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Assignment- Due 0n 30th of April 2019 (150 Pts)

*Keep space under each question before your print this. Work on the problem and Show your
work with needed steps under each question.

*Points are allocated to the steps in certain questions.

*Do Not answer in separate papers or in a separate page

*Assignment submission after the due date is not accepted

*Refer the text book for key equations, constant values and book values

1. Zn(s) + 2 HCl(aq) → H2(g) + ZnCl2(aq)

When 25.0 g of Zn reacts, how many L of H2 gas are formed at 25 °C and a pressure of
854 mmHg?

2. A sample of chlorine has two naturally occurring isotopes. The isotope Cl-35 (mass 35.0
amu) makes up 75.8% of the sample, and the isotope Cl-37 (mass = 37.0 amu) makes up
24.3% of the sample. What is the average atomic mass for chlorine?

3. In a sulfuric acid solution, where the [ H3O+] is 0.01 M, what is the pH?

4. Write the correctly balanced equation for the complete neutralization of H3PO4 with
Ca(OH)2?

5. In a neutralization reaction, how many moles of HClO4 react with 1 mole of Al(OH)3?

6. When solutions of KCl and Pb(NO3)2 are mixed, a precipitate forms. Write the balanced
equation for the double replacement reaction that occurs?

7. What is the concentration, in m/v percent, of a solution prepared from 50. g NaCl and 2.5
L of water?

8. How many moles of CaCl2 are in 250 mL of a 3.0 M of CaCl2 solution?

9. Use the reaction for Q 09:


2AgNO3(aq) + H2SO4(aq) → Ag2SO4(s) + 2H2O(l).
What volume of 0.123 M AgNO3(aq) is needed to form 0.657 g of Ag2SO4(s)?

10. What is the pressure, in mmHg, of a 4.00 g sample of O2 gas, which has a temperature of
30.0 °C, and a volume of 3000 mL?

11. A gas sample contains 4.0 g of CH4 and 2.0 g of He. What is the volume of the sample at
STP?

12. SO3 (g) + H2O (l) → H2SO4(l)


a. What is the classification of this reaction?
b. How many molecules of SO3 are present in 1.3 moles of SO3?
c. How many moles of water will be reacted with 2.5 g of SO3 when 15g of H2SO4
is produced?

13. When a volcano erupts, 175 g of steam at 100.0 °C is released. How many kilojoules are
lost when the steam condenses, then freezes, at 0.0 °C?
(Heat Vaporization = 2260 J/g , Specific heat = 4.184 J/g0C, Heat of Fusion = 334 J/g)

14. Draw the lewis structures for H20, NH3, CO2, CCl4 and BH3 (show all the steps for each
structure)

15. Name the following compounds


a. Na2SO4
b. SF6
c. N2O3
d. CCl4
e. Ba(NO2)2

16. Write the correct formula for following compounds.


a. Di phosphorous pentoxide
b. Hydrogen peroxide
c. Calcium sulfite
d. Hydrogen cyanide
17. Identify the physical state(s) corresponding to the regions on the cooling curve below.

18. A 2.5 g sample of smashed potatoes is placed in a calorimeter with 300.0 g of water at an
initial temperature of 25 °C. After combustion of the potatoes, the water has a
temperature of 47 °C. What is the caloric value (kcal/g) of the smashed potatoes?

19. How many calories are required to raise the temperature of a 35.0 g sample of iron from
25 °C to 35 °C? Iron has a specific heat of 0.108 cal/g °C.

20. A dose of mortrin of 5.0 mg per kilogram of body weight has been prescribed to reduce
the fever of an infant weighing 7.5 pounds. Calculate the number of milligrams of
mortrin that should be administered.

21. Write the electron configuration for Ca, P, N3-, Ar, S2-

22. Which of the answers for the following conversions contains the correct number of
significant figures?
a) 2.543 m × = 100.1942 in

b) 2 L × = 2.12 qt

c) 24.95 min × = 0.4158 hr

d) 12.0 ft × × = 370 cm

e) 24.0 kg × = 11 lb
23. A cheeseburger from a fast food restaurant contains 19 g of fat, 20. g of carbohydrate,
and 28 g of protein. How many kcal of energy does the cheeseburger contain? (The accepted
caloric values for foods are 4.0 kcal/g for carbohydrate, 9.0 kcal/g for fat, and 4.0 kcal/g for
protein.) Report the answer to 2 significant figures.
a) 70. kcal
b) 360 kcal
c) 400 kcal
d) 630 kcal
d) 280 kcal

24. How many calories are required to increase the temperature of 13 g of alcohol from 11 °C
to 23 °C? The specific heat of alcohol is 0.588 cal/g °C.
a) 83 cal
b) 0.63 cal
c) 92 cal
d) 0.54 cal
e) 170 cal

25. What is the abbreviated electron configuration for nickel (atomic number 28)?
A) [He]2s22p3
B) [Ar]4s23d8
C) [Kr]4s23d8
D) [Ar]4s24p4
E) [Ar]3d8