ANTOINE:

DATOS EXPERIMENTALES:

PARAMETROS DE NRTL Y UNIQUAC :

ECUACION DE NRTL

Temperatura 40 °C n - Pentane
313.15 K Propionaldehyde

PARÁMETROS DE INTERACCIÓN A12= 1920.1

A21= 2007.6
α= 0.3
R= 8.314

TABLA DE INTERACCIÓN τ12 0.737498959

τ21 0.771107187
Pvp1 865.7106777

x1 x2 ϒ1 ϒ2 P mmHg y1
0.0001 0.9999 3.965527532 1.000000014 570.9392091 0.0006012899
0.05 0.95 3.442522204 1.003582243 693.0737362 0.2150008054
0.1 0.9 3.015569794 1.014263805 781.9744812 0.3338486144
0.15 0.85 2.665125607 1.032081829 846.7006279 0.4087444167
0.2 0.8 2.375483113 1.057250403 893.9546817 0.4600862073
0.25 0.75 2.134618194 1.090163966 928.5694167 0.4975292451
0.3 0.7 1.933246749 1.131409151 954.0390976 0.5262779139
0.35 0.65 1.764143956 1.181785552 972.8865209 0.5494303594
0.4 0.6 1.621647814 1.242336602 986.9169714 0.5689953132
0.45 0.55 1.501293849 1.314392418 997.3928147 0.5863875731
0.5 0.5 1.399544142 1.399627439 1005.150928 0.6026957112
0.55 0.45 1.313584896 1.500136777 1010.677335 0.618843856
0.6 0.4 1.241174331 1.618536809 1014.147855 0.6357048624
0.65 0.35 1.180527924 1.758097589 1015.43942 0.6541967404
0.7 0.3 1.130231729 1.922917626 1014.113167 0.6753857413
0.75 0.25 1.089177106 2.118155661 1009.367141 0.7006213691
0.8 0.2 1.056512064 2.350339919 999.952709 0.7317416245
0.85 0.15 1.031605838 2.627783705 984.0442458 0.7714199481
0.9 0.1 1.014024347 2.961148398 959.0453461 0.8238051909
0.95 0.05 1.003514996 3.364212771 921.3058645 0.89581104
0.9999 0.0001 1.000000014 3.85385056 865.84404 0.9997460038
 A B C DATOS EXPERIMENTA
7.57242 1482.01 279.74 N P (mmHg)
6.87644 1055.479 216.18 1 570.82
2 589.4
3 705.02
J/mol 4 747.81
J/mol 5 770.76
6 789.4
J/mol.K 7 835.04
DIAGONAL 8 871.9
G12 0.801516527 x y 9 875.47
G21 0.793475864 0 0 10 913.19
Pvp2 570.6529662 1 1 11 935.97
12 956.93
y2 y1+y2 13 971.44
0.99939871 1 14 990.05
0.784999195 1 15 993.23
0.666151386 1 16 1001.8
0.591255583 1 17 1001.87
0.539913793 1 18 1006.4
0.502470755 1 19 1012.29
0.473722086 1 20 1017.88
0.450569641 1 21 1022.95
0.431004687 1 22 1017.76
0.413612427 1 23 1001.71
0.397304289 1 24 961.29
0.381156144 1 25 923.49
0.364295138 1 26 865.77
0.34580326 1
0.324614259 1
0.299378631 1
0.268258375 1
0.228580052 1
0.176194809 1
0.10418896 1
0.000253996 1
ATOS EXPERIMENTALES:
X1 Y1
0 0
0.0059 0.0335
0.0503 0.2121
0.0725 0.2747
0.0835 0.3033
0.1014 0.3452
0.1272 0.3811
0.1647 0.4288
0.1746 0.4347
0.2212 0.4685
0.2615 0.4987
0.3019 0.5281
0.3476 0.5539
0.4082 0.5686
0.4135 0.5725
0.4463 0.5877
0.46 0.5875
0.4759 0.6002
0.5031 0.6146
0.561 0.6311
0.6812 0.6827
0.7597 0.7293
0.8333 0.7669
0.918 0.8452
0.9577 0.9114
1 1
 1

0.9

0.8

0.7

0.6

0.5 NRTL
Y

DATOS EXP.
DIAGONAL
0.4 Linear (DIAGONAL)

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X
 1200

1000

800

600 X TEORICO Vs P
Axis Title
Y TEORICO Vs P
X EXP Vs P
Y EXP Vs P

400

200

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Axis Title
ECUACION DE UNIQUAC

A B C
n - Pentane 7.5742 1482.01 279.74
Propionaldehyde 6.87644 1055.479 216.18

Temperatura 40 °C
313.15 K

PARÁMETROS DE INTERACCIÓN A12= 2021.5 J/mol

A21= 365.3 J/mol

TABLA DE INTERACCIÓN r q l
3.8254 3.316 -2.5707
2.5735 2.336 -1.45475

τ12 0.4600380416 Pvp1 869.266162

τ21 0.869089166 Pvp2 570.6529662

x1 x2 φ1 φ2 θ1 θ2 ϒ1
0.0001 0.9999 0.000148639 0.999851361 0.0001419461 0.999858054 8.732188818
0.05 0.95 0.072558083 0.927441917 0.0695178197 0.93048218 6.904506501
0.1 0.9 0.141750257 0.858249743 0.1362366475 0.863763353 5.556564501
0.15 0.85 0.207805424 0.792194576 0.2003221909 0.799677809 4.547698906
0.2 0.8 0.270932193 0.729067807 0.2619273302 0.73807267 3.780897507
0.25 0.75 0.331321075 0.668678925 0.3211933359 0.678806664 3.189955792
0.3 0.7 0.389146409 0.610853591 0.3782509506 0.621749049 2.728881399
0.35 0.65 0.444568038 0.555431962 0.4332213513 0.566778649 2.365197004
0.4 0.6 0.497732788 0.502267212 0.4862170088 0.513782991 2.075623758
0.45 0.55 0.548775764 0.451224236 0.5373424559 0.462657544 1.843248365
0.5 0.5 0.597821501 0.402178499 0.5866949752 0.413305025 1.655632598
0.55 0.45 0.644984971 0.355015029 0.6343652174 0.365634783 1.503532288
0.6 0.4 0.690372491 0.309627509 0.6804377565 0.319562244 1.380017202
0.65 0.35 0.734082519 0.265917481 0.724991591 0.275008409 1.279858944
0.7 0.3 0.776206364 0.223793636 0.7681005956 0.231899404 1.199100988
0.75 0.25 0.816828829 0.183171171 0.8098339303 0.19016607 1.134754564
0.8 0.2 0.856028777 0.143971223 0.8502564103 0.14974359 1.084583153
0.85 0.15 0.893879644 0.106120356 0.8894288419 0.110571158 1.046950824
0.9 0.1 0.930449893 0.069550107 0.9274083282 0.072591672 1.020717988
0.95 0.05 0.965803437 0.034196563 0.9642485461 0.035751454 1.005173963
0.9999 0.0001 0.999932724 6.72762E-05 0.9999295516 7.04484E-05 1.000000021
 DIAGONAL
x y
0 0
1 1
DATOS EXPERIMENTALE
N P (mmHg)
1 570.82
2 589.4
Z= 10 3 705.02
R= 8.314 J/mol.K 4 747.81
5 770.76
6 789.4
7 835.04
8 871.9
9 875.47
10 913.19
11 935.97
12 956.93
ϒ2 P mmHg y1 y2 y1+y2 13 971.44
1.0000000245 571.3549745 0.001328525 0.998671475 1 14 990.05
1.0060224976 845.4779295 0.35493853 0.64506147 1 15 993.23
1.0238673293 1008.858985 0.478771916 0.521228084 1 16 1001.8
1.0535691101 1104.013103 0.537107861 0.462892139 1 17 1001.87
1.0956298935 1157.500812 0.567879734 0.432120266 1 18 1006.4
1.1510196893 1185.854757 0.584582684 0.415417316 1 19 1012.29
1.22121121 1199.458738 0.593298674 0.406701326 1 20 1017.88
1.3082495967 1204.856736 0.597245283 0.402754717 1 21 1022.95
1.4148617762 1206.144841 0.598359148 0.401640852 1 22 1017.76
1.5446143341 1205.814358 0.597955266 0.402044734 1 23 1001.71
1.7021340002 1205.256605 0.597045222 0.402954778 1 24 961.29
1.8934118208 1205.04984 0.596517533 0.403482467 1 25 923.49
2.1262219127 1205.095291 0.597265096 0.402734904 1 26 865.77
2.4106999368 1204.635321 0.600305947 0.399694053 1
2.760147535 1202.162453 0.606936723 0.393063277 1
3.1921607483 1195.206808 0.618974727 0.381025273 1
3.7302290047 1179.966397 0.639198836 0.360801164 1
4.4060265485 1150.713904 0.672249708 0.327750292 1
5.262736613 1098.867673 0.726700827 0.273299173 1
6.3599377469 1011.541394 0.820604606 0.179395394 1
7.7776523544 869.6230875 0.999489625 0.000510375 1
DATOS EXPERIMENTALES
X1 Y1
0 0
0.0059 0.0335
0.0503 0.2121
0.0725 0.2747
0.0835 0.3033
0.1014 0.3452
0.1272 0.3811
0.1647 0.4288
0.1746 0.4347
0.2212 0.4685
0.2615 0.4987
0.3019 0.5281
0.3476 0.5539
0.4082 0.5686
0.4135 0.5725
0.4463 0.5877
0.46 0.5875
0.4759 0.6002
0.5031 0.6146
0.561 0.6311
0.6812 0.6827
0.7597 0.7293
0.8333 0.7669
0.918 0.8452
0.9577 0.9114
1 1
 1

0.9

0.8

0.7

0.6

0.5
UNIQUAC
y

DATOS EXP.
DIAGONAL
0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X
 1400

1200

1000

800

X TEORICO Vs P
P

y teorico Vs P
600 x exp. Vs P
Y exp Vs P

400

200

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X-Y
ECUACION DE UNIFAC

A B C
n - Pentane 7.57242 1482.01 279.74
Propionaldehyde 6.87644 1055.479 216.18

PARTE COMBINATORIAL
r1 3.8254 PARTE RESIDUAL:
r2 2.5735 X11 0.6 X12 0.333333333
q1 3.316 X21 0.4 X22 0.333333333
q2 2.336 X31 0 X32 0.333333333
l1 -2.5707
l2 -1.45475
z 10

x1 x2 ln(γ1) ln(γ2) γ1 γ2 φ1
0.0001 0.9999 1.246278626 1.1069296E-08 3.477378226 1.0000000111 0.000148639
0.0303 0.9697 1.180101764 0.0010231703 3.254705398 1.0010236939 0.044385454
0.0606 0.9394 1.115085671 0.0041206939 3.04982945 1.0041291956 0.087499921
0.090833333 0.909166667 1.051623239 0.0093214109 2.862293535 1.0093649905 0.129306338
0.1212 0.8788 0.989333273 0.0167103575 2.68944075 1.0168507565 0.170128185
0.1515 0.8485 0.928665458 0.0262905001 2.531129025 1.0266391439 0.209740841
0.1818 0.8182 0.869516803 0.0381210425 2.385757784 1.0388569712 0.248280624
0.2121 0.7879 0.811923442 0.0522483042 2.252235868 1.0536373327 0.285790539
0.2424 0.7576 0.755922299 0.0687195709 2.129574722 1.0711357893 0.322311322
0.2727 0.7273 0.701551104 0.0875831167 2.016878671 1.0915329853 0.357881587
0.303 0.697 0.648848414 0.1088882281 1.913336188 1.1150377135 0.392537968
0.3333 0.6667 0.597853631 0.1326852268 1.818212055 1.1418905053 0.426315237
0.3636 0.6364 0.548607026 0.1590254946 1.730840321 1.1723678354 0.459246425
0.3939 0.6061 0.501149754 0.1879614982 1.650617985 1.206787051 0.491362929
0.4242 0.5758 0.455523882 0.2195468149 1.576999328 1.2455121551 0.522694611
0.4463 0.5537 0.423425264 0.2442865055 1.527183615 1.2767100625 0.545068482
0.4848 0.5152 0.369939275 0.2908854094 1.447646704 1.3376112975 0.583115836
0.5151 0.4849 0.330069417 0.3307516359 1.391064689 1.3920140231 0.612258232
0.5454 0.4546 0.292208759 0.3734931295 1.339382597 1.4528005821 0.640721667
0.5757 0.4243 0.256404253 0.4191694308 1.292275028 1.520697986 0.668529595
0.606 0.394 0.222703902 0.46784136 1.249450559 1.5965441069 0.695704403
0.6363 0.3637 0.191156784 0.5195710487 1.210649248 1.6813062965 0.722267469
0.6666 0.3334 0.161813083 0.5744219707 1.175640473 1.7761035902 0.748239221
0.6969 0.3031 0.134724109 0.6324589752 1.144221061 1.8822332583 0.773639185
0.7272 0.2728 0.109942334 0.6937483205 1.116213701 2.0012026414 0.798486038
0.7575 0.2425 0.087521416 0.7583577082 1.091465639 2.134767429 0.822797653
0.7878 0.2122 0.067516229 0.8263563187 1.069847622 2.2849778227 0.84659114
0.8181 0.1819 0.049982896 0.8978148478 1.051253115 2.454234372 0.869882889
0.8484 0.1516 0.034978819 0.9728055442 1.035597773 2.6453557205 0.892688603
0.8787 0.1213 0.02256271 1.0514022476 1.022819173 2.8616610633 0.915023339
0.909 0.091 0.012794629 1.133680429 1.01287683 3.107070836 0.936901537
0.9393 0.0607 0.00573601 1.2197172309 1.005752493 3.3862300769 0.958337055
0.9696 0.0304 0.001449706 1.3095915093 1.001450757 3.7046600837 0.979343192
0.9999 0.0001 1.58069E-08 1.4033838768 1.000000016 4.0689455074 0.999932724
 DATOS EXPERIMENTALES: GRUPOS FUNCIONALES
N P (mmHg) X1 Y1 n - Pentane
1 570.82 0 0 Propionaldehyde
2 589.4 0.0059 0.0335
3 705.02 0.0503 0.2121
4 747.81 0.0725 0.2747 SUBGRUPO
5 770.76 0.0835 0.3033 CH2
6 789.4 0.1014 0.3452 j CH3
7 835.04 0.1272 0.3811 CHO
8 871.9 0.1647 0.4288
9 875.47 0.1746 0.4347
10 913.19 0.2212 0.4685
11 935.97 0.2615 0.4987
12 956.93 0.3019 0.5281 R1 0.6744
13 971.44 0.3476 0.5539 R2 0.9011
14 990.05 0.4082 0.5686 R3 0.998
15 993.23 0.4135 0.5725
16 1001.8 0.4463 0.5877
17 1001.87 0.46 0.5875
18 1006.4 0.4759 0.6002
19 1012.29 0.5031 0.6146
20 1017.88 0.561 0.6311
21 1022.95 0.6812 0.6827
22 1017.76 0.7597 0.7293
23 1001.71 0.8333 0.7669
24 961.29 0.918 0.8452
25 923.49 0.9577 0.9114
26 865.77 1 1
 lnΓ11 0.1 lnΓ12 0.223770465
lnΓ21 0.1 lnΓ22 0.351402508
lnΓ31 2.8100415478 lnΓ32 0.6781389452

Θ11 0.4885404101 Θ12 0.2311643836 ψ11 1

Θ21 0.5114595899 Θ22 0.3630136986 ψ21 1
Θ31 0 Θ32 0.4058219178 ψ31 0.1987604492

φ2 θ1 θ2 ln(γ1)C1 ln(γ2)C2 ln(γ1)R1

0.999851361 0.0001419461 0.9998580539 -0.775712886 7.0360443E-05 4.9287883625
0.955614546 0.0424715961 0.9575284039 -0.7391741374 0.0209276703 4.598390669
0.912500079 0.083890209 0.916109791 -0.703706496 0.0410929473 4.2626327826
0.870693662 0.1242067065 0.8757932935 -0.6694562031 0.0604873567 3.9226032777
0.829871815 0.1637213334 0.8362786666 -0.6361520754 0.079268513 3.5752373824
0.790259159 0.2022057018 0.7977942982 -0.6039713612 0.0973403682 3.2219529897
0.751719376 0.2397810167 0.7602189833 -0.5727965405 0.1147732052 2.8610796608
0.714209461 0.2764791116 0.7235208884 -0.5425866788 0.1315938053 2.4916243218
0.677688678 0.3123303512 0.6876696488 -0.5133029763 0.147827535 2.1124993408
0.642118413 0.3473637144 0.6526362856 -0.4849086326 0.1634984365 1.7225036117
0.607462032 0.3816068729 0.6183931271 -0.4573687198 0.178629312 1.3202999324
0.573684763 0.4150862642 0.5849137358 -0.4306500666 0.1932418011 0.9043876169
0.540753575 0.4478271592 0.5521728408 -0.4047211502 0.2073564534 0.4730689438
0.508637071 0.4798537264 0.5201462736 -0.3795519957 0.2209927948 0.0244075739
0.477305389 0.5111890907 0.4888109093 -0.3551140838 0.2341693894 -0.4438235993
0.454931518 0.5336210695 0.4663789305 -0.3377352819 0.2435002549 -0.7991475358
0.416884164 0.5718738261 0.4281261739 -0.3083246732 0.2592131282 -1.4497738195
0.387741768 0.6012647151 0.3987352849 -0.2859226641 0.2711130906 -1.994098524
0.359278333 0.6300475319 0.3699524681 -0.2641507321 0.2826190388 -2.5714625762
0.331470405 0.6582409542 0.3417590458 -0.242986452 0.2937455155 -3.187044397
0.304295597 0.6858629022 0.3141370978 -0.2224084175 0.3045063924 -3.8471932623
0.277732531 0.7129305772 0.2870694228 -0.2023961843 0.3149149076 -4.5598112902
0.251760779 0.7394604967 0.2605395033 -0.1829302171 0.3249837011 -5.3349028084
0.226360815 0.7654685286 0.2345314714 -0.1639918408 0.3347248469 -6.1853873718
0.201513962 0.7909699225 0.2090300775 -0.1455631936 0.3441498844 -7.1283440628
0.177202347 0.8159793396 0.1840206604 -0.1276271841 0.3532698467 -8.1869937419
0.15340886 0.8405108808 0.1594891192 -0.1101674505 0.3620952876 -9.3940145791
0.130117111 0.8645781133 0.1354218867 -0.0931683228 0.3706363072 -10.797434184
0.107311397 0.8881940954 0.1118059046 -0.0766147867 0.3789025749 -12.471946406
0.084976661 0.9113714004 0.0886285996 -0.0604924505 0.386903352 -14.543018979
0.063098463 0.9341221388 0.0658778612 -0.0447875133 0.3946475129 -17.246336811
0.041662945 0.9564579793 0.0435420207 -0.0294867353 0.4021435639 -21.111619621
0.020656808 0.9783901689 0.0216098311 -0.0145774103 0.4093996625 -27.828377941
6.72762E-05 0.9999295516 7.0448402878E-05 -4.733921570166E-05 0.4164236339 -84.784549723
C5H12
C3H6O

k
k Rk Qk Vk1(C5H12) Vk2(C3H6O)
3 0.6744 0.54 1 3
2 0.9011 0.848 1 2
1 0.998 0.948 1 0

Q1 0.54 V11 3 V12 1

Q2 0.848 V21 2 V22 1
Q3 0.948 V31 0 V32 1
 ψ12 1 ψ13 0.114986644
ψ22 1 ψ23 0.114986644
ψ32 0.1987604492 ψ33 1

ln(γ2)R2 lnΓ1 lnΓ2 lnΓ3 X1 X2 X3

-0.0002506046 0.2237217875 0.3513260664 0.678264079 0.333377775 0.333344444 0.3332777815
-0.0777283927 0.209416213 0.3288610159 0.716385191 0.346533359 0.33663334 0.3168333007
-0.1591131596 0.195815354 0.3075026301 0.755316137 0.359220813 0.339805203 0.3009739844
-0.2440721801 0.1829414659 0.2872858575 0.794878417 0.371398638 0.34284966 0.2857517025
-0.3333273509 0.1706633775 0.2680047114 0.83537469 0.383172958 0.34579324 0.2710338021
-0.4264897706 0.1590209867 0.2497218458 0.876583261 0.394489858 0.348622464 0.2568876779
-0.5239776997 0.1479480975 0.2323333087 0.918638879 0.405398977 0.351349744 0.2432512784
-0.6260618929 0.1374101779 0.2157848719 0.961592763 0.415921967 0.353980492 0.230097541
-0.7330616914 0.1273762692 0.200027919 1.005501028 0.426078972 0.356519743 0.2174012856
-0.8453509675 0.1178186184 0.1850188674 1.05042513 0.435888757 0.358972189 0.2051390534
-0.9633657791 0.1087123686 0.1707186825 1.096432391 0.44536883 0.361342207 0.1932889628
-1.0876141112 0.1000352987 0.1570924691 1.143596616 0.454535537 0.363633884 0.1818305787
-1.2186882282 0.0917676075 0.1441091318 1.191998815 0.463404164 0.365851041 0.170744795
-1.3572803535 0.0838917353 0.1317410955 1.241728049 0.471989017 0.367997254 0.1600137283
-1.5042026643 0.0763922207 0.1199640799 1.292882414 0.480303503 0.370075876 0.1496206216
-1.6171605149 0.0711518325 0.1117347296 1.331153526 0.486204593 0.371551148 0.1422442583
-1.8270480687 0.0624702737 0.0981014669 1.399911246 0.496170899 0.374042725 0.1297863765
-2.005467379 0.056026561 0.0879824514 1.456038528 0.503746712 0.375936678 0.1203166096
-2.1973111757 0.049916573 0.0783875073 1.514100048 0.511098074 0.377774518 0.1111274078
-2.4045791384 0.0441342757 0.0693071589 1.57426107 0.518234812 0.379558703 0.1022064846
-2.6297385261 0.0386755236 0.0607348963 1.636706775 0.525166192 0.381291548 0.0935422602
-2.8758762015 0.033538141 0.052667303 1.70164545 0.53190095 0.382975238 0.0851238122
-3.1469175481 0.0287220473 0.045104252 1.769312327 0.538447337 0.384611834 0.0769408289
-3.44795076 0.0242294325 0.0380491829 1.839974235 0.544813146 0.386203286 0.0689835678
-3.7857235314 0.0200649954 0.0315094743 1.913935271 0.551005747 0.387751437 0.0612428161
-4.1694347739 0.0162362572 0.0254969372 1.991543772 0.557032115 0.389258029 0.053709856
-4.612059449 0.012753971 0.0200284581 2.073200944 0.562898855 0.390724714 0.0463764315
-5.1327037855 0.0096326537 0.0151268339 2.159371632 0.568612226 0.392153056 0.0392347181
-5.761130032 0.0068912763 0.0108218561 2.250597892 0.574178164 0.393544541 0.0322772952
-6.5473971177 0.0045541631 0.0071517229 2.347516249 0.579602304 0.394900576 0.0254971203
-7.5856350039 0.0026521701 0.0041648894 2.450879894 0.584889996 0.396222499 0.0188875052
-9.0875680264 0.0012242417 0.001922513 2.561587548 0.590046325 0.397511581 0.012442094
-11.728812585 0.0003194898 0.0005017173 2.680721492 0.595076126 0.398769031 0.0061548429
-34.464325719 3.6083341E-09 5.666421E-09 2.809598388 0.599983999 0.399996 2.00008E-05
Hallando los parametros de interaccion binaria:

k
SUBGRUPO CH2 CH3
GRUPO PRINCIPAL 1 1
CH2 1 0 0
CH3 1 0 0
CHO 10 505.7 505.7

a11 0 a12 0 a13

a21 0 a22 0 a23
a31 505.7 a31 505.7 a33
 Θ1 Θ2 Θ3 P(mmhg) T (K) Pvp1 pvp2
0.231200917 0.36303477 0.405764313 574.07494129 313.15 870.0539833 573.8297672
0.242095554 0.369318433 0.3885860132 642.814965 313.15 870.0539833 573.8297672
0.252755712 0.375466855 0.3717774323 702.08463514 313.15 870.0539833 573.8297672
0.263132212 0.381451674 0.355416114 752.79945864 313.15 870.0539833 573.8297672
0.27330233 0.387317458 0.3393802123 796.38211275 313.15 870.0539833 573.8297672
0.283207284 0.393030304 0.3237624121 833.50117357 313.15 870.0539833 573.8297672
0.292878269 0.398608205 0.3085135258 865.12033537 313.15 870.0539833 573.8297672
0.302323479 0.404055887 0.2936206345 891.99512571 313.15 870.0539833 573.8297672
0.311550728 0.409377856 0.2790714157 914.78815817 313.15 870.0539833 573.8297672
0.320567476 0.414578415 0.2648541091 934.07948939 313.15 870.0539833 573.8297672
0.329380844 0.419661671 0.2509574848 950.37560541 313.15 870.0539833 573.8297672
0.337997637 0.424631549 0.237370814 964.11716585 313.15 870.0539833 573.8297672
0.346424358 0.4294918 0.2240838412 975.68561134 313.15 870.0539833 573.8297672
0.354667229 0.434246013 0.2110867583 985.40871831 313.15 870.0539833 573.8297672
0.362732201 0.438897619 0.1983701806 993.56516362 313.15 870.0539833 573.8297672
0.368505654 0.442227554 0.189266792 998.66167873 313.15 870.0539833 573.8297672
0.378350997 0.447906018 0.173742985 1006.0680423 313.15 870.0539833 573.8297672
0.385915507 0.452268975 0.161815518 1010.7542148 313.15 870.0539833 573.8297672
0.393323514 0.456541666 0.1501348201 1014.5557341 313.15 870.0539833 573.8297672
0.400579825 0.460726864 0.1386933114 1017.5411575 313.15 870.0539833 573.8297672
0.407689052 0.464827228 0.1274837195 1019.7371441 313.15 870.0539833 573.8297672
0.414655623 0.468845314 0.1164990637 1021.1258022 313.15 870.0539833 573.8297672
0.421483788 0.472783571 0.1057326409 1021.6405751 313.15 870.0539833 573.8297672
0.428177632 0.476644357 0.0951780115 1021.1604028 313.15 870.0539833 573.8297672
0.434741079 0.480429934 0.0848289869 1019.5018273 313.15 870.0539833 573.8297672
0.441177904 0.484142479 0.0746796173 1016.4086011 313.15 870.0539833 573.8297672
0.447491734 0.487784085 0.0647241802 1011.5382361 313.15 870.0539833 573.8297672
0.453686063 0.491356767 0.0549571698 1004.4447654 313.15 870.0539833 573.8297672
0.459764251 0.494862463 0.0453732866 994.55678365 313.15 870.0539833 573.8297672
0.465729533 0.498303038 0.0359674282 981.14956263 313.15 870.0539833 573.8297672
0.471585028 0.501680292 0.02673468 963.30969204 313.15 870.0539833 573.8297672
0.477333738 0.504995956 0.0176703063 939.89024407 313.15 870.0539833 573.8297672
0.482978558 0.508251699 0.0087697431 909.45387172 313.15 870.0539833 573.8297672
0.488522278 0.511449132 2.8589506E-05 870.20047981 313.15 870.0539833 573.8297672
 A12 A21
1.2465 1.4037
CHO
10
677
677
0
DIAGONAL
0 0
1 1
677
677
0
 y1 y2 y1+y2
0.000527023 0.999472977 1
0.133479488 0.866520512 1
0.229036611 0.770963389 1
0.300487439 0.699512561 1
0.35611421 0.64388579 1
0.400282774 0.599717226 1
0.436204265 0.563795735 1
0.465948864 0.534051136 1
0.490965713 0.509034287 1
0.512303443 0.487696557 1
0.530743683 0.469256317 1
0.546885276 0.453114724 1
0.561199374 0.438800626 1
0.574066697 0.425933303 1
0.585803573 0.414196427 1
0.593807881 0.406192119 1
0.6069376 0.3930624 1
0.616793112 0.383206888 1
0.626455282 0.373544718 1
0.636129296 0.363870704 1
0.6460255 0.3539745 1
0.656367712 0.343632288 1
0.667402617 0.332597383 1
0.679411096 0.320588904 1
0.692722686 0.307277314 1
0.707734836 0.292265164 1
0.724939557 0.275060443 1
0.744961499 0.255038501 1
0.768614164 0.231385836 1
0.796985595 0.203014405 1
0.831573784 0.168426216 1
0.874509432 0.125490568 1
0.92894014 0.07105986 1
0.999731685 0.000268315 1
 1

0.9

0.8

0.7

0.6

0.5
UNIFAC
Y

DATOS EXP.
diagonal
0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X
 1200

1000

800

600 x teorico Vs P
P

y teorico VS P
x exp Vs P
Y EXP. Vs P

400

200

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X-Y