic massive-sulphide de
posits in the Superior Province of Ontario. Thus, ex
ploration methods rely on the ability of the geoscien-
tist to identify coarse pyroclastic breccias in proximal volcanic rocks found in association with known ore-
to vent environments in the search for such deposits. deposits are well described and understood in terms
Secondly, physical volcanology and mineral ex of their eruptive mechanisms and environments of
ploration can be related in a conceptual sense, as deposition, important associations between ore and
shown in Figure 1.1 b. Here, physical volcanology and particular rock types could be missed, making it dif
facies analysis have been used to develop models of ficult to deduce models for ore-genesis and explora
ore genesis, as is shown in this example from the tion.
Kuroko region of Japan. Such models can then be
used to outline areas of favourable mineral potential SCOPE OF CHAPTER
in other similar areas. Even though the Kuroko model in this chapter the authors hope to:
for the genesis of massive-sulphide deposits was
developed for a modern volcanic region, the model 1. provide an introduction to the types of volcanic
has been successfully applied to Archean mining eruptions and the products of these eruptions
camps (Franklin era/. 1981). 2. provide an introduction to the classification of
In both these cases, physical volcanology and volcanic products
facies analysis are tools which can be used in con 3. discuss criteria that can be used to distinguish
junction with other tools such as stratigraphic correla different eruptive products, with emphasis on
tion and geochemistry to form the basis of mineral pyroclastic rocks
exploration programs (Trowell, Chapter 2, this vol
ume). This, however, is a two-way process, for unless

4. discuss volcanic facies, and how facies analysis
of volcanic rocks can aid mineral exploration
programs
5. present some examples of how physical vol
canology can be applied to mineral exploration
In doing so, the authors hope to illustrate the
utility, the limitations, and the application of physical
volcanology studies in the Archean to aid mineral
exploration.
The chapter is divided into three, semi-indepen
dent sections. The first section is a review of vol
canic rock classifications, emphasizing field meth
ods, the types of materials produced by volcanic
eruptions, and their mode of emplacement. The sec
ond section examines facies models for volcanic
rocks to the extent that is possible at present, be
cause this subject is still in its infancy. The final
section presents several examples from the Superior
Province showing how facies analysis and physical
volcanology can be used to narrow the search area
for mineral deposits.
TERMINOLOGY
For the purposes of this chapter, the following terms
are defined below:
Physical Volcanology can be defined as the study
of the products of volcanic eruptions, eruptive
mechanisms, and the landforms produced by vol
canic eruptions. By definition, physical volcanology
includes aspects of the physical character of erup
tion products and facies analysis (the focus of this
chapter), stratigraphy (Trowell, Chapter 2, this vol
ume), and the reconstruction of paleoenvironments (a
goal of most geologic mapping).
A facies is a deposit or an eruptive unit, or part
thereof, having distinct spatial and geometric rela
tions and internal characteristics (Self 1982d).
A facies model is a generalized summary of the
organization of the deposits in space and time. The
model should be a "norm", a basis for interpretation,
and a predictor of new geologic situations (Self
1982d).
Pyroclastic deposits/rocks is used in a broad
sense, as recommended by the IUGS (Schmid 1981).
Schmid (1981) defined a pyroclast as "being gen
erated by disruption as a direct result of volcanic
action"; pyroclastic deposits are assemblages of
pyroclasts. Moreover, Schmid (1981) allowed
pyroclastic deposits to contain as much as 25 07o by
volume of epiclastic, organic, chemical, sedimentary,
and diagenetic admixtures. Included in the term
pyroclastic deposits are subaerial and subaqueous
fall, flow, and surge deposits, lahars, subsurface, and
vent deposits, hyaloclastites, intrusion and extrusive
breccias, and diatremes.
PHYSICAL VOLCANOLOGY
TYPES OF VOLCANIC ERUPTIONS
Before the methods of classifying and subdividing
volcanic products are discussed, it is necessary to
review how volcanic rocks are produced. This is
because eruptive mechanisms affect the physical
character of volcanic products, how and where they
P.M. EASTON AND G. W. JOHNS
are deposited, and hence, their usefulness as an
exploration tool. For example, in order to use Sang-
ster's (1972) observation that coarse pyroclastic
breccias ("mill-rock") are associated with massive-
sulphide deposits as an exploration tool, it is neces
sary to know how such breccias are formed. In re
cent volcanic terrains, coarse pyroclastic breccias
may form by a variety of mechanisms:
1. pyroclastic flow, including ignimbrites,
"block-and-ash" flows
2. autobrecciation during flowage or extrusion of
lava domes
3. phreatic eruptions
4. debris flows, including lahars, mudflows
Naturally, not all of these deposits are likely to
be mineralized. Phreatic eruption breccias are be
lieved to be the most closely associated with
massive-sulphide deposits in the Archean (Hodgson
and Lydon 1977; Franklin el at. 1981). Thus, if dif
ferent volcanic breccias and their eruptive mecha
nisms can be distinguished, such knowledge can be
used to reduce the size of the potential exploration
area.
For the purposes of this chapter, three main
eruptive mechanisms exist:
1. Phreatic (steam) eruptions result when meteoric
water is vapourized with sufficient pressure to
fracture and eject the confining rocks. Purely
phreatic explosions expel no juvenile (magmatic)
material.
2. Phreatomagmatic (Surtseyan) eruptions are pro
duced by the interaction of ground or surface
water and magma, and may eject much lithic
(accidental or accessory) material as well as
juvenile material.
3. Magmatic eruptions result from the ejection on
surface of molten material, either in an explosive
or an extrusive eruption. Magmatic eruptions are
further divided into several types. These are
named after volcanoes which typically produce
eruptions of that type (Table 1.1). In order of
increasing intensity, they are basaltic flood erup
tions, Hawaiian eruptions, Strombolian eruptions,
Vulcanian eruptions, Sub-Plinian eruptions,
Plinian eruptions, and Ultra-Plinian eruptions. Fur
ther details on these eruption types are given in
Macdonald (1972), Williams and McBirney
(1979), and in Table 1.1. An individual volcano
may exhibit one or more of these eruptive
mechanisms during its lifetime.
ERUPTION PRODUCTS
The eruptive mechanisms cited above produce two
broad classes of deposits:
1. Extrusive Deposits. These include lava flows and
lava domes produced only during magmatic erup
tions.
2. Explosive/Pyroclastic Deposits. These include
fall, flow, and surge deposits, and other
pyroclastic deposits which may be produced by
all three types of volcanic eruptions.
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Figure 1.2. Relationship of landform to environ COMMON

ment for basaltic volcanism. The figure reflects
volcanism in 4 distinct environments; such as
LANDFORM
at varying elevations in an island system, with
A being 500 m above sea level; B being 10 m Cinder cone'
above; C being WO m below; and D being Little or No
1000m below sea level. Eruptive mechanisms Water
responsible for these landforms are: A, D -
magmatic eruption; B, C - phreatic or
phreatomagmatic eruptions, or both. (Modified Ground Water
from Wholetz and Sheridan 1983).

Shallow Surface
Water

Deep Water

fine
PROXIMAL DISTAL ash-fall
0 ^ deposit

one
laterally extensive flow
co-ignimbrite ash-fall unit

;a
pyroclastic surge pyroclastic
surge
deposit
ignimbrite flow units Plinian ash-fall X'; Plinian
ash-fall
deposit

Figure 1.3. a) Facies model for pyroclastic deposits resulting from a medium- to large-scale silicic explosive
eruption in a subaerial environment. X-X' denotes cross section shown in b. After Wright et al. (1981). b)
Schematic diagram showing the deposits of an explosive silicic eruption. An inversely graded Plinian
ash-fall bed is overlain by a surge deposit. The basal layer of the pyroclastic flow unit (a) may show
inverse grading, whereas in the main part of the flow (b), lithic inclusions (filled clasts) are concentrated
near the base, and pumice fragments (large open clasts) and fumarolic pipes are concentrated near the
top of the flow. Deposits of fine co-ignimbrite ash occur above the flow unit. A lava flow may cap the
sequence, which reflects eruption of increasingly volatile-poor magma. (After Self 1982a, 1982b and
Sparks et al, 1973).

Some important factors which influence the type
of volcanic products involved in any one eruption
are:
1. Environment. For example, a subaerial magmatic
eruption may produce a pahoehoe, aa, or block
lava flow of andesitic composition, but a sub
aqueous eruption of the same magma will pro
duce a pillowed flow, perhaps with associated
pillow-breccia and hyalotuff. Indeed, the amount
of water-magma interaction, which may be in
directly related to water depth, can have a sig
nificant effect on the types of volcanic products
erupted as shown in Figure 1.2.
The Flow Unit Concept. In many cases, a flow,
either of lava or a pyroclastic flow, may be com
posed of a variety of distinct rock types. All of
these rock types constitute a flow unit, and are
the product of a single eruptive event. An exam-
CHAPTER 1
500
Figure 1.4. Model of an Archean island volcanic system.
pyroclastic cone has been constructed atop an earlier
constructed atop a mafic shield volcano. Most volcanic
subaerially, but are deposited, or redeposited subaqueously.
pie of this can be seen in the ash-flow deposit
shown in Figure 1.3. Recognition of flow units is
important in recognizing volcanic facies, recon
struction of paleoenvironments, and eruptive
mechanisms, as discussed in later sections.
3. Facies. The facies regime of a particular deposit
being studied has an effect on the volcanic pro
ducts observed. Figure 1.3 is a facies model for
a subaerial pyroclastic flow. The cross section
shown in Figure 1.3b is what a deposit in the
proximal facies of the flow would resemble. A
deposit in the distal facies (Figure 1.3a) would
consist of only the Plinian ash-fall deposit and
the co-ignimbrite ash-fall, and may not be readily
recognized as part of a pyroclastic flow deposit.
Near the vent, a co-ignimbrite lag deposit would
be present interfingering with the main part of the
pyroclastic flow. Thus, an approximate idea of
what facies regime the deposits under study may
be in is required in order to accurately interpret
the depositional mechanisms that formed the
rocks under study.
4. Island Systems. Ayres (1982) has argued that
many Archean volcanic systems, especially the
mafic-felsic systems, were islands (Figure 1.4). In
this case, most products may be erupted sub
aerially after a certain point in the evolution of
the volcanic edifice has been passed. Most pro
ducts, however, will be deposited subaqueously,
either through primary deposition, or through re
working and redeposition. This is an important
concept when it comes to the application of stud
ies of modern volcanoes (mainly subaerial) to
Archean volcanism.
VOLCANIC ROCK CLASSIFICATION
Now that we are aware of how volcanic rocks are
produced, how do we classify such rocks, and how
do we distinguish between different kinds of volcanic
products, in particular explosive (pyroclastic) depos
its?
Even though in this chapter, volcanic rocks are
separated into two groups, extrusive rocks and vol
canic fragmental (explosive) rocks, the reader should
8
second generation
pyroclastic cone
first
generation
pyroclastic
cone
Second generation felsic to intermediate
wave-modified pyroclastic cone. Both are
products of the second cone are erupted
(After Ayres 1982).
be aware that the two are commonly intimately inter
mixed. In this chapter, emphasis is placed on the
mesoscopic and microscopic lithological features of
volcanic rocks, and not on the classification of vol
canic rocks on the basis of chemistry.
Extrusive Rocks
Extrusive volcanic rocks are classified mainly on the
basis of grain size, primary textures, structures, and
flow morphology. Salient points of such classifica
tions are listed below:
Grain Size Classification A commonly used system
is that of Moorhouse (1959):
Aphanitic: grains not visible with a hand lens
Fine grained: -O mm
Medium grained: 1 to 5 mm
Coarse grained: ^ mm
Textures Most standard igneous petrology texts de
fine common textural terms (for example: Joplin 1968;
Williams et at. 1954; Harker 1962; Macdonald 1972),
and hence these are not repeated here. Some tex
tures, however, may be diagnostic of individual flows
or flow units; or of the specific chemical composition
and flow type (for example, spinifex texture in ul
tramafic flows).
Structures Many flows in the Archean are mapped
on the basis of internal structures, or lack of struc
tures as in the case of massive flows. Some of the
more important structures are discussed as follows:
Pillow Lavas. Pillow lavas are common throughout
Archean volcanic terrains. Features to note in de
scribing pillow lavas include the following:
1. size and shape
2. amygdaloidal or non-amygdaloidal
3. variolitic or non-variolitic
4. selvage thickness and possible differences in
chemistry from the interior outward
5. internal structure, for example, radial, concentric

PROXIMAL DISTAL
ra PILLOW
La!) BRECCIA
S PILLOW
53 LAVA
pq MASSIVE
L2JLAVA
Figure 1.5. Two types of facies variation observed
in subaqueous basalt and andesite flows. Each
column represents a flow unit, and is com
posed of varying proportions of hyalotuff, pillow
breccia, pillow lava, and massive lava.
(Modified from Dimroth et al. 1978). For com
plete range of possible flow unit variation, see
Dimroth et al. (1978).
6. packing relations, possible top determinations
7. amount and type of interpillow material
Dimroth et al. (1978, 1979), Dimroth and Rocheleau
(1979), and Wells et al. (1979) have described how
features such as size and shape and packing rela
tions can be used to map out pillowed flows, and
have developed a facies concept for pillowed flows
(Figure 1.5; see Facies Section).
Moore et al. (1971) pointed out some of the
dangers in making top and thickness determinations
of ancient pillow lavas because the bedding plane
measured may actually be from foreset beds on an
initially steep slope. Borradaile (1982) has also exam
ined how deformation can affect the accuracy of top
determinations in pillowed volcanic sequences. In
shallow dipping pillow lava sections, the accurate
determination of facing directions may not be possi
ble because of the shallow-angle of the exposed
plane through the sequence.
Vesicles and Amygdules. A vesicle is a cavity of
variable shape in a lava which is formed by the
entrapment of a gas bubble during solidification of
the lava (AGI 1980). An amygdule is a gas cavity or
vesicle in an igneous rock which is filled with such
secondary minerals as calcite, quartz, chalcedony, or
a zeolite (AGI 1980).
In a study of vesicles in pillow lavas, Jones
(1969) concluded that the size of vesicles
(amygdules in most Archean flows) were related to
water depth, that is, the deeper the water, the smaller
the vesicles. The maximum water depth of vesicle
formation is about 2000m. Higgins (1971) arrived at
the same conclusions. Moore (1970) noted that al
kalic basalts are more vesicular than tholeiitic basalts
that have been erupted at the same water depth.
Note that vesicle size and abundance is a measure
of the depth of emplacement, not necessarily the
depth of eruption (Jones 1969). Vesicles also occur
RM EASTON AND G. W. JOHNS
(r*
o o" 0 . O"
O oo o Ooo
o 0 o, 0 o
co
Figure 1.6. Vesicle shape and distribution in: a) aa;
b) pahoehoe; and c) pillowed lava flows.
in subaerial flows; aa flows and pahoehoe flows
have characteristic vesicle shape and size and abun
dance (Macdonald 1972; Figure 1.6), and can be
used to distinguish between the two flow types. Fea
tures that should be noted in the field pertaining to
vesicles and amygdules include the following:
1. size and variation in size: possible indication of
flow type, or relative water depth
2. shape: spherical, elongate, deformed
3. filling: mineralogy, variation if any
4. distribution in pillows, sometimes concentrated at
pillow top
Varioles and Variolitic Lavas. Varioles are pea-
sized spheres, usually composed of radiating crystals
of plagioclase or pyroxene. This term is generally
applied only to these spherical bodies in basic ig
neous rocks (AGI 1980). A spherulite is a rounded or
spherical mass of acicular crystals, commonly com
posed of feldspar, radiating from a central point (AGI
1980).
Varioles are common in Archean mafic lavas,
and have been used in tracing individual flows and
packages of flows in Archean "greenstone belts".
The origin of varioles has been a subject of con
troversy (Carstens 1963; Furnes 1973; Gelinas et al.
1976; Hughes 1977: Philpotts 1977; Dimroth and
Rocheleau 1979). There are probably two varieties of
varioles: those formed by devitrification processes;
and those formed by spherulitic crystallization of
immiscible silicate globules.
Melson and Thompson (1973) and Furnes (1973)
have noted that varioles have been found in basalts
dredged from the ocean floor at depths of 1600 to
5000 m. Amygdules, which are known to form in
water depths of ^000 m, have also been reported in
variolitic flows. In pillow lavas, Dimroth and
Rocheleau (1979) noted three types of variole dis
tribution:
1. rim type which is close to the inner chill margin
in a zone up to 15 cm thick
2. central type which is close to the pillow core,
margins may be variole-free
3. random type
Varioles have also been observed in hyaloclastite
units (Dimroth and Rocheleau 1979; Furnes 1973).
CHAPTER 1

a Figure 1.7. Flow

morphology in aa (a),
pahoehoe (b), and
pillowed (c) lava flows
as seen in cross section.
Arrows indicate top
indicators commonly
found in the flows. Dark
areas represent voids.

FLOW DOME
1m surface breccia
5m finely vesicular pumice
surface spines
ramp ridges
structure
flow blocky 15m Z^r^LHl-T^ obsidian
banding top

9m •'.•['•'•'•••'•'•'' coarse 'y vesicular pumice

. , . . blocky
blocky spherulitic
base lava basal breccia
tephra

Figure 1.8. a) Schematic cross section through an endogeneous dome and flow of viscous lava. (After Self
1982c). b) Schematic cross section through a rhyolitic obsidian flow. Compare with mafic flow cross
section shown in Figure L7a. (After Self 1982c).

PROXIMAL DISTAL Figure 1.9. Structure of

an Archean subaqueous
hyalotuff layered breccia massive breccia rhyolite flow from
500 metres -
metres———^....)}....^ ...,.^-l ..... T; .... ....... T7TT^;;... ......,\ .... ...... Rouyn-Noranda, Quebec.
.00.. o" 0 . jr;'-oo
'•'•'." 0 ''"' Vo;^ov o:V^Vo;7"V-":
00 ''-'* 0 0 -*o'o'"•O'L'o
0 o ."-voVoiroT
o '" (Modified from Dimroth
and Rocheleau 1979).
"O - O o-0
0.0
Compare with mafic
'o\oo0!;
' O0 f ' 0

flows shown in Figure

' '. oOo 1.5.

brecciated rhyolite lava heterogeneous fine microbreccia

microbreccia

10

TEMPERATURE PHASE
CONTROLLED CONTROLLED
lahars
WATER
lahars
GAS ash ash flows
flows
100 200 o 100 200
Figure 1.10. Illustration showing the inherent clas
sification problems with some pyroclastic
rocks. Note the difference in the fields for ash
flows and mudflows (lahars) according to
whether temperature (left) or the nature of the
continuous phase (liquid water or gas) (right) is
regarded as more important. (Adapted from
Walker 1981).
Flow Morphology Flow morphology refers to the
constitution of an individual flow unit. Differences in
flow morphology can be seen in Figure 1.7, where
the morphology of an aa, pahoehoe, and pillowed
flow are compared. In addition, flow morphology may
show lateral variations, such as is shown in the
pillowed flows shown in Figure 1.5. These lateral
variations may be related to a facies model, as in the
case of pillowed flows (Dimroth et at. 1978, 1979;
see Facies Section). In addition, lava domes and
flows of felsic and intermediate composition have
morphology different from mafic extrusive rocks
(compare Figure 1.7 with Figure 1.8). Pillow lavas are
restricted to andesitic or more mafic lavas, but a
modern pillow composed of dacite has been reported
at one locality (Macdonald 1972). The pillow forma
tion in that case was ascribed to an unusually high
volatile content. Although pillowed structures are not
normally found in felsic and intermediate flows, Dim
roth and Rocheleau (1979) and de Rosen-Spence et
al. (1980) suggested that subaqueous rhyolite and
dacite flows behaved much the same as their more
mafic counterparts. These flows consist of a massive
core overlain by fine breccia and hyalotuff derived
from the flow near the vent, and consist of breccia
and hyalotuff distal to the vent (Figure 1.9).
Lava domes may occur in both vent and proximal
areas, and may precede or follow large-scale caldera
collapse. Lava domes do not indicate a waning of
volcanic activity as was previously considered
(Newhall and Melson 1983). In addition, lava domes
can be associated with phreatomagmatic eruptions,
and can occur in a number of volcanic environments.
Lava domes may have associated lava flows, that
can form by breaching of the dome and outflow.
Morphology of lava domes in subaerial and sub
aqueous environments is probably similar, although
more breccia and hyalotuff may be present with the
latter. Domes may also be associated with pyroclastic
flows, either directly, as in the case of pyroclastic
flows generated by dome collapse, or indirectly, as in
the association with post-caldera collapse volcanism.
As discussed by Thurston (Chapter 7, this volume),
R.M. EASTON AND C. W. JOHNS
lava domes associated with caldera collapse may be
mineralized. Domes may also occur as shallow-level,
subsurface intrusions.
Several zones are commonly developed within
lava domes and flows, and are labelled in Figures
1.8a and 1.8b, respectively. Descriptions of lava
domes are given in Macdonald (1972), Williams and
McBirney (1979), and Self (1982c), and of viscous
lava flows in Christiansen and Lipman (1966), Fink
(1980), Self (1982C), and Macdonald (1972).
Volcanic Fragmental Rocks
The classification of volcanic fragmental rocks pre
sented herein is based on the classification schemes
of Schmid (1981) and Wright et al. (1980), as well as
the work of Fisher (1966), Parsons (1969), Schmin-
cke (1974), and Dimroth (1977). Volcanic fragmental
rocks are classified on the basis of the method of
fragmentation, grain size, and fragment composition
(Schmid 1981). These rocks can also be classified
on the basis of the method of emplacement, as is the
case for many modern volcanic fragmental rocks
(Wright et al. 1980).
Type of Fragmentation Autoclastic Rocks. Fragmen
tation is due to mechanical deformation where dif
ferent parts of a flow or dome differ in viscosity.
Flowage will cause the less viscous parts of the flow
to deform plastically, whereas the outer more brittle
parts which are cooler than the interior will fracture.
Pyroclastic Rocks. Fragmentation is related to either
magmatic, phreatomagmatic, or phreatic eruptions, as
was discussed earlier. In addition, fragmentation may
also occur due to rapid chilling of hot magma with
water, causing shattering of the magma with no ex
plosive activity producing hyaloclastic rocks.
Alloclastic Rocks. These rocks are formed by the
fragmentation of pre-existing rocks by subsurface
volcanic processes, such as intrusion (Wright and
Bowes 1963). Under the IUGS classification scheme
(Schmid 1981), these rocks are pyroclastic rocks, as
their origin is directly related to volcanic action. Al
loclastic rocks are typically found in eroded volcanic
vents and show crosscutting relationships.
Redeposited Fragmental Rocks. This is an important
subcategory of volcanic fragmental rocks, that does
not neatly fit into a classification system based on
the fragmentation mechanism. These rocks consist
entirely of volcanic material, and many form by direct
volcanic action (Crandell 1971), and hence, are
pyroclastic rocks as defined by the IUGS (Schmid
1981). These deposits include debris avalanche and
debris flow deposits, of which lahars are an impor
tant subset. These rocks pose many difficulties in
terms of classification, partly because of the various
usages of the terms in the past, and inherent clas
sification problems as are shown in Figure 1.10. Be
cause of the confusion surrounding terms such as
lahar, a brief discussion of these rocks is warranted.
The following definitions are used in this chapter,
and follow the usage of Fisher (1982b) and Lipman
and Mullineaux (1981).
A debris avalanche is the result of the very rapid
and usually sudden sliding and flowage of incoher-
11
CHAPTER 1

ent, unsorted mixtures of soil and bedrock (AGI

1980). TABLE 1.2: ORIGIN OF LAHARS (AFTER
A debris flow is a moving mass of rock frag CRANDELL 1971).___________________
ments, soil, and mud. More than half of the particles
are larger than sand size (2mm) (AGI 1980). Mud I. DIRECT AND IMMEDIATE RESULT OF
flow should be restricted to debris flows consisting ERUPTION
dominantly of mud (that is, ^007o sand, silt, and 1. Eruption through crater lake, snow,
clay) (Fisher 1982b; Sharp and Nobles 1953). A lahar or ice.
is a special class of debris flow composed of vol 2. Heavy rain during an eruption.
canic particles (Fisher 1982b). A lahar may consist of 3. Flow of hot pyroclastic material
mainly mud (ash), and may grade into mudflows with into rivers or onto snow or ice.
increasing distance from the vent. Not all lahars form
as a direct result of volcanic activity (Crandell 1971; II. INDIRECTLY RELATED TO AN ERUPTION
Table 1.2), and technically, not all lahars are 1. Triggering of water-soaked debris
pyroclastic rocks. In practice, it is not always possi by earthquake.
ble to determine the origin of an Archean laharic
2. Bursting and rapid drainage of
deposit. Thus, if such a deposit is composed of crater lakes.
^5 07o epiclastic material, it is commonly considered 3. Dewatering of large avalanches
a pyroclastic rock. Table 1.3 compares the char
acteristics of other coarse-grained volcanic fragmen originating from collapse of volcano
side.
tal rocks with lahars. Subaqueous lahars are believed
to be similar to subaerial lahars (Fisher 1982b).
III. NOT RELATED TO CONTEMPORANEOUS
VOLCANIC ACTIVITY
Grain Size Classification Grain size limits of 1. Mobilization of loose tephra by rain
pyroclasts are comparable to the grain size limits or meltwater.
used by sedimentologists, as is shown in Figure 1.11. 2. Collapse of unstable clay- and
These size limits apply to autoclastic, pyroclastic, water-rich debris.
alloclastic, and hyaloclastic rocks, as well as to de 3. Bursting of dams from overloading.
bris flows. The terms for unimodal, well-sorted 4. From volcanoes or volcanic terrains
pyroclastic rocks (Figure 1.11; Schmid 1981) are de undergoing active weathering and
scribed below: erosion.

TABLE 1.3: COMPARISON OF OTHER COARSE-GRAINED DEPOSITS WITH LAHARS (AFTER FISHER 1982 b).
LAHARS TILL (EXCLUDING UNWELDED FLUVIAL
WATER-LAID TILL) IGNIMBRITE DEPOSITS
Large fragments May have boulders May have boulders Extremely large Extremely large
^2 mm) weighing many tons. weighing many tons. boulder absent. boulders rare.
Sorting Poor. May contain Poor. May contain Poor. Clay-size Poor. Clay-size
abundant clay-size abundant clay-size material rare or material sparse.
material. material. absent.
Grading Commonly reversed. Commonly absent. Commonly Commonly
May be normal or absent, but may normal.
absent. be normal or
reverse.
Bedding and Commonly very thick Very thick. No bedding. Commonly very Thin with
thickness with vague internal thick with vague channels and
bedding. internal layering. crossbeds.
Composition Commonly 100 07o Commonly heterolithic Pyroclastic. May Material usually
volcanic. May be and mostly contain abundant 100 07o epiclastic.
pyroclastic or mixed non-volcanic materials. breadcrust
with epiclastic Epiclastic bombs.
materials. May contain
breadcrust bombs.
Round ing of Commonly angular to Commonly subangular Commonly Commonly
large fragments subangular. to subrounded. May be subangular. subrounded to
faceted. rounded.
Pumice Common in some Not present. Common. Not present.
lahars.
Lower surfaces Commonly not Commonly erosional. Commonly not Erosional.
erosional erosional.

12

UNCONSOLI DATED DEPOSITS CONSOLIDATED
SIZE EPICLASTIC PYROCLASTIC
mm
BOULDERS Coarse BLOCKS
O RC or BRECCIA
COBBLE Fine BOMBS
LAPILLI -
PEBBLE LAPILLI TUFF
- 2 —
SAND Coarse Coarse
- 1/16
SILT ASH
- 1/256- Fine Fine
CLAY
Figure 1.11. Granulometric classification for un
imodal, well sorted pyroclastic rocks, both un
consolidated and consolidated. Terms for epi
clastic rocks are shown for comparison.
A pyroclastic breccia is a pyroclastic rock whose
average pyroclast size exceeds 64 mm and in which
angular pyroclasts (blocks) predominate. If rounded,
aerodynamically shaped pyroclasts predominate
(Photo 1.1), then the rock is termed an agglomerate.
Table 1.4 is a classification of pyroclastic breccias
based on the type of fragmentation.
A lapilli-tuff is a pyroclastic rock whose average
pyroclast size is 2 to 65 mm.
A tuff is a pyroclastic rock whose average
pyroclast size is ^ mm.
Polymodal or poorly sorted pyroclastic rocks con
taining pyroclasts of more than one dominant size
fraction can be named by using an appropriate com
bination of the terms which are given above, and are
also given in Figure 1.12 (Schmid 1981). For some
field areas, additional subdivisions can be made, as
illustrated in Figure 1.13. Figure 1.13 represents a
modification of Fisher's (1966) classification, and
has been made consistent with the IUGS terminology.
Boundaries between rock types are based on the
ease of use in the field when detailed granulometric
analysis is not possible.
Terms for mixed pyroclastic-epiclastic rocks are
listed in Table 1.5.
Fragment Composition and Shape Observation of
fragment shape can give clues to the mechanism of
fragmentation and to the eruptive processes involved.
Roundness classes used in sedimentary rock de
scriptions can also be applied to volcanic fragments.
Bounding of vesicular and pumiceous fragments may,
however, occur very rapidly and with only minor
transport when compared to sedimentary environ
ments. The specific shapes of fragments, fine
shards, and crystals can all aid in understanding the
mode of formation of volcanic fragmental rocks
R.M. EASTON AND G. W. JOHNS
TABLE 1.4: SOME TYPES OF VOLCANIC
BRECCIAS (AFTER PARSONS 1969)._______
I. Autoclastic volcanic breccias
A. Friction breccias
1. Flow breccias, by autobrecciation
of lavas
2. Crumbling of plugs, domes, and
spines
B. Explosion breccias (disruption by gas
explosion)
TUFF
II. Pyroclastic breccias
A. Vulcanian breccias: aerial ejection by
explosive eruption
1. Breccias by strombolian and
lava-fountain eruptions
B. Pyroclastic-flow breccias
C. Hydrovolcanic breccias
1. Breccias formed by phreatic
eruptions
2. Laharic breccias (volcanic-mudflow
deposits)
3. Hyaloclastic breccias
(hyaloclastites)
D. Vent agglomerates and vent breccias
III. Alloclastic volcanic breccias
A. Intrusion breccia (caused by intrusion
of magma)
B. Explosion breccias
C. Intrusive breccias (show crosscutting
relationships)
IV. Epiclastic volcanic breccias
A. Laharic breccias (in part)
B. Water-laid volcanic breccias
(Figures 1.12 and 1.13), as will be discussed later in
more detail.
Fragment composition is also an important cri
teria in the classification of volcanic fragmental rocks
(Figures 1.12 and 1.13). Three sources of fragments
may be found in volcanic fragmental rocks, as fol
lows:
1. essential or juvenile fragments: particles of cool
ed magma
2. accessory fragments: solidified volcanic rocks
from previous eruption
3 accidental fragments: broken solid country rock
In addition, the proportion of rock fragments to
crystals to glass shards can be used to classify tuffs
(Figure 1.12).
Method of Emplacement Wright et al. (1980) pro
posed a working classification for pyroclastic rocks
on the basis of depositional/eruptive mechanism.
This classification, unlike that of Schmid (1981) and
Fisher (1966) is genetic in character, and hence,
cannot always be applied to Archean volcanic rocks.
13
CHAPTER 1

BLOCKS a BOMBS PUMICE,

GLASS

PYROCLASTIC
BRECCIA

CRYSTAL
TUFF
ASH

64-2mm c2mm CRYSTALS, ROCK

LAPILLI ASH CRYSTAL FRAGMENTS FRAGMENTS

Figure 1.12. Granulometric classification of pyroclastic deposits (left) and subdivision of tuffs and ashes
according to their fragmental composition (right).

BLOCKS 8 BOMBS Nevertheless, it has utility in understanding recent

^4 mm
64-2 mm ^ 2 mm
ASH
LAPILLI
Figure 1.13. Granulometric classification for poly
modal volcanic fragmental rocks where a more
detailed classification than shown in Figure
1.12 is needed. (Adapted from Schmid 1981
and Fisher 1966). The term tuff- breccia would
include lapilli- and ash-tuff breccia.
pyroclastic deposits, and in interpreting the mecha
nisms that may have produced Archean pyroclastic
deposits.
Wright et al. (1980), following Sparks and Walker
(1973), recognized three basic types of pyroclastic
deposits (see Figure 1.15, Table 1.6):
1. Pyroclastic Fall Deposits. These are produced
when material is explosively ejected from the
vent forming an eruption column. Fall deposits
show mantle bedding (Photo 1.1, Figure 1.14),
maintaining a uniform thickness over restricted
areas while draping all but the steepest topog
raphy. The deposits are generally well sorted.
Although Wright et al. (1980) only discussed air-
fall deposits, fall deposits may also form by
settling through water, either from a subaerial, or
a subaqueous eruption column.
2. Pyroclastic Flow Deposits. Pyroclastic flows in
volve the lateral movement of pyroclasts as a
gravity-controlled, hot, high concentration
gas/solid dispersion (Wright et al. 1980). Depos
its are topographically controlled in high-aspect
ratio flows (average thickness versus horizontal
dimension, Walker 1983), and fill valleys and
depressions. In contrast to fall deposits these
flows are poorly sorted. Low aspect-ratio flows
are controlled by topography only in a minor way.
3. Surge Deposits. Pyroclastic surges involve the
lateral movement of pyroclasts as expanded, tur
bulent, low-concentration gas/solid dispersions
(Wright et al. 1980). Deposits mantle topography,
but accumulate in depressions (Figure 1.15).
Surge deposits are most commonly associated
with phreatomagmatic eruptions. Such deposits
are often thin, and near-vent; hence, in terms of

14
 R.M. EASTON AND G. W. JOHNS

TABLE 1.5: TERMS FOR MIXED PYROCLASTIC-EPICLASTIC ROCKS (AFTER SCHMID 1981).

Pyroclastic Tuffites (Mixed Epiclastic Average Clast

Pyroclastic-Eplclastic) (Volcanic and/or Size (mm)
Nonvolcanic)
Agglomerate, agglutinate
pyroclastic breccia Tuffaceous conglomerate Conglomerate, 64
breccia
Lapilli-tuff Tuffaceous breccia
coarse Tuffaceous sandstone Sandstone 2
(Ash) tuff
fine Tuffaceous siltstone Siltstone 1/16
Tuffaceous mudstone, shale Mudstone, shale 1/256
IOQ-75% by volume Pyroc lasts 25-00/0
D-25% by volume Volcanic -t- nonvolcanic
epiclasts ^ minor amounts of
biogenic, chemical sedimentary
and authigenic constituents)

Photo 1.1. Structure and features in Archean and Proterozoic volcanic fragmental rocks, a) Aerodynamically
shaped bomb in coarse tuff to lapilli-tuff, Back River Complex, Archean age, Northwest Territories, b)
Bomb and bomb-sag in underlying stratified layers, Archean tuff, Rouyn-Noranda, Quebec, c) Eutaxitic
structure (flattened pumic) in a Proterozoic age, partly welded, ignimbrite, Great Bear Lake, Northwest
Territories, d) Large-scale stratification in lapilli-tuff and tuff-breccia, subaqueous pyroclastic flow and
fall deposits, Rouyn-Noranda, Quebec.

15
CHAPTER 1

plagioclase
u 7 welded
'oY/TvA glass
ift&S *hard
flattened
pumice

quartz

basalt hyaloclastite vitric welded crystal lithic

ash tuff tuff tuff tuff

Figure 1.14. Sketch showing characteristics of various pyroclastic rocks under the microscope. Field
Diameter is 2 mm. a) Sketch showing characteristic outlines of fragments in glassy basaltic ash
(magmatic origin). (After Macdonald 1972). b) Sketch showing characteristic outlines of fragments in
hyaloclastite (phreatomagmatic origin). (After Macdonald 1972). c) Vitric tuff from the unwelded top of
an ignimbrite. The tuff consists of angular glass shards, showing typical arcuate and forked forms, bits
of pumice, and crystals of quartz and feldspar. Fine dust matrix is not shown. (Modified from Macdonald
1972 and Williams et al. 1954). d) Welded tuff from base of ignimbrite is c). Constituents as in c), but
pumice and glass shards are deformed and flattened. Fine dust matrix is not shown. (Modified from
Williams et al. 1954). e) Crystal tuff consisting of broken crystal fragments of quartz, feldspar, and mafic
minerals. Accessory rock fragments are a minor component. Fine dust matrix is not shown. (Modified
from Williams et al. 1954). f) Lithic tuff containing a variety of accessory fragments, as well as broken
crystal fragments and glass shards. (After Williams e t al. 1954).

the Archean rock record, are uncommon relative

surge
Figure 1.15. The three main types of pyroclastic
deposit based on depositional mechanism, and
their geometic relations with the underlying
topography. (After Wright et al. 1980).
to fall and flow deposits.
Characteristics of the 3 main pyroclastic types
are listed in Table 1.6. Table 1.7 describes the types
of pyroclastic flows found in recent volcanic terrains;
Table 1.8 compares summary descriptions of the var
ious types of pyroclastic flow and surge deposits.
Figure 1.16 shows the classification scheme for
pyroclastic fall deposits proposed by Wright et al.
(1980). This scheme cannot be rigorously applied to
Archean terrains, although areally well distributed
rocks in Archean volcanic belts could be distin
guished in a rough way using this scheme.
In terms of classification, genetic interpretations
can best be indicated by a prefix, for example, "air-
fall tuff", "laharic ash-lapilli tuff", "vent agglomer
ate". Purely genetic terms, such as "hyaloclastite"
and "lahars" should only be used where the deposit
is well described. One man's "lahar" may be an
other's "phreatic breccia". This confusion in terminol
ogy can only be resolved by detailed rock descrip
tions (see next section and Table 1.9 for suggestions
on what should be included in such descriptions).
CRITERIA USED TO DISTINGUISH TYPES OF
VOLCANIC FRAGMENTAL ROCKS
In terms of potential utility in mapping and explora
tion, it is not only necessary to be able to subdivide
pyroclastic rocks into lithologic types, but it is neces-

16

TABLE 1.6: SOME CHARACTERISTICS OF THE 3 MAIN PYROCLASTIC DEPOSIT TYPES (AFTER WALKER
1981).
1. Pyroclastic fall deposits show:
(a) mantle bedding
(b) good to moderate sorting
(c) more or less exponential decrease in
thickness and grain size with distance
from vent
(d) block impact structures
Exception - water-flushed ash may show (a) only,
but gives independent evidence for water flushing
(e.g. accretionary lapilli, vesicles). Fall deposits
can be sufficiently hot when they accumulate to
show primary welding near vent.
2. Pyroclastic flow deposits show:
(a) ponding in depressions, with a nearly
level top surface
(b) irregular thickness variation with distance
from vent
(c) minimal sorting or internal stratification
(d) evidence for being hot (e.g. welding,
pervasive thermal colouration)
Exception - low-aspect ratio ignimbrites include a
mantling layer which passes laterally into the
valley-pond ignimbrite.
Note 1 - ignimbrite can be defined as a pyroclastic
flow deposit made mostly from pumiceous material
(pumice, shards).
Note 2 - primary mudflows (lahars) resemble
pyroclastic flow deposits but lack (d).
sary to go one step further and speculate on the
mode of emplacement and the genesis of the rocks
in question. Some criteria that can be used to sub
divide pyroclastic rocks in the field are listed in
Table 1.9. In Table 1.10, these criteria are tabulated
in a form designed to show key characteristics of
various volcanic breccias. In many instances, a sin
gle criterion may not be diagnostic, but several cri
teria may allow for distinction between various brec
cia types. What follows is a brief discussion of how
the criteria listed in Table 1.9 can be applied. Exam
ples are also provided. Some of the factors listed in
Table 1.9 are the same factors used for rock clas
sification.
Grain Size
In addition to its use in rock classification, as shown
in Figure 1.11, grain size can be used to classify
pyroclastic rocks as to mode of emplacement. In
Figure 1.17, pyroclastic fall deposits generally have a
lower Md0 (medium grain diameter), that is, the de
posits are finer grained, and have a lower 0
(deviation from median), that is, the deposits are
better sorted, than pyroclastic flow deposits.
R.M. EASTON AND G. W. JOHNS
3. Pyroclastic surge deposits show:
(a) draping of topography
(b) rapid and irregular or periodic thickness
fluctuations
(c) general decrease in thickness and grain
size with distance from source
(d) commonly erosional base
Two main types of pyroclastic surges occur:
A - cold, damp or wet...base surges; deposits
show:
(a) good internal stratification or
cross-stratification
(b) great grain size variations between
contiguous beds
(c) evidence for dampness (e.g. accretionary
lapilli, vesicles, plastering of up-vent side
of obstacles)
(d) association with vents in low-lying or
aqueous situations, or vents containing
water (crater lakes)
B - hot, dry...surges of nuee ardente types;
deposits show:
(a) little or no internal stratification
(b) good sorting, depletion in fine or
lightweight particles (but these may occur
in an overlying fall deposit)
(c) evidence for being hot
Exception - very similar deposits underlying
ignimbrite can be produced by sedimentation from
the pyroclastic flow.
and 0 are determined in modern volcanic rocks
through sieving. Naturally, this is not practical in
Archean deposits. Mean grain size may be substi
tuted (Schmid 1981) and can be measured on the
outcrop. In addition, a qualitative estimate can be
made on the outcrop of the size range in size of
grains from the mean. Thus, with appropriate modi
fication, Figure 1.18 can be adopted for use in Ar
chean volcanic terrains. Fox (1977) has proposed
that a measurement of the ten largest fragments in
volcanic breccias can be a useful measure to trace
very rapidly lateral grain size variations in pyroclastic
breccias. In addition, lahars differ in grain- size dis
tribution compared to pyroclastic flows, in this case,
ignimbrites (Figure 1.18).
Fragment Type
Fragment type is also an important criterion for sub
dividing volcanic breccias, as it is in subdividing
tuffs (see Figure 1.12). Important features to look for
are pumice and glass shards. Abundant pumice and
glass shards indicate that the deposit is an ignimbrite
or pyroclastic flow if the deposit is poorly sorted. If
the deposit is well sorted, it is probably a fall deposit.
17
CHAPTER 1

TABLE 1.7: TYPES OF PYROCLASTIC FLOWS (MODIFIED FROM SELF 19823).

ESSENTIAL FRAGMENTS ERUPTIVE MECHANISM PYROCLASTIC FLOW DEPOSIT
VESICULATED

PUMICE FLOW- - IGNIMBRITE,

PUMICE, AND
ASH DEPOSIT

ERUPTION COLUMN
COLLAPSE

'SCORIA FLOW- - SCORIA AND

ASH DEPOSIT

Decreasing
average density
of juvenile clasts

.EXPLOSIVE-LAVA- -BLOCK AND

DEBRIS FLOW ASH DEPOSIT
(NUEE ARDENTE)

LAVA/DOME COLLAPSE

GRAVITATIONAL-LAVA- -BLOCK AND

DEBRIS FLOW ASH DEPOSIT
(NUEE ARDENTE)
NON-VESICULATED

Both pumice and shards can be observed with a
hand lens (see Photo 1.1), or under the microscope
(see Figure 1.14). Pumice in ignimbrites is often flat
tened due to post-emplacement compaction, or weld
ing, or both, and deformation (see Photo 1.1).
Other features include the presence of lithic frag
ments, the proportion of lithic to other fragments, and
their variation vertically or laterally, or both, in the
deposit. Some phreatic breccias may consist almost
entirely of lithic fragments (Photo 1.2). If crystals and
crystal fragments are abundant, then the deposit may
be an ignimbrite. Euhedral crystals may be more
abundant in lava flows and domes than in ignim
brites. The presence, or absence of a dominant frag
ment type may also be important. A monolithic brec
cia is composed of fragments which have the same
composition, mineralogy, texture, and colour. Such a
breccia consisting of glass fragments composed of
basaltic material is most likely to be a strombolian or
a hyaloclastite deposit (Photo 1.3). The presence of
broken pillow rinds in addition would favour the latter
(Photo 1.3). A heterolithic breccia, a breccia in which
the fragments have a differing composition, mineral
ogy, texture, and colour, may be a phreatic breccia
(Photo 1.2), a lahar, or a pyroclastic flow. If pumice is
abundant, the latter is more likely. If there is no one
dominant fragment type, the breccia is most likely to
be a lahar (Fisher 1982b; Photo 1.2).
Fragment Shape
Phreatic and phreatomagmatic eruptions produce an
gular fragments (Photo 1.3). Rounded fragments may
indicate pyroclastic flow deposits (Photo 1.2), or re
deposition. The variations in fragment shape are also

18
 RM EASTON AND G. W. JOHNS

TABLE 1.8: SUMMARY DESCRIPTIONS OF TYPES OF PYROCLASTIC FLOW AND SURGE DEPOSITS
(MODIFIED FROM SELF 1982a).
Deposit Description
FLOW
Ignimbrite Pumice Unsorted ash deposits containing variable amounts of rounded salic pumice
and Ash lapilli and blocks up to 1 m in diameter. The pumice fragments are generally
reversely graded, whereas the lithic clasts show normal grading.
The coarser smaller volume deposits usually form valley infills, whereas the
larger volume deposits may form large ignimbrite sheets. They may show 1 or
more zones of welding.
Scoria and Ash Topographically controlled, unsorted ash deposits containing basalt to andesite
vesicular lapilli and scoriaceous ropey surfaced clasts up to 1 m in diameter. In
some circumstances, they may contain large non-vesicular cognate lithic clasts.
Block and Ash Topographically controlled, unsorted ash deposit containing large, generally
non-vesicular, jointed, cognate lithic blocks which can exceed 5 m in diameter.
The deposits are usually reversely graded.
SURGE

Base Surge Stratified and laminated deposits containing juvenile vesiculated fragments
ranging from pumice to non-vesiculated cognate lithic clasts, ash, and crystals
with occassional accessory lithics (larger ballistic ones may show bomb sags
near-vent) and deposits produced in some phreatic eruptions which are
composed totally of accessory lithics. Juvenile fragments are usually OO cm in
diameter due to the high fragmentation caused by the water/magma
interaction. Deposits show unidirectional bedforms. Generally, they are
associated with maar volcanoes and tuff rings. When basaltic in composition,
they are usually altered to palagonite.
Ground Surge Generally -d m thick; composed of ash, juvenile vesiculated fragments,
crystals, and lithics in varying proportions depending on the parent pyroclastic
flow (or constituents in the eruption column in the case of those not associated
with a pyroclastic flow). Typically enriched in denser components (less well
vesiculate juvenile fragments, crystals, and lithics) compared to parent flow.
Again they show unidirectional bedforms.
Ash Cloud Surge Thin, stratified ash deposits found at the top of the flow units of pyroclastic
flows. They show unidirectional bedforms, pinch and swell structures and may
occur as discrete separated lenses. Composed of ash sized material;
proportions of components vary depending on the parent pyroclastic flow.

useful in distinguishing between pyroclastic deposits, loclastic breccias. Fall deposits are commonly well
as are shown in Figure 1.14 and Photo 1.3. sorted.

Welding
Welding is mainly present in pyroclastic flows
(ignimbrites), and can occur in both subaqueous and
subaerial pyroclastic flows. In ignimbrites in which
welding is fully developed, three characteristic zones
are present. These are dense, partial and incipient,
and no welding (Smith 1960). Welding has been
reported in some near-vent, pyroclastic surge depos
its (Wright et al. 1980).
Sorting
As seen in the section on grain size and Figure 1.17,
the rock names are an expression of both fragment
sorting and size. Poorly sorted deposits are generally
pyroclastic flows, lahars, and autoclastic and al
Bedding/Stratification
Bedding thickness terms applicable to tuffs are listed
in Table 1.11. For coarse breccias, no uniform terms
exist to describe the stratification of large-scale bed
ding. Stratification does occur in some pyroclastic
flows and lahars, and may be more prominent in the
upper part of the deposit (see Photos 1.1 and 1.2).
Matrix
The nature of the matrix may vary considerably be
tween volcanic breccias (Photo 1.3). The same fac
tors used to describe the entire deposit also apply to
the matrix, the mean of and range in grain size,
fragment type, and shape and sorting. Is the deposit
matrix- or fragment-supported?

19
CHAPTER 1

100 l
SURTSEYAN l PHREATOPLINIAN
l " ULTRA- TABLE 1.9: CRITERIA FOR SUBDIVIDING
I PLINIAN
PYROCLASTIC ROCKS.
GRAIN SIZE - mean vs. range
50-
i0 S PLINIAN '
/l 7 FRAGMENT TYPE - glass pumice
S shards
STROMBOLIAN^^-'
HAWAIIAN _^-\—-''~\ SUB-PLINIAN
- lithic fragments
- crystals
0.05 5 500 50000 - dominant fragment type
D km 2 (if any)
FRAGMENT SHAPE
WELDING
Figure 1.16. Classification scheme of pyroclastic SORTING (may be affected by the depositional
fall deposits (after Wright et a/. 1980 and environment)
Walker 1973). F is weight percentage of de BEDDING/STRATIFICATION
posit finer than 1 mm on the axis of dispersal MATRIX - composition, size, proportion
where it is crossed by the 0.1 T max isopach, EXTENT OF DEPOSIT/RELATION TO ADJACENT
where T = thickness. D is the area enclosed ROCKS
by the 0.1 T max isopach. This scheme is not
readily adaptable to Archean terrains, although
widespread deposits, if not reworked, are prob
ably the result of Plinian or Ultra-Plinian erup
tions.
TABLE 1.10: SELECTED CHARACTERISTICS OF SOME COMMON BRECCIA TYPES.
-^>I2o MENT
PE
FRAG MENT
Sl- APE
FRAG ABUNDA MCE STRATIFIC 5 SORT ING WEL DING

Esacsecntz
esi,alory,
BRECCIA TYPE ~c
0 1
3
Monolithic Haccidental E a. g
Unstratif ed •o
T3
3 TJ
1
V
o
0) -o
1 T3 XI

s O"
1
0)
K |
S 2
tt LJ z I

AUTO CLASTIC
FLOW
BRECCIAS
BRECCIA
x x x -*
x X
x x *— -X
CRUMBLE BRECCIA
x x x x
—* x
x x x *—

PYROC LASTIC BRECCIAS

STROM BOLIAN
x x x X x x
VULCANIAN
BRECCIA x x X x x x
SUBAERIAL
ASH-FLOWS
x- x- -* x -* x x- X -x —*x
x X x x *— x ^—

SUBAQUEOUS
ASH- FLOWS
x- x- -* x -* x X" - x X x x x x -* x

PHREATOMAGMATIC X" x- -* x h4 X
x x x x x
PHREATIC
BRECCIA x x X x x x x
BASE-SURGE
DEPOSITS
x- x- ^ x -* x
x x x x x
HYALOCLASTITES
X x- 4 X x- x- x
-* x
x —* x -* x

ALLOCLASTIC BRECCIAS
x x- -) X
X x x x
EPICLA STIC BRECCIAS ~x x-
X f—— i-* X x- x- -x -x
-* x
x -* x x *— x*—

x x-
LAHARIC

TALUS BRECCIA
x X x x x x -* X

x - grade into - commonly presenl x - rare to uncommon

20
 P.M. EASTON AND G. W. JOHNS

T7 field of ^
pyroclastic
flow deposits

x \x\ \\x\\ x\ xxx \x\\\\\\\\ \vx"s^

;field of pyroclastic fall deposits
X, X, \ X, \ \ X, •fX-'X \ "~. ":. \ X. \ X \ X X \ \ V X. V \ S \ \ s

4 6 Md 0
1/16 Md mm I28 2 l I/2 I/8 I/32 I/I28 I/5I2
Diameter in mm

Figure 1.17. Ma'0/0 (Median grain diameter vs.

deviation in grain diameter) plot showing the Figure 1.18. Grain-size distribution in ash-flows
fields of pyroclastic fall and flow deposits and lahars (after Schmincke 1974).
(after Walker 1971, 1973; Wright et al. 1980).
Note that pyroclastic flow deposits are coarse
(greater Mcty) and less sorted (greater 0j than
pyroclastic fall deposits. Mean grain diameter
(as measured on outcrop) and range in grain To cope with these problems, facies models de
size (as measured on outcrop) can be used for veloped for more youthful volcanic terrains, must be
Archean pyroclastic rocks, where MdQ/ti can investigated, and then these models should be ap
not be readily measured (Schmid 1981; Fox plied to Archean volcanic sequences. Facies analysis
1977; see text for further discussion). of modern and deformed volcanic rocks is still in its
infancy, and facies analysis in the Archean is just
beginning. In this section, the authors will review
what is known about volcanic facies, and suggest
how this knowledge may be applied to Archean vol
Facies and Extent of Deposit canic terrains. In the final section, the authors will
present some case examples of how volcanic facies
Facies is important because distance from the vent have been interpreted in the Superior Province of
will affect the degree of sorting, the size distribution, Ontario and Quebec, and how this information can be
and so on. In addition, the relationship of the deposit of use in mineral exploration.
in question to other rocks is important. For example, Firstly, a word of caution must be given. Facies
is the deposit part of a flow unit, or is it a flow unit in
itself? (see Figures 1.3 and 1.5). analysis involves an examination of the lateral and
vertical changes in a volcanic sequence, or a vol
canic deposit. As such, it requires a regional exami
Summary nation of outcrops, as well as detailed outcrop study.
The application of these criteria is illustrated in Fig Hence, it is not always possible to determine the
ure 1.19, which compares some of the more common volcanic facies for an area by examining only a few
breccia types. In Table 1.12, these criteria are used outcrops of limited areal extent. In addition, we must
to distinguish volcanic versus epiclastic rocks. face the basic problem of dealing with deformed
Many pyroclastic breccias can be subdivided on volcanic rocks, namely: deformation and metamor
the basis of origin and mode of emplacement by phism destroy delicate textures and structures; and
using the relatively straightforward criteria given analytical techniques used with unconsolidated or
above and those listed in Table 1.9. This information weakly consolidated deposits cannot be used with
can then be applied to the development of a facies metamorphosed pyroclastic deposits. Despite these
model for the area in question. This is elaborated on difficulties, knowledge of volcanic facies is critical
in the next section. when it comes to the interpretation of Archean vol
canic terrains.
VOLCANIC FACIES
Volcanic Facies
Introduction
Scale is an important consideration in regard to vol
One of the difficulties faced by geologists working in canic facies. The authors would apply different cri
Archean (and other Precambrian) volcanic terrains is teria in trying to understand the facies setting of a
the interpretation of the highly varied and discontinu large volcanic feature, such as a shield volcano
ous outcrops of volcanic rocks present in these re (Figure 1.20), a composite volcano (Figure 1.20), or a
gions. The original constructional volcanic landform smaller volcanic edifice such as a cinder cone ver
has long since been destroyed by erosion, and the sus a particular volcanic unit or units (for example,
normal rules applied to interpreting layered se Figures 1.3 and 1.5). We will start by examining
quences of rocks have only limited application in large-scale facies variations, and proceed to deposit-
volcanic terrains, as discussed by Trowell and Johns scale facies variations.
(Chapter 3, this volume), and Trowell (Chapter 2, this
volume).

21
CHAPTER 1

Photo 1.2. Pyroclastic breccias, a) Lahar, Back River Complex, Northwest Territories, Archean age. May be
derived from flow front of a lava dome. Dark fragments are epiclastic sediments. Most fragments are
lithologically similar to nearby rhyolite lava domes and flows, b) Phreatic breccia, Noranda, Quebec,
Archean age. Note angular fragment size, and overall monolithic character of this outcrop, c)
"Block-and-ash" flow sandwiched between an upper and lower air-fall pumice layer. Hammer is in
f'block-and-ash" flow. Older deposits of Mount St. Helens volcano, Washington, U.S.A. d) Subaqueous
pyroclastic flow, lower massive unit is shown, Wawa, Ontario, Archean in age.

22
 P.M. EASTON AND G.W. JOHNS

Photo 1.3. Flow breccias and hyaloclastics. a) Broken pillow fragment in hyaloclastite matrix, Rouyn-
Noranda, Quebec, Archean in age. b) Disrupted rhyolite flow. Near border between massive and breccia
facies as shown in Figure 1.9. Rouyn-Noranda, Quebec, Archean in age. c) Flow breccia with matrix of
epiclastic, weakly laminated sediment. Back River Complex, Northwest Territories, Archean in age. d)
Basal flow breccia, consisting of hyaloclastite matrix and angular fragments. Large clast by hammer is a
clast from an adjacent breccia unit (top of underlying flows). Yellowknife, Northwest Territories, Archean
in age.

Volcanic Facies on a Regional Scale An example of
facies variation on a regional scale is illustrated in
Figure 1.21, a schematic diagram of volcanic rock
distribution in the Lesser Antilles volcanic arc in the
Caribbean. A prevailing westerly wind direction
causes considerable lithologic differences to exist
between the western and the eastern basins. Air-fall
and turbidity current-deposited rocks predominate in
the east, debris flow and pyroclastic flow deposits
dominate in the west. Similar sorts of facies variation
might be expected in Archean basinal environments.
Additional modern examples are described in Si-
gurdsson (1982).
Composite Volcano As discussed in the previous
section and in Ayres (1982, 1983), an island type
setting is a reasonable assumption to explain Ar
chean late volcanic sequences. Such volcanic se
quences will develop composite, central vent volca
noes, such as are shown in Figure 1.22. Volcanic
rocks of any age, or for that matter, any edifice, can
be divided into 4 volcanic facies as shown in Figure
1.22:
1. central or vent facies
2. proximal facies
3. distal facies
4. epiclastic facies
The characteristics of each of these volcanic
facies will vary depending on the type of volcanic
edifice in question. In the Archean, the two most
common are probably the composite volcano shown
in Figure 1.22 and the shield volcano (Figure 1.23).
The characteristics of each facies zone for a central
vent volcano are listed in Table 1.13. Important fea
tures of each volcanic facies are described below.
Central or Vent Facies (0.5 to 2 km from vent) Rocks
from this facies are primarily depositional in origin,
and may consist of the deposit types listed in Table

23
CHAPTER l

PROXIMAL FACIES:
DEBRIS FLOW (lahar) PYROCLASTIC FLOW FLOW BRECCIA
.fluvial sedimentary
' structures uniform layering -^massive lava
crossbedding variable grain size .matrix:
r epiclastic,
variable grain size locally sorted,
coarse clasts stratified
coarser clasts are common
near base "^ sub-angular clasts,
fine ash layers monolithic
bread crust bomb vesicular fragments
layering variable clast -supported
breccia
lensoidal

coarser clasts
near base fine ash and pumice massive lava
^non-eroded base mantle topography
^fluvial volcanic at base
sediments
(preceeded
mud flow)

VENT FACIES:
PHREATIC BRECCIA AGGLOMERATE TALUS BRECCIA
(heterolithic breccia)

angular bomb sag pillowed

fragments stratified, cinders flow
fragment
lithic fragments
sand,
breccia, silt matrix
mainly layer of bombs, breccia
source rock partly agglomerate fragment
altered
fragment
unbrecciated sharp base
source rock underlying breccia

Figure 1.19. Schematic diagrams showing characteristics of some common volcanic fragmental rocks.

1.13. The important ones, with respect to massive
sulphides, are dikes, sills and domes, and the crum
ble breccias or talus from domes. Phreatic breccias
associated with the vent, or with the domes are also
potential zones for mineralization. Salient features of
phreatic breccias are given in Table 1.10 and Figure
1.19. The two most prevalent aspects of central or
vent facies are their bewildering structural and
lithologic diversity.
Proximal Facies (2 to 15 km from the vent) Rocks
within this zone may be the result of primary deposi
tion or the result of secondary transport and re
deposition. The resultant deposit may be mapped as
volcanic or sedimentary depending on the bias of the
observer, the distance travelled, and the degree of
reworking. Rocks from this facies which are deposi
tional in origin are domes and flows with their atten
dant breccias, air-fall tephra, pyroclastic flow depos
its, and subaqueous pyroclastic flow deposits. Re-
deposited rocks include debris flows (lahars), tur-
bidites, and subaqueous pyroclastic flows. Debris
avalanche and other large-scale slump deposits may
also be expected. Subaqueous pyroclastic flows, and
lava flows and domes and their attendant breccias
have the greatest mineral potential.
Distal Facies (5 to 15km from the vent) Distal fa
cies rocks can often be delineated by their greater
lateral continuity. As in the proximal facies, these
rocks may be the result of deposition, or, erosion and
redeposition. Again, they may be mapped as volcanic
or sedimentary depending on transport distance and
bias. Distal facies rocks tend to be finer grained,
better sorted, and more distinctly bedded than rocks
found in the proximal facies.
Epiclastic Facies (0.5 to 15km from vent) Epiclastic
sediments also form in an active volcanic environ
ment, and are intercalated with the volcanic deposits.
These rocks include sheetwash fans related to flash-
floods in rapidly eroding volcanic terrains; perched
ponds, volcanic moats, and other lacustrine deposits,
and talus and landslide deposits. As such, they can
be classified as a separate facies. Their metallogenic

24
 R.M. EASTON AND G. W. JOHNS

TABLE 1.11: BEDDING THICKNESS TERMS. STRATO-VOLCANO

COMPOUND VOLCANO
COMPLEX VOLCANO COMPOSITE VOLCANO
Thinly laminated ^.3 cm
Thickly laminated 0.3 to 1 cm
Very thinly bedded 1 to 3 cm
Thinly bedded 3 to 10 cm
Medium bedded 10 to 30 cm
Thickly bedded 30 to 100 cm (1 m)
Very thickly bedded 1 m to 3 m SHIELD VOLCANO
Extremely thickly bedded ^ m

A*^ o-o-o- o- o
j.0
*t-^.
^ ^ ^ ^
•PYROCLASTIC CONES'

TABLE 1.12: FIELD CRITERIA USED IN THE Figure 1.20. Types of volcanoes. Schematic pro
GREENSCHIST FACIES, TO DISTINGUISH files are vertically exaggerated by 2 to 1
BETWEEN FELSIC METATUFF, PORPHYRITIC (shaded) and 4 to 1 (dark). Relative sizes are
FELSIC FLOWS, AND POORLY BEDDED, only approximate. (After Simkin et at. 1981).
MUSCOVITE-BEARING METAGREYWACKE. MOST
OF THESE CRITERIA ARE MORE EASILY
RECOGNIZED ON WEATHERED SURFACES
THAN ON FRESH SURFACES (AFTER AYRES Caribbean
1969).___________________________ aoo-FT7!
ash-fall
FELSIC METATUFF
100- dispersed ash
pyroclastic gravity
1. Abundant sand-size, lenticular, felsic E53 flow deposits
fragments lavas and domes
Atlantic
Forearc
2. Rare sand-size, lenticular, mafic fragments 80-
*1 pyroclastic flows Region
3. Abundant angular, sand-size plagioclase
4. Rare sand-size quartz
5. Rare felsic metavolcanic lapilli
6. Abundant, wispy, very fine grained,
quartz - plagioclase - white mica matrix

PORPHYRITIC FELSIC FLOWS

1. Sand-size rock fragments absent

2. Rare metavolcanic lapilli
3. Subhedral to euhedral, locally oriented,
fine- to medium-grained, plagioclase
phenocrysts
4. Rare fine- to medium-grained, quartz
phenocrysts
5. Abundant very fine grained, locally
aphanitic, quartz-plagioclase-white mica
groundmass
MUSCOVITE-BEARING METAGREYWACKE

1. Rare visible, sand-size rock fragments

2. Abundant sand-size quartz
3. Abundant angular to rounded, sand-size
plagioclase
4. Sand-size quartz and plagioclase appear
to form an intact to slightly disrupted
framework; visible matrix is rare
5. Rare quartz, metachert, and felsic and Figure 1.21. Pyroclastic rock distribution in the
mafic metavolcanic pebbles western and the eastern Caribbean. (Adapted
from Sigurdsson et al. 1980).

25
CHAPTER 1

CENTRAL ZONE-

PROXIMAL ZONE epiclastic

rocks
dome
DISTAL ZONE dikes
.sills
mixture of lava
and pyroclastic flows
and air-fall deposits

epiclastic
rocks

volcanic' sediments subvolcanic

air-fall deposits," ' intrusions
debris flows,
pyroclastic flows POTENTIAL ZONE FOR COLLAPSE FEATURES^

Figure 1.22. Principal facies variation in volcanic rocks related to a large central vent composite volcano.
Central zone is also known as the vent facies. Epiclastic facies can occur in all three zones. Products of
each zone/facies are listed in Table 1.13. (Modified from Williams and McBirney 1979).

significance may be to serve as a caprock or an
aquifer for hydrothermal systems, and thus may be
closely associated with ore in some instances.
Mafic Shield Volcano Shield volcanoes are probably
the best analogy for the large, mafic volcanic piles
that constitute the bulk of the volcanic material pre
sent in Archean "greenstone belts". There is prob
ably not a great deal of difference between the
volcanic facies present in a subaerial (Figure 1.23a)
and a submarine shield (Figure 1.23b). Important fea
tures of each facies are described below.
Central or Vent Facies (0.5 to 2km from the
Vent) Rocks from this facies are primarily deposi
tional in origin, and may consist of the deposit types
listed in Table 1.14. The important ones with respect
to mineralization are found in the vent complex, an
area of collapse features, talus cones, minor sub
aerial and submarine shields. Phreatic breccias and
phreatomagmatic deposits can also be expected in
this facies.
Proximal Facies (2 to 15km from the vent) Rocks
within this zone are mainly the result of primary
deposition. In the Archean, subaerial lavas would be
for the most part eroded, so pillow lavas will be the
main rock type in this setting. Massive lavas will be
abundant near the vent, with the pillowed lavas in
creasing in abundance as distance from the vent
increases. Flow thickness will generally decrease
away from the vent. Subaqueous debris flows and
tuffs will also be present. If another sediment source
region is present adjacent to the shield volcano,
wackes and other epiclastic rocks will also occur in
the upper part of the volcanic sequence. Shear
zones, possibly the remnant of syn-volcanic faults,
may also form in this zone.
Distal Facies (5 to 15km from the vent) As in the
proximal facies, pillow lavas will be the dominant
rock type, but massive lava will be uncommon, and
both tube-fed and isolated pillow types will be pre
sent. Flow breccia and pillow breccia will also be
more abundant. Tuffaceous material will be more
common, and landslide and debris avalanche depos
its may also be present. Wackes and other epiclastic
rocks can be expected to be interdigitated with the
distal flow rocks and breccias.
Volcanic Facies on a Deposit Scale Volcanic facies
regimes can also be recognized in deposits from a
single eruption, either as lateral or vertical scale
variations or both. As shown in Figure 1.24, the
facies variations are the result of a change in trans
port mechanism and depositional mechanism with
increasing distance from the vent. Figure 1.24 applies
to both pyroclastic and epiclastic deposits. Fisher
(1982a, 1982b) and Fisher and Schmincke (1984)
illustrated in greater detail, the nature of the flow
mechanisms involved. Deposit scale variations can
also occur in both mafic and felsic composition
rocks, as outlined below.
Felsic and Intermediate Pyroclastic Flows An exam
ple of facies variation in a deposit from a single
eruptive event is shown in Figure 1.3, which depicts
a subaerial pyroclastic flow. The left-hand side of

26
 RM EASTON AND G. W. JOHNS

CENTRAL ZONE
PROXIMAL ZONE-
DISTAL ZONE
pahoehoe and aa flows
epiclastic rocks
mixture of phreatic ash, phreatomagmatic ash,
flow breccias, isolated pillows, and pillow breccia

landslide deposits

^^^
CX^
cZ?^
** subvolcanic
intrusions
^ - -V'-v- "'"^rr—^-^rr^TTI'Tx - xN T^T^^----^^^, , v u 'i^^\T:^7J~----...^|*' 4 , iT w-* *A V
isolated and tube-fed' pillows,\,'';-\-;M'7s ' ^,X\ ^(,x V massive lava', megapillowsTj*. '*-^* ^ * 4 ,T 7.

X-V^J^M^^^ICQ isi-7^frTc^iy^^r" e"t' ' ^^i^r^v^^v^'1 ^'^ iM^vN *^^4 ^ * * ^ ^ y JT"

pillow breccia, thin flows , \^S~^^L( -VV^VixT^C? x~ tube ~ fed Pi"ows,thick^ flows^ A ^^ " ^ \ *'f'-x/

phreatomagmatic
hyalotiiff

phreatic and
phreatomagmatic breccia

tube-fed pillows
pillow breccias^ i;
minor massive lavas
epiclastic rocks

subvolcanic
intrusions

Figure 1.23. Principal facies variation in volcanic rocks related to a large shield volcano. Central zone is
also known as the vent facies. Upper half shows a subaerial and a submarine volcano, lower half shows
a subaerial and a submarine volcano, lower half shows a submarine volcano. Model is based on
knowledge of Hawaiian-type shield volcanoes. Note, vertical exaggeration 2X, horizontal shortening, 5X.
Products of each zone are listed in Table L 14. Compare with Figure 1.22.

27
CHAPTER 1

TABLE 1.13: PRODUCTS ASSOCIATED WITH TABLE 1.14: PRODUCTS ASSOCIATED WITH
THE 4 MAIN VOLCANIC FACIES OF A THE MAIN VOLCANIC FACIES OF A MAFIC
CENTRAL VENT, COMPOSITE VOLCANO, AS SHIELD VOLCANO, AS SHOWN IN FIGURE
SHOWN IN FIGURE 1.22. (ADAPTED FROM 1.23.__________________________
WILLIAMS AND MCBIRNEY 1979).———————-
CENTRAL OR VENT FACIES
CENTRAL OR VENT FACIES (within 0.5 to 2 km of vent)
(within 0.5 to 2 km vent)
Depositional
- dikes, sills, subvolcanic
Depositional
- dikes, sills, and domes intrusions
- co-ignimbrite lag deposits - hydrothermal alteration related
- phreatomagmatic deposits to subvolcanic intrusions
________- talus breccia, megabreccia - alloclastic breccias
- phreatomagmatic and phreatic
PROXIMAL FACIES deposits
(up to 2 to 15 km from vent) - talus breccia, fault breccia,
caldera fill
Depositional
- air-fall deposits (tuffs) - thick flows in pit craters
- pyroclastic flows ________(subaerial only)_________
- subaqueous pyroclastic flows
- lava flows and domes PROXIMAL FACIES
Redeposited Recognizable as - lahars (up to 2 to 15 km from vent)
volcanic - pyroclastic
flows Depositional - air-fall deposits (tuffs)
- tuffs - thick-bedded lava flows, mainly
massive lava, minor pillow lava
Recognizable as - debris flows and pillow breccias, tube-fed
volcanic - arenites pillows
________sediments____- wackes^^^
Redeposited - Recognizable - subaqueous
DISTAL FACIES as volcanic debris flows
(more than 5 to 15 km from vent) - tuffs
-' Recognizable - debris flows
Depositional - air-fall deposits (tuffs) as volcanic - wackes
- pyroclastic flows sediments
- subaqueous pyroclastic flows
- lava flows DISTAL FACIES
Redeposited - Recognizable - lahars (more than 5 to 15 km from vent)
as volcanic - pyroclastic
flows Redeposited - air-fall deposits (tuffs)
- tuffs - thin-bedded tube-fed pillowed
lava and pillow breccia, isolated
- Recognizable - debris flows pillows
as volcanic - arenites - landslide and debris avalanche
sediments - wackes deposits
- siltstones
Recognizable as - subaqueous
EPICLASTIC FACIES volcanic debris flows
- tuffs
Redeposited - talus - Recognizable - debris flows
- debris flows as sedimentary - wackes
sediments - in crater lakes - siltstones and
(active, mudstones
extinct)
- perched ponds
- alluvial fans

28
 P.M. EASTON AND G. W. JOHNS

SOURCE:
volcanic slopes,
deltas,
narrow shelves;
active faults

TURBIDIfY CURRENTS:
laminar, ijcjuilied, or
fluid i zed u n d er f f o w s
with turbulent
t

F/gure r.24. Conditions of initiation and types of subaqueous transport. Range of subaqueous transport
influences the type of deposits found in volcanic facies regime. Scale of figure ranges from Ws of m to
100s of km. (After Fisher 1982b).

ERUPTIVE EVENTS DEPOSITS

mudstone

turbidity currents,
fine ash,
minor pumice lapilli

pumice lapilli,
fine crystals

dense fragments,
large crystal
fragments

pumice fragments
in ash and
crystal matrix

lithic and
pumice fragments
fine ash

Figure 1.25. Schematic drawings of a submarine eruption producing subaqueous pyroclastic Hows, and
subsequent appearance of the deposits of such an eruption. A. Beginning of eruption. Vesiculating
magma is erupted into sea water. Some fine ash may be deposited near the vent. B. Climax of eruption.
Submarine columm carries much debris high into suspension. Sorting splits the debris into various
fractions. Buoyant pumice floats; dense fragments, large crystals, and compact pumice lapilli settle
around the vent, and are transported laterally in a subaqueous pyroclastic flow. Most ash remains in
suspension. C. End of eruption. Steady pyroclastic flow ceases as amount of erupted material decreases
and is replaced by turbidity current flow. Later turbidity currents contain finer and less dense has
settled from suspension. As shown in the right-hand side of the figure, an important characteristic of
subaqueous pyroclastic deposits are their doubly graded nature. Each bed is graded, and the beds at
the base of the sequence contain coarser and denser ash than the beds at the top of the sequence
(Modified from Fiske and Matsuda 1964 and Fiske 1969).

29
CHAPTER 1

PROXIMAL DISTAL
lava domes, lapilli-tuff, tuff,
lava flows, coarse tuff-breccia, doubly-graded beds,
/minor breccia f minor lava flows turbidites \

fine tuff -breccia, lapilli-tuff, tuff

Figure 1.26. Lateral facies variation in subaqueous pyroclastic flows. (Based on data from Fiske 1963, Fiske
and Matsuda 1964).

Figure 1.27. Structure

Tuff sequences of
subaqueous pyroclastic
flows. See text for
details. (Modified from
Tasse e t at. 1978 and
--- Dimroth and Rocheleau
1979).

Debris Flow Deposits Turbidity Flow Deposits

IVa
Tuff

Lapilli
and
Ash
O

Figure 1.3 shows the model developed by Sparks et
a/. (1973) for pyroclastic flows, and the right-hand
side shows a section through the central part of the
deposit.
More relevant to the Archean would be a model
for subaqueous pyroclastic flows, such as the one
developed by Fiske and Matsuda (1964). Key fea
tures of their model are illustrated in Figure 1.25, and
include a massive lower part, which fines upward in
terms of non-vesicular material, and an upper lami
nated part, which also fines upward. Reverse grading
is common in some beds due to flotation of pumice
(vesicular). The two units are often referred to as a
doubly graded sequence, and they have been recog
nized in the Archean, for example, in the Skead
Group as discussed in the next section. With increas
ing distance from the vent, bedding becomes more
prominent, and the upper laminated deposits are
more commonly emplaced as turbidity currents
(Figures 1.25, 1.26). Smaller eruptive events would
mainly form graded, laminated deposits in the proxi
mal environment. In a larger eruption, graded, lami
nated deposits would occur farther from the vent
(that is, in a more distal environment).
As discussed by Dimroth and Rocheleau (1979)
and Tasse et a/. (1978), subaqueous pyroclastic
flows commonly show diagnostic structure se
quences (Figure 1.27; Walker 1976). Walker (1976)
interpreted sequence l (disorganized bed) as debris
flow deposits, and structures III and IV (normal grad
ed bedding) as turbidites. Reversed graded bedding
is the result of shearing during deposition. Proximal-
distal changes noted by Tasse et at. (1978) are as
follows:

30
 P.M. EASTON AND G. W. JOHNS

1. Bed thickness and grain size decrease away

Figure 1.28. Facies model for subaqueous mafic
flows on the flank of a shield volcano, showing
proximal massive facies and distal pillowed fa
cies. Cross sections of this facies regime are
shown in Figure 1.5. (Modified from Dimroth
and Rocheleau 1979).
from the source.
2. The number of disorganized beds and beds with
reverse grading decreases away from the source.
3. The number of beds with normal grading in
creases away from the source.
4. The thickness of stratified upper divisions of
beds increases away from the source.
Mafic Flows A facies model for subaqueous mafic
flows on the flank of shield volcano is shown in
Figure 1.28 and is based on the work of Dimroth et
al. (1978, 1979) and Dimroth and Rocheleau (1979).
Near the vent, high flow rates result in the extrusion
of mainly massive lava. As distance from the vent
increases, large channel systems develop, and are
akin to tube-fed subaerial flows (Swanson 1973).
With a further increase in distance from the vent, the
lava channel forms tube-fed pillow lavas. Cross sec
tions of such a flow system are shown in Figure 1.5.
Environment Indicators One important aspect in the
assignment of volcanic facies, and in the application
of the appropriate facies model is the determination
of the depositional environment, that is, subaerial or
subaqueous, and if the latter, what water depth is
involved. If this knowledge is available, constraints
can be placed not only on the type of deposits to be
expected in a particular facies, but also on the erup
tive processes that may have produced those depos
its. Figure 1.29 is an illustration of the various envi
ronmental indicators that can be used in the field,
and the constraints they place on the setting of
volcanic activity.

SUBAERIAL
PYROCLASTIC DEBRIS:
FLOWS

: ond ;i
PYROCLASTIC
FALL BRECCIAS

VARIOLES*
SUBAQUEOUS
{non-1 mm isc i bte,
t*P*);M
VARIOLES
; immiscible!

Figure 1.29. Environment of formation of volcanic breccias and specific lava flow features (water depth
figures only approximate).

31
CHAPTER 1
Figure 1.30. Distribution of the pyroclastic rocks of the Skead Group in southern Bryce and Tudhope
Townships (from Figure 13 in Johns 1983). See Figure 1.31 for distribution of volcanic facies.
Summary The various models that exist for volcanic
regimes that seem most applicable, or have been
previously applied to Archean volcanic rocks have
been outlined in this section. Volcanic facies analysis
in Archean terrains is still in its infancy, and improve
ments will undoubtedly be made on the models pre
sented here. In the next section, the authors illustrate
the use of volcanic facies information in mapping
Archean sequences, and its role in mineral explora
tion.
CASE STUDIES
MAPPING OF PYROCLASTIC SEQUENCES AND
IDENTIFICATION OF VOLCANIC FACIES
The next two examples illustrate how the principles
outlined in the previous sections can be applied to
actual rock sequences in the Archean of the Superior
Province. In both examples, one of the authors (G.W.
Johns) has mapped a pyroclastic accumulation at a
scale of 1 inch to 1/4 mile with the Ontario Geologi
cal Survey, and subsequently has assigned the
pyroclastic rocks to a volcanic facies setting.
Example 1 - Skead Group, Abitibi Subprovince
The Skead Group pyroclastic rocks lie within the
Abitibi Subprovince in the vicinity of Elk Lake (Bryce
32
Cobalt Group,
Gowganda Formation
Tuff, Lapilli-Tuff,
Lapilli Ash Tuff
Tuff-Breccia,
Pyroclastic Breccia
Pyroclastic Breccia,
Tuff-Breccia
Quartz-Feldspar
Porphyry (subvolcanic)
Mafic Flows
geological contact
fault
Township) and have been described by Johns
(1983). Figure 1.30 is a map of the generalized dis
tribution of the pyroclastic rocks. Figure 1.31 is an
interpretation of the facies distribution of the rocks
shown in Figure 1.30. Both figures are based on
information collected in 1980 (Johns e t a/. 1981). The
geological units shown in Figure 1.30 are based on
the major pyroclastic type present in each unit. Finer
or coarser material may also be present in associ
ation with the main rock type.
All the pyroclastic rocks shown within the facies
boundaries (Figure 1.31) are genetically related, as
many outcrops contain multiple pyroclastic rock types
gradational into one another. The coarser, unsorted
pyroclastic rocks grade into finer unsorted pyroclastic
rocks. Sharp contacts have been observed and finer
grained beds pinch out along strike.
The greatest abundance of coarse pyroclastic
rocks is in the vicinity of Heather Lake (Figure 1.30)
where a 700 m thick amoeboid-shaped deposit com
posed of predominantly pyroclastic breccia is 2500 m
long and grades laterally and vertically into predomi
nantly tuff-breccia. These pyroclastic breccias are
poorly to moderately sorted and include both clast-
and matrix- supported parts. Mafic and intermediate
to felsic clasts are round to angular and many have
bleached reaction rims. Essential clasts include

T^LO ZrZ miles~-EZ 1/2 ^^^^^^. 1Z
Figure 1.31. Distribution of volcanic facies of the pyroclastic rocks of the Skead Group in southern Bryce
and Tudhope Townships.
clasts consisting of quartz-feldspar porphyry, similar
to the body stratigraphically below the breccias
(Figure 1.30). Accessory material includes lithic
clasts of tuff, lapilli-tuff, and lapilli-tuff-breccia. The
matrix composed of lithic and crystal ash and lapilli,
is generally more mafic in composition than the
clasts.
In the immediate vicinity of Heather Lake, the
pyroclastic breccia is very coarse, angular, very poor
ly sorted, unbedded, and heterolithic. Away from
Heather Lake, the pyroclastic breccia deposit be
comes finer, contains more subangular fragments,
and forms thick indistinct beds. This assemblage
also contains fine epiclastic material gradational into
the pyroclastic breccia. Sharp contacts between the
individual pyroclastic deposits are not common.
These very coarse, chaotic pyroclastic breccias
are vent facies deposits (Figure 1.31). The lack of
stratification is the result of deposition from phreatic
eruptions and rapid, direct deposition. The heat
source giving rise to these phreatic explosions was
the quartz-feldspar porphyry stratigraphically below
the deposit.
Tuff-breccia, composed of a massive, thick-
bedded, chaotic assemblage laterally interdigitates
with and immediately overlies the pyroclastic breccia.
These rocks are poorly sorted, matrix-supported, and
RM EASTON AND G.W. JOHNS
Cobalt Group,
Gowganda
Formation
Quartz-Feldspar
Porphyry
:: (subvolcanic)
Mafic Flows
Vent Facies
Proximal Facies
EE Distal Facies
contain subangular to subround clasts of feldspar-
phyric tuff, hornblende porphyry, pumice, vesiculated
mafic material, and ribbed mafic bombs. The matrix
is composed of euhedral and broken crystal ash and
lithic ash and lapilli.
These deposits are composed of both essential
and accessory clasts. These rocks were deposited in
the near proximal volcanic environment (Figure 1.31).
The massive poorly to indistinct bedding and the
gradation with other pyroclastic deposits was due to
rapid, continuous deposition from phreatic magmatic
eruption of varying magnitude. These deposits were
emplaced as subaqueous debris flows as is shown in
Figure 1.25b.
Lapilli-tuff is interbedded or is in gradational con
tact with the coarser pryroclastic rocks. Lithic clasts
are rounded to subrounded feldspar porphyry, pum
ice, and mafic volcanic material. The matrix is com
posed of ash-sized feldspar and pyroxene crystals,
lithic fragments, and amygdaloidal and globular al
tered glass. Lapilli-ash tuff, a chaotic assemblage of
lapilli, ash, and minor blocks is interbedded with tuff,
lapilli-tuff, and tuff-breccia.
These deposits, composed of essential and ac
cessory clasts, were emplaced in a proximal environ
ment by phreatomagmatic eruptions. Deposition was
rapid and continuous as subaqueous debris flows.
33
CHAPTER 1
OLDER UNITS BERRY RIVER FORMATION
Point Bay Group Quartz-Feldspar Porphyry
Vent Facies
Warclub Group Proximal Deposition
Distal Deposition
Snake Bay Formation
Distal Redeposition
Granitoids Epiclastic Facies
Figure 1.32. Volcanic facies of the Berry River formation, eastern Lake of the Woods. See text for further
details.
The irregularly shaped quartz-feldspar porphyry
intrusion stratigraphically below the proximal facies
deposits (Figure 1.31) has sharp contacts. Metamor
phosed fragments of the pyroclastic host rock are
found within the porphyry as incorporated blocks
which have indistinct boundaries. This intrusion is
envisaged to be, in part, a high-level magma cham
ber.
The majority of the finer pyroclastic material
northwest of Heather Lake (Figure 1.30) occurs in the
stratigraphically lower part of the sequence. These
rocks are generally fine grained and have sharper
contacts than in the southeastern part of the area.
These rocks are interpreted to occur in the distal
facies (Figure 1.31). They were emplaced as
pyroclastic flows similar to those described by Fiske
(1963). Dimroth and Rocheleau (1979) described
similar rocks from the Noranda-Rouyn area of Que
bec. Under their classification, the distal facies units
are turbidity flow deposits (see Figure 1.27). The
source area for these deposits is not known.
Figure 1.26 is an idealized cross section of the
Ohanapecosh Formation in Washington, U.S.A. (Fiske
1963), and shows some similarity with the distribution
of the pyroclastic rocks as seen in Figure 1.30. The
general model for the pyroclastic rocks in the vent or
proximal facies (Figure 1.31) may be similar to that
proposed by Fiske (1963) for the Ohanapecosh For
mation.
34
VOLCANIC FACIES
OF THE BERRY RIVER FORMATION
cs^
^ Diabase Dike
Long Bay - Lobstick Bay Area
— ~- fault
Eastern Lake of the Woods
——— lithologic contact
1 — stratigraphic contact
........ f ac i es boundary
Example 2 - Berry River formation, Wabigoon
Subprovince
The Skead Group pyroclastic rocks discussed above
are relatively undeformed, and hence are relatively
easy to interpret compared to most Archean exam
ples. It is still possible, however, to assign facies
settings to more severely deformed pyroclastic rocks
by cautiously applying similar principles. The facies
contacts may not be as precisely located, but work
ing hypotheses can be developed.
Mapping of the deformed metavolcanic rocks in
the eastern part of the Lake of the Woods has di
vided the pyroclastic rocks of the Berry River forma
tion into volcanic facies (Figure 1.32). The Berry River
formation is a 2713.9 Ma year old (Davis and Ed
wards 1982) intermediate to felsic metavolcanic com
plex consisting of quartz-feldspar porphyry and
pyroclastic rocks with minor interbedded sedimentary
rocks. The stratigraphic setting of the Berry River
formation within the western Wabigoon Subprovince
is described by Trowell and Johns (Chapter 3, this
volume). In brief, it is a predominantly pyroclastic
complex within the Warclub group of metasedimen-
tary and metavolcanic rocks.
Two ages or events of intermediate to felsic
pyroclastic volcanism appear to have built the Berry
River formation. The distal depositional and the distal
redeposition facies are the products of the older
event. The quartz-feldspar porphyry, vent facies, and
proximal deposition facies are the result of the youn
ger event.

Between the northeastern shore of Long Bay and
the diabase dike (Figure 1.32), the pyroclastic rocks
of the distal deposition facies overlie the Warclub
group with a slight unconformity. These rocks vary
from pyroclastic breccias to tuffs. Tuff and lapilli-ash
tuff predominate, with tuff-breccia the next dominant
rock type, and pyroclastic breccia the least abundant.
Clasts are felsic to intermediate in composition, are
equigranular, subrounded to subangular, and matrix-
supported. Individual units are distinct and range
from very thickly to very thinly bedded. Many of the
bedded units exhibit double-grading similar to those
shown on the right-hand side of Figure 1.25. These
beds were deposited by subaqueous debris flows,
resulting from a volcanic process similar to the one
proposed by Fiske and Matsuda (1964) and shown
on the left-hand side of Figure 1.25. Fine-grained,
thin-bedded metasediments are found interbedded
with the pyroclastic rocks. The source of these
pyroclastic rocks was to the east, perhaps in the area
where the Kishquabik Lake Stock is presently lo
cated.
Associated with these distal deposited
pyroclastic rocks are the laterally interdigitated rocks
classed as distal redeposited. These overlie and are
infolded with the Warclub group. Generally, these
rocks are finer than the distal deposited pyroclastic
rocks, and tuff and lapilli-ash tuff predominate. Dou
bly graded beds are not common, but normal grading
does occur. In the vicinity of Mist Inlet, wacke inter
bedded on an outcrop scale with redeposited
pyroclastic rocks is common. The clasts within the
pyroclastic rocks are subrounded to subangular and
heterolithic. Clasts of wacke are found within some
of the pyroclastic beds. Scouring of the underlying
beds has also been noted. This facies consists of
reworked and redeposited pyroclasts from the afore
mentioned proximal deposition facies.
The younger sequence of pyroclastic rocks of
the Berry River formation overlie the two previous
facies (Figure 1.32). If there is a hiatus present, the
length of time involved is not known.
The vent facies rocks found southeast of Berry
Lake consist primarily of an ovoid quartz-feldspar
porphyry body containing xenoliths and large rafts of
pyroclastic material. Parts of the porphyry are mas
sive, but others are subtly clastic or brecciated. The
porphyry has a distinctive lithologic type with
phenocrysts of rounded white and blue quartz and
smaller euhedral sericitized feldspar in a very fine
grained to crystalline matrix. This porphyry may in
part be a high-level subvolcanic intrusion, and in part
an extrusive lava dome. The relationships in the area
are very complex.
A linear body of similar quartz-feldspar porphyry
which may be in part, extrusive, can be traced from
Lobstick Bay west to Long Bay (Figure 1.32).
South of the linear porphyry body, along the
northern shore of Lobstick Bay and within the eastern
end of Long Bay, proximal deposited pyroclastic
rocks occur (Figure 1.32). These rocks are generally
coarse, clastic, and homoiolithic with the main clast
type being an angular to subangular quartz-feldspar
porphyry that is lithologically similar to the porphyry
bodies. Beds of mafic pumice-bearing, fine-grained
RM EASTON AND G.W. JOHNS
tuff occur within the homoiolithic sequence. The
pyroclastic units are matrix- to clast-supported, and
poor to well bedded. Some of the beds have char
acteristics similar to the model developed by Wright
et at. (1981) and Sparks ef a/. (1973) for subaerial
pyroclastic flows (Figure 1.3). Clastic horizons are
bounded by thin fine-grained tuff zones, which could
be ground surge or cloud surge deposits, or both.
Many depositional features seen in this facies cannot
be explained by debris flow emplacement and may
have a primary depositional origin.
If the vent facies porphyry is a volcanic dome
and the lateral porphyry a flow, then explosive activ
ity from the end of the flow would account for the
proximal deposition facies rocks in Long Bay. Rose et
al. (1976) have documented explosive activity from
andesite flow fronts on the flank of the endogenous
dome at Santiaquito in Guatemala.
Epiclastic rocks that may or may not be directly
associated with the Berry River formation are found
west of Mist Inlet. These well bedded wackes, many
of which exhibit good Bouma Sequences (Bouma
1962), are more quartz-rich than the other wackes of
the Warclub group. Rounded quartz grains are slightly
larger than the associated plagioclase feldspar and
lithic grains in these wackes. These quartz-rich wac
kes may be the distal equivalent of reworked debris
flows and volcanic debris flows of the Berry River
formation that were deposited by turbidity currents.
VOLCANIC FACIES AND KNOWN MASSIVE-SULPHIDE
DEPOSITS
The previous two examples of Archean volcanolog-
ical facies are of rocks containing no known
massive-sulphide deposits. The potential for base-
metal mineralization in Bryce Township is high, and
there is also potential at the eastern end of the Berry
River formation.
Examples of known massive-sulphide deposits in
the Noranda area of Quebec can be recognized with
in a particular volcanic facies. The Millenbach and
Corbet Mines are 8 km north of the city of Rouyn-
Noranda, Quebec. The Millenbach Mine is associated
with subaqueous quartz-feldspar porphyry bodies
and the Corbet Mine is related to coarse phreatic
breccia in mafic metavolcanics. Both deposits are in
a vent facies environment.
The Millenbach Deposit
The Millenbach deposit consists of 15 massive-
sulphide lenses located on and around a quartz-
feldspar porphyry (Knuckey, Comba, and Riverin
1982). The quartz-feldspar porphyry was extruded
from three or more vents along a northeast-trending
feeder system (Comba and Gibson 1983). It was
extruded endogenously and as flow lobes over a
length of 2 km. The thickest parts of the porphyry
body are over the main vents (Comba and Gibson
1983).
The Millenbach volcano cosisted of an upper and
lower part known as the upper QFP and the lower
QFP, as shown in Figure 1.36 from the paper by
Knuckey, Comba, and Riverin (1982). The lower QFP
was extruded on the thin Millenbach andesite which
35
CHAPTER 1
Q F P MASSIVE
DIORITE
SULPHIDE
MILLENBACH STRINGER
FELSIC DYKE
ANDESITE SULPHIDE
AMULET AMULET
DALMATIANITE
ANDESITE RHYOLITE
FAULT
Figure 1.33. Geology of the Millenbach deposit,
looking northeast along a northwest-southwest
section. (From Knuckey e t a l. 1982, Figure 6).
overlies the Amulet Rhyolite (Figure 1.33). The lower
QFP formed a hummocky ridge 760 m by 300m and
up to 110m thick. The main orebody was deposited
on the upper surface of the lower QFP together with
a local cherty horizon (Knuckey, Comba, and Riverin
1982). The upper QFP may have been coeval or
slightly younger and was extruded to the northwest
of the lower QFP and locally overlapped it. A small
lens of massive sulphide was deposited on top of the
upper QFP in an area of constant hot spring activity
just northwest of the main centre. A local cherty
exhalite is associated with these sulphides.
Deep-seated northeast-trending syn-volcanic
faults controlled the quartz- feldspar porphyry (QFP)
volcanism and the ore-forming hydrothermal solu
tions. Breccia associated with the extrusive QFP is
not believed to be phreatic, but rather the result of
syn-volcanic slumping (Comba and Gibson 1983).
The Corbet Mine
Although phreatic breccias are not associated with
the Millenbach Mine, they are related to mineraliza
tion at the Corbet Mine. This mine is 1000 m lower in
the Noranda area stratigraphy than the Millenbach
Mine. The Corbet Mine is located within the top
250 m of the Flavrian andesite, as shown in Figure
1.34 from the paper by Knuckey and Watkins (1982).
Figure 1.34 is a section through a part of the Corbet
36
FELDSPAR L"a"J FLAVRIAN
PORPHYRY DYKE LVJ VOLCANICLASTIC MASSIVE SULPHIDE
l l FLAVRIAN STRINGER SULPHIDE
FELSIC DYKE |___l ANDESITE
NW
V/fy MASSIVE MAGNETITE 'ORE OUTLINE
RHYOLITE
Figure 1.34. Geology through the Corbet Mine,
looking north along section 800 N. (From Knuc
key and Watkins 1982, Figure 1).
Mine. The breccia (Flavrian volcaniclastic, Figure
1.34) is composed of in-situ flow breccia grading to
highly vesiculated andesite debris consisting of un
sorted, angular to subangular fragments set in a
microbreccia matrix. Locally, there is a weak layering
and occasional grading. This debris locally reaches
thicknesses of up to 100 m. Clasts composed of new
magma are not found within this breccia (Knuckey
and Watkins 1982). This breccia is probably a
phreatic breccia.
A roughly concordant quartz-diorite sill stratig-
raphically below the orebodies has domed the
Flavrian andesites. This sill was intruded syn-
volcanically and acted as a heat source to circulate
hydrothermal fluids (Knuckey and Watkins 1982). Ini
tial heat required for the formation of the phreatic
breccias would likely have come from rising magma
forming the mafic flows. During formation of the
massive- sulphide lenses, the overlying mafic flows
encrusted the active vent resulting in the formation of
smaller sulphide lenses above the main body
(Knuckey and Watkins 1982; Figure 1.34).
DISCUSSION
These two examples show that volcanogenic
massive-sulphide deposits occur in both felsic to
intermediate and mafic metavolcanic environments.
Sulphide horizons tend to be localized over the dis
charge vents of submarine hydrothermal systems,
which are most likely in proximal and vent facies
environments. Subvolcanic intrusions are a significant
 R.M. EASTON AND G.W. JOHNS

TABLE 1.15: EXPLORATION CRITERIA FOR ARCHEAN VOLCANOGENIC MASSIVE-SULPHIDE DEPOSITS.

EXPLORATION CRITERIA

REQUIREMENT OF MODEL GENERAL SPECIFIC VOLCANIC FACIES

Heat - near surface magma - volcanotectonic vent and/or proximal
depression
- exposed central intrusion
or underlying sill
- abundant dikes
Self-sealing cap rock - phreatic explosion - coarse lithic fragment vent
products breccia with altered
mineralized clasts
- evidence of relatively - vesicular, texturally proximal
shallow water K500 m) complex lavas, pyroclastic
rocks, hyaloclastite
Cross-stratigraphic synvolcanic faults - structures filled with vent and/or proximal
permeability synvolcanic dikes
- alignment of structurally vent to proximal
localized features, (eg.
domes, sulphide deposits,
dike swarms)
- alignment of rapid proximal
thickness of facies
changes in units (flows,
slump breccias, ponded
sediments)
- clastic sediments derived proximal to distal
from erosion of unstable
fault scarps, mud flow
breccia, conglomerate

feature, acting as a source of heat for the hydrother SUMMARY

mal systems, and possibly causing phreatic and
phreatomagmatic eruptions. Franklin et at. (1981) es
timated that the subvolcanic intusive body must have
had a volume of several km3 in order to sustain a
hydrothermal circulation system large and long
enough to form an orebody.
Hodgson and Lydon (1977) have discussed vol
canogenic massive-sulphide deposits and their asso
ciation with active hydrothermal systems. These au
thors have outlined the exploration implications for
such deposit types (Table 2 in Hodgson and Lydon
1977). Table 1.15 is adapted from their table, and is
an attempt to assign a facies concept to some of the
features they noted in their table.
The assignment of volcanic facies in the eastern
Lake of the Woods area (Figure 1.32) and the Skead
Group pyroclastic rocks (Figure 1.31) was made from
data collected from 1:15840 scale mapping. Data
gathered from a single outcrop or small claim group
is generally not sufficient to permit accurate inter
pretation of a facies, and must be combined with all
the information available from a region before mean
ingful trends can be established.
Knowledge of volcanic facies is of potential use in
mineral exploration, both in helping to understand
how orebodies are formed in volcanic terrains, and in
developing new techniques to explore for them.
Knowledge of volcanic processes and volcanic rock
classification are essential prerequistes to the study
of volcanic facies. The overview presented here
should not be taken as the final word, but rather as
an introduction to the rapidly developing field of
activity applicable to Archean volcanism and ore-
genesis.
ACKNOWLEDGMENTS
This chapter has benefited greatly from an earlier
review of volcanic rock classification for the Ontario
Geological Survey prepared by Norm Trowell, Jim
Pirie, and Larry Jensen. The authors would also like
to thank Barbara Moore, who drafted all figures
(except Figures 1.2, 1.4, 1.11, 1.18, 1.26, 1.33, and
1.34 and Photos 1.1, 1.2, and 1.3), for putting our
ideas on paper so clearly and beautifully.

37
CHAPTER 1
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Ayres, L.D.
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1982: Pyroclastic Rocks in the Geologic Record;
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Borradaile, G.J.
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39
CHAPTER 1
1982d: Nature of Subaerial Pyroclastic Deposits
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40
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Chapter 2

Stratigraphic Correlation Techniques

N.F. Trowell

CONTENTS ABSTRACT
Abstract .......................................................................... 41 Volcanic rocks are by nature complex, and have
Introduction 41 highly variable modes of eruption, physical and
The Nature of"'volcan'ic''stratigraph711IIIII 42 chemical attributes, and resultant landforms and sur-
, . . , . . , t. , face features. Observation of modern volcanic rocks
Examples of Stratigraphic Correlate from provjdes jnsjght jmo tnejr form and environmental
Archean Terra ins .. . ............................................ 43 settj ng but precise correlation, even in these rocks,
Stratigraphic Marker Horizons ...........,.................. 43 js difficult. Archean volcanic rocks vieweo only in
pedostratigraphic Correlation.............................. 43 two.dimens i 0ns . present many additional problems.
Statistical correlation ......... .............................. 44 For examp|e tne asymmetric, discontinuous, and
htravolcanic Sediments and Bio- variable shapes of volcanic units are further corn-
Correlation .................................................... 44 p|j cated by erosion, deformation, and metamorphism.
htravolcanic Iron Formation ................................... 45 Thjs coupled with generally discontinuous exposure.
Geophysical Correlation .....................,................. 45 makes such features as calderas and cauldrons ex-
Geochronology.......................................................... 45 treme | y difficult to recognize. Walking out stratig-
A Word About Scale ..................................................... 46 raphic units is generally impossible due to their len-
References ..................................................................... 47 ticular form and limited areal extent. Many rules that
_____________________________ apply to stratigraphic interpretation in sedimentary

2-' srntechniquesusedinthe——7S
TABLES

.................................................................
assemblages must be applied cautiously. Abrupt

correlation techniques used in Archean terrains differ

2.2 Stromatolite occurrences in Archean somewhat from those used in conventional stratig-
of Ontario .............................................................. 45 raphy.
2.3 Zircon uranium-lead geochronology Correlation can be made by use of stratigraphic
for Savant Lake-Crow Lake area ...................... 46 marker norizons such as variolitic flows, interflow
———————————————————————— chemical sediments, and distinctive tephra layers.
FIGUHbb-^—————-——^——————-^^———- Volcanic rocks can be assigned to specific chemical
2.1. Differential erosion of a sequence of suites. Recognition of komatiitic volcanic rocks in the
ash flows............................................................... 42 Abitibi Belt has allowed the correlation of both local
2.2 Differential erosion leading to and regional stratigraphic sequences. Volcanic rocks
inversion of relief 42 can be assigned to facies by delineating physical
o o C^KQ™O*;^ HiQrtrom'^'f'^wr^io'otio""""""""""" ar|d structural features related to distance from erup-
^no^fc frnrJf? vin^Tc A, tive centres. Flows commonly exhibit certain intrinsic
deposits from St. Vincents ................................. 42 geopnysical properties. it is possible to trace and
2.4 Schematic diagram of volcanic distinguish between high-Fe and high-Mg tholeiitic
deposits from St. Vincents showing f | OWS on tne basis of their magneti c signature.
different volcanic environments ....................... 43 . L
n r. ,, , . . .. . . , . Recently, radiometric ages have proven to be
2.5. Knee Lake area of Manitoba showing f , t *, both , d fj * , , stratigraphy and
distinctive marker horizons in regional correlation.
(porphyritic rocks) ............................................... 44 a
26 Mattaaami area of Oueber illu^tratina Tne imPortance of Stratigraphic studies to Ar-
i^iSta^^^ chean mineral ex P |oration can be demonstrated by
^onc^n
honzons m minir?
mineral ?v5nSt^n
exploration ......................... AA
44 analogy
are ^^ with the Kuroko stratigraphjc
IQ specjfjc base-metal deposits. These
fe^sic volcanjc
2.7. Sketch map showing broad sequences, and paleontological evidence suggests
lithostratigraphic relationships of that deposits as widely separate as 300 km formed
Savant Lake-Crow Lake area............................. 44 simultaneously.
2.8. Sketch map to show distribution of _____________________________
volcanic suites in the Savant Lake- INTRODUCTION
Crow Lake area.................................................... 44 —————————————————————————————
2.9. Measured section of pyroclastic ™ s chaPter wi " ? iscuss a few techniques used for
rocks in the Kirkland Lake area (after tnf correlation of volcanic rocks specifically with
o in Hyde
o u 1978)* y........................................................... 45 reference and application
phosed Archean terrains. to deformed and metamor-
2. 10. Schematic of first derivation vertical
aeromagnetic data over part of the Volcanic rocks are by their very nature complex.
Abitibi Belt illustrating how different As one 9oes further and further back in geologic
volcanic suites can be distinguished time ' if becomes increasingly difficult to:
on the basis of their magnetic 1. reconstruct volcanic sequences
character ............................................................... 46 2. correlate volcanic deposits

41
CHAPTER 2

Pyroclastic Deposits, St. Vincent (East Coast)

Figure 2.3. Schematic diagram of pyroclastic de

posits from St. Vincents.

3. determine the geologic setting in which they

Figure 2.1. Differential erosion of a sequence of
ash flows.
were erupted.
One of the prime reasons for this lack of knowl
edge is the fact that volcanic rocks often form con
structional topographic features which inevitably
leads to their relatively rapid destruction by erosion.
By contrast, the deposition of sedimentary rocks in
protected basins can preserve thick stratigraphic sec
tions, completely documenting geological events over
tens of millions of years.
Assuming that physical and chemical laws are
immutable, one should first look at examples of the
morphology of younger volcanoes and their products
to gain insight into the types of problems inherent in
correlating Archean strata. These examples are from
the subaerial environment, but beyond doubt, similar
processes operate subaqueously.

THE NATURE OF VOLCANIC STRATIGRAPHY""

Figure 2.2. Differential erosion leading to inversion
of relief.
Constrasting mechanical properties of volcanic rocks
often produce classic examples of differential ero
sion. An example of how an area could be misinter
preted after erosion is shown in Figure 2.1. A lower
ash flow unit (top illustration) has filled in the pre
existing topography, but was not extensive enough to
cover the ridge crests. The degree of compaction of
ash flows is a function of their thickness, and thus
will be greatest in areas of negative relief as the ash
flows "fill-in" the topography. Subsequent ash flows
(middle illustration) would tend to follow the same
paths, but erosion due to water and/or ice along the
valleys might completely scour out those deposits
leaving the situation seen in the bottom illustration.
Any volumetric calculations, stratigraphic sec
tions, and attempted correlations based on a limited
exposure of such terrain would be very misleading.
Figure 2.2 illustrates how erosion can cause an
inversion of relief. A basaltic lava flow (lined pattern)
that occupied a valley bottom is more competent and
thus less easily eroded than the underlying bedrock.
Because of this contrast, the final configuration after
stream erosion is a string of basalt-capped hills
(bottom illustration).
Figure 2.3 is a schematic diagram showing a
sequence of pyroclastic deposits from St. Vincents.
What significance does the steep erosional unconfor
mity have? It may in fact represent only a short
period of time during eruptive activity. Abrupt vari
ations in dip over short distances due to mantle

42

detrital fan M)eoch deposits
subaqueous environment
Larakai Bay, St. Vincent
Figure 2.4. Schematic diagram of volcanic depos
its from St. Vincents showing different volcanic
environments.
bedding are meaningful on only the local scale and
have no structural significance. Of course, one never
sees excellent exposures like this in Archean terrain.
This increases these problems of structural inter
pretation several-fold.
Figure 2.4, a schematic diagram, also of volcanic
deposits from St. Vincents, illustrates how different
volcanic environments and their product lithologies
can occur together in one relatively restricted area.
Active erosion of constructional topographic features
is occurring as is shown by formation of the alluvial
deposits. An Archean analogue in which a similar
area was eroded, covered by younger deposits and
then deformed, would obviously be very difficult to
interpret, especially where only a two-dimensional
view is available.
The question of erosion is one of critical impor
tance, specifically for pyroclastic rocks which tend to
form constructional topographic land forms. As Ayres
has recently pointed out (Ayres 1983), from 2x to 4x
the observed volume of felsic volcanic rocks in his
study area of Archean rocks had been eroded to
provide detritus to subjacent sedimentary environ
ments.
In many cases it may not be possible to do
extended correlations in areas having only partial
volcanological records.
EXAMPLES OF STRATIGRAPHIC
CORRELATION FROM ARCHEAN TERRAINS
Table 2.1 is a listing of some of the correlation
techniques used in Archean terrains. Discussion of
these techniques will be brief, but will provide an
introduction to more detailed descriptions in the ac
companying chapters of this volume.
STRATIGRAPHIC MARKER HORIZONS
Figure 2.5 from Green (1975) shows a distinctive
glomeroporphyritic horizon that can be traced for
several km in the Knee Lake area of Manitoba. Simi
larly, variolitic horizons in the Abitibi Belt of Ontario
and Quebec can be traced for distances in excess of
N.F. TROWELL
TABLE 2.1: CORRELATION TECHNIQUES IN THE
ARCHEAN.________________________
STRATIGRAPHIC MARKER HORIZONS
Glomeroporphyritic, variolitic flows
Interflow sediments/pyroclastics
CHEMOSTRATIGRAPHIC CORRELATION
STATISTICAL CORRELATION
INTRAVOLCANIC SEDIMENTS
Stromatolites
Iron Formation
GEOPHYSICAL CORRELATION
GEOCHRONOLOGY
70 km. It should be kept in mind, however, that it is
not one individual flow that is being traced, but rather
a stratigraphic package wherein variolitic or
glomeroporphyritic lavas are the dominant volcanic
products. Since these flow types are not rare, caution
should always be exercised to ensure that it is the
same stratigraphic package being correlated.
In the Mattagami area of Quebec (Figure 2.6 after
Costa et al. 1983), on the southern limb of the Allard
Anticline, the lower Watson Lake Group consists of
felsic flows and pyroclastic rocks. It is separated
from the overlying Wabasee Group of both mafic
flows and felsic pyroclastic rocks by the "Key Tuf
fite" horizon. The Key Tuffite horizon consists of
chemical sediment and airfall ash material. Not only
is the Key Tuffite horizon important for correlation
purposes, but it also overlies the orebodies of Mat
tagami, Orchan, and Bell Allard, making it a prime
target in mineral exploration. Furthermore, its pres
ence allowed Roberts (1975) to do a palimspastic
reconstruction of the paleotopography and paleoen
vironment of ore deposition. Recognition of the airfall
ash component of this unit is an example, albeit on a
local scale, of the more specialized correlation tech
nique of tephrochronology.
CHEMOSTRATIGRAPHIC CORRELATION
Volcanic rocks can be assigned to specific chemical
suites based on field and laboratory criteria.
In the Savant Lake-Crow Lake area of North
western Ontario (Figure 2.7), local stratigraphy was
deciphered and volcanic sequences were assigned
an approximate chemical composition on the basis of
field determination of mafic mineral content (Trowell
et al. 1980). Subsequent chemical data allowed for
both the assignment of these sequences to their
respective chemical suites (Figure 2.8), and the rec
ognition of specific stratigraphic distribution patterns
based on those suites. Correlation of discontinuous
sequences in this area still relied, however, on other
means, specifically, geochronology to demonstrate
the time relationships between these suites.
43
CHAPTER 2

MAGNESIAN THOLEIITIC FLOWS (MTF)

—— sediments y.
~ granitic rocks]- THOLEIITIC TO CALC ALKALINE FLOWS
AND PYROCLASTICS (TCFP)
•^ porphyritic rocks FE THOLEIITIC SIOUKiOOKOUT
felsic volcanic FLOWS (FTF)
mafic volcanic SEDIMENTS

FAULTS

IRON FORMATION

50 100 KM
CROW
(KAKAGlfLA~KE

Figure 2.5. Knee Lake area of Manitoba showing Figure 2.7. Sketch map showing broad lithostratig
distinctive marker horizons (porphyritic rocks). raphic relationships of Savant Lake-Crow Lake
area.

Matagarni

LOWER-MOST MAFIC FLOWS

——— FAULTS

v* — IRON FORMATION

ALLARD CROW
(KAKAGI) LAKE

Figure 2.8. Sketch map to show distribution of

volcanic suites in the Savant Lake-Crow Lake
area.
Intrusions
probability of one facies succeeding another in the
stratigraphic section.
Wabassee Group This method should prove to be very helpful in
the correlation of areas where exposure is poor, and
Watson Lake Group it could have applications for mineral exploration if,
for example, one particular facies is deemed to have
an high mineral potential.

Figure 2.6. Mattagami area of Quebec illustrating INTRAVOLCANIC SEDIMENTS AND

importance of stratigraphic marker horizons in
mineral exploration.
STATISTICAL CORRELATION
During the process of analyzing volcanic rocks, sta
tistical manipulation of qualitative data is used to
predict stratigraphic relationships and correlations. In
the Kirkland Lake area, Hyde (1978) has successfully
used Markov Chain Analysis, a statistical technique,
in the study of the alkalic volcanic rocks of the
Timiskaming Group. Figure 2.9 shows a measured
section of pyroclastic rocks that have been assigned
to their respective facies whether airfall, ash flow, or
reworked. Statistically, it is possible to estimate the
BIO-CORRELATION
While it probably can be said that the Archean record
does not abound in fossils, it is to the Archean that
we must look for the earliest traces of life. At present,
stromatolites are the only abundant fossils recog
nized in the Archean rocks of Ontario that can be
used for bio-correlation.
Archean stromatolites are known to be present at
several localities in Ontario (Table 2.2). More occur
rences are likely to exist. Attendant upon future finds,
detailed studies of their morphology may permit the
recognition of specific assemblages, useful, not only

44
 N.F. TROWELL

for purposes of correlation, but also for more detailed 9 -i

palaeoenvironment and paleogeography analysis.
Microfossils have been documented in rocks as B
old as the 3500 Ma year old Warrawoona Group of
Western Australia. Recently, laminated algal mats and 8 -
stromatolites have been identified in the Helen iron
formation at Wawa, suggesting that they may hold covered
some promise as a correlation tool of the future. The
chapter on the stratigraphy of the Western Uchi Sub-
province (Chapter 6, this volume) will discuss how
stromatolitic horizons might be used as potential cor
relation tools, and will illustrate some of the pitfalls
inherent in correlating apparently similar though
widely separate stromatolitic units. 6 -\
INTRAVOLCANIC IRON FORMATION
Due to their great lateral extent, intravolcanic iron
formations can be used to correlate separate and 5 -
discontinuous volcanic sequences. In the chapter on
the Wawa area (Chapter 4, this volume), an extended
discussion is given on the use of Michipicoten-type
iron formations in the correlation of volcanic se
quences in a region that has suffered extensive faul
:-:-:-:J
4 — .•.•.-.-.•.•.- i cB
ting.
Even though neither stromatolites nor iron forma C airfall
tions are volcanic rocks, for the purposes of regional
correlation, all the tools available should be used. 3 -
Even simply determining that two widely separated B
volcanic sequences are older or younger than a spe
cific, laterally continuous, intravolcanic sedimentary ash flow

m
unit is an important first step in refining regional
correlation within the Superior Province. 2 -
B
GEOPHYSICAL CORRELATION A reworked
One example of geophysical correlation is the use of
aeromagnetic data to distinguish and trace packages 1 — B
of volcanic rocks with distinct chemical and therefore A
physical characteristics over a part of the Abitibi Belt metres
B
straddling the Porcupine-Destor Break (see Letros et
al. 1983). 0— A
Figure 2.10 is a schematic diagram of a first
derivative vertical gradient map of aeromagnetic Figure 2.9. Measured section of pyroclastic rocks
data. Packages of rocks, in this case magnesian in the Kirkland Lake area (after Hyde 1978).
tholeiites and high-iron tholeiitic basalts, can be dis
tinguished on the basis of a particular geophysical
parameter, in this case magnetic susceptibility.

GEOCHRONOLOGY
Correlation of local Archean sequences on a regional
to geological subprovince- and province-wide scale
has, until the present, relied upon similarities in
lithologies and recognition of extensive sedimentary TABLE 2.2: STROMATOLITE OCCURRENCES
or tectonic events. Lithocorrelation is, however, re IN SUPERIOR PROVINCE OF ONTARIO.
stricted by the extent of the lithostratigraphic units in
question. This limits the reliability of such regional Woman Lake Uchi
correlations.
Recently, radiometric age determination methods Red Lake Subprovince
have proven to be powerful tools both in defining
local stratigraphy and regional correlation. The impor Steeprock Wabigoon
tance of geochronologic studies to Archean mineral Subprovince
exploration can be demonstrated by an analogy with
the Kuroko base-metal deposits. These deposits are Kirkland Lake? Abitibi-Wawa
confined to specific stratigraphic felsic volcanic se Wawa Subprovince
quences; both paleontological and paleomagnetic

45
CHAPTER 2

Figure 2.10. Schematic

of first derivation
vertical aeromagnetic
data over part of Abitibi
Belt illustrating how
different volcanic suites
can be distinguished on
the basis of their
magnetic character.

felsic intrusions
alkalic volcanics and clastic sediments
mafic-ultramafic intrusions
. ,. ,. . __ ,,w, i,, Branch of the
calc-alkalic volcanics ———— Porcupine-Destor Fault
iron-rich tholeiites -. - x -
magnesium tholeiites ~ ~ Porcup.ne-Destor Fault
komatiitic volcanics Munro Syncline

evidence suggests that deposits separated by as

much as 300 km. formed simultaneously (Scott 1980;
Ueno 1975). With this in mind, a geochronologic
study (Davis and Edwards 1982; Davis and Trowell
1982; Davis ef a/. 1982) was done in the Savant
Lake-Crow Lake area of Northwestern Ontario to TABLE 2.3: ZIRCON U/PB GEOCHRONOLOGY
bracket the time of formation of the Sturgeon Lake FOR SAVANT LAKE.
base-metal deposits, and to compare this age with
the ages of other volcanic sequences throughout the : i——t———; BERRY :CREEK COMPLEX i
belt (Table 2.3). This study is being continued by the \ ;-*- FELSIC TUFF, KAKAGI LAKE GROUP
private sector. : ; THUNDERCLOUD PORPHYRY ——i
—*—— TAYLOR ^LAKE STOCK \ : \ l
RHYOLITE TUFF NEAR TOP OF '-.
A WORD ABOUT SCALE CTTt .
o J. J-ii-i —*—
i BOYER LAKE VOLCANICS
:
j i -*- SABASKONG BATHOLITH j
When mapping at a scale of 1:15840, it is highly DASH LAKE STOCK -*- } \ ; :
fortuitous if individual flows or pyroclastic horizons i : GABBRO -—*—— BEIDELMAN BAY
can be traced for an appreciable distance. Under : i FELSIC TUFF: -*- CENTRAL VOLCANIC BELT
favourable conditions, however, packages of units DORE LAKE LOBE —*— ATIKWA BATHOLITH
can be correlated between traverse lines. A mineral CONTACT BAY RHYOLITE —*—— i ; ;
explorationist, for whom a 1/4 mile can represent the i EAGLE LAKE LOBE --*- ATIKWA BATHOLITH i
surface extent of a viable mineral deposit, may find it i : EAGLE LAKE i DACITE -*- i :
necessary to correlate to the outcrop scale. Hence, : : HANDY ; LAKE VOLCANICS -^ l ;

the precision required and attained in correlation de

pends very much on the purpose of the geologist
involved and the amount of time and effort he is
willing to expend.

46

Whatever the scale, it will be the education,
experience, and skill of the field mapper that will
ultimately determine the quality of any stratigraphic
correlation.
REFERENCES
Ayres, LD.
1983: Bimodal Volcanism in Archean Greenstone
Belts Exemplified by Greywacke Composition,
Lake Superior Park, Ontario; Canadian Journal of
Earth Sciences, Volume 20, p. 1168-1194.
Costa, U.R., Barnett, R.L, and Kerrich. R.
1983: The Mattagami Lake Mine Archean Zn-Cu Sul
phide Deposit, Quebec: Hydrothermal
Coprecipitation of Talc and Sulphides in a Sea-
Floor Brine Pool Evidence from Geochemistry,
18Q/16Q anc| Mineral Chemistry; Economic Geol
ogy, Volume 78, p. 1144-1203.
Davis, D.W., Blackburn, C.E., and Krogh, T.E.
1982: Zircon U-Pb Ages from the Wabigoon-Manitou
Lakes Region, Wabigoon Subprovince, Northwest
Ontario; Canadian Journal of Earth Sciences, Vol
ume 19, p.254-266.
Davis, D.W., and Edwards, G.R.
1982: Zircon U-Pb Ages from the Kakagi Lake Area,
Wabigoon Subprovince, Northwest Ontario; Cana
dian Journal of Earth Sciences, Volume 19,
p. 1235-1245.
Davis, D.W. and Trowell, N.F.
1982: U-Pb Zircon Ages from the Eastern Savant
Lake-Crow Lake Metavolcanic-Metasedimentary
Belt, Northwest Ontario; Canadian Journal of
Earth Sciences, Volume 19, p.868-877.
N.F. TROWELL
Green, N.L.
1975: Glomeroporphyritic Basalts; Canadian Journal
of Earth Sciences. Volume 12, p. 1770-1784.
Hyde, R.S.
1978: Sedimentology, Volcanology, Stratigraphy, and
Tectonic Setting of the Archean Timiskaming
Group, Abitibi Greenstone Belt, Northeastern On
tario, Canada; Unpublished Ph.D. Thesis,
McMaster University, Hamilton, Ontario, 423p.
Letros, S., Strangway, D.W., Tasillo-Hirt, A.M., Geiss
man, J.W., and Jensen, L.S.
1983: Aeromagnetic Interpretation of the Kirkland
Lake-Larder Lake Portion of the Abitibi Green
stone Belt, Ontario; Canadian Journal of Earth
Sciences, Volume 20, p.548-560.
Roberts, R.G.
1975: The Geological Setting of the Mattagami Lake
Mine, Quebec: A Volcanogenic Massive Sulphide
Deposit; Economic Geology, Volume 70,
p. 115-129.
Scott, S.O.
1980: Geology and Structural Control of Kuroko-Type
Massive Sulphide Deposits; p.705-722 in The
Continental Crust and its Mineral Deposits, edited
by D.W. Strangway, Geological Association of
Canada, Special Paper Number 20, 804p.
Trowell, N.F., Blackburn, C.E., and Edwards, G.R.
1980: Preliminary Synthesis of the Savant Lake-Crow
Lake Metavolcanic Metasedimentary Belt, North
western Ontario, and Its Bearing Upon Mineral
Exploration; Ontario Geological Survey, Miscella
neous Paper 89, 30p. Accompanied by Chart A.
Ueno, Hirotomo
1975: Duration of the Kuroko Mineralization Episode;
Nature, Volume 253, Number 5491, p.428-429.
47
Part Two: Volcanic Stratigraphy in
Archean Greenstone Belts
Chapter 3

Stratigraphic Correlation of the Western Wabigoon

Subprovince, Northwestern Ontario
N.F. Trowell and G.W. Johns

CONTENTS ABSTRACT
Abstract .......................................................................... 50 The Savant Lake-Crow Lake metavolcanic-
Introduction 50 metasedimentary belt extends for 300 km within the
Chemostratigrap'hic"c'orrela'tion'II.r.'Ii:i"."r. 51 weste™ Part of the Wabigoon Subprovince. Correla-
n , L. T i o o i u r-n tion of stratigraphy in this area was initially made on
Long Bay-Lobstick Bay Stratigraphy........................ 52 the basjs ofy the following observations: 1) general
Local Geochemical Synthesis ,,.....,.,..,..,.,,.,...,. 54 inward facing of metavolcanic-metasedimentary se-
Regional Geochemical Synthesis............................... 55 quences; 2) thick basal mafic assemblages are all
Geochronology 55 situated at the outer edges of the belt; 3) overlying,
Stratigraphy and G^ld^ineralizati(^'I'III'"'I 58 mi*ed mafic to felsic sequences are more internal
and contain thick assemblages of mafic flows that
Heterences.................................................................... bo are most |y toward or at the top of these sequences,
Q——————————————————————— and in some places may be allochthonous; 4) associ-
rlCaURtb________________________ at j On Of clastic sedimentary rocks with mixed mafic
3.1. Sketch map showing broad to felsic parts of volcanic sequences; and 5) lateral
lithostratigraphic relationships and continuity of certain ironstone-bearing formations.
structural complexity of the Savant Recent mapping has extended the correlation of
Lake-Crow Lake area .......................................... 51 stratigraphy into the Gibi Lake and Lobstick Bay-Lake
3.2. Stratigraphic map of the Long Bay- of the Woods area.
Lobstick Bay area ................................................ 52 Local and regional geochemical studies support
3.3. Simplified stratigraphic sections the stratigraphic relationships outlined. Geochronol-
within the Long Bay Lobstick Bay ogy has also been used successfully to refine the
area ........................................................................ 54 stratigraphy.
3.4. Jensen cation plot for Jutten Local and regional mapping, combined with
volcanics. Northern volcanic belt, lithogeochemical syntheses and geochronological
and Wapageisi volcanics, showing studies have produced a much clearer picture of the
their tholeiitic, relatively magnesian geological evolution of this area. Future studies will
character .............................,................................ 55 allow placement of mineral deposits of this area into
3.5. Jensen cation plots for Rowan Lake this new tectonostratigraphic framework.
volcanics, Kakagi Lake volcanics, .^——--——-——-———.————--—-.—-————
Lower Wabigoon volcanics, Manitou INTRODUCTION
Lakes section, North and South ————-—————————-——————————————-
Sturgeon Lake volcanics, and A 300 km Ion9 metavolcanic-metasedimentary belt
Beckington Road and Morgan Island ( R 9 ure 3 - 1 )- stretching from Savant Lake in the east
sections of the Northeast Arm to the eastern part of Lake of the Woods in the west,
volcanics showing their calc-alkalic forms tne western end of the Wabigoon Subprovince
to tholeiitic character ,,.,,.,.,,.,,,,,,,.,,,,. 56 (Mackasey et al. 1974).
3.6. Jensen cation and AFM plots of Tne Wabigoon Subprovince is a major tec-
recent data from the Central Volcanic tonostratigraphic subdivision of the Superior Prov-
Belt Sioux Lookout area ,. .....,. ........ ............... 57 ince, consisting of belts of predominantly metavol-
3.7. Jensen cation plots for Brooks Lake cat™ r^ks and .subordinate metasedimentary rocks
volcanics, Katimagamak volcanics, intruded by granitoid bodies some of bathol.th.c d.-
Boyer Lake volcanics. Upper E8"! 10^'^8 bor6^ l0 th? ™rth and south by
Wabigoon volcanics, and Central he .^"^ * lver and Que ICO Subprov.nces, respec-
Sturgeon Lake volcanics, showing tlve! v' wh ' ch COR;slst m. ainljf of metasediments, m,g-
their tholeiitic, relatively iron-rich ma lte ' and 9ranitic rocks of both anatectic and mag-
character ,,,,,.,,,,,,,,,,,,,,,,,,,,,,.,,... 57 matlc or'9' n -
3.8. Jensen cation and AFM plots of the ln tne 1960s - Goodwin (1965) compared and cor-
Berry Creek Complex and Warclub related volcanic stratigraphic sections on the basis of
group, and Snake Bay formation...................... 58 tneir geochemistry and suggested a two-fold subdivi-
on ci^*^ ~,o,, ^ r^,., ^-otr^,,*^^ ^f slon of the volcanic sequences at Lake of the
3.9. Sketch map o show distr but.on o WoQds Goodwjn no^such evj(jence f
the three volcanic suites m the study f subdivision elsewhere in the eastern half of the
aica ,,,,,,,.,.,.,,.,.,,..,..,.,.,....,,.,.,,...,,.. ^^
op/3,0 ^M
area unc|er discussion: in this area he concluded that
3. 10. Zircon uranium-lead geochronology on |y tne lower subdivision was present.
for Savant Lake-Crow Lake area ...................... 59 |p ^ ^^ HDR m ^ ^ coworkers
(Wilson et al. 1974; Wilson and Morrice 1977; Morrice

50

lowermost mafic flows
mafic to felsic flows and pyroclastic rocks'
middle l upper mafic flows
sediments
granitic rocks
CROW ,
(KAKAGI)
LAKE
1977) studied the volcanic and sedimentary stratig
raphy of the western Wabigoon Subprovince. These
authors proposed a four-fold sequential model based
upon comparable sequences in Archean greenstone
terrains of South Africa and Australia. They attempted
to apply this model to the area from Lake of the
Woods to Sturgeon Lake on the basis of literature
reviews and mapping of selected sections.
In the 1970s, N.F. Trowell, C.E. Blackburn, and
G.R. Edwards of the Ontario Geological Survey con
ducted a synoptic study of the metavolcanic se
quences from Crow (Kakagi) Lake to Savant Lake,
emphasizing lithogeochemistry across recognized
stratigraphic sections. Among their conclusions,
Trowell, Blackburn, and Edwards (1980) found that
the four-fold subdivision proposed by Wilson and
coworkers was not tenable, but that there was a
general succession of lithogeochemically distinct se
quences throughout the area.
A geochronological program carried out under
the direction of D.W. Davis of the Royal Ontario
Museum in the late 1970s and early 1980s, allowed
for refinement of correlation of volcanic sequences
throughout the belt (Davis, Blackburn, and Krogh
1982; Davis and Trowell 1982; Davis and Edwards
1982).
Further work by Trowell, Logothetis, and Caldwell
(1980), Trowell (in preparation), and Johns (1981,
1982, 1983) has provided more detailed information
on the stratigraphy and lithogeochemistry of the east
ern part of the Lake of the Woods area. This chapter
represents a synopsis of that work intended to show
how lithogeochemistry and geochronology can be
used as correlation tools in deciphering Archean ter
rains. Wherever possible, the reader is referred to
previous publications for details of local stratigraphy.
Since information on the eastern Lake of the Woods
area is new and as yet unpublished, a more complete
description of that stratigraphy as interpreted from
recent mapping by Johns and Richey (1982), Johns
and Davison (1983), Johns, Good, and Davison
(1984) is provided in this chapter.
N.F. TROWELL AND C.W. JOHNS
Figure 3.1. Sketch map
showing broad
lithos fra tigraphic
relationships and
structural complexity of
the Savant Lake-Crow
Lake area. Area "A" is
the recently mapped
Long Bay-Lobstick Bay
area.
faults
iron formation
facing direction
so 100
kilometres
CHEMOSTRATIGRAPHIC CORRELATION
In any attempt at regional correlation based upon the
chemical character of local stratigraphic sections, the
following reservations must be kept in mind. Firstly,
the present state of detailed mapping is such that in
most cases individual sequences have not yet been
traced between geographic areas. Secondly, se
quences are disrupted, both by tectonism and by
batholithic intrusion. Sense and movement on long
faults are not well documented. Emplacement of
large granitic bodies have likely removed voluminous
amounts of volcanic rock by stoping, particularly from
the basal parts of these volcanic sequences. Lastly,
stratigraphic sequences in one geographic area, with
particular chemical affinities are not necessarily time-
equivalent to lithologic packages exhibiting similar
chemical characteristics in other areas.
Figure 3.1 (from Trowell, Blackburn, and Edwards
1980) illustrates a tentative correlation of the main
part of the metavolcanic metasedimentary belt, while
Figure 3.2 outlines the recently interpreted stratig
raphy at the western end of the Wabigoon Sub
province in the Lake of the Woods area. These cor
relations were made based on tracing marker hori
zons, and on general comparison of lithologic char
acteristics prior to obtaining significant amounts of
chemical data.
Five general observations are of paramount im
portance in making this preliminary correlation. These
are:
1. Discounting the many reversals due to folding,
doming due to batholithic emplacement, and
complications due to faulting, it can be noted that
sequences predominantly face inward toward the
axis of the belt. In particular, volcanic rocks near
the contact with enclosing batholiths invariably
face inward.
2. In the lower stratigraphic sequences, thick suc
cessions of mafic flows are invariably situated at
the margins of the belt.
3. Away from the margins of the belt, highly vari
able sequences of mafic to felsic flows and
51
CHAPTER 3
Gibi Lake Volcanics
Warclub Group
Figure 3.2. Stratigraphic map of the Long Bay-Lobstick Bay area. The area is structurally complex due to
the intrusion of the Aulneau and Dryberry Batholiths and the Viola Lake Stock.
pyroclastic rocks predominate. Where thick accu
mulations of mafic flows occur in these upper
volcanic sequences, they are found at or near
the very top.
4. Thick sequences of clastic sedimentary rocks are
associated both laterally and vertically with the
volcanic sequences containing mafic to felsic
flows and pyroclastic rocks. In contrast, few sedi
mentary rocks are associated with the thick
mafic successions in either the lower or upper
sequences.
5. Iron formations, predominantly oxide facies, oc
cur discontinuously within the clastic sedimen
tary zones. It is probable that within each sedi
mentary zone, the iron formation units are correl
ative.
The general geology of the main part of this belt
was described previously (Trowell, Blackburn, and
Edwards 1980, p.2-6; Blackburn era/. 1982). Mapping
since then (Johns and Richey 1982; Johns and
Davison 1983; Johns, Good, and Davison 1984) has
provided us with a more detailed and accurate
knowledge of the far western part of the belt, and an
expanded discussion on this subject is presented
below.
52
intermediate intrusive rocks
mafic intrusive rocks
metasediments and intermediate to felsic metavolcanics
intermediate to felsic metavolcanics
mafic metavolcanics
stratigraphic contact
lithologic contact 01 234 56 789 10
fault
LONG BAY - LOBSTICK BAY STRATIGRAPHY
To date, there has been no detailed stratigraphic
subdivision of the Lake of the Woods part of the
Wabigoon Subprovince. Mapping carried out between
Lake of the Woods and the area studied by Trowell,
Logothetis, and Caldwell (1980) at present permits a
preliminary stratigraphic synthesis. Elements of the
stratigraphy identified by Trowell, Blackburn, and Ed
wards (1980) have been recognized and may be
used to extend correlations into the Lake of the
Woods area. Further mapping is required, however, to
subdivide the supracrustal sequences in the rest of
the Lake of the Woods area.
Figure 3.2 is a lithostratigraphic map of the Long
Bay Lobstick Bay area. The Snake Bay volcanics,
Populus volcanics, and Warclub sediments outlined
on Chart A in Trowell, Blackburn, and Edwards (1980)
have been recognized in the Long Bay Lobstick Bay
area. This area was subdivided into several geologic
domains based upon their positions relative to the
regional Pipestone Cameron Fault and, to date, cor
relation has not been attempted between them.
Southwest of the Pipestone-Cameron Fault, the
Snake Bay formation (Figure 3.2) is a north- to
northeast-facing mafic metavolcanic sequence of
fine-grained and medium-grained flows, fine-grained
pillowed flows, and coarse massive and pillowed
glomeroporphyritic flows. These flows are interdigitat-
ed with fine intermediate pyroclastic rocks in the

western part of the area. The base of the Snake Bay
formation is in intrusive contact with the Aulneau
Batholith, and the top may have been technically
removed by the Pipestone-Cameron Fault.
Morrice (1977) was able to subdivide the Snake
Bay formation into lower and middle mafic groups.
Morrice's lower mafic group is 3650 m thick and has
been subdivided into 12 formations. The middle
mafic group is 6350 m thick and consists of 10 dis
tinct formations (Morrice 1977). In the Long Bay-
Lobstick Bay area, only the lower mafic group ap
pears to be present.
Northeast of the Pipestone-Cameron Fault, six
stratigraphic subdivisions within the supracrustal
rocks may be discerned. These subdivisions are
shown on Figure 3.2 as the Point Bay group, Populus
volcanics, Black Lake volcanics, Gibi Lake volcanics,
and Warclub group which includes the Berry River
formation.
The presumed oldest supracrustal assemblage in
the Long Bay Lobstick Bay area is the Point Bay
group. This group has been largely intruded and
assimilated by the Dryberry Batholith and only rem
nants are found rimming the contact. The Point Bay
group is a diverse assemblage of highly metamor
phosed mafic volcanic rocks, intermediate volcanic
rocks, and metawackes intruded by thick, differen
tiated ultramafic to mafic sills. South of Dryberry
Lake, the sequence is south facing, while west of the
lake, it occurs in the nose of a series of folds. Roof
pendants, discontinuous remnants, and xenoliths of
this assemblage are found in the rocks of the
Dryberry Batholith and Berry Lake Stock.
The Populus volcanics (Trowell, Blackburn, and
Edwards 1980) are a largely northwest-facing se
quence of massive and pillowed mafic flows,
hyaloclastite, pillow breccia, and pyroclastic rocks
with some interbedded intermediate pyroclastic
rocks. These metavolcanics strike northeast from
Dogpaw Lake where they have been juxtaposed
against the Snake Bay formation by the Pipestone -
Cameron Fault. The relationship between the Point
Bay group and the Populus volcanics is unknown as
there is no direct contact between them, but it can be
assumed that the Populus volcanics are somewhat
younger than the Point Bay group.
The Black Lake volcanics also bear an uncertain
relationship to the Point Bay group. The Black Lake
volcanics, which consist primarily of massive and
pillowed mafic flows, occupy an anticlinal structure
between Yellow Girl Bay and Bug Lake. Car (1980)
completed a study in the western part of the Eastern
Peninsula and hypothesized the existence of an Ar
chean composite cone in that area. In the Adams
River Bay area, coarse mafic debris flows, fine mafic
tuff, wacke, and mafic flows are interbedded. This
clastic sequence represents the distal part of the
composite volcano hypothesized by Car (1980) over
lying and interdigitated with mafic flows of the Black
Lake volcanics. The Black Lake volcanics may repre
sent flank flows from this prograding volcano, for
ming a platform on which the composite volcano
continued to grow.
Figure 3.3 shows simplified stratigraphic sections
in the Long Bay Lobstick Bay area. In the Gibi Lake
N.F. TROWELL AND C. W. JOHNS
area, Trowell (in preparation) interpreted the stratig
raphic sequence to be mafic flows of the Dogtooth
Lake volcanics, overlain by wackes of the northern
metasedimentary belt, overlain by the felsic and
mafic pyroclastic rocks of the Gibi Lake volcanics.
Mapping in the Long Bay-Lobstick Bay area has re
vealed a similar stratigraphic succession in the vi
cinity of Rat Lake (see Figures 3.2 and 3.3). Mafic
flows of the Black Lake volcanics are overlain by a
thin wacke sequence which is overlain by felsic to
intermediate pyroclastic rocks. On the basis of
stratigraphic similarity one of the authors (GWJ) cor
relates the Black Lake volcanics with the Dogtooth
Lake volcanics and equates the pyroclastic rocks at
Rat Lake with the Gibi Lake volcanics.
The Gibi Lake volcanics as defined by Trowell,
Logothetis, and Caldwell (1980) occur in the north
western part of Figure 3.2. Here, they are composed
of intermediate to felsic pyroclastic rocks overlain by
a mafic tuff unit. Within the Gibi Lake area (Trowell in
preparation), the Gibi Lake volcanics consist of inter
calated fine to medium, intermediate pyroclastic
rocks, and fine mafic pyroclastic rocks. Around Rat
Lake in the Long Bay-Lobstick Bay area, the felsic to
intermediate pyroclastic rocks equated with the Gibi
Lake volcanics are predominantly fine.
The Warclub group overlies all other stratigraphic
subdivisions. Blackburn (1978) documented the exis
tence of pyroclastic rocks within the Warclub Series
of metasediments of Burwash (1934) and the War
club sediments of Davies and Watowich (1958). Fel
sic to intermediate pyroclastic rocks are found inter
bedded with metasediments throughout the Long
Bay-Lobstick Bay area. Since the structure and
stratigraphy of the metasediments and the interbed
ded pyroclastic rocks is complex within the area, the
author (GWJ) has grouped all of these rocks into the
Warclub group.
There are a number of different metasedimentary
rock types within the Warclub group: thinly bedded
arenite and quartzose siltstone; interbedded arenite
and wacke; wacke and magnetite ironstone; and
wacke alone. These lithologies are found in a number
of stratigraphic positions:
1. Thinly bedded arenite and quartzose siltstone
overlie the Gibi Lake volcanics north of Yellow
Lake.
2. Interbedded arenite and wacke underlie the Gibi
Lake volcanics north of Graphic Lake (Trowell,
1984, in preparation).
3. Interbedded arenite and wacke overlie the Gibi
Lake volcanics on Rat Lake.
4. Wacke and magnetite ironstone overlie the north
ern limb of the Black Lake volcanics at Bug Lake.
5. Wacke overlies the southern limb of the Black
Lake volcanics.
6. Intermediate pyroclastic rocks and wacke overlie
the Point Bay group south of Dryberry Lake.
7. Wacke overlies the Populus volcanics south of
Dirtywater Lake.
8. Interbedded wacke and arenite, and wacke over
lie and underlie the Berry River formation.
53
CHAPTER 3

1 Figure 3.3. Simplified

stratigraphic sections
- — — — — - Warclub within the Long
~--------- Group ------ Bay-Lobstick Bay area.
A ^ 3 V f Warclub The Gibi Lake section is
•7 •3 A ^7 Warclub Group
rt A *
* V \ •---.--r-----
Group from work by Trowell (in
^
A A •—---- Warclub Mafic preparation). Correlation
A V A
A y Group /* ^
•7* ^
Metavolcanics between the Gibi Lake
Gibi Lake V Gibi Lake VA V
A M < Metavolcanics
A
V A
*
Metavolcanics /'S and Rat Lake sections is
V V A y
A* 4 A C*
S V A
based on stratigraphic
Metasediments s V A Berry River similarity.
Meta- — — — **A*
s
^.^
4 V
V l/ sediments t- ±1 i-
* *
^ -7 TA* A A V 4 ^
V A*
t, -1
-7
^ -7
V ~r \ ^-^ 4 f

* "A-
T
-r ^ Dogtooth Lake A *- \
/l Metavolcanics Black Lake ^
-7
^
Black Lake
\1 Metavolcanics l'
W di LtlUU

v *-
-7
\ A A V Group
^ * <
\
-7
t". \ -1-7 h\-
y A -i -7
Point Bay
Group
GIBI LAKE RAT LAKE BLACK RIVER LONG BAY

North of Black Lake Metavolcanics South of Black Lake Metavolcanics

arenite T A 4 v) mafic pyroclastic rocks

wacke o^A^l felsic to intermediate pyroclastic rocks
v\ mafic flows -^--— stratigraphic tie lines not to scale

9. Wacke interdigitates with and is probably the also used 152 analyses from a previous study by
distal sedimentary equivalent of the Berry River Goodwin (1970) and 67 analyses by Morrice (1977).
formation northwest of Mist Inlet (see Figure 1.35, Jensen cation plots (Jensen 1976) of the lower
Chapter 1, this volume). most mafic volcanic sequences are shown in Figure
These lithologies, in their various stratigraphic 3.4. There is some scatter of the data, and no ob
positions, are commonly interbedded with intermedi vious trend from komatiitic to magnesian tholeiitic is
ate pyroclastic rocks. Numerous formations may ulti present. These sequences were previously designat
mately be defined within the Warclub group, and ed (Trowell, Blackburn, and Edwards 1980) as mag
much additional work will be required to determine nesian tholeiitic flows (MTF). Except for a few flows
their inter-relationships. At this time, no coherent with komatiitic chemistry, there is no evidence (for
stratigraphic model exists to explain this sequence. It example spinifex texture) to indicate the presence of
may be that within the Long Bay Lobstick Bay area, true komatiites.
this group represents the interfingering of several Mixed sequences of felsic to intermediate
sedimentary environments and periods of deposition. pyroclastic rocks and subordinate flows, and mafic
The Berry River formation has been dated at flows and subordinate pyroclastic rocks are
2713.9 Ma by Davis and Edwards (1982), and is volumetrically the predominant volcanic assemblages
assumed on the basis of its stratigraphic position to in the study area. Plots for each of nine sections are
be younger than the Black Lake volcanics, Gibi Lake given in Figure 3.5 (from Trowell, Blackburn, and
volcanics, and Point Bay group. South of Berry Lake, Edwards 1980). New data for the Central Volcanic
the Berry River formation is a south-facing homoclinal Belt is given in Figure 3.6 (from Blackburn ef at.
sequence within the Warclub group proper and over 1982). There is a considerable scatter of data points
lies part of that group with slight unconformity. with samples falling in both the calc-alkalic and
The Berry River formation has been subdivided tholeiitic fields, but predominantly the calc-alkalic
into volcanic facies (see Chapter 1, this volume). Two field. Because all suites contain samples that plot in
ages or events of deposition have been interpreted. the tholeiitic and calc-alkalic fields, these were des
A unit of quartz-feldspar porphyry associated with the ignated (Trowell, Blackburn, and Edwards 1980) as
younger age overlies rocks related to the older event. tholeiitic to calc-alkalic flows and pyroclastic rocks
The younger event is believed to be located at the (TCFP).
eastern extremity of the Berry River formation, south- Plots from 5 thick upper mafic sequences are
east of Berry Lake. shown on Figure 3.7 (modified after Trowell, Black
burn, and Edwards 1980). Data from Morrice (1977)
LOCAL GEOCHEMICAL SYNTHESIS for the Snake Bay volcanics are presented in Figure
3.8.
A first evaluation of major element analyses (Trowell,
Blackburn, and Edwards 1980) of more than 1000 Data presented by Morrice (1977) show that the
samples supports and augments the general stratig rocks of the lower mafic group exhibit little or no
raphic relationships outlined above. The authors have chemical variation; K20 content is very low, generally

54

Northern
Volcanic Belt
92 points
AI 203
^.10 070 ; Ti02 content is O 070 ; while FeO (total) is
between 1007o and 13 070 . With increasing stratigraphic
height in the middle mafic group, AI 2O3, CaO, and
MgO decrease in amount, while FeO (total), Ti02,
Na20, and P 205 increase.
Morrice's (1977) samples when plotted on the
AFM ternary diagram of Irvine and Baragar (1971)
and the AI-Fe-Mg cation plot of Jensen (1976) as
shown in Figure 3.8, show that the lower mafic group
and middle mafic group of flows are magnesium
tholeiitic basalts and iron tholeiitic basalts, respec
tively.
As noted previously (Trowell, Blackburn, and Ed
wards 1980), the Katimiagamak Lake volcanics are at
the base of the sequence in the Kakagi Lake area
(Figure 3.7). While the Katimiagamak volcanics were
then correlated with the entire Snake Bay formation, it
would appear that chemically (Figure 3.8) they only
compare with the middle mafic section of that forma
tion. The lower mafic section of the Snake Bay For
mation has not yet been correlated with any mafic
metavolcanic suite in the immediate area.
Figures 3.7 and 3.8 show that although there is
considerable scatter of data, the majority of samples
fall in the tholeiitic field, with a tendency to be on the
high-Fe side of the high-Mg/high-Fe divider. Also, in
contrast to magnesium tholeiitic flow sequences,
there is a tendency towards Fe enrichment. These
assemblages were previously (Trowell, Blackburn,
N.F. TROWELL AND G.W. JOHNS
Figure 3.4. Jensen cation
plot for Jutten volcanics,
Northern volcanic Belt,
and Wapageise
volcanics, showing their
tholeiitic, relatively
magnesian character
(from Trowell,
Blackburn, and Edwards
1980).
MgO
and Edwards 1980) designated as Fe-tholeiitic flows
(FTF).
REGIONAL GEOCHEMICAL SYNTHESIS
The distribution of the three types of volcanic suites
is shown on Figure 3.9. Some general trends are
apparent.
Lower mafic flow sequences are tholeiitic and,
apart from Katimiagamak Lake and perhaps the mid
dle mafic section of the Snake Bay Volcanics, they
tend to be predominantly magnesian tholeiites. Mid
dle mixed sequences of Figure 3.9 are highly vari
able and in general show a distinct calc-alkalic trend.
Upper mafic flow sequences are predominantly Fe-
tholeiitic.
GEOCHRONOLOGY
In an attempt to test, and in many cases refine the
correlations proposed in the study area, a radiometric
dating program using precise uranium-lead zircon
ages was initiated in the late 1970s under the direc
tion of D.W. Davis of the Royal Ontario Museum,
Toronto. Several publications in the early 1980s
(Davis ei al. 1982; Davis and Trowell 1982; Davis and
Edwards 1982) have presented numerous ages for
various volcanic sequences and plutonic rocks
throughout the study area. A summary of these ages
is presented in Figure 3.10 (from Blackburn et al.
1982). As yet, none of the lower magnesian tholeiitic
55
CHAPTER 3

Figure 3.5. Jensen cation

Lower plots for Rowan Lake
Wabigoon volcanics, Kakagi Lake
Volcanics volcanics, Lower
154 points Wabigoon volcanics,
(82 from Manitou Lakes section,
Goodwin, North and South
1970) Sturgeon Lake
Rowan Lake
volcanics, and
Beckington Road and
47 points
(24 from
Morgan Island sections
\ Goodwin, of the Northeast Arm
1970) volcanics showing their
calc-alkalic to tholeiitic
character (from Trowell,
FeCH-Fe 2 O3*TiO Blackburn, and Edwards
1980).
\ Manitou
Section
98 points

Kakagi Lake
30 points
(18 from
Goodwin,
1970)

Handy Lake Volcanics

69 points

North Northeast Arm Volcanics

Sturgeon Lake (Beckington Road Section)
Volcanics 79 points
72 points

South Sturgeon Lake Volcanics

49 points A, Q
MgO
Northeast Arm Volcanics
(Morgen Island Section)
107 points

56
 N.F. TROWELL AND C. W. JOHNS

Fe 2 O3*FeO*TiO 2 Fe 2 O3 *FeO*TiO 2 Figure 3.6. Jensen cation

and AFM plots of recent
data from the Central
Volcanic Belt, Sioux
Lookout area (from
Trowell etal. 1983),

AI 203 MgO AI 20 3 MgO

Figure 3.7. Jensen cation

Upper Wabigoon Volcanics
plots for Brooks Lake
volcanics, Katimagamak
34 points
(28 from Goodwin 1970), volcanics, Boyer Lake
volcanics, Upper
Wabigoon volcanics,
and Central Sturgeon
Lake volcanics, showing
their tholeiitic, relatively
Fe-rich character (from
Trowell, Blackburn, and
Edwards 1980).
Katimiagamak Volcanics
34 points

AI 2 O 3 MgO
Central Sturgeon Lake
Volcanics
70 points

Boyer Lake Volcanics

27 points
Brooks Lake Volcanics
61 points

57
CHAPTER 3

FeO sequences have been dated mainly because of the

(total) lack of zircon-bearing phases in them, so the total
time span of volcanism represented in the study area
is still unknown. Future uranium-lead zircon dating
programs and the use of new dating techniques
should resolve this problem. One of the youngest
volcanic sequence so far dated is the Berry River
formation situated in eastern part of the Lake of the
Woods area. Age dating in the Lake of the Woods
area proper will determine whether or not the appar
ent younging of volcanic sequences from Savant
Lake southwest to Kakagi Lake is in fact a valid
interpretation.

STRATIGRAPHY AND GOLD MINERALIZATION

A brief discussion of mineral deposits in the study
area was published previously (Trowell, Blackburn,
and Edwards 1980). Since that time, however, there
has been renewed interest in gold exploration. For
example, the Goldlund Deposit, southwest of Sioux
Lookout, is at present being mined; a new gold occur
rence has been discovered by Steep Rock Mines
Na 2OK 20 MgO Limited at Sturgeon Lake, and numerous other known
occurrences or past producers such as the St. An
thony Mine at Sturgeon Lake are being re-examined.
Berry River In a previous publication (Trowell, Blackburn, and
analyses from Morrice Formation
(1977) Edwards 1980), it was suggested that three broad
Snake Bay categories of gold occurrences can be recognized in
Formation the area: 1) those related to volcanic and subvol
canic stratigraphy, 2) those occurrences associated
with later felsic intrusions cutting the volcanic stratig
raphy, and 3) occurrences situated within quartz
veins having, as yet, no apparent relationship to
volcanic activity or igneous intrusions. These cate
gories were defined on the basis of lithologic control,
and were not meant to imply genetic relationships, or
to rule out the importance of structural control in the
localization of gold deposits. Additional categories
that could be added include gold occurrences in
carbonated, commonly silicified shear zones (for ex
ample, Cameron Lake), and gold occurrences situ
ated in mafic volcanic rocks at the greenschist am
phibolite metamorphic facies interface.
A guide to areas of gold potential could be the
recognition of favourable "packages" of lithologies.
Al Mg For example at Armit Lake west of Savant Lake, the
following lithologies are present: mafic volcanic
rocks, carbonatized ultramafic rocks (one komatiitic
flow), chert magnetite-iron silicate sulphide iron for
mation and intermediate to felsic tuffaceous rocks.
These lithologies suggest active volcanism, with qui
Figure 3.8. Jensen cation and AFM plots of the escent periods when deposition of iron formation and
Berry Creek Complex and Warclub group, and outpourings of mafic and ultramafic lava occurred; an
Snake Bay formation (analyses from Morrice environment which could be considered to be
1977). favourable for gold mineralization.
In the Long Bay-Lobstick Bay area, gold occurs
in silicified-carbonatized shear zones, feldspar por
phyry, and granitoid stocks. Probably the association
having the most economic potential is that of the
silicified carbonatized shear zones within mafic
metavolcanics. The most extensive shear zone is the
Pipestone-Cameron Fault. Within the Long Bay-Lob
stick Bay area a significant gold occurrence is found
within this fault zone between Regina Bay and Reed
Narrows. Here, the Wabigoon Fault and the

58
 N.F. TROWELL AND G.W. JOHNS

tholeiitic to calc-alkalic flows and pyroclastic rod Figure 3.9. Sketch map
to show distribution of
magnesian-tholeiitic flows the three volcanic
iron-tholeiitic flows suites in the study area.

sediments
granitic rocks
iron formation
faults

WABIGOON SUBPROVINCE

O SABASKONG GNEISS

O HERONRY DIORITE

O STEPHEN LAKE STOCK (POST TECTONIC)

O KATIMIAGAMAK GABBRO
KAKAGI LAKE,
1———*—————— BERRY CREEK COMPLEX
ATIKWA LAKE
*-*-~ TUFF, TOP OF KAKAGI LAKE GROUP

'—*—— GABBRO, KAKAGI SILL

—*— SABASKONG BATHOLITH

-*- DACITE, DASH LAKE

— TAYLOR LAKE STOCK (POST TECTONIC!

1————*———————————————' TUFF, BOYER LAKE VOLCANICS MANITOU STORMY

LAKES
THUNDERCLOUD PORPHYRY •—9 — --
'——*——' ATIKWA BATHOLITH, DORE LAKE

'——*———- RHYOLITE. CONTACT BAY EAGLE WABIGOON

—*—' ATIKWA BATHOLITH, EAGLE LAKE LAKES
-*- DACITE, EAGLE LAKE .

O TUFF, ABRAM GROUP

SIOUX LOOKOUT
-*— TUFF. NEEPAWA GROUP

—9—— TUFF. TOP CYCLE, SOUTH STURGEON LAKE VOLCANICS

LOWER CYCLES, t-*-" SOUTH STURGEON LAKE VOLCANICS

STURGEON LAKE
1———*———' GABBRO, PIKE LAKE

preliminary data BEIDELMAN BAY PLUTON

O
published data, error bars represent a 9596 confidence E- HANDY LAKE
VOLCANICS
SAVANT LAKE

2690 2700 2710 2720 2730 2740 2750 2760

AGE (millions of years)

Figure 3.10. Zircon uranium-lead geochronology for Savant Lake-Crow Lake Area.

59
CHAPTER 3
Pipestone-Cameron Fault merge. Between Hope Lake
and the Kishquabik Lake Stock, recent discoveries of
gold have been made in smaller quartz-carbonate
shear zones cutting the Populus volcanics. Gold has
also been noted near feldspar porphyries within the
Berry River formation and the Populus volcanics.
The Regina Bay Stock is a tonalite body intruding
the Snake Bay formation. A past producer, the Regina
Mine, is situated on the south contact of the stock
with the mafic metavolcanics where auriferous quartz
veins cross the contact. There is potential for addi
tional occurrences in similar situations.
REFERENCES
Blackburn, C.E.
1978: Populus Lake-Mulcahy Lake Area in Savant
Lake Crow Lake Special Project, Districts of
Thunder Bay and Kenora; p.28-44 in Summary of
Field Work, 1978, by the Ontario Geological Sur
vey, edited by V.G. Milne, O.L White, R.B. Barlow,
and J.A. Robertson, Ontario Geological Survey,
Miscellaneous Paper 82, 235p.
Blackburn, C.E., Breaks, F.W., Edwards, G.R., Poulsen,
K.H., Trowell, N.F., and Wood, J.
1982: Stratigraphy and Structure of the Western
Wabigoon Subprovince and its Margins; Field Trip
Guidebook, Trip 3, Geological Association of
Canada-Mineralogical Association of Canada
Joint Annual Meeting, Winnipeg, Manitoba, 105p.
Burwash, E.M.
1934: Geology of the Kakagi Lake Area; Ontario De
partment of Mines, Annual Report for 1933, Vol
ume 42, Part 4, p.41-92.
Car, D.P.
1980: A Volcaniclastic Sequence on the Flank of an
Early Precambrian Stratavolcano Lake of the
Woods, Northwestern, Ontario; Unpublished Mas
ter of Science Thesis, University of Manitoba,
111p.
Davis, D.W., Blackburn, C.E., and Krogh, T.E.
1982: Zircon U-Pb Ages from the Wabigoon-Manitou
Lakes Region, Wabigoon Subprovince, Northwest
Ontario; Canadian Journal of Earth Sciences, Vol
ume 19, p.254-266.
Davis, D.W., and Edwards, G.R.
1982: Zircon U-Pb Ages from the Kakagi Lake Area,
Wabigoon Subprovince, Northwest Ontario; Cana
dian Journal of Earth Sciences, Volume 19,
p. 1235-1245.
Davis, D.W., and Trowell, N.F.
1982: U-Pb Zircon Ages from the Eastern Savant
Lake-Crow Lake Metavolcanic-Metasedimentary
Belt, Northwest Ontario; Canadian Journal of
Earth Sciences, Volume 19, p.868-877.
Davies, J.C., and Watowich, S.N.
1958: Geology of the Populus Lake Area; Ontario
Department of Mines, Annual Report for 1956,
Volume 65, Part 4, 24p.
60
Goodwin, A.M.
1965: Preliminary Report on Volcanism and Mineral
ization in the Lake of the Woods-Manitou Lake-
Wabigoon Region of Northwestern Ontario; On
tario Department of Mines, Preliminary Report
1965-2, 63p. Accompanied by Chart, scale 1:253
440.
1970: Archean Volcanic Studies in the Lake of the
Woods-Manitou Lake Wabigoon Region of West
ern Ontario; Ontario Department of Mines, Open
File Report 5042, 47p.
Irvine, T.N., and Baragar, W.R.A.
1971: A Guide to the Chemical Classification of the
Common Volcanic Rocks; Canadian Journal of
Earth Sciences, Volume 8, p.523-548.
Jensen, L.S.
1976: A New Cation Plot for Classifying Subalkalic
Rocks; Ontario Division of Mines, Miscellaneous
Paper 66, 22p.
Johns, G.W.
1981: MacQuarrie McGeorge Townships Area, District
of Kenora; p.22-25 in Summary of Field Work,
1981, by the Ontario Geological Survey, edited
by John Wood, O.L. White, R.B. Barlow, and A.C.
Colvine, Ontario Geological Survey, Miscella
neous Paper 100, 255p.
1982: Long Bay Area, District of Kenora; p. 15-18 in
Summary of Field Work, 1982, by the Ontario
Geological Survey, edited by John Wood, O.L.
White, R.B. Barlow, and A.C. Colvine, Ontario
Geological Survey, Miscellaneous Paper 106,
235p.
1983: Long Bay Area, District of Kenora; p. 11-14 in
Summary of Field Work, 1983, by the Ontario
Geological Survey, edited by John Wood, O.L
White, R.B. Barlow, and A.C. Colvine, Ontario
Geological Survey, Miscellaneous Paper 116,
313p.
Johns, G.W., and Davison, J.G.
1983: Precambrian Geology of the Long Bay-Lobstick
Bay Area, Western Part, Kenora District; Ontario
Geological Survey, Map P.2594, Geological Series
Preliminary Map, scale 1:15 840 or 1 inch to 1/4
mile. Geology 1982.
Johns, G.W., Good, D.J., and Davison, J.G.
1984: Precambrian Geology of the Long Bay-Lobstick
Bay Area, Eastern Part. Kenora District; Ontario
Geological Survey, Map P.2595, Geological
Series-Preliminary Map, scale 1:15 840 or 1 inch
to 1/4 mile. Geology 1982, 1983.
Johns, G.W., and Richey, Scott
1982: Precambrian Geology of the MacQuarrie Town
ship Area, Kenora District; Ontario Geological
Survey, Map P.2498, Geological Series Prelimi
nary Map, scale 1:15 840 or 1 inch to 1/4 mile.
Geology 1981.
Mackasey, W.O., Blackburn, C.E., and Trowell, N.F.
1974: A Regional Approach to the Wabigoon-Quetico
Belts and its Bearing on Exploration in Northern
Ontario; Ontario Division of Mines, Miscellaneous
Paper 58, 30p.

Morrice, M.G.
1977: Stratigraphic and Geochemical Evaluation of
Archean Greenstone Belts, Lake of the Woods-
Kakagi Lake Stormy Lake Regions Northwestern
Ontario; Unpublished Report, Centre for Precam
brian Studies, University of Manitoba.
Trowell, N.F.
In preparation: Geology of the Gibi Lake Area; Ontario
Geological Survey.
Trowell, N.F., Bartlett, J.R., and Sutcliffe, R.H.
1983: Geology of the Flying Loon Lake Area, District
of Kenora; Ontario Geological Survey, Report 224,
109p. Accompanied by Maps 2458 and 2477,
scale 1:50 000 and one Chart.
Trowell, N.F., Blackburn, C.E., and Edwards, G.R.
1980: Preliminary Synthesis of the Savant Lake-Crow
Lake Metavolcanic Metasedimentary Belt, North
western Ontario, and its Bearing upon Mineral
Exploration; Ontario Geological Survey, Miscella
neous Paper 89, 30p. Accompanied by Chart A.
N.F. TROWELL AND G.W. JOHNS
Trowell, N.F., Logothetis, J., and Caldwell, G.F.
1980: Gibi Lake Area, District of Kenora; p. 17-20 in
Summary of Field Work, 1980, by the Ontario
Geological Survey, edited by V.G. Milne, O.L
White, R.B. Barlow, J.A. Robertson, and A.C. Col
vine, Ontario Geological Survey, Miscellaneous
Paper 96, 201 p.
Wilson, H.D.B., and Morrice, M.G.
1977: The Volcanic Sequence in Archean Shields;
p.355-376 in Volcanic Regimes in Canada, edited
by W.R.A. Baragar, LC. Coleman, and J.M. Hall,
Geological Association of Canada, Special Paper
Number 16, 476p.
Wilson, H.D.B., Morrice, M.G., and Ziehlke, D.V.
1974: Archean Continents; Geoscience Canada, Vol
ume 1, Number 3, p. 12-20.
61
Chapter 4

Stratigraphic Correlation in the Wawa Area

R.P. Sage

CONTENTS ABSTRACT
Abstract.......................... 62 Strike-slip faulting and subsequent folding followed
Introduction .................... 62 by northwest left-lateral faulting created an unusually
General Geology ........... 62 complex structural pattern in the supracrustal rocks
of the Wawa area, Ontario. Stratigraphic correlation
Correlation Techniques 63 between faulted parts of the supracrustal sequence
Conclusions ................... 68 can be made based on the recognition of repeated
References ..................... 68 systematic compositional variation in the lithologic
package, facing directions, and a regionally continu
FIGURES ous band of iron formation. Rapid lithologic variation
in primary volcanic textures prevents correlation with
4.1. Sketch map showing location of the
Wawa supracrustal belt...................................... 63 in lithologic sections of similar composition.
4.2. Generalized geologic sketch map of Both gold and base-metal mineralization occur
mapped area of Wawa supracrustal within the first of four cycles of volcanism. Gold
belt................................................................... 64 mineralization is exclusively associated with the
fourth cycle of volcanism. Most known gold occur
4.3. Idealized composite stratigraphic rences which are located at roughly the same gen
section for the Ruth and Josephine eral position in the volcanic stratigraphy occur within
iron ranges ...................................................... 65 the thermal aureoles of granitic stocks, or within
4.4. Idealized schematic of facies in shallow-dipping shear zones or reverse faults dis
Michipicoten iron formation ......................... 65 playing carbonate and silica alteration. Except for a
4.5. Jensen cation diagram of oldest mafic to ultramafic stock which hosts disseminated
cycle volcanic rocks ..................................... 66 copper and nickel mineralization, most base-metal
4.6. Geologic sketch map of oldest cycle occurrences are quartz veins containing minor con
volcanic rocks ................................................ 67 centrations of base-metal sulphides.
Ontario Geological Survey mapping continues to
delineate areas of economic interest within the first
cycle volcanic rocks and to assess the economic
potential of later cycles of volcanism. An enhanced
understanding of stratigraphy in the supracrustal
rocks of the Wawa area will aid in the search for
additional deposits of gold and base metals.

INTRODUCTION
In 1979, the Ontario Geological Survey undertook a
program to map the main part of the structurally
complex Wawa supracrustal belt (Figure 4.1). Thus
far, six townships, totalling 560 km2, have been com
pletely mapped and mapping in parts of five others
has begun. Reports on this work are in preparation.
Before commencing mapping in 1979, examina
tion of previous work indicated a structurally complex
belt with a broad range of lithologies. in recognition
of the structural complexity, emphasis has been
placed on unravelling the framework of the supra
crustal sequences. Considerable time and effort has
been expended in determining facing directions with
in supracrustal sections, and in tracing fault zones
that subdivide the supracrustals into numerous
blocks. Mapping of this complex supracrustal pack
age is continuing.

GENERAL GEOLOGY
The Wawa supracrustal sequence consists of three
and possibly four cycles of volcanic rocks. Most of
the present mapping has been concentrated in the
first or oldest cycle of volcanism which is a north-
facing mafic-felsic sequence bounded beneath by

62

l l granitic, migmatitic rocks
Hill metavolcanics, metasediments
Sudbury Structure
sediments
the external granitic terrain and overlain by the lat
erally extensive Michipicoten iron formation. Within
the lower mafic part of the first cycle, a discontinu
ous sequence of intermediate to felsic volcanic rocks
locally capped with minor iron formation defines an
internal subcycle.
Overlying the Michipicoten iron formation and
lying beneath clastic sedimentary rocks is approxi
mately 1000 m of intermediate to mafic volcanic
rocks which defines part of second cycle volcanism.
The clastic sediments consist of wacke, siltstone,
argillite, and conglomerate. These sediments are
most likely the detritus from the intermediate to felsic
volcanic rocks representing the upper part of second
cycle volcanism. A volcanic centre associated with
second cycle volcanism is represented by the rocks
north of the Magpie River. Lateral correlation of the
sedimentary and volcanic rocks is difficult due to
faulting and folding (Figure 4.2). Within incompletely
mapped townships in the north-central part of the
belt, the clastic sedimentary rocks are overlain by
intermediate to mafic volcanic rocks which may de
fine a third cycle of volcanism.
South of Wawa, a caldera-like structure, defined
by the quartz diorite to granodiorite Jubilee Stock
enclosed in a partial ring of quartz-feldspar porphyry,
may represent a fourth cycle of volcanism (Sage
1979). Correlation of lithologic units across Wawa
Lake is difficult due to strike-slip faulting and possi
ble folding beneath Wawa Lake.
The supracrustal sequence at Wawa has been
subjected to strike-slip faulting, minor reverse fault
ing, and intense folding. The folding has become
recumbent, and in some areas of the belt such as in
Chabanel and Musquash Townships, the stratigraphy
is overturned.
After strike-slip faulting and folding, the supra
crustal sequence was broken into fault blocks by a
series of northwest-trending left-lateral faults. These
northwest-trending faults have been intruded by dia
P.P. SAGE
Figure 4.1. Sketch map
showing location of the
Wawa supracrustal belt.
base dikes, and minor post-dike deformation is lo
cally recognizable. In Late Proterozoic time, a car
bonatite complex was emplaced within the Archean
supracrustal rocks east of the town of Wawa (Figure
4.2). Numerous lamprophyre dikes which cut the
Wawa supracrustal rocks are probably the same age
as the carbonatite intrusion.
The structural complexity of the belt and the
broad spectrum of rock types present have made it
very difficult to unravel its structural and stratigraphic
relationships with certainty.
CORRELATION TECHNIQUES
Correlation between various fault-bounded lithologic
packages is difficult because of extensive strike-slip
and left-lateral faulting and folding. An iron formation
unit has proven the most reliable lithologic marker
horizon (Figure 4.2). The individual fault segments
are named after the segment of iron formation con
tained within each faulted block: that is, the Lucy iron
range, Eleanor iron range, and Josephine-Bartlett iron
range.
No single method of correlation by itself has
proven satisfactory in further refining the volcanic
stratigraphy of the area. Structure and stratigraphy
must be used together to unravel the framework of
the belt. Marker horizons are absent within the mafic
and felsic volcanic sections. Few texturally distinctive
lithologic units are present, this inhibits correlation
over short distances.
Lithologic correlation can be best made on the
basis of rock composition rather than physical fea
tures such as varioles, pumice, clast size or shape,
or pillow morphology. Major lithological contacts are
placed at rock compositional breaks which are not
necessarily time equivalent. Recognition of major
compositional breaks in combination with bedding
and facing attitudes permit correlation within and
between fault blocks.
63
CHAPTER 4

granitic rocks
quartz feldspar porphyry
and felsic intrusive rocks
mafic intrusive rocks
carbonatite
felsic volcanic rocks
mafic volcanic rocks
sedimentary rocks
iron formation
T— fault zone
syncline
anticline
inclined bedding, top unknown
bedding, top (arrow) from grain
gradation (inclined, vertical)
lava flow, top (arrow) from pillows

Figure 4.2. Generalized geologic sketch map of mapped area of Wawa supracrustal belt.

64

strike slip fault
100-300 iron formation
T
A A
(main unit)
300-400 felsic tuffs and breccia
0-70- ferruginous dolomite
60-100 mafic breccia
0-150 iron formation
30-120 altered mafic volcanic —
rocks MI
-iron formation .j
0-500
-felsic tuffs and breccia ^
(subcycle) o
mafic intrusive rocks
4800-5000
massive and pillowed
mafic volcanic rocks
felsic intrusive rocks
Hawk Lake
metres granite complex
RUTH and JOSEPHINE IRON RANGE
STRATIGRAPHIC SECTION
Figure 4.3. Idealized composite stratigraphic sec
tion for the Ruth and Josephine iron ranges.
Note the stratigraphic position of the ferrugin
ous dolomite and mafic breccia.
The Michipicoten iron formation represents a pe
riod of chemical clastic sedimentation during a hiatus
between first and second cycle volcanism.
Within the central mafic part of the oldest cycle,
a discontinuous zone of felsic volcanic rocks defines
an internal subcycle (Figure 4.3) which is locally
capped with iron formation. The felsic volcanic rocks
of the subcycle consist of tuffs, lapilli-tuffs, quartz-
feldspar-phyric crystal tuffs, and minor amounts of
breccia. The iron formation of the subcycle consists
of a lower sulphide and upper chert member and is
narrower and more discontinuous than the iron for
mation that caps the major cycle. Carbonate facies
(that is, siderite) have not been observed in this iron
formation, and the chert-magnetite and graphite-argil-
lite facies are either absent or poorly developed.
Carbonate facies iron formation has been reported to
be present in the Kathleen iron range which is part of
the internal cycle (Assessment Files Research Office,
Ontario Geological Survey, Toronto (AFRO)).
By contrast, within the Michipicoten iron forma
tion, a consistent facies variation has proven to be a
reliable facing indicator. From bottom to top, the
commonly observed sequence is siderite, pyrite,
chert-magnetite-wacke, chert-wacke, and argillite-py-
rite (Figure 4.4). One or more of these facies may be
absent in any given area, but where two or more are
present, facing direction can be determined.
A mafic breccia at the top of the intermediate to
mafic part of the oldest cycle and a ferruginous
dolomite stratigraphically above the breccia have
proven to be reliable local marker horizons beneath
the Lucy, Ruth, and Josephine-Bartlett iron ranges
(see Figure 4.3). Mapping has disclosed numerous
P.P. SAGE
mafic volcanic rocks
argillite,
graphite, pyrite
chert,
graphite, argillite
chert, wacke
chert, magnetite
chert, pyrite,
siderite
massive pyrite,
minor siderite
siderite, pyrite
massive siderite
felsic volcanic rocks
MICHIPICOTEN TYPE
IRON FORMATION
Figure 4.4. Idealized schematic of facies in
Michipicoten iron formation. Note sharp upper
and lower contacts and gradational internal
contacts.
magnetite-bearing flows in the mafic part of the early
cycle and these could be used as geophysical mark
er horizons.
The mafic breccia likely consists of more than
one flow unit and contains considerable carbonate.
The clasts are rounded to angular and more felsic
than the dark green to black matrix. They commonly
display both a reaction rim and a accretionary rim up
to 4 to 6 mm thick. The breccia unit, which displays
crude bedding and poor sorting, is locally polymictic
containing iron formation and sulphide clasts in addi
tion to felsic volcanic clasts, some of which are
vesicular and pumiceous.
The ferruginous dolomite associated with the
mafic breccia is fine grained, massive, and rusty
weathered, with a thinly bedded base. The unit com
monly displays a random criss-crossing pattern of
milky quartz stringers. The criss-crossing stringers of
quartz and rusty weathering make this unit easily
recognizable in the field.
The volcanic rocks of the oldest cycle consist of
a lower sequence of massive to pillowed volcanic
rocks of iron tholeiite composition (Figure 4.5). The
overlying felsic volcanic rocks consist of tuff, lapilii-
tuff, feldspar phyric crystal tuff, quartz-feldspar-
65
CHAPTER 4
FeOFe 2O3"TiO2
intermediate to felsic volcanic rocks
intermediate to mafic volcanic rocks
Wawa Lower Cycle Volcanic Rocks (cation
Figure 4.5. Jensen cation diagram of oldest cycle
volcanic rocks. Note strongly bimodal character
and big h- iron tholeiitic nature of mafic volcanic
rocks.
phyric crystal tuff, spherulitic flows, and coarse brec
cias of rhyolite to dacite composition. The calc-al
kalic and tholeiitic parts of the oldest cycle are com-
positionally strongly bimodal, implying no simple di
rect petrogenetic relationship (Figure 4.5).
The mafic and felsic volcanic rocks of the sec
ond cycle display primary structures similar to first
cycle rocks and are indistinguishable in the field
from first cycle volcanic rocks on the basis of ap
pearance.
The Hawk Lake granitic complex, which contains
inclusions of the mafic part of the oldest cycle, has
been dated by uranium-lead zircon techniques as
2888 ± 2 Ma (Turek 1983), and felsic tuffs imme
diately below the Michipicoten iron formation at the
Helen iron range have been dated by uranium-lead
techniques as 2749 ± 2 Ma (Turek et al. 1982).
Hence, on the basis of these isotopic ages, the
development of the oldest cycle exceeds 130 Ma.
The felsic volcanic rocks of the second cycle have
been dated by uranium-lead techniques as 2696 ± 2
Ma (Turek e t al. 1982).
Within the area mapped to the present, most
mineralization occurs in the oldest cycle (Figure 4.6).
Gold mineralization, by itself without any other asso
ciated economic mineralization, occurs in association
with the epiclastic tuffs of Cycle Four that have been
intruded by the Jubilee Stock.
On the basis of records on file in the Assessment
Files Research Office, Ontario Geological Survey, To
ronto, anomalous levels of copper and gold occur in
a minor iron formation unit overlying felsic volcanic
rocks within the mafic part of the oldest cycle. Sur
face samples collected during the present survey
66
have not yet fully confirmed these reports of anoma
lous copper and gold.
The value of the Michipicoten iron formation is its
iron content only. Geochemically anomalous values
of copper, nickel, gold, and zinc have been reported
(Assessment Files Research Office, Ontario Geologi
cal Survey, Toronto; Collins and Quirke 1926; Richter
1952) but again, surface sampling during the recent
mapping has not indicated anomalous base-or
precious-metal contents.
The gold showings in the southeastern part of
the region (Figure 4.6) are in most cases quartz veins
associated with shearing and carbonatization at
lithologic contacts. These showings appear to occur
regionally where metamorphic grade is transitional
from greenschist to lower amphibolite. This transition
is recognized in the field by decreasing carbonate
content and the appearance of amphibole. The am
phibole has been altered to chlorite suggesting that it
has undergone retrograde metamorphism.
The same gold showings all occur at approxi
mately the same distance from the contact of the
Hawk Lake granitic complex and may be related to
the thermal aureole of that complex. The possibility,
therefore, exists that 1 or more lithologic units once
contained gold that has been remobilized and con
centrated into veins or shear zones.
Base-metal showings are nearly all sulphide-
bearing quartz veins of limited extent, and are re
stricted to the lower part of the oldest cycle. The
most significant base-metal mineralization in the
mapped part of the belt involves disseminated cop
per and nickel sulphides with platinum values in a
mafic intrusion cutting volcanic rocks of the oldest
cycle. This body sharply crosscuts lithologic trends.
Immediately south of the disseminated copper and
nickel occurrence, a massive sulphide showing, 1 m
in width, occurs along a contact between mafic vol
canic rocks and a quartz porphyry intrusive rock.
Based on diamond drilling, this high grade copper,
zinc, and silver occurrence does not appear to be
traceable laterally or to cjepth.
A high grade silver, lead, and lead-bearing quartz
vein is the only mineralization found in the felsic part
of the oldest cycle and in fact, occurs in a quartz
diorite intrusion cutting the volcanic rocks. This
showing lies below the Helen iron formation and
appears to be quite small. Grab samples from this
vein exceed 40 ounces silver per ton.
South of Wawa, an area of gold mineralization
may be associated with the thermal aureole around
the Jubilee Granitic Stock which appears to be cen
tred within a caldera structure (Sage 1979; Figure
4.6). The central stock is of dioritic to granodioritic
composition, contains numerous blocks of volcanic
rocks, and locally displays an intrusive breccia mar
gin. The stock is exposed at a structurally high level.
An outer ring fracture is occupied by massive quartz-
feldspar porphyry that partly encloses the stock. The
gold commonly occurs within quartz lenses that cut
and are concordant with redeposited tuffaceous units
of andesitic to dacitic composition, marginal to the
granitic stock. These epiclastic tuffs are tentatively
interpreted to represent the fourth cycle of volcanism
in the Wawa area. Bedding in the tuffs dips away
 P.P. SAGE

LAKE
GRANITE

granitic rocks
quartz feldspar porphyry
and felsic intrusive rocks
mafic intrusive rocks
carbonatite
felsic volcanic rocks
mafic volcanic rocks
JUBILEE
STOCK sedimentary rocks
iron formation
-—T- fault zone
syncline
anticline
mineral occurrence

Figure 4.6. Geologic sketch map of oldest cycle volcanic rocks with more prominent mineral occurrences
and former producing mines.

67
CHAPTER 4
from the stock and strikes parallel to the volcanic -
plutonic contact. Lensoid in plan view, these
lithologic units occupy former topographic depres
sions on the flanks of the former volcano and repre
sent rapid subaqueous deposition of volcanic detritus
from the volcanic edifice which existed above the
Jubilee Stock.
Early studies of the gold deposits south of Wawa
classified the deposits as quartz veins (Frohberg
1937; Gledhill 1927). These investigators recognized
at least two ages of veining. The gold mineralization
was said to be associated with the older quartz veins
that display a sugary texture and contain minor con
centrations of sulphide, principally pyrite and chal
copyrite. Later, coarsely crystalline quartz veins were
described as barren with respect to gold and are
deficient in sulphides (Gledhill 1927; Frohberg 1935).
Samples of coarsely crystalline barren quartz vein
material collected during recent mapping generally
confirmed these observations.
Recently, a re-evaluation of several gold deposits
south of Wawa has been completed by Dunraine
Mines Limited under the direction of Mr. G. Harper
and Dr. P. Studemeister, Consulting Geologists. At
least some of the gold-bearing veins are presently
referred to as lenses and are interpreted to be sugary
quartzites, or in some cases, recrystallized cherty
tuffs deposited within a sequence of redeposited
tuffs on the flanks of a former volcano (H. Koza,
Dunraine Mines Limited, personal communication,
1983). The lenses are limited in exposure and lack
internal bedding and contain volcanoclastic frag
ments. The gold deposits are considered to have
formed either as subaqueous placers or as redeposit
ed gold-bearing cherty tuffs. This interpretation is
based on the presence of tuffs displaying good pri
mary sedimentary structures above and below the
Parkhill gold-bearing lenses, the crudely conformable
nature of some lenses, and the presence of gold-
bearing siliceous tuff lenses within the epiclastic
tuffs. Outlines of underground slopes on existing
mine plans suggest the possibility that meandering
streams may have influenced gold distribution. If this
model is correct, the source beds proximal to the
volcanic vent have likely been removed by erosion of
the former volcanic edifice above the Jubilee Stock,
however, the location of allocthonous deposits of
economic significance may be possible.
Gold also occurs as lenzoid quartz bodies within
altered early shear zones. These zones possibly re
present reverse faults that cut the Jubilee Stock. The
nature of these quartz lenses is uncertain and some
could be siliceous mineralized tuffs incorporated into
the faults. The reverse faults and strike-slip faults are
the oldest recognized faults in the Wawa area and
are offset by northwest-trending left-lateral faults. In
addition to silicification, the shear zones are car
bonated and contain minor disseminated pyrite.
68
CONCLUSIONS
In summary, geologic mapping in the Wawa area so
far has shown that major gold and base-metal min
eralization is largely restricted to one major mafic-
felsic volcanic cycle and that a period of solely gold
mineralization occurs in the latest cycle of volcanism.
Most base-metal occurrences are restricted to a
broad zone that parallels stratigraphy. Gold mineral
ization occurs in discrete lithologic units, in a broad
zone that is parallel to lithologic trends, and in the
thermal aureoles of granitic intrusions. Gold also oc
curs in early reverse faults in association with
silicification and carbonatization.
Due to the complex structure of the Wawa supra
crustal belt, much time consuming detailed mapping
is required to unravel the structure and stratigraphy
and to trace zones of economic interest. Plans for the
future are to continue mapping lower cycle volcanic
rocks and to complete additional mapping and eco
nomic evaluation of the volcanic rocks of the later
cycles. The mapping program will ultimately provide
the data base to permit identification of areas of
greatest mineral potential.
REFERENCES
Collins, W.H., and Quirke, T.T.
1926: Michipicoten Iron Ranges; Geological Survey of
Canada. Memoir 147, 173p.
Frohberg, M.H.
1937: The Ore Deposits of the Michipicoten Area;
Ontario Department of Mines, Annual Report for
1935, Volume 44, Part 8, p.39-83.
Gledhill, T.L
1927: Michipicoten Gold Area, District of Algoma;
Ontario Department of Mines, Annual Report for
1927, Volume 36, Part 2, p. 1-49.
Richter, D.H.
1952: Mineralogy and Origin of the Michipicoten Iron
Formations; Unpublished Thesis, Queen's Univer
sity, Kingston, Ontario, 97p.
Sage, R.P.
1979: Wawa Area, District of Algoma; p.48-53 in Sum
mary of Field Work, 1979, by the Ontario Geologi
cal Survey, edited by V.G. Milne, O.L White, R.B.
Barlow, and C.R. Kustra, Ontario Geological Sur
vey, Miscellaneous Paper 90, 245p.
Turek, A.
1983: The Evolution in Time of the Wawa-
Gamitagama Plutonic-Volcanic Terrains, Superior
Province, Northern Ontario; Geological Associ
ation of Canada, Mining Association of Canada,
and Canadian Geophysical Union, Program with
Abstracts, Volume 8, p.A70
Turek, A., Smith, P.E., and Van Schmus, W.R.
1982: Rb-Sr and U-Pb Ages of Volcanism and Granite
Emplacement in the Michipicoten Belt, Wawa, On
tario; Canadian Journal of Earth Sciences, Vol
ume 19, p. 1608-1626.
Chapter 5

Mineralization and Volcanic Stratigraphy in the

Western Part of the Abitibi Subprovince
L.S. Jensen

CONTENTS ABSTRACT
Abstract .......................................................................... 69 The distribution of mineralization in the western part
Introduction 69 of tne Archean Abitibi Subprovince is closely related
Regional Stratigraphy 'and Structuri""!!!! ~ 70 to the volcacnic sedimentary stratigraphy of the sub-
-. f . , t , .,. t A,.-*-.-' province. Supergroups composed of komatiitic,
Petrogenesis of the Western Ab.t.b. tholeiitic, calc-alkalic, and alkalic volcanic groups de-
bubprovince................................................................... 72 veloped during cycles of volcanism. Separate superg-
Mineraiization ................................................................ 72 roups can be recognized in different parts of the
Introduction ................................................................ 72 area. Mineralization repeatedly occurs in the same
Tectono-stratigraphic Setting.................................. 74 nthologies at the same stratigraphic position in each
Massive Copper-Zinc-Lead Sulphide Of the supergroups. Massive copper-lead-zinc depos-
Deposits ..................................................................... 75 jts, Iron Formation, and stratiform gold mineralization
Iron Ore Deposits ...................................................... 77 occur in the calc-alkalic phases of at least two super-
Stratiform Gold Mineralization ................................ 78 groups. Massive nickel deposits, and asbestos, mag-
Nickel Sulphide Deposits ........................................ 81 nesite, and talc deposits are associated with the
Asbestos, Magnesite, and Talc Deposits .............. 83 komatiitic flows and related intrusions. Lode gold
Lode Gold Deposits .................................................. 83 deposits are concentrated near the Kirkland Lake-
Summary ........................................................................ 84 Larder Lake and Destor Porcupine Fault Zones and
References..................................................................... 85 are associated with late alkalic volcanism and intru-
_____________________________ sions of the youngest supergroup.
TABLES________________________ A knowledge of regional stratigraphy and struc-
5. 1 Types of mineralization occurring in tu. re in combination with a geological model of green-
the western part of the Abitibi stone belt development allows interpretation of env.-
. n Subprovince
.t ^ . •••••"•••••••••••••••"•••••••••••••••••••••••••••••••••- 70 ronments
jhe favourablemodel
megacauldron for mineral
suggestsdeposit formation.
that base-metal
5.2 Stratigraphy of the volcanic sulphide deposits, iron formations, and stratiform
sequence m the western part of the go|d mjnera | ization are preferentially located in the
AbitiDi Belt............................................................. 77 centra | vent area sne|f and outer sne|f margins of a
mature calc-alkalic pile, respectively. Nickel mineral-
ization occurs where komatiitic lavas onlap rocks of
5.1 Map of the Abitibi Subprovince ......................... 70 an older calc-alkalic pile, whereas asbestos, talc, and
5.2 Geological map of the Timmins- magnesite occur in peridotitic sills with olivine-rich
Kirkland Lake area 71 cumulates which have been penetrated by hydrous

5- 3 !sar^^^
resulting from volcan.c cycles ..........................
5.4 Geological map of the Timmins area ...............
5.5 Geological map of the Kirkland Lake-
Larder Lake area .................................................
5.6 Geological map of the Kirkland Lake-
Noranda area........................................................
c- ~ . . . . 4 , . . ... L ...
5.7 Geological map of the LaKe Abitibi
area ........................................................................
5.8 Regional stratigraphic correlation for
the eastern part of the Abitibi
Subprovince..........................................................
5.9 Development of a primary
megacauldron above a mantle diapir...............
5.10 Development of a secondary
megacauldron marginal to a primary
meoacauldron south of Kirkland Lake .............
5.11 Distribution of komatiites and general
stratigraphy in the Timmins-Kirkland
Lake part of the Abitibi Subprovince................
72
72
73
where stratjform gO,d.Deari ng sedimentary rocks may
nave been deposited and buried by younger mafic
volcanic rocks.
74 _____________________________
INTRODUCTION
75 ———-—-————:————————;————-——
This chapter examines the general relationship be-
tween various types of mineralization and volcanic
7b stratigraphy in the western part of the Archean Abitibi
Subprovince of the Canadian Shield (Figure 5.1). Six
principal types of mineralization occur in this part of
76 the Abitibi Subprovince (Table 5.1). Numerous au-
thors have long recognized the close spatial associ-
78 ation between specific kinds of mineralization and
certain volcanic, sedimentary, and intrusive rock
types within mining camps (Goodwin 1965; Hutch-
79 inson 1973; Pyke 1976). However, attempts to inter-
^la(te minin9 famPs^haXe , met with, limited sV,cceSS
fC,olv,ne et al. 1984). On y recently has suf icient
80 information become available about the volcan.c
stratigraphy in this region to permit discussion of the
relationship between mineral deposits in the various
mining camps and the overall volcanic stratigraphy.

69
CHAPTER 5

Figure 5.1. Map of the

Abitibi Subprovince.

suggest where in the western part of the Abitibi

TABLE 5.1: TYPES OF MINERALIZATION Subprovince similar mineralization could be present.
OCCURRING IN THE WESTERN PART OF THE Volcanic stratigraphy can be an important guide
ABITIBI SUBPROVINCE. for mineral exploration, both on regional and local
scales. On a local scale, volcanic stratigraphy has
MINERALIZATION ASSOCIATED ROCK played an important role in locating additional min
TYPES eralization in many of the mining camps and will be
increasingly important as Archean volcanism and
1. Massive Cu-Zn-Pb Proximal and central crustal development becomes better understood.
Deposits vent calc-alkalic
volcanic rocks On a regional scale, volcanic stratigraphy serves
several purposes in the field of mineral exploration. It
2. Iron Ore Deposits Distal calc-alkalic provides an essential panoramic view of the variety
felsic tuffs, turbidic of rocks and their distribution, which gives insight
sedimentary rocks ± into patterns of Archean volcanism, sedimentation,
mafic and ultramafic and plutonism in a given greenstone belt. This in
volcanic rocks formation, when applied to more general models of
3. Stratiform Gold Turbiditic and chemical Archean greenstone belt development, helps in the
Deposits sedimentary rocks ± recognition of favourable environments for mineral
mafic and ultramafic deposit formation by comparing existing Archean de
volcanic rocks posits with more recent examples of mineralization.
As well, the distinctive types of mineralization found
4. Massive Ni-Cu Ultramafic volcanic in widely separated mining camps within a green
Deposits rocks ± turbiditic stone belt can be put in perspective.
sedimentary rocks and
calc-alkalic felsic tuffs Jensen (1981 a) and Jensen and Langford (1985)
proposed that the rocks of the western part of the
5. Asbestos, Ultramafic intrusive Abitibi Subprovince were formed by a series of
Magnesite, and Talc and extrusive rocks megacauldrons originating above mantle diapirs. This
Deposits model can be applied to explain the volcanic stratig
6. Lode Gold Deposits Alkalic felsic intrusive raphy, structural features, and metamorphism found
and extrusive rocks in this part of the Subprovince. It is the author's
opinion that folding and faulting were contempora
neous with volcanic activity and exerted control on
the volcanic stratigraphy and environments favoura
Numerous petrogenetic theories and models ble to particular types of mineralization (Jensen
have been proposed to explain the types of min 1981a, 1981 b).
eralization listed in Table 5.1. No single model ade
quately explains all the features which are asso REGIONAL STRATIGRAPHY AND STRUCTURE"
ciated with any of these types of mineralization. In The volcanic and sedimentary rocks of the Timmins-
this paper, brief reference will be made to various Kirkland Lake Noranda part of the Abitibi Sub
models as they relate to the volcanic stratigraphy. No province form a large east-trending synclinorium
exhaustive attempt will be made to prove or disprove (Figure 5.2). Domal tonalitic to trondhjemitic
any particular model; instead, the aim will be to batholiths and gneissic terrains are present north,
identify the stratigraphic environment in which par south, and west of the central synclinorium. Two
ticular types of mineralization tend to occur, and to major fault zones, the Destor-Porcupine Fault Zone
and the Kirkland Lake-Cadillac Fault Zone, transect

70
 LS. JENSEN

Figure 5.2. Geological

map of the Timmins-
K irk land Lake area.

ROUND
\ -h j -* -f
BATHOLI
4- -V -* -f
SOUTHERN 1

LEGEND

Proterozoic
Keeweenawan diabase (not shown) 7 7a, 7b, Kinojevis Group, 7c Kinojevis Group
12 Cobalt Group (Middle Fm., Tisdale Group)
Archean 6 6a Larder Lake Group, 6b Stoughton-
Matachewan diabase (not shown) Roquemaure Group, 6c Lower Fm., Tisdale
Granitic rocks Group
11 Granodiorite, monzonite, quartz 5 5c Porcupine Group
monzonite, syenite Lower Supergroups
10 Massive to gneissic quartz diorite, 4 4a Skead Group, 4b Hunter Mine Group,
tonalite, trondhjemite 4c Upper Fm., Deloro Group
Upper Supergroup 3 3a Catherine Group, 3c Middle Fm., Deloro
9 9a* Timiskaming Group, 9b* * Destor- Group
Porcupine Complex 2 2a Wabewawa Group, 2c Lower Fm., Deloro
8 8a, 8n, Blake River Group, 8c* * * Blake Group
River (Upper Fm., Tisdale Group) 1 1a Pacaud tuffs* ' * *

i refers to Kirkland Lake Area, south limb of synclinorium (Jensen 1978c, 1979).
*b refers to Kirkland Lake Area, north limb of synclinorium (Jensen 1976, 1978b).
* *c refers to Timmins Area (Pyke, 1980).
*** (Goodwin, 1965).

the northern and southern limbs of the synclinorium,
respectively, and numerous small plutons of
granodioritic to syenitic composition cut all the vol
canic and sedimentary rocks. Diabase dikes varying
from Archean to Late Proterozoic in age occur
throughout the area, and Proterozoic sedimentary
rocks of the Huronian Supergroup onlap the Archean
rocks from the south. Regional metamorphism of the
Archean rocks is subgreenschist facies (Jolly 1976,
1978; Gelinas era/. 1982).
A regional synthesis of the volcanic stratigraphy
of the Abitibi Subprovince has recently been pub
lished in Map 2484 (MERO-OGS 1983). The volcanic
rocks form a number of supergroups, which consist
of a group of komatiitic flows at the base, overlain in
turn by groups of tholeiitic lavas, calc-alkalic vol
canic rocks, and in places, alkalic lavas (Figure 5.3).
The various supergroups are shown on Figures
5.4, 5.5, 5.6. and 5.7. They include: the Deloro Group
(Pyke 1982) south of Timmins (Figure 5.4), the top of
which has been dated at 2725 ± 2 Ma (Nunes and
Pyke 1980); the Wabewawa-Catherine-Skead Superg
roup south of Kirkland Lake (Figure 5.5), dated at
2710 ± 2 Ma (P.D. Nunes, formerly with Royal Ontario
Museum, personal communication, 1982) and the Up
per Supergroup shown in Figure 5.6, the upper parts
of which have been dated at 2703 ± 2 Ma (Nunes
and Jensen 1980). The Upper Supergroup comprises
komatiitic flows of the Lower Tisdale Group (Figure
5.4), Larder Lake Group (Figure 5.5), Stoughton-
Roquemaure Group (Figure 5.7), and the Malartic
Group (Figure 5.6) (MERQ-OGS 1984). These
komatiitic successions are overlain by the tholeiitic
Kinojevis Group and calc-alkalic Blake River Group

71
 CHAPTER 5
Alkalic volcanic Gr.
•*~ sedimentary rocks.
Calc-alkalic volcanic Gr.
Volcanic ± sedimentary rocks.
Cycle
Supergroup
of a
megacauidron
Tholeiitic volcanic Gr.
Komatiitic volcanic Gr.
± sedimentary rocks.
Calc-alkalic volcanic Gr.
± sedimentary rocks,* alkalic
Volcanic '
volcanic rocks.
Cycle Tholeiitic volcanic Gr. Supergroup
Komatiitic volcanic Gr,
i sedimentary rocks.
Volcanic) Calc-alkalic volcanic Gr. /Super group
Cycle ± sedimentary rocks.
-H--H-
+ 4-H- Granitoid pluton
Figure 5.3. Illustration of stratigraphic column re
sulting from volcanic cycles.
(Figure 5.6). Alkalic flows of the Timiskaming Group
unconformably overlie the Kinojevis and Blake River
Groups. The apparent stratigraphic thickness of the
Wabewawa-Catherine-Skead Supergroup is 16 km
and the thickness of the Upper Supergroup is ^0
km. The Kidd Creek Rhyolites (2708 ± 2 Ma, Nunes
and Pyke 1980), Pacaud Tuffs, and Hunter Mine
Group (2710 ± 2 Ma, Nunes and Jensen 1980) are
considered to be the upper calc-alkalic parts of less
well preserved supergroups (Figures 5.4, 5.5, and 5.7,
respectively). Regional correlation of the volcanic
stratigraphy is presented in Figure 5.8 and Table 5.2.
PETROGENESIS OF THE WESTERN ABITIBI
SUBPROVINCE___________________
Jensen (1981 a) and Jensen and Langford (1985)
proposed that each supergroup represented a vol
canic cycle related to the development of a
megacauidron formed above a mantle diapir (Figure
5.9). The first magmas to reach surface formed
komatiitic and tholeiitic lavas. As the accumulations
of these flows thickened above the diapir, they sub
sided by downfolding and faulting, particularly in the
central parts of the megacauidron. With depth, under
increasing pressures and temperatures, the lower
core komatiites and tholeiites were transformed into
more dense amphibolite, garnet granulite, and ec
logite which further promoted subsidence of the
overlying rocks. At lower crustal and upper mantle
depths, the komatiites and tholeiites which had been
partly converted to eclogite began to undergo about
1007o partial melting. This resulted in the formation of
calc-alkalic magmas which then rose to the surface,
producing the observed change from tholeiitic to
calc-alkalic volcanism. A thick succession of calc-
72
alkalic volcanic rock accumulated in the core of the
megacauidron as the result of continued subsidence
and the simultaneous formation of volcanic edifices.
Ultimately, the partial melting of basal calc-alkalic
volcanic rocks resulted in formation of trondhjemitic
magmas which intruded the cores of the calc-alkalic
piles. Distal calcalkalic tuffs and sedimentary rocks
were deposited on the margins of these volcanic
piles. At depth, the garnet-bearing residuum from the
partial melting of the volcanic rocks sank farther into
the mantle.
In the older megacauldrons, where the calc-al
kalic piles formed sufficiently large masses, the
growth of core trondhjemitic rocks resulted in com
posite batholiths. The low specific gravity of the
trondhjemitic rocks caused the rocks near surface at
the centres of the megacauldrons to stop subsiding.
Instead, the denser marginal volcanic and sedimen
tary packages subsided by their supporting rocks
being drawn downward and inward under the batho
lith to replace eclogitic rocks sinking below it. At
surface, these marginal packages gradually tilted to
face away from the actual batholith. Marginal subsi
dence continued where accumulation of additional
komatiitic and tholeiitic rocks from a newly develop
ing megacauidron nearby overlapped the rocks of the
older megacauldrons, and resulted in these rocks
forming thick outward-facing homoclinal successions.
For example, the Round Lake. Lake Abitibi, and
Kenogamissi Batholiths were primary megacauldrons
(see Figure 5.2). The calc-alkalic volcanic Pacaud
Tuffs and Hunter Mine Group are all that remain of
the volcanic phases from these primary megacaul
drons (Figure 5.5 and 5.7). Succeeding megacaul
drons developed east of the Round Lake Batholith to
form the east-facing homoclinal Wabewawa-
Catherine-Skead Supergroup (Figure 5.10). The De
loro Group, and, north of Timmins, the Kidd Creek
Rhyolites (Figure 5.4) were formed east of the
Kenogamissi Batholith.
The youngest megacauidron developed in the
area is presently occupied by the Central Syn
clinorium (Figures 5.11 and 5.6). Initial komatiitic
flows at the base of the Upper Supergroup lapped
onto the rocks at the edges of the older megacaul
drons. Where these rocks are still preserved, they
serve to outline the youngest megacauidron. As vol
canism progressed, subsidence of the central
komatiitic and succeeding volcanic rocks occurred in
the central part of the megacauidron, largely by
downfolding and faulting along the Destor-Porcupine
and Kirkland Lake-Larder Lake Fault Zone. The loca
tion of these two fault zones is believed to approxi
mate the edges of the volcanic-sedimentary piles
associated with the earlier megacauldrons. Downfol
ding and faulting also occurred in the core of the
synclinorium during the accumulation of the calc-
alkalic Blake River Group (Figure 5.6).
MTNERALIZATION
INTRODUCTION
Pyke (1982) concluded that much of the mineraliza
tion in the Timmins area occurred near the contact
between the felsic volcanics and sedimentary rocks
of the older volcanic cycles (Deloro and Porcupine
 L.S. JENSEN

Granodiorite. Monzonite
and Syenite
Tonalite and Trondhjemite

Upper Formation,
Tisdale Group
Middle Formation,
Tisdale Group
,' (] Lowei Formation,
Tisdale Group
Sedimentary Rocks
Porcupine Group

Lower Supergroup
Upper Formation,
Deloro Group
Middle Formation,
Deloro Group
Lower Formation,
Deloro Group

----Geological Boundary
Synclinal Axis
Anticlinal Axis
— — Fault
— — Township Boundary
-J— Stratigraphic Top
Scale
5 o 5 10 Km

Figure 5.4. Geological map of the Timmins area.

73
CHAPTER 5
----'''
GRANITOID INTRUSIONS
E3 Granodiorite, Monzonite, Syenite
E3 Tonalite and Trondhjemite
Upper Supergroup
11 11 Timiskaming Group
l l Blake River Group
EZ3 Kinojevis Group
^'•~^ l ^ Larder Lake Group (vole., sed.)
Lower Supergroups
EH Skead Group
t"^-l Catherine Group
EH Wabewawa Group
H Pacaud Tulfs
Figure 5.5. Geological map of the Kirkland Lake-Larder Lake area.
Groups) and the komatiitic rocks of the younger vol
canic cycle (Tisdale Group) (Figure 5.4). The deter
mination of the significance of this stratigraphic con
tact is critical to the understanding of interrelation
ships between the gold, nickel, base-metal, talc, mag
nesite, asbestos, and iron ore deposits of the Tim
mins area, as is an assessment of the degree of
stratigraphical control of mineralization. It is also im
portant to determine whether or not possible stratig
raphic controls also apply in other mining camps in
the Abitibi Subprovince.
TECTONO-STRATIGRAPHIC SETTING
Base-metal, iron ore, and stratiform gold deposits
appear to have been closely associated with epi
sodes of calc-alkalic volcanism and sedimentation
during the development of the megacauldrons. In the
calc-alkalic volcanic piles, base-metal deposits are
found in the proximal and near vent flows and tuffs.
Away from the vent areas, banded iron formation
tends to be interbedded with distal tuffs and tuff-
breccias interlayered with sedimentary rocks com
posed of volcanic debris, chert, and in places, car
bon and carbonate that likely formed in shelf areas
marginal to the calc-alkalic pile. Farther away from
74
---
Stratigraphic Top
Geological Boundary
Syncline
Anticline
Fault
Township Boundary
Scale
O 6 10
the pile, where the shelves sloped steeply into neigh
bouring basins, stratiform gold deposits developed in
association with deposition of chert, carbonate units,
graphite, ironstone, and distal ash tuff. These min
eralized sediments tend to be interlayered with tur-
biditic wacke, mudstone, and congiomerate eroded
from the calc-alkalic volcanic pile. In the Abitibi Sub
province, the stratiform gold-bearing sedimentary
rocks occur interlayered with komatiitic and tholeiitic
flows that were laid down at the onset of volcanism
associated with the development of younger
megacauldrons in the neighbouring basins. Because
of tectonic activity along the shelf-basin interface
and the emplacement of komatiitic and tholeiitic mag
mas, the gold tends to be remobilized into fractures,
quartz and carbonate veins, and alteration zones. In
this chapter, these types of lode gold deposits are
distinguished from lode gold mineralization closely
associated with late alkalic extrusive and intrusive
rocks.
Massive nickel sulphide deposits and asbestos,
magnesite, and talc deposits are associated with the
komatiitic volcanic sequences of the megacauldrons.
The nickel mineralization is largely concentrated in
komatiitic flows that are in contact with sediments,
 LS. JENSEN

^OTEROZOIC
B Cobalt
RCHEAN
Granitoid Intrusions
] Q ranod t M ds

El Quart! Gabbro and Diorite

Upper Supergroup
intamino Cad li d
__ Ouparquet Groups Lower Supergroup
[_J Blake River Group til Porcupine Group and
E3 Kino evis Grou Lois Formation
Larder Lake, Stoughton-Roquemaure 53 Skead and Hunter Mine Grou
and Malart.c Grou s E3 Catherine Grou
123 Wabewa.a Group

Figure 5.6. Geological map of the Kirkland Lake-Noranda area.

felsic tuffs, iron formation, and calc-alkalic lavas of
the preceeding megacauldrons. Asbestos, magnesite,
and talc deposits are located in dunitic parts of
peridotitic stocks, sills, and thick komatiitic lava flows
that are found near the base of the komatiitic suc
cession and intruding the older rocks of the preceed
ing megacauldron.
Lode gold mineralization is also closely asso
ciated with the final magmatic phase of a megacaul
dron that typically produces alkalic felsic intrusive
and extrusive rocks. Gold is epigenetically concen
trated in quartz and quartz-carbonate veins, in frac
ture fillings, in alteration zones and contact metamor
phic aureoles, and in the felsic rocks themselves.
MASSIVE COPPER-ZINC-LEAD SULPHIDE DEPOSITS
Massive copper-zinc-lead sulphide deposits are lo
cated in the proximal and central vent facies of calc-
alkalic volcanic rocks in the Lower Supergroups as
well as in the Upper Supergroup formed by succes
sive megacauldrons. In the Upper Supergroup, the
main massive sulphide deposits are in the Blake
River Group (2703 ± 2 Ma, Nunes and Jensen 1980).
In the Lower Supergroup, they are located north of
Timmins associated with the Kidd Creek Rhyolites
(2708 ± 2 Ma. Nunes and Pyke 1980) (Figure 5.4). In
addition, the Normetal Mine, immediately northeast of
Lake Abitibi, is situated in calc-alkalic volcanic rocks
(Bertrand and Hutchinson 1973) which maybe part of
the Hunter Mine Group (2709 ± 2 Ma, Nunes and
Jensen 1980). These massive sulphide deposits have
accessory economic quantities of silver, gold, tin, and
cadmium.
The most favoured model for the formation of
massive copper-zinc-lead sulphide deposits consists
of hydrothermal solutions coming to surface and sub-
aqueously forming syngenetic sedimentary and near-
surface mineralization proximal to volcanic vents dur
ing periods of relative quiescence (Walker et al.
1975). Directly below the massive mineralization, the
older volcanic rocks exhibit "pipes" of alteration and
mineralization through which the hydrothermal solu
tions reached the surface. In the Noranda Mining
Camp, several massive sulphide deposits occur at
the same stratigraphic level, but others are situated
at different stratigraphic levels in the volcanic pile
(Spence 1975).
The hydrothermal solutions responsible for the
mineralization are thought to be a result of seawater
circulating through the volcanic pile and discharging
near its core. Metals are leached from the surround
ing volcanic rocks and precipitated in the zone of
discharge. Widespread leaching of copper, zinc, and
lead and associated alteration phenomena, however,
has been difficult to detect in the volcanic rocks of
the Noranda area.

75
CHAPTER 5

LEGEND
---- Geological Contact
ARCHEAN
-i— Syncline
Granitoids -J- Anticline
Granodiorite, Monzonite
[T] Tonalrte
Upper Supergroup
Blake River Group
Kinojevis Group
'J Stoughton-Roquemaure G

l\77r--*3^A -*
v:Mx/-"***-"
sH?^Slj tt&^Offi**^*
^V^;^:^:v^^^*SH^
J?--^'(,--S' **'** ' t" V/l/'vJ-^y ^

^: : ^^Y.'X'^^^^'^7,^^v^r'^R46l^E^/lLxE^^ .~l"
^M^Mi^f.r:!*M^
-*** xx
"x-' CENTRAL FAULT BLOCK

HARKER HOLLOWAY MARRI

Figure 5.7. Geological map of the Lake Abitibi area.

Figure 5.8. Regional

LEGEND
LV: Sedimentary Rocks
Erd Alkalic Volcanic Rocks
——
L^J Calc-alkalic Volcanic Rocks
f——
~i Tholeiitic Volcanic Rocks
stratigraphic correlation
for the eastern part of
poorl the Abitibi Subprovince.
expos
Stoughton-Roquemaure Gr
l

\(L , Komatiitic Volcanic Rocks

PORCUPINE F.Z.
TIMMINS *
~ Timiskaming Group
-v. Blake River Group
2703±2Ma
Kinojevis Group

Upper F Uncxposed
LAKE F.Z.
Deloro Group -

LarderL;
A A Skead Group 27 lot 2 Ma
Catherine Group l
Wabewawa Group
Pacaud Tuffs

76
 LS. JENSEN

TABLE 5.2: STRATIGRAPHY OF THE VOLCANIC SEQUENCE IN THE WESTERN PART OF THE ABITIBI BELT.
SOUTH OF TIMMINS NORTH OF TIMMINS LAKE ABITIBI QUEBEC KIRKLAND LAKE

Upper Fm Blake River Gr Blake River Gr

UPPER Tisdale Gr Blake River Gr
2703±2 2703± 2
SUPERGROUP 2703±2
Middle Fm
Kinojevis Gr Kinojevis Gr Kinojevis Gr
Tisdale Gr

Lower Fm Lower Fm Stoughton-

Roquemaure Gr Malartic Gr Larder Lake Gr
Tisdale Gr Tisdale Gr
r *~t—————-J2—-, (Sedimentary and

?- h-*-*" ~~*~t- -^-^^ Lois Fm

Volcanic Rocks)

Kidd Creek
Hunter Mine Gr Skead Gr
Rhyolite
LOWER
Porcupine Gr 2708 + 2 271012 2710 + 2
SUPERGROUP II
Catherine Gr

Wabewawa Gr
.^—————-^
II~^-7
Pacaud Tuffs
Upper Fm
Deloro Gr
LOWER
2725± 2 - - . ---?
SUPERGROUP 1 Middle Fm
Deloro Gr
- - - --?
Lower Fm
Deloro Gr
Pyke (1978a,1978b Pyke (1982) Jensen (1978b) Dimroth et al Jensen (1978c)
SOURCES OF 1982) (1982,1983a,1983b
Nunes and Pyke Nunes and Jensen Nunes, Pers. Comm.
INFORMATION Nunes and Pyke Nunes and Jensen
(1980) (1980) (1980) (1980) (1981)

An alternative model can be suggested if the
premise that calc-alkalic volcanic rocks are the prod
uct of 10 0Xo partial melting of tholeiitic and komatiitic
volcanic rocks of Jensen (1981 a) is accepted. Low
temperature melting components and most incompati
ble elements tend to be extracted during the early
stage of partial melting and concentrated in the melt.
For example, if the original partly melted mafic vol
canic rocks averaged 50 ppm copper, the generated
calc-alkalic volcanic rocks should contain ^00 ppm
copper rather than have an average of about 50 ppm
copper. It is probable that much of the copper and
other base metals are concentrated in the first 1 07o
partial melt, which separates as a sulphide-rich hy
drous solution from the silicate magma and is driven
toward the surface by heat from the volcanism. Every
10 km3 of mafic volcanic rock that was partly melted
would contain enough base metal to from a large
sulphide deposit for each 1 km3 of calc-alkalic rocks
formed.
In a vertically subsiding calc-alkalic volcanic pile
such as the Blake River Group (Jensen 1981 b), mas
sive sulphide deposits could readily form in a
"stacked" configuration at different stratigraphic lev
els, as well as occurring concentrated along specific
stratigraphic levels as described by Spence (1975).
In other megacauldrons where the calc-alkalic pile
has tilted sideways during its development (Figure
5.10), massive sulphide deposits would be more
deeply buried and difficult to detect. Elsewhere, em
placement of large tonalitic batholiths in the calc-
alkalic core of a megacauldron would cause massive
sulphide deposits to be assimilated, and/or sloped
away, or exposed and removed by erosion. This
erosion would result in the dispersion of the base
metals, iron, and sulphur into sedimentary rocks de
posited on the margins of the calc-alkalic piles and in
more distal basins.
Areas favourable for further base-metal explora
tion include the calc-alkalic volcanic rocks north of
Timmins, the Shaw and Halliday Domes south of
Timmins (Figure 5.4), the Hunter Mine Group south of
Lake Abitibi (Figure 5.7), and the Blake River Group
north of Kirkland Lake (Figure 5.6). Potential for
base-metal sulphides also occurs in the eastern
proximal facies of the Skead Group in Skead Town
ship south of Kirkland Lake (Figure 5.5).
IRON ORE DEPOSITS
At present, the only banded iron formation being
exploited for iron ore occurs at the Adams Mine in
Boston Township south of Kirkland Lake (Figure 5.5).
Here, iron formation is interbedded with cherty tuffs
and carbonaceous pyritic cherts near the base of the

77
CHAPTER 5
LEGEND
K-rich granitic rocks
Trondhjemite rocks
Sedimentary rocks
Calc-alkalic volcanic rocks
Dunite, pyroxenite and gabbro
Tholeiitic volcanic rocks
Komatiitic volcanic rocks
Primary crust-mantle
(carbonaceous chondrite)
-Eclogite
Partial melting
of eclogite
Granulite facies
O 6
Garnet-rich residuums
Figure 5.9. Development of a primary megacaul-
dron above a mantle diapir: a) Diapir above
which komatiitic flows accumulate; b) Subsi
dence of komatiitic flows and further accu
mulation of tholeiitic flows; c) Partial melting of
komatiitic and tholeiitic rocks resulting in a
calc-alkalic volcanic pile flanked by tuffs and
sediments; d) Partial melting of calc-alkalic vol
canic rocks resulting in tonalitic intrusions.
Larder Lake Group (Jensen 1978c). Komatiitic and
tholeiitic lavas directly overlie and underlie the de
posit, respectively. This iron formation was formed on
the margins of the Skead volcanic pile shortly after
komatiitic and tholeiitic lavas of the next volcanic
cycle began to accumulate on its northern edge
(Jensen and Langford 1985). Additional units of iron
formation occur below the Larder Lake Group in the
marginal depositional facies of the Skead Group
(Jensen 1981 a) and at the base of the volcanic
succession in the Pacaud Tuffs (Figure 5.5).
In the Timmins area, iron formation occurs toward
the top of the Upper Formation of the Deloro Group
78
around the Shaw Dome and farther south (Pyke
1978b, 1982) (Figure 5.4). Here, it is interlayered with
calc-alkalic tuffs and grades into argillites and car
bonaceous sedimentary rocks of the Porcupine
Group. Iron formation is also intercalated with the
distal tuffs and cherts of the calc-alkalic volcanic
Hunter Mine Group (Dimroth et ai 1973; Jensen and
Langford 1983) (Figure 5.7).
Thin beds rich in magnetite occur in the turbiditic
sedimentary rocks of the Larder Lake, Pontiac, and
Porcupine Groups. The deposition of banded iron
formation and beds of magnetic clastic sediments
appear to require shelf and basinal environments
marginal to maturing calc-alkalic piles where periods
of local volcanic quiescence commonly occurred.
Iron formation and clastic sediments rich in mag
netite appear to be rare in volcanic successions
where distal felsic tuffs and sedimentary rocks asso
ciated with calc-alkalic volcanism are lacking. Iron
formation is limited to absent in the Stoughton-
Roquemaure Group (Figure 5.7), Wabewawa Group,
Catherine Group, the upper part of the Larder Lake
Group (Figure 5.5), and the Kinojevis Group (Figure
5.6), which suggests that the development of iron
formation is not favoured during komatiitic and
tholeiitic volcanism. Banded iron formation is absent
in the Blake River Group calc-alkalic volcanic rocks
and in the proximal and central vent facies rocks of
the Hunter Mine Group and Skead Group. Hence, the
development of iron formation is largely limited to
marginal and basinal depositional facies of calc-al
kalic volcanic piles.
Exhalative and sedimentary models have been
suggested to explain iron formation deposition. Alter
ation pipes which may be related to the development
of overlying iron formation from exhalative fluids oc
cur in the Wawa Greenstone Belt (Goodwin 1966). In
the Timmins Kirkland Lake area, alteration pipes,
however, have not been identified for any of the
numerous units of iron formation. Unlike massive
sulphide deposits which are lensoidal, banded iron
formations tend to extend laterally for a km or more
with constant thicknesses and are interbedded with
relatively carbonaceous chert, cherty tuff, and argil
lites which may or may not contain disseminated
sulphides. The absence of banded iron formation in
the Blake River Group subaqueous proximal and near
vent volcanic rocks suggests that iron formation
tends to be developed in more distal parts of calc-
alkalic piles as observed in the Skead and Hunter
Mine Groups (Jensen and Langford 1983).
The strong association of iron formation with the
felsic tuffs and turbiditic sedimentary rocks favours
the model of Shegelski (1978) whereby iron forma
tions are deposited in basins marginal to eroding
volcanic piles. The silica and iron required for their
formation were possibly derived from a distant vol
canic exhalative source in the proximal or vent parts
of calc-alkalic piles.
STRATIFORM GOLD MINERALIZATION
Stratiform gold deposits are those gold deposits and
mines in which a significant part of their ore is
hosted by carbonaceous mudstones, wackes, tuffs,
cherts, iron formations and chemical carbonate-rich

Trondhjemite
stock
inal tuffs and basinal sediments
plex
t t
Komatiitic magmas
-Sinking eclogite
masses
a Initiation of komatiitic volcanism marginal to the calc-alkalic
volcano
Wabewawa Group
Catherine Group
\
x Cumulates of
fractionated
tholeiitic magma
b Development of the Wabewawa and Catherine Groups from mantle
derived magmas and the downward displacement of the Pacaud
tuffs and sedimentary rocks concomitant with the growth of the
Round Lake batholith.
Figure 5.10. Development of a secondary megacauldron marginal to a primary megacauldron south of
Kirkland Lake: a) Initiation of komatiitic volcanism marginal to the calc-alkalic Pacaud volcano; b)
Development of the Wabewawa and Catherine Groups from mantle derived magmas and the downward
displacement of the Pacaud Tuffs and sedimentary rocks concomitant with the growth of the Round
Lake Batholith; c) Initiation of calc-alkalic volcanism of the Skead Group by partial melting of the
subsiding eclogitic komatiitic and tholeiitic flows and cumulates; d) Cessation of calc-alkalic volcanism
and later deposition of the Cobalt Group sedimentary rocks.
sedimentary rocks. These deposits include the Kerr
Addison Mine and several smaller deposits in the
vicinity of Larder Lake, and the Pamour, Hollinger,
Owl Creek, and other major deposits in the Timmins
area. Also there is the recently discovered gold min
eralization east of Matheson in Holloway Township
(see The Northern Miner Press, December 27, 1984
issue). All of these deposits are located near, but not
directly on the Kirkland Lake-Larder Lake and Destor-
Porcupine Fault Zones. The gold-bearing sedimentary
rocks occur as interflow sediments to komatiitic and
tholeiitic flows, or are interlayered with coarse mass
flow turbiditic sedimentary rocks composed mainly of
locally derived volcanic detritus.
The komatiitic and tholeiitic volcanic rocks of the
Timmins and Larder Lake areas belong to the
komatiitic successions at the base of the Upper
Supergroup. In the Timmins camp, the flows form part
of the Lower Formation of the Tisdale Group (Pyke
1982) (Figure 5.4), which correlates with the Larder
Lake Group in the vicinity of Larder Lake (Figure 5.8).
In the Timmins and Larder Lake areas, the
komatiitic and tholeiitic lavas and the interflow sedi
mentary rocks are part of volcanic sedimentary suc
cessions deposited on the margins of older calc-
alkalic volcanic piles (Jensen and Langford 1985).
LS. JENSEN
Skead Group
Sinking eclogite
masses
C Initiation of calc-alkalic volcanism of the Skead Group by partial
melting of subsiding eclogitic komatiite and tholeiite flows
and cumulates.
Present erosional
surface
"o/ Primary crust?
Y
VjL
d Cessation of calc-alkalic volcanism and later deposition of
Cobalt Group sedimentary rocks.
Detritus from those older calc-alkalic volcanic piles is
also incorporated in the sedimentary rocks of the
succession.
Several models have been proposed for the gen
esis of stratiform gold mineralization. These models
can be group into three main types:
1. Gold was deposited with clastic and chemical
sedimentary rocks (for example, Hinse 1984;
Jensen 1981 a).
2. Gold was precipitated at and near surface by
hydrothermal solutions penetrating fractures
along the major fault zones during the accumula
tion of volcanic and sedimentary rocks (for ex
ample, Fyon and Crocket 1983; Karvinen 1981).
3. Gold was concentrated epigenetically in the
rocks along fault zones during late tectonism and
felsic igneous activity (Hodgson 1983; Colvine et
al. 1984).
In the first model, the source of gold is an older
eroding calc-alkalic volcanic pile where volcanism
and fumarolic activity had occurred or was still oc
curring and erosion of the pile was occurring. Gold
was transported in solution, and in colloidal and de
trital forms across the shelf of the volcanic pile and
selectively concentrated in sedimentary traps along
the tectonically unstable edges of the shelf at the
79
CHAPTER 5

.. .. 1^1 ".f* ^f-*-^Ui f I ft'^r^ D — _. .- ^T^*-Jj* .x. Z **-*L* \ *

Key
upper supergroup
volcanic rocks :
+\ 5 alkaline
Kenogamiss
4- + + + H 4 calc-a!kaline
Batholith M
* 'f -1- -t- +V V i
+V+I +
3 tholeiitic

* * A A -1
__ i l l S*f± + Round + Lake
+ •f + * + * +\ +V ^' /
V \/v , j———l n . 7-^- + + + + + + + + + -
•^ "^ * t *A 4-\ \ l * i WataLchewqn + + + + + + + + H-
+ + + +^+ X \ ' 1 s, + +~+ + + + •f + -^• + + ;
* * -1- \ V\ ^ \ /T + + + Batholith ^ + * ^
' ^ \ \ \ i S+. + + + + + + + + + 1 ' ^^^ 2 sedimentary rocks
\ \ \ l x^4- f + + + + + + + -^--
\ \ NV+.K * * -1- -1-
4- 4- 4- V
\ \ \ 'I++.+ + + + + + l calc-al kal ine and tholeiitic
\ volcanic rocks
\

50 km

Figure 5.11. Distribution of komatiites and general stratigraphy in the Timmins-Kirkland Lake part of the
Abitibi Subprovince (Jensen and Pyke 1982).

basin-shelf interface. The gold probably underwent form magnesite, dolomite, talc, and fuschite. Gold
several sedimentary reworkings prior to its final de and sulphides are concentrated along fractures and
position with carbonaceous muds, carbonates, cherts, quartz veins.
tuffites, and ferruginous sediments where sulphur- The Kirkland Lake-Larder Lake and the Destor-
rich reducing environments prevailed (see Springer Porcupine Fault Zones represent long-lived growth
1983). At the edge of the shelf, the gold-bearing faults (Jensen and Langford 1985). After the devel
sediments could be intercalated in a predominately opment of a calc-alkalic volcanic pile with sedimenta
sedimentary-tuffaceous succession as with other tion along its margins, komatiitic and tholeiitic vol
clastic sedimentary units as observed in the Hemlo canism related to the next volcanic cycle began in
deposits, or be interlayered with komatiitic and the adjoining basins. As this occurred, the basin
tholeiitic flows associated with a newly forming subsided with much of the displacement occurring
megacauldron as found in the Larder Lake and Tim along the basin-shelf interface where stratiform gold
mins area. deposits had formed. This deformation and asso
In stratiform gold deposits, much of the gold ciated metamorphism caused some of the gold to
occurs in quartz and quartz-carbonate veins and in migrate toward fractures (Jensen 1981 b). This model
shear zones which may have formed as a result of explains why stratiform gold deposits and the major
local komatiitic and tholeiitic volcanism and tectonic fault zones such as the Kirkland Lake-Larder Lake
movements. Huppert et at. (1984) pointed out that and Destor-Porcupine Fault Zones occupy the same
sedimentary rocks overridden by komatiitic magmas geological environment. A basin was present be
at 1400C to 17000C would be actively eroded and tween Timmins and Kirkland Lake with gold-bearing
assimilated by the komatiitic lava, resulting in exten sedimentary rocks being deposited at approximately
sive contamination and alteration of the lavas and the same time on its northern and southern margins
the overridden sedimentary rocks Silica, carbon, car (Figure 5.8). Subsequent filling of the basin with
bonate, alkalis, and water within the sediments would rocks of the Upper Supergroup caused subsidence;
be expected to strongly react with the magmas to much of the downward movement occurred along its

80

northern and southern margins forming the two major
fault zones.
In the second model, Fyon and Crocket (1983)
proposed that during the komatiitic volcanism and
sedimentation, seafloor alteration occurred due to hy
drothermal fluids consisting of modified seawater.
These fluids penetrated upward via fractures asso
ciated with the Destor-Porcupine and Kirkland Lake-
Larder Fault Zones and formed carbonate alteration
zones in the volcanic rocks. During intervals of vol
canic quiescence, exhalative action deposited aurif
erous cherty dolomite and pyritiferous graphite on the
seafloor. Fyon and Crocket (1983) discounted the
quartz-feldspar porphyries and the komatiitic lavas as
being significant sources of the gold mineralization in
the Timmins Mining Camp. More recently, Fyon et
a/. 1983 have suggested that gold was mainly intro
duced epigenetically by C02-rich fluids rather than
during the deposition of the supracrustal rocks of the
Timmins Mining Camp.
Support for the proposals of Fyon and Crocket
(1983) and Fyon et al. (1983) comes from the abun
dance of carbonatized komatiitic flows and
carbonate-rich sediments located near the Destor-
Porcupine and Kirkland Lake-Larder Lake Fault
Zones. Although komatiitic and tholeiitic flows under
lie large areas of the Abitibi Subprovince, the car
bonatized komatiites and carbonate-rich sedimentary
rocks are largely limited to the two major fault zones;
they are not extensively developed elsewhere.
Zones of carbonatized komatiitic flows with ex
tensive quartz veining are located in many places
along the length of the two major fault zones and are
not unique to the Timmins and Larder Lake Mining
Camps. Many of these other zones of carbonatization
have been subjected to intense exploration with little
success, which suggests that factors other than just
carbonatization and alteration must be critical to the
development of auriferous rocks in the vicinity of the
Destor-Porcupine and Kirkland Lake-Larder Lake
Fault Zones.
The epigenetic concentration of gold during late
tectonism and felsic igneous activity forms the basis
of the third group of models, and applies mainly to
lode gold deposits discussed later in this paper. Hod
gson (1983) and Colvine et al. (1984) have sug
gested that all the gold mineralization formed during
a late stage cratonic stabilization of the Superior
Province marked by felsic alkaline volcanism and
intrusion and that gold was introduced by magmatic
hydrothermal C02-dominated fluids. Support for this
model comes from the close association between
felsic intrusions and gold mineralization in lode de
posits and the fact that gold in stratiform deposits is
strongly associated with quartz veining. carbonate
alteration, and tectonic deformation. Stable light iso
tope data suggest magmatic sources have influenced
the mineralizing hydrothermal fluid in the deposits
considered to be stratiform. Colvine et al. (1984)
discounted sedimentary processes for concentrating
gold and instead, suggested that chemical sediments
such as carbonaceous rocks selectively collected
gold during hydrothermal activity.
Several features of the epigenetic model conflict
with field data. Much of the carbonatization found in
L S. JENSEN
the komatiitic flows must have occurred syn-
genetically, definitely predating Timiskaming vol
canism and sedimentation. Chemical and detrital car
bonate units occur within the Larder Lake Group.
Some are conglomeratic containing both carbonatized
and noncarbonatized, spinifex-textured komatiitic
clasts. Clasts of carbonatized komatiite commonly
occur in carbonate-poor conglomerates. These sedi
mentary rocks are interlayered with carbonatized and
noncarbonatized komatiitic lavas.
In the Timiskaming Group, extensive carbonatiza
tion is rare. However, carbonate detritus can be
abundant in the basal conglomerates and in a few
upper conglomeratic units higher in the Group, scat
tered carbonatized and noncarbonatized komatiitic
pebbles can be easily recognized. Thus, this car
bonate material appears to have been derived by
erosion of the earlier formed Larder Lake Group
(Jensen and Langford 1983). Along the Kirkland
Lake-Larder Lake Fault, carbonatized komatiitic lavas
and carbonate sedimentary rocks are juxtaposed
against unaltered Timiskaming Group rocks.
Local carbonatization of komatiitic flows oc
curred during the emplacement of syenite, monzonite,
and granodiorite bodies close to the Kirkland Lake-
Larder Lake Fault Zone and the Destor-Porcupine
Fault Zone. In these places, the intrusive rocks also
have carbonate-rich phases, and it is probable that
they assimilated carbonate during their emplacement.
Away from the major fault zones felsic alkalic intru
sive rocks and the associated carbonatization of the
host komatiites sharply decreases; instead, talc and
tremolite-rich rocks are formed where syenite, mon
zonite, and granodiorite cut the komatiitic flows.
The use of light stable isotopic evidence in sup
port of the magmatic fluid model for gold deposits
can be also questioned. Seawater during the Archean
was buffered by mantle-derived volcanic rocks unlike
present-day seawater which is buffered by continen
tal rocks (Veizer et al. 1982, Veizer, 1984). Light
stable isotope abundances in Archean seawater
would be difficult to distinguish from those of mag
matic origin derived from mantle and lower crustal
sources. The mantle is poor in gold relative to other
metallic elements, and, would probably have been
depleted in gold by earlier melting episodes to form
the host supracrustal rocks. Erosion of calc-alkalic
volcanic piles would serve to further concentrate gold
in restricted sedimentary environments of the crustal
rocks.
NICKEL SULPHIDE DEPOSITS
In the western part of the Abitibi Subprovince, nickel
sulphide mineralization occurs mainly near the base
of the komatiitic Lower Formation of the Tisdale
Group in the Timmins area (Pyke 1982) (Figure 5.4).
The largest and best studied deposits include the
Langmuir, Texmont, McWalters, Hart, Alexo, and Soth
man Deposits (Coad 1979). Similar nickel mineraliza
tion occurs in Lamotte Township, Quebec (Marbidge
Deposit) in the komatiitic flows of the Malartic Group,
and in the komatiitic flows and intrusions south of
Kirkland Lake and in the Munro Township area.
Disseminated low grade nickel mineralization is
present in many of the large gabbroic sills north of
81
CHAPTER 5
Timmins, particularly in the Kamiskotia Gabbroic
Complex (Wolfe 1970). These sills, although tholeiitic
in composition (Coad 1979), appear to be closely
associated with the komatiitic and tholeiitic flows of
the Lower Formation of the Tisdale Group (Pyke
1982).
The Lower Formation of the Tisdale Group and
Malartic Group are correlated with the Stoughton-
Roquemaure Group and Larder Lake Group (Figures
5.4, 5.5, 5.6, 5.7 and 5.8) (MEQ-OGS 1984). All four
groups are considered to represent the komatiitic
base of the Upper Supergroup formed during the
development of the youngest megacauldron. These
komatiitic lavas extended to overlap sedimentary and
tuffaceous rocks deposited on the margins of calc-
alkalic volcanic piles formed by earlier megacaul-
drons.
Sulphide mineralization consists of massive to
disseminated pyrrhotite, pyrite, pentlandite, and minor
chalcopyrite. Magnetite and chromite are common
and millerite, violarite, heazlewoodite, and sphalerite
can be present (Coad 1979). In the volcanogenic
deposits, mineralization, particularly where massive,
tends to be concentrated as nonconcordant lenses
near the base of peridotitic komatiitic flows. In some
deposits, mineralization extends upward into the mid
dle and upper parts of the host komatiite unit; in
others, mineralization locally crosscuts the base of
the host komatiite and extends into the underlying
rocks which are commonly calc-alkalic tuffs and tuff-
breccias and carbonaceous mudstones with asso
ciated iron formation.
Four genetic models have been proposed to ex
plain volcanogenic nickel sulphide mineralization
(Coad 1979). Naldrett (1966) proposed a sulphuriza-
tion model, whereby a reaction occurred between
sulphur from an external source and nickel-bearing
silicates. Sulphur could be introduced through melting
of pyritiferous sedimentary and volcanic rocks by
very hot (14000 to 17000C) with much komatiitic lava
(Huppert et al. 1984).
In a second model, Naldrett (1973) suggested
that magmatic sulphides formed liquid droplets im
miscible in the komatiitic magma brought up from
depth. As the lava flowed out on surface, the
droplets rapidly settled toward the base of the flow,
concentrating close to the feeder.
To explain certain features of the Kambalda De
posits in Western Australia not adequately covered
by Naldrett's second model, Ross and Hopkins
(1975) proposed that a sulphide magma could sepa
rate ahead of the komatiitic flow, and later be over
ridden by the flow.
Lusk (1976) proposed a volcanic exhalative
model to explain the abundance of pyrite and the
presence of other base-metal sulphides in nickel sul
phide deposits and in the underlying carbonaceous
sedimentary rocks and iron formation which com
monly form the footwall rocks. The exhalative model
fails to explain the magmatic textures found in many
of the deposits (Coad 1979).
Both the Abitibi and the Australian volcanogenic
nickel sulphide deposits tend to occur in an environ
ment where the host peridotitic komatiites have
82
flowed over calc-alkalic volcanic and sedimentary
rocks (Coad 1979). In the Timmins area, the
komatiitic flows overlie calc-alkalic volcanic rocks of
different ages. South of Timmins, the calc-alkalic
rocks are tuffs and tuff-breccias that grade into car
bonaceous argillites and iron formation deposited at
the edges of volcanic piles represented by the Upper
Formation of the Deloro Group dated at 2725 ± 2 Ma
(Jensen 1981 b). During the calc-alkalic volcanism,
tuffs and turbiditic sediments of the Porcupine Group
(Figure 5.8) were being deposited in basins to the
east of the Shaw Dome (Jensen and Langford 1983).
Later, a second calc-alkalic volcanic pile developed
north of Timmins (Kidd Creek Rhyolites, 2708 ± 2 Ma,
Nunes and Pyke 1980), and more sediments were
deposited in the areas to the southeast (Porcupine
Group, Figure 5.4). A volcanic pile represented by the
Halliday Dome also developed to the west of
Matachewan. Following this calc-alkalic volcanism
and sedimentation, widespread komatiitic volcanism
was initiated in the basins between these calc-alkalic
volcanoes. Komatiitic magmas cut through the calc-
alkalic volcanic and sedimentary rocks forming
stocks and sills and komatiitic flows (Pyke 1982). In
places, nickel mineralization appears to have formed
in the peridotitic komatiitic lavas as they came in
contact with the various older rocks.
Sulphur-poor peridotitic lavas contain from 1500
to 2500 ppm nickel which is concentrated in the
lattice of silicate minerals. Sulphurization of the basal
peridotitic flows overriding pyrite-rich sedimentary
and volcanic rocks appears to best explain the
stratigraphic location of the nickel sulphide deposits.
In many areas, particularly south of Kirkland Lake,
peridotitic komatiites, however, can be observed di
rectly overlying pyritiferous sediments and felsic tuffs
without the development of nickel sulphides.
The immiscible liquid model does not easily ac
count for the restriction of the largest sulphide de
posits to the base of the komatiitic successions. This
model requires that the initial magmas formed by
partial melting of the mantle and incorporated most of
the available sulphide liquid, leaving very little for
subsequent magma batches.
The magmatic textures and the restriction of
nickel sulphides to the base of the komatiitic succes
sion poses problems for the exhalative model and for
hydrothermal emplacement models that have been
suggested. Even though some alteration is present
near some nickel deposits, it is not as extensive as
can be found elsewhere in the komatiitic succession,
such as in zones around gold deposits and asbestos-
magnesite deposits. The exhalative model would re
quire nickel-bearing solutions reaching the surface to
precipitate as nickel sulphides on the seafloor prior
to the extrusion of komatiitic lavas. As the peridotitic
komatiite lavas flowed over the sulphides, they would
have to incorporate the sulphides to produce the flow
to result in the observed magmatic textures.
Regardless of the model selected to explain sul
phide mineralization, the most favourable environ
ment, seems to be the lower contact of the komatiitic
flows with iron formation, carbonaceous sediments,
and/or calc-alkalic tuffs and flows. In the Timmins
area, this environment is represented by the

komatiitic flows of the Tisdale Group where they are
in contact with calc-alkalic volcanic rocks and asso
ciated sedimentary rocks of different ages.
Similar stratigraphic settings occur in the Kirkland
Lake area (Figure 5.5) and the Lake Abitibi area
(Figure 5.7). South of Kirkland Lake, peridotitic
komatiitic flows of the Larder Lake Group and the
Wabewawa Group are in contact with calc-alkalic
tuffs, sedimentary rocks and tuffs of the Skead
Group and Pacaud Tuffs, respectively. In the Lake
Abitibi area, Stoughton-Roquemaure peridotitic
komatiites overlie the calc-alkalic volcanic rocks,
sedimentary rocks and iron formation contained in
the Hunter Mine Group.
ASBESTOS, MAGNESITE, AND TALC DEPOSITS
In the western part of the Abitibi Subprovince, asbes
tos, magnesite, and talc deposits occur in ultramafic
rocks associated with komatiitic volcanism at the
base of the Upper Supergroup (Pyke 1982). The ma
jor asbestos deposits are in Munro and Garrison
Townships south of Lake Abitibi, in Penhorwood
Township west of Timmins, and in Midlothian Town
ship near Matachewan (Figures 5.2, 5.4, and 5.7).
Magnesite and talc deposits in Deloro Township
south of Timmins (Pyke 1982) occur in large peri
dotitic sills which have extensive cumulates of
olivine toward their base.
Many peridotitic-gabbro sills in the western part
of the Abitibi Subprovince were explored in the 1950s
and 1960s and were found to contain only minor
amounts of asbestos. The main difference between
economic and noneconomic sills appears to be the
degree and type of alteration that took place during
or subsequent to their emplacement. Pods and dikes
of rodingite characterize the economic asbestos de
posits. Zones of pervasive carbonatization can occur
near and in contact with the asbestos mineralization
(Satterly 1952).
Asbestos cross-fiber occurs in closely spaced,
generally polygonal fractures associated with mag
netite in massive serpentinitized dunites. The frac
tures may have been cooling fractures, along which
hydrous fluids penetrated shortly after solidification,
or later, during subsequent hydrothermal events. The
asbestos deposits are located near, but not on the
Destor-Porcupine and Kirkland Lake-Larder Lake
Fault Zones which may have have been the foci of
extensive fluid movement. The deposits contain
footwall felsic tuffs and sedimentary rocks that may
have once contained trapped pore fluids. These
fluids percolated into the peridotitic sills because
these footwall rocks underwent compaction and in
creased temperatures associated with the emplace
ment of the sills.
In talc and magnesite deposits, the dunites and
peridotites, instead of being serpentinized, have been
transformed into talc and magnesite ± quartz by
pervasive penetration of C02-rich hydrous solutions
(see Pyke 1982). The talc and magnesite deposits
are hosted by strongly carbonatized mafic and ul
tramafic volcanic rocks.
Limited amounts of talc, magnesite, and serpen
tine slip-fiber are formed by the alteration and shear
L S. JENSEN
ing of peridotitic komatiite flows, both near alkali
felsic intrusive bodies and along faults, particularly
the Destor-Porcupine and Kirkland Lake-Larder Lake
Fault Zones. Chlorite, actinolite, quartz, and antigorite
are associated with the mineralization. Along the fault
zones, iron-dolomite, calcite, fuchsite, and in a few
places, gold and sulphide mineralization can also be
formed. However, gold and sulphide mineralization
are notably absent in the major deposits of talc,
magnesite, and asbestos, which again suggests that
factors other than C0?-rich hydrothermal fluids were
responsible for gold mineralization.
Peridotitic sills with olivine cumulates occur with
numerous other small subcircular unfractionated peri
dotite plugs and stocks cutting the lower parts of the
komatiitic succession of the Upper Supergroup and
the underlying calc-alkalic rocks of the Lower Super
groups (Figures 5.4, 5.5, 5.6, and 5.7). They probably
served as feeders to the komatiitic flows throughout
the western part of the Abitibi Subprovince. From
their distribution, they do not appear to have intruded
along any particular fracture zone. There seems,
however, to be greater potential for asbestos, talc,
and magnesite in large layered sills with olivine cu
mulates in close proximity to major fault zones such
as the Destor-Porcupine Fault Zone and the Kirkland
Lake-Larder Lake Fault Zone.
LODE GOLD DEPOSITS
Several gold deposits in the western part of the
Abitibi Subprovince appear to be epigenitically asso
ciated with the emplacement of late alkalic to subal
kalic felsic porphyritic to granitic textured intrusions
(Colvine et al. 1984). Gold mineralization is restricted
to veins, fractures, alteration zones and metamorphic
aureoles around these intrusions. In places, mineral
ization can be in the late granitic rocks themselves,
either as disseminated gold, or gold concentrated in
veins, fractures, and alteration zones. Included in this
group of gold deposits are the gold mines located
along the Kirkland Lake "Main Break" (Thomson
1950), the Ross Mine, Golden Arrow Mine, New
Keloro Mine located near Matheson, the Young Da
vidson Mine at Matachewan, and the mineralization
of the Garrison Stock in Garrison Township. The num
ber of major economic gold discoveries directly asso
ciated with these late felsic intrusions; however, is
small relative to the total number and volume of
these intrusions, and most of the discoveries to date
are limited to intrusions proximal the Destor-Porcu
pine and Kirkland Lake-Larder Lake Fault Zones.
The late alkalic to subalkalic felsic intrusions are
part of a large suite of intrusive and extrusive rocks
that is extremely variable in composition, texture, and
distribution. The felsic end members consist of
granodiorite, monzonite, quartz monzonite, syenite,
and sodium-rich syenodiorite, but ultramafic, mafic,
and intermediate phases including several varieties
of lamprophyre are common. The extrusive equiv
alents show a similar range in composition.
The late felsic intrusive rocks differ substantially
from rocks of the Round Lake and Lake Abitibi
Batholiths. The late felsic intrusive rocks tend to be
richer in alkalis, particularly potassium, and have
more numerous inclusions of country rock than the
83
CHAPTER 5
batholiths. Also the gneissic textures of the tonalitic-
trondhjemitic batholiths is lacking in the late felsic
intrusive rocks. The batholiths form domal structures
at the base of the volcanic succession, whereas the
late felsic intrusions tend to crosscut the rocks in all
parts of the succession without appreciably doming
the surrounding rocks.
The distribution pattern of the late alkalic intru
sions does not suggest preferential intrusion along
fault systems. The largest volume of these rocks
occurs between the Destor-Porcupine Fault Zone and
the Kirkland Lake-Larder Lake Fault Zone southeast
of Timmins. The Watabeag Batholith composed of
syenite and granodiorite, forms part of this group of
intrusions. The second largest concentration is be
tween the Round Lake Batholith and Kirkland Lake-
Larder Lake Fault Zone, and another concentration
occurs along the southern edge of the Destor-Porcu
pine Fault Zone from Timmins eastward to Harker
Township (Figure 5.2). Alkalic intrusive rocks are
rare, both north of the Destor-Porcupine Fault Zone
and in the area underlain by the Blake River Group
(Figures 5.6 and 5.7).
Alkalic volcanic rocks are abundant along the
Kirkland Lake-Larder Fault Zone and along the
Destor-Porcupine Fault Zone. They are interlayered
with Timiskaming clastic sedimentary rocks, cut by
the alkalic intrusive rocks. Porphyry clasts derived
from the intrusions are found within the sedimentary
rocks, further suggesting that the alkalic volcanic
rocks and intrusive rocks are directly related.
Studies on the alkalic intrusive and extrusive
rocks in the Kirkland Lake area (Watson and Kerrich
1983; Kerrich and Watson 1984) and in other Ar
chean terrains (Arth and Hanson 1975), suggest that
these rocks were derived from the partial melting of
sediments at crustal depths. The distribution of the
alkalic intrusive and extrusive rocks corresponds
closely to the areas of deposition and deep burial of
thick wedges of sedimentary rocks derived from the
erosion of calc-alkalic volcanic piles (Jensen and
Langford 1985) (see Figure 5.9). Before partial melt
ing occurred, these rocks underwent deep burial
caused by the younger accumulation of the 16 km
thick Wabewawa-Catherine-Skead Supergroup and
the 30 km thick Upper Supergroup (Jensen and Lang
ford 1983).
With the exception of the Kirkland Lake "Main
Break" zone and the Ross Mine, a very small propor
tion of the total number of alkalic intrusive bodies
explored have yielded mineable tonnages of gold
ore. Numerous small occurrences are present
(Hodgson 1983) as would be expected if the alkalic
intrusive and extrusive rocks were derived from the
partial melting of sedimentary rocks with normal to
slightly higher than normal background levels of gold
and other elements Reimer (1984). The distribution of
large mineable lode gold deposits associated with
the alkalic magmatism suggests either that gold oc
curred in anomalous quantities in isolated parts of
the precursory succession of sedimentary packages
that were dehydrated and partly melted, or that gold
was in anomalous concentrations in some of the
rocks encountered by the alkalic magmas enroute to
surface in the vicinity of the Destor-Porcupine and
84
Kirkland Lake-Larder Lake Fault Zones. The distribu
tion of lode gold deposits closely coincides with
areas favourable for stratiform gold mineralization in
the vicinity of the major fault zones (see Stratiform
Gold Mineralization). Lode gold deposits tend to oc
cur on the downfaulted side of the major fault zones,
and stratiform gold deposits tend to occur on the
upsides, where the older rocks are still exposed. For
example, along the southern side of the Kirkland
Lake-Larder Lake Fault Zone are the stratiform Larder
Lake Camp gold deposits; the Kirkland Lake Camp
lode deposits occur on the northern downfaulted side
(Jensen 1981 a; Jensen and Langford 1985). Simi
larly, along the northern side of the Destor-Porcupine
Fault there are the stratiform Timmins Camp deposits;
the Golden Arrow, Ross, and Garrison lode deposits
are found on the southern downfaulted side.
Careful study of the volcanic stratigraphy is re
quired to predict the location of possible lode gold
deposits. First, it is necessary to reconstruct the sedi
mentary facies relationship on the flanks of the older
calc-alkalic volcanic piles, particularly where the
more distal, gold-bearing shelf and basinal sedimen
tary rocks may have been deeply buried by younger
ultramafic and mafic volcanic rocks. Second, it is
necessary to look for structural discontinuities cros
scutting the younger volcanic and sedimentary rocks
and younger discordant intrusions which may have
caused the remobilization of gold and allowed it to
reach near surface along dilatant fracture zones. The
Destor-Porcupine and Kirkland Lake-Larder Lake
Fault Zones become broad dilatant zones near sur
face, and formed graben structures in which late
Timiskaming sedimentary and volcanic rocks accu
mulated and were preserved (Jensen and Langford
1985).
SUMMARY
Mineralization in the western part of the Abitibi Sub-
province is controlled, in large part, by volcanic and
sedimentary stratigraphy. Specific suites of volcanic
rock are favourable to certain types of mineralization.
Massive copper-zinc-lead deposits, iron formations,
and stratiform gold mineralization are associated with
calc-alkalic volcanism; nickel deposits and asbestos,
talc, and magnesite are associated with komatiitic
volcanism; and lode gold deposits are associated
with late alkalic to subalkalic felsic volcanism and
intrusion. These suites of rocks occupy discrete posi
tions in the stratigraphic column.
Mineralization is obviously not present every
where within each of these favourable suites. Depo
sitional environments conducive to the formation of a
certain type of mineralization must be present while
these rocks were being laid down, and these environ
ments must since have been preserved close to the
present bedrock surface for the mineralization to be
of economic value.
To recognize environments favourable to min
eralization, the explorationist must combine stratig
raphic and structural data with a geological model
concerning greenstone belt development. The
megacauldron model of Jensen and Langford (1983)
serves to show that base-metal, iron formation, and
stratiform gold deposits occur, respectively, in the

depositional proximal, shelf, and basin edge environ
ments of a maturing calc-alkalic pile, whereas, mas
sive nickel deposits are formed where komatiitic
flows lapped onto sedimentary and tuffaceous rocks
associated with older calc-alkalic piles. Asbestos,
talc, and magnesite deposits occur in olivine cu
mulates of sills near the base of the basal komatiitic
successions where they could be penetrated by intro
duced C02-rich and CO2-poor hydrous fluids. Lode
gold deposits are preferentially located near major
fault zones associated with late felsic intrusive and
extrusive rocks. Their gold may be derived from
deeply buried gold-bearing sedimentary and tuf
faceous rock, originally deposited at the unstable
shelf edge of a calc-alkalic pile.
Environments favourable for different types of
mineralization commonly overlap, as observed in the
Timmins area by Pyke (1982). Calc-alkalic piles were
developed both north and southwest of Timmins,
making the area favourable for base-metal, iron for
mation, and gold deposits. Komatiitic lavas and peri-
dotitic intrusions lapped onto the edges of these
calc-alkalic piles, and allowed massive nickel sul
phide as well as talc and magnesite deposits to be
formed.
In the Kirkland Lake-Larder Lake area, two calc-
alkalic piles developed in succession south of Kir
kland Lake. Iron formation and gold-bearing sedi
ments were deposited on the northern shelves and
basins followed by komatiitic volcanism and major
faulting along the shelf edges of the volcanic piles.
As a result, both stratiform and lode gold deposits
are found in these areas along with iron ore deposits.
Potential for base-metal deposits occurs in the near
vent and proximal calc-alkalic volcanic rocks in the
Blake River Group north of Kirkland Lake.
Environments favourable for the formation of
base-metal, gold, nickel, and asbestos deposits simi
lar to those of Timmins and Kirkland Lake are present
along the Destor-Porcupine Fault Zone east of
Matheson, south of Lake Abitibi, and along the Kir
kland Lake-Larder Lake Fault Zone in the
Matachewan area.
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Arth, J.G., and Hanson, G.N.
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Bertrand, C., and Hutchinson, R.W.
1973: Metamorphism at the Normetal Mine, North
western Quebec; Canadian Institute of Mining
and Metallurgy Transactions, Volume 76,
p.226-234.
Coad, P.R.
1979: Nickel Sulphide Deposits Associated With Ul
tramafic Rocks of the Abitibi Belt and Economic
Potential of Mafic-Ultramafic Intrusions; Ontario
Geological Survey, Study 26, 84p.
LS. JENSEN
Colvine, A.C., Andrews, A.J., Cherry, M.E., Durocher,
M.E., Fyon, A.J., Lavigne, M.J., Jr., Macdonald, A.J.,
Marmont, S., Poulsen, K.H., Springer, J.S., and Troop,
D.G.
1984: An Integrated Model for the Origin of Archean
Lode Gold Deposits; Ontario Geological Survey,
Open File Report 5524, 98p.
Dimroth, E., Boivin, P., Goulet, N., and Larouche, M.
1973: Preliminary Report on Tectonic and Volcanolog-
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partment of Natural Resources, Open File Report
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Dimroth, E., Imreh, L., Rocheleau, M., and Goulet, N.
1982: Evolution of the South-Central Part of the Ar
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and Paleogeographic Model: Canadian Journal of
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Dimroth. E., Imreh, L., Goulet, N., and Rocheleau, M.
1983a: Evolution of the South-Central Segment of the
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Evolution and Geomechanical Model: Canadian
Journal of Earth Sciences, Volume Two,
p. 1355-1373.
1983b: Evolution of the South-Central Segment of the
Archean Abitibi Belt, Quebec, Part III: Plutonic
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Fyon, J.A., and Crocket, J.H.
1983: Gold Exploration in the Timmins Area Using
Field and Lithogeochemical Characteristics of
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charts and two maps.
Fyon, J.A., Crocket, J.H., and Schwarcz, H.P.
Ontario Geoscience Research Grant Program, Grant
No.49 Application of Stable Isotope Studies to
Gold Metallogeny in the Timmins-Porcupine
Camp, Ontario Geological Survey Open File Re
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Maps in back pocket.
Gelinas, L., Mellinger, M., and Trudel, P.
1982: Archean Mafic Metavolcanics from the Rouyn-
Noranda District, Abitibi Greenstone Belt, Quebec
1. Mobility of the Major Elements; Canadian Jour
nal of Earth Sciences, Volume 19, p.2258-2275.
Goodwin, A.M.
1965: Mineralized Volcanic Complexes in the
Porcupine-Kirkland Lake Noranda Region,
Canada: Economic Geology, Volume 60,
p.955-971.
1966: The Relationship of Mineralization to Precam
brian Stratigraphy in Certain Mining Areas of On
tario and Quebec; Geological Association of
Canada, Special Paper Number 3, p.57-73.
Hinse, G.J.
1984: Gold Environment of the Larder Lake-Vir-
giniatown Area, Ontario: p.86-114 in Geological
Association of Canada Field Trip Guidebook 4,
Joint Annual Meeting, London, Ontario.
Hodgson, C.J.
1983: Preliminary Report on the Timmins-Kirkland
Lake Area Gold Deposits File; Ontario Geological
Survey, Open File Report 5464, 238p.
85
CHAPTER 5
Huppert, H.E., Sparks, R.S.J., Turner, J.S., and Arndt,
N.T.
1984: Emplacement and Cooling of Komatiite Lavas;
Nature, Volume 309, p. 19-22.
Hutchinson, R.W.
1973: Volcanogenic Sulphide Deposits and Their
Metallogenic Significance; Economic Geology,
Volume 68, p. 1223-1246.
Jensen, LS.
1978a: Geology of Thackeray, Elliott, Tannahill, and
Dokis Townships, District of Cochrane: Ontario
Geological'Survey, Report 165, 71 p.
1978b: Geology of Stoughton and Marriott Townships,
District of Cochrane: Ontario Geological Survey,
Report 173, 73p.
1978c: Archean Komatiitic, Tholeiitic, Calc-Alkalic
and Alkalic Volcanic Sequences in the Kirkland
Lake Area; p.237-259 in Toronto '78 Field Trips
Guidebook, edited by A.L. Currie and W.O. Mac
kasey, Geological Society of America-Geological
Association of Canada-Mineralogical Association
of Canada, 361 p.
1981 a: Gold Mineralization in the Kirkland Lake-Lar
der Lake Area; p.59-65 in Genesis of Archean,
Volcanic-Hosted Gold Deposits, Symposium held
at the University of Waterloo, March 7, 1980,
Ontario Geological Survey, Miscellaneous Paper
97, 175p.
1981 b: A Petrogenetic Model for the Archean Abitibi
Belt in the Kirkland Lake Area, Ontario; Un
published Ph.D. Thesis, University of Saskatch
ewan, Saskatoon, Saskatchewan.
Jensen, L.S., and Langford, F.F.
1983: Geology and Petrogenesis of the Archean Ab
itibi Belt in the Kirkland Lake Area, Ontario: On
tario Geological Survey, Open File Report 5455,
512p.
1985: Geology and Petrogenesis of the Archean Ab
itibi Belt in the Kirkland Lake Area, Ontario; On
tario Geological Survey, Miscellaneous Paper
123, 130p. Accompanied by Maps P.2434 and
P.2435, scale 1:63 360 or 1 inch to 1 mile and
sheet of microfiche.
Jensen, L.S., and Pyke, D.R.
1982: Komatiites in the Ontario Portion of the Abitibi
Belt; p. 147-157 in Komatiites, edited by N.T. Arndt
and E.G. Nisbet, published by George Allen and
Unwin, London, 526p.
Jolly, W.T.
1976: Metamorphic History of the Archean Abitibi
Belt; P.409-412 in Report of Activities, Part A,
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1978: Metamorphic History of the Archean Abitibi Belt
in Metamorphism in the Canadian Shield; Geo
logical Survey of Canada, Paper 78-10, p.63-78.
Karvinen, W.O.
1981: Geology and Evolution of Gold Deposits, Tim
mins Area, Ontario; p.29-46 in Genesis of Ar
chean, Volcanic-Hosted Gold Deposits, Sympo
sium Held at the University of Waterloo, March 7,
1980, Ontario Geological Survey, Miscellaneous
Paper 97, 175p.
86
Kerrich, R., and Watson, G.P.
1984: The Macassa Mine Archean Lode Gold Depos
its, Kirkland Lake, Ontario; Geology, Patterns of
Alteration and Hydrothermal Regimes; Economic
Geology, Volume 79, p. 1104-1130.
Lusk, J.
1976: A Possible Volcanic-Exhalative Origin for Len
ticular Nickel Sulphide Deposits of Volcanic As
sociation with Special Reference to Those in
Western Australia; Canadian Journal of Earth Sci
ences, Volume 13, p.451-458.
MERQ-OGS
1983: Lithostratigraphic Map of the Abitibi Sub-
province; Ontario Geological Survey/Ministere de
I'Energie et des Ressources, Quebec; catalogued
as Map 2484 in Ontario and D.V. 83-16 in Que
bec, Scale 1:500 000.
Naldrett, A.J.
1966: The Role of Sulphurization in the Genesis of
Iron-Nickel Sulphide Deposits of the Porcupine
District, Ontario, Canadian Institute of Mining and
Metallurgy Transactions, Volume 69, p. 147-155.
1973: Nickel Sulphide Deposits-Their Classification
and Genesis with Special Emphasis on Deposits
of Volcanic Association, Canadian Institute of
Mining and Metallurgy, Transactions, Volume 76.
p. 183-201.
Nunes, P.D., and Jensen, L.S.
1980: Geochronology of the Abitibi Metavolcanic Belt,
Kirkland Lake Area Progress Report p.34-38 in
Summary of Geochronology Studies, 1977-1979,
edited by E.G. Pye, Ontario Geological Survey,
Miscellaneous Paper 92, 45p.
Nunes, P.D., and Pyke, D.R.
1980: Geochronology of the Abitibi Metavolcanic Belt,
Timmins Matachewan Area-Progress Report,
p.34-38 Summary of Geochronology Studies,
1977-1979, edited by E.G. Pye. Ontario Geologi
cal Survey Miscellaneous Paper 92, 45p.
Pyke, D.R.
1976: On the Relationship Between Gold Mineraliza
tion and Ultramafic Volcanic Rocks in the Tim
mins Area, Northeastern Ontario; Canadian In
stitute of Mining and Metallurgy Bulletin, Volume
69, p.79-87.
1978a: Geology of the Redstone Area, District of
Timiskaming; Ontario Division of Mines, Geologi
cal Report 161, 75p. Accompanied by Maps 2363
and 2364, scale 1:31 680 or 1 inch to 1/2 mile.
1978b: Geology of the Peterlong Lake Area, Districts
of Timiskaming and Sudbury; Ontario Geological
Survey Report 171, 53p. Accompanied by Map
2345, scale 1:50,000.
1982: Geology of the Timmins Area, District of Coch
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141p. Accompanied by Map 2455, Scale 1:50
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Reimer, T.O.
1984: Alternative Model for the Derivation of Gold in
the Witwatersrand Supergroup, Journal of the
Geological Society of London, Volume 141,
p.263-272.

Ross, J.R., and Hopkins, G.M.F.
1975: Kambalda Nickel Sulphide Deposits: p.100-121
in Economic Geology of Australia and Papau New
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Monograph Series, Number 5, Australasian In
stitute of Mining and Metallurgy, Victoria Austra
lia, 1126p.
Satterly, J.
1952: Geology of Munro Township: Ontario Depart
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60, Part 8, 60p.
Shegelski, R.J.
1978: Stratigraphy and Geochemistry of Archean Iron
Formations in the Sturgeon Lake-Savant Lake
Greenstone Terrain, Northwestern Ontario;
Ph.D.Thesis, University of Toronto, 251 p.
Spence, C.D.
1975: Volcanogenic Features of the Vauze Sulfide
Deposit, Noranda, Quebec: Economic Geology,
Volume 70, p. 102-114.
Springer, J.
1983: Invisible Gold; p.240-250 in The Geology of
Gold in Ontario, edited by A.C. Colvine, Ontario
Geological Survey, Miscellaneous Paper 110,
278p.
LS. JENSEN
Thomson, J.E.
1950: Geology of Teck Township and the Kenogami
Lake Area, Kirkland Lake Gold Belt, Timiskaming
District; Ontario Department of Mines, Annual Re
port for 1948, Volume 57, Part 5, p. 1-29.
Veizer, J.
1984: Geological Evolution of Archean-Early Prot
erozoic Earth p.240-259 in Earth's Earliest Bio
sphere, Its Origin and Evolution, edited by J.W.
Schopf, 543p.
Veizer, J., Compston, W., Hoefs, J., and Nielsen, H.
1982: Mantle Buffering of the Early Oceans; Naturwis-
senschaften, Volume 69, p. 173-480.
Walker, R.R., Matulich, A., Amos, A.C., Watkins, J.J.,
and Mannard, G.W.
1975: The Geology of the Kidd Creek Mine; Economic
Geology, Volume 70, p.80-89.
Watson, G.P., and Kerrich, R.
1983: Macassa Mine, Kirkland Lake, Production His
tory, Geology, Gold Ore Types and Hydrothermal
Regimes; p.56-74 in The Geology of Gold in On
tario, edited by A.C. Colvine, Ontario Geological
Survey, Miscellaneous Paper 110, 278p.
Wolfe, W.J.
1970: Distribution of Copper, Nickel, Cobalt and Sul
phur in Mafic Intrusive Rocks of the Kamiskotia-
Whitesides area, District of Cochrane: Ontario
Department of Mines and Northern Affairs, Mis
cellaneous Paper 44, 28p.
87
Chapter 6
Developments in Stratigraphic Correlation: Western
Uchi Subprovince
H. Wallace , P.C. Thurston 1 , and F. Corfu2
Supervising Geologist, Ontario Geological Survey, Toronto
2Geochronologist. Royal Ontario Museum, Toronto
CONTENTS
Abstract.......................................
Introduction .................................
Background: Two Solitudes ..
Missing Links ..........................
A Second Look .......................
New Geochronology Data
New Geochemical Data ....
Revised Red Lake Stratigraphy .................
Economic Significance of Regional
Correlations ..................................................
Further Regional Comparisons and Their
Implications ...................................................
Summary .......................................................
References ....................................................
TABLE
6.1 Geochronology of the Western Uchi
Province ................................................
FIGURES
6.1. Location map showing the
distribution of supracrustal belts
within the Uchi Subprovince of
Northwestern Ontario ...................
6.2. Stratigraphic interpretation of the Red
Lake Belt .................................................
88
6.3. The first zone of pervasive
. 89 hydrothermal alteration identified in
the eastern part of the Red Lake Belt
. 89 relative to major gold deposits and
. 89 stratigraphic contacts.......................................... 90
. 91 6.4. Stratigraphic sections in the Uchi-
. 91 Confederation Lakes area.................................. 92
. 91
. 94 6.5. Geological map of the Uchi-
Confederation Lakes area.................................. 92
, 96
6.6. Geological map of the Red Lake Belt............... 93
. 97 6.7. Stratigraphic map of the Red Lake
Belt......................................................................... 93
. 99 6.8. Original regional stratigraphic
. 99 correlation map of the western Uchi
Subprovince.......................................................... 94
100 6.9. Geological map of the Red Lake Belt
— showing all geochronological data
_ available in 1983 ................................................. 95
6.10. Distribution of zones of pervasive
95 alteration in the Red Lake Belt
— relative to major gold deposits,
_ based on data available in 1983 ...................... 96
6.11. Location of deformation zones within
the Red Lake Belt ................................................ 97
6.12. Stratigraphic map of the Red Lake
89 Belt, 1983.............................................................. 98
6.13. Schematic cross-sections through
90 parts of the Red Lake Belt.................................. 98
6.14. Stratigraphic map of the western
Uchi Subprovince, 1983 ..................................... 99

ABSTRACT
The Red Lake and Uchi-Confederation Lakes Belts
together form the western Uchi Subprovince, part of
the Superior Province in Northwestern Ontario. In
1981, for the first time, geological mapping and
radiometric dating permitted correlation of stratig
raphy between these two Archean supracrustal belts.
A three-fold stratigraphic subdivision of volcanic
rocks (Cycles l, II, and III), previously established in
the Uchi-Confederation Lakes area, was extended
into the Red Lake Belt. Subsequent geological, geo
chemical, and geochronological tests of this correla
tion scheme, however, showed that some assump
tions made in the first comparison of the two belts
were invalid, and led to extensive revision of the
regional stratigraphic interpretation.
Base-metal deposits in the Uchi-Confederation
Lakes area, and gold deposits in both of these belts
are believed to be. at least in part, stratigraphically
controlled. The regional correlation presented allows
the application of mineral exploration criteria devel
oped in one belt, to the other, and calls attention to
parts of the belts which have seen little prospecting
activity in recent years.
Current mapping and research will determine
whether the general stratigraphic scheme developed
in this chapter can be applied to other supracrustal
belts in the Uchi Subprovince, and to northern
"greenstone" belts where mapping and preliminary
geochronological data suggest comparable patterns
of episodic volcanism.
INTRODUCTION
Several chapters in this Volume (Sage, Chapter 4;
Jensen, Chapter 5; Trowell and Johns, Chapter 3)
describe successful application of correlation tech
niques outlined by Trowell (Chapter 2) and Easton
and Johns (Chapter 1). It is also useful, however, to
W ENGLISH RIVER
Figure 6.1. Location map showing the distribution of supracrustal belts (shaded areas) within the Uchi
Subprovince of Northwestern Ontario.
H. WALLACE ETAL
examine some of the problems inherent in attempting
stratigraphic correlation and analysis in the Superior
Province. This chapter represents a case study of
attempts by the authors to correlate between the Red
Lake and Uchi-Confederation Lakes greenstone belts
(Figure 6.1), and to interpret relationships between
stratigraphy and mineral deposits of the western Uchi
Subprovince. The evolution of the stratigraphic
scheme devised by the authors between 1981 and
1984 and the accumulation of new and more refined
geological, geochronological, and geochemical data
illustrate the need to carefully test fundamental as
sumptions upon which such interpretations are
based. This history of incremental "improvement" in
our understanding of the regional geology also sug
gests that the stratigraphic picture proposed later in
this chapter should be viewed as only one more step
in a long, intriguing process.
BACKGROUND: TWO SOLITUDES
Both the Red Lake and Uchi-Confederation Lakes
Belts have long histories involving mineral explora
tion activity and government-sponsored geological
surveys. The Red Lake Belt, the site of one of
Canada's richest gold camps, has seen almost con
tinuous Ontario Department of Mines-Ontario Geologi
cal Survey mapping since the 1950s, and has been
explored for gold since the mid-1920s. However, the
only comprehensive survey of the entire area was
done by Horwood (1945). The many township-sized
maps and reports published more recently are by
several authors (Chisholm 1954; Ferguson 1965,
1966, 1968; Riley 1975, 1976, 1978a, 1978b; Pirie
and Sawitzky 1977a, 1977b; Pirie and Grant 1978a,
1978b; Pirie and Kita 1979a, 1979b, 1979c). none of
whom completed work on more than half of the 18
townships which make up the belt. This patchwork of
geological information reflecting changes and refine
ments in geological mapping and interpretation over
Lake St.Joseph-Pashkokogan Lake
89
CHAPTER 6

Figure 6.2. Stratigraphic

interpretation of the Red
GRAVES CALC-ALKALIC SEQUENCE Lake Belt (after Pirie
1981).
RED LAKE AREA
VOLCANIC SEQUENCES

BALL KOMATHTIC)
CALC-ALKALIC
ViiSEQUENCE

the last 25 years, has made correlation within the

K\\\\\V4zone of intense hydrothermal alteration
* major gold deposits n 111 n calc-alkalic sequence
i -t- -H felsic plutonic rocks l ~l lower mafic sequence
Figure 6.3. The first zone of pervasive hydrother
mal alteration identified in the eastern part of
the Red Lake Belt relative to major gold depos
its and stratigraphic contacts (Pirie 1981).
belt difficult. Structural and stratigraphic patterns
within the belt are still being unravelled.
Pirie (1981) made the first modern attempt to
explain the gross tectonostratigraphic features of the
Red Lake area based on his detailed mapping of the
eastern part of the belt, reconnaissance mapping
elsewhere, lithogeochemical data, and aeromagnetic
patterns. According to Pirie (1981), the belt consists
of two predominantly volcanic successions, a lower
tholeiitic to komatiitic sequence underlying the axial
portion flanked by calc-alkalic sequences occupying
the northeastern, southeastern, and northwestern cor
ners of the belt (Figure 6.2). These sequences were
believed to form an anticlinorium, but in fact, few
unequivocal facing directions and other structural
data were available for most parts of the belt.
The other notable conclusion emphasized by Pir
ie (1981) was the spatial association between highly
altered rocks in the lower tholeiitic to komatiitic se
quence and most gold deposits in the eastern part of
the Red Lake Belt (Figure 6.3).
By 1980, the southern part of the Uchi-Confed-
eration Lakes area had been mapped in detail,
thanks in large part to the discovery and develop
ment of the major copper-zinc deposits at South Bay
on Confederation Lake in 1968. In the hope of finding
more such deposits, the area was examined inten
sively by both government and exploration geologists
between 1968 and 1980. Detailed published maps of
the area include those by Pryslak (1970a, 1970b;
1971a, 1971b; 1972), Thurston et al. (1974; 1975a,
1975b, 1975c), Thurston and Jackson (1978), and
Johns and Falls (1976a, 1976b). The results of these
surveys allowed Thurston (1981 a) to develop a com
prehensive stratigraphic synthesis of this belt. Build
ing on the work of Goodwin (1967) and Pryslak
(1971 a). Thurston recognized three volcanic cycles
(Figure 6.4; Thurston 1981 a). The overall structure of

90

the belt proved to be a simple synclinorium (Figure
6.5; Thurston and Jackson 1978). Base-metal depos
its of the South Bay-type are restricted to the upper
most cycle, and are related to resurgent volcanism
following the formation and subsequent collapse of a
major caldera centred in that area (Thurston 1981 a).
Detailed lithogeochemical studies in the Uchi-
Confederation area showed that volcanic cycles are
far from simple entities. The three cycles follow the
classical mafic to intermediate to felsic trend de
scribed by Goodwin (1968). As in the Red Lake area,
the overall trends are toward more fractionated vol
canic products with time, however, both major and
trace element patterns indicate the operation of a
variety of complex magma-generating processes
(Thurston and Fryer 1983).
At the top of the second cycle there is a distinc
tive chemical metasedimentary sequence including
stromatoiitic carbonate on Woman Lake (Thurston
and Jackson 1978; Hofmann et al. 1985). Nunes and
Thurston (1980) determined the ages of these cycles
by applying the uranium-lead dating techniques of
Krogh (1973, 1982a, 1982b) to zircons from the felsic
rocks near the top of each cycle. The results (Figure
6.4), show that the difference in age between the
youngest volcanic products in consecutive cycles is
on the order of 100 to 130 Ma. The duration of
individual cycles and the length of the hiatuses be
tween cycles is unknown. This is a reflection of the
paucity of dateable felsic volcanic material in the
lower parts of individual cycles.
MISSING LINKS
On existing Ontario Geological Survey compilation
maps of the western Uchi Subprovince, the area
between Red Lake and Confederation Lake is largely
uncoloured (Ferguson ef al. 1970). Exposure is poor
because of the thick glaciolacustrine silt-clay over
burden, and most of the few known outcrops are of
high metamorphic rank. These problems prevented
effective stratigraphic correlation between the two
belts until 1981.
During the 1981 field season, Thurston (1981 b)
succeeded in tracing volcanic units of Cycles II and
III from Confederation Lake into the Gullrock Lake
part of the Red Lake Belt (Figure 6.6), using detailed
mapping, diamond-drill log data, and geophysical in
formation made available by Selco Inc. In the same
year, four uranium-lead ages on zircons from felsic
volcanic rocks in the Red Lake Belt were determined
(Thurston et al. 1981; Corfu and Wallace 1985).
These four ages, 2982, 2830, 2739, and 2733 Ma,
were originally obtained to test the tectonostratig-
raphic model that Pirie (1981) had proposed for the
Red Lake Belt, and indeed they did corroborate the
anticlinal nature of the belt (Figure 6.7). The very
close agreement between these dates and those in
the Uchi-Confederation Lakes belt, however, was
quite unexpected, and suggested that a three-fold
subdivision of volcanic stratigraphy might apply
across the region.
In order to extend this temptingly simple correla
tion framework through the Red Lake Belt, a number
of assumptions were made. The most convincing of
these, at the time, pertained to carbonate units. A
H. WALLACE ETAL
stromatoiitic marble unit overlying Cycle II volcanic
rocks at Woman Lake in the Uchi-Confederation
Lakes Belt; the felsic volcanic rocks below these
carbonate beds have been dated at 2840 Ma (Corfu,
unpublished data). At Red Lake, thick carbonate se
quences occur in two places (Figure 6.6). In the
central part of the belt, on northern McKenzie Island,
a massive sequence of dolomitic marble at least 100
m thick occurs. This is immediately underlain by
felsic to intermediate, heterolithic and monolithic
pyroclastic beds, one of which was dated at 2830 Ma
(Corfu and Wallace 1985). Hence, the McKenzie Is
land and Woman Lake carbonates appeared to oc
cupy similar time-stratigraphic positions.
At the western end of Red Lake, another car
bonate unit is exposed at and east of Pipestone Bay
(Figure 6.6). North of the bay, these rocks have been
metamorphosed to massive diopside-tremolite-
grossuiarite-bearing skarns. but elsewhere the car
bonate units commonly exhibit fine layering and oth
er sedimentary structures, which in several places
were positively identified as stromatolites (Riley 1972;
Hofmann ef al. 1985). Since stromatolite occurrences
in the Archean rocks of the northern hemisphere are
extremely rare, correlation between the Woman Lake,
McKenzie Island, and Pipestone Bay carbonate se
quences seemed a safe conclusion. Hence, the cor
relation of carbonate sequences formed the back
bone in of the regional stratigraphic scheme outlined
by Thurston ef al. (1981) (Figure 6.8).
A second point used in the correlation was based
on the assumption that the "mini cycles" defined by
Thurston (1981 a) in Cycle II at Confederation Lake as
60 to 120m thick, mafic to felsic sequences each
capped by chert and magnetitic iron formation, had
stratigraphic equivalents in the Red Lake Belt. For
example, on the southern side of Hoyles Bay, mafic,
intermediate, and felsic volcanic units are intercalat
ed with chemical and clastic metasediments over
comparable stratigraphic intervals. These sequences
appear to be roughly on strike with the carbonates on
McKenzie Island, assuming no major intervening
structural dislocations. In the area west of Pipestone
Bay, there is a similar rapidly alternating succession.
Taken together the carbonate and mini cycle correla
tions led to the conclusion that much of the western
and central parts of the Red Lake Belt were underlain
by rocks equivalent in age, and possibly genetically
related to Cycle II at Confederation Lake.
A SECOND LOOK
New Geochronology Data
In 1982, a second series of age determinations were
made to test the proposed correlation pattern. The
results of this series are summarized in Table 6.1
and Figure 6.9, and are obviously at odds with the
authors' first stratigraphic interpretation of the Red
Lake area. Although the new dates (column C, Table
6.1) fall roughly in the same age groups as the
original Red Lake and Confederation Lake data
(columns B and A, Table 6.1), the spatial distribution
of the dated rocks clearly shows that the areas in the
Red Lake Belt inferred to be of Cycle II age are much
older, roughly equivalent in fact to the oldest cycle
(2900 to 3000 Ma).
91
CHAPTER 6

A F Figure 6.4. Stratigraphic

^S?^? *-2840 G,.^^^ sections in the Uchi-
iiiiiiii my ~^^^
; J
Con federa tion L akes
c area (adapted from
D Thurston 1981 a).
^
^'J,V-N'^
pijl Section lines are shown
D
Plifer Mlni-Cvcle II :- 'r.'-.- in Figure 6.5.
J " " HT t\"0\yv^j
X
J
2^{?.i*, M my
''
Cycle 1
L'-~v1-'I.""' Cycle III

':-'i['^f:(
' C
k B, ^-2959
my L- V I,;-\|
J.-j'T'-V;' rnafic m

[::;:;:;:;|||:i|| interme
^ ^r^jjj^
i)^ v ^^^ felsic m

x
J
i | llllil lil ! c|astic
2 L- —••"l chemica
0 ,..........

HI
Ij::!:!:-:!^ granodiorite
granodi( and quartz feldspar porphyry
r ["•"•"•"l granitic
f A*

Figure 6.5. Geological

map of the Uchi-
Con federa tion Lakes
area (after Thurston e t
al. 1978). Cross-sections
are shown in Figure 6.4.
Map legend identical to
Figure 6.4.

92

TTj felsic plutonic and intrusive rocks \-\\\\\\****^
mafic intrusive rocks \\^\\
metasedimentary rocks ,\\\\
felsic metavolcanic rocksV
intermediate metavolcanic rocks +
mafic metavolcanic rocks \\\\
chemical sediments \\\\\\*
::::;: VOLCANICS CYCLE i:. :H. WALLACE, 1981:;
VOLCANICS CYCLE
VOLCANICS CYCLE
CLASTIC SEDIMENTS:;:
INTRUSIVE ROCKS X : : : : ::
•••-....•" | CHEMICAL SEDIMENTS
U/Pb ZIRCON AGE
In the western part of the Red Lake Belt, felsic
pyroclastic units just above and below the
stromatolitic carbonate unit were dated at 2925 and
2940 Ma, respectively. These dates closely bracket
the age of this marble, and discredit the assumption
that it is time equivalent to the McKenzie Island and
Woman Lake carbonates. Stromatolite-building organ
isms must have thrived in this region during two
periods: between 2925 and 2940 Ma as around
Pipestone Bay, and again after 2840 Ma at Woman
Lake.
The date of 2992 Ma from felsic pyroclastic
rocks on the southern side of Hoyles Bay prove that
the mini cycles there cannot be of Cycle II age.
H. WALLACE ET AL.
Figure 6.6. Geological
map of the Red Lake
Belt
Figure 6.7. Stratigraphic
map of the Red Lake
Belt (Thurston et a/.
1981). This
interpretation was
based in part on four
uranium-lead zircon age
determinations
performed in 1981.
In fact, no additional ages comparable to Cycle II
were obtained. The 2830 Ma date from northern
McKenzie Island was then severely scrutinized to
determine whether this unique age could be ex
plained by the mixing of two generations of zircons,
that is, from Cycle l (2900 to 3000 Ma) and Cycle III
(2730 to 2750 Ma) rocks. Petrographic study con
firmed that the dated rock is of heterolithic character;
all of the fragments are of felsic to intermediate
volcanic origin. Age determinations were then made
on several carefully separated, morphologically dis
crete populations of zircons from that rock. In all,
eight determinations were made, all of which in
dicated apparent ages between 2800 and 2835 Ma
93
CHAPTER 6
Cycle l
CIEZZZl Cycle II
Cycle III
U/Pb (my) zircon age
Figure 6.8. Original regional stratigraphic correlation map of the western Uchi Subprovince (Thurston et a/.
1981), integrating local interpretations shown in Figures 6.5 and 6.7.
(Corfu and Wallace 1985). Clearly, the original vol
canic rocks from which this heterolithic volcaniclastic
unit was formed had crystallized at a time roughly
equivalent to the Cycle II rocks at Confederation
Lake. In fact, the spread of ages found may reflect
the duration of Cycle II volcanism on a regional
scale.
Another notable discrepancy between the au
thors original stratigraphic interpretation and the new
geochronological data was evident south of Balmer-
town. A sample from a sequence of felsic pyroclastic
rocks, previously assumed to be of Cycle II age, was
dated at 2748 Ma. That sample was collected OOO m
from two sample sites to the north which gave an
age of 2964 Ma. (The preliminary age of 2982 Ma
reported by Thurston ef at. (1981) was later shown to
be too old due to the incorporation in the rock of
inherited zircon; new determinations yield an age of
2964 Ma for the unit (Corfu and Wallace 1985)). A
swamp between the two dated volcanic sequences
precludes direct examination of the intervening
stratigraphy; however, diamond-drill information sug
gests that they are separated by chemical and clastic
metasediments. There is no evidence of Cycle II
volcanic rocks in that area. An age of 2744 Ma was
also obtained from a rhyolitic unit at or near the top
of the tholeiitic to komatiitic sequence in Madsen
(Corfu, unpublished data). The gap in time of at least
200 Ma over such a small stratigraphic interval can
only be explained by the presence of a major break,
either a fault or an unconformity, between the two
volcanic sequences (that is, of Cycle l and Cycle III
age).
New Geochemical Data
In 1982, chemical analyses from several areas of the
Red Lake Belt became available, shedding new light
on stratigraphic problems, and on the relationships
between stratigraphy, alteration, and gold mineraliza
tion.
94
Of prime importance was the realization that the
major and trace element compositions of volcanic
rocks in the western part of Red Lake, in the north-
central part of the belt, and in Baird Township, were
quite similar to those documented in the Balmertown-
Cochenour area (Pirie 1981). Komatiitic rocks and
primitive tholeiitic basalts are the predominant
lithoiogies in all of these areas. Rocks previously
mapped as intermediate, calc-alkalic volcanic rocks
in nearly all cases proved to be altered tholeiites. For
example, in the western part of the belt ,the Ball
calc-alkalic sequence of Pirie (1981) in fact consists
of a bimodal succession of tholeiitic basalts and
calc-alkalic rhyolites, a fairly common Archean asso
ciation (Thurston, Chapter 7, this volume).
Basalts and rhyolites have been altered to vary
ing degrees. In the case of the rhyolites, there is
commonly little visible change with alteration, but
chemically, sodium depletion, carbonatization, and
both potassium depletion and addition are quite ob
vious. On the other hand, the mafic, and in some
cases ultramafic volcanic rocks can be radically
changed in appearance by pervasive alteration. On
the basis of hand specimen examination alone, al
tered rocks are readily mistaken for andesites or
dacites. In some cases, however, sodium depletion in
such rocks gives rise to aluminous metamorphic as
semblages commonly containing garnet and/or an
dalusite. In most such rocks, chemical criteria based
on relatively immobile elements such as nickel and
chromium clearly identify the mafic progenitors of
these altered rocks. Their tholeiitic affinity can be
assumed from their close spatial association with
unaltered mafic volcanic rocks along strike and by
their low yttrium and zirconium contents comparable
to adjacent tholeiitic and komatiitic volcanic rocks.
Regional mapping suggests that the alteration
zones are sub-conformable in the areas south and
east of Pipestone Bay (Figures 6.6 and 6.10). These
alteration zones include nearly all of the significant
gold deposits and prospects found in this part of the
belt so far. This spatial relationship and the general
 H. WALLACE ETAL.

TABLE 6.1: GEOCHRONOLOGY OF THE WESTERN UCHI SUBPROVINCE (U-Pb ZIRCON AGES IN MILLIONS
OF YEARS).
RED LAKE
UCHI-
CYCLE CONFEDERATION 1981 1983
2959±2 1 (2982)3"5 2992 + 20/-9 4
2964 + 5/-1 4
2940±2 4
2925±34
2894+1 4
2840 2 2830±153
2738 + 5/-2 1 2739±33 2748+10/-54
2733±1 3 2744±1 2
NOTES:
1 Nunes and Thurston 1980
2Corfu unpublished data 1985
thurston ei al. 1981
4Corfu and Wallace 1985
5age too old due to incorporated inherited zircon; new determinations = 2964 Ma.

Figure 6.9. Geological

*. \ ".[ felsic plutonic and intrusive rocks ^* t ^U7Pb ^my) zircon map of the Red Lake
mafic intrusive rocks Belt showing all
metasedimentary rocks geochronological data
felsic metavolcanic rocks'-^
available in 1983.
intermediate metavolcanic rocks t
mafic metavolcanic rocks
chemical sediments \' t '

2894 : vBalmertown
2964

style of alteration are reminiscent of the situation
described by Pirie (1981) within the "highly altered
zone" around Cochenour-Balmertown (Figure 6.3).
In the Madsen area, detailed mapping and
lithogeochemical studies by Durocher (1983) have
shown that auriferous units, which were long as
sumed to be intermediate pyroclastic rocks, are in
fact highly altered and deformed tholeiitic basalts.
These rocks are similar, in terms of their trace ele
ment contents, to tholeiitic and komatiitic volcanic
rocks elsewhere in Baird Township (Figure 6.11).
Although differing in detail from the alteration in the
Cochenour-Balmertown and Pipestone Bay areas, the
general characteristics of all these zones are very
similar. Again, the zones are crudely conformable
and occur near the top of the lower tholeiitic-
komatiitic sequence. They do, however, appear to
crosscut stratigraphy northeast of Madsen.
One interpretation of the distribution of alteration
zones throughout the belt is that they are controlled
by a conjugate set of large northeast- and west-
northwest trending deformation zones (Figure 6.11;
Andrews and Durocher 1983). These deformation
zones appear restricted to the older (Cycle l)
tholeiitic-komatiitic sequence; only the Pipestone Bay-
St. Paul Bay Deformation Zone (Andrews and
Durocher 1983) clearly transects stratigraphy.
On the southern limb of the Red Lake anti
clinorium, that is, south of Madsen and Balmertown,

95
CHAPTER 6
Cycle l volcanics
cle II volcanics
Cycle III volcanics
clastic sediments
intrusive rocks
highly altered zones
gold producer, major prospect
two distinct tholeiitic sequences can be recognized.
To the north, tholeiitic and komatiitic basalt flows of
Cycle l age have primitive chemistry; the southern
2750 Ma old sequence includes variolitic basalts and
andesites. On the basis of major element chemistry,
this sequence is clearly tholeiitic, yet is highly
evolved being characterized by zirconium and yttrium
levels much higher than in the older tholeiites, and
comparable to levels in the overlying calc-alkalic
sequence. The younger tholeiitic sequence is similar,
but measurably older than the predominantly calc-
alkalic volcanic rocks which underlie most of Heyson
Township. The younger tholeiites may represent a
discrete stratigraphic package, or one gradational
into the calc-alkalic rocks to the south.
On the northern limb of the Red Lake anti
clinorium no sequence comparable to the younger
tholeiites, described above, has been identified. The
calc-alkalic volcanic rocks north of Red Lake are
separated from the lower tholeiitic to komatiitic se
quence by a thick unit of clastic metasediments. In
general terms, these metasediments grade from
wacke-mudstones, with intercalated polymictic con
glomerate containing clasts of mixed volcanic origin,
into a sequence of more mature arkosic sandstone
and conglomerate beds with mostly clasts of felsic
intrusive rocks. Although these rocks require much
more careful study, the sequence appears to reflect a
prolonged period of erosion of a complex volcanic
terrain during which underlying batholiths were even
tually exposed. This was presumably the result of a
major tectonic event following the tholeiitic-komatiitic
(Cycle l) volcanism and prior to calc-alkalic (Cycle III)
volcanic activity.
The existence of this metasedimentary package
suggests that the structural break inferred from
geochronological and geochemical data south of Bal-
mertown and Madsen is an unconformity. Because of
its inherent weakness, this unconformity was a locus
96
Figure 6.10. Distribution
of zones of pervasive
alteration in the Red
Lake Belt relative to
major gold deposits,
based on data available
in 1983.
for later tectonic movement which created the
"deformation zone" evident in the Madsen area.
REVISED RED LAKE STRATIGRAPHY
On the basis of data collected in 1982 and 1983, the
authors' stratigraphic interpretation of the Red Lake
Belt was revised to that shown in Figures 6.12 and
6.13, and in the regional correlation map (Figure
6.14). The main change with respect to the 1981
versions (Figures 6.7 and 6.8) is the restriction of
Cycle II to the area of McKenzie Island, and the
expansion of Cycle l to occupy roughly 70 07o of the
Red Lake Belt.
Cycle l, as shown in the new interpretation, in
cludes rocks varying in age by almost 100 Ma (2992
to 2894 Ma). Clearly it constitutes a very complex
stratigraphic sequence. It is doubtful that this pack
age can be stratigraphically subdivided across the
belt without much more geochronological work. The
main reason for this is the strong probability that
Cycle l and Cycle II rocks were subject to two major
folding events. Cross folding is suggested in some
areas by overturned minor folds, curving axial traces,
aeromagnetic patterns, and, in a few cases, by the
configuration of marker horizons. As previously dis
cussed, a major folding event prior to Cycle III vol
canism is required to explain formation of the thick
sedimentary sequence between Cycles l and III north
of Red Lake, and the apparent unconformity south of
Balmertown.
The isolation of the small block of Cycle II
pyroclastic and derived sedimentary rocks on McKen
zie Island may be explained in a number of ways;
original stratigraphic and/or structural boundaries of
the block have been obscured by the Dome Stock
and the waters of Red Lake, so it is difficult to
evaluate these possibilities. The block may have
been downfaulted or infolded into Cycle l, assuring

1. Cochenour Mine l—T—l
li_±J Felsic Intrusive Rocks
2. Campbell Mine
l___l Volcanic i Sedimentary Rocks
3. A.W. White Mine
4. Howey Mine ; D.Z. Deformation Zone
5. Hasaga Mine B Mine
6. Buffalo Mine A Occurrence
7. Madsen Mine (A) McKenzie Channel
8. Starratt-Olsen Mine (B) McKenzie Stock
9. Lake Rowan Mine (C) Dome Stock
10. Keeley-Frontier Mine
Figure 6.11. Location of deformation zones within the Red Lake Belt (after Andrews and Durocher 1983).
preservation while erosion removed all other traces
of Cycle II rocks in the Red Lake area. Major strata-
parallel faults, shown as the Post Narrows Deforma
tion Zone on Figure 6.11, probably form the northern
boundary of this block, and explain why older rocks
on the northern side of Red Lake appear to overlie
the Cycle II sequence.
A variety of felsic to intermediate lithic and
pumiceous clasts and chert fragments are the main
clast types in the volcaniclastic units on McKenzie
Island. Similar rock-types form the subaerial and
shallow water pyroclastic deposits (Thurston 1981 a)
on the western limb of the Uchi-Confederation Belt.
Lithogeochemical evidence linking rocks from these
two areas is as yet unavailable.
Although rocks of Cycle III age and character are
traceable between belts, the continuity of individual
units or formations is difficult to determine because
of poor exposure and the high metamorphic grade of
supracrustal sequences between the belts. The Cycle
III volcanic rocks in the Red Lake area may, in fact,
be products of a separate but similar eruptive centre.
ECONOMIC SIGNIFICANCE OF REGIONAL
CORRELATIONS———^—-—^^—-——
Stratigraphy appears to be one controlling factor in
the localization of base-metal deposits in the Uchi-
Confederation Lakes Belt, and gold deposits in the
Red Lake camp.
H. WALLACE ETAL
* *-
In the case of South Bay-type copper-zinc depos
its in the Uchi-Confederation Lakes area, the relation
ship between mineralization and stratigraphy is easily
documented and explainable on the basis of the
Smith and Bailey (1968) caldera cycle. The deposits
are believed to have formed syngenetically, at and
near the rock-shallow water interface, during late
stage hydrothermal activity within a collapsed cal
dera structure (Thurston 1981 a). The mineralizing
fluids were restricted to( and were concentrated in
relatively small topographic features, the caldera it
self, and adjacent grabens. Careful mapping, and
facies analysis must be carried out to find these
small, high potential, exploration targets in such com
plex volcanic environments.
Rocks comparable in age, stratigraphic position,
and major element composition to the South Bay
Mine sequence are now known to occur on both the
northern and southern flanks of the Red Lake Belt. In
light of this, these rocks should be evaluated
geochemically to assess their genetic relationship
with the South Bay Mine sequence. Comparison of
trace element characteristics, combined with volcanic
facies analysis between the two belts will perhaps
determine whether similar mineralization can be ex
pected around Red Lake. If the Red Lake rocks are
distal, and were formed well outside the caldera
environment, or if they prove to be products of an
entirely different volcanic complex, then the chances
of finding South Bay-type deposits are diminished.
97
CHAPTER 6

Cycle l volcanics
Figure 6. 72.
Cycle II volcanics
Stratigraphic map of the
Cycle III volcanics
Red Lake Belt, 1983.
clastic sediments
Interpretation based on
intrusive rocks
geochronological,
iron formation (chemical
geochemical, and
marble (sediments geological data
U/Pb zircon age (my)\* t
accumulated between
1981 and 1983.

^^2925
+Y ' ' **^.X\ s
^

On the other hand, in more modern volcanic terrains,

RED LAKE STRATIGRAPHY calderas tend to occur in "fields" in which several
calderas follow similar patterns of evolution, and de
283oU7Pb zircon age (my) velop in close proximity at roughly the same time.
intermediate metavolcanics Rocks of comparable age and chemistry throughout
the region should be examined with this in mind.
felsic metavolcanics^E The relationship between gold deposits and
felsic intrusives stratigraphy in the Red Lake Belt is less precise than
clastic sediments for base-metal deposits in the Uchi-Confederation
Lakes area. Empirically, a rather loose spatial correla
iron formation tion between Cycle l volcanic rocks, major zones of
calc-alk basalt ( c ) alteration, and gold deposits seems to apply in all
tholeiitic basalt (t) parts of the Red Lake area. Conversely, very few
deposits, and none of proven economic importance,
have been found in areas underlain by Cycle II and
2739 III rocks, which constitute roughly 30 0Xo of the supra
crustal belt.
2830
2748 At the detailed scale, the dominant factor control
ling the location and character of ore zones in the
2894 area's past and presently producing mines is struc
2964
ture. The ore zones occur where deformation created
volumes of rock in which low fluid pressures and
high permeability permitted the easy movement of
mineralizing solutions. Determination of the nature of
these fluids, their source(s), the origin of the gold,
and the reasons they preferentially affect rocks of
Cycle l age are problems of considerable importance
and controversy. They are not, however, easily re
solved on either theoretical or empirical grounds, and
will not be considered here. The authors, however,
do suggest, based on the spatial association noted
above, that some factor inherent in the stratigraphic
make-up of Cycle l is particularly conducive to the
Figure 6.13. Schematic cross-sections through formation of gold deposits. Hence, the identification
parts of the Red Lake Belt. Lines of sections of Cycle l rocks in other parts of the region is of
are shown in Figure 6.6. economic significance.
Cycle l rocks in all parts of the Red Lake Belt
continue to be prime targets for gold exploration. In
the Uchi-Confederation Lakes area, these rocks are

98

Cycle l
Cycle II
Cycle
U/Pb (my) zircon age
Figure 6.14. Stratigraphic map of the western Uchi Subprovince, 1983.
on the flanks of the belt. On the west, they occur
north and south of Corless Lake, while on the eastern
side of the belt they are found north and south of the
Perrigo Lake Intrusion. In the Birch Lake area, Cycle l
rocks have tentatively been identified around Seag
rave Lake, and may occur elsewhere in the northern
part of the belt. None of these areas has been
intensively explored for gold in the past. Although
gold has been mined in several parts of the Birch-
Uchi-Confederation Lakes area, these previously
known deposits are found in Cycle II and III rocks
which occupy the core of the belt.
FURTHER REGIONAL COMPARISONS AND
THEIR IMPLICATIONS________________
In parts of the central and eastern Uchi Subprovince
(Figure 6.1) detailed geological mapping has also led
to the recognition of polycyclic volcanism. In the
Bamaji-Fry Lakes area, Wallace (1980) documented
three lithologically and chemically distinct volcanic
sequences. As in the Red Lake Belt, the youngest
sequence appears to be separated from the older
cycles by a marked unconformity. Geochemically,
however, the patterns are quite different. Whereas
chemical affinities in the Red Lake area change from
dominantly tholeiitic-komatiitic to calc-alkalic with
time, the sequence in the Bamaji-Fry Lake Belt is
from calc-alkalic to tholeiitic, and finally to rocks of
alkalic composition. In the Meen-Dempster Lakes
Belt, Stott (1982; Stott and Wallace 1984) recognized
at least two, and possibly three volcanic cycles on
the basis of relative superposition. These sequences,
not as yet geochemically characterized, may be
traceable northeastward into the Pickle Lake area. In
the southern part of the Subprovince, Berger (1981)
identified complex volcanic stratigraphy around the
western end of Lake St. Joseph. Much farther to the
east, Wallace (1981) reported at least three major
volcanic sequences in the Miminiska Lake area. The
second and third sequences are separated by an
unconformity and a thick package of turbiditic
metasediments.
H. WALLACE ETAL
It is unlikely that the stratigraphic patterns in
these widely separated areas will ever be correlated
directly. In many places once continuous supracrustal
sequences have been completely dissected by
plutons, and even where this has not occurred, the
scarcity of outcrop makes it impossible to trace in
dividual stratigraphic units. Hence, the only viable
approach to long-range stratigraphic correlation is to
compare these isolated, relatively well exposed and
understood areas using geochronological data. Such
dating programs are currently underway, but no re
sults are yet available.
To the north, in the Sachigo Subprovince, geoch
ronological studies have already been completed fol
lowing detailed mapping in the North Spirit Lake
(Nunes and Wood 1980) and Favourable Lake Belts
(Corfu ef a/. 1981). Results of these studies are
surprisingly similar to those from the western Uchi
Subprovince. Major episodes of volcanic activity be
tween 2910 and 3020 Ma and again between 2720
and 2740 Ma are common to these areas. The signifi
cance of these similarities is a matter of conjecture. It
seems likely that a large part of the Superior Province
was affected by a common sequence of magmatic
events, the periodicity of which was governed by
some first-order tectonic process. If such characteris
tics are common, exploration criteria developed in
any one area on the basis of lithological, primary
geochemical and stratigraphic factors may be much
more widely applicable.
SUMMARY
The structural and stratigraphic complexity of Ar
chean supracrustal terrain makes correlation be
tween, and even within, individual greenstone belts
difficult and uncertain. Tentative points of correlation
based on lithological or chemical similarities must be
tested carefully using independent criteria before
marker horizons, such as rare carbonate units, can
be relied upon.
On the basis of geochronological comparison,
the authors have correlated major stratigraphic pack-
99
CHAPTER 6
ages between the Red Lake and Uchi-Confederation
Lakes Belts. Volcanic stratigraphy (Cycle III) can be
traced between these areas; however, interbelt cor
relation of older units (Cycle l and Cycle II) remains
tentative. Although volcanic sequences of broadly
similar age occur within the two belts, much work
must be done to determine how, or indeed whether
these rocks are related genetically.
If the Red Lake and Uchi-Confederation Lakes
areas share a common stratigraphic development,
and if interbelt correlation can be refined, geologists
can apply this concept as a powerful exploration tool.
Exploration criteria developed here may also be ap
plicable in other parts of the Uchi Subprovince to the
east, and in supracrustal belts to the north where
similar patterns of polycyclic volcanism are known or
suspected.
The strong possibility that cyclic volcanism oc
curred in synchronous fashion over a wide area of
the Superior Province is fundamentally significant
when considering theories of Archean tectonics and
crustal development.
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Berger, B.R.
1981: Stratigraphy of the Western Lake St.Joseph
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100
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Horwood, H.C.
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Johns. G.W., and Falls, R.M.
1976a: Honeywell Township, District of Kenora
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1973: A Low-Contamination Method for Hydrothermal
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Nunes, P.D., and Thurston, P.C.
1980: Two Hundred and Twenty Million Years of Ar
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Nunes, P.O., and Wood, J.
1980: Geochronology of the North Spirit Lake, District
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Pirie, James
1981: Regional Setting of Gold Deposits in the Red
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1978a: Balmer Township Area, District of Kenora
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Pirie, J., and Kita, J.H.
1979a: Ranger Township, District of Kenora (Patricia
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Pirie, J., and Sawitzky, E.
1977a: Graves Township, District of Kenora (Patricia
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(Patricia Portion); Ontario Geological Survey, Pre
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Pryslak, A.P.
1970a: Dent Township, District of Kenora (Patricia
Portion); Ontario Department of Mines, Prelimi
nary Map P.592, scale 1:15 840.
1970b: Mitchell Township, District of Kenora (Patricia
Portion); Ontario Department of Mines, Prelimi
nary Map P.593, scale 1:15 840.
1971 a: Corless Township, District of Kenora (Patricia
Portion); Ontario Department of Mines and North
ern Affairs, Preliminary Map P.634, scale
1:15840.
1971 b: Knott Township, District of Kenora (Patricia
Portion); Ontario Department of Mines and North
ern Affairs, Preliminary Map P.635, scale
1:15840.
1972: Goodall Township, District of Kenora (Patricia
Portion); Ontario Department of Mines, Prelimi
nary Map P.763, scale 1:15 840.
Riley, R.A.
1972: Ball Township, District of Kenora (Patricia Por
tion); Ontario Division of Mines, Preliminary Map
P.792, scale 1:12000.
1975: Ball Township, District of Kenora (Patricia Por
tion); Ontario Division of Mines, Map 2265, scale
1:12000.
H. WALLACE ETAL.
1976: Mulcahy Township, District of Kenora (Patricia
Portion); Ontario Division of Mines, Map 2295,
scale 1:12000.
1978a: Todd Township, District of Kenora (Patricia
Portion); Ontario Geological Survey, Map 2406,
scale 1:12 000.
1978b: Fairlie Township, District of Kenora (Patricia
Portion); Ontario Geological Survey, Map 2407,
scale 1:12 000.
Smith, R.L, and Bailey, R.A.
1968: Resurgent Cauldrons; p.613-662 in Studies in
Volcanology, edited by R.R. Coats, R.L Hay and
C.A. Anderson Geological Society of America,
Memoir 116, 679p.
Stott, G.M.
1982: Meen Lake Area, District of Kenora (Patricia
Portion); p. 10-14 in Summary of Field Work, 1982,
by the Ontario Geological Survey, edited by John
Wood, Owen L. White, R.B. Barlow, and A.C. Col
vine, Ontario Geological Survey, Miscellaneous
Paper 106, 235p.
Stott, G.M., and Wallace, H.
1984: Regional Stratigraphy and Structure of the Cen
tral Uchi Subprovince: Meen Lake-Kasagiminnis
and Pashkokogan Lake Sections; p.7-13 in Sum
mary of Field Work, 1984, by the Ontario Geologi
cal Survey, edited by John Wood, Owen L. White,
R.B. Barlow, and A.C. Colvine, Ontario Geological
Survey, Miscellaneous Paper 119, 309p.
Thurston, P.C.
1981 a: Volcanology and Trace Element Geochemistry
of Cyclic Volcanism in the Archean Confeder
ation Lake Area, Northwestern Ontario; Un
published Ph.D. Thesis, University of Western
Ontario, London, Ontario, 553p.
1981 b: Western Uchi Subprovince Synoptic Survey;
p.8-11 in Summary of Field Work, 1981, by the
Ontario Geological Survey, edited by J. Wood,
O.L White, R.B. Barlow,,and A.C. Colvine, Ontario
Geological Survey, Miscellaneous Paper 100,
255p.
Thurston, P.C., and Fryer, B.J.
1983: The Geochemistry of Repetitive Cyclical Vol
canism from Basalt Through Rhyolite in the Uchi-
Confederation Greenstone Belt, Canada; Contri
butions to Mineralogy and Petrology, 83,
p.204-226.
Thurston, P.C., and Jackson, M.C.
1978: Confederation Lake Area, District of Kenora
(Patricia Portion); Ontario Geological Survey, Pre
liminary Map P. 1975, scale 1:15 840.
Thurston, P.C., Raudsepp, M., and Wilson, B.C.
1974: Earngey Township and Part of Birkett Town
ship, District of Kenora (Patricia Portion); Ontario
Division of Mines, Preliminary Map P.932, scale
1:15840.
Thurston, P.C., Wallace, H., and Corfu, F.
1981: Tentative Stratigraphic Correlation of the Birch-
Uchi and Red Lake Belts (Abstract); p. 14/n Geo
science Research Seminar, December 9-10, 1981,
Abstracts, Ontario Geological Survey, 15p.
101
CHAPTER 6
Thurston, P.C.. Wan, J., Squair, H.S., Warburton, A.F.,
and Wierzbicki, V.W.
1978: Volcanology and Mineral Deposits of the Uchi-
Confederation Lakes Area, Northwestern Ontario;
p.302-324 in Toronto '78 Field Trips Guidebook,
edited by A.L Currie and W.O. Mackasey, Geo-
logical Society of America-Geological Association
of Canada-Mineralogical Association of Canada,
Joint Annual Meeting, Toronto, 361 p.
Thurston, P.C., Waychison, W., Falls, R., and Baker,
D.F.
1975a: Agnew Township, District of Kenora (Patricia
Portion); Ontario Division of Mines, Preliminary
Map P. 1056, scale 1:15840.
102
1975b: Birkett Township, District of Kenora (Patricia
Portion); Ontario Division of Mines, Preliminary
Map P. 1058, scale 1:15 840.
1975c: Costello Township, District of Kenora (Patricia
Portion); Ontario Division of Mines, Preliminary
Map P.1057, scale 1:15840.
wallace, H.
1 980: Geology of the Slate Falls Area; District of
Kenora (Patricia Portion); Ontario Geological Sur-
vey, Open File Report 5314, 145p., 8 figures, 5
tables, 8 photographs. 4 maps.
1981: Geology of the Miminiska Lake Area, Districts
of Kenora (Patricia Portion) and Thunder Bay;
Ontario Geological Survey, Report 214, 96p. Ac
companied by Maps 2416 and 2417, scale
1:31 680.
Part Three: Volcanic Lithogeochemistry
and Mineral Exploration
Chapter 7

Volcanic Cyclicity in Mineral Exploration; the Caldera

Cycle and Zoned Magma Chambers
P.C. Thurston

CONTENTS 7.4. CaO-AI 203 -MgO (wt7o) with

Abstract........................................................ 105
Introduction .................................................. 105
Definitions ................................................ 105
Scale of Cyclicity ........................................ 105
Types of Cyclicity ....................................... 106
Komatiitic Cycles .................................... 107
Komatiitic, Tholeiitic, Calc-Alkalic,
Alkalic Cycles ......................................... 107
Tholeiitic Basalt to Calc-Alkalic Felsic
Volcanic Rocks........................................ 108
Bi-Modal Type ..................................... 109
Full-Fractionation Type ...................... 109
Tholeiitic Basalt-Calc-Alkalic Basalt-
Rhyolite-Alkalic Volcanic Rocks ........... 110
Calc-Alkalic Basalt-Rhyolite .................. 111
Tholeiitic Basalt-Calc-Alkalic Felsic
Volcanic Rocks-Tholeiitic Basalt.......... 111
Tholeiitic Basalt-Metasediments .......... 111
Cyclicity Within Major Units ...................... 111
Cyclicity in Mafic Rocks ........................ 111
Cyclicity in Felsic Sequences............... 112
Mega-scale Cyclicity.......................... 112
Meso-scale Cyclicity .......................... 113
Micro-scale Cyclicity .......................... 113
Hiatus............................................................ 113
Depositional Unit Scale.......................... 114
Iron-Enrichment Cycle Scale................. 114
Hiatuses in Felsic Sequences .............., 115
Magma Clan Transitions ........................ 116
The Caldera Cycle....................................... 116
Zoned Magma Chambers ........................... 118
Applications to Exploration..................... 119
Summary ....................................................... 119
References .................................................... 119
TABLES
7.1. Styles of Archean cyclical volcanism 108
7.2. Types of Archean cyclical volcanism 108
FIGURES
7.1. Minor cycle scale cyclical volcanism
in Cycle II at Confederation Lake,
stratigraphic section.......................................... 106
7.2. Major cycle scale cyclical volcanism
in the Gamitagama Lake Setting Net
Lake area, Gods Lake Subprovince ............... 107
7.3. Super cycle scale cyclical volcanism
in the Abitibi Subprovince ................................ 107
komatiitic rocks of the Munro
Township area........................................ 109
7.5. Histogram of about 2300 analyses of
Blake River Group volcanic rocks ......., 109
7.6. Histogram of volcanic classes Lake
of the Woods-Wabigoon Subprovince, 109
7.7. Na20 -i- K2O -FeO + Fe203-MgO
(AFM) diagram in wt 07o of the Yoke
Lake volcanic rocks .............................., 110
7.8a. Schematic stratigraphic section
Cycle III Confederation Lake ............... 110
7.8b. A similar cycle at Flin Flon, Manitoba 110
7.9. Schematic cross section of the
Batchewana area with the lower
tholeiitic unit overlain by calc-alkalic
felsic pyroclastic rocks or clastic
metasediments ....................................... 111
7.10. Iron enrichment cycle within the
basalts of Cycle II Confederation
Lake .................................................. 111
7.11. Schematic cross section of the
Redstone Nickel deposit................. 112
7.12. Compositional zonation within the
upper felsic part of Cycle III
Confederation Lake......................... 112
7.13. Schematic cross section of an
individual mafic flow at the Maybrun
Mine with large pillows at the base of
the flow, small pillows toward the
top, and fine-grained tuff at the top .... 113
7.14a. Schematic cross section of barite-
bearing units in the North Pole area,
Pilbara Block, Western Australia .......... 114
7.14b. Schematic cross section of the
Hemlo area .............................................. 114
7.15. Minor scale cycles within the upper
part of Cycle II Confederation Lake ... 115
7.16. Schematic cross section of a typical
ash-flow .................................................. 115
7.17. Cycle III Confederation Lake-
schematic cross section of the Selco
copper-zinc-silver orebody .................. 116
7.18. The caldera Cycle ................................. 117
7.19. Schematic cross section of a
compositionally zoned magma
chamber.................................................. 118
PHOTOGRAPH
7.1. Compositionally zoned ash-flow from
Cycle III Confederation Lake ........................... 106

104

ABSTRACT
Volcanic cyclicity pertains to the cyclic repetition of
rock units. In the Archean, this has meant the repeti
tion of mafic to felsic volcanism. Cyclicity occurs on
several scales including 1) mini-cycles within single
beds; 2) minor-cycles within 10s to 100s of m; 3)
major-cycles within a few 100s to 1000s of m and, 4)
super-cycles operative on the scale of 1000s of m.
The types of volcanic cycles commonly observed
in the Archean are listed as follows: 1) Komatiite
suite, peridotitic komatiite-peridotitic basalt komatiitic
dacite; 2) Tholeiitic basalt-tholeiitic rhyolite; 3)
Tholeiitic basalt-calc-alkalic felsic; 4) Tholeiitic
basalt-calc-alkalic felsic tholeiitic basalt; 5) Komatiite
suite peridotitic komatiite; 6) Tholeiitic basalt-calc-
alkalic rhyolite-alkalic volcanic rocks; 7) Calc-alkalic
basalt-calc-alkalic rhyolite.
Within these units are Fe and Mg enrichment and
depletion cycles in komatiites and mafic rocks, and
depositional and compositionally zoned cycles in fel
sic rocks. Geochemical data indicate the above cy
cles rarely represent continuous fractionation se
quences. Therefore, hiatuses represented by clastic
and chemical sediments occur frequently within
them.
Volcanologically, gold can be related to iron en
richment cycles in basalts and associated hiatuses.
In addition, gold can be related as well to volcanic-
hydrothermal events involving hydro-fracturing of
cherts and production of sedimentary barite units.
Early epithermal veins directly relatable to volcanism
are found in modern terrains, but not in the Archean.
Most precious metal epithermal veins are related in
directly in terms of volcano collapse and so on,
producing fracture sets or hiatuses in volcanism
which allow the development of impermeable sedi
mentary caprocks.
Geochemical and volcanological observations al
low ordering of many of the types of cycles and the
chemically zoned magma chamber genetic hypo
theses for volcanic sequences into the caldera cycle.
The caldera cycle was developed to explain the
sequence of events in caldera development. The sev
en stages of the cycle are: 1) regional tumescence
and generation of ring fractures; 2) caldera forming
eruptions; 3) caldera collapse; 4) pre-resurgence vol
canism and sedimentation; 5) resurgent doming; 6)
major ring fracture volcanism; 7) terminal solfataric
and hot-spring activity.
Volcanogenic massive sulphides are often asso
ciated with volcanic domes produced in stages 5 and
6 with some involvement of stage 7 fluids. This
simplistic analysis does not explain the presence of
basalts in mineralized felsic sequences or the unique
heavy rare earth enriched character of copper-zinc
mineralized rhyolites.
These features are explicable by invoking a
chemically zoned magma chamber with a rhyolitic
upper part in which large trace element gradients
occur, and a basaltic lower part which is often erupt
ed late in the eruptive sequence, yielding an associ
ation of high Fe tholeiites with copper-zinc mineral
ized rhyolites.
P.O. THURSTON
Field and chemical evidence for zoned magma
chambers consist of: 1) mafic pumice toward the top
of rhyolitic ignimbrites; 2) zonation in phenocryst type
and abundance in felsic sequences; 3) the presence
of minor cycles of basaltic andesite and rhyolite, with
each rock type being of two distinct chemical types
not inter-related by fractionation; 4) compositional
zonation of stratigraphic sequences, for example at
Confederation Lake Cycle III.
INTRODUCTION
This chapter treats the relationships between cyclicity
in Archean volcanic stratigraphy, and the localization
of mineral deposits by discussing:
1. volcanic cyclicity; the definition of the term, the
various types of cyclicity found in "greenstone
belts", the economic applications of various
types of cyclicity, that is, location of mineral
deposits in terms of volcanic cyclicity and a
degree of stratigraphic control of some appar
ently epigenetic deposits.
2. the caldera cycle; how the complexities of
stratigraphy can be analyzed in terms of the
Smith and Bailey (1968) caldera cycle which
involves large Plinian eruptions, collapse of an
edifice forming a caldera, and renewed or resur
gent volcanism. The caldera cycle and its reflec
tion in regional stratigraphy permits the separa
tion of felsic volcanic successions into those
with high and low mineral potential with respect
to volcanogenic copper-zinc massive sulphide
mineralization.
3. chemically zoned magma chambers; their role in
the genesis of massive sulphide mineralization
and gold-silver deposits.
This chapter attempts to demonstrate that an
appreciation of volcanic eruption processes and their
products, the temporal succession of eruption types,
and the character of the magma chamber from which
the rocks are produced, can lead to a better under
standing of mineralization in volcanic stratigraphy,
and hence, and improved ability to evaluate mineral
potential and locate mineral deposits.
DEFINITIONS
A cycle is defined as (AGI 1972): "A series of events
or changes that are normally, but not inevitably, con
sidered to be recurrent and to return to a starting
point, that are repeated in the same order several or
many times at more or less regular intervals and that
operate under conditions which, at the end of the
series, are the same as they were at the beginning."
Cyclical volcanism pertains to the repetition of vol
canic rocks. In the classical Archean context, this
has generally referred to the repetition of sequences
progressing from mafic to felsic (Goodwin 1967,
1968).
SCALE OF CYCLICITY
Anhaeusser (1971) examined cyclicity in Archean
volcanic rocks and described its occurrence on four
scales:
105
CHAPTER 7

1. mini-cycles: measured in cm or parts thereof, for somewhat arbitrary process. Glikson and Jahn (1984)
example, wacke-mudstone couplets or felsic tuff- have summarized investigations which have shown
chert couplets (Photo 7.1). there is a compositional gap between komatiites
2. minor cycles: measured in m, 10s of m, 100s of (peridotitic, pyroxenitic, and basaltic) and the so-
m, for example, parts of Cycle II at Confederation called high-Mg basalts. However, Johnson et al.
Lake where basaltic andesite to rhyolite cycles (1978) have shown that a complete gradation exists
take place over about 150 m intervals (Thurston between volcanic rocks of tholeiitic and calc-alkalic
1981 b) (Figure 7.1). affinity. Therefore, in the following review of types of
chemical cyclicity in Archean volcanism, the reader
3. major cycles: "a few hundred to many thousands should realize that classification on the basis of an
of metres" thick, for example, the cyclical vol AFM or AFTM (Jensen 1976) diagram (that is, relative
canism of Ayres (1977) or Thurston (1981 b) to a line separating rocks of two affinities) is not
(Figure 7.2). Cyclicity on this scale occurs in the appropriate; rather, the presence or absence of the
Norseman area of Western Australia (Doepel
1965; quoted by Glikson 1976) and in the
Bulawayan Group of Zimbabwe (Bliss and
Stidolph 1969).
4. super cycles: include the whole of a volcanic
sedimentary to calc-alkalic to alkalic volcanic
Confederation Lake Area
cycle and constitute 1000s of m of stratigraphy.
In the Abitibi Subprovince, Pyke (1978) and Jen chert A
sen (1978a) described the three-fold recurrence felsic tuff y
of a volcanic super cycle involving basaltic and ^Intermediate flow in
peridotitic komatiite succeeded by high-Fe and \felsic tuff
high-Mg tholeiitic basalt through tholeiitic rhyolite
mafic pillow o
to calc-alkalic basalt through rhyolite (Figure
7.3). Volcanic cycles of this magnitude appear to breccia o
be unusual in their stratigraphic thickness and
chemical variety. A further compilation of exam cc
ples of the various scales of volcanic cyclicity is mafic flow
o
listed in Table 7.1. z
TYPES OF CYCLICITY
Six major types of volcanic cyclicity recognized in
the Ontario Archean based upon magma clan affinity ^felsic tuff
are shown in Table 7.2. Three major magma clans -*mafic flow
are represented: komatiite, tholeiite, and calc-alkalic.
Classification into these clans is. of necessity, a
22 -•-felsic tuff
LLJ
—l
O
>
o
cc
o
60 -^gabbro

felsic tuff

Figure 7.1. Minor cycle scale cyclical volcanism in

Photo 7.1. Compositionally zoned ash-flow from Cycle II at Confederation Lake, stratigraphic
Cycle III Confederation Lake. Rhyolite frag section. The cycle progresses from mafic
ments at base are shown by arrow. The unit (basaltic andesite) flows to rhyolite tuffs and
grades upward to mostly andesitic pumice. chemical sediments at the top.

106
 P.O. THURSTON

25-
GAMITAGAMA LAKE GREENSTONE BELT
SW NE SUPER-CYCLE SCALE
VOLCANISM
V.
Q)

20-
Q)
metavolcanics;
mafic metavolcanics^
mafic metavolcanics;
^metasedimentary formation///

Figure 7.2. Major cycle scale cyclical volcanism in 15- tholeiitic felsic rocks
the Gamitagama Lake-Setting Net Lake area,
Gods Lake Subprovince. Cyclicity is on the
scale of 102 to 1C? m (Ayres 1969).

calcalkalic rocks
hallmark of tholeiitic affinity, the iron enrichment
trend must be tested for.
10- Q)
KOMATIITIC CYCLES
Within the komatiite class, Arndt (1975), Arndt et at. tholeiitic rocks
(1977), and subsequent workers (Nisbet 1982) have
demonstrated that a fractionation (fractional crystalli
zation) relationship exists between a parental magma
of peridotitic komatiite through pyroxenitic komatiite,
and that a hiatus in nickel, chromium, aluminium, and komatiitic rocks
rare earth element data exists relative to high-Mg
basalts of undoubted komatiitic affinity. The gap is 5 -
explained by a model involving convection in a 0)
chemically zoned magma above primitive, freshly
mantle-derived peridotitic komatiite (Nisbet 1982).
(O
The high-Mg basalts are the predominant units in 0 *- o
i.
these successions. *-
(D
•o
Q) S
Field and chemical studies of cyclicity within
these successions are important in that Arndt (1978) E
o
has observed that syngenetic nickel mineralization,
exsolved immiscibly out of komatiitic liquids, is re
stricted to the Mg-rich part of the cycle as shown in
Figure 7.4. Tholeiitic basalts and calc-alkalic Figure 7.3. Super cycle scale cyclical volcanism in
pyroclastic rocks are intercalated within nominally the Abitibi Subprovince. Jensen (1978a) pos
komatiitic major stratigraphic units in the Abitibi Sub tulated the existence of two super-cycles 10*
province and at Red Lake. The origin of these units m thick ranging from a komatiitic base through
which mark the cessation of komatiitic volcanism is tholeiitic rocks, a calc-alkalic unit, to an alkalic
obscure; Glikson and Jahn (1984) suggested the volcanic top. This is a generalized cross sec
units may have originated by partial melting of tion of Cycle II (after Jensen 1978b).
komatiites.

KOMATIITIC, THOLEIITIC, CALC-ALKALIC, ALKALIC

CYCLES
Jensen (1978a) and Pyke (1978) have described
cyclicity in the Abitibi Subprovince in which 2 super
cycles have a komatiitic unit at the base surmounted
by a tuff-chemical sediment unit together totalling 10
000 m in thickness, succeeded upward by a 6000 to
10 000 m thick tholeiitic unit, then a 7500 to 10 000
m thick calc-alkalic unit. The tholeiitic unit consists
(Letros et al. 1983) of several minor-cycle-scale iron
enrichment cycles, some of which evolve by frac
tional crystallization (Thurston 1981 a) to rare tholeiitic
rhyolite tuffs. The calc-alkalic unit consists of basalt
through rhyolite characterized by lath-like plagioclase
phenocrysts. Jensen (1984) suggested that rock
types of this unit represent fractional crystallization
from a calc-alkalic basalt parent magma.
These cycles are characterized by large scale
cyclicity, that is, from komatiite through tholeiite to

107
CHAPTER 7

TABLE 7.1: STYLES OF ARCHEAN CYCLICAL VOLCANISM.

AREA UNITS REPRESENTED SCALE OF CYCLICITY REFERENCE
(AFTER WILSON ET AL. (AFTER ANHAEUSSER
1974) 1971)
S. Africa (Onverwaacht Lower basic, middle basic Super cycle, major cycle Anhaeusser 1971
Grp.)
Rhodesia (Bulawayan) Lower basic, middle basic, Super, major, minor, Bliss and Stidolph 1969
upper felsic mini-cycles
W. Australia Lower basic, middle basic, Super, major, minor,
(Kalgoorlie) middle felsic mini-cycles
(Norseman) Lower basic, middle basic, Major, mini, minor cycles Doepel 1965
middle felsic
Canada
Gods Lake Subprovince Upper cyclic Major, minor, mini-cycle Hubregtse 1976; Ayres
1977
Wabigoon Subprovince Lower basic, middle basic, Super cycle, minor, and Blackburn, Trowell, and
middle felsic, upper mini-cycle Edwards 1978
cyclic, alkalic
Abitibi Subprovince Lower basic, middle basic, Super, minor, mini-cycle Pyke 1978; Jensen 1976,
middle felsic, upper 1978a, 1978b,
cyclic, alkalic
Uchi Subprovince Lower basic, middle basic, Super, major, minor, This work; Wallace,
middle felsic mini-cycles personal communication,
1978

calc-alkalic volcanic rocks. Within each of these ma

jor magma clan units, there is minor scale cyclicity,
particularly in the lower part of the super cycle.
Within Quebec, in the upper part of Cycle III
(MERQ/OGS 1984), Gelinas el al. (1984) have ob
served minor scale cyclicity within the nominally
calc-alkalic Blake River Group. This cyclicity consists
of cycles, each 100s of m thick that have mafic
bases of either tholeiitic or calc-alkalic affinity and
progress upward to rhyolite. In fact, within the Duprat-
Montbray Complex or cycle, four small scale basalt to TABLE 7.2: TYPES OF ARCHEAN CYCLICAL
rhyolite cycles exist (Thurston et at. 1984). VOLCANISM.
________TYPES OF CYCLICITY________
The minor scale cyclicity within the Blake River
Group shows that small scale cyclicity exists within
large scale cycles. The seemingly random alterations 1) KOM perid kom — dacite
between tholeiitic and calc-alkalic affinity for the
basaltic rocks of the Group (Gelinas et al. 1984) 2) KOM perid kom — TH bas — rhy
suggest that the Gelinas and Ludden (1984) hypoth
esis involving variable degrees of contamination as — CA bas — rhy — alk
the explanation for the varying magma clan affinity of
these units may be valid. 3) TH bas — andes — TH andes — CA dac
— rhy
THOLEIITIC BASALT TO CALC-ALKALIC FELSIC
VOLCANIC ROCKS 4) TH bas — andes — CA bas — rhy — alk
This type of cyclicity is probably the most common 5) CA bas — rhy
type in the Canadian Shield, according to surveys of
Goodwin (1982) and Goodwin et al. (1982). This 6) TH bas — CA dac — rhy — TH bas
cyclicity consists of basal tholeiitic basalts and an-
desites succeeded upwards by calc-alkalic felsic vol KOM:komatiitic TH:tholeiitic — fractionation
canic rocks. Examples of such cyclicity include: Con
federation Lake (Thurston 1981 b; Thurston and Fryer CA:calc-alkalic alk:alkalic — no
1983), Red Lake (Wallace et al. 1984; Pirie 1981), fractionation
vast parts of the Wabigoon Subprovince (Trowell et

108
 P.O. THURSTON

MgO 15- L~U ABITIBI

mineralized komatiites EOCYCLE II nM06
0 non-mineralized EZ3CYCLE III nM33
komatiites 10-

* tholeiites
5-

60 70
SiO2 (wt

Figure 7.5. Histogram of about 2300 analyses of

Blake River Group volcanic rocks (after Thur
ston e t a l. 1985). Vertical axis number of sam
ples; horizontal axis-volatile-free wf/o SiO^.
The bimodal distribution of Si02 values is quite
evident, clustered at andesite and rhyolite.
CaO ALO
2^3

60 —
Figure 7.4. CaO-A!2 O3-MgO (wf/o) with komatiite
rocks of the Munro Township area (after Arndt
1978). The diagram illustrates the lack of ma 50 — Manitou Lake
jor element discontinuities in this sample suite,
the round filled symbols are komatiites with
associated nickel deposits. Uchi Lake
~ 40 —

a/. 1980), and the Favorable Lake area (Ayres 1977).

This type of cyciicity may be subdivided into two o
such types: a) bi-modal basalt-rhyolite type, and b) a 2
CT —
full fractionation type. d)
"20 —
Bi-Modal Type ——
Thurston ef at. (1985) showed that the Blake River
Group in the upper part of Cycle III in the Abitibi 10 —
Subprovince was clearly bi-modal, based upon 2300
analyses in the Quebec part of the unit. The two end - '

members are andesite and rhyolite (Figure 7.5). Bi

modal volcanic cycles with basalt and rhyolite end
members are more common, with numerous exam
ples being cited by Thurston ef a/. (1985).
This type of bi-modal volcanism must be recon
ciled with the data (Figure 7.6) obtained in a survey
by Goodwin (1977). This compilation shows a de
creasing volume 07o from basalt to rhyolite for the
Confederation area and part of the Wabigoon Sub
province. These data are consistent with an origin of
the sequence by fractionation from a basaltic parent
magma. Thurston and Fryer (1983) have shown that
intermediate compositions in Cycle II at Confeder
ation Lake are produced by magma mixing of
tholeiitic basalt and trondhjemite, crystallization from
primary andesite melts, and fractionation of basaltic
liquids. The available evidence shows that while ba
saltic liquids fractionate to andesites, more felsic
differentiates are not produced. The apparent greater
abundance of andesites in Goodwin's (1977) com
pilation may have been produced by sampling of
heterolithic pyroclastic rocks, or by the practice of
chip sampling which can incorporate altered pillow
basalt andesite dacite rhyolite
Figure 7.6. Histogram of volcanic classes Lake of
the Woods-Wabigoon Subprovince (after Good
win 1977). Vertical axis-weighted mean abun
dance based upon stratigraphic thickness; hori
zontal axis-generalized rocks types.
selvages, or the inclusion of several fragment types
in the sample.
Thurston et al. (1985) have shown that bi-modal
basalt rhyolite volcanism is the most frequently de
scribed type of volcanism in the Superior Province,
based upon sedimentologic, volcanologic, and geo
chemical evidence.
Full-Fractionation Type
This type of cycle is represented by calc-alkalic
volcanic rocks ranging in composition from basalt to

109
CHAPTER 7

FeO*0.8998Fe 0O,
A. flows (mafic)
metres
45 debris flows_____
150 -and air fall (felsic)
A
A
A
tuff to (andesite)
tuff breccia (rh ;o0lite)
A

dome, flows (felsic)

ash flows (dacite)

A
A A A
MgO

Figure 7.7. Na2 0 * K2 0-FeO -f Fe2 O3-MgO (AFM) J5

flows (mafic)
diagram in wf/o of the Yoke Lake volcanic
rocks (after Thurston et al. 1984). The Yoke
Lake sequence is of calc-alkalic affinity and is
the youngest sequence in the Straw Lake area
of the Wabigoon Subprovince. A complete data CYCLE III
set would show a lack of compositional gaps in
the suites. CONFEDERATION LAKE

rhyolite with no gaps in major element compositions.

Trace element data exist for only a few suites, mak
ing petrogenetic conclusions tentative. Giles (1982),
Giles and Hallberg (1982) and Hallberg et al. (1976) INTRUSIVE CONTACT

have shown that some of these complexes are pro ••. .".''-.'••7 i ''; .i :^'v'.'''.''.''."''-',r-/, 1"' dacite
duced by the melting of a mafic source in the lower ;:'-'-,;".'-:.' '."•, l V-,:} O;.::;':' ',.- r ;
andesitic carbonate-bearing sediment
intermediate tuff

crust, followed by fractionation in a high level magma : mudstone, tuff, chert

chamber. Sparse data on Canadian examples sug rhyolite crystal tuff
gest that the sequence at Yoke Lake in the Wabigoon
Subprovince may be similar (G.R. Edwards, Professor, massive rhyolite lobes,
York University, personal communication, 1983). rhyolite breccia,
microbreccia ^-,
massive sulphides
^_andesitic
heterolithic breccia dacite tuff,
pumice-bearing tuff
THOLEIITIC BASALT-CALC-ALKALIC BASALT-
RHYOLITE-ALKALIC VOLCANIC ROCK
This type of volcanic cycle, with an uppermost unit of basaltic andesite
alkalic volcanic rocks has been viewed as being
relatively uncommon with the major example cited :INLET ARM FAULT:
-6.4 km"
being Cycle III in the Abitibi Subprovince capped by
the Timiskaming Group alkalic volcanic rocks
(MERQ/OGS 1984). Jensen (1984) has noted, how
ever, that the top of Cycle li in the Abitibi includes
conglomerate with trachytic clasts. Other examples of Figure 7.8. a. Schematic stratigraphic section,
this type of cyclicity include: the Wawa Subprovince Cycle III, Confederation Lake. The cycle con
west of Thunder Bay (Shegelski 1980); the Wabigoon sists of a tholeiitic base, a calc-alkalic upper
Subprovince south of Dryden (Blackburn et al. 1984); part with the uppermost unit being mafic
the Birch Lake area of the Uchi Subprovince; and tholeiitic flows.
Oxford Lake Manitoba (Brooks et al. 1982). A number b. A similar cycle at Flin FIon, Manitoba (after
of gold deposits occur in the Kirkland Lake area that Syme et al. 1982).
are spatially associated with plutonic equivalents to
these volcanic rocks (Ploeger 1980); a spatial associ
ation of late volcanic rocks and gold also occurs at
Shebandowan (Stott and Schnieders 1983).

110

BATCHEWANA AREA
0K; :/'j
— — — — —d '' VV--M
.————.
~—"~—~—-^———- •^ iYu-V:;
— — — — — basinal
; -~ ^"~,\'^,\^ felsic
--------~-- sedimentary volcanic
—---—-L-—L.-
rocks rocks
— — — — —
Z—Z—~—~—~-
banded iron formatio n /flows
*tuff
tholeiites
* interflow wack.es:;:;
x BASAL SEQUENCE
ttuff
Figure 7.9. Schematic cross section of the
Batchewana area based upon relations de
scribed in Grunsky (1983), with the lower
tholeiitic unit overlain by calc-alkalic felsic
pyroclastic rocks or clastic metasediments.
Recognition of these sequences in the field can
be difficult. At Kirkland Lake, the alkalic volcanic
rocks vary from being undersaturated to oversaturat
ed, even within individual flows, however, trachytic
textures and unusual colours, ranging from red to
green to yellow, aid in their identification. High potas
sium and uranium contents in biotite-rich mafic rocks
at Sunshine Lake in the Wabigoon Subprovince, give
those rocks distinctive radiometric expressions.
CALC-ALKALIC BASALT-RHYOLITE
Cyclicity which results in a sequence with a com
positional range from calc-alkalic basalt to rhyolite is
reported to comprise the upper part (immediately be
low the alkalic volcanic rocks) of the super-cycles of
the Abitibi Subprovince (Jensen 1984). This type of
cyclicity also occurs in the Yoke Lake area of the
Wabigoon Subprovince (Edwards 1984) and Figure
7.7. The main feature of this type of cyclicity is that it
usually represents fractional crystallization of a ba
saltic parent liquid, and therefore compositional gaps
are not common (Giles 1982; Giles and Hallberg
1982).
THOLEIITIC BASALT-CALC-ALKALIC FELSIC
VOLCANIC ROCKS-THOLEIITIC BASALT
In this type of cycle, basal tholeiitic basalts are
overlain by calc-alkalic felsic volcanic rocks ranging
from andesite to rhyolite in composition. The felsic
volcanic rocks range from proximal flows and domes
to proximal and more distal pyroclastic rocks with
intercalated sediments. The cycle is capped by
tholeiitic flows. This type of stratigraphy occurs in
Cycle III at Confederation Lake (Thurston and Hodder
1982 and Figure 7.8). It may also occur in parts of
Cycle III in the Abitibi (Gelinas et al. 1984) and is
known in the Proterozoic succession at Flin Flon
(Syme et al. 1982).
P.O. THURSTON
^""X"1
4 -
mixed
calcalkalic Cycle II Basalts
tholeiitic
pillow basalts Confederation Lake Area
sX'./'1 ^
!5
•*~*
I *- 2
.C
"53
O)
1 JC
I
i
10 15 20
FeO* (wt
Figure 7.10. Iron enrichment cycle within the ba
salts of Cycle II Confederation Lake. Vertical
axis-wf/o FeO (?); horizontal axis stratigraphic
height above an arbitrary datum at the base of
Cycle II in the area of Narrow Lake.
This type of cyclicity has spatial and genetic
association with volcanogenic copper-zinc massive
sulphides (Thurston and Hodder 1982); a relationship
which will be more fully described in a later section.
THOLEIITIC BASALT-METASEDIMENTS
This type of cyclicity, in which basal tholeiitic basalts
with or without komatiitic units are overlain by clastic
and/or chemical sediments, is of regional impor
tance. These basalts underlie vast parts of the Supe
rior Province. As shown in Figure 7.9, this type of
cycle can be explained by the effects of regional
facies variation. In the east, a basalt-sediment cycle
occurs, but in the west, the cycle is a basalt-calc-
alkalic felsic volcanic cycle. This is interpreted (E.
Grunsky, Geologist, Ontario Geological Survey, per
sonal communication, 1984) as a proximal volcanic
environment in the west giving way eastward to a
more distal sedimentary environment.
CYCLICITY WITHIN MAJOR UNITS
As discussed above, volcanic cycles occur on vary
ing scales, however, cyclicity of several types occurs
within the various units of the cycles, that is, within
mafic and felsic volcanic units.
CYCLICITY IN MAFIC ROCKS
In basaltic sequences, Fe-enrichment cycles pro
gressing from iron-poor units (67o to 87o FeO*) at the
base to Fe rich (187c to 2070 FeO*) at the top, are
common. In the example shown in Figure 7.10, ba
salts low in the iron-enrichment cycle have 87o to
107o FeO*, increase to higher FeO* values, and are
often followed by chemical or clastic sediments suc
ceeded upward by two additional iron-enrichment cy
cles. Thurston and Fryer (1983) have interpreted
these cycles to represent an initial mantle-derived
111
CHAPTER 7
l diabase Deloro Group
i monzonite to granodiorite
Tisdale Group J intrusive rocks
K^^i komatiitic flows s sulphide/silicate
KNNN komatiitic peridotite flows ! iron formation
k—HFe-Ni layer ] dacite tuffs
i disseminated and net- l dacite tuffs/
textured sulphides J quartz feldspar porphyry
Figure 7.11. Schematic cross section of the Red
stone Nickel deposit (after Robinson and
Hutchinson 1982).
tholeiitic liquid which evolved by open-system crystal
fractionation (O'Hara 1977) of olivine and plagioclase
with late crystallization of clinopyroxene. In this type
of system, the magma chamber is an open system in
the sense that it is periodically refilled with batches
of new magma while fractional crystallization contin
ues.
The deposition of chemical sediments in Cycle III
at Confederation Lake (Thurston 1981 b) at the top of
the Fe-enrichment cycles has been interpreted to
mark the closing down of a magma chamber system.
The chemical sediments have economic significance.
At Confederation Lake, a sulphide facies iron forma
tion in Cycle III above the lowest iron-enrichment
cycle, has an above background (170 to 200 ppb)
gold content (Thurston 1981 b). The elevated gold
content may have been derived from pervasive pre-
metamorphic hydrothermal introduction of calcium.
This event is marked by epidotization of the pillowed
basalts. Epidotization is most intensely developed
beneath the chemical sediment unit and is marked
by pervasive alteration of the flows, giving way
downward to epidotization concentrated around the
interpillow space.
An association of gold mineralization occurs at
Red Lake and Confederation Lake with high Fe ba
salts (Pirie 1981; Thurston 1982). The gold mineral
ization is generally associated with late vein systems
(McGeehan and Hodgson 1981). If gold is at least in
part transported by the thio complex (HS'), then the
above spatial association may mean gold is in part
fixed by pyrite-forming reactions in iron-rich rocks.
112
Cycle III Confederation Lake
basalt
mafic flows
andesite
felsic debris flows
and air fall tuff
tuff
massive breccia
banded tuff
1500
layered breccia rhyolite
hyalotuff
massive flow
rhyolite dome
Figure 7.12. Compositional zonation within the up
per felsic part of Cycle III, Confederation Lake.
In a regional sense, this unit is the upper felsic
part of the cycle, however, note that the upper
unit changes gradationally from rhyolite to an
desite bulk composition. The diagram consists
of proximal facies on the left and more distal
units on the right.
Cyclicity in komatiites has been little studied, but
Arndt (1978) has noted the association of komatiite-
hosted Ni deposits with the high-MgO parts of
komatiite units (Figure 7.11) in Ontario and Western
Australia. Beyond a general spatial association with
high MgO-komatiites, no particular type of komatiite
unit appears to be favoured as the locus for nickel
mineralization. The ores occur in the basal part of
individual flows, and most authors suggest the nickel
sulphides occur there as a result of sulphide droplets
settling out of the silicate magma due to immiscibility.
Robinson and Hutchinson (1982) ascribe a
volcanogenic-exhalative origin to the Redstone nickel
deposit south of Timmins. The deposit of nickel sul
phides occurs above a calc-alkalic dacite tuff as
massive iron-nickel sulphides which grade along
strike into sulphide facies iron formation. This unit,
interpreted to be composed of chemical metasedi-
ments, is capped by komatiitic flows. In terms of
cyclical volcanism, then, the deposit occurs at a
stratigraphic level representing a volcanic hiatus. The
deposit originated by hydrothermal fluids circulating
through underlying komatiites and depositing Ni sul
phides at the rock-water interface.
CYCLICITY IN FELSIC SEQUENCES
Cyclicity in felsic volcanic sequences occurs on
scales ranging from the macro (103 m) through the
meso scale (102 m) to the micro scale (m to cm).
Only selected examples of each type wil! be de
scribed.
Mega-Scale Cycles
At Confederation Lake Cycle III, the youngest cycle,
can be subdivided (Figure 7.12) into a mafic base

felsic tuff
Figure 7.13. Schematic cross section of an individ
ual mafic flow at the Maybrun Mine with large
pillows at the base of the flow, small pillows
toward the top, and fine-grained tuff at the top
(after Setterfield et at. 1983).
(formation K) above which are dacitic pyroclastic
rocks of formation L and formation M, a rhyolitic
dome, and correlative flows and pyroclastic rocks. In
a regional sense, formations L and M together form
the felsic upper part of Cycle III. However, formation
L is composed of dacitic lapilli-tuff to tuff-breccia
with abundant shards, and broken phenocrysts. Also,
some evidence of welding which led Thurston
(1981 b) to interpret it as an ash-flow is present in this
formation. Formation M (above formation L) is inter
preted to be composed of dome-related flows and
less extensive pyroclastic units than in formation L.
These rocks accumulated in a fault-bounded trough.
Violent, extensive eruption of ash-flows (formation L),
followed by dome-related siliceous volcanism, has
been interpreted as a Plinian eruption followed by
caldera collapse; namely, formation of a sector
graben occurred. This represents major scale cyclic-
ity of volcanic processes and products. In younger
terrains, this type of cyclicity has been explained in
terms of the caldera cycle (Smith and Bailey 1968;
Smith 1979). Other Precambrian examples are at
Noranda (Dimroth et al. 1982), the Setting Net Lake
area (Ayres 1977), and Flin Flon, Manitoba (Syme et
al. 1982).
P.O. THURSTON
Meso-Scale Cyclicity
Formation M is the uppermost unit of Cycle III at
Confederation Lake. The formation consists of a
rhyolitic endogeneous dome with lenticular deposits
of collapse debris and about 1500m of overlying
felsic flows. These flows are succeeded by 1000 m
of felsic tuff-breccia to lapilli-tuff which grades
gradually to an andesitic composition. This is fol
lowed by 150m of felsic debris flows, air-fall tuffs,
and 45 m of pillowed mafic flows (Figure 7.12). The
cyclicity within this sequence is two fold: 1) eruption
type and products and 2) compositional cyclicity. The
sequence progresses from quiescent extrusion of
flows through violent eruption of coarse pyroclastic
rocks to quiescent eruption of mafic flows. Com-
positionally, this 1000 m thick sequence grades from
rhyolite at the base to andesite at the top. In the area
of southern Fly Lake (Thurston 1981 b), a single de
positional unit of ash-flow contains predominantly
essential fragments of dacite with some rhyolite frag
ments at the base and andesite fragments at the top
(Thurston and Hodder 1982). This single com-
positionally zoned unit and the overall compositional
zonation of formation M have been ascribed by Thur
ston and Hodder (1982) to eruption from a com-
positionally zoned magma chamber.
Micro-Scale Cyclicity
Ash-flows ranging in thickness from 1 to 5 m occur in
formation M at Confederation Lake (Thurston and
Hodder 1982). These rocks are poorly bedded lapilli-
tuff to tuff units displaying normal density and re
verse size grading of ash, pumice, and lithic frag
ments. The clast-types, geometry, and vertical se
quence of primary structures (compare Sparks et al.
1973, Figure 7.13) suggest an ash-flow origin
(Thurston 1981 b). The concentrations of pumice have
been flattened, extensively silicified, and epidotized
during vapour-phase recrystallization shortly after de
position. The mobility of sulphides is economically
significant in this regime. Pyrite has partly replaced
pumice fragments at the top of each thin ash-flow
depositional unit, creating areas of pyrite, minor pyr
rhotite, and traces of sphalerite forming up to 30 07o to
40 07o of the rocks over thicknesses of 15cm. This
phenomenon produced anomalous geophysical re
sponse (Assessment Files Research Office, Ontario
Geological Survey, Toronto) which was subsequently
drilled. This type of sulphide occurrence, however,
has limited economic potential.
HIATUSES
Stratigraphic hiatuses in volcanic sequences are of
ten marked by interflow units of clastic sediment,
chemical sediment, or fine-grained distal facies tuffs.
By virtue of their generally fine grain size, interflow
units can form the impermeable cap of Hodgson and
Lydon (1977) beneath which hydrothermal activity
produces mineral deposits at scales ranging from
single depositional units to meso-scale cycles.
113
CHAPTER 7

NORTH POLE BARITE volcanic rocks

sedimentary rocks
felsics volcaniclastics
barite±chert
basalts and quartz-feldspar
komatiites schist
sediments
chert Playter
Harbour
flows ——A~~ A ——— A Group
chert A A AA
pillowed flows A
pyroclastic rocks
BaSO4 and chert A
A A

Lower
Warrawoona mafic flows
Group
HEMLO
COMPOSITE
SECTION
Figure 7.l4a. Schematic cross section of barite-
bearing units in the North Pole area, Pilbara Figure 7.14b. Schematic cross section of the
Block, Western Australia (after Hickman et al. Hem lo area (after Muir 1982 and Patterson
1980). 1984).

DEPOSITIONAL UNIT SCALE
At the Maybrun Mine south of Kenora, Setterfield et
al. (1983) described mafic flows with minor interflow
cherty tuffs or zones of collapsed pillows sealing the
top of individual flows. Copper-gold mineralization is
preferentially concentrated toward the top of individ
ual flows because interpillow space increases up
ward in each flow as pillows become smaller and
more loosely packed (see Figure 7.13).
FE-ENRICHMENT CYCLE SCALE
We noted earlier that gold deposits at Red Lake,
Timmins, and Western Australia (Groves and Gee
1980) tend to be spatially associated with the iron-
rich top of tholeiitic sequences, the iron-rich basalts
are often overlain by auriferous chemical sediments,
usually ironstone. A non-economic example is the
Bobjo Prospect where sulphide facies ironstone over
lies variolitic iron-rich basalt in Formation K of Cycle
III at Confederation Lake/There, Thurston (1982) de
scribed the presence of above background (170 to
200 ppb) levels of gold in chemical sediments above
hydrothermally altered, epidotized tholeiitic basalts.
Hydrothermal alteration with substantial seawater
input is involved in the production of sedimentary
barite in South Africa (Heinrichs and Reimer 1977)
and Australia (Hickman et al. 1980) (Figure 7.14a).
These Archean barite occurrences represent both
veins and barite-rich sedimentation during a hiatus in
volcanism. Given the fact that barium and gold are
spatially associated, and the fact that the major
source of barium is seawater (Heinrichs and Reimer
1977), and the major source of gold is the surround
ing volcanic rocks (Fyfe and Kerrich 1984), a hy
drothermal system is probably the source of this

114

Confederation Lake Area
chert
^intermediate LLJ
felsic ^
1 Layer 2;^0 ,^ o;
^
"fr
--mafic
::::: i ::::
u ir
--felsic
•iiiiiSiiii-i
M
-mafic
felsic
O o
O)
III
mafic
B IIH
CO
0)
felsic
Figure 7.15. Minor scale cycles within the upper
part of Cycle H Confederation Lake. This is a
generalized overview to permit an appreciation
of the gross features of this scale of cyclicity.
Please see Figure 7.1 for greater detail.
mineralization type. The accumulation of gold in
chemical sediments such as barite in some occur
rences (Heinrichs and Reimer 1977) suggests that
perhaps the barium-gold mineralization at Hemlo
(Patterson 1984) may be related to a hiatus in vol
canism (Figure 7.14b). This very premature sugges
tion is subject to verification in the field.
Chert fragment-rich conglomerates with angular
chert fragments occur above the basalt in the
Phinney-Dash Lakes area (Edwards and Hodder
1981). These authors suggest the chert represents
chemical sedimentation during a hiatus in basaltic
volcanism. Brecciation and slumping of the chert to
form the conglomerate was produced by hydrother-
P.O. THURSTON
v L a y e r 1 |^f|g||jgS fine ash-fall
deposit
i
pumice c?
clasts
o
o p 0 0..o. o D
lithic . 0o'.'Q-,?-.'0 ?. one flow unit
cc clasts no 9.9^0c
o
t\ ground surge
vLayer 3 deposit
Plinian ash-fall
deposit
LLJ
-J Figure 7.16. Schematic cross section of a typical
O ash-flow (after Sparks et a l. 1973). Layer 1
> consists of crossbedded tuffs of base surge
origin. Layer 2 is lapilli-tuff to tuff-breccia,
poorly sorted, showing reverse size grading,
cc that is, concentration of pumice fragments in
o the upper part and normal density grading with
denser lithic fragments toward the base. This
unit is produced by gravitational collapse of
the eruption column. Layer 3 is poorly sorted,
poorly and generally thin bedded tuff deposited
from the ash cloud.
mal activity beneath the immpermeable chert cap
leading to steam-driven brecciation of the chert. Gold
prospects are associated with this unit (Edwards and
Hodder 1981).
Minor scale chemical cycles in volcanism are
important in Au deposition at the Hill-Sloan-Tivey
quartz horizon east of Confederation Lake (Thurston
1982). Four minor cycles, each above 150 m thick,
occur in Cycle II. These cycles consist of basal
basaltic "andesites overlain by rhyolite and chemical
sediment (Figure 7.15). The chemical sediment units
represent hiatuses in volcanism, terminating some of
the minor scale cycles. Based upon chemical evi
dence, Thurston and Fryer (1983) suggested these
cycles were the product of eruption from a chemi
cally zoned magma chamber. Gold mineralization oc
curs in the chemical sediments at the top of one of
the minor cycles (Thurston 1982) and in vein systems
cutting these units.
HIATUSES IN FELSIC SEQUENCES
Hiatuses in felsic volcanism may be produced by the
catastrophic emptying of the magma chamber during
a Plinian eruption, that is the production of ignim-
115
CHAPTER 7
South Bay Mine 1050 foot level
Figure 7.17. Cycle III Confederation Lake-schematic cross section of the Selco Cu-Zn-Ag orebody (after
Thurston et al. 1978).
brites. A cross section of a typical ignimbrite is
shown in Figure 7.16.
As described above, the top of formation L in
Cycle III at Confederation Lake marks the cessation
of Plinian eruptive activity and the onset of caldera
collapse. The collapse is the sagging of the magma
chamber roof which may founder piecemeal or as a
unit. The cause of the collapse is the catastrophic
emptying of the magma chamber. This is represented
in stratigraphic terms by a hiatus in volcanism, where
small scale hydrothermal activity may occur by anal
ogy with similar systems in younger terrain (Cruson
and Pansze 1983). The lack of large scale hydrother
mal activity at this stratigraphic level at Confeder
ation Lake, for example, has been noted by Sopuck
(1977).
The hiatus in felsic volcanic activity marked by
the contact between the endogeneous quartz-feld
spar prophyry dome and associated dome-collapse
talus deposits (Pollock et al. 1970; Thurston 1981 b) is
the site of the South Bay copper-zinc-gold vol
canogenic massive sulphide deposit (Figure 7.17).
Following the conventional model for volcanogenic
massive sulphide genesis (Franklin et al. 1981), the
mineralizing hydrothermal activity took place during a
hiatus in volcanism.
MAGMA CLAN TRANSITIONS
As shown in the above survey of chemical types of
volcanic cyclicity, there are ample opportunities for
development of depositional hiatuses during the tran
116
qQFP-1
.j i_j dacite breccia
jQFP-2 incipient ^felsite dike
QFP-2 \lllh orebody
rhyolite
sition from one magma clan to another. This provides
the opportunity for chemical or clastic sedimentation
of marble, barite, ironstone, and so on, with or with
out gold mineralization. Examples of mineralized
magma clan transition include the Adams Mine, a
komatiitic tholeiite transition (MERQ/OGS 1984), and
the Sherman Mine, a tholeiite calc-alkalic transition
(Bennett 1978). Both are iron deposits. Gold occurs at
the tholeiite-calc-alkalic transition in Cycle II at Con
federation Lake (Thurston 1982). The location of iron
stone and massive sulphide bodies toward the top of
the Cycle II calc-alkaline sequence in the Abitibi
Subprovince (MERQ-OGS 1984; Pyke and Middleton
1970) are basically controlled by the transition from
calc-alkalic volcanism of Cycle II to the komatiitic
volcanism which begins Cycle III.
THE CALDERA CYCLE
This section describes the application of conceptual
models developed for modern volcanic rocks to Ar
chean sequences. This is done to show that Archean
volcanism does not differ substantially from
Phanerozoic analogues and, more importantly, that
these conceptual models may be used to predict the
place of mineralization in Archean sequences. Exam
ples of this type of analysis for the Confederation
Lake area are described in detail, herein.
The complexities of volcano evolution from qui
escent eruptions to large-scale violent Plinian erup
tions, caldera formation, and renewed volcanism are
all part of a logical, connected series of events, the

slump deposits from caldera wall
Figure 7.18. The Caldera cycle (after Smith and Bailey 1968). The numbers refer to stages in the Caldera
cycle explained in the text.
caldera cycle (Figure 7.18). The caldera cycle was
developed by Smith and Bailey (1968) to unify these
apparently disparate events into an organized con
cept. Their work was based upon the series of events
at the Valles caldera in the U.S.A., and has the
following seven stages:
1. regional tumescence and generation of ring frac
tures
The area of tumescence is generally larger than the
outer ring fractures of a given cauldron.
2. caldera forming eruptions
P.O. THURSTON
pre-resurgent volcanic rocks
ring fracture volcanic rocks ring fracture volcanic rocks
^
Stages S&7
The caldera "a circular volcanic depression, more or
less circular or cirque-like in form" (Williams 1941) is
produced by the collapse of the roof of the magma
chamber upon the catastrophic emptying of the
chamber at eruption. The eruptions are Plinian; pro
duced by the explosive frothing and disintegration of
magma by internally produced gas bubbles (Sparks
1978). This explosive fragmentation produces a large
eruption column with a vertical extent of 30 to 50 km,
a high degree of fragmentation, and dispersal of the
products (Walker 1973). This stage is represented by
formation l at Confederation Lake.
3. caldera collapse
117
CHAPTER 7
andesite
Figure 7.19. Schematic cross section of a com-
positionally zoned magma chamber (after Hil
dreth 1979). The chamber is Si, LIL element
(Rare Earths and so on) and volatile rich at the
top and phenocryst poor. Silicon content, LIL
elements, and volatiles decrease and
phenocrysts become more abundant down
ward. The chamber is heated by periodic intru
sion of mantle derived basalt.
The catastrophic emptying of the magma chamber
leads to piecemeal or monolithic collapse of the
magma chamber roof. The collapse allows the cal
dera to fill with the products of Stage II above, giving
rise to the notion of an intracaldera ignimbrite
(Lipman 1976) trapped within the topographic wall of
the caldera usually volumetrically dominant, and an
outflow facies, the smaller part, which spills out of
the caldera. This stage is marked by the intrusion of
granitic sills at Confederation Lake (Thurston (1981).
4. preresurgence volcanism and sedimentation
This stage chiefly involves infilling of the caldera
with debris from the caldera walls by caving, ava
lanches, and gravity sliding. Volcanism is relatively
uncommon, but is found in the Creede caldera. Lake
beds are often found with calderas (for example,
Hildebrand 1982). This stage has not been recorded
at Confederation Lake.
5. resurgent doming
This stage involves topographic doming within the
caldera as the magma chamber re-inflates. A variety
of types of grabens, with dips up to 65C are produced
by the doming. The question of the causes of resur
gence and associated doming was addressed by
Marsh (1981). He feels that in a theoretical analysis,
regional detumescence, the sinking of the regional
surface after inflation prior to the first eruption, is
favoured because it produces the observed time lag
of about 105 years between caldera initiation and
resurgence.
6. major ring-fracture volcanism
This stage involves volcanism from the moat or ring-
fracture and the products are often intercalated with
sediments from Stage IV above. This stage often
completely fills the caldera. M this stage, about 800
000 years from caldera initiation will have elapsed.
This stage is represented in several areas by post-
118
collapse volcanic domes and associated extrusives
(Thurston 1981).
7. terminal solfataric and hot-spring activity
This stage, when present, is due to the incomplete
evacuation of the magma chamber. The remaining
magma freezes in place, but the gradual loss of heat
is accomplished by conduction by hydrothermal
fluids which: 1) alter surrounding volcanic rocks; 2)
are responsible for leaching of copper, zinc and so
on from their surroundings and deposition in cooler
areas as volcanogenic massive sulphide deposits.
The hydrothermal activity of Stage VII does hot occur
during Stages III to V of the caldera cycle because
the magma chamber has been catastrophically emp
tied during Stage II, hence, there is no magma avail
able which needs to lose heat by conduction through
flow by hydrothermal fluids and no source of
halogens to increase the efficiency of the metal-
leaching process. This stage is represented by vol
canogenic copper-zinc sulphide deposits in several
Superior Province greenstone belts.
ZONED MAGMA CHAMBERS
Within the Caldera Cycle model provided by Smith
and Bailey (1968), more recent work (Hildreth 1979,
1981; Smith 1979) has shown that many ignimbrite-
producing magma chambers are chemically zoned
(Figure 7.19). These chambers are large, with a domi
nant volume of rhyolitic magma forming the upper
part of the chamber. The rhyolite is underlain succes
sively by dacitic, andesitic, and basaltic liquid. Epi
sodic addition of mantle-derived basalt to the base of
the chamber supplies heat to keep the upper part
liquid. Convection occurs throughout the chamber
(McBirney and Noyes 1976), and some combination
of convection, a slow process in viscous felsic melts,
and volatile streaming is active in the upper rhyolitic
part of the chamber. In a major element sense, this
upper part is rhyolitic; however, Hildreth (1979) de
scribed large trace element concentration gradients
within melts of essentially constant major element
composition.
Commonly, these chambers are catastrophically
emptied during Plinian eruptions (Smith 1979). This
may occur when the arrival of a fresh batch of
basaltic magma at the base of the chamber saturates
the felsic part of the system in volatiles which trig
gers the eruption (Sparks et al. 1977). Alternatively,
the small convective cells present in a compositional-
ly zoned chamber may rapidly roll over (Rice 1981;
Huppert et al. 1982). This process can occur (Huppert
et al. 1982) when the specific gravities of the basaltic
and overlying rhyolitic magmas become equal. This
can come about through the fractionation of mafic
minerals of high specific gravity from the basalt. This
has two effects. It immediately makes the basaltic
magma lighter, and renders the magma supersaturat
ed in volatiles, causing vesiculation which again de
creases its specific gravity.
Thurston and Hodder (1982) have analyzed the
development of Archean stratigraphy at Confeder
ation Lake in terms of a model involving the tapping
of a compositionally zoned magma chamber during
resurgent volcanism (Stage VI of Smith and Bailey
1968). Observations fitting the model include:

1. a progressive decrease in SiO2 with stratigraphic
height within Cycle III
2. a decrease of Si02 with stratigraphic height in
individual ignimbrite depositional units
3. crossing rare earth elements patterns related to
the heavy rare earth element enriched character
of the top of the Cycle III magma chamber similar
to that found in younger, compositionally zoned
chambers
Thurston and Hodder's (1982) analysis indicates
that Cycle III of Confederation Lake represents cal
dera collapse and resurgent magmatism developed
from a compositionally zoned magma chamber.
These authors suggest both features are present in
many copper-zinc mineralized successions. Further
analysis showed (Thurston el al. 1984) that rhyolites
involved in development of copper-zinc deposits are
produced by contamination of felsic magma with
large volumes of sialic crust. The crust provides the
abundant fluorine and other volatiles needed for met
al transport.
APPLICATIONS TO EXPLORATION
The stratigraphy of Cycle III at Confederation Lake
has been analyzed in terms of resurgent volcanisms
in a caldera cycle model involving a compositionally
zoned magma chamber. The question is whether this
problem is repeated elsewhere and whether there is
a pattern with application to exploration. Some intrigu
ing possibilities exist.
The stratigraphy of Noranda has been analyzed
in terms of a caldera collapse (de Rosen-Spence
1976). Gibson has demonstrated (Gibson et at. 1983)
that post-collapse volcanism is directly related to
copper-zinc deposits. Composite dikes mapped by
Gibson (Geologist, Falconbridge Copper, personal
communication, 1983 ) include xenoliths of partly
melted granitic rocks, showing directly the involve
ment of melted sial in petrogenesis. This scenario is
also borne out by analysis of trace element geo
chemistry (Gelinas and Ludden 1984).
Caldera collapse is described in the Setting Net
Lake area (Ayres 1977), where alteration within the
caldera sequence is widespread (L.D. Ayres, Profes
sor, University of Manitoba, personal communication,
1980). Lead-rich vein deposits occur within the cal
dera sequence (Adams 1976).
Stratigraphic and volcanologic analysis of other
Archean terrains should yield similar histories of vol-
canological processes in that collapse often follows
large ignimbrite eruptions. In fact, Thurston et al.
(1985) suggested that ignimbrite eruptions were the
dominant style of Archean felsic volcanism. The com
positionally zoned nature of many Archean felsic
successions is shown by a unique trace element
geochemical signature (Campbell et al. 1984) which
Thurston et al. (1985) maintained was the result of
compositionally zoned magma chambers.
SUMMARY
In this paper, it is noted that a knowledge of stratig
raphic position in particular types of volcanic cycles
is essential. A model of the volcano's behaviour can
P.O. THURSTON
be developed which is based upon stratigraphic suc
cessions such as ash-flows (Plinian) followed by
domes, flows, and small-scale ash flows. These
models involve caldera collapse after ash-flow erup
tions, re-inflation of a compositionally zoned cham
ber, and resurgent volcanism. This pattern of collapse
and resurgence occurs around a compositionally zon
ed chamber as evidenced by the major and trace
element variation patterns and stratigraphic charac
teristics.
An understanding of these processes and cyclic-
ity on a variety of scales permits the geologist to
predict more confidently probable sites of mineraliza
tion. This, of course, does not avoid the necessity for
conventional exploration procedures. It simply pro
vides a new means of evaluating the mineral poten
tial of large tracts of "greenstone" successions.
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Ayres, P.C. Thurston, K.D. Card, and W.W. Weber,
Geological Association of Canada, Special Paper
Number 28.
Thurston, P.C., and Fryer, B.J.
1983: The Geochemistry of Repetitive Cyclical Vol
canism from Basalt Through Rhyolite in the Uchi-
Confederation Greenstone Belt, Canada; Contri
butions to Mineralogy and Petrology, Volume 83,
p.204-226.
Thurston, P.C., and Hodder, R.W.
1982: Trace Element Geochemistry and Volcanology
of a Mineralized Felsic Center; Geoscience Re
search Seminar, December 8-9, 1982, Abstracts,
Ontario Geological Survey, 15p.
Thurston, P.C., Wan, J., Squair, H.S., Warburton, A.F.,
and Wierzbicki, V.W
1978: Volcanology and Mineral Deposits of the Uchi
Confederation Lakes Area, Northwestern Ontario;
p.302-324 in Toronto '78 Field Trips Guidebook,
edited by A.L Currie and W.O. Mackasey, Geo
logical Society of America-Geological Association
of Canada-Mineralogical Association of Canada,
361 p.
P.O. THURSTON
Trowell, N.F., Blackburn, C.E., and Edwards, G.R.
1980: Preliminary Geological Synthesis of the Savant
Lake-Crow Lake Metavolcanic Metasedimentary
Belt, Northwestern Ontario, and Its Bearing Upon
Mineral Exploration; Ontario Geological Survey,
Miscellaneous Paper 89, 30p. Accompanied by
Chart A.
Viljoen, R.P., and Viljoen, M.J.
1969: The Geological and Geochemical Significance
of the Upper Formations of the Onverwacht
Group; p. 113-152 in Upper Mantle Project, Geo
logical Society of South Africa, Special Publica
tion Number 12.
Walker, G.P.L
1973: Explosive Volcanic Eruptions-A New Classifica
tion Scheme; Geologische Rundschau, Volume
62, p.431-446.
Wallace, H., Thurston, P.C., and Corfu, F.
In Press: The Western Uchi Subprovince: A Case
Study; in Volcanism and Mineral Exploration, edit
ed by H. Wallace, Ontario Geological Survey,
Miscellaneous Paper.
Williams. H.
1941: Calderas and Their Origin; California University
Publications in the Geological Sciences, Volume
25, p.239-346.
Wilson, H.D.B., Morrice, M.G., and Zielke, D.V.
1974: Archean Continents; Geoscience Canada, Vol
ume 1, p. 12-20.
123
Chapter 8

Recognition of Alteration in Volcanic Rocks Using

Statistical Analysis of Lithogeochemical Data
E.G. Grunsky

CONTENTS 12a. K20 unprocessed .............................. 137

Abstract ........................................................... 125 12b. K20 residual....................................... 137
Introduction .................................................... 125 13a. Ti02 unprocessed ............................. 138
Geology of the Ben Nevis Township Area 126 13b. Ti02 residual...................................... 138
Alteration ........................................................ 127 14a. C02 unprocessed .............................. 139
Lithogeochemistry ........................................ 128 14b. C02 residual ...................................... 139
Isochemical Contour Plots............................ 129 8 15a. Sulphur unprocessed ....................... 140
Normalization Schemes and Techniques 15b. Sulphur residuals .............................. 140
for Identifying Alteration .............................., 147 16a. H 2O^ unprocessed........................... 141
Statistical Techniques .................................., 149 16b. HJO+ residual ................................... 141
Conclusions ..................................................., 161 17a. Gold unprocessed ............................ 142
Acknowledgments ........................................, 161 17b. Gold residual..................................... 142
References ....................................................., 172 18a. Copper unprocessed ........................ 143
18b. Copper residuals............................... 143
TABLES 19a. Lithium unprocessed ........................ 144
Correspondence analysis: major 19b. Lithium residual ................................ 144
oxides ..................................................... 150 20a. Nickel unprocessed.......................... 145
2. Correspondence analysis: major 20b. Nickel residual .................................. 145
oxides and trace elements .................. 159 21a. Zinc unprocessed ............................. 146
Dynamic cluster nucleii and average 21b. Zinc residual...................................... 146
compositions of each cluster ............. 163
22. Distribution of normative corundum . 148
Dynamic cluster nucleii and average
compositions of each cluster ............. 167 23. Distribution of normative calcite....... 148
24a to 24e. Correspondence analysis,
FIGURES factor scores of samples and
chemical components ......................... 151
8.1. Location map ....................................... 125
25a to 25e. Contour expressions of
8.2. Geology of the Ben Nevis area......... 126 Factors 1 to 5 ....................................... 152
8.3. AFM diagram of the Ben Nevis area 126 26a to 8.26e. Correspondence analysis,
8.4. Distribution of samples in the Ben factor scores of samples and
Nevis area........................................... 128 chemical components ......................... 156
8.5a. Distribution of SiO2 outlining rock 27a to 8.27e. Positive and negative
types .................................................... 130 anomalies.............................................. 157
8.5b. Si02 residual ...................................... 130 28a to 8.28e. Geographic presentation
8.6a. AI203 unprocessed ............................ 131 of some of the groups in the Ben
8.6b. AI 203 residual .................................... 131 Nevis area, and location of some of
the groups in the factor space .......... 161
8.7a. Fe203 unprocessed ........................... 132
.29a to 8.29d. Geographic presentation
8.7b. Fe203 residual.................................... 132
of certain groups in the Ben Nevis
8.8a. FeO unprocessed .............................. 133 area using dynamic cluster analysis
8.8b. FeO residual ...................................... 133 and groups in the factor space. ........ 166
8.9a. MgO unprocessed ............................. 134
8.9b. MgO residual ..................................... 134 PHOTOGRAPHS
8.10a. CaO unprocessed ........................... 135 8.1 Carbonate, quartz, and chlorite
8.10b. CaO residual.................................... 135 amygdules in a pillowed basalt....................... 127
8.11a. Na20 unprocessed.......................... 136 8.2. Replacement of Ca-rich plagioclase
8.11b. Na20 residual .................................. 136 phenocryst by calcite........................................ 127

124

ABSTRACT
A statistical study of the lithogeochemistry of the
volcanic rocks in the Ben Nevis area of Ontario has
shown that spatial presentation combined with cor
respondence analysis and dynamic cluster analysis
can be used to delineate stratigraphy as well as
alteration zones characterized by carbonatization and
sulphur enrichment. An extensive zone of carbonatiz-
ed volcanic rocks surrounds a zone of mineralization
in this area.
Correspondence analysis calculates factors
which explain the distribution of data with respect to
the variation patterns that are represented by the
chemical component abundances. In the case of the
Ben Nevis data, when major oxides are used, the first
and most significant factor describes the com
positional variation in the original igneous trend
(fractionation trend); the second factor characterizes
the compositional variation due to the process of
carbonatization; the third factor indicates com
positional variation in the form of sulphur enrichment
associated with mineralization. The use of major ox
ides combined with trace elements produces similar
results.
Dynamic cluster analysis groups together sam
ples that have been affected by similar processes.
Groups related to fractionation trends can be clearly
distinguished from groups that have undergone alter
ation processes.
When properly applied and interpreted, these sta
tistical techniques can assist in mineral exploration.
Figure 8.1. Location map.
EC. GRUNSKY
INTRODUCTION
Volcanic rocks are commonly host to several types of
mineral deposits such as massive sulphide deposits
(Sangster and Scott 1976) and epithermal deposits
(Rose and Burt 1979). Alteration is associated with
these deposits and is discernible in the form of
mineralogical, textural, and chemical changes due to
the circulation of hydrothermal fluids. Most deposits
are surrounded by haloes of alteration defined by
anomalous chemical abundances; these zones are
spatially much larger than the ore deposits them
selves and form significant exploration targets. The
use of lithogeochemistry can be instrumental in de
tecting these alteration zones if statistical techniques
are used effectively to recognize patterns of alter
ation within sample populations.
A lithogeochemical study was carried out by the
Ontario Geological Survey in the Ben Nevis Township
area, Ontario (Figure 8.1), in which zones of alter
ation associated with mineralized occurrences
(Figure 8.2) were identified using the technique of
correspondence analysis combined with dynamic
cluster analysis. A previous study by Wolfe (1977) in
the same area outlined a zone of zinc enrichment
related to a dispersion halo which Wolfe attributed to
an alteration pipe associated with the formation of
volcanogenic massive sulphide deposits.
Locally, the two most significant mineral occur
rences are the Canagau Mines Deposit and the Crox-
all Property. Detailed property and deposit descrip
tions can be found in Jensen (1975).
The Canagau Mines Deposit is underlain by
strongly carbonatized, sericitized, and silicified mafic
and felsic volcanic rocks. Mineralization consists of
galena, sphalerite, gold, silver, and pyrite within east-
125
CHAPTERS

ii4.'-*r; A
vCahaga
-Mihes

^^an'ge'
Lake

mineral occurrence ® mafic and intermediate intrusive rocks

fault —— mafic and intermediate volcanic rocks
granitic rocks n~ri felsic volcanic rocks

Figure 8.2. Geology of the Ben Nevis area.

trending fractures and shear zones that dip 40C to 60C
toward the south. Grades and tonnages are unknown,
but the deposit is not currently considered to be
economic.
The Croxall Property consists of a zone of brec
ciated and sheared rhyolite with interstitial pyrite,
chalcopyrite, chlorite, calcite, and quartz. Gold as
says have been reported up to 0.04 ounce per ton.
nected by planar stringers of quartz and/or carbonate
•O mm across. These stringers probably represent a
microfracture system that increased the permeability
of the rocks and controlled the circulation of fluids.
Many zones of large amygdules cut across pillows
FEO (TOTAL)

GEOLOGY OF THE BEN NEVIS TOWNSHIP

AREA_________________________
The Archean volcanic rocks of the Ben Nevis area
comprise the top of the Blake River Group within the
Abitibi volcanic-sedimentary belt in Ontario. This
group is exposed in a broad east-trending syn
clinorium from south of the Matheson area in Ontario
eastward to the Noranda area of Quebec (see Figure
8.1). The area has been mapped in detail by Jensen
(1975; Figure 8.2) and is underlain by volcanic rocks
of calc-alkalic affinity (Figure 8.3). The most common
volcanic rocks are basaltic pillowed flows, pillow
breccias, and breccias.
Many of these volcanic rocks appear to be amyg
daloidal, with vesicles varying in amounts from -clVo
to ^00Xo, and with a size range of 1 mm to 3 cm
across. Such vesicularity provides the porosity for the
circulation of hydrothermal fluids. In some areas, Figure 8.3. AFM diagram of the Ben Nevis area.
many of the larger amygdules ^5 mm) are con Note the calc-alkalic trend.

126

Photo 8.1. Carbonate, quartz, and chlorite amyg-
clules in a pillowed basalt. The larger "ovoids"
are interconnected by quartz-carbonate tilled
microfractures and may be secondary in origin.
and pillow selvages. This would suggest a secondary
origin. Macdonald (1983) suggested that "ovoids" in
mafic volcanic flows, that are commonly mistakenly
identified as amygdules, are possibly due to secon
dary effects related to alteration. It seems probable,
therefore, that many of the larger quartz-carbonate
ovoids that are connected by microfractures are sec
ondary in origin and related to the development of
the alteration zone.
Two major felsic volcanic units consisting of
rhyolitic and dacitic tuff, tuff-breccia, and flows occur
within the predominantly mafic volcanic sequence.
The volcanic environment in the Ben Nevis area is
interpreted as proximal, with a volcanic centre occur
ring in the vicinity of the Clifford Stock. The volcanic
sequence is intruded by gabbroic and dioritic bodies
of tholeiitic affinity (Figure 8.3) and is folded into a
domical anticlinal structure within the larger Blake
River Synclinorium (see Figure 8.1).
The area is intersected by several faults that are
believed to be related to volcanic activity and later
doming of the sequence. A major north-trending fault
in the eastern part of Ben Nevis Township is part of a
regional lineament that transects the Blake River
Group. This fault may be a deep seated structure; a
possible conduit for hydrothermal fluids that passed
through the eastern part of the Ben Nevis area.
ALTERATION
Rocks of the Ben Nevis area have been metamor
phosed under conditions of burial metamorphism and
are represented by zeolite facies and prehnite-pum-
pellyite facies (Jensen 1975). Around the felsic intru
sions, the metamorphic grade is albite-epidote horn
fels facies.
Through the Ben Nevis area, chlorite is a com
mon constituent in the amygdules and in the ground
mass of the mafic to intermediate volcanic rocks. The
origin of the chlorite is probably due to the inter
action of C02-rich hydrothermal fluids with the host
rock and the resultant destabilization of Ga and the
resultant assemblage of chlorite and/or albite (Michel
EC. GRUNSKY
carbonate-rich
groundmass
Photo 8.2. Replacement of calcium-rich plagioclase
phenocryst by calcite. Groundmass contains
fine-grained calcite and dolomite.
Mellinger, Research Scientist. Saskatchewan Re
search Council, personal communication, 1985).
Petrographic studies have shown the presence of
saussurite that formed from the breakdown of
plagioclase. Saussurite occurs throughout the mafic
to intermediate volcanic sequence where C02 phases
were not present ( Michel Mellinger, Research Scien
tist, Saskatchewan Research Council, personal com
munication. 1985). Sericite is also present in both the
mafic to intermediate volcanic rocks and the felsic
volcanic rocks. Its presence within the felsic volcanic
rocks may be explained by the breakdown of or
thoclase, albite, and other potassium-bearing min
erals during metamorphism; however, the sericite
within the mafic to intermediate volcanic rocks sug
gests that fluids enriched in potassium passed
through these rocks causing alteration.
In the field, the most obvious form of alteration is
pervasive carbonatization (Photo 8.1). The bleached
appearance and deep weathering rind typical of
these rocks allow for easy visual identification.
Intense pervasive silicification occurs only in the
Canagau Mines Deposit. Within the main zone of
pervasive carbonatization, the quartz-carbonate
ovoids are much less abundant. Ovoids that do occur
contain only carbonate. This may be due to replace
ment of quartz by calcite. Alternatively, quartz could
have formed only away from the main centre of
carbonate alteration where different temperature or
chemical conditions prevailed.
In thin section, the carbonate occurs as large
anhedral patches in the matrix of mafic flows (Photo
8.2). Pervasive replacement of the matrix is most
widespread close to the north-trending fracture in the
eastern part of Ben Nevis Township. X- ray diffraction
studies of the carbonate indicate that the dominant
phase is calcite with only trace amounts of mag
nesite, dolomite, ankerite, and siderite (Geoscience
Laboratories, Ontario Geological Survey, Toronto). Do
lomite was noted to be more common in the matrix
than in the ovoids or amygdules. Thin section studies
indicate that the carbonate commonly formed through
replacement of plagioclase; thus, it appears that cal
cium was not added to the system, but was recom-
bined with externally derived C02. Other evidence,
that will be presented below, suggests that calcium
127
CHAPTER 8
790 48'00"
48"20'30
;- -- \ :\ v.\ --W
\ \ N, V .
\ \ \ \
Figure 8.4. Distribution of samples in the Ben Nevis area.
was removed from the main centre of carbonatiza
tion.
Away from the main zone of carbonatization, the
pervasive carbonate alteration decreases, and there
is an increase in carbonate and silica flooding (Photo
8.2). The flooding commonly takes the form of amyg
dule or "ovoid" fillings and interconnecting microfrac-
tures filled with quartz and/or calcite. The increase
of flooding and decrease of pervasive alteration may
reflect a temperature gradient in the alteration zone.
Textural relationships within quartz-rich ovoids gen
erally show that the chlorite-rich rims formed first,
followed by infilling with quartz. Calcite occurs as the
latest mineral phase within the ovoids.
Locally, zones enriched in pyrite occur in the
Canagau Mine area and the Croxal! Property. These
zones contain disseminated pyrite and minor
amounts of other sulphides and occur within the
larger alteration zones surrounding both mineral oc
currences. A zoning of sulphide abundance is more
pronounced at the Croxall Property where the min
eralization is in the form of a breccia-pipe from which
sulphur-rich fluids circulated outward into the sur
rounding host rock. The effects of S enrichment will
be shown in the subsequent treatment of the data.
LITHOGEOCHEMISTRY
The samples used in this study were collected from
three sources. These are:
1. samples collected by Jensen (1975)
2. samples collected by Wolfe (1977)
3. samples collected by the author from 1979 to
1981
128
' \ \ ,
.-\ \
- —--—l 48" 16'25"
79" 37'32"
The samples collected by Jensen and Wolfe
were analyzed by techniques outlined by Wolfe
(1977, p. 10); samples collected by the author were
analyzed by methods outlined by Grunsky (in prep
aration). A total of 864 samples were used for the
study and 39 components were analyzed for each
sample: Si02, AI 203. Fe203, FeO, MgO, CaO. Na2O,
K 20, Ti02 , P 2O5, MnO, CO2 , S, H 2CK, H 2O-, Ag, As, Au,
Ba, Be, Bi, CI, Co, Cr, Cu, F, Ga, Li, Ni, Pb, Zn, B. Mo,
Sr. V, Y, Zr, Se, and Sn. Every outcrop sampled in the
area is represented in the data by at least one
sample typical of the outcrop. Figure 8.4 shows the
distribution of the samples over the area. It is impor
tant to note that the distinction between pervasive
and non-pervasive alteration cannot be distinguished
by lithogeochemistry alone.
Complications in sampling commonly occurred
because many breccia units are heterolithic and be
cause amygdaloidal rocks are highly variable in
amygdule/ovoid content. One of the purposes of the
study was to determine if any significant indications
of alteration could be detected by sampling the typi
cal or dominant rock type of a given outcrop. Thus,
samples were selected for their geochemical signa
ture with respect to alteration as opposed to their
original rock type. The lithogeochemistry of a car-
bonatized heterolithic breccia may not provide a use
ful indication of the different rock types that com
prise the unit; however, the amount of C02 present
will show up regardless of the rock types involved.
On the other hand, the lithogeochemistry of a
silicified heterolithic breccia will probably not reflect
an increase in silica since the rock might be inter
preted as a rhyolite. Such problems had to be consid
ered in the interpretation of lithogeochemical data.

Samples rich in sulphides were collected and
analyzed; however, some were eliminated in the sub
sequent data processing. Such samples tend to ex
hibit highly varied component abundances. This
causes spiked peaks in spatially distributed anoma
lies and can mask the more subtle lithogeochemical
indicators of alteration. Because sulphide-rich rocks
are very different compositionally from unmineralized
volcanic rocks, they tend to produce a high degree of
variance in the data and can result in misleading
interpretations. Emphasis in this study has been
placed on selecting samples that will yield broad
generalized patterns of alteration detectable on a
reconnaissance scale that enable selection of sites
for mineral exploration.
ISOCHEMICAL CONTOUR PLOTS
Figures 8.5 through 8.21 contain isochemical contour
plots of the elements that were analyzed for the
study. The contour diagrams are modified from plots
drawn by the Surface II Graphics Systems (Sampson
1975). Each figure is composed of two parts. Figure
"A" shows the contoured raw data. Figure "B" shows
the "residual" value of the chemical component, that
is, the abundance of a chemical component after an
"expected" value has been subtracted from the ac
tual abundance. The "expected" value is defined as
the component abundance that would be expected
for a given rock type.
These expected values were defined in the fol
lowing way. The standards (expected values) were
computed from the lithogeochemical database for the
study area only. This was done because rock types
that are "normal" (unaltered) in the Ben Nevis area
may be somewhat different in composition from other
areas.
Each sample was classified using the chemical
classification methods of Irvine and Baragar (1971)
and Jensen (1976). For each chemically classified
group of samples (for example, calc-alkalic basalts),
a mean and standard deviation was computed for
each chemical component. Every component of each
sample was then compared with the mean of each
component for the calculated group. If the component
value exceeded the mean plus two standard de
viations, then the sample was rejected. A new mean
for each component of each group was calculated on
the sample population that was not rejected, and the
comparison of the samples with the new mean val
ues was repeated. This method was carried out three
times, forcing a "normal" or "expected" value on
each chemical component of each chemically clas
sified group.
This can be thought of as a method of correcting
or normalizing the geochemical data which is re
quired because of the natural chemical variation in a
volcanic suite even before alteration. This method
has limitations and is discussed below.
The unprocessed (Figure"A") isochemical plots
typically reflect three phenomena:
1. compositional variation due to rock type
2. regional zones of alteration (regional car
bonatization, Ga depletion)
E.G. GRUNSKY
3. local zones of mineralization-chalcophile distribu
tion
Typically, the spatially mapped abundances of
Si02 (Figure 8.5a), AI 203 (Figure 8.6a), Fe203 (Figure
8.7a), FeO (Figure 8.8a), MgO (Figure 8.9a), CaO
(Figure 8.10a), K 20 (Figure 8.12a), Ti02 (Figure
8.13a), C02 (Figure 8.14a). H 2CT (Figure 8.16a), and
Ni (Figure 8.20a) reflect the compositional variation.
However, some elements such as MgO, CaO, Fe203,
Zn, Cr, and H 20 not only vary with composition due
to rock type, but also vary in abundance due to the
effects of hydrothermal alteration. Elements such as
Au (Figure 8.17a), Cu (Figure 8.18a), Zn (Figure
8.21 a), Pb, and Sn are typically low in abundance at
the regional scale. Locally, high abundances of these
components are often found around zones of alter
ation and/or mineralization. Zinc is unique because it
can substitute for Fe^ 2 in lattices of ferromagnesian
minerals; thus, its abundance varies directly with
rock composition. Hydrothermal alteration can cause
the breakdown of these ferromagnesian minerals.
This frees the Zn. In the vicinity of an alteration halo,
the Zn may recombine in part with S, and substitute
into the chlorite lattice to create an anomaly asso
ciated with rock composition, hydrothermal alteration,
and sulphide concentration.
The association of certain components with alter
ation and mineralization cannot always be easily de
tected. As discussed earlier, compositional variation
due to rock type can mask these secondary features.
If the influence due to rock type is removed, it is
possible to "see" which components have been af
fected by alteration, and which are associated with
mineralization. To "normalize" or correct for rock
type, the expected value of the component is sub
tracted from its measured value, the difference being
termed the "residual". The "residual" value does not
necessarily reflect the amount of alteration. Some
components such as Si02 show a highly variable
concentration in individual rock types. Residual val
ues should only be considered anomalous if greater
than the standard deviation or some other determined
confidence level. Figure 8.5b shows Si02 anomalies
with residual values ^.0 070 (silicification) and ^.07o
(silica leaching). The pattern is erratic over the area,
but locally, strong silica enrichment is seen in the
vicinity of the Canagau Mine Deposit and the Croxall
Property. Silica depletion occurs in sulphide-rich
zones and mafic plutons.
More typically, residuals reflect the components
associated with alteration and mineralization. Compo
nents such as AI 203 (Figure 8.6b), Fe203 (Figure
8.7b), MgO (Figure 8.9b), CaO (Figure 8.10b), K20
(Figure 8.12b), Ti02 (Figure 8.13b), C02 (Figure
8.14b), Li (Figure 8.19b), Ni (Figure 8.20b), and Zn
(Figure 8.21 b) show anomalous abundances in the
form of addition or depletion around the Canagau
Mines Deposit and the Croxall Property. Elements that
are typically considered to be "immobile" under most
conditions, such as AI 203 (Figure 8.6b), Ti02 (Figure
8.13b), Ni (Figure 8.25b) have in fact undergone
considerable changes in abundance.
129
CHAPTERS

felsic Hi ^0.0
rocks l—1R4.0-70.

l 154.0-58.0
mafic mm --c/i n
rocks 111LU <54.0

Figure 8.5a. Distribution of Si02 outlining rock types.

SiO

Figure 8.5b. Si02 residual, showing small zones of addition/depletion due to alteration and misclassification
(plutonic rocks).

130
 EC. GRUNSKY

AI2O3 UNPROCESSED
Compositional Variation and Alteration Zones

kilometres

Figure 8.6a. AI2 O3 unprocessed, showing compositional variation and alteration zones.

AI2O3 RESIDUAL
Depletion Around Zones of Alteration

\\*

l t/J
Figure 8.6b. AI2 03 residual, showing depletion around zones of alteration,

131
CHAPTER 8

Fe2O3 UNPROCESSED
Compositional Variation and CO2 Alteration

Figure 8.7'a. Fe2 03 unprocessed, showing compositional variation and CO2 alteration.

/ Fe2O3 RESIDUAL

\\\\\
\\ \ \\\\
Zone of Alteration Depletion

Figure 8.7b. Fe2 03 residual, showing zone of alteration and depletion.

132
 EC. GRUNSKY

s
/
FeO UNPROCESSED
Compositional Variation

X
/
A
\

Figure 8.8a. FeO unprocessed, showing compositional variation.

FeO RESIDUAL
Flat X
x
\ \ \\ \' /-•l
\\

li^ * ^
\

-r -' c^

Figure 8.86. FeO residual, showing minor depletion around Canagau Mine, Croxall Property, and Verna Lake
Stock.

133
CHAPTER 8

MgO UNPROCESSED
Compositional Variation

\\

Figure 8.9a. MgO unprocessed, showing compositional variation.

S MgO RESIDUAL v
/ Slight Indication of Zones of Alteration
\ \\ \ \\
/ \ \\\ \ \
/ \ \\\ \
A

\;^.Y~
L/ ^^
s kilometres

Figure 8.9b. MgO residual, showing slight indication of alteration zones.

134
 EC. GRUNSKY

CaO UNPROCESSED Compositional Variation^

Depletion in Mineralized and Altered Areas

\\\ \\

Figure 8.10a. CaO unprocessed, showing compositional variation and depletion in mineralized and altered
areas.

RESIDUAL Alteration Zones

Enrichment Around Altered Zones

Figure 8.1 Ob. CaO residual, showing depletion around alteration zones and zone of enrichment around
altered zones.

135
CHAP TER 8

/ NaO UNPROCESSED Erratic

Depletion in Sulphur Enriched Areas \

Figure 8.11 a. Na2 0 unprocessed, showing erratic depletion in S enriched areas.

Na 2O RESIDUAL Alteration Zones

Depletion in Areas of Sulphur Enrichment /
\\\\ \\
\\.\\ \\

kilometres

Figure 8.11 b. Na2 0 residual, showing alteration zones and depletion in areas of S enrichment.

136
 E.G. GRUNSKY

K2O UNPROCESSED
Compositional
Variation

Figure 8.12a. K2 0 unprocessed, showing compositional variation.

. K2O RESIDUAL
' Alteration Zones

\\.\\ \\

Figure B. 12b. K2 0 residual, showing enrichment in alteration zones.

137
CHAPTERS

TiO2 UNPROCESSED
Compositional Variation
-\\ \ o\\ -"

Figure 8.13a. Ti02 unprocessed, showing compositional variation.

S TiO2 RESIDUAL
Alteration Zones

O____1 2
•••^ZI^^MMZZ
kilometres

Figure 8.13b. TiO2 residual, showing depletion in alteration zones.

138
 EC. GRUNSKY

CO 2 UNPROCESSED

\
> 6.0\ X
i——i 3.0-6.0/
1.0-3.0

Figure 8.14a. C02 unprocessed, showing hydrothermal alteration.

CO2 RESIDUAL l
Hydrothermal Alteration
Carbonatization

Figure 8.14b. C02 residual, showing hydrothermal alteration and carbonatization.

139
CHAPTER 8

/ S UNPROCESSED
/ Sulphide Mineralization

Figure 8.15a. Sulphur unprocessed, showing sulphide mineralization.

S RESIDUALS
Sulphide Mineralization
\ \\ \ \\
\ \\\ \\
\
\

Figure 8.15b. Sulphur residuals, showing sulphide mineralization.

140
 E.G. GRUNSKY

l ' H 2O* UNPROCESSED X X

li/ Compositional Variation
^^^ X
(^ ^ Altered Areas ^^
y
\ ' \ x"*^X. U
.f—^

Figure 8.16a. /-^CT unprocessed, showing compositional variation and some indication of alteration zones.

Figure 8.16b. HiO* residual, showing slight indication of alteration zones.

141
CHAPTER 8

"7
Au UNPROCESSED

kilometres

Figure 8.17a. Gold unprocessed, showing enrichment.

Figure 8.17b, Gold residual, showing enrichment.

142
 EC. GRUNSKY

Cu UNPROCESSED

Figure 8.18a. Copper unprocessed, showing local enrichment.

Figure 8.18b. Copper residuals, showing enrichment.

143
CHAPTER 8

7—Y
7 Li UNPROCESSED
/ CO2 Alteration Hydrothermal 7
\ \\\ X
7
\ \\\
\ \\\

figure 8.19a. Lithium unprocessed, showing hydrothermal alteration.

Li RESIDUAL
CO2 Alteration
Hydrothermal
\ \ \\ \\
\ \\\ \
\ \

Figure 8.19b. Lithium residual, showing CO2 alteration hydrothermal.

144
 EC. GRUNSKY

Figure 8.20a. Nickel unprocessed, showing compositional variation in volcanic rocks.

Ni RESIDUAL
CO 2 Alteration
Depletion
\ \\\ \\
\ \\\ \

Figure 8.20b. Nickel residual, showing alteration zones.

145
CHAPTER 8

Zn UNPROCESSED
Compositional Variation
Felsic Volcanics
Hydrothermal Systems

Figure 8.21 a. Zinc unprocessed, showing compositional variation of volcanic rocks and hydrothermal
alteration.

Zn RESIDUAL
S Enrichment
COo Alteration

Figure 8.21 b. Zinc residual, showing sulphur enrichment and CO2 alteration.

146

NORMALIZATION SCHEMES AND TECHNIQUES
FOR IDENTIFYING ALTERATION_________
Sopuck (1977), Sopuck et al. (1980), and Lavin
(1976) used Si02 as an independent variable against
which all other oxide/element abundances would be
measured. Regression curves were derived for each
oxide/element with respect to Si02. Residuals were
then computed based on the actual abundance of an
oxide/element in comparison to its expected value
determined from the Si02 content of the rock and the
regression formula. This classification scheme works
providing the original Si02 content of the volcanic
rocks has not changed. Studies by Gibson et al.
(1983), Franklin and Thorpe (1982), Deptuck et at.
(1982), Knuckey et al. (1982), Urabe and Salo (1978),
Knuckey and Watkins (1982), Riverin and Hodgson
(1980), and MacGeehan and Maclean (1980) all
show that Si02 as well as other oxides/elements are
mobile in altered volcanic domains. Thus, the use of
any individual oxide/element as an independent or
"immobile" variable by which the expected abun
dance of other components can be determined is
questionable.
In this study, the two classification schemes
which are used are based on components that are
known to be mobile. The classification scheme of
Jensen (1976) uses Al, Fe3, Fe2, Ti, Mn, and Mg; but
Mg and Fe are known to be mobile around sulphide
deposits (Riverin and Hodgson 1980; Knuckey et al.
1982). The classification scheme of Irvine and
Baragar (1971) uses Na20, K20, MgO, FeO, Si02 , and
AI 203. Na and K are particularly mobile in altered
areas and in regional metamorphic domains. This can
cause significant errors in the classification of the
volcanic rocks. All classification schemes will fail
when the independent variables used are susceptible
to alteration. The mobility of these components can
be readily recognized because their use will lead to
inconsistent results within the classification scheme.
If a rock is misclassified because the critical compo
nents to make a particular classification have been
altered, the expected values for other components
within that sample are likely to show abnormal abun
dances. As an example, if a basalt has been
silicified, a regression equation would indicate that
the Na or K are too low and Ti. Fe, and Mg are too
high. These would show up as large residual values
on contour maps. Similarly, the use of the cation
classification scheme of Jensen (1976), should show
that rocks enriched in Mg will indicate high residual
values in Si and Al.
Various classifications exist in which the calcula
tion of residual values is part of the classification
process. They can be used successfully if properly
interpreted. However, the problems stated above are
unavoidable, and interpretation of residual data must
take these problems into account.
Beswick and Soucie (1978) and Beswick (1981)
have shown that logarithmic molecular proportion ra
tio (LMPR) diagrams produce straight lines when the
the major oxide values of modern day volcanic rocks
are used as data. Thus, rocks that do not fit on the
lines can be interpreted as being altered. Beswick
and Soucie (1978) developed a correction procedure
through which original component abundances can
B.C. GRUNSKY
be determined. The method assumes AI 203 immobil
ity. Aluminium does not remain immobile in Archean
rocks (Gibson et al. 1983; Riverin and Hodgson
1980), although it does not vary as much as other
elements. Beswick (1981) has shown that discrimi
nant function analysis in conjunction with LMPR plots
can be used to calculate "scores" that assist in the
identification of mineralized zones based on the al
teration of several components.
The use of molecular proportions (Pearce 1969)
and mass balance transfers (Gresens 1967) allow the
precise calculation of a component where there has
been addition or depletion. Again, these methods
assume that at least one component is immobile.
Normative mineral calculations have been used in
conjunction with mass balance calculations (Gresens
1967) by Knuckey et al. (1982), and Riverin and
Hodgson (1980) to show which components have
been added or subtracted from the rocks, as well as
determining volume changes. Normative minerals cal
culated for unmetamorphosed "Kuroko type" volcanic
rocks have been used to determine the original com
positions of alteration pipes.
Studemeister (1983) has shown that the ratio of
Fe+VFe (total) is a good indicator of the oxidation
state which prevailed in zones where hydrothermal
alteration has occurred.
Gelinas et al. (1977) have used normative corun
dum as an indication of alteration. The presence of
corundum indicates that Na, K, Ca, Al, and Si are not
present in the correct proportions for formation of
normative feldspars. The mobility of components
(usually K and Na) are indirectly recognized using
this method. Figure 8.22 displays the abundance of
normative corundum in the Ben Nevis area, several
anomalous zones have been delineated by its high
abundances.
Excessive amounts of calcite in a normative min
eral calculation within volcanic rocks could indicate
that carbonatization had occurred. Figure 8.23 shows
the distribution of normative calcite throughout the
area. Numerous zones of Ca and CO2 enrichment are
outlined in the figure and indicate some degree of
carbonate alteration. However, Ca is notably absent
around the Canagau Mines area (see Figure 8.1 Ob),
hence normative calcite does not show up in the
vicinity of the mine. Figure 8.14a shows the wide
spread abundance of C02 throughout the Canagau
Mines area. The C02 that cannot form calcite be
cause of the low Ca level probably forms dolomite,
magnesite, or siderite. If normative mineral calcula
tions were modified to compute these minerals, then
the zone of CO2 alteration would be more extensive
than shown in Figure 8.14b.
The abundance of several other normative min
erals can be used to detect various alteration pat
terns. Minerals such as acmite indicate excess Na,
and the undersaturated minerals such as nepheline
and leucite indicate silica depletion and alkali enrich
ment.
Normative minerals that are "expected" in a nor
mative mineral calculation (for example quartz,
olivine, albite, and so on) must be used cautiously
because their abundance will vary with rock com-
147
CHAPTER B

NORMATIVE
CORUNDUM/

Figure 8.22. Distribution of normative corundum.

Figure 8.23. Distribution of normative calcite.

148

position; only carefully calculated residual values
would be helpful in delineating altered zones.
STATISTICAL TECHNIQUES
A drawback with methods using either single compo
nent or multicomponent residual values is that ex
pected values are required in order to calculate the
residual values. Again, the determination of residual
values is based on the assumption that the compo
nent abundances are normally distributed, and that
the classification schemes use immobile components
in order to determine residuals. For reasons stated
earlier, residual values can be misleading since
rocks must first be classified before residuals can be
calculated. If the rock is misclassified, then the resid
ual values will be incorrect.
Any method that uses models with the data (that
is, comparison of the data with expected values) is
subject to scrutiny since such models assume an
understanding of the distribution of the data. Tech
niques such as discriminant function analysis predict
the expected behaviour of data based on models.
Since the data being used with the discriminant func
tions may not reflect the same geological process
and/or environment as those for which the technique
was developed, the resultant residual values may not
be significant. For example, if the expected value for
a basalt is that typical of a tholeiitic basalt, but the
rock that is being tested is in fact calc-alkalic, resid
ual values will mostly reflect the difference between
a tholeiitic and a calc-alkalic basalt. Any residual
effect due to alteration will probably be masked by
this more significant difference.
For these reasons, it was decided that a statisti
cal approach employing a minimum of assumptions
regarding expected component values would best
distinguish altered from unaltered rocks; Correspon
dence Analysis is such a technique.
"Correspondence analysis can be viewed as
finding the best simultaneous representation of two
data sets that compose the rows and columns of a
data matrix" (Lebart ef al. 1984). This means that a
matrix consisting of rows of samples and columns of
chemical components represent the data matrix from
which the simultaneous relationship of variables with
samples and samples with variables can be extract
ed. The details of the method will not be discussed
here, but can be found in Lebart et al. (1984), Jambu
and Lebeaux (1983), David et al. (1977), Hill (1975),
and Teil (1975). Correspondence analysis was
originally developed for contingency tables, which
were based on probabilities, that consisted of posi
tive numbers and were used in a variety of applica
tions. Applications of this technique has been carried
out in the geological sciences with continuous mea
surement data by Teil (1975), David et al. (1977), and
Mellinger (1984).
An aim of correspondence analysis is to repre
sent the data in terms of a number of axes (factors)
that describe the distribution of the data. Each factor
can be thought of as describing geological processes
such as differentiation (partial melting, crystal frac
tionation, and so on) and alteration in so far as each
process produces variation patterns in the data under
study. Such processes include carbonatization,
EC. GRUNSKY
silicification, and alkali depletion. In a suite of unal
tered volcanic rocks, there is generally an inverse
relationship between (Na, K) and (Ca, Mg, Fe). If the
data distribution were governed only by those com
ponents, the compositional variation would be domi-
nantly along one axis illustrating a differentiation
trend (that is, Harker diagrams). However, if the rocks
within a given suite have been altered by some
process such as carbonatization then, not only is the
data distributed along a direction defining its
petrogenesis, but also along an axis that describes
the departure of the data by one or more of the
affected components (for example C02 ).
In correspondence analysis, the factors are char
acterized by eigenvectors which determine their ori
entation in the data space and by eigenvalues which
measure how much of the data variation occurs
along each factor.
Table 8.1 a shows the eigenvalues and percent
age contribution of each factor. Note that the first
factor accounts for 35.33 07o of the variation of the
data, and the first five factors combined explain
92.86 07o of the data variation. Table 8.1 b lists the
computed factor values for each component. Figure
8.24a shows projections of the samples and compo
nents onto the first five axes. Table 8.1 c gives the
contribution of each chemical component over the
five computed factors (relative contribution or prox
imities to the factorial axes/or squared correlations)
and the percentage that each component contributes
to each factor (absolute contribution/or contributions
to the factorial axes inertias). Note that in Table 8.1 c,
Si, Fe, Mg, Ca, K. and H 20 contribute heavily to the
first factor and are the components that define the
compositional variation due to magmatic differenti
ation (see Figure 8.24a). Over 94 070 of the second
factor is defined by the distribution of C02 and over
90 07o of the third factor is defined by the distribution
of S. This can be seen in Figures 8.24a and 8.24b.
The ability to plot the component-factor coordi
nates (R-mode) and the sample factor coordinates
(Q-mode) is a unique feature of correspondence ana
lysis. The distribution of the data along the first
factor (F1) reflects the compositional variation due to
the magmatic trend of volcanic differentiation. The
basalts have a greater Ca, Fe, and Mg abundance
relative to the rhyolites which are enriched in K;
samples plot closest to the components they contain
in greater abundance relative to the other samples in
the population. As the values along the second factor
increase, this reflects an increasing C02 content in
samples (Figure 24a and 24c). Figure 24c shows the
distribution of the altered samples in a projection
looking along the compositional line (Factor 1) of the
magmatic trend in the F2-F3 plane. The fourth factor
(F4) indicates that Ca, Na, and Mg account for most
of the variation of the data in that factor. The ele
ments K, Na, and Ca account for most of the vari
ation in the fifth factor (F5) (see Table 8.1 c).
Comparison of the relative contributions of the
components over the 5 factors in Table 8.1 c shows
that most of the components are accounted for by
F1, the first factor. Only Na, K, Ca, CO2, and S are
mostly accounted for by other factors. The second
factor (F2) accounts for over 99 07o of the C02 dis-
149
 CHAPTER 8

TABLE 8.1: CORRESPONDENCE ANALYSES, MAJOR OXIDES.

TABLE 8.1a.
R MODE: MEAN EIGENVALUES 07o OF VARIATION CUMULATIVE Ve
VARIABLES VALUES (NON TRIVIAL EIGENVALUES)
Si02 58.56 0.037 787 25 35.32 35.32
AI203 15.56 0.026 188 00 24.48 59.80
Fe203 1.74 0.019 76203 18.47 78.27
FeO 4.74 0.009 276 52 8.67 86.94
MgO 4.10 0.006 328 67 5.92 92.86
CaO 5.68 0.003012 14 2.82 95.67
Na20 3.31 0.001 45605 1.36 97.04
K?0 0.80 0.001 294 54 1.21 98.25
TiO2 0.83 0.001 012 32 0.95 99.19
P205 0.12 0.000385 18 0.36 99.55
MnO 0.10 0.000 266 72 0.25 99.80
C02 1.32 0.000 15547 0.15 99.95
S 0.13 0.000 057 44 0.05 100.00
H2CH 2.65
TABLE 8.1 b.
FACTORS (COORDINATES)
VARIABLE 1 2 3 4 5
Si02 -0. 1 20 4 -0.016 2 -0.012 3 0.012 3 -0.001 9
AI 203 0.058 4 -0.038 3 -0.013 8 -0.000 8 0.005 9
Fe203 0.244 4 -0.163 5 0.057 5 -0.0159 -0.004 3
FeO 0.338 4 0.004 0 0.111 9 -0.115 7 -0.066 5
MgO 0.420 0 -0.021 4 0.033 5 -0.1642 -0.116 9
CaO 0.382 5 0.035 5 -0.045 6 0.272 4 0.113 8
Na20 -0. 1 1 1 3 -0.070 0 -0.120 8 -0.284 7 0.222 5
K20 -0.560 1 0.178 2 0.191 9 0.201 0 -0.551 0
Ti02 0.292 5 -0.047 1 0.001 5 -0.070 0 -0.013 8
P205 0.2193 -0.026 6 0.041 7 -0.095 0 -0.016 7
MnO 0.267 7 0.084 5 0.032 3 -0.047 3 -0.051 7
C02 -0.015 7 1.363 5 0.051 4 -0.080 1 0.069 5
S -0.493 2 -0.304 7 3.774 8 0.059 1 0.554 3
H 2O* 0.309 9 0.020 3 0.045 7 -0.041 1 -0.098 8
TABLE 8. 1C.
ABSOLUTE AND RELATIVE CONTRIBUTIONS
WEIGHT AC(1) RC(1) AC(2) RC(2) AC(3) RC(3) AC(4) RC(4) AC(5) RC(5)
Si02 0.587 735 22.54 96.21 0.59 1.75 0.45 1.01 0.96 1.01 0.03 0.02
AI 2O3 0.156 120 1.41 66.80 0.88 28.77 0.15 3.73 0.00 0.01 0.09 0.69
Fe203 0.017 417 2.75 66.33 1.78 29.70 0.29 3.67 0.05 0.28 0.01 0.02
FeO 0.047 572 14.41 79.04 0.00 0.01 3.01 8.65 6.87 9.25 3.33 3.06
MgO 0.041 165 19.21 80.69 0.07 0.21 0.23 0.51 11.97 12.34 8.89 6.25
CaO 0.057 007 22.07 61.78 0.27 0.53 0.60 0.88 45.60 31.34 11.68 5.47
Na20 0.033 195 1.09 7.62 0.62 3.02 2.45 8.98 29.01 49.90 25.98 30.48
K20 0.008 065 6.70 43.19 0.98 4.37 1.50 5.07 3.51 5.56 38.70 41.80
Ti02 0.008 343 1.89 92.14 0.07 2.38 0.00 0.00 0.44 5.27 0.03 0.21
P205 0.001 178 0.15 80.35 0.00 1.18 0.01 2.90 0.11 15.10 0.01 0.47
MnO 0.001 038 0.20 84.56 0.03 8.42 0.01 1.23 0.02 2.63 0.04 3.15
C02 0.013 271 0.01 0.01 94.22 99.25 0.18 0.14 0.92 0.34 1.01 0.26
S 0.001 260 0.81 1.63 0.45 0.62 90.83 95.66 0.05 0.02 6.12 2.06
H 20-f 0.026 632 6.77 87.31 0.04 0.37 0.28 1.90 0.49 1.54 4.11 8.88

150
 EC. GRUNSKY

o, M
oo'
4
|CO2
-K IAJO R O XII )E s-
!
-
orr
'

*J —
O '
— 1—
'
O
0- <
*.lLJ-- *
, 1 \

0
' ' tt .
t* le
**
^*
*J * **
Ai K4 4
^. J t ^C a
o /* V ;Si^ •*?;l
** .
rV M 9
o
d f
*r^
^ 1jm.v VN^
!t!lti^t'
^t, V
h
DF:

-a- J5
o
O •A •Q
i F Zl R 1
-0.40 0.00 0.40 O.IJO 1.1?0

Figure 8.24a to 8.24e. Correspondence analyses,

factor scores of samples (+J and chemical
components.

151
CHAPTERS
tribution and the third factor (F3) accounts for over
95 07o of the S distribution. The fourth and fifth factors
show that Ca, Na, and K, which are generally consid
ered to be the most mobile elements in zones of
alteration, are the major contributions.
Figure 8.25 displays contour plots of the first 5
factors for the Ben Nevis area. As described pre
viously, the first factor accounts for the original com
positional variation, and this can be seen in Figure
8.25a. The plot closely resembles the lithologic map
of the area (Figure 8.2) for example, negative factor
values (Figure 8.24a) represent the Na, K-rich sam
ples, most notably the felsic volcanic rocks. Examina
tion of a contour plot of factor 2 (Figure 8.25b) shows
that the positive anomalies are coincident with high
C02 values (see Figure 8.24a). Figure 8.25c shows
that the positive anomalies of Factor 3 are the result
of the presence of sulphides (see Figure 8.24b);
good targets for exploration. Positive Factor 4 values
show a tendency towards Ca enrichment (see Figure
8.24d). In Figure 8.25d. positive Factor 4 anomalies
are found around the carbonatized zone in the
Canagau Mines deposit area. These anomalies repre
sent Ca enrichment around the main zone of car
bonatization. Negative Factor 4 anomalies (not
shown) indicate Na depletion around the Canagau
Mines Property and the Croxall Property. Factor 5
contours in Figure 8.25e show zones of K enrichment
associated with negative Factor 5 anomalies (seealso
Figure 24d). Extremely high values (X3.40) of Factor
/ MAJOR OXIDES FACTOR 1
/
Compositional Variation
\ \
Figure 8.25a. Contour expression of Factor 1 with potassium enriched rocks ^0.20 and mafic rocks X).25.
152
5 indicate S enrichment while more moderate values
(0.1 to 0.3) indicate Na enrichment.
Correspondence analysis was also applied to the
combined major oxides and trace elements. A scaling
problem exists between the two groups of compo
nents because the major oxides are expressed in
weight percent and the trace elements are expressed
in parts per million. In order to maintain the propor
tions of relative abundance within the sample popula
tion, the weight percent major oxides were trans
formed into parts per million.
The results of the combined correspondence
analyses are shown in Table 8.2 and in Figure 8.26
and 8.27. The results are nearly identical to those of
the major oxides. Part of the reason for this is that
the trace elements have small weights relative to the
major oxides; however, the trace elements provide
additional information and verify what was observed
in the isochemical plots. Table 8.2c shows the actual
and relative contributions of the components. It is
clearly seen from an examination of Table 8.2c and
Figure 8.26a that the Si02, Al,03 . Fe203, FeO, MgO,
CaO, Ti02, P 205, MnO, H 2CT. Co, Cr, Ni, V, and Zr
distributions are accounted for in the first factor and
represent the compatibilities of trace elements that
co-exist with the primary magmatic mineralogical
phases. This is to be expected because these com
ponents are part of the igneous process of com
positional variation in volcanic rocks.
\
\\
 EC. GRUNSKY

X MAJOR OXIDES FACTOR 2

CO2 Enrichment
\ \\ \ \\
\ \\\ \\
\~\ \\ \
i\\\.
o-/
x^"\ /r" 7 X

Figure 8.25b. Contour expression of Factor 2 values X). 15 representing carbonatized zones.

MAJOR OXIDES FACTOR 3

, S Enrichment

\ \\\ \\

kilometres

Figure 8.25C. Contour expression of Factor 3 values X). 15 representing areas enriched in sulphur.

153
CHAPTERS

MAJOR OXIDES FACTOR 4

Ga Enrichment

\ \\\ \\
\ \\\ \\
\ \\\ \

\\ ii L/
l ' —N

kilometres

figure 8.25d. Contour expression of Factor 4 values X).07 representing rocks anomalously rich in calcium.

S MAJOR OXIDES FACTOR 5

K Enrichment

/' \ \\ \ \\
\ \\\ \\ .

kilometres

Figure 8.25e. Contour expression of Factor 5 values ^. 1 representing rocks enriched in potassium.

154

Figures 8.26a, 8.26b, 8.26c, and 8.26d show the
samples and components of Factor 1 plotted against
the other four. Figure 8.26a clearly shows the com
positional variation of the sample population along
Factor 1. The addition of the trace elements enhance
the compositional line by extension due to the pres
ence of Gr, Mi, and Co at the mafic end of the factor
(X3.10), while Ba and Zn occur toward the felsic end
of the factor K-0.10).
Figure 8.27a shows the distribution of the more
felsic volcanic rocks in the map area. The actual
contributions of components to the second factor is
weighted heavily by C02 variation as indicated in
Table 8.2c. The C02 abundance is great. It accounts
for 94.18 07o of the component. From the relative con
tribution of Factor 2, it can be seen that 55.33 07o of
the Li variation is accounted for by the second factor.
The association of C02 and Li is well displayed by
this factor and is verified by comparison of Figures
8.14b and 8.24b with Figure 8.27b. The pattern in
Figure 8.26a is almost identical to that of Figure
8.24a in that the departure of the samples from the
main compositional trend line is the same, with en
richment in COo and Li. The second factor obviously
outlines the trend line zone of hydrothermal alter
ation. Also, the first factor shows that nearly 16 07o of
the Li variation is accounted for by the main mag
matic trend. This indicates in an indirect way, the
relative amount of trace element compatibility that
can be explained over the data space.
Factor 3 accounts for the distribution of S and Cu
almost exclusively (Table 8.2c). A minor component
of Zn associated with S also shows up in the relative
contributions column. It is not surprising to see the
obvious relationship of Cu and S. Figure 8.26b dis
plays the relationship of Cu and S-enriched samples
with the main compositional trend line. Figure 8.27c
shows the S-Cu rich areas and as such is a good
target for the investigation of sulphide occurrences.
Factor 4 accounts for Sl.43% and 49.89 07o of the
CaO and Na2 variations respectively in Table 8.2c;
MgO, Ti02 and Li are also accounted for in lesser
amounts (Table 8.2c). Examination of Figure 8.26d
shows that positive Factor 4 values are associated
with relative CaO enrichment and negative values are
associated with relative Na20 enrichment. This re
flects the inverse relationship of CaO and Na20
abundances between mafic and felsic volcanic
rocks. Thus, it might be expected that positive Factor
4 values outline mafic volcanic rocks and negative
Factor 4 values outline felsic volcanic rocks. How
ever, this pattern does not emerge from an examina
tion of Figure 8.27d. This is due to the fact that only
8.637o of the data distribution (Table 8.2a) is defined
by Factor 4. The positive anomalies of Figure 8.27c
appear to outline zones of CaO enrichment similar to
that outlined in the correspondence analysis of the
major oxides. Thus, a zone of CaO enrichment ar
ound the main zone of carbonatization is delineated.
Since the bulk of the sample analyses plotted in
Figure 8.26c have Factor 4 values X).0, only the
extreme negative values outline the zones of Na20
enrichment.
E.G. GRUNSKY
Factor 5 accounts for only S.91% of the data
distribution (Table 8.2a) and is significantly contri
buted by Na20, K2, Ba, and Zn. The association of
Na20, K20, and Zn with alteration is well established
through the isochemical plots of Figures 8.11, 8.12,
and 8.21. Positive Factor 5 anomalies indicate K20,
Zn, and Ba enrichment (Figure 8.26e) and both the
Croxall Property and Canagau Mines Limited Property
anomalies are defined in Figure 8.27e.
Within the distribution of the data over the fac
tors (axes), it can be seen that several "clouds" or
groups of sample points occur (Figures 8.24 and
8.26). Some of these groups have an obvious geo
logical interpretation such as those relating to car
bonatization or fractionation. It is difficult, however, to
"see" some groups of points that may occur along
the factor axes which are easily obscured when
several groups of data are projected onto a two-
dimension plot for visual presentation. A technique
for detecting groups of points in n-dimensioned
space is that of Dynamic Cluster Analysis. This meth
od was developed by Diday (1973), and is also
discussed in Lefebvre and David (1977). The dy
namic cluster analysis method works by selecting
groups of samples closest to randomly chosen
nuclei! over the factored space derived from the
correspondence analysis. By iteration, the nucleii lo
cations are refined until the locations no longer
change and the nucleii represent centres of sample
groups.
The results of the dynamic cluster analysis on
the major oxide data from Ben Nevis rocks are shown
in Figure 8.28a and Table 8.3. Figure 8.28a outlines
the spatial positioning of the groups; Table 8.3a
shows the factor space coordinate of the groups as
well as the mean composition and standard deviation
of each component for each group. The mean com
positions and standard deviations allow the analyst to
determine which components define to the unique
ness of each group. Dynamic cluster analysis iden
tified 28 groupings based on the factor coordinates
of the groups. Each of these groups reflects some
geological process. Groups 1 and 2 represent the
mafic volcanic rocks (Table 8.3b). Groups 7, 8, 9, 12,
14, 13, 17, and 27 contain anomalous C02. These
groups, when spatially plotted (Figure 8.28b and e),
show the progressive increase of C02 within the main
zone of carbonatization in the eastern part of Ben
Nevis Township. Groups 11, 20, 21, 22, 23, 26, and
28 indicate increasing S within the sample popula
tion. The reader should realize that not all groups
could be on the figures because of space problems.
It is noteworthy that Group 11 (Figure 8.28 a, c, e)
represents 17 samples. Of these 17 samples, 14 are
from the Croxall Property area in western Ben Nevis
Township and represent significant S enrichment.
The 18 samples in Group 10 are significant be
cause of their high Ga values. These samples are
from around the main zone of carbonatization and
may reflect a chemical zoning effect of Ga enrich
ment away from the main zone of hydrothermal cir
culation (Figure 28d). Groups 7, 8, 14, and 17, which
are associated with C02 enrichment, are also slightly
depleted in Ga relative to other groups.
155
CHAPTER 8

CO,
CN
MAJOR OXIDES
o ^_
r tt TRACE ELEMENT!
O *
•'
O
<
LL
0
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t
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FACTOR MAJOR OXIDE! o
MAJOR OXID ES'S
O -x 1 rRACE ELEME NI
T'RACE ELEMENT s
c )u
, 4
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20

Figure 8.26a to 8.26e. Correspondence analyses,

factor scores of samples (+J and chemical FACTOR
5 MAJOR OXIDES l—
o
components. TRACE ELEMENTS-

K LSI

a ^2f!r*
** .
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156
 EC. GRUNSKY

MAJOR OXIDES FACTOR 1

TRACE ELEMENTS COMPOSITIONAL VARIATION

factor score '

1^ -0.20
kilometers

Figure 8.27a. Negative anomalies outline sodium, potassium, barium-enriched felsic volcanic rocks.

MAJOR OXIDES FACTOR 2 OXLi.Zn \^

TRACE ELEMENTS HYDROTHERMAL ALTERATION
\ \ \ '

\ \ \\\
\ \\
\\
\ \

Figure 8.27b. Positive anomalies outline C02, Li, Zn enriched areas.

157
CHAPTERS

MAJOR OXIDES FACTOR 3

ELEMENTS S.Cu ENRICHMENT

factor score
^ > 0.05
kilometers

Figure 8.27c. Positive anomalies indicate Cu, S rich zones (sulphide mineralization).

MAJOR OXIDES FACTOR 4

TRACE ELEMENTS Ga ENRICHMENT

Figure 8.27d. Positive anomalies indicate Ca enriched zones. Note the band of Ca enrichment around the
carbonated area. Compare with Figure 8.27b.

158
 EC. GRUNSKY

MAJOR OXIDES FACTOR 5

TRACE ELEMENTS Zn,K,Ba ENRICHMENT

/f \ \\ v "
//
A
\

Figure 8.2?'e. Positive anomalies indicate Zn, K, Ba enriched zones.

TABLE 8.2: CORRESPONDENCE ANALYSIS, MAJOR OXIDES AND TRACE ELEMENTS.

TABLE 8.2a. OXIDES AND TRACE ELEMENTS.
R MODE: MEAN EIGENVALUES 07o OF VARIATION CUMULATIVE 070
VARIABLES VALUES (NON TRIVIAL EIGENVALUES)
SiOo 585 593.55 0.03 786 090 35.21 35.21
AI 263 155551.22 0.02617004 24.34 59.55
Fe,03 17 354.01 0.01 978 271 18.40 77.95
FeO 47 398.54 0.00 927 626 8.63 86.58
Mgo 41 015.45 0.00 635 597 5.91 92.49
CaO 56799.15 0.00 304 222 2.83 95.32
Na 20 33 074.45 0.00 146906 1.37 96.68
K20 8 035.89 0.00 130 136 1.21 97.89
Ti02 8312.53 0.00 101 779 0.95 98.84
P205 1 173.97 0.00 038 944 0.36 99.20
MnO 1 034.31 0.00 026 862 0.25 99.45
C02 13222.87 0.00016093 0.15 99.60
S 1 255.11 0.00013438 0.12 99.73
H 2CH 26 535.04 0.00 009 840 0.09 99.82
Ba 208.11 0.00005 193 0.05 99.87
Co 22.61 0.00 003 896 0.04 99.90
Cr 85.37 0.00 003 444 0.03 99.94
Cu 56.18 0.00 002 528 0.02 99.96
Li 17.01 0.00 002 042 0.02 99.98
Mi 78.88 0.00 001 446 0.01 99.99
Zn 88.78 0.00 000 386 0.00 99.99
Sr 135.11 0.00 000 241 0.00 100.00
V 131.40 0.00 000 220 0.00 100.00
Y 24.13 0.00 000 093 0.00 100.00
Zr 132.48

159
CHAPTERS

TABLE 8.2b.
FACTORS (COORDINATES)
VARIABLE 1 234 5
SiOo -0.1205 -0.0163 -0.0124 0.0122 0.001 7
AL203 0.058 3 -0.038 2 -0.0139 -0.000 6 -0.005 8
Fe203 0.244 4 -0.1633 0.057 4 0.0162 0.004 5
FeO 0.338 3 0.004 4 0.111 6 -0.1154 0.066 5
MgO 0.420 1 -0.020 9 0.033 2 -0.1642 0.1168
CaO 0.382 1 0.035 9 -0.045 8 0.272 8 -0.1136
NA20 -0.111 1 -0.070 2 -0. 1 20 8 -0.284 5 -0.222 3
K20 -0.560 9 0.1778 0.192 4 0.201 0 0.551 9
Ti02 0.292 5 -0.046 7 0.001 4 -0.069 6 0.0139
P205 0.219 2 -0.026 3 0.041 5 -0.094 8 0.0170
MnO 0.267 6 0.084 8 0.032 1 -0.047 1 0.051 8
C02 -0.017 2 1.3634 0.051 8 -0.079 9 -0.070 4
S -0.491 2 -0.306 7 3.774 2 0.058 8 -0.554 4
H2o* 0.309 7 0.020 7 0.045 5 -0.040 9 0.098 5
Ba -0.304 3 0.047 6 -0.012 3 0.063 7 0.334 7
Co 0.432 0 -0.068 9 0.1199 -0.091 3 0.008 1
Cr 0.597 7 -0.036 4 0.051 0 -0.220 9 0.161 7
Cu 0.030 6 -0.092 7 0.881 4 0.051 5 -0.071 1
Li 0.196 1 0.364 9 0.1070 -0.202 5 0.1289
Ni 0.525 3 -0.027 1 0.018 5 -0.1663 0.084 4
Zn 0.058 7 0.149 2 0.1242 -0.022 5 0.272 6
Sr 0.203 1 -0.151 2 -0.011 7 0.062 0 -0.083 3
V 0.423 2 -0.066 1 0.004 7 -0.008 9 -0.024 3
Y -0.095 3 -0.051 6 -0.020 6 0.002 4 -0.020 4
Zr -0.1400 -0.026 3 0.023 3 -0.006 8 0.030 9

TABLE 8.2C.
ABSOLUTE AND RELATIVE CONTRIBUTIONS
WEIGHT AC(1) RC(1) AC(2) RC(2) AC(3) RC(3) AC(4) RC(4) AC(5) RC(5)
Si02 0.587 158 22.51 96.22 0.60 1.77 0.45 1.01 0.94 0.99 0.03 0.02
AI203 0.155967 1.40 66.77 0.87 28.77 0.15 3.78 0.00 0.01 0.08 0.67
Fe2O3 0.017400 2.75 66.40 1.77 29.63 0.29 3.66 0.05 0.29 0.01 0.02
FeO 0.047 525 14.37 79.11 0.00 0.01 2.99 8.61 6.83 9.21 3.31 3.06
MgO 0.041 125 19.17 80.73 0.07 0.20 0.23 0.50 11.95 12.33 8.82 6.24
CaO 0.056 951 21.97 61.69 0.28 0.54 0.60 0.89 45.68 31.43 11.55 5.45
Na20 0.033 163 1.08 7.61 0.62 3.04 2.45 8.99 28.94 49.89 25.79 30.47
K20 0.008 057 6.69 43.20 0.97 4.34 1.51 5.08 3.51 5.55 38.61 41.83
Ti02 0.008 335 1.88 92.22 0.07 2.35 0.00 0.00 0.43 5.21 0.03 0.21
PA 0.001 177 0.15 80.43 0.00 1.16 0.01 2.89 0.11 15.04 0.01 0.48
MnO 0.001 037 0.20 84.50 0.03 8.49 0.01 1.22 0.02 2.62 0.04 3.17
C02 0.013258 0.01 0.02 94.18 99.24 0.18 0.14 0.91 0.34 1.03 0.26
S 0.001 258 0.80 1.62 0.45 0.63 90.62 95.66 0.05 0.02 6.09 2.06
H20* 0.026 606 6.74 87.36 0.04 0.39 0.28 1.89 0.48 1.52 4.06 8.84
Ba 0.000 209 0.05 43.85 0.00 1.08 0.00 0.07 0.01 1.92 0.37 53.08
Co 0.000 023 0.01 87.15 0.00 2.22 0.00 6.71 0.00 3.89 0.00 0.03
Cr 0.000 086 0.08 81.92 0.00 0.30 0.00 0.60 0.05 11.19 0.04 5.99
Cu 0.000 056 0.00 0.12 0.00 1.08 0.22 97.83 0.00 0.33 0.00 0.64
Li 0.000017 0.00 15.98 0.01 55.33 0.00 4.76 0.01 17.03 0.00 6.90
Ni 0.000 079 0.06 88.50 0.00 0.23 0.00 0.11 0.02 8.87 0.01 2.29
Zn 0.000 089 0.00 2.97 0.01 19.20 0.01 3.30 0.00 0.44 0.10 64.09
Sr 0.000 135 0.01 54.98 0.01 30.47 0.00 0.18 0.01 5.12 0.01 9.25
V 0.000 132 0.06 97.25 0.00 2.37 0.00 0.01 0.00 0.04 0.00 0.32
Y 0.000 024 0.00 72.12 0.00 21.14 0.00 3.38 0.00 0.05 0.00 3.32
Zr 0.000 133 0.01 89.77 0.00 3.16 0.00 2.48 0.00 0.21 0.00 4.38

160

Trace elements were also used in conjunction
with major oxides for the dynamic cluster analysis.
Figure 8.29a shows the spatial position of some of
the groups delineated by the dynamic cluster analy
sis along the factor axes. Figure 8.29b shows the
distribution of the groups over the Ben Nevis area,
and Table 8.4 lists the factor coordinate positions
and mean abundances for each component of each
group. Groups 2, 3, and 4 contain most of the mafic
volcanic rocks; Groups 5, 6, 10, and 12 include inter
mediate to felsic volcanic rocks (Table 8.4). Groups 7
and 8 are enriched in Zn, Li, C02. S and K (Figure
8.29b and d) and represent samples around the al
tered areas of the Croxall Property and the Canagau
Mines Deposit (Figure 8.29a). Group 11 contains S
and Cu enriched samples that occur at the Canagau
Mines Deposit and Croxall Property as well as some
isolated sulphide enriched samples (Figure 8.29c).
Group 6 represents Cr, Ni, enriched samples asso
ciated with mafic intrusive and tholeiitic volcanic
rocks of the area. Group 10 represents rocks of the
Ga enriched zone, similar to Group 10 in the previous
analysis using major oxides. The progressive C02
enrichment that was clearly shown by Groups 7, 8,
and 14 in the major oxides analysis also show up
when the major oxides and trace elements are com
bined. Thus, trace elements reflect and/or enhance
the analysis of the major oxides.
CONCLUSIONS
When using any technique for locating mineralized
areas, it is essential to select the proper components
in order to locate anomalous zones. Chemical com
pounds such as Si02 , Al,03, MgO, Ti02, Ni, Co, Cr, V,
and Zn are all very useful indicators for discriminat
ing rock types due to their variation associated with
fractionation in calc-alkalic suites. In hydrothermal
systems, certain components are known to be mobile
and these components are desirable indicators when
searching for altered rocks. In the Ben Nevis area,
certain major oxides and trace elements were noted
for such characteristics. For hydrothermal systems,
Na, K, Ca, C02, F, Zn, B, As, and Li are useful
indicators of alteration.
Dynamic Cluster Analysis
EC. GRUNSKY
Several oxides and some trace elements are use
ful indicators of mineralization; Factors 2 and 3 from
the correspondence analysis summarize the effects
of the major element and trace element alteration
around the Ben Nevis area. Dynamic cluster analysis
can assist in identifying groups of data related to S
enrichment (Croxall Property) or carbonatization
(Canagau Mines Deposit) which were not readily ap
parent after correspondence analysis alone.
It is important to have a full understanding of the
geological complexities of an area to best interpret
lithogeochemical information. A mixture of chemical
environments (that is, calc-alkalic and tholeiitic
rocks) would make interpretation of the Ben Nevis
data more difficult; certain critical components may
not be as useful in discriminating zones of alteration
under those circumstances.
ACKNOWLEDGMENTS
The author wishes to thank Dr. F.P. Agterberg of the
Geological Survey of Canada, Dr. M. Mellinger of the
Saskatchewan Research Council, and Henry Wallace
of the Ontario Geological Survey for critical reviews
of this work. The comments and suggested improve
ments are greatly appreciated. The author also wish
es to thank Dr. R. Froidevaux of Currie, Cooper, and
Lybrand Limited for his original suggestion of the
application of correspondence analysis. Thanks are
also due to Walter Volk (Geological Assistant, Ontario
Geological Survey), to Barbara Moore (Draftsperson,
Ontario Geological Survey) for the drafting of the
figures, to Doug Webster (Geological Assistant, On
tario Geological Survey) who assisted in the field
work and petrographic studies early on in the study,
and finally to Dave Good (Geologist, Ontario Geologi
cal Survey) who as a geological assistant helped in
the field work and sample collection program.
Figure 8.28a. Geographic
presentation of some of
the groups computed
from the Dynamic
Cluster Analysis in the
Ben Nevis area.
161
CHAPTER 8

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Figure 8. 28 b. Locations of Groups 7, 8, and 14 in Figure 8.28d. Location of Group 10 in the factor
the factor space. space.

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Figure 8.28c. Location of Group 11 in the factor Figure 8.28e. More locations of Groups 7, 8, 11,
space. and 14 in the factor space.

162
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CHAPTER 8

MAJOR OXIDES Dynamic Cluster Analysis Figure 8.29a. Geographic

TRACE ELEMENTS presentation of Group

\\ \\\ \\ >
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and Groups 7, 8, and 14
(C02, Li, and Zn
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V-V 7 \S\\ Group 7 k 8

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GROUPS 7,8,14 - CO2,Li,Zn ENRICHMENT
GROUP 11 - S.Cu ENRICHMENT kilometers

MAJOR OXIDES

Figure 8.29b. Locations of Groups 7, 8, and 14 in Figure 8.29c. Location of Group 11 in the factor
the factor space. space.

MAJOR OXIDES

Figure 8.29(1. Locations of Groups 7,8, 11, and 14

in the factor space.

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CHAPTERS
REFERENCES
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Beswick, A.E., and Soucie, G.
1978: A Correction Procedure for Metasomatism in an
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Franklin, J.M., and Thorpe, R.I.
1982: Comparative Metallogeny of the Superior, Slave
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Gelinas, L, Brooks, C., Perrault, G., Carignan, J.,
Trudel, P., and Grasso, F.
1977: Chemo-Stratigraphic Divisions Within the Abitibi
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Gibson, H.L, Watkinson, D.H., and Comba, C.D.A.
1983: Silicification: Hydrothermal Alteration in an Ar
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Rhyolite Formation, Noranda, Quebec; Economic
Geology, Volume 78, p.954-971.
Gresens, R. L.
1967: Composition-Volume Relationships of
Metasomatism; Chemical Geology, Volume 2,
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Grunsky, E.C.
In Press: Statistical Techniques for the Recognition of
Alteration in Volcanic Rocks in the Abitibi Belt,
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Irvine, T.N., and Baragar, W.R.A.
1971: A Guide to the Chemical Classification of the
Common Volcanic Rocks; Canadian Journal of
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Jambu, M., and Lebeaux, M.O.
1983: Cluster Analysis and Data Analysis; North-Hol
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Jensen, LS.
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District of Cochrane; Ontario Division of Mines,
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Map 2283, scale 1 inch to 1/2 mile.
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Joreskog, K.G., Klovan, J.E., and Reyment, R.A.
1976: Geological Factor Analysis: Elsevier Scientific
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1984: Multivariate Descriptive Statistical Analysis,
Correspondence and Related Techniques for
Large Matrices; John Wiley and Sons, 231 p.
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Deposit Noranda District, Quebec; p.297-318 in
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791 p.
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ciation of Canada, Special Paper Number 25,
791 p.
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Canadian Shield; Unpublished M.Sc.Thesis,
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173
Index
Aa flows ............................................................................ 9
Abitibi Belt................................................................. 43,45
Western Part, types of mineralization.................... 70
Abitibi Subprovince ............... 69,74,81,83,107,109-111
Mineralization ............................................................ 84
Adams Mine ............................................................ 77,116
Adams River Bay........................................................... 53
Age dating:
Carbonate beds ........................................................ 91
Cycle l ........................................................................ 96
Deloro Group ........................................................ 71,82
Felsic pyroclastic rocks ...................................... 93,94
Felsic volcanics ........................................................ 91
Helen iron range ....................................................... 66
Hunter Mine Group ................................................... 72
Kidd Creek Rhyolites........................................... 72,82
Pacaud Tuffs ............................................................. 72
Radiometric dating............................................... 45,55
Red Lake Belt ....................................................... 91,96
Southern sequence, Red Lake Belt........................ 96
Stromatolitic carbonate unit.................................... 93
Upper Formation ....................................................... 82
Upper Supergroup..................................................... 71
Uranium-lead zircon ................................................. 58
Volcanic activity........................................................ 99
Wabewawa-Catherine-Skead
Supergroup ................................................................ 71
Albite-epidote hornfels facies .................................. 127
Alexo Deposit ................................................................ 81
Algal mats, laminated................................................... 45
Allard Anticline .............................................................. 43
Alloclastic rocks ............................................................ 11
Alloclastic volcanic breccia ........................................ 13
Alteration:
Effects ...................................................................... 147
Haloes ...................................................................... 125
Immobile component.............................................. 147
Patterns .................................................................... 147
Pipe........................................................................... 125
Amulet rhyolite .............................................................. 36
Amygdules ........................................................ 9,126-128
Analyses:
Archean volcanic facies.......................................... 32
Cluster..................................................... 125, 155, 161
Major element............................................................ 54
Markov Chain ............................................................ 44
Andalusite ...................................................................... 94
Ankerite ........................................................................ 127
Anomalous zones, criteria for location.................... 161
Anticlinorium.................................................................. 90
Red Lake ............................................................... 95,96
Antigorite ........................................................................ 83
Archean composite cone............................................. 53
Archean cyclical volcanism ...................................... 108
Archean island volcanic system, model...................... 8
Archean stromatolites .................................................. 44
Table........................................................................... 45
Armit Lake ...................................................................... 58
Asbestos ............................................................. 74,83-85
Location...................................................................... 75
Ash................................................................................. 14
Ash cloud surge......................,.................................... 19
Ash-flows ................................................................ 19,113
Plinian.....,.............................................................. 119
Assays:
Gold ...............................................................,......... 126
Silver........................................................................... 66
Autoclastic rocks .....................................,................... 11
Autoclastic volcanic breccia..................................,... 13
Baird Township .........................,............................ 94,95
Balmertown ............................................................... 94-96
Balmertown-Cochenour area ................................. 94,95
Bamaji-Fry Lakes area .......,........................................ 99
Barite...................................................................... 114,115
Barium............................................................................ 14
Barium-gold mineralization,,,,,,,,,,,,,.,,,,,,. 115
Basaltic flood eruption ,,.,.,,,,,,,.,.,,,,.,,,.,,,,, 6
Basalts ,,,,,,,,.,,,,,,,,,,.,,,,,.,,.,,.,,,,,,,., 94
Base surge ,,,.,,,,,,,,,,.,,,,.,..,,,.,,.,,,,,,,, 19
Base-metal ,,,,,.,,,,,.,,,,,.,,.,,,.,,.,,,,,,,.,, 74
Deposits ,,.,,,,,,.,,,,.,,,,.,,.,.,,,.,.,,,,, 74,91
Deposits, potential ,,,,,,,.,,,.,.,,.,,,,,,,,,,, 85
Deposits, Sturgeon Lake,,,,,,,,,,,,,,,,,,,,, 46
Mineralization ,,,.,,,,,,,,,,,,,,,,,,,,,,,, 74,8
Mineralization, potential ,,,.,,,.,,,,,,,.,,,,.,.
Bedding thickness terms ,,,,,,,,,.,.,,,,,.,,,,,
Bell Allard orebody ,,,.,,,,,,,.,,,,,,,,,,,,,,,., 43
Berry Lake ,,,,,.,.,.,,,,,,,,,,,,,,,.,,,,,,,., 35,54
Berry Lake Stock.,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 53
Berry River ,.,,.,,,,,,,.,,,,,,,.,,,,,,.,,,,,,,,, 54
Berry River formation ,,,,,,,,,,,, 34,35,53,54,58,60
Radiometric age ,.,,,,,,,,,,,,,,.,,,,.,.,.,.,,, 54
Bimodal succession ,,,,,,,,,,,,.,,,,,.,,,.,,,,, 94
Bimodal volcanic cycles ,,,.,,,,,,,,,,,.,,.,,.,, 109
Birch Lake ,,,,,,,.,,,,.,,,,,.,,,,,,,,,,,,,, 99,100
Birch-Uchi-Confederation Lakes area ,,,.,,,,,,,, 99
Black Lake volcanics ,,,,,,,,,,,,,,,,.,,.,,,, 53,54
Blake River Group ,,,,,,,,,,,,,,.,,, 71,72,75,77,78,
84,85,108,109,126,127
Blake River synclinorium ,,,,,,,,,,,,.,,.,,.,,,, 127
Bobjo Prospect ,,,,,,,,,,,,,,,,.,,,,,,,,,.,,,, 114
Boston Township ,,,,,.,,,,,,,,,.,,,,,.,.,,,,,,., 77
Bouma Sequences ,,,,,,,,,,,,,,,,,,,,,,,,,,,, 35
Breccia:
Characteristics ,,,.,,,.,,,,,,,,,,,,.,,,,,,,,., 20
Mafic ,,.,,,,,,,,,.,,,,,,,.,,,.,,.,,,,,.,.,,,,, 65
Phreatic ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 24
Pyroclastic ,,,,,,,,.,,,,,,,,,.,,,.,,,,,,, 5,32,33
Tuff,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 33
Units,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 128
Volcanic ,,,,,,,,,,,.,,.,,.,,,,,,,,,,,,,,,,,, 13
Bryce Township ,.,,,,,.,,,,,,,,,.,,,,,,,,,,., 32,35
Bug Lake ,,,,,.,.,,,,,,,,,,,,,.,.,,,,,,,,,,,,,, 53
Cadmium ,,,,,,,,,,.,,,,,,.,,,,.,,..,,.,,,.,,,.,, 75
Calc-alkalic flows ,,,,,,,,,.,,,,,,,,,,,,,,,,,,, 54
Calc-alkalic unit ,,,,.,,,,,,,,,,,,,.,,,.,,,,,.,, 107
Calc-alkalic volcanic rocks, origin ,.,.,,,,,,.,,,,, 77
175
 VOLCANOLOGY AND MINERAL DEPOSITS
Caldera:
Collapse ................................................................... 119
Cycle.......................................................... 105,113,117
Cycle model...................................................... 118,119
Forming eruptions ................................................... 117
Structure ..................................................................... 97
Valles ........................................................................ 117
Cameron Lake ............................................................... 58
Canadian Shield.......................................................... 108
Canagau Mines ............................................ 128,129,147
Canagau Mines Deposit...................... 125,127,152,161
Canagau Mines Property .......................................... 152
CaO enrichment.......................................................... 155
Carbonate .................................................................... 127
Beds, age dating ....................................................... 91
Complex ..................................................................... 63
Facies iron formation ............................................... 65
Units............................................................................ 91
Carbonatization ........................................................... 127
Effects ............................................................... 147,149
Carbonatized komatiitic flows .................................... 81
Catherine Group............................................................ 78
Cauldron:
Megacauldron............................ 70,72,74,77,80,82,84
Central facies ........................................................... 23,26
Central Synclinorium .................................................... 72
Central vent composite volcano:
Facies variation......................................................... 26
Products ..................................................................... 28
Central vent facies rocks ............................................ 78
Central Volcanic Belt.................................................... 54
Chabanel Township...................................................... 63
Chalcopyrite ..................................................... 68,82,126
Chemically zoned magma chambers ...................... 105
Chert ............................................................................. 115
Chlorite ......................................................................... 126
Origin ........................................................................ 127
Chromite ......................................................................... 82
Chromium ....................................................................... 94
Classification:
Extrusive volcanic rocks............................................. 8
Fragment shape ........................................................ 18
Fragment type ...................................................... 17,18
Grain size .............................................................. 12,17
Granulometric, pyroclastic rocks............................ 13
Schemes, problems ................................................ 149
Schemes, volcanic rocks ...................................... 147
Volcanic eruptions ....................................................... 6
Volcanic fragmental rocks ................................. 11,13
Clifford Stock............................................................... 127
Cluster analysis ........................................... 125,155,161
Component-factor coordinates ................................. 149
Factor 1 .................................................................... 155
Factor 2 .................................................................... 155
Factor 3 .................................................................... 155
Factor 4 .................................................................... 155
Factor 5 .................................................................... 155
Composite dikes ......................................................... 119
Concentration of metals .............................................. 77
Conceptual models..................................................... 116
176
Confederation Lake........................... 90,91,94,108,109.
111-116,118,119
Contacts:
Deloro-Porcupine Groups ........................................ 72
Endogeneous quartz-feldspar porphyry
dome - associated dome-collapse talus
deposit...................................................................... 116
Felsic volcanics-sedimentary rocks ...................... 72
Komatiitic flows-sediments ..................................... 74
Timiskaming-Kinojevis-Blake River
Groups ........................................................................ 72
Contour diagrams ....................................................... 129
Contour plots ............................................................... 152
Convective cells ......................................................... 118
Copper............................................................. 66,118,119
Copper-lead-zinc deposits .......................................... 84
Copper-zinc deposit ..................................................... 90
South Bay-type .......................................................... 97
Copper-zinc-gold deposit .......................................... 116
Copper-zinc-lead sulphide deposits,
location ........................................................................... 75
Corbel Mine .............................................................. 35,36
Geology ...................................................................... 36
Corless Lake.................................................................. 99
Correlation:
Precision .................................................................... 46
Techniques, table ..................................................... 43
Volcanic rocks, problems ........................................ 41
Correspondence analysis................................... 125,152
Discussion ............................................................... 149
Major oxides ............................................................ 150
Major oxides and trace elements ......................... 159
Creede caldera ........................................................... 118
Crow (Kakagi) Lake...................................................... 51
Croxall Property.............. 125,126,128,129,152,155,161
Cycle Four...................................................................... 66
Cycle l............................................................. 95,96,98,99
Age dating.................................................................. 96
Rocks, targets for gold ............................................. 98
Cycle II........................... 91,93,94,96,97,99,109,110,116
Cycle III....................... 91,93,96,97,99,108-114,116,119
Formation K ...................................................... 113,114
Formation L............................................... 113,116,117
Formation M ............................................................. 113
Cycles:
Felsic volcanic rocks ............................................... 65
Major cycles ............................................................ 106
Mini-cycles.......................................................... 91,106
Minor cycles ............................................................ 106
Cyclical volcanism ..................................................... 105
Cyclicity......................................................... 107,108,112
Mineral deposits, relationship............................... 105
Debris flow..................................................................... 12
Deformation zones:
Pipestone Bay-St. Paul Bay ..................................... 95
Post Narrows ............................................................. 97
Deloro Group ....................................................... 71,72,78
Age dating............................................................. 71,82
Deloro Township ........................................................... 83

Deposits:
Explosive/Pyroclastic ................................................. 5
Extrusive........................................................................ 5
Ross lode ................................................................... 84
Destor-Porcupine Fault Zone ........... 70,72,79-81,83-85
Diabase dikes........................................................... 63,71
Diapir, mantle ........................................................... 70,72
Dikes:
Composite ................................................................ 119
Diabase ................................................................. 63,71
Lamprophyre ............................................................. 63
Diorite, quartz sill .......................................................... 36
Dirtywater Lake ............................................................. 53
Discriminant function analysis ................................. 149
Distal deposited pyroclastic rocks ............................. 35
Distal facies .............................................................. 24,26
Dogpaw Lake................................................................. 53
Dogtooth Lake volcanics ............................................. 53
Dolomite ................................................................ 127,147
Dome Stock.................................................................... 96
Doming, resurgent....................................................... 118
Double-graded sequence ............................................ 30
Dryberry Batholith ......................................................... 53
Dryberry Lake ................................................................ 53
Dryden .......................................................................... 110
Dunraine Mines Ltd....................................................... 68
Duprat-Montbray Complex ......................................... 108
Dynamic Cluster Analysis .......................... 125,155,161
Eastern Peninsula ......................................................... 53
Eigenvalues ................................................................. 149
Eigenvectors ................................................................ 149
Eleanor iron range ........................................................ 63
Elk Lake.......................................................................... 32
English River.................................................................. 50
Environment, factor in volcanism.................................. 7
Epiclastic facies ............................................................ 24
Epiclastic rocks ............................................................. 35
Epiclastic volcanic breccia ......................................... 13
Epigenetic model .......................................................... 81
Eruptions:
Basaltic flood ............................................................... 6
Hawaiian ....................................................................... 6
Magmatic....................................................................... 5
Phreatic (steam)....................................................... 5,6
Phreatomagmatic ..................................................... 5,6
Plinian............................................. 6,113,115,116,118
Strombolian................................................................... 6
Sub-Plinian.................................................................... 6
Surtseyan ...................................................................... 5
Vulcanian ...................................................................... 6
Eruptive centre .............................................................. 97
Eruptive mechanisms ...................................................... 5
Evolution of Western Abitibi Subprovince ................ 72
Exhalative models of iron formation.......................... 78
Exploration:
Implications................................................................ 37
Targets........................................................................ 97
Explosive/Pyroclastic deposits ..................................... 5
VOL CANOL OG Y AND MINERAL DEPOSITS
Extrusive deposits ........................................................... 5
Extrusive volcanic rocks, classification ....................... 8
Facies ............................................................................ 5,8
Albite-epidote hornfels .......................................... 127
Analysis................................................................... 4,21
Central................................................................... 23,26
Distal...................................................................... 24,26
Epiclastic................................................................... 24
Greenschist field criteria ......................................... 25
Models................................................................ 5,21,31
Prehnite-pumpellyite .............................................. 127
Proximal................................................................. 24,26
Subgreenschist ......................................................... 71
Variation in central vent composite
volcano....................................................................... 26
Variation in shield volcano ..................................... 27
Vent........................................................................ 23,26
Zeolite....................................................................... 127
Facing indicator, consistent facies
variation.......................................................................... 65
Factor coordinate positions....................................... 161
Factored space ........................................................... 155
Faults:
Porcupine-Destor Break ........................................... 45
Pipestone-Cameron .................................. 52,63,58,60
Favourable Lake area ................................................ 109
Favourable Lake Belt ................................................... 99
Favourable suites for mineralization ......................... 84
Fe-tholeiitic flows ......................................................... 55
Feldspar porphyries ..................................................... 60
Felsic flows:
Porphyritic .................................................................. 25
Pyroclastic ................................................................. 26
Felsic metatuff .............................................................. 25
Felsic pyroclastic rocks, age dating ..................... 93,94
Felsic volcanic rocks, cycles...................................... 65
Felsic volcanics, age dating ....................................... 91
Felsic volcanism, hiatuses ........................................ 115
Ferruginous dolomite ................................................... 65
Flavrian andesite .......................................................... 36
Flin Flon........................................................................ 111
Flows:
Breccias, photo ......................................................... 23
Carbonatized komatiitic ........................................... 81
Mafic........................................................................... 31
Magnetite-bearing..................................................... 65
Morphology ................................................................ 11
Aa lava .............................................................. 10,11
Pahoehoe lava ................................................. 10,11
Pillowed lava .................................................... 10,11
Near vent.................................................................... 74
Porphyritic felsic ....................................................... 25
Unit................................................................................. 8
Concept..................................................................... 7
Fluorine......................................................................... 119
Fly Lake........................................................................ 113
Folding and faulting, relationship to
volcanism ....................................................................... 70
Fractional crystallization............................................ 111
Fragment shape ............................................................ 13
177
VOLCANOLOGY AND MINERAL DEPOSITS
Fragmental composition ........................................ 13, 14
Fragmentation, types.................................................... 11
Fuchsite..................................................................... 80,83
Gabbro, peridotite sill.................................................. 83
Galena .......................................................................... 125
Garrison lode deposit................................................... 84
Garrison Stock ............................................................... 83
Garrison Township................................................... 83 50
Geochemistry .............................................................. 129
Lithogeochemical information,
interpretation ........................................................... 161
Lithogeochemistry, sample sources .................... 128
Geophysical correlation ............................................... 45
Gibi Lake volcanics ................................................. 53,54
Glomeroporphyritic horizon......................................... 43
Gold............................. 60,74,75,79,83,112,114-116,125
Gold deposits .............................................. 68,83,85,110
Lode.................................................................. 81,84,85
Types ...................................................................... 74
Model.......................................................................... 79
Stratigraphy, relationship......................................... 98
Stratiform............................................................... 78,80
Gold exploration............................................................ 58
Gold mineralization:
Location...................................................................... 83
Stratiform.................................................................... 84
Model...................................................................... 79
Types .......................................................................... 75
Gold occurrences, categories ..................................... 58
Gold potential area, shear zones .......................... 58,60
Gold showings............................................................... 66
Golden Arrow lode deposit.......................................... 84
Golden Arrow Mine ....................................................... 83
Goldlund Deposit .......................................................... 58
Grain size classification .............................................. 12
Granulometric classification:
Polymodal volcanic pyroclastic rocks ................... 14
Pyroclastic deposits ................................................. 14
Pyroclastic rocks ...................................................... 13
Graphic Lake ................................................................. 53
Greenschist facies, field criteria ................................ 25
Ground surge................................................................. 19
Growth faults ................................................................. 80
Guatemala...................................................................... 35
Gullrock Lake ................................................................ 91
Halliday Dome .......................................................... 77,82
Harker Township........................................................... 84
Harper, G........................................................................ 68
Hart Deposit................................................................... 81
Hawaiian eruption ............................................................ 6
Hawk Lake granitic complex, age dating.................. 66
Heather Lake ....................................................... 32,33,34
Heazlewoodite............................................................... 82
Helen iron formation................................................ 45,66
Helen iron range, age dating ...................................... 66
Hemlo............................................................................ 115
Hemlo deposits ............................................................. 80
178
Heyson Township ......................................................... 96
Hiatuses ....................................................................... 114
Felsic volcanism ..................................................... 115
Stratigraphic ........................................................... 113
Hill-Sloan-Tivey quartz horizon ................................ 115
Hollinger deposit........................................................... 79
Holloway Township ...................................................... 79
Hope Lake...................................................................... 60
Hot spring activity ......................................................... 36
Hoyles Bay................................................................ 91,93
Hunter Mine Group................................... 63,72,75,77,78
Age dating.................................................................. 72
Huronian Supergroup ................................................... 71
Hyaloclastics, photo ..................................................... 23
Hydrothermal alteration ............................................. 114
Hydrothermal circulation system................................ 37
Hydrothermal solutions ................................................ 75
Hydrothermal system ................................................. 114
Ignimbrite ...................................................... 116,118,119
Pumice........................................................................ 19
Immobile component, alteration effects.................. 147
"Immobility" variable ................................................. 147
Indicators of mineralization....................................... 161
Intermediate pyroclastic flow...................................... 26
Intravolcanic iron formations ...................................... 45
Iron-enrichment cycles .............................................. 111
Iron enrichment trend ................................................. 107
Iron formation ...................................................... 78,84,85
Exhalative .................................................................. 78
Intravolcanic .............................................................. 45
Lithologic correlation methods ............................... 63
Michipicoten .................................................... 63,65,66
Sedimentary............................................................... 78
Source ........................................................................ 78
Iron ore ...................................................................... 74,77
Iron ranges:
Helen .......................................................................... 66
Josephine-Bartlett................................................ 63,65
Kathleen ..................................................................... 54
Lucy ....................................................................... 63,65
Ruth............................................................................. 65
Island systems ................................................................. 8
Isochemical contour plots ......................................... 129
"Expected" value.................................................... 129
"Residual" value..................................................... 129
Jensen cation plots ...................................................... 54
Josephine-Bartlett iron range................................. 63,65
Jubilee Stock ....................................................... 63,66,68
Kakagi Lake......................................................... 51,55,58
Kambalda Deposit ........................................................ 82
Kamiskotia Gabbroic Complex ................................... 82
Kathleen iron range ...................................................... 65
Katimiagamak Lake volcanics .................................... 55
Kenogamissi Batholith ................................................. 72
Kenora .......................................................................... 114
Kerr Addison Mine ........................................................ 79

"Key Tuffite".................................................................. 43
Kidd Creek Rhyoiites............................................... 72,75
Age dating............................................................. 72,82
Kinojevis Group........................................................ 71,78
Kirkland Lake ................................... 71,77,80,81-85,111
Kirkland Lake "Main Break" zone......................... 83,84
Kirkland Lake area ....................................................... 44
Kirkland Lake Camp ..................................................... 84
Kirkland Lake-Cadillac Fault Zone ............................ 70
Kirkland Lake-Larder Lake Fault Zone 72,79-81,83-85
Kishquabik Lake Stock ........................................... 35,60
Knee Lake area............................................................. 43
Komatiite class ............................................................ 107
Komatiitic unit.............................................................. 107
Koza, H. .......................................................................... 68
Lahar............................................................................... 12
Coarse-grained deposits comparison ................... 12
Origin .......................................................................... 12
Lake Abitibi.................................................... 75,77,83,85
Lake Abitibi Batholith .............................................. 72,83
Lake of the Woods ............................................. 37,50,58
Preliminary stratigraphic synthesis........................ 52
Stratigraphy ............................................................... 51
Lake St. Joseph............................................................. 99
Laminated algal mats ................................................... 45
Lamotte Township......................................................... 81
Lamprophyre.................................................................. 83
Dikes........................................................................... 63
Langmuir Deposit.......................................................... 81
Lapilli-tuff.................................................................. 13,33
Larder Lake............................................................... 79,80
Larder Lake Camp ........................................................ 84
Larder Lake Group ................................... 71,78,79,81-83
Larder Lake Mining Camp ........................................... 81
Late felsic intrusions .................................................... 84
Lateral facies variation ................................................ 30
Lava domes ................................................................... 11
Lead-quartz vein ........................................................... 66
Lead-uranium zircon dating programs ...................... 58
Lesser Antilles volcanic arc........................................ 23
Lithic block deposit...................................................... 19
Lithogeochemical information,
interpretation................................................................ 161
Lithogeochemistry, sample sources ........................ 128
Lithologic correlation methods:
Iron formation ............................................................ 63
Rock composition ..................................................... 63
Lobstick Bay .................................................................. 35
Lode gold deposits ............................................. 81,84,85
Long Bay ........................................................................ 35
Long Bay-Lobstick Bay area .................................. 54,58
Lower Formation ................................................. 79,81,82
Lower Supergroups.................................................. 75,83
Lower Tisdale Group .................................................... 71
Lucy iron range ........................................................ 63,65
Madsen area............................................................. 94-96
VOLCANOLOGY AND MINERAL DEPOSITS
Mafic breccia................................................................. 65
Mafic flows .................................................................... 31
Subaqueous, model.................................................. 31
Mafic shield volcano, products .................................. 28
Magma chambers, chemically zoned........................ 15
Magma clan .......................................................... 106,116
Magma clan units........................................................ 108
Magmatic eruptions ......................................................... 5
Magmatic fluid model................................................... 81
Magmatism, resurgent................................................ 119
Magnesian tholeiitic flows (MTF) .......................... 54,55
Magnesite..................................................... 74,83-85,147
Location...................................................................... 75
Magnetite........................................................................ 82
Magnetite-bearing flows .............................................. 65
Magpie River.................................................................. 63
Major cycles ................................................................ 106
Major element analyses............................................... 54
Major ring-fracture volcanism ................................... 118
Malartic Group ..................................................... 71,81,82
Manitoba....................................................................... 110
Mantle diapir............................................................. 70,72
Mantle-derived tholeiitic liquid ................................. 112
Mapping progress ......................................................... 62
Marbidge Deposit.......................................................... 81
Markov Chain Analysis ................................................ 44
Massive copper-zinc-lead sulphide
deposits, model............................................................. 75
Massive sulphides, "stacked"
configuration.................................................................. 77
Massive-sulphide deposits..................................... 35-37
Massive-sulphide lens ................................................. 36
Matachewan ........................................................ 82,83,85
Matheson...................................................... 79,83,85,126
Mats, laminated algal................................................... 45
Mattagami area ............................................................. 43
Maybrun Mine.............................................................. 114
McKenzie Island .................................................. 91,93,96
McWalters Deposit........................................................ 81
Meen-Dempster Lakes Belt ......................................... 99
Megacauldron..................................... 70,72,74,77,80,82
Model.......................................................................... 84
Melting, partial............................................................... 77
Sediments .................................................................. 84
Metamorphism, effect on volcanic rocks.................. 21
Metavolcanic sequences ............................................. 51
Michipicoten iron formation .............................. 63,65,66
Midlothian Township .................................................... 83
"Mill-rock"..................................................................... 4,5
Millenbach deposit, geology ....................................... 36
Millenbach Mine............................................................ 35
Millenbach volcano ...................................................... 35
Millerite........................................................................... 82
Miminiska Lake ............................................................. 99
Mineral deposits............................................................ 58
179
 VOLCANOLOGY AND MINERAL DEPOSITS
Mineral exploration:
Applications ............................................................... 44
Volcanic facies ......................................................... 37
Mineral potential:
Evaluation ................................................................ 119
Wawa area ................................................................. 68
Mineralization:
Abitibi Subprovince .................................................. 84
Asbestos .................................................................... 47
Barium-gold ............................................................. 115
Base-metal............................................................ 74,85
Cadmium .................................................................... 75
Chalcopyrite ....................................................... 68,126
Chlorite ..................................................................... 126
Copper................................................................. 66,119
Favourable suites ..................................................... 84
Galena ...................................................................... 125
Gold .......................................................... 74,75,79,125
Iron ore ....................................................................... 74
Magnesite................................................................... 74
Nickel..................................................................... 74,82
Pyrite..................................... 68,112,113,125,126,128
Pyrrhotite .................................................................. 113
Silver.................................................................... 75,125
Sphalerite .......................................................... 113,125
Talc ............................................................................. 74
Tin ............................................................................... 75
Types, Western part of Abitibi Belt ........................ 70
Zinc ...................................................................... 66,119
Mini-cycles.............................................................. 91,106
Minor cycles ................................................................ 106
Mist Inlet.................................................................... 35,54
Molecular proportions ................................................ 147
Mud flow......................................................................... 12
Munro Township....................................................... 81,83
Muscovite-bearing metagreywacke ........................... 25
Musquash Township .................................................... 63
N-dimensioned space ................................................ 155
Near tuffs ....................................................................... 74
Near vent flows ............................................................. 74
Negative factor values ............................................... 152
New Keloro Mine........................................................... 83
Nickel.................................................................... 74,82,94
Deposits ..................................................................... 84
Redstone .............................................................. 112
Nickel sulphide ........................................................ 66,85
Hydrothermal emplacement.................................... 82
Immiscible liquid model........................................... 82
Sulphurization model ............................................... 82
Volcanic exhalative model...................................... 82
Noranda................................................................. 113,119
Noranda area................................................................. 35
Noranda Mining Camp ................................................. 75
Noranda-Rouyn area .................................................... 34
Normetal Mine ............................................................... 75
North Spirit Lake Belt ................................................... 99
Ohanapecosh Formation ............................................. 34
Oldest cycle................................................................... 66
Orchan orebody ............................................................ 43
Ore zones, structure ..................................................... 98
180
"Ovoids"................................................................ 127,128
Owl Creek ...................................................................... 79
Oxford Lake ................................................................. 110
Oxidation state indicator............................................ 147
Pacaud Tuffs ....................................................... 72,78,83
Age dating.................................................................. 72
Pahoehoe flows ............................................................... 9
Pamour ........................................................................... 79
Partial melting................................................................ 77
Penhorwood Township................................................. 83
Pentlandite ..................................................................... 82
Peridotitic-gabbro sills ................................................. 83
Perrigo Lake Intrusion .................................................. 99
Phinney-Dash Lakes area ......................................... 115
Phreatic breccias .......................................................... 24
Phreatic eruption.......................................................... 5,6
Phreatomagmatic (Surtseyan) eruptions .................. 5,6
Physical volcanology .................................................. 4,5
Conceptual sense ........................................................ 4
Empirical sense............................................................ 4
Pickle Lake .................................................................... 99
Pillow lavas ................................................................. 8,11
Pipestone Bay..................................................... 91,93-95
Pipestone Bay-St. Paul Bay Deformation
Zone................................................................................ 95
Pipestone-Cameron Fault ............................ 52,53,58,60
Platinum values ............................................................. 66
Plinian eruption ................................. 6,113,115,116,118
Plots .............................................................................. 155
Point Bay group ........................................................ 53,54
Polycyclic volcanism............................................. 99,100
Polymodal volcanic pyroclastic rocks:
Granulometric classification ................................... 14
Pontiac Group ................................................................ 78
Populus volcanics ............................................... 52,53,60
Porcupine Group ...................................................... 78,82
Porcupine-Destor Break ............................................... 45
Porphyritic felsic flows ................................................ 25
Porphyry, vent facies ................................................... 35
Post Narrows Deformation Zone ................................ 97
Prehnite-pumpellyite facies ...................................... 127
Preresurgence volcanism and
sedimentation .............................................................. 118
Problems of interpretation ...................................... 42,43
Products:
Central vent composite volcano............................. 28
Mafic shield volcano................................................ 28
Prograding volcano ...................................................... 53
Proterozoic succession.............................................. 111
Proximal facies......................................................... 24,26
Proximal tuffs ................................................................ 74
Proximal vent facies rocks.......................................... 78
Proximal vent flows ...................................................... 74
Proximal volcanic environment ............................... 4,33
Pumice ............................................................................ 19
Pyrite ............................... 65,68,82,112,113,125,126,128

Pyroclast............................................................................ 5
Pyroclastic breccia ............................................. 13,32,33
Formation mechanism.............................................. 19
Photo........................................................................... 22
Pyroclastic deposits:
Explosive ....................................................................... 5
Fall ......................................................................... 14,17
Granulometric classification ................................... 14
Types ..................................................................... 14,16
Pyroclastic flows:
Deposits ................................................................ 14,17
Felsic .......................................................................... 26
Intermediate............................................................... 26
Types ..................................................................... 18,19
Subaqueous ............................................................... 30
Pyroclastic rocks................................................... 5,11,54
Distal deposited ........................................................ 35
Granulometric classification ................................... 13
Polymodal volcanic .................................................. 14
Skead Group......................................................... 32,37
Subdivision ................................................................ 20
Unimodal.................................................................... 13
Well sorted ................................................................. 13
Pyroclastic surge deposits ..................................... 14,17
Types .......................................................................... 19
Pyroclastic-epiclastic rocks, terms ............................ 15
Pyrrhotite ................................................................. 82,113
Quartz, blue ................................................................... 35
Quartz lenses ................................................................ 68
Quartz veins................................................................... 80
Lead ............................................................................ 66
Quartz-carbonate shear zone ..................................... 60
Quartz-carbonate veins ............................................... 80
Quartz-diorite sill........................................................... 36
Quartz-feldspar porphyry ....................................... 33-36
Quebec ...................................................................... 35,81
Quetico Subprovince .................................................... 50
Radiometric age determination methods .................. 45
Radiometric ages, Red Lake Belt ............................... 91
Radiometric dating........................................................ 55
Rare earth element data ............................................ 107
Red Lake .................... 53,91,94,96,97,107,108,112,114
Red Lake anticlinorium ........................................... 95,96
Red Lake area, stratigraphic development............. 100
Red Lake Belt ................................... 89,90,91,93,96-100
Radiometric ages ...................................................... 91
Red Lake Camp............................................................. 97
Redeposited fragmental rocks .................................... 11
Redstone nickel deposit ............................................ 112
Reed Narrows ................................................................ 58
Regina Bay..................................................................... 58
Regina Bay Stock .......................................................... 60
Regina Mine ................................................................... 60
Regional correlation, volcanic stratigraphy .............. 72
Relationship between stratrigraphy and
mineral deposits............................................................ 69
Resurgent doming ....................................................... 118
Resurgent magmatism................................................ 119
VOLCANOL OG Y AND MINERAL DEPOSITS
Rhyolites......................................................................... 94
Endogeneous dome ............................................... 113
Magma...................................................................... 118
Ross lode deposit......................................................... 84
Ross Mine.................................................................. 83,84
Round Lake Batholith ......................................... 72,83,84
Rouyn-Noranda, city ..................................................... 35
Ruth iron range .............................................................. 65
Sample point "clouds" or groups ............................. 155
Sample sources, lithogeochemistry......................... 128
Sampling problems ..................................................... 128
Santiaquito ..................................................................... 35
Saussurite .................................................................... 127
Savant Lake ......................................................... 50,51,58
Savant Lake-Crow Lake area...................................... 43
Scoria.............................................................................. 19
Seafloor model.............................................................. 81
Seagrave Lake .............................................................. 99
Second cycle ................................................................. 66
Second factor.............................................................. 155
Sedimentary models of iron formation ...................... 78
Sediments, partial melting ........................................... 84
Selco Inc......................................................................... 91
Sericite.......................................................................... 127
Setting Net Lake................................................... 113,119
Shaw Dome.......................................................... 77,78,82
Shebandowan.............................................................. 110
Sherman Mine ............................................................. 116
Shield volcano............................................................... 21
Facies variation......................................................... 27
Mafic, products ......................................................... 28
Siderite ............................................................ 65,127,147
Silicification ................................................................. 127
Sill:
Peridotitic-gabbro ..................................................... 83
Quartz-diorite............................................................. 36
Silver.................................................................. 66,75,125
Assay .......................................................................... 66
Silver-quartz vein .......................................................... 66
Si02 independent variable......................................... 147
Sioux Lookout................................................................ 58
Site selection criteria.................................................. 129
Skead Group ............................................. 30,34,77,78,83
Pyroclastic rocks ................................................. 32,37
Skead Township............................................................ 77
Snake Bay formation .......................................... 52,55,60
Snake Bay formation-Aulneau Batholith
contact............................................................................ 53
Snake Bay volcanics ............................................... 52,54
Solfataric, terminal and hot-spring activity ............. 118
Sothman Deposit........................................................... 81
South Bay ................................................................ 90,116
South Bay Mine ............................................................. 97
South Bay-type copper-zinc deposits........................ 97
Southern sequence, age dating.................................. 96
Spatial position ..................................................... 155,161
181
 VOLCANOLOGY AND MINERAL DEPOSITS
Spatially mapped abundance ................................... 129
Sphalerite ........................................................ 82,113,125
Spherulite .......................................................................... 9
Spiked peaks ............................................................... 129
St. Anthony Mine........................................................... 58
St. Vincents .................................................................... 43
Stage II.......................................................................... 118
Stage IV ........................................................................ 118
Steep Rock Mines Ltd................................................... 58
Stock, Regina Bay......................................................... 60
Stoughton-Roquemaure Group.......................... 71,78,82
Stratiform gold:
Deposits ................................................................ 78,80
Mineralization ............................................................ 84
Model...................................................................... 79
Stratigraphic contact, significance............................. 74
Stratigraphic hiatuses ................................................ 113
Stratigraphic position ................................................. 119
Stratigraphic scheme, evolution ................................. 89
Stratigraphy and mineral deposit,
relationship ............................................................... 69,77
Stromatolites .................................................................. 91
Archean ...................................................................... 44
Stromatolitic carbonate ................................................ 91
Age dating.................................................................. 93
Stromatolitic horizons, potential correlation
tools ................................................................................ 45
Stromatolitic marble...................................................... 91
Strombolian eruption ....................................................... 6
Studemeister, P. ............................................................ 68
Sturgeon Lake ............................................................... 58
Base-metal deposits................................................. 46
Styles of Archean cyclical volcanism ..................... 108
Sub-Plinian eruption ........................................................ 6
Subaqueous mafic flows, model................................ 31
Subaqueous pyroclastic flows:
Discussion ................................................................. 30
Model.......................................................................... 30
Subaqueous transport.................................................. 29
Subcycle......................................................................... 65
Subgreenschist facies ................................................. 71
Submarine eruption ...................................................... 29
Submarine hydrothermal systems ............................. 36
Sulphide minerals ......................................................... 82
Chalcopyrite .............................................................. 82
Chromite..................................................................... 82
Heazlewoodite........................................................... 82
Magnetite ................................................................... 82
Massive sulphides:
Copper-zinc-lead deposits .................................. 75
Deposits ............................................................ 35-37
Lens ........................................................................ 46
"Stacked" configuration ...................................... 77
Millerite....................................................................... 82
Nickel..................................................................... 66,85
Hydrothermal emplacement................................ 82
Immiscible liquid model....................................... 82
Sulphurization model ........................................... 82
Volcanic exhalative model.................................. 82
182
Pentlandite ................................................................. 82
Pyrite........................................................................... 82
Pyrrhotite.................................................................... 82
Sphalerite................................................................... 82
Violarite ...................................................................... 82
Sunshine Lake............................................................. 111
Super cycles ................................................. 106,107,111
Supergroups................................................................... 71
Superior Province.................................... 81,100,109,111
Surface II Graphics Systems..................................... 129
Surge:
Ash cloud ................................................................... 19
Base............................................................................ 19
Ground........................................................................ 19
Surtseyan eruptions......................................................... 5
Synclinorium ..................................................... 71,91,126
Talc ....................................................................... 74,84,85
Location...................................................................... 75
Tectonostratigraphic model.................................... 90,91
Tephrochronology......................................................... 43
Terminal solfataric and hot-spring activity ............. 118
Texmont Deposit........................................................... 81
Thickness:
Upper Supergroup..................................................... 72
Wabewawa-Catherine-Skead
Supergroup ................................................................ 72
Thio complex ............................................................... 112
Tholeiitic to calc-alkalic flows and
pyroclastic rocks........................................................... 54
Tholeiitic unit............................................................... 107
Thunder Bay ................................................................ 110
Timiskaming Group.......................................... 44,81,110
Timmins ................................ 71,72,77,78,80-85,112,114
Timmins Mining Camp........................................ 79,81,84
Tin ................................................................................... 75
Tisdale Group ................................................ 74,79,81-83
Lower.......................................................................... 71
Trace elements..................................................... 155,161
Tuff............................................................................. 13,14
Lapilli ..................................................................... 13,33
Near ............................................................................ 74
Pacaud ............................................................. 72,78,83
Age dating ............................................................. 72
Proximal...................................................................... 74
Tuff-breccia ................................................................... 33
Tuff-chemical sediment unit..................................... 107
Tuffite ............................................................................. 43
Tumescence ................................................................ 117
Types of Archean cyclical volcanism ..................... 108
Types of volcanoes ...................................................... 25
Uchi Subprovince ............................... 89,91,99,100,110
Uchi-Confederation Lakes area ................. 90,91,97,98
Stratigraphic development.................................... 100
Uchi-Confederation Lakes Belt................. 89,91,97,100
Upper Formation ........................................................... 78
Age dating.................................................................. 82
Upper QFP ................................................................. 35,26

Upper Supergroup .................................... 71,75,79,82-84
Thickness................................................................... 72
Uranium-lead zircon dating programs ....................... 58
Valles caldera ............................................................. 117
Varioles ............................................................................. 9
Horizons ..................................................................... 43
Lavas ............................................................................. 9
Origin ............................................................................. 9
Vein:
Lead-quartz................................................................ 66
Silver-quartz............................................................... 66
Vent facies ................................................................ 23,26
Porphyry ..................................................................... 35
Rocks .......................................................................... 35
Vesicles ..................................................................... 9,126
Water depth .................................................................. 9
Violarite .......................................................................... 82
Volcanic activity, age dating....................................... 99
Volcanic breccia:
Alloclastic .................................................................. 13
Autoclastic ................................................................. 13
Epiclastic.................................................................... 13
Pyroclastic ................................................................. 13
Types .......................................................................... 13
Volcanic centre ...................................................... 63,127
Volcanic cycles ................................... 63,72,90,105,119
Volcanic domes .......................................................... 118
Volcanic environment ................................................ 127
Volcanic facies ............................................................. 54
Analysis, Archean..................................................... 32
Mineral exploration ................................................... 37
Regimes, recognition ................................................... 4
Volcanic fragmental rocks, classification............ 11,13
Volcanic products ............................................................ 6
Volcanic rocks.................................................................. 5
Volcano evolution, complexities............................... 116
Volcanoes, types .......................................................... 25
Volcanogenic deposits................................................. 82
VOLCANOLOGY AND MINERAL DEPOSITS
Volcanogenic massive-sulphide deposits:
Exploration criteria.................................................... 37
Occurrences .............................................................. 36
Vulcanian eruption........................................................... 6
Wabasee Group ............................................................ 43
Wabewawa Group.................................................... 78,83
Wabewawa-Catherine-Skead Supergroup ........... 71,84
Thickness................................................................... 72
Wabigoon Fault............................................................. 58
Wabigoon Subprovince...................... 34,50,51,108-111
Warclub group ..................................................... 34,35,53
Rock types, stratigraphic details ............................ 53
Sediments .................................................................. 52
Warrawoona Group....................................................... 45
Watabeag Batholith ...................................................... 84
Watson Lake Group ...................................................... 43
Wawa area ..................................................... 45,63,66,68
Mineral potential ....................................................... 68
Structure ..................................................................... 63
Wawa Greenstone Belt................................................. 78
Wawa Lake .................................................................... 63
Wawa Subprovince..................................................... 110
Wawa supracrustal belt............................................... 62
Wawa supracrustal sequence, cycles ....................... 62
Western Abitibi Subprovince, evolution .................... 72
Western Australia............................................. 45,82,114
Woman Lake............................................................. 91,93
Yellow Girl Bay.............................................................. 53
Yellow Lake ................................................................... 53
Yoke Lake ............................................................. 110,111
Young Davidson Mine .................................................. 83
Yttrium ....................................................................... 94,96
Zeolite facies............................................................... 127
Zinc .................................................................. 66,118,119
Zircon.............................................................................. 94
Uranium-lead dating program ................................. 58
Zirconium .................................................................. 94,96
183
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